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Phytochemical preparation of Zinc Stannate nanoparticles by using lemon and grapefruit peels for removal of cadmium ions 利用柠檬皮和柚子皮的植物化学制备纳米锡酸锌颗粒以去除镉离子
Pub Date : 2024-07-26 DOI: 10.1088/1402-4896/ad6811
Aneta Salova, Sura Mohammad Mohealdeen, Abbas Hameed Abdul Hussein, Dheyaa Flayih Hasan, Hiba Mushtaq, A. Idan, R. Fallah Amer
The synthesis of Zinc Stannate (Zn2SnO4) nanoparticles may be achieved by utilizing lemon and grapefruit peels, as indicated by the results of this study. This analysis outlines a sustainable, cost-effective, and readily available approach. The Zn2SnO4 nanoparticles were generated biologically and were discovered to have a cubic crystalline structure, as established by structural analysis using Rietveld refinement. TEM microstructural examinations revealed that Zn2SnO4 nanoparticles exhibit a homogeneous distribution and possess an average diameter of around 21 nm. The Zn2SnO4 nanoparticles have an optical energy band gap of 3.05 eV and demonstrate a UV region peak, which showed that Zn2SnO4 nanoparticles were being formed. More precisely, the pH of the solution greatly affects the absorption of Cd2+ ions. Kinetic analysis involves the use of two types of models: pseudo-first-order and pseudo-second-order. The previous model yields an R2 value of 0.9031 and a rate constant (k1) of 0.41×10-2 min-1. However, the pseudo-second-order model provides a better match, as seen by its very high R2 value of 0.9932 and rate constant (k2) value of 4.4×10-3 g.(mg.min)−1. In addition, isotherm modeling shows that the experimental data closely match the Freundlich isotherm model.
本研究结果表明,利用柠檬皮和柚子皮可以合成纳米锡酸锌(Zn2SnO4)。该分析概述了一种可持续、经济高效且随时可用的方法。Zn2SnO4 纳米粒子由生物生成,通过使用里特维尔德精炼法进行结构分析,发现其具有立方晶体结构。TEM 显微结构检查显示,Zn2SnO4 纳米粒子分布均匀,平均直径约为 21 纳米。Zn2SnO4 纳米粒子的光能带隙为 3.05 eV,并显示出紫外区峰值,这表明 Zn2SnO4 纳米粒子正在形成。更确切地说,溶液的 pH 值会极大地影响 Cd2+ 离子的吸收。动力学分析包括使用两种模型:伪一阶模型和伪二阶模型。前一种模型的 R2 值为 0.9031,速率常数(k1)为 0.41×10-2 min-1。然而,伪二阶模型的 R2 值非常高,为 0.9932,速率常数(k2)为 4.4×10-3 g. (mg.min)-1,由此可见,伪二阶模型提供了更好的匹配。此外,等温线模型显示实验数据与 Freundlich 等温线模型非常吻合。
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引用次数: 0
A Robust Integrated Navigation Optimization Method for USV in Signal Occlusion Environment 信号闭塞环境下 USV 的稳健综合导航优化方法
Pub Date : 2024-07-26 DOI: 10.1088/1402-4896/ad680e
Naiyuan Lou, Wei Liu, Yuan Hu, Shengzhe Wang, Bing Han
Unmanned surface vehicles (USV) can use global navigation satellite systems (GNSS) and inertial navigation systems (INS) for combined positioning and navigation. However, buildings such as port facilities and bridges blocking GNSS signals will increase the error in the discriminator output in the GNSS vector tracking loop and reduce positioning accuracy. Meanwhile, due to the cumulative error in the inertial navigation system, the credibility of the navigation results when the signal is blocked is further reduced. In this regard, this study proposes a robust integrated navigation optimization method. Specifically, the RTS smoothing optimized Kalman filter is used to constrain the carrier phase error and code phase error output by the discriminator, which can dynamically adjust the gain of the vector tracking loop, thereby improving the signal tracking capability. Simultaneously, the prediction results of the gated recurrent unit (GRU) network optimized based on the attention mechanism are combined with the inertial navigation system to improve navigation accuracy. Furthermore, an adaptive Kalman filter is utilized as the integrated navigation filter. The actual path of the carrier refers to the navigation solution of the existing receiver. In the open environment, the proposed optimization method reduces horizontal positioning error and speed error by 44.7% and 37.1% respectively compared with existing methods. Simultaneously, it can effectively improve the robustness of positioning in signal obstruction environments. The proposed integrated navigation method provides new possibilities for optimizing USV navigation solutions.
