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Enhanced dielectric, magnetic, and photocatalytic properties of sol-gel synthesized Eu-Cr codoped BiFeO3 nanoparticles 溶胶-凝胶合成的 Eu-Cr 共掺杂 BiFeO3 纳米粒子的增强介电性能、磁性能和光催化性能
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d08
S. Parida, Jyotirmayee Nanda
A series of polycrystalline Eu-Cr co-doped BiFeO3 nanoparticles were synthesized using the sol-gel method. The obtained samples were characterized by employing the XRD, FTIR, FESEM, UV-vis, LCR meter, and SQUID techniques. XRD analysis confirmed rhombohedral phase formation for all samples, and the crystallite sizes decreased with higher Cr3+ doping concentrations. The stretching and bending vibrations of Fe-O bondings in FeO6 octahedra and the formation of perovskite nature were confirmed by the FTIR analysis. From microstructural studies, a decrease in crystallite size with increased doping concentration was observed, corroborating the XRD results. The magnetic studies revealed an enhanced magnetization, probably caused by the distorted cycloid spin structure of the Cr-doped nanoparticles with size ≤ 62 nm. The lower value of the squareness ratio of the M-H loop indicated strong interaction between the magnetic domains, which might have played a great role in the enhancement of the saturation magnetization of the doped samples. The dielectric constant and loss tangent were evaluated as a function of frequency at room temperature. The photocatalytic activities of all the samples were evaluated by measuring the degradation of RhB dye under sunlight irradiation. The highest photocatalytic degradation efficiency of 94% was achieved with the substitution of Cr3+ and Eu3+ ions in BiFeO3 nanoparticles
采用溶胶-凝胶法合成了一系列多晶 Eu-Cr 共掺杂 BiFeO3 纳米粒子。利用 XRD、FTIR、FESEM、UV-vis、LCR meter 和 SQUID 技术对所获得的样品进行了表征。XRD 分析证实了所有样品都形成了斜方体相,且晶体尺寸随着 Cr3+ 掺杂浓度的增加而减小。傅立叶变换红外光谱分析证实了 FeO6 八面体中 Fe-O 键的伸缩和弯曲振动以及包晶性质的形成。微观结构研究表明,随着掺杂浓度的增加,晶体尺寸也在减小,这与 XRD 的结果相吻合。磁性研究表明,掺杂了铬的纳米粒子的磁化增强,这可能是由于其扭曲的摆线自旋结构造成的,其尺寸≤ 62 nm。M-H 环的平方比值较低,表明磁畴之间存在较强的相互作用,这可能对掺杂样品饱和磁化的增强起到了重要作用。在室温下,评估了介电常数和损耗正切与频率的函数关系。通过测量 RhB 染料在阳光照射下的降解情况,评估了所有样品的光催化活性。在 BiFeO3 纳米粒子中取代 Cr3+ 和 Eu3+ 离子后,光催化降解效率最高,达到 94%。
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引用次数: 0
Study of Changes in the Pulsation Period of six Cepheids Variable 六颗倒灶变星的脉动周期变化研究
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d04
mohamed Adel Sabour, mohamed ibrahim nouh, Essam Elkhouly, Ian R Stevens
We study the period change of six Cepheids using 19376 accurate flux observations of the Solar Mass Ejection Imager (SMEI) onboard the Coriolis spacecraft. All observations for the six Cepheids have been derived as templates for each star, independent of the specific sites utilized to establish and update the O-C values. Sometimes, sinusoidal patterns are superimposed on the star's O-C changes, which cannot be regarded as random fluctuations in the pulsation period. Random period changes were detected and computed using Eddington's and Plakidis's approaches. A comparison of the observed and predicted period change reveals a good agreement with some published models and a very substantial divergence with others. Between the reported period change and that estimated by the current technique, a linear fit with a correlation coefficient of 90.08 percent was obtained. The temporal rate of period change in Cepheid stars might be connected to how well these stars' mass losses are known today.
