首页 > 最新文献

Journal of Building Physics最新文献

英文 中文
Coupled hygrothermal and mechanical simulations of highly anisotropic building material during freezing and thawing 高各向异性建筑材料在冻结和融化过程中的湿热和力学耦合模拟
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-04-05 DOI: 10.1177/17442591231165992
Kazuma Fukui, C. Iba, D. Ogura
Porous building materials, such as board materials, wood, stones, fired clay materials, and bio-based materials, often have anisotropic properties. This study investigates adequate numerical models for the coupled hygrothermal and mechanical behaviors of strongly anisotropic building materials during freezing and thawing. First, strain measurements are reported for two types of fired clay materials to confirm the anisotropy of deformation during freezing and thawing. In calculations, the anisotropy of the Biot coefficient of a material is considered based on anisotropic poroelasticity. The comparison between the measurements and calculations revealed that the anisotropic deformation during the measurement cannot be reproduced without considering the anisotropies of the Biot coefficient as well as those of the mechanical properties. In addition, analysis of the causes of the deformation reveals that the expansion in the direction normal to the material thickness due to the water pressure development during the freezing is suppressed by the small Biot coefficient. These results indicate that the anisotropy of the Biot coefficient significantly influence the deformation due to frost actions; consequently, the anisotropic Biot coefficient should be adequately considered in numerical simulations.
多孔建筑材料,如板材、木材、石材、烧制粘土材料和生物基材料,往往具有各向异性。本文研究了强各向异性建筑材料在冻融过程中的热湿力学耦合行为的数值模型。首先,对两种烧制粘土材料进行了应变测量,以确定其冻融变形的各向异性。在计算中,基于各向异性孔隙弹性考虑材料Biot系数的各向异性。测量结果与计算结果的对比表明,如果不考虑比奥系数的各向异性和力学性能的各向异性,就不能再现测量过程中的各向异性变形。此外,对变形原因的分析表明,由于冻结过程中水压的发展,在材料厚度垂直方向上的膨胀被较小的Biot系数所抑制。结果表明,Biot系数的各向异性显著影响了冻害变形;因此,在数值模拟中应充分考虑各向异性Biot系数。
{"title":"Coupled hygrothermal and mechanical simulations of highly anisotropic building material during freezing and thawing","authors":"Kazuma Fukui, C. Iba, D. Ogura","doi":"10.1177/17442591231165992","DOIUrl":"https://doi.org/10.1177/17442591231165992","url":null,"abstract":"Porous building materials, such as board materials, wood, stones, fired clay materials, and bio-based materials, often have anisotropic properties. This study investigates adequate numerical models for the coupled hygrothermal and mechanical behaviors of strongly anisotropic building materials during freezing and thawing. First, strain measurements are reported for two types of fired clay materials to confirm the anisotropy of deformation during freezing and thawing. In calculations, the anisotropy of the Biot coefficient of a material is considered based on anisotropic poroelasticity. The comparison between the measurements and calculations revealed that the anisotropic deformation during the measurement cannot be reproduced without considering the anisotropies of the Biot coefficient as well as those of the mechanical properties. In addition, analysis of the causes of the deformation reveals that the expansion in the direction normal to the material thickness due to the water pressure development during the freezing is suppressed by the small Biot coefficient. These results indicate that the anisotropy of the Biot coefficient significantly influence the deformation due to frost actions; consequently, the anisotropic Biot coefficient should be adequately considered in numerical simulations.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"6 1","pages":"659 - 685"},"PeriodicalIF":2.0,"publicationDate":"2023-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81701975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Model validation and 2-D hygrothermal simulations of wetting and drying behavior of cross-laminated timber 交叉层合木材干湿特性的模型验证和二维湿热模拟
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-04-01 DOI: 10.1177/17442591231165987
Lin Wang, H. Ge, Jieying Wang
Cross-laminated timber (CLT) is one of the most important mass timber materials that are commonly used in mid-rise or even high-rise timber buildings. However, exposure to moisture during construction may increase the moisture damage risks, and impact the durability performance of CLT buildings. To investigate potential solutions for avoiding wetting of CLT components during construction, CLT specimens having different moisture protection measures were tested in the damp and mild wintertime climate in Vancouver. This follow-up work focuses on two-dimensional (2-D) hygrothermal modeling of the wetting and drying behavior of bare CLT (without any protection) and the validation with measurements from the field exposure test, emphasizing the influence of material properties. The hygrothermal models are firstly calibrated for two CLT specimens positioned horizontally, with and without a butt joint, by using material properties from different laboratory tests, and assuming different rain penetration paths. The calibrated models are then applied to simulate CLT specimens positioned vertically, which have end grain directly exposed to rain or damp concrete in the test. The work reveals that the moisture storage function above RH 95%, which includes the saturation water content reported in different literature, has a significant influence on the hygrothermal simulation results; meanwhile, assigning different water absorption coefficients for the transverse and longitudinal directions of wood significantly improves the accuracy of the hygrothermal model created for simulating rainwater penetration into the CLT panel. This paper provides a recommendation on how to properly model the CLT panels exposed to rainwater, which often occurs during construction.
