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A review of the research progress of composite bipolar plates for proton exchange membrane fuel cells with different substrate materials 不同基底材料质子交换膜燃料电池复合双极板研究进展综述
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.517.2023
Yutian Zeng
As an important component in proton exchange membrane fuel cells, the performance of bipolar plates, such as electrical conductivity, bending strength, corrosion resistance, gas tightness, etc., directly determines the lifetime of fuel cells and their promotion applications. Composite bipolar plates have become a research hotspot and have been applied and promoted in related fields because of their strong design, flexible formulation, excellent performance, low cost, and applicability to various operating environments. This paper analyzes in detail the research progress of composite bipolar plates using different matrix materials, briefly analyzes and introduces the research on improving the performance of composite bipolar plates, and makes an outlook on the future development trend of composite bipolar plates for proton exchange membrane batteries.
作为质子交换膜燃料电池的重要组成部分,双极板的导电性、抗弯强度、耐腐蚀性、气密性等性能直接决定了燃料电池的使用寿命和推广应用。复合双极板因其设计性强、配方灵活、性能优异、成本低廉、适用于各种工作环境等特点,已成为研究热点,并在相关领域得到应用和推广。本文详细分析了采用不同基体材料的复合双极板的研究进展,简要分析和介绍了提高复合双极板性能的研究,并对质子交换膜电池用复合双极板的未来发展趋势进行了展望。
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引用次数: 0
Advances in Nickel-cobalt Electrode Materials for Supercapacitors 超级电容器用镍钴电极材料的研究进展
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.610.2023
Linkun Sun, Yuxuan Zhang
With the rapid development of society, supercapacitors have been widely studied in energy storage devices for their unique advantages of high energy density, good cycle stability, fast charge and discharge speed. However, the development of supercapacitors is limited by low energy density. To address this challenge, it is important to develop and prepare electrode materials with excellent electrochemical properties for supercapacitors. To improve the energy density of supercapacitors, nickel-cobalt electrode materials have been widely studied due to their advantages of high energy density, high safety and long life. In this review, the research progress in material morphology and microstructure of supercapacitors prepared from nickel-cobalt metal oxides/hydroxides, sulfides, selenides and phosphates in recent years is summarized and prospected.
随着社会的快速发展,超级电容器以其能量密度高、循环稳定性好、充放电速度快等独特优势,在储能设备中得到了广泛的研究。然而,由于能量密度低,超级电容器的发展受到了限制。为应对这一挑战,开发和制备具有优异电化学性能的超级电容器电极材料非常重要。为了提高超级电容器的能量密度,镍钴电极材料因其能量密度高、安全性高和寿命长等优点而被广泛研究。本综述总结并展望了近年来利用镍钴金属氧化物/氢氧化物、硫化物、硒化物和磷酸盐制备超级电容器的材料形态和微观结构的研究进展。
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引用次数: 0
Study on diel migration of zooplankton in the Arctic surrounding seas during summer season based on mathematical statistics 基于数理统计的北极周边海域浮游动物夏季昼夜迁移研究
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.570.2023
Leyi Wang
Marine zooplankton have diel vertical migration behavior and play a key role in the transport of surface organic compounds to the deep ocean, which is of great significance in studying marine climate change. In this research, the manual visual interpretation method was used to preprocess the biological backscattering intensity data of acoustic Doppler current profiler (ADCP) during the eighth Arctic expedition. Results showed that the extracted vertical migration trajectory was in good agreement with the variation of backscattering intensity data. The amount of zooplankton in the Arctic Ocean is significantly lower than that in the North Pacific and the North Atlantic, and sea ice cover has a significant effect on the diel vertical migration of zooplankton. Characteristics of zooplankton distribution in the North Atlantic Ocean were analyzed based on mathematical statistical methods. The results also prove that the backscattering intensity of -90dB can distinguish scattering layer and water, and that of -78dB can distinguish general scatters and zooplankton. There are two significant concentrations of zooplankton in the Atlantic Ocean which were located at the surface and at depths of 350-450 m, respectively.
