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Influence of Alloying Elements on Heat Resistance of Ni-Based Fillers and Brazed Joints 合金元素对镍基钎料及钎焊接头耐热性的影响
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-03-01 DOI: 10.1007/s11003-023-00711-4
S. Maksymova, V. Voronov, P. Kovalchuk, I. V. Zvolinsky
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引用次数: 2
Healing of Cracks in a Transtropic Elastic Body Under Torsion 扭转作用下正交弹性体裂纹的修复
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-03-01 DOI: 10.1007/s11003-023-00714-1
V. Sylovanyuk, N. А. Ivantyshyn, M. Filipov
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引用次数: 0
Plasma-Powder Surfacing of Alloys Based on Nickel and Cobalt on Copper 镍、钴基合金在铜表面的等离子粉末堆焊
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-03-01 DOI: 10.1007/s11003-023-00712-3
I. Ryabtsev, E. F. Perepletchikov, A. Babinets, I. Ryabtsev, I. Lentyuhov, I. L. Bogaichuk
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引用次数: 0
Room-temperature compressive creep behavior of Ti-6Al-4V ELI alloys with basketweave microstructure under an alternating compressive stress 交变压应力作用下Ti-6Al-4V篮组织ELI合金的室温压缩蠕变行为
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-02-24 DOI: 10.5755/j02.ms.31914
Hao-Hsiang Huang, Yu Zhang, Jiafei Lu, Z. Dan, Hui Chang, Lian Zhou
Titanium alloys have great potential as candidate materials for the deep-sea facilities. Long-term creep deformation behavior of the pressure-bearing structures made of titanium alloys under alternating compressive stress has a direct impact on the structural stability. The compressive creep evaluations of Ti-6Al-4V ELI alloys with basketweave microstructure under alternating stresses have been carried out by a uniaxial compressive creep tester. The compressive creep deformations have strong stress sensitivity due to the larger creep strain by the higher applied compressive stress. The dislocation densities in α and β phases increase with the increase of applied compressive stresses. The dislocation slip and dislocation multiplication occur in α phases accompanying with high dislocations density in β phases caused by compressive deformation. The large strain concentration occurs at the grain boundaries of α/β phase due to dislocation plug after creep, which causes the grain boundary pinning. The compressive creep deformation of Ti-6Al-4V ELI alloys under alternating stress is a decelerating creep process and controlled by dislocation slip. The slight refinements of the grains and hardening have been confirmed after creeps. The synergistic effects of dislocation multiplication, grain boundary pinning and grain refinements lead to strengthening the Ti-6Al-4V ELI alloys and decelerating the compressive creeps.
钛合金作为深海设施的候选材料具有巨大的潜力。钛合金承压结构在交变压应力作用下的长期蠕变变形行为直接影响结构的稳定性。用单轴压缩蠕变试验机对具有篮编织组织的Ti-6Al-4V ELI合金在交变应力作用下的压缩蠕变进行了评价。压缩蠕变变形具有较强的应力敏感性,这是由于施加的压缩应力越大,蠕变应变越大。α相和β相中的位错密度随着施加的压应力的增加而增加。位错滑移和位错增殖发生在α相中,伴随着压缩变形引起的β相中的高位错密度。蠕变后,由于位错塞的作用,α/β相的晶界产生了较大的应变集中,导致晶界钉扎。Ti-6Al-4V ELI合金在交变应力作用下的压缩蠕变变形是一个由位错滑移控制的减速蠕变过程。蠕变后证实了晶粒的轻微细化和硬化。位错增殖、晶界钉扎和晶粒细化的协同作用导致Ti-6Al-4V ELI合金的强化和压缩蠕变的减速。
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引用次数: 0
Diffusion and Thermal Shock Behaviour of Silicate Dental Ceramics 硅酸盐牙科陶瓷的扩散和热冲击行为
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-02-24 DOI: 10.5755/j02.ms.30414
B. Ertuğ
The purpose of this study is to examine the diffusion and thermal shock behaviour of the alternative dental silicates. The samples derived from BaO-SiO2 system have been produced by melting process and followed by the heat treatment. X-ray examinations have indicated that the amount of orthorhombic sanbornite phase rised due to treatment temperature as revealed by the peak intensities. The alteration of the morphology by treatment temperature was evident from scanning electron microscopy SEM images. Crystallization at low temperature produced small crystallites and coarsening was not observed with a rise in temperature. The failure of the dental samples after the thermal shock test was examined using SEM. A continuous crack geometry and very few crack branching were observed. Diffusivity constant (D) and diffusion rate were examined vs treatment temperature for the present system. Diffusion depth (L) was doubled when the crystallization treatment was applied. Based on the obtained results, these silicate samples might take part in the further characterization studies to be used as alternative dentistry materials.