交叉层合木(CLT)是中高层木结构建筑中常用的一种重要的块状木材材料。然而,施工过程中受潮会增加CLT建筑受潮破坏的风险,影响CLT建筑的耐久性。为了探讨避免CLT构件在施工过程中润湿的潜在解决方案,在温哥华潮湿温和的冬季气候中对具有不同防潮措施的CLT试件进行了测试。这项后续工作侧重于裸CLT(没有任何保护)的二维(2-D)湿热建模,并通过现场暴露试验的测量结果进行验证,强调材料特性的影响。首先,通过使用不同实验室测试的材料特性,并假设不同的雨水渗透路径,对两个水平放置的CLT试件进行了湿热模型校准,其中有对接节点和没有对接节点。然后将校正后的模型应用于模拟垂直放置的CLT试件,其端粒在试验中直接暴露于雨水或潮湿的混凝土中。研究表明,相对湿度95%以上的蓄湿函数(包括不同文献报道的饱和含水量)对湿热模拟结果有显著影响;同时,为木材的横向和纵向分配不同的吸水系数,显著提高了为模拟雨水渗入CLT面板而创建的湿热模型的准确性。本文就如何对施工中经常发生的雨水暴露的CLT板进行适当的建模提出了建议。
{"title":"Model validation and 2-D hygrothermal simulations of wetting and drying behavior of cross-laminated timber","authors":"Lin Wang, H. Ge, Jieying Wang","doi":"10.1177/17442591231165987","DOIUrl":"https://doi.org/10.1177/17442591231165987","url":null,"abstract":"Cross-laminated timber (CLT) is one of the most important mass timber materials that are commonly used in mid-rise or even high-rise timber buildings. However, exposure to moisture during construction may increase the moisture damage risks, and impact the durability performance of CLT buildings. To investigate potential solutions for avoiding wetting of CLT components during construction, CLT specimens having different moisture protection measures were tested in the damp and mild wintertime climate in Vancouver. This follow-up work focuses on two-dimensional (2-D) hygrothermal modeling of the wetting and drying behavior of bare CLT (without any protection) and the validation with measurements from the field exposure test, emphasizing the influence of material properties. The hygrothermal models are firstly calibrated for two CLT specimens positioned horizontally, with and without a butt joint, by using material properties from different laboratory tests, and assuming different rain penetration paths. The calibrated models are then applied to simulate CLT specimens positioned vertically, which have end grain directly exposed to rain or damp concrete in the test. The work reveals that the moisture storage function above RH 95%, which includes the saturation water content reported in different literature, has a significant influence on the hygrothermal simulation results; meanwhile, assigning different water absorption coefficients for the transverse and longitudinal directions of wood significantly improves the accuracy of the hygrothermal model created for simulating rainwater penetration into the CLT panel. This paper provides a recommendation on how to properly model the CLT panels exposed to rainwater, which often occurs during construction.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"101 1","pages":"737 - 761"},"PeriodicalIF":2.0,"publicationDate":"2023-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84109136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deformation of fired clay material during rapid freezing due to supercooling 烧制粘土材料在速冻过程中由于过冷引起的变形
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-02-27 DOI: 10.1177/17442591231154010
Kazuma Fukui, C. Iba, D. Ogura
To better understand the mechanisms of the deformation of fired clay materials due to frost actions, we investigated the effects of rapid freezing due to supercooling on the deformation through both experimental and numerical approaches. We conducted a freeze–thaw experiment to measure the strain evolution of the material during freezing and thawing. Subsequently, we developed a coupled hygrothermal and mechanical model of the freezing and thawing processes including supercooling, and conducted numerical simulations corresponding to the freeze–thaw experiment. The model was based on the theory of poromechanics. The results of the freeze-thaw experiment revealed that the supercooling effects were small in fired clay materials compared to cement-based materials examined in literature, and the material expanded significantly associated with subsequent freezing after the rapid freezing due to the supercooling stopped. Based on the results of the experiments and numerical simulations, the equilibrium freezing temperature and water movement toward the material surfaces enhanced by relatively large moisture permeability restrict pressure development in the material even though the freezing of the supercooled water in the material was considerably rapid. The results of the numerical simulations also showed that the effect of the supercooling can be much more significant if a material had a low moisture permeability.