无人水面飞行器(USV)可使用全球导航卫星系统(GNSS)和惯性导航系统(INS)进行联合定位和导航。然而,港口设施和桥梁等建筑物会阻挡全球导航卫星系统信号,从而增加全球导航卫星系统矢量跟踪环路中鉴别器输出的误差,降低定位精度。同时,由于惯性导航系统的累积误差,当信号被遮挡时,导航结果的可信度会进一步降低。为此,本研究提出了一种稳健的综合导航优化方法。具体来说,利用 RTS 平滑优化卡尔曼滤波器对鉴相器输出的载波相位误差和码相位误差进行约束,动态调整矢量跟踪环路的增益,从而提高信号跟踪能力。同时,基于注意力机制优化的门控递归单元(GRU)网络的预测结果与惯性导航系统相结合,提高了导航精度。此外,还利用自适应卡尔曼滤波器作为集成导航滤波器。载波的实际路径参考现有接收器的导航解决方案。在开放环境中,所提出的优化方法与现有方法相比,水平定位误差和速度误差分别减少了 44.7% 和 37.1%。同时,它还能有效提高信号障碍环境下定位的鲁棒性。所提出的综合导航方法为 USV 导航方案的优化提供了新的可能性。
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引用次数: 0
Mixed localized waves and their interaction structures for a spatial discrete Hirota equation 空间离散广达方程的混合局部波及其相互作用结构
Pub Date : 2024-07-26 DOI: 10.1088/1402-4896/ad6810
Jun Yang, Yueya Chang, Lili Wen
Mixed localized wave solutions and interactions are of great significance in nonlinear physical systems. This paper aims to investigating the generalized (m,N-m)-fold Darboux transformation and the mixed localized wave solutions of a spatial discrete Hirota equation. First, we construct the generalized (m,N-m)- fold Darboux transformation for the spatial discrete Hirota equation, which can produce the interactions between the breathers, degenerate breathers and rogue waves. For the Darboux transformation formula, we discuss the above order-1,2,3 localized wave solutions, as well as their dynamics by choosing the number of m = 1. We plot some specific examples such as the spatial (time)-periodic breather, second- order and third-order degenerate breathers, solutions, and higher-order rogue waves with novel patterns. Furthermore, when m > 1, we give several kinds of mixed interaction solutions between the first-order rogue waves and first (second)-order (degenerate) breathers, between the first-order breather and second- order degenerate breathers, between second-order rogue waves and first-order breathers. At last, we also sum up the various mathematical features of the degenerate breathers and the mixed localized wave solutions.