海洋浮游动物具有昼夜垂直迁移行为,在表层有机化合物向深海的迁移中起着关键作用,对研究海洋气候变化具有重要意义。本研究采用人工目视判读方法对第八次北极考察期间声学多普勒海流剖面仪(ADCP)的生物反向散射强度数据进行了预处理。结果表明,提取的垂直洄游轨迹与反向散射强度数据的变化非常吻合。北冰洋浮游动物数量明显低于北太平洋和北大西洋,海冰覆盖对浮游动物的昼夜垂直洄游有显著影响。基于数理统计方法分析了北大西洋浮游动物的分布特征。结果还证明,-90 分贝的后向散射强度可以区分散射层和水,-78 分贝的后向散射强度可以区分一般散射层和浮游动物。大西洋的浮游动物有两个重要的聚集区,分别位于海面和 350-450 米深处。
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引用次数: 0
The micro-structure and mechanical performance of Nickel-based single crystal alloy 镍基单晶合金的微观结构和机械性能
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.683.2023
ZiHeng Guang
Because of the increasing temperature in front of turbine in aero-engine field, Ni-base single crystal alloys are of high demand, which achieve high strength at high temperature. Therefore, a variety of methods have been developed to detect or describe nickel-base single crystal alloys. This article will take stock of the alloy valve and the mainstream description of valve methods. This paper will describe the basic micro-mechanism of rafting. Then the channel width method, which is the most widely used method to describe the degree of rafting, is introduced. After that, the updated version of the channel width method, the method to describe the rate of rafting and the effect on its strength, and the related methods of image processing are described. It is hoped that this paper can help readers to have a preliminary understanding of the principle and mathematical description method of nickel-base alloy rafting. There are many branches of mathematical description, but the main ideas are very similar. It is hoped that the researchers concerned will be able to develop some mathematical models that require fewer measurement parameters but not reducing the overall accuracy of the measuremen.
由于航空发动机领域涡轮前的温度不断升高,因此对在高温下具有高强度的镍基单晶合金的需求量很大。因此,人们开发了多种方法来检测或描述镍基单晶合金。本文将对合金阀和主流的阀描述方法进行盘点。本文将描述筏式的基本微观机制。然后介绍描述筏化程度最广泛使用的沟道宽度法。然后,介绍通道宽度法的最新版本、描述筏形化速度及其对强度影响的方法以及图像处理的相关方法。希望本文能帮助读者初步了解镍基合金筏形的原理和数学描述方法。数学描述的分支很多,但主要思想非常相似。希望相关研究人员能够开发出一些数学模型,在不降低整体测量精度的前提下,减少对测量参数的要求。
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引用次数: 0
Synthesis of hydrogen-bond-enriched, fluorescent and triboelectric hyperbranched polymers via Michael addition reaction 通过迈克尔加成反应合成富含氢键、荧光和三电超支化聚合物
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.645.2023
Ziyi Qiu, Weiying Li
It is very meaningful to realize color recognition and mechanical-electrical energy conversion in one material simultaneously, which is very essential in improving the equipment of border guards. However, simultaneously endowing one material with color regonition and mechanical-electrical energy conversion presents challenges because they result from different mechanism. Herein, a series of hyperbranched polymers, HP9, HP10, and HP11, were synthesized via the Michael addition reaction to solve the dilemma. Extensive hydrogen bonding was embedded into these hyperbranched polymers, so that the polymers exhibit good triboelectrification ability. The voltage output is about 347 V, the current output is about 2.8 μA, and the charge quantity is about 150 nC, respectively. Moreover, the polymers display excellent fluorescence under 365 nm ultraviolet light based on the mechanism of aggregation-induced emission (AIE). Furthermore, the thermodynamic behavior and mechanical properties of the hyperbranched polymers can be regulated by adjusting the content of the hard segments. The Young's modulus and strength gradually increase with the increase of the hard segment unit. The Young’s modulus, strength and toughness of HP10 are 3.72 MPa, 2.69 MPa and 19.55 MJ/m3, respectively. The combination of fluorescence and frictional electrification will have great application potential in the equipment of border guards.