为了更好地理解烧制粘土材料在霜冻作用下的变形机制,我们通过实验和数值方法研究了过冷快速冻结对变形的影响。我们进行了冻融实验来测量材料在冻融过程中的应变演变。随后,我们建立了包括过冷在内的冻融过程的湿热和力学耦合模型,并进行了与冻融实验相对应的数值模拟。该模型基于孔隙力学理论。冻融实验结果表明,与文献研究的水泥基材料相比,烧制粘土材料的过冷效应较小,并且由于过冷停止而导致的快速冻结后材料膨胀与后续冻结相关。实验和数值模拟结果表明,尽管过冷水在材料中的冻结速度相当快,但相对较大的透湿性增强了材料表面的平衡冻结温度和水向材料表面的运动,限制了材料内压力的发展。数值模拟结果还表明,过冷效应在材料透湿率较低时更为显著。
{"title":"Deformation of fired clay material during rapid freezing due to supercooling","authors":"Kazuma Fukui, C. Iba, D. Ogura","doi":"10.1177/17442591231154010","DOIUrl":"https://doi.org/10.1177/17442591231154010","url":null,"abstract":"To better understand the mechanisms of the deformation of fired clay materials due to frost actions, we investigated the effects of rapid freezing due to supercooling on the deformation through both experimental and numerical approaches. We conducted a freeze–thaw experiment to measure the strain evolution of the material during freezing and thawing. Subsequently, we developed a coupled hygrothermal and mechanical model of the freezing and thawing processes including supercooling, and conducted numerical simulations corresponding to the freeze–thaw experiment. The model was based on the theory of poromechanics. The results of the freeze-thaw experiment revealed that the supercooling effects were small in fired clay materials compared to cement-based materials examined in literature, and the material expanded significantly associated with subsequent freezing after the rapid freezing due to the supercooling stopped. Based on the results of the experiments and numerical simulations, the equilibrium freezing temperature and water movement toward the material surfaces enhanced by relatively large moisture permeability restrict pressure development in the material even though the freezing of the supercooled water in the material was considerably rapid. The results of the numerical simulations also showed that the effect of the supercooling can be much more significant if a material had a low moisture permeability.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"51 1","pages":"762 - 788"},"PeriodicalIF":2.0,"publicationDate":"2023-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86171061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Surface heat transfer coefficients in building envelopes: Uncertainty levels in experimental methods 建筑围护结构表面传热系数:实验方法的不确定度
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-01-31 DOI: 10.1177/17442591221150250
Roberto Garay-Martinez, B. Arregi, M. Lumbreras
There are several research methods for the on-site assessment of U-values that aim to avoid the use of surface heat flux measurements and rely on tabulated or empirically developed correlations to define this parameter. This works performs a detailed process to estimate indoor surface heat transfer coefficients based on several experimental campaigns over building walls. Data is filtered out to remove periods with large temperature variations and/or unstable convective conditions due to HVAC. A statistical analysis is conducted, and the outcomes used to test the validity of U-value estimation approaches. The outcomes show that the actual surface heat transfer coefficients are in the range of reference works, but variations in the range of up to 2 W/m2 K are found. Uncertainty levels associated to the estimation of surface heat transfer coefficient are in the range 60% for instantaneous values while this is reduced down to 12%–20% for 8-h averages. Variations and uncertainty levels are higher for low temperature gradient situations, which are considered to be very likely for modern insulation levels. It is concluded that methods seeking to avoid the use of surface heat flux measurements need to develop much deeper knowledge in this field to gain accuracy and reliability.
有几种现场评估u值的研究方法,其目的是避免使用表面热通量测量,而依靠制表或经验开发的相关性来定义该参数。这项工作执行了一个详细的过程,以估计室内表面传热系数基于几个实验运动在建筑墙壁上。数据被过滤掉,以去除大的温度变化和/或不稳定的对流条件,由于暖通空调。进行了统计分析,并将结果用于检验u值估计方法的有效性。结果表明,实际的表面换热系数在参考作品的范围内,但变化范围高达2 W/m2 K。对于瞬时值,与表面传热系数估计相关的不确定性水平在60%范围内,而对于8小时平均值,这一不确定性降低到12%-20%。对于低温梯度情况,变化和不确定性水平更高,这被认为很可能是现代绝缘水平。结论是,寻求避免使用表面热通量测量的方法需要在这一领域发展更深入的知识,以获得准确性和可靠性。
{"title":"Surface heat transfer coefficients in building envelopes: Uncertainty levels in experimental methods","authors":"Roberto Garay-Martinez, B. Arregi, M. Lumbreras","doi":"10.1177/17442591221150250","DOIUrl":"https://doi.org/10.1177/17442591221150250","url":null,"abstract":"There are several research methods for the on-site assessment of U-values that aim to avoid the use of surface heat flux measurements and rely on tabulated or empirically developed correlations to define this parameter. This works performs a detailed process to estimate indoor surface heat transfer coefficients based on several experimental campaigns over building walls. Data is filtered out to remove periods with large temperature variations and/or unstable convective conditions due to HVAC. A statistical analysis is conducted, and the outcomes used to test the validity of U-value estimation approaches. The outcomes show that the actual surface heat transfer coefficients are in the range of reference works, but variations in the range of up to 2 W/m2 K are found. Uncertainty levels associated to the estimation of surface heat transfer coefficient are in the range 60% for instantaneous values while this is reduced down to 12%–20% for 8-h averages. Variations and uncertainty levels are higher for low temperature gradient situations, which are considered to be very likely for modern insulation levels. It is concluded that methods seeking to avoid the use of surface heat flux measurements need to develop much deeper knowledge in this field to gain accuracy and reliability.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"200 1","pages":"62 - 91"},"PeriodicalIF":2.0,"publicationDate":"2023-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75912453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Prefabricated thermally-activated fiber-polymer composite building slab P-TACS: Toward the multifunctional and pre-fabricated structural elements in buildings 预制热活化纤维-聚合物复合建筑板P-TACS:面向建筑中的多功能预制结构构件
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-01-26 DOI: 10.1177/17442591221150257
D. Khovalyg, Alexandre Mudry, T. Keller
The traditional sequential design of building elements, where every element performs only one dedicated function, carries significant embodied energy. Thus, modular pre-fabricated load-bearing elements could overcome the disadvantages of the current carbon-intensive construction practice and go beyond; as such, lightweight glass fiber-polymer composite profiles could be more advantageous in performance. Cellular structures of such profiles can be advantageous for adding water channels for active heating and cooling indoors and for fire protection. Therefore, the development of such a modular active building slab referred to as P-TACS (Prefabricated Thermally-Activated Fiber-Polymer Composite Slab) is explored in this work. The structural performance of a proposed P-TACS design is verified in terms of serviceability and ultimate limit states. The addition of local carbon fiber inclusions allows for an increase in the span of the slab to 10 m and a more uniform surface temperature. Thermal performance of the structurally optimized geometrical configuration is analyzed by, first of all, determining water parameters based on the 1D approach partially adopted from the standard radiant systems analysis and, secondly, by a detailed 2D thermal analysis using ANSYS Fluent numerical simulations. The hydraulic and thermal performance comparison of the novel P-TACS design with two standard radiant systems (ESS Type A and RCP) reveals that the P-TACS design outperforms the standard embedded surface system ESS Type A, both for floor heating and cooling case. In addition, the response time of P-TACS is three times faster compared to the ESS response time. The main advantage of the P-TACS is in lower mean water temperature, compared to traditional embedded radiant systems (e.g., EES type), required for conditioning the space, potentially resulting in lower operational energy use. The fire outbreak scenario is considered to complete the analysis, and the measures to switch water flow from nominal to fire scenario are proposed.