我们利用科里奥利航天器搭载的太阳质量抛射成像仪(SMEI)的 19376 次精确通量观测,研究了六颗仙王座的周期变化。对这六颗蛇夫座恒星的所有观测结果都是作为每颗恒星的模板得出的,与用来建立和更新O-C值的具体地点无关。有时,恒星的 O-C 变化会叠加正弦模式,这不能被视为脉动周期的随机波动。利用爱丁顿和普拉基迪斯方法检测并计算了随机周期变化。对观测到的周期变化和预测的周期变化进行比较后发现,观测到的周期变化与一些已发表的模型十分吻合,而与另一些模型则有很大差异。在报告的周期变化和当前技术估计的周期变化之间,得到了线性拟合,相关系数为 90.08%。仙王座恒星周期变化的时间率可能与目前对这些恒星质量损失的了解程度有关。
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引用次数: 0
An efficient hybrid approach for numerical study of two-dimensional time-fractional Cattaneo model with Riesz distributed-order space-fractional operator along with stability analysis 对带有里兹分布阶空间分数算子的二维时间分数卡塔尼奥模型进行数值研究和稳定性分析的便捷混合方法
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d02
M. Derakhshan, S. L. Mortazavifar, P. Veeresha, J. F. Gómez‐Aguilar
In this article, we study and analyze the two-dimensional time-fractional Cattaneo model with Riesz space distributed-order. To obtain approximate solutions of this type of fractional model the combined and effective numerical approach based on the ADI Galerkin method and the Legendre spectral method used the ADI Galerkin numerical method uses the finite difference approach. The ADI Galerkin numerical method is used to approximate the proposed model in terms of the time variable, and the Legendre spectral method is applied to discretize the fractional model with respect to the space variable. Also, the convergence analysis and stability of the proposed method are discussed and reviewed in this manuscript. In the end, some numerical examples are tested for the effectiveness and accuracy of the proposed method.
本文研究分析了具有里兹空间分布阶的二维时间分数卡塔尼奥模型。为了得到这类分数模型的近似解,我们采用了基于 ADI Galerkin 方法和 Legendre 光谱法的组合而有效的数值方法。ADI Galerkin 数值方法用于在时间变量上近似拟建模型,而 Legendre 频谱方法则用于在空间变量上离散分形模型。此外,本手稿还讨论和评述了所提方法的收敛性分析和稳定性。最后,通过一些数值实例检验了所提方法的有效性和准确性。
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引用次数: 0
The corrections to the metric of Reissner-Nordström Black Hole from the Generalized Uncertainty Principle 广义不确定性原理对赖斯纳-诺德斯特伦黑洞度量的修正
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d0a
A. Sefiedgar, Hossein Jabari
The emergence of the minimal observable length is commonly accepted in most of the quantum gravitational candidates. The existence of such a minimal length in high energy physics necessitates some revisions to the standard uncertainty principle. The generalized uncertainty principle is particularly suitable for incorporating such a finite resolution of the space-time and may provide a useful phenomenological approach to study the physics of quantum gravity. It is possible to use the generalized uncertainty principle to modify the black hole thermodynamics straightforwardly. However, it is also possible to use the generalized uncertainty principle to modify the black hole metric itself. In this paper, we are going to modify the Reissner-Nordström metric in the presence of the quantum gravitational effects via the generalized uncertainty principle. Then, we use the modified charged black hole metric to study the black hole thermodynamics. The modified metric is also applied to study the light deflection angle.
最小可观测长度的出现已被大多数量子引力候选者普遍接受。在高能物理中存在这种最小长度,就有必要对标准不确定性原理进行一些修订。广义不确定性原理特别适合纳入这种有限的时空分辨率,并可能为研究量子引力物理学提供一种有用的现象学方法。利用广义不确定性原理可以直接修改黑洞热力学。然而,利用广义不确定性原理修改黑洞度量本身也是可能的。在本文中,我们将通过广义不确定性原理修改存在量子引力效应的赖斯纳-诺德斯特伦度量。然后,我们利用修改后的带电黑洞度量来研究黑洞热力学。修正度量还被用于研究光的偏转角。
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引用次数: 0
Entropy generation in Newtonian Vs Non-Newtonian nanofluid flow under vibration 振动下牛顿与非牛顿纳米流体流动中的熵产生
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d11
S. Mishra, Alka Mishra, Pushpendra Singh
Numerical investigation into the effects of vibration on heat transfer and entropy generation in Newtonian and Non-Newtonian nanofluid flows through pipes reveals enhanced heat transfer via intensified fluid agitation and improved particle dispersion. Mechanical vibrations destabilize fluid flow and heat transfer but increase heat transfer rates by inducing swirling motion and enhancing radial mixing, leading to a more uniform temperature distribution. Thermal entropy generation analysis shows reduced irreversibility in vibrated flow, indicating improved flow mixing. Vibration enhances heat transfer by intensifying fluid agitation and promoting particle dispersion near the wall, resulting in a significantly more uniform temperature distribution along the pipe, approximately 100 times more than steady-state flow. This study underscores vibration's potential to optimize heat