混合局部波解和相互作用在非线性物理系统中具有重要意义。本文旨在研究空间离散 Hirota 方程的广义 (m,N-m)-Fold Darboux 变换和混合局部波解。首先,我们构建了空间离散 Hirota 方程的广义(m,N-m)-折达布克斯变换,它可以产生呼吸波、退化呼吸波和流氓波之间的相互作用。针对达布变换公式,我们讨论了上述阶数为 1、2、3 的局部波解,以及通过选择 m = 1 的数量来讨论它们的动力学。我们绘制了一些具体的例子,如空间(时间)周期呼吸波、二阶和三阶退化呼吸波、解以及具有新模式的高阶流氓波。此外,当 m > 1 时,我们给出了几种一阶流氓波与一阶(二阶)(退化)呼吸器之间、一阶呼吸器与二阶退化呼吸器之间、二阶流氓波与一阶呼吸器之间的混合相互作用解。最后,我们还总结了退化呼吸器和混合局部波解的各种数学特征。
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引用次数: 0
Exploring chaotic behavior of optical solitons in complex structured Conformable Perturbed Radhakrishnan-Kundu-Lakshmanan Model 探索复杂结构可变形扰动拉达克里希南-昆杜-拉克希曼南模型中光孤子的混沌行为
Pub Date : 2024-07-25 DOI: 10.1088/1402-4896/ad67b1
Rashid Ali, Mohammad Mahtab Alam, Shoaib Barak
In this research, we aim to construct and examine optical soliton solutions for the complex structured Conformable Perturbed Radhakrishnan-Kundu-Lakshmanan Model (CPRKLM) using the Generalized-Kudryashov-Auxiliry Jacobian Method (GKAJM). The current study is notable for its thorough examination and for shedding insight on the chaotic behavior of families of localized optical soliton. Through the creation of 3D and contour visualizations that effectively capture the chaotic behaviors shown by these solitons, we are able to demonstrate that the optical solitons exhibit two distinct forms of perturbations: axial and periodic. Our research stimulates improvements in data processing tools and optical equipment, with consequences for communication networks and nonlinear fiber optics. Through a deeper understanding of optical solitons and their applications, this work also makes a substantial contribution to the discipline of nonlinear optics.
在这项研究中,我们旨在利用广义库德里亚绍夫-阿克西里雅各布方法(GKAJM),构建和检验复杂结构可变形扰动拉达克里希南-昆杜-拉克希曼模型(CPRKLM)的光学孤子解。当前研究的显著特点是对局部光孤子家族的混沌行为进行了深入研究和揭示。通过创建能有效捕捉这些孤子所表现出的混沌行为的三维和轮廓可视化,我们能够证明光学孤子表现出两种不同形式的扰动:轴向扰动和周期扰动。我们的研究促进了数据处理工具和光学设备的改进,并对通信网络和非线性光纤产生了影响。通过加深对光孤子及其应用的理解,这项工作还为非线性光学学科做出了重大贡献。
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引用次数: 0
Analyzing the Kuralay-II equation: Bifurcation, chaos, and sensitivity insights through conformable derivative and Jacobi elliptic function expansion 分析库拉雷-II方程:通过保形导数和雅可比椭圆函数展开深入了解分岔、混沌和敏感性
Pub Date : 2024-07-25 DOI: 10.1088/1402-4896/ad67af
Muhammad Ishfaq Khan, Abdullah Khan, Aamir Farooq
This study explores the intricate dynamics of the Kuralay-II equation by employing the conformable derivative. Using the Galilean transformation, we can establish a dynamical system related to the equation. We investigate bifurcation methods in this derived system using planar dynamical systems theory. By introducing a perturbed term, we thoroughly investigate the possibility of chaotic behaviors in the Kuralay-II equation using comprehensive two-phase portraiture. Through careful analysis, we have determined that even small changes in the initial conditions have little impact on the stability of the solution which has been confirmed by employing the Runge-Kutta method. In addition, we obtain exact solutions for the Kuralay-II equation by the Jacobi elliptic function expansion method. Graphical results of some solutions are showcased, offering a comprehensive evaluation using MATLAB across various dimensions. This study has yielded significant findings, such as the discovery of bifurcation points, the determination of conditions for chaos, and the analysis of stability under perturbations. These results have enhanced our understanding of the behavior of the Kuralay-II equation.