传统的建筑元素的顺序设计,每个元素只执行一个专用功能,承载着重要的体现能量。因此,模块化预制承重元件可以克服目前碳密集型建筑实践的缺点,并超越;因此,轻质玻璃纤维-聚合物复合型材在性能上更有优势。这种型材的蜂窝状结构对于增加用于室内主动加热和冷却以及用于防火的水通道是有利的。因此,在这项工作中,我们探索了这种被称为P-TACS(预制热活化纤维-聚合物复合板)的模块化活性建筑板的发展。提出的P-TACS设计的结构性能在可用性和极限状态方面进行了验证。局部碳纤维夹杂物的添加允许将板的跨度增加到10米,并且表面温度更均匀。对结构优化后的几何构型进行热性能分析,首先基于部分采用标准辐射系统分析的一维方法确定水参数,然后利用ANSYS Fluent数值模拟进行详细的二维热分析。新型P-TACS设计与两种标准辐射系统(ESS A型和RCP)的水力和热性能比较表明,P-TACS设计在地板采暖和冷却情况下都优于标准嵌入式表面系统ESS A型。此外,P-TACS的反应时间比ESS的反应时间快3倍。与传统的嵌入式辐射系统(例如EES类型)相比,P-TACS的主要优点是平均水温较低,从而降低了空间调节所需的操作能耗。考虑了火灾情景来完成分析,并提出了从名义流向火灾情景转换的措施。
{"title":"Prefabricated thermally-activated fiber-polymer composite building slab P-TACS: Toward the multifunctional and pre-fabricated structural elements in buildings","authors":"D. Khovalyg, Alexandre Mudry, T. Keller","doi":"10.1177/17442591221150257","DOIUrl":"https://doi.org/10.1177/17442591221150257","url":null,"abstract":"The traditional sequential design of building elements, where every element performs only one dedicated function, carries significant embodied energy. Thus, modular pre-fabricated load-bearing elements could overcome the disadvantages of the current carbon-intensive construction practice and go beyond; as such, lightweight glass fiber-polymer composite profiles could be more advantageous in performance. Cellular structures of such profiles can be advantageous for adding water channels for active heating and cooling indoors and for fire protection. Therefore, the development of such a modular active building slab referred to as P-TACS (Prefabricated Thermally-Activated Fiber-Polymer Composite Slab) is explored in this work. The structural performance of a proposed P-TACS design is verified in terms of serviceability and ultimate limit states. The addition of local carbon fiber inclusions allows for an increase in the span of the slab to 10 m and a more uniform surface temperature. Thermal performance of the structurally optimized geometrical configuration is analyzed by, first of all, determining water parameters based on the 1D approach partially adopted from the standard radiant systems analysis and, secondly, by a detailed 2D thermal analysis using ANSYS Fluent numerical simulations. The hydraulic and thermal performance comparison of the novel P-TACS design with two standard radiant systems (ESS Type A and RCP) reveals that the P-TACS design outperforms the standard embedded surface system ESS Type A, both for floor heating and cooling case. In addition, the response time of P-TACS is three times faster compared to the ESS response time. The main advantage of the P-TACS is in lower mean water temperature, compared to traditional embedded radiant systems (e.g., EES type), required for conditioning the space, potentially resulting in lower operational energy use. The fire outbreak scenario is considered to complete the analysis, and the measures to switch water flow from nominal to fire scenario are proposed.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"43 1","pages":"686 - 707"},"PeriodicalIF":2.0,"publicationDate":"2023-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84235808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Development of a hysteresis model based on axisymmetric and homotopic properties to predict moisture transfer in building materials 基于轴对称和同伦特性的滞回模型的发展,以预测建筑材料中的水分转移
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-01-20 DOI: 10.1177/17442591221144785
Ahmad Deeb, F. Benmahiddine, J. Berger, R. Belarbi
Current hygrothermal behaviour prediction models neglect the hysteresis phenomenon. This leads to a discrepancy between numerical and experimental results, and a miscalculation of buildings’ durability. In this paper, a new mathematical model of hysteresis is proposed and implemented in a hygrothermal model to reduce this discrepancy. The model is based on a symmetry property between sorption curves and uses also a homotopic transformation relative to a parameter s ∈ [ 0 , 1 ] . The advantage of this model lies in its ease of use and implementation since it could be applied with the knowledge of only one main sorption curve by considering s = 0 , in other words, we only use the axisymmetric property here. In the case where the other main sorption curve is known, we use this curve to incorporate the homotopy property in order to calibrate the parameter s .The full version of the proposed model is called Axisymmetric + Homotopic. Furthermore, it was compared not only with the experimental sorption curves of different types of materials but also with a model that is well known in the literature (CARMELIET’s model). This comparison shows that the Axisymmetric + Homotopic model reliably predicts hysteresis loops of various types of materials even with the knowledge of only one of the main sorption curves. However, the full version of Axisymmetric + Homotopic model is more reliable and covers a large range of materials. The proposed model was incorporated into the mass transfer model. The simulation results strongly match the experimental ones.