本研究的目的是研究替代牙科硅酸盐的扩散和热冲击行为。采用熔融法制备了BaO-SiO2体系样品,并对样品进行了热处理。x射线检查表明,由于处理温度的升高,正交三斑岩相的数量增加,如峰值强度所示。从扫描电镜(SEM)图像可以看出,处理温度对合金形貌的影响是明显的。低温结晶产生小晶粒,温度升高时未观察到粗化现象。用扫描电子显微镜观察热冲击试验后牙体试样的破坏情况。裂纹几何形状连续,裂纹分支极少。测定了该体系的扩散系数常数(D)和扩散速率随处理温度的变化。结晶处理使扩散深度(L)增加了一倍。基于所获得的结果,这些硅酸盐样品可能会参与进一步的表征研究,以用作替代牙科材料。
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引用次数: 0
Stress Field Simulation and its Experimental Verification of Carburizing-Quenching Process Performed on 18CrNiMo7-6 Steel 18CrNiMo7-6钢渗碳淬火过程应力场模拟及试验验证
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-02-24 DOI: 10.5755/j02.ms.30932
S. Qin, H. Ma, Lianxiang Wang
The carburizing and quenching process of 18CrNiMo7-6 steel was performed through simulation methods and experiments. The study was carried out to accurately predict the residual stress distribution of carburized samples after the quenching process. The stress and retained-austenite amount were measured via X-ray diffraction. Similarly, the carbon content was determined using a carbon sulfur analyzer, respectively. A detailed model with the coupling of thermal, metallic, and mechanical fields was built to predict the evolution of the stress field during the quenching process. The carburized “thoroughly” specimens at different carbon potentials were used to obtain the required mechanical property parameters and dilatometric parameters for FEM simulation. According to the results, the martensite transformation kinetic parameters α value of 18CrNiMo7-6 alloy steel should be 0.0202. With the increase of carbon content, the changing trend of the transformation plasticity coefficient K appeared as a 'tick' shape. A compressive residual stress field was generated at the carburized layer surface after the quenching process, and the maximum value of 340 MPa occurred at ~ 0.9 mm below the surface. The carbon profile and residual stress fields predicted from the FEM simulation corresponded closely to the experimentally determined results.
通过模拟方法和实验,对18CrNiMo7-6钢的渗碳淬火过程进行了研究。本研究旨在准确预测渗碳试样淬火后的残余应力分布。通过X射线衍射测量应力和残余奥氏体量。类似地,分别使用碳硫分析仪测定碳含量。建立了热场、金属场和机械场耦合的详细模型,以预测淬火过程中应力场的演变。使用不同碳势的渗碳“彻底”试样来获得有限元模拟所需的力学性能参数和膨胀参数。结果表明,18CrNiMo7-6合金钢的马氏体相变动力学参数α值应为0.0202。随着碳含量的增加,转变塑性系数K呈“蜱”形变化。淬火过程后,渗碳层表面产生压缩残余应力场,最大值340MPa出现在表面以下~0.9mm处。有限元模拟预测的碳分布和残余应力场与实验确定的结果非常一致。
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引用次数: 1
Combinatorial Effects of the Recipes of the Initial Gas-atomized Powder Sizes on Microstructure and Passivation Characteristics of the SLM-ed Ti-6Al-4V Bulk Alloys 初始气体雾化粉末尺寸配方对SLM化Ti-6Al-4V大块合金组织和钝化特性的组合影响
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-02-24 DOI: 10.5755/j02.ms.31220
Yu Zhang, Jiazhuo Lei, Z. Dan, Hui Chang, Lian Zhou
Bulk Ti-6Al-4V alloys have been fabricated by selective laser melting (SLM) in three recipes with different combinations of powder sizes. Combinatorial effects of initial gas-atomized powder sizes on microstructure and corrosion properties of SLM-ed Ti-6Al-4V alloys have been investigated by optical microscopy, X-ray diffraction, electrochemical measurements and surface free energy. The SLM-ed Ti-6Al-4V alloys are composed of acicular α' martensite and α phases. Many pinhole defects and twin boundaries exist in the SLM-ed Ti-6Al-4V alloys. According to electrochemical tests and surface free energy calculation, the SLM-ed Ti-6Al-4V alloys with 0 – 53 μm powders have the most positive corrosion potential, the lowest current density and the smallest surface free energy of 20.89 mJ m2. The passive film of SLM-ed Ti-6Al-4V alloys with 0 – 53 μm powders has superior protection ability due to their large thickness. The carrier concentration of SLM-ed Ti-6Al-4V alloys with 0 – 53 μm powders is the lowest by the Mott-Schottky curves. The SLM-ed samples with contact angles higher than 90º are hydrophobic, but the small contact angle of 46.98º reflects the hydrophilic features of as-rolled Ti-6Al-4V alloys. The combinatorial recipe of SLM-ed Ti-6Al-4V alloys with 0 – 53 μm powders is optimal for improvements on the corrosion resistance.