transfer and reduce entropy generation in nanofluid systems, emphasizing velocity and rheological impacts. Comparison of vibrated flow to steady-state flow for Newtonian and non-Newtonian fluids reveals significant improvements under vibration, particularly at lower Reynolds numbers where non-Newtonian fluids exhibit pronounced effects. Future research directions include exploring thermal radiation's impact on entropy generation, analyzing different nanofluid compositions, and investigating varied boundary conditions and geometries to advance understanding in this field. This study provides valuable insights into the complex interplay among vibration, fluid dynamics, and heat transfer in nanofluid flows. Its findings have practical implications for optimizing thermal management systems in diverse engineering applications
对振动对牛顿和非牛顿纳米流体流经管道时的传热和熵产生的影响进行的数值研究表明,通过加强流体搅拌和改善颗粒分散,传热得到了增强。机械振动破坏了流体流动和传热的稳定性,但通过诱导漩涡运动和加强径向混合提高了传热率,从而使温度分布更加均匀。热熵生成分析表明,振动流动的不可逆性降低,表明流动混合得到改善。振动通过加强流体搅拌和促进颗粒在管壁附近的分散来增强传热,从而使管道沿线的温度分布明显更加均匀,约为稳态流动的 100 倍。这项研究强调了振动在优化纳米流体系统传热和减少熵产生方面的潜力,同时强调了振动对速度和流变的影响。将牛顿流体和非牛顿流体的振动流动与稳态流动进行比较后发现,在振动条件下,尤其是在雷诺数较低时,非牛顿流体会表现出明显的影响,因此振动对流体有显著的改善作用。未来的研究方向包括探索热辐射对熵产生的影响、分析不同的纳米流体成分以及研究不同的边界条件和几何形状,以促进对这一领域的理解。这项研究为了解纳米流体流动中振动、流体动力学和热传递之间复杂的相互作用提供了宝贵的见解。其研究结果对优化各种工程应用中的热管理系统具有实际意义
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引用次数: 0
Vortex superlattice induced second-order topological mid-gap states in first-order topological insulators and superconductors 一阶拓扑绝缘体和超导体中涡旋超晶格诱导的二阶拓扑中隙态
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d1a
Jing He, Yu Yan, Yajie Wu
Topological defects such as vortex and dislocations, support zero-energy localized states as a reflection of the bulk topology, in first-order topological insulators and superconductors. Furthermore, emergent first-order topological mid-gap states have been discovered driven by the magnetic vortex superlattice. However, whether the higher-order topological mid-gap states would emerge from the first-order topological insulators and superconductors with the vortex superlattice remains elusive. In this work, we propose vortex superlattice could induce second-order topological mid-gap states with staggered lattice spacings for vortices in first-order topological insulators and superconductors. These higher-order topological mid-gap states originate from the staggered tunneling between vortex-induced bound states and the emergent π flux on vortex superlattices, as an intrinsic exhibition of the interplay between vortices and bulk topology for the first-order topological states. Our work uncovers higher-topological characteristics of topological-defect superlattice in first-order topological states, and develops a controllable environment for the creation and exploration of higher-order topological states.
在一阶拓扑绝缘体和超导体中,涡旋和位错等拓扑缺陷支持零能局部态,作为体拓扑结构的反映。此外,人们还发现了由磁涡旋超晶格驱动的新兴一阶拓扑中隙态。然而,在具有涡旋超晶格的一阶拓扑绝缘体和超导体中是否会出现更高阶的拓扑中隙态,仍然是一个未知数。在这项工作中,我们提出涡旋超晶格可以在一阶拓扑绝缘体和超导体中诱导出具有交错晶格间距的二阶拓扑中隙态。这些高阶拓扑中隙态源于涡旋诱导的束缚态与涡旋超晶格上出现的π通量之间的交错隧穿,是涡旋与一阶拓扑态的体拓扑之间相互作用的内在表现。我们的工作揭示了拓扑缺陷超晶格在一阶拓扑态中的高拓扑特性,并为创建和探索高阶拓扑态开发了一种可控环境。
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引用次数: 0
First-principles study on electronic and mechanical properties of Ru2XAl (X=Mn, Zr, Ti, Hf) alloys 关于 Ru2XAl(X=Mn、Zr、Ti、Hf)合金电子和机械特性的第一性原理研究
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d0f
Peichen Hao, Wenzhi Liu, Jian Wang
The magnetic properties of Heusler alloys have been a hot research topic. However, the current understanding of the properties of Ru-based Heusler alloys is still very limited. The magnetic, electronic, and mechanical properties of four Ru-based Heusler alloys, Ru2XAl (X=Mn, Zr, Ti, Hf) were calculated by the first-principles. This article studied the basic mechanical parameters of four types of Heusler alloys, such as bulk elastic modulus, Cauchy pressure, Pugh’s ratio, shear modulus, Kleinman parameter, Young's modulus, Poisson's ratio, and elastic constant. The calculated results of the elastic constant prove that all four alloys are mechanically stable. Ru2MnAl alloy exhibits brittleness, while the other three alloys exhibit excellent ductility based on Poisson's ratio and Pugh’s ratio. The Kleinman parameter of the four alloys are all greater than 0.5, indicating that they have stronger stability in the tensile state. In addition, the magnetism of Ru2MnAl is 2.113 , which is consistent with the SP rule and other theoretical calculations.