目前的热液行为预测模型忽略了滞后现象。这导致了数值与实验结果之间的差异,以及对建筑物耐久性的错误计算。本文提出了一种新的迟滞数学模型,并在热液模型中实现,以减少这种差异。该模型基于吸收曲线之间的对称性,并且还使用了相对于参数s∈[0,1]的同伦变换。该模型的优点在于易于使用和实现,因为在考虑s = 0的情况下,只需要知道一条主吸收曲线就可以应用该模型,换句话说,我们在这里只使用轴对称性质。在已知其他主要吸收曲线的情况下,我们使用这条曲线来结合同伦性质,以便校准参数s。所提出模型的完整版本称为轴对称+同伦。此外,还将其与不同材料的实验吸附曲线进行了比较,并与文献中著名的模型(CARMELIET模型)进行了比较。这一比较表明,轴对称+同伦模型即使只知道其中一条主吸收曲线,也能可靠地预测各种材料的磁滞回线。而完整版的轴对称+同伦模型更可靠,涵盖的材料范围更广。该模型被纳入到传质模型中。仿真结果与实验结果吻合较好。
{"title":"Development of a hysteresis model based on axisymmetric and homotopic properties to predict moisture transfer in building materials","authors":"Ahmad Deeb, F. Benmahiddine, J. Berger, R. Belarbi","doi":"10.1177/17442591221144785","DOIUrl":"https://doi.org/10.1177/17442591221144785","url":null,"abstract":"Current hygrothermal behaviour prediction models neglect the hysteresis phenomenon. This leads to a discrepancy between numerical and experimental results, and a miscalculation of buildings’ durability. In this paper, a new mathematical model of hysteresis is proposed and implemented in a hygrothermal model to reduce this discrepancy. The model is based on a symmetry property between sorption curves and uses also a homotopic transformation relative to a parameter s ∈ [ 0 , 1 ] . The advantage of this model lies in its ease of use and implementation since it could be applied with the knowledge of only one main sorption curve by considering s = 0 , in other words, we only use the axisymmetric property here. In the case where the other main sorption curve is known, we use this curve to incorporate the homotopy property in order to calibrate the parameter s .The full version of the proposed model is called Axisymmetric + Homotopic. Furthermore, it was compared not only with the experimental sorption curves of different types of materials but also with a model that is well known in the literature (CARMELIET’s model). This comparison shows that the Axisymmetric + Homotopic model reliably predicts hysteresis loops of various types of materials even with the knowledge of only one of the main sorption curves. However, the full version of Axisymmetric + Homotopic model is more reliable and covers a large range of materials. The proposed model was incorporated into the mass transfer model. The simulation results strongly match the experimental ones.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"70 1","pages":"567 - 601"},"PeriodicalIF":2.0,"publicationDate":"2023-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85009052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Study on efficient and accurate protocols of measuring sorption isotherm of porous building materials using three-dimensional hygrothermal simulation 三维湿热模拟测量多孔建筑材料吸附等温线的高效准确方案研究
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-01-17 DOI: 10.1177/17442591221145470
Kazuma Fukui, S. Takada
The sorption property of porous building materials in the hygroscopic region (sorption isotherm) is an important input to hygrothermal simulation. In this study, we proposed efficient and accurate protocols to obtain sorption isotherms using the static desiccator method. We developed a calculation model for three-dimensional simultaneous heat and moisture transfer in a material corresponding to the measurement specified in ISO 12571. Using an international database of the material properties, we conducted numerical simulations of the sorption process for five types of materials. The evolution of the amount of adsorbed moisture in a specimen and the time to reach equilibrium during the measurement were calculated under various humidity levels and specimen dimensions. According to the simulated results, we improved timing and interval for weighting the specimen to confirm the attainment of equilibrium for each type of a material and for each humidity level from the viewpoint of efficiency and accuracy. Meanwhile, the influence of size of a specimen on the time necessary to obtain the results was quantitatively demonstrated. Moreover, it was demonstrated that the method used for the determination of the attainment of equilibrium provided in ISO 12571 can underestimate the moisture content of materials with low moisture content and vapor permeability, and a policy to reduce risks of the underestimation was proposed.