在一种材料中同时实现色彩识别和机械电能转换是非常有意义的,这对改善边防装备非常重要。然而,同时赋予一种材料颜色识别和机械电能转换功能是一项挑战,因为它们产生于不同的机理。为了解决这一难题,我们通过迈克尔加成反应合成了一系列超支化聚合物 HP9、HP10 和 HP11。在这些超支化聚合物中嵌入了广泛的氢键,因此这些聚合物具有良好的三电化能力。其电压输出约为 347 V,电流输出约为 2.8 μA,电荷量约为 150 nC。此外,基于聚集诱导发射(AIE)机制,聚合物在 365 纳米紫外线下显示出优异的荧光性能。此外,超支化聚合物的热力学行为和力学性能可通过调整硬段的含量来调节。杨氏模量和强度随着硬段单元的增加而逐渐增大。HP10 的杨氏模量、强度和韧性分别为 3.72 兆帕、2.69 兆帕和 19.55 兆焦耳/立方米。荧光和摩擦电化的结合将在边防装备中具有巨大的应用潜力。
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引用次数: 0
Research on Advanced Treatment Technology of Fluorine Containing Wastewater from Graphite Production 石墨生产含氟废水先进处理技术研究
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.638.2023
Yanli Liu, Iyang Qiao, Xiang Ma, Zhilong Zhao, Fengbiao Liu, Shifu Shen
With the gradual improvement of environmental emission requirements in China, the graphite industry is facing environmental pressure from advanced treatment. This article first conducted a study on the current status of advanced treatment technology for fluorinated wastewater. Subsequently, a single defluorination agent experiment was conducted, and it was found that compared to several agents used in the experiment, such as PAC, PAFS, and CaCl2, PAC had the best defluorination effect. The optimization of PAC conditions showed that its optimal reaction pH was 7, and equilibrium could be achieved after 3 minutes of reaction. The study also conducted orthogonal experiments with mixed salts, and the best conditions for the combination of fluoride removal agents were found to be PAC adding 400 mg/L, CaCl2 adding 400 mg/L, PAFS adding 200 mg/L, which can remove fluoride to 0.92 mg/L, below 1 mg/L, meeting the Class III water standard in the " Environmental quality standards for surface water ".The SEM image of the sludge generated by the reaction between the composite fluoride removal agent and fluoride containing wastewater shows a larger particle size of up to 50 μm which is beneficial for the separation and removal of sludge. The generated sediment sludge is mainly composed of Al, Fe, Ca, O, and Si according to EDS results, and belongs to general industrial solid waste.
随着我国环保排放要求的逐步提高,石墨行业面临着先进处理带来的环保压力。本文首先对含氟废水深度处理技术的现状进行了研究。随后,进行了单一除氟剂实验,发现与实验中使用的 PAC、PAFS、CaCl2 等几种除氟剂相比,PAC 的除氟效果最好。对 PAC 条件的优化表明,其最佳反应 pH 值为 7,反应 3 分钟后即可达到平衡。研究还进行了混合盐的正交实验,发现除氟剂组合的最佳条件为 PAC 加入量为 400 mg/L,CaCl2 加入量为 400 mg/L,PAFS 加入量为 200 mg/L,可将氟化物去除到 0.复合除氟剂与含氟废水反应生成的沉淀污泥的扫描电镜图像显示,其粒径较大,可达 50 μm,有利于污泥的分离和去除。根据 EDS 结果,生成的沉淀污泥主要由 Al、Fe、Ca、O 和 Si 组成,属于一般工业固体废物。
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引用次数: 0
Habitat Suitability Evaluation and Environmental Factor Identification for Spatial Distribution of Urban Birds: A Case Study of Hongshan District, Wuhan City, China 城市鸟类空间分布的栖息地适宜性评价与环境因子识别:中国武汉市洪山区案例研究
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.557.2023
Bidan Yin, Xingyu Chai
The article takes 11 species of birds in Hongshan District as the research object based on the bird observation data 2020 and then identifies the spatial distribution of their habitats through the MaxEnt model. According to the results, we analyze the distribution characteristics and problems of bird habitats in Hongshan District and finally put forward the optimization suggestions according to the cohort groups. We conclude that water habitats and urban forest parks have higher suitability for bird spatial distribution and that the influence of various environmental factors on different types of birds is somewhat different. Based on the data analysis results, we provide references for the conservation of bird diversity and habitat restoration in Hongshan District: (1) Control the area of construction land and the number of high-rise buildings to make room for bird migration, enhance gene exchange among birds in different patches, and enrich species diversity. (2) Increase the number of bird migration “stations” between long-distance habitat patches to provide resting points for birds during long-distance migration. (3) Increase the number of bird migration "stations" between long-distance habitat patches to provide resting points for birds in the urban forest park. (4) Adopt tree-shrub-grass planting to provide more living space for birds. (5) Reserve a green corridor around urban roads and water systems to reduce the impact of urban roads on the distribution pattern of bird suitability.