Heusler 合金的磁性能一直是研究的热点。然而,目前对 Ru 基 Heusler 合金特性的了解仍然非常有限。本文通过第一性原理计算了四种 Ru 基 Heusler 合金 Ru2XAl(X=Mn、Zr、Ti、Hf)的磁性、电子和力学性能。本文研究了四种 Heusler 合金的基本力学参数,如体积弹性模量、Cauchy 压力、Pugh 比、剪切模量、Kleinman 参数、杨氏模量、泊松比和弹性常数。弹性常数的计算结果证明这四种合金都具有机械稳定性。根据泊松比和普氏比,Ru2MnAl 合金表现出脆性,而其他三种合金则表现出优异的延展性。四种合金的克莱因曼参数都大于 0.5,表明它们在拉伸状态下具有更强的稳定性。此外,Ru2MnAl 的磁性为 2.113,与 SP 规则和其他理论计算结果一致。
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引用次数: 0
Investigation of a cascaded piezoelectric transducer with cone horn for multi-mode power ultrasound application 带锥角的级联压电换能器在多模式功率超声应用中的研究
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d05
Guo Li, Ming Lei, XiaoLi Zhang, Yan Zeng, Shaojie Tang, Jianxu Shi, Liqing Hu
To meet the ultrasonic application requirement of high power intensity and large mechanical displacement, a new theoretical method is used to study the multi-mode characteristic of the cascaded piezoelectric transducer with cone horn in this paper. Based on equivalent circuit and Kirchhoff's law to obtain the frequency equation and vibration velocity expression of the transducer, then the resonance frequency and effective electromechanical coupling coefficient can be calculated, the velocity amplification ratio can be obtained in the meantime. This method is distinguish from traditional theoretical analysis, which avoids complex transformation of the multi-excitation sources in cascaded structure, and can calculate more performance parameters. The relationships between these performance parameters and the excitation position of the piezoelectric stack, the length and output end radius of the cone horn are analyzed and compared with the numerical simulation, and the optimized parameters of the transducer size are given. A transducer is manufactured for experimental test, the results show that the experimental value is in good agreement with theoretical calculation and finite element simulation. This work is expected to be used in the optimal analysis of the multi-mode transducer in high power ultrasonic field.
为满足高功率强度和大机械位移的超声应用要求,本文采用一种新的理论方法来研究带锥角的级联压电换能器的多模特性。基于等效电路和基尔霍夫定律求得传感器的频率方程和振动速度表达式,进而计算共振频率和有效机电耦合系数,同时求得速度放大比。这种方法区别于传统的理论分析,避免了级联结构中多激励源的复杂变换,可以计算出更多的性能参数。分析了这些性能参数与压电堆激励位置、锥角长度和输出端半径之间的关系,并与数值模拟进行了比较,给出了换能器尺寸的优化参数。制造了一个换能器进行实验测试,结果表明实验值与理论计算值和有限元模拟值吻合良好。这项工作有望用于大功率超声领域多模换能器的优化分析。
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引用次数: 0
Thermal modeling and simulation applied to novel microwave hybrid heating process 应用于新型微波混合加热工艺的热建模与模拟
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d06
Tarunpreet Singh, Shankar Sehgal
Owing to the unique encouraging characteristics of microwave hybrid heating, primarily volumetric heating, and additional potentials such as being repeatable, quick, economical, and green; it has been utilized in various processing techniques. The efficient joining of mild steel pipes through microwave hybrid heating in a multimode applicator at 2.45 GHz and 900 W for an operational time of 480s has already been performed. The modeling and simulation of the process have been performed in this research paper as the numerical analysis of the working environment is crucial for evaluating various aspects of a technique, decreases process-design cycle time, and found to be more economical than experimental trials. The numerical analysis provides in-depth insight-taking into consideration of the electromagnetic field distribution, its interaction with the materials, heat generation and transfer, along with the thermal analysis of the experimental assembly, in addition to the comprehensive parametric analysis. The numerical model of the assembled set-up was developed in order to simulate a real-life heating environment by solving electromagnetic and heat transfer equations and providing analytically predicted results with an accuracy of 3.75% against the experimental results. The analytical modeling and simulation have been strategically fragmented into three phases which are pre-processing, processing, and post-processing phase and elucidated extensively, providing a systematic working of the analytical model. This research will be utilized further in optimizing the microwave hybrid heating process in order to make it time-efficient and inexpensive for its applications to industrial environments.