采用三种不同粉末尺寸组合的配方,通过选择性激光熔化(SLM)制备了大块Ti-6Al-4V合金。用光学显微镜、X射线衍射、电化学测量和表面自由能等方法研究了初始气体雾化粉末尺寸对SLM化Ti-6Al-4V合金微观结构和腐蚀性能的组合影响。SLM-ed Ti-6Al-4V合金由针状α′马氏体和α相组成。SLM-edTi-6Al-4V合金中存在许多针孔缺陷和孪晶边界。根据电化学测试和表面自由能计算,0–53μm粉末的SLM-ed Ti-6Al-4V合金具有最大的正腐蚀电位、最低的电流密度和最小的表面自由能,为20.89 mJ m2。0–53μm粉末SLM修饰的Ti-6Al-4V合金钝化膜厚度大,具有优异的保护能力。根据Mott-Schottky曲线,0–53μm粉末的SLM-ed Ti-6Al-4V合金的载流子浓度最低。接触角大于90º的SLM-ed样品具有疏水性,但46.98º的小接触角反映了轧制态Ti-6Al-4V合金的亲水性特征。SLM-ed Ti-6Al-4V合金与0–53μm粉末的组合配方对于提高耐腐蚀性是最佳的。
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引用次数: 0
Effects of Nanomaterials Reinforced Aggregate on Mechanical Properties and Microstructure of Recycled Brick Aggregate Concrete 纳米材料增强骨料对再生砖骨料混凝土力学性能和微观结构的影响
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-02-22 DOI: 10.5755/j02.ms.32715
Ting Wang, Qingshan Wang, Shenao Cui, Haihe Yi, Tian Su, Zhenyu Tan
In this paper, the effects of nano-SiO2 and nano-Al2O3 on the brick aggregate properties, compressive strength of brick aggregate concrete at different ages, and microstructure of brick aggregate concrete are investigated. The results show that the water absorption of recycled brick aggregate decreases with the increase of nanomaterials solution concentrations, and the crush index of recycled brick aggregate decreases. Nano-SiO2 and nano-Al2O3 improve the compressive strength of recycled brick aggregate concrete at different ages, and the effect of nanomaterials on the early strength of concrete are more obvious. With the increase of nano-solution concentration, the compressive strength of nano-SiO2 reinforced brick aggregate concrete increases first and then decreases, while that of nano-Al2O3 reinforced brick aggregate concrete increases. The internal structure of nanomaterials reinforced brick aggregate is denser, micro cracks and pores are filled with hydration products, and the interfacial transition zone is more compact.