多孔建筑材料在吸湿区的吸附特性(吸附等温线)是热湿模拟的重要输入。在这项研究中,我们提出了有效和准确的协议,以获得吸附等温线使用静态干燥器的方法。我们根据ISO 12571中规定的测量方法,开发了一种材料中三维同时热湿传递的计算模型。利用国际材料特性数据库,我们对五种材料的吸附过程进行了数值模拟。在不同的湿度水平和试样尺寸下,计算了试样中吸附水分量的演变和在测量过程中达到平衡的时间。根据模拟结果,我们改进了试样称重的时间和间隔,以确保从效率和准确性的角度来看,每种材料和每种湿度水平都达到平衡。同时,定量论证了试样尺寸对获得结果所需时间的影响。此外,还证明了ISO 12571中所提供的用于测定平衡是否达到的方法可能会低估含水量和透气性较低的材料的含水量,并提出了降低低估风险的策略。
{"title":"Study on efficient and accurate protocols of measuring sorption isotherm of porous building materials using three-dimensional hygrothermal simulation","authors":"Kazuma Fukui, S. Takada","doi":"10.1177/17442591221145470","DOIUrl":"https://doi.org/10.1177/17442591221145470","url":null,"abstract":"The sorption property of porous building materials in the hygroscopic region (sorption isotherm) is an important input to hygrothermal simulation. In this study, we proposed efficient and accurate protocols to obtain sorption isotherms using the static desiccator method. We developed a calculation model for three-dimensional simultaneous heat and moisture transfer in a material corresponding to the measurement specified in ISO 12571. Using an international database of the material properties, we conducted numerical simulations of the sorption process for five types of materials. The evolution of the amount of adsorbed moisture in a specimen and the time to reach equilibrium during the measurement were calculated under various humidity levels and specimen dimensions. According to the simulated results, we improved timing and interval for weighting the specimen to confirm the attainment of equilibrium for each type of a material and for each humidity level from the viewpoint of efficiency and accuracy. Meanwhile, the influence of size of a specimen on the time necessary to obtain the results was quantitatively demonstrated. Moreover, it was demonstrated that the method used for the determination of the attainment of equilibrium provided in ISO 12571 can underestimate the moisture content of materials with low moisture content and vapor permeability, and a policy to reduce risks of the underestimation was proposed.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"32 1","pages":"541 - 566"},"PeriodicalIF":2.0,"publicationDate":"2023-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80453299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of green roof and green facade on building thermal performance and carbon sequestration in subtropical climate of China 中国亚热带气候下绿色屋顶和绿色立面对建筑热学性能和碳汇的影响
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-01-12 DOI: 10.1177/17442591221145514
Chao Jiang, Yan Zhou, Kai Li, Difang Wei
This paper investigates the case building’s cooling effect, energy saving, and carbon sequestration with green facade and green roof. The west and east GF is covered with wisteria, and the GR is planted with different kinds of vegetables. The cooling effect of the GF and GR is analyzed by field test. The cooling energy saving of the GF and GR is deeply discussed with EnergyPlus software simulation. Carbon sequestrations of the GF and GR are calculated considering both plant photosynthetic and energy saving with the field test and simulation. The results show that the average external surface temperature reduction of the west GF, east GF, and GR is 4.5°C, 4.2°C, and 9.7°C on sunny days, 1.3°C, 1.3°C, and 1.4°C respectively on cloudy days. The total cooling energy saving of the GF and GR is 4.75 kWh/m2. The cooling energy saving of the GR with seven kinds of vegetables varies from 529.6 to 2936.3 kWh, which is related to the LAI and height of vegetables. The daily cooling energy saving in hot sunny weather scenario is almost three times that in cool sunny. The carbon sequestration ability per planted GF area is 1.4 kg C/m2, and per planted GR area with seven different vegetables varies from 0.88 to 2.21 kg C/m2, in which the strongest is peanut, and the weakest is lettuce. At last, the cooling energy savings of GF in different orientations on hot, warm, and cool sunny days are discussed, which is shown that the cooling energy saving effect of the different oriented GF mainly depends on the received solar radiation amount in this orientation. The results of this research can provide some assistance in improving the design of the building GR and GF.