文章以2020年鸟类观测数据为基础,以洪山区11种鸟类为研究对象,通过MaxEnt模型确定其栖息地的空间分布。根据研究结果,分析了洪山区鸟类栖息地的分布特征及存在的问题,最后根据群组情况提出了优化建议。我们得出结论:水域栖息地和城市森林公园对鸟类空间分布的适宜度较高,各种环境因素对不同类型鸟类的影响存在一定差异。根据数据分析结果,我们为洪山区鸟类多样性保护和栖息地恢复提供参考:(1)控制建设用地面积和高层建筑数量,为鸟类迁徙腾出空间,加强不同斑块鸟类间的基因交流,丰富物种多样性。(2) 增加远距离栖息地之间的鸟类迁徙 "驿站 "数量,为鸟类远距离迁徙提供休息点。(3) 增加远距离栖息地之间的鸟类迁徙 "驿站 "数量,为城市森林公园中的鸟类提供休息点。(4) 采用树-灌木-草的种植方式,为鸟类提供更多的生存空间。(5) 在城市道路和水系周围保留绿色走廊,以减少城市道路对鸟类适宜性分布格局的影响。
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引用次数: 0
The Effects of Mist Cannon Trucks on Human Health and Reducing Dust 喷雾炮车对人体健康和减少粉尘的影响
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.510.2023
Yihan Xu
More and more attention has been paid to dust removal by Mist Cannon Trucks (MCT). It is necessary to study the effect and influencing factors of dust removal by MCT. This study discusses the effectiveness and hazards of using MCT to reduce airborne dust by conducting lead testing, color identification, pH testing, and chlorine testing on collected samples. The results show that dust can be significantly reduced by MCT, and the effect of fog cannon decreases with the increase of distance. The MCT is currently safe for pedestrians because it has very few corrosive and toxic substances, and the lead content is also very low, which is below the safe value. At the same time, the sprayed water captured a lot of dust compared to the water in the tank. The main harm to the human body is the excessive lead content in water..
雾炮车(MCT)除尘越来越受到关注。有必要研究 MCT 除尘的效果和影响因素。本研究通过对收集的样本进行铅测试、颜色鉴定、pH 值测试和氯测试,讨论了使用 MCT 减少空气中粉尘的效果和危害。结果表明,MCT 可以显著减少灰尘,而且雾炮的效果会随着距离的增加而减弱。目前,MCT 对行人是安全的,因为它的腐蚀性和有毒物质很少,铅含量也很低,低于安全值。同时,与水箱中的水相比,喷出的水捕获了大量灰尘。对人体的主要危害是水中铅含量过高。
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引用次数: 0
The Coupling Effects Between Floating Insulation Plates and the Thermal Convection in their Bottoms---- An Understanding of Continental Drift 浮动隔热板与其底部热对流之间的耦合效应---- 对大陆漂移的理解
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.664.2023
Chenlin Fang, Siyuan Wang
The phenomenon of dumpling drift was discovered during a cooking process, which triggered our thinking of the continental drift. After refining the existing common problems, an experiment on the thermal convection interaction between the floating heat insulation plates and the bottoms is designed. Through controlling variables, this paper investigates the floating patterns of floating insulation plates of different sizes on a thermally convective surface and the principles behind them. The findings show that the appropriate sizing of a floating plate can result in the manifestation of cyclic reciprocating movement on the water’s surface. The periodic movement observed in this phenomenon can be attributed to the obstruction of heat exchange between the water surface and the surrounding air by the floating plate. Consequently, alterations in the direction of water flow induce corresponding shifts in water temperature, which subsequently affect the movement direction of the floating plate. The final outcome is characterized by a periodic reciprocal movement of the floating plate as it interacts with the heat convection occurring at the bottom. Floating plates that are either undersized or oversized would remain stationary without exhibiting any cyclic drift. The decrease in water depth leads to a diminished thermal drive, thereby amplifying the cyclical nature of the motion shown by the floating plate. The above findings indicate that the dimensions of the continental plates present on the Earth's surface have an impact on both the velocity and duration of their movement. The observation that a plate that is too small stagnates on top of a subduction current, while a plate that is too large stagnates on top of an upwelling current, suggests that the smaller continent of New Zealand is likely to experience a decrease in elevation due to its location above a subduction current. Conversely, the larger continent of Africa is expected to undergo uplift and attain a higher elevation as a result of its position above an upwelling current.