本研究利用保角导数探索库拉雷-II方程的复杂动力学。利用伽利略变换,我们可以建立一个与该方程相关的动力学系统。我们利用平面动力系统理论研究了这个派生系统的分岔方法。通过引入扰动项,我们利用全面的两相描绘深入研究了库拉雷-II 方程中混沌行为的可能性。通过仔细分析,我们确定即使初始条件发生微小变化,对解法稳定性的影响也很小,这一点已通过使用 Runge-Kutta 方法得到证实。此外,我们还通过雅可比椭圆函数展开法获得了库拉雷-II方程的精确解。我们展示了一些解法的图形结果,并使用 MATLAB 从不同维度进行了全面评估。这项研究取得了重大发现,如发现分岔点、确定混沌条件以及分析扰动下的稳定性。这些结果加深了我们对 Kuralay-II 方程行为的理解。
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引用次数: 0
An Adaptive Two-Step Staircase Static Reconfiguration Method for Improving the Power Generation of PV Array 改进光伏阵列发电量的自适应两步阶梯式静态重构方法
Pub Date : 2024-07-25 DOI: 10.1088/1402-4896/ad67b3
Lingzhi Yi, Siyue Cheng, Yahui Wang, Bote Luo, Jingxuan Tan, Jiangyong Liu
Partial shading of solar photovoltaic (PV) panels can significantly affect the performance of solar PV arrays. Various reconfiguration techniques have been explored in recent years. Still, their applicability to actual PV power generation is controversial due to the number of electrical switches, physical locations, interconnections and complexity. This study proposes an adaptive two-step staircase (A2SS) static reconfiguration method. The technique is experimentally validated in several conditions and compared with the conventional TCT connection, single-step staircase (1SS) static reconfiguration method, Arrow soduku, modified odd–even–prime (MOEP) and two-step staircase(2SS) static reconfiguration method. For the eight shading cases of LN, LW, LD, Ran, Cen, Cor, CD, and Plus at SET#1, after reconfiguring the PV array using A2SS, the power has a significant improvement of 17.6%, 17.0%, 13.4%, 13.4%, 20.6%, 20.2%, 3.1%, and 0.82% than TCT. In the four shading cases of Lr. C, Lr. O, Lr. T, and Lr. U at SET#2, the power showed a significant improvement of 11.8%, 9.2%, 10.7%, and 15.8% compared to TCT. It also has the best performance in various reconfiguration techniques, which are mentioned. In addition, the A2SS reconfiguration method can be better applied to various sizes of PV arrays. By optimizing the shading distribution and adjusting the row irradiance deviation, the power stability of PV power generation is improved while maximizing energy efficiency.
太阳能光伏(PV)板的局部遮阳会严重影响太阳能光伏阵列的性能。近年来,人们探索了各种重新配置技术。然而,由于电气开关的数量、物理位置、互连和复杂性,这些技术在实际光伏发电中的适用性仍存在争议。本研究提出了一种自适应两步阶梯(A2SS)静态重新配置方法。该技术在多种条件下进行了实验验证,并与传统的 TCT 连接、单步阶梯(1SS)静态重新配置方法、Arrow soduku、改进的奇偶校验(MOEP)和两步阶梯(2SS)静态重新配置方法进行了比较。在 SET#1 的 LN、LW、LD、Ran、Cen、Cor、CD 和 Plus 八种遮光情况下,使用 A2SS 重新配置光伏阵列后,功率比 TCT 分别显著提高了 17.6%、17.0%、13.4%、13.4%、20.6%、20.2%、3.1% 和 0.82%。在 Lr.C、Lr.O、Lr.T 和 Lr.在 SET#2 的 Lr.U、Lr.C、Lr.O、Lr.T 和 Lr.U 四种遮光情况下,与 TCT 相比,功率分别显著提高了 11.8%、9.2%、10.7% 和 15.8%。在各种重构技术中,它的性能也是最好的。此外,A2SS 重新配置方法可以更好地应用于各种规模的光伏阵列。通过优化遮阳分布和调整行辐照度偏差,可以提高光伏发电的功率稳定性,同时最大限度地提高能源效率。
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引用次数: 0
Evidence of spin-phonon interactions in MgCu2O3: low temperature Raman studies MgCu2O3 中自旋与声子相互作用的证据:低温拉曼研究
Pub Date : 2024-07-25 DOI: 10.1088/1402-4896/ad67b0
Somesh Chandra, Gurpreet Kaur, Rajkumar Gupta, S. Chakravarty, G. M. Bhalerao, Govindaraj Ramanujam
Experimental low temperature Raman spectroscopy studies upto the temperature of 83 K were performed on MgCu2O3 compound using 785 nm excitation source. Experimentally obtained Raman spectra compare well with those obtained from DFPT calculations. Phonon modes show different behaviour below and above the Néel temperature ~95 K. Anharmonic contribution is prominent above the Néel temperature but a significant departure from the anharmonic behaviour was observed for certain Ag and B3g modes below the Néel temperature. This behaviour is attributed to spin-phonon coupling present in the compound. The spin-phonon coupling arises due to modulation in the exchange integral by the lattice vibrations. The atomic vibrations of each mode and their effect on the exchange integral are discussed.