本文研究了纳米SiO2和纳米Al2O3对砖骨料性能、不同龄期砖骨料混凝土抗压强度和砖骨料混凝土微观结构的影响。结果表明,随着纳米材料溶液浓度的增加,再生砖集料的吸水率降低,再生砖骨料的压碎指数降低。纳米SiO2和纳米Al2O3提高了再生砖骨料混凝土不同龄期的抗压强度,纳米材料对混凝土早期强度的影响更为明显。随着纳米溶液浓度的增加,纳米SiO2增强砖骨料混凝土的抗压强度先增大后减小,而纳米Al2O3增强砖骨料的抗压强度增大。纳米材料增强砖骨料的内部结构更致密,微裂缝和孔隙中充满了水化产物,界面过渡区更紧密。
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引用次数: 1
Calcium phosphate brushite cements made from substituted tricalcium phosphate Ca3(PO4)2 and reinforced with silicate glass fiber 由取代的磷酸三钙Ca3(PO4)2制成并用硅酸盐玻璃纤维增强的磷酸钙-刷石水泥
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-02-21 DOI: 10.31044/1684-579x-2023-0-5-19-27
Sharifjon A Musoev, A. Knotko, Y. Filippov
The reinforcement of reaction hardening phosphate materials (phosphate cements) for bone implants, based on isomorphically cation- (Na+, K+) and anion- (SiO44-, SO42-) substituted tricalcium phosphate (β and α-TCP, Ca3(PO4)2), that are reinforced with silicate (basalt-based) fiberglass, is considered. The obtained materials were characterized by the XRD and SEM methods, mechanical compression tests were carried out, the setting times of cements were determined, changes in the pH of the aqueous medium in contact with the cements under study were measured. Microstructure analysis has been shown that the surface of the reinforcing fiber in contact with the matrix of hardening cement is partially corroded with the formation of phosphate microparticles on it. By pH-metry it was found that the samples during prolonged contact with water do not significantly change the pH value of the aquatic environment, which remains in the nearly neutral range from 5 to 7.5, favorable for further biological tests.
考虑了基于同构阳离子-(Na+,K+)和阴离子-(SiO44-,SO42-)取代的磷酸三钙(β和α-TCP,Ca3(PO4)2),用硅酸盐(玄武岩基)玻璃纤维增强的骨植入物反应硬化磷酸盐材料(磷酸盐水泥)的增强。通过XRD和SEM方法对所获得的材料进行了表征,进行了机械压缩试验,确定了水泥的凝结时间,测量了与所研究的水泥接触的水介质的pH值的变化。微观结构分析表明,与硬化水泥基体接触的增强纤维表面被部分腐蚀,并在其上形成磷酸盐微粒。通过pH测定发现,样品在长时间与水接触时,不会显著改变水环境的pH值,其保持在从5到7.5的几乎中性的范围内,有利于进一步的生物测试。
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引用次数: 0
Synthesis of Carboxymethyl Cellulose-Acrylate-OvPOSS Graft Copolymer and its Application in Paper Protection 羧甲基纤维素-丙烯酸酯OvPOSS接枝共聚物的合成及其在纸张防护中的应用
IF 1.1 4区 材料科学 Q3 Engineering Pub Date : 2023-02-13 DOI: 10.5755/j02.ms.29181
Jinjie Zhang, Yingping Qi, Yongfeng Shen, Hua Li
As an important part of cultural heritage, paper cultural relics have important historical, scientific and humanistic values. However, a large number of paper cultural relics are suffering from aging, mildew, yellowing, cracks, embrittlement and other threats, or are even completely damaged. To enhance the strength of paper cultural relics and prolong the life of paper cultural relics, a novel CMC-acrylate-OVPOSS graft copolymer was synthesized with carboxymethyl cellulose (CMC), methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA), octavinyl polyhedral oligomeric silsesquioxane (OVPOSS). The synthesized materials were analyzed by infrared spectroscopy, X-ray diffractometer, thermal analyzer and X-ray photoelectron spectroscopy. In addition, the reinforcement solution was coated on the surface of the paper, and the protective effect of the reinforcement solution on the paper was evaluated by testing the mechanical and optical properties of the paper. When the reinforcement solution with a mass concentration of 10 % was coated on the paper, the mechanical properties of the paper were greatly improved, and the gloss and whiteness were basically unchanged.
纸质文物作为文化遗产的重要组成部分,具有重要的历史、科学和人文价值。然而,大量纸质文物正遭受着老化、霉变、发黄、开裂、脆化等威胁,甚至完全损毁。为了提高纸质文物的强度,延长纸质文物的使用寿命,以羧甲基纤维素(CMC)、甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)、甲基丙烯酸酯羟乙酯(HEMA)、甲基缩水甘油酯(GMA)、八乙烯基多面体低聚倍半硅氧烷(OVPOSS)为原料,合成了一种新型的CMC-丙烯酸酯OVPOSS接枝共聚物。用红外光谱、X射线衍射仪、热分析仪和X射线光电子能谱对合成的材料进行了分析。此外,将增强溶液涂覆在纸张表面,并通过测试纸张的机械和光学性能来评估增强溶液对纸张的保护作用。当质量浓度为10%的增强溶液涂布在纸上时,纸的机械性能大大提高,光泽度和白度基本不变。
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引用次数: 1
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Materials Science-Poland
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