在一次烹饪过程中发现的饺子漂移现象,引发了我们对大陆漂移的思考。在对现有共性问题进行提炼后,设计了浮动隔热板与底部热对流相互作用的实验。通过控制变量,本文研究了不同尺寸的浮动隔热板在热对流表面的浮动规律及其背后的原理。研究结果表明,适当的浮动隔热板尺寸可以使其在水面上表现出周期性的往复运动。这一现象中观察到的周期性运动可归因于浮板阻碍了水面与周围空气之间的热交换。因此,水流方向的改变会引起水温的相应变化,进而影响浮板的运动方向。最终的结果是浮板在与底部发生的热对流相互作用时周期性地往复运动。尺寸过小或过大的浮板将保持静止,不会出现任何周期性漂移。水深的减小导致热驱动力的减弱,从而放大了浮板运动的周期性。上述发现表明,地球表面大陆板块的尺寸对其运动速度和持续时间都有影响。过小的板块会停滞在俯冲流之上,而过大的板块则会停滞在上升流之上,这一观察结果表明,较小的新西兰大陆由于位于俯冲流之上,海拔很可能会下降。相反,较大的非洲大陆由于位于上升流之上,预计会发生隆起,海拔会升高。
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引用次数: 0
High-performance supramolecular ionogel synthesized via click chemistry 通过点击化学合成高性能超分子离子凝胶
Pub Date : 2023-11-15 DOI: 10.56028/aetr.8.1.655.2023
Yanran Zhu
The development of high-strength ionogels is of great significance for high-performance flexible sensing and soft robots. However, the introduction of ionic liquids will cause a decrease in the modulus and strength of ionogels and can cause unnecessary leakage problems. This poses a challenge for designing high-strength ionogels. In this work, based on the design concept of click chemistry, a modular polymer is constructed. The polymer self-assembled a phase-separated microstructure between soft phase and hard phase, exhibiting an ionic liquid-free, flexible, high-strength characteristic. By adjusting the molar ratio of the hard segment and the soft segment, it endows ionogels with various mechanical properties. When the content of hard segment increases from 5mol% to 20mol%, the Young’s modulus of the ionogel increases from 4.37 MPa, 25.17 MPa to 129.94 MPa, the strength increases from 4.34 MPa, 9.67 MPa to 18.39 MPa, and the elongation at break decreases from 1129%, 1063% to 797%, respectively. Meanwhile, the supramolecular ionogel shows good stress-sensing ability and stability, which has promoted the development of high-performance flexible sensing and soft robots.
开发高强度离子凝胶对高性能柔性传感和软机器人具有重要意义。然而,离子液体的引入会导致离子凝胶的模量和强度降低,并可能引起不必要的泄漏问题。这给高强度离子凝胶的设计带来了挑战。本研究基于点击化学的设计理念,构建了一种模块化聚合物。该聚合物在软相和硬相之间自组装出一种相分离的微结构,表现出不含离子液体、柔韧、高强度的特性。通过调整硬段和软段的摩尔比,它可以赋予离子凝胶各种机械性能。当硬段含量从 5mol% 增加到 20mol% 时,离子凝胶的杨氏模量分别从 4.37 MPa、25.17 MPa 增加到 129.94 MPa,强度分别从 4.34 MPa、9.67 MPa 增加到 18.39 MPa,断裂伸长率分别从 1129%、1063% 下降到 797%。同时,超分子离子凝胶具有良好的应力传感能力和稳定性,促进了高性能柔性传感和软机器人的发展。
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引用次数: 0
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