使用 785 nm 激发光源对 MgCu2O3 复合物进行了温度高达 83 K 的低温拉曼光谱实验研究。实验获得的拉曼光谱与 DFPT 计算获得的拉曼光谱对比良好。在奈尔温度(约 95 K)以下和以上,声子模式表现出不同的行为。在奈尔温度以上,非谐波贡献非常突出,但在奈尔温度以下,某些 Ag 和 B3g 模式明显偏离了非谐波行为。这种行为归因于化合物中存在的自旋-声子耦合。自旋-声子耦合是由于晶格振动对交换积分的调制而产生的。本文讨论了每种模式的原子振动及其对交换积分的影响。
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引用次数: 0
Performance enhancement of silicon photodiodes through the integration of green synthesized reduced graphene oxide variants 通过集成绿色合成的还原氧化石墨烯变体提高硅光电二极管的性能
Pub Date : 2024-07-25 DOI: 10.1088/1402-4896/ad67b8
D. E. Yıldız, O. Surucu, H. Mert Balaban, I. Bilici, Murat Yıldırım
This study examines the potential of enhancing the optoelectronic properties of silicon photodiodes by producing and analyzing heterostructures that incorporate reduced graphene oxide (rGO) synthesized with silicon using different reduction methods. Graphene oxide (GO) was manufactured utilizing an enhanced Hummers' method. Subsequently, reduced graphene oxides (rGOs) were made by chemical and thermal reduction processes, which are considered ecologically friendly. The use of ascorbic acid to produce ascorbic acid-reduced graphene oxide (ArGO) and thermal processing to produce thermally reduced graphene oxide (TrGO) have significantly contributed to the development of high-performance photodiode technology. The electrical properties were carefully assessed under different levels of light, revealing the substantial impact of integrating reduced graphene oxides (rGOs) on the performance of the diodes. Comparing ArGO/Si, TrGO/Si, and GO/Si heterostructures shows that customized rGO has the potential to greatly influence the responsivity and efficiency of Si-based optoelectronic devices, making a significant contribution to photodiode technology.
本研究通过生产和分析采用不同还原方法将还原氧化石墨烯(rGO)与硅合成在一起的异质结构,探讨了增强硅光电二极管光电特性的潜力。氧化石墨烯(GO)是利用增强型 Hummers 方法制造的。随后,还原石墨烯氧化物(rGOs)是通过化学和热还原工艺制成的,这些工艺被认为是生态友好型的。使用抗坏血酸制备抗坏血酸还原氧化石墨烯(ArGO)和热处理制备热还原氧化石墨烯(TrGO)极大地促进了高性能光电二极管技术的发展。我们仔细评估了不同光照强度下的电学特性,揭示了还原石墨烯氧化物(rGOs)的集成对二极管性能的重大影响。对 ArGO/Si、TrGO/Si 和 GO/Si 异质结构的比较表明,定制的 rGO 有可能极大地影响硅基光电器件的响应性和效率,从而为光电二极管技术做出重大贡献。
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引用次数: 0
Real-time particle concentration measurement from a hologram by deep learning 通过深度学习从全息图实时测量颗粒浓度
Pub Date : 2024-07-25 DOI: 10.1088/1402-4896/ad67ac
Hongjie Ou, Wendi Lin, Wei-Na Li, Xiangsheng Xie
Although current methods for measuring the concentration of transparent particles in digital holographic technology are effective, they involve complex procedures and require significant time and computational resources. The objective of this study was to accurately measure particle concentration from a single hologram. Deep learning was employed to measure the quantities of the particles of the same size, and we achieved a relative error less than 10% compared to the ground truth values. This indicates the potential to obtain results closely aligned with actual particle quantities without the reconstruction and denoising processes. The time needed for hologram prediction was at millisecond level, which offers a new possibility for real-time processing.