由于微波混合加热(主要是容积加热)具有独特的令人鼓舞的特性,以及可重复、快速、经济和绿色等其他潜力,它已被用于各种加工技术中。在 2.45 GHz 和 900 W 的多模应用器中,通过微波混合加热对低碳钢管进行高效连接,工作时间为 480 秒。本研究论文对该工艺进行了建模和仿真,因为工作环境的数值分析对于评估一项技术的各个方面至关重要,可以缩短工艺设计周期,而且比实验试验更经济。除了综合参数分析之外,数值分析还考虑了电磁场分布、电磁场与材料的相互作用、热量产生和传递,以及实验装配的热分析,从而提供了深入的见解。为了模拟现实生活中的加热环境,通过求解电磁和传热方程,开发了组装装置的数值模型,并提供了分析预测结果,与实验结果相比,精确度达到 3.75%。分析建模和模拟从战略上分为三个阶段,即前处理、处理和后处理阶段,并进行了广泛阐释,为分析模型提供了系统的工作方法。这项研究将进一步用于优化微波混合加热工艺,使其在工业环境中的应用既省时又便宜。
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引用次数: 0
Label-free biochemical sensor for hydrogen peroxide detection enabled by a misaligned square coreless fiber 利用错位方形无芯光纤实现过氧化氢检测的无标记生化传感器
Pub Date : 2024-08-08 DOI: 10.1088/1402-4896/ad6d17
Xiao Liu, Qianying Feng, Jixuan Wu, Binbin Song, Hanchao Sun, Jifang Wang
Hydrogen peroxide (H2O2) is a common chemical substance that is widely used in many industries. Within a certain concentration range, hydrogen peroxide is hazardous and toxic. Therefore, it is crucial to accurately determine the concentration of hydrogen peroxide for safety and diagnostic purposes. Herein, a label-free biochemical sensor is proposed and experimentally demonstrated for highly efficient H2O2 detection. The biosensor is based on a misaligned square coreless fiber, which is fabricated using ultrasonic vibrational cutting technology. The surface of the square coreless fiber is functionalized with catalytic enzymes through covalent bonding, allowing for the accurate detection of H2O2 concentration. The experimental results show that label-free biochemical sensor exhibits a sensitivity of 0.0083 nm/μM within the H2O2 concentration range of 0-800 μM. A low limit of detection of 7.95×10-4mol/L is also obtained during the detection of H2O2solution. Furthermore, the developed optical sensor provides a biochemical platform for determining enzyme-catalyzed reactions and can be applied in the fields of food safety, health monitoring, and environmental protection.
过氧化氢(H2O2)是一种常见的化学物质,广泛应用于许多行业。在一定浓度范围内,过氧化氢具有危险性和毒性。因此,准确测定过氧化氢的浓度对于安全和诊断至关重要。本文提出了一种用于高效检测过氧化氢的无标记生化传感器,并进行了实验验证。该生物传感器基于错位方形无芯光纤,采用超声振动切割技术制作而成。方形无芯纤维的表面通过共价键与催化酶功能化,从而实现对 H2O2 浓度的精确检测。实验结果表明,在 0-800 μM 的 H2O2 浓度范围内,无标记生化传感器的灵敏度为 0.0083 nm/μM。在检测 H2O2 溶液时,检测限也较低,为 7.95×10-4mol/L。此外,所开发的光学传感器为测定酶催化反应提供了一个生化平台,可应用于食品安全、健康监测和环境保护等领域。
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引用次数: 0
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Physica Scripta
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