本文对该案例建筑采用绿色立面和绿色屋顶的降温效果、节能效果和固碳效果进行了研究。西边和东边的GF覆盖着紫藤,而GR则种植着各种蔬菜。通过现场试验分析了GF和GR的冷却效果。通过EnergyPlus软件仿真,对GF和GR的冷却节能进行了深入探讨。通过田间试验和模拟计算,同时考虑植物光合作用和节能,计算了GF和GR的固碳量。结果表明:晴天时西GF、东GF和GR的平均外表面温度降低4.5°C、4.2°C和9.7°C,阴天时分别降低1.3°C、1.3°C和1.4°C。GF和GR合计制冷省电4.75 kWh/m2。7种蔬菜GR的制冷节能值在529.6 ~ 2936.3 kWh之间,与蔬菜的LAI和高度有关。炎热晴朗天气下的日制冷节能量几乎是凉爽晴朗天气下的3倍。GF种植面积的固碳能力为1.4 kg C/m2, 7种不同蔬菜的GR种植面积的固碳能力在0.88 ~ 2.21 kg C/m2之间,其中花生最强,生菜最弱。最后讨论了不同朝向GF在炎热、温暖和凉爽晴天的制冷节能效果,表明不同朝向GF的制冷节能效果主要取决于该朝向接收的太阳辐射量。研究结果可为改进建筑GR和GF的设计提供一定的帮助。
{"title":"Impact of green roof and green facade on building thermal performance and carbon sequestration in subtropical climate of China","authors":"Chao Jiang, Yan Zhou, Kai Li, Difang Wei","doi":"10.1177/17442591221145514","DOIUrl":"https://doi.org/10.1177/17442591221145514","url":null,"abstract":"This paper investigates the case building’s cooling effect, energy saving, and carbon sequestration with green facade and green roof. The west and east GF is covered with wisteria, and the GR is planted with different kinds of vegetables. The cooling effect of the GF and GR is analyzed by field test. The cooling energy saving of the GF and GR is deeply discussed with EnergyPlus software simulation. Carbon sequestrations of the GF and GR are calculated considering both plant photosynthetic and energy saving with the field test and simulation. The results show that the average external surface temperature reduction of the west GF, east GF, and GR is 4.5°C, 4.2°C, and 9.7°C on sunny days, 1.3°C, 1.3°C, and 1.4°C respectively on cloudy days. The total cooling energy saving of the GF and GR is 4.75 kWh/m2. The cooling energy saving of the GR with seven kinds of vegetables varies from 529.6 to 2936.3 kWh, which is related to the LAI and height of vegetables. The daily cooling energy saving in hot sunny weather scenario is almost three times that in cool sunny. The carbon sequestration ability per planted GF area is 1.4 kg C/m2, and per planted GR area with seven different vegetables varies from 0.88 to 2.21 kg C/m2, in which the strongest is peanut, and the weakest is lettuce. At last, the cooling energy savings of GF in different orientations on hot, warm, and cool sunny days are discussed, which is shown that the cooling energy saving effect of the different oriented GF mainly depends on the received solar radiation amount in this orientation. The results of this research can provide some assistance in improving the design of the building GR and GF.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"35 1","pages":"602 - 629"},"PeriodicalIF":2.0,"publicationDate":"2023-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78387677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Design hygrothermally functional wooden insulation systems: A parametric study for mixed climate 设计湿热功能的木质保温系统:混合气候的参数化研究
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-01-01 DOI: 10.1177/17442591221142506
Mosha Zhao, H. Künzel, S. Mehra
According to existing measurements and simulation results, the indoor thermal comfort in traditional wooden buildings (still remaining in a large amount) in the Chinese Hot-Summer-Cold-Winter zone is very poor in winter. However, few studies can be found regarding the energy retrofitting of their wooden enclosures, which is increasingly regarded as essential for improving indoor thermal comfort and maintaining built heritage. Therefore, this study demonstrates a method based on parametric study applying the widely validated WUFI®Plus software to help design hygrothermally functional insulation systems for this area. The parametric study was conducted on the example of traditional exterior wooden walls in Tongren in southern China. Five parameters were investigated, including internal and external insulation systems, vapor-open (mineral wool) and vapor-tight (XPS) insulation materials, a U-value of 0.8 W/(m2K) as well as a lower U-value of 0.24 W/(m2K) for the insulated walls, different capabilities and positions of an additional vapor control layer, as well as different cooling/dehumidification conditions in the warm period of a year. It has been found in this study that, if possible, a lower U-value than the current Chinese design standard for energy efficiency of buildings (0.8 W/(m2K) should be preferred for energy retrofitting. This can limit the yearly duration of a high internal surface relative humidity over 80% shorter than 30 days without any dehumidification devices. Besides, this study provides some feasible wall configurations with instructions on their limitations to guide future work regarding the design of insulated building components and the operation of renovated traditional wooden buildings.
根据已有的测量和仿真结果,我国夏热冬冷地区的传统木结构建筑(仍大量存在)在冬季的室内热舒适性非常差。然而,很少有研究可以找到关于他们的木制围护结构的能源改造,这越来越被认为是改善室内热舒适和维护建筑遗产的必要条件。因此,本研究展示了一种基于参数化研究的方法,应用广泛验证的WUFI®Plus软件来帮助设计该地区的湿热功能保温系统。以铜仁市传统外木墙为例进行了参数化研究。研究了5个参数,包括内外保温系统、开汽(矿棉)和密汽(XPS)保温材料、保温墙体的u值为0.8 W/(m2K)和较低的u值为0.24 W/(m2K)、附加蒸汽控制层的不同功能和位置,以及一年中暖季不同的冷却/除湿条件。本研究发现,在可能的情况下,节能改造应优先采用低于中国现行建筑能效设计标准(0.8 W/(m2K))的u值。在没有除湿设备的情况下,可以将内部表面相对湿度超过80%的年高持续时间限制在30天以内。此外,本研究还提供了一些可行的墙体配置,并说明了它们的局限性,以指导未来建筑隔热构件的设计和改造后传统木结构建筑的运营工作。