尽管目前在数字全息技术中测量透明粒子浓度的方法很有效,但它们涉及复杂的程序,需要大量的时间和计算资源。本研究的目标是通过单张全息图精确测量颗粒浓度。我们采用深度学习来测量相同大小颗粒的数量,结果与地面真实值相比,相对误差小于 10%。这表明,无需重构和去噪过程,我们就有可能获得与实际颗粒数量接近的结果。全息图预测所需的时间仅为毫秒级,这为实时处理提供了新的可能性。
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引用次数: 0
Numerical analysis of electrohydrodynamic printing under electric field focusing mode 电场聚焦模式下的电流体动力印刷数值分析
Pub Date : 2024-07-25 DOI: 10.1088/1402-4896/ad67aa
Dongqiao Bai, Jin Huang, Jianjun Wang, H. Gong, Chaoyu Liang, Jinquan Zhang
As an emerging micro/nanoscale 3D printing technology, Electrohydrodynamic (EHD) printing has undergone rapid development in recent years. However, in most EHD printing processes, voltage is directly applied to both the nozzle and the substrate, resulting in the electric field being influenced by the printing height. This poses challenges for printing three-dimensional curved surface structures. This study presents a comprehensive investigation into the EHD jetting process, utilizing a novel voltage loading method that separates electrodes from both the nozzle and the substrate. Through experimental setups and numerical simulations, this research was conducted to examine the effects of printing height, voltage, and electrode diameter on jetting behavior. The results show that compared to the traditional electrode form, the new voltage loading method will increase the electric field intensity of the liquid surface before ejection by 37.1% and is more conducive to the formation of Taylor cones. It can ensure that the printing fluctuation is less than 2.4% when the printing height varies between 1.5-2.5 times the nozzle diameter, which is more favorable for printing multi-layer structures. The threshold voltage for ejection is provided in this model. When the electrode is reduced, the efficiency of electric field utilization will be further improved, but the acceleration of the jet velocity will cause an increase in droplet size. The findings highlight the method's capability to maintain consistent droplet sizes and electric field intensities across varying conditions, thereby enhancing printing stability and efficiency. The study's innovations provide valuable insights for advancing micro/nano 3D printing technologies, emphasizing the potential for improved EHD printing processes in practical engineering applications.
作为一种新兴的微米/纳米级三维打印技术,电流体动力(EHD)打印近年来得到了快速发展。然而,在大多数 EHD 打印工艺中,电压直接作用于喷嘴和基底,导致电场受打印高度的影响。这给打印三维曲面结构带来了挑战。本研究采用一种新颖的电压加载方法,将电极与喷嘴和基底分开,对 EHD 喷射过程进行了全面研究。通过实验设置和数值模拟,本研究考察了打印高度、电压和电极直径对喷射行为的影响。结果表明,与传统的电极形式相比,新的电压加载方法将喷射前液体表面的电场强度提高了 37.1%,更有利于泰勒锥的形成。当打印高度在喷嘴直径的 1.5-2.5 倍之间变化时,它能确保打印波动小于 2.4%,更有利于打印多层结构。本模型中提供了弹射的阈值电压。当电极减小时,电场利用效率会进一步提高,但喷射速度的加快会导致液滴尺寸增大。研究结果凸显了该方法在不同条件下保持液滴大小和电场强度一致的能力,从而提高了印刷稳定性和效率。这项研究的创新为推进微米/纳米三维打印技术提供了宝贵的见解,强调了在实际工程应用中改进 EHD 打印工艺的潜力。
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引用次数: 0
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Physica Scripta
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