{"title":"Design hygrothermally functional wooden insulation systems: A parametric study for mixed climate","authors":"Mosha Zhao, H. Künzel, S. Mehra","doi":"10.1177/17442591221142506","DOIUrl":"https://doi.org/10.1177/17442591221142506","url":null,"abstract":"According to existing measurements and simulation results, the indoor thermal comfort in traditional wooden buildings (still remaining in a large amount) in the Chinese Hot-Summer-Cold-Winter zone is very poor in winter. However, few studies can be found regarding the energy retrofitting of their wooden enclosures, which is increasingly regarded as essential for improving indoor thermal comfort and maintaining built heritage. Therefore, this study demonstrates a method based on parametric study applying the widely validated WUFI®Plus software to help design hygrothermally functional insulation systems for this area. The parametric study was conducted on the example of traditional exterior wooden walls in Tongren in southern China. Five parameters were investigated, including internal and external insulation systems, vapor-open (mineral wool) and vapor-tight (XPS) insulation materials, a U-value of 0.8 W/(m2K) as well as a lower U-value of 0.24 W/(m2K) for the insulated walls, different capabilities and positions of an additional vapor control layer, as well as different cooling/dehumidification conditions in the warm period of a year. It has been found in this study that, if possible, a lower U-value than the current Chinese design standard for energy efficiency of buildings (0.8 W/(m2K) should be preferred for energy retrofitting. This can limit the yearly duration of a high internal surface relative humidity over 80% shorter than 30 days without any dehumidification devices. Besides, this study provides some feasible wall configurations with instructions on their limitations to guide future work regarding the design of insulated building components and the operation of renovated traditional wooden buildings.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"26 1","pages":"474 - 509"},"PeriodicalIF":2.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74581981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Dynamic water vapor sorption in wood-based fibrous materials and material parameter estimation 木基纤维材料的动态水蒸气吸附及材料参数估计
IF 2 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-01-01 DOI: 10.1177/17442591221142496
P. Huttunen, J. Vinha
Building physical simulation software rely on assumptions regarding the local equilibria in materials’ pore systems, which may be unjustified for certain materials. While local hygrothermal non-equilibrium has still been in focus in some previous studies, it has been unclear how significant factor it may be when modeling real structures. In case of wood, the non-equilibrium is related to the slowness of intrusion of water molecules into the hygroscopic cell walls. Including local non-equilibrium in macroscopic model requires separate variables for pore air vapor and adsorbed moisture, and modeling the local mass transfer between pore air and adsorbed moisture requires effective material parameters, whose experimental determination is not straightforward. Commercially available sorption balances can be used to record data, which can be used in the parameter estimation. In this type of problem of parameter estimation from time-dependent data the mathematical challenge is to find global optimum from different solutions, which yield similar values for objective function. This difficulty can be overcome by using statistical inversion approach, which we applied in studying low-density woodfibre material (LDF). Dynamic sorption parameters were finally applied in numerical analysis of a laboratory test assembly. Based on the results, our conclusion is that the slowness of sorption is obvious in small LDF sample, which is exposed to changing humidity, but with the studied material the sorption seem to happen fast enough so that local non-equilibrium may have only slight effects in modeling of real structures.
构建物理模拟软件依赖于关于材料孔隙系统局部平衡的假设,这对于某些材料可能是不合理的。虽然局部湿热不平衡在以前的一些研究中仍然是重点,但在模拟真实结构时,它可能是多么重要的因素尚不清楚。以木材为例,这种不平衡与水分子侵入吸湿细胞壁的缓慢有关。在宏观模型中包含局部非平衡需要单独的孔隙空气蒸汽和吸附水分变量,而模拟孔隙空气和吸附水分之间的局部传质需要有效的材料参数,而这些参数的实验确定并不简单。市售的吸附天平可用于记录数据,可用于参数估计。在这类基于时变数据的参数估计问题中,数学上的挑战是从不同的解中找到全局最优解,这些解产生的目标函数值相似。利用统计反演方法可以克服这一困难,我们将其应用于研究低密度木纤维材料(LDF)。最后将动态吸附参数应用于某实验室试验装置的数值分析。基于这些结果,我们的结论是,在小的LDF样品中,暴露在变化的湿度下,吸附的缓慢性是明显的,但对于所研究的材料,吸附似乎发生得足够快,以至于局部非平衡可能对实际结构的建模只有轻微的影响。
{"title":"Dynamic water vapor sorption in wood-based fibrous materials and material parameter estimation","authors":"P. Huttunen, J. Vinha","doi":"10.1177/17442591221142496","DOIUrl":"https://doi.org/10.1177/17442591221142496","url":null,"abstract":"Building physical simulation software rely on assumptions regarding the local equilibria in materials’ pore systems, which may be unjustified for certain materials. While local hygrothermal non-equilibrium has still been in focus in some previous studies, it has been unclear how significant factor it may be when modeling real structures. In case of wood, the non-equilibrium is related to the slowness of intrusion of water molecules into the hygroscopic cell walls. Including local non-equilibrium in macroscopic model requires separate variables for pore air vapor and adsorbed moisture, and modeling the local mass transfer between pore air and adsorbed moisture requires effective material parameters, whose experimental determination is not straightforward. Commercially available sorption balances can be used to record data, which can be used in the parameter estimation. In this type of problem of parameter estimation from time-dependent data the mathematical challenge is to find global optimum from different solutions, which yield similar values for objective function. This difficulty can be overcome by using statistical inversion approach, which we applied in studying low-density woodfibre material (LDF). Dynamic sorption parameters were finally applied in numerical analysis of a laboratory test assembly. Based on the results, our conclusion is that the slowness of sorption is obvious in small LDF sample, which is exposed to changing humidity, but with the studied material the sorption seem to happen fast enough so that local non-equilibrium may have only slight effects in modeling of real structures.","PeriodicalId":50249,"journal":{"name":"Journal of Building Physics","volume":"3 21 1","pages":"399 - 424"},"PeriodicalIF":2.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90156098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
Journal of Building Physics
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1