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Exploring the Microscopic Physical Processes of Z-pinch by a Modified Electrostatic Direct Implicit Particle-in-Cell Algorithm 用修正的静电直接隐含粒子池算法探索 Z-pinch 的微观物理过程
Pub Date : 2024-06-07 DOI: 10.1088/1674-1056/ad553a
Kaixuan Li, Cheng Ning, Ye Dong, Chuang Xue
For investigating efficiently the stagnation kinetic-process of Z-pinch, we develop a novel modified electrostatic implicit particle-in-cell (PIC) algorithm in radial one-dimension for Z-pinch simulation in which a small-angle cumulative binary collision algorithm is used. In our algorithm, the electric field in z-direction is solved by a parallel electrode-plate model, the azimuthal magnetic field is obtained by Ampere's law, and the term for charged particle gyromotion is approximated by the cross product of the averaged velocity and magnetic field. In simulation results of 2 MA deuterium plasma shell Z-pinch, the mass center implosion trajectory agree generally with that obtained by one dimensional MHD simulation, and the plasma current also closely aligns with the external current. The phase space diagrams and radial velocity probability distributions of ions and electrons are obtained. The main kinetic characteristic of electron motion is thermal equilibrium and oscillation, which should be oscillated around the ions, while that of ion motion is implosion inwards. In the region of stagnation radius, the radial velocity probability distributions of ions transit from the non-equilibrium to equilibrium state with the current increasing, while electron’s is basically the equilibrium state. When the initial ion density and current peak aren’t high enough, the ions may not reach their thermal equilibrium state through collisions even in its stagnation phase.
为了有效研究 Z-夹子的停滞动力学过程,我们开发了一种新颖的径向一维静电隐式粒子入胞(PIC)算法,用于 Z-夹子模拟,其中使用了小角度累积二元碰撞算法。在我们的算法中,Z 方向的电场由平行电极板模型求解,方位磁场由安培定律求得,带电粒子回旋运动项由平均速度和磁场的乘积近似得到。在 2 MA 氘等离子体壳 Z-pinch 的模拟结果中,质心内爆轨迹与一维 MHD 模拟结果基本一致,等离子体电流也与外部电流密切相关。得到了离子和电子的相空间图和径向速度概率分布。电子运动的主要动力学特征是热平衡和振荡,应围绕离子振荡,而离子运动的主要动力学特征是向内内爆。在停滞半径区域,随着电流的增大,离子的径向速度概率分布从非平衡态过渡到平衡态,而电子的径向速度概率分布基本处于平衡态。当初始离子密度和电流峰值不够高时,即使在停滞阶段,离子也可能无法通过碰撞达到热平衡状态。
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引用次数: 0
Phase structure evolution and its effect on magnetic and mechanical properties of B-doped Sm2Co17-type magnets with high Fe content 高铁含量的掺 B Sm2Co17 型磁体的相结构演化及其对磁性和机械性能的影响
Pub Date : 2024-06-07 DOI: 10.1088/1674-1056/ad5535
Yao-Wen Li, Zhuang Liu, Hai-Chen Wu, Fang Wang, Chao-Qun Zhu, Dong-Liang Tan, Yu Liu, Yang Yang, Ming-Xiao Zhang, Ren-Jie Chen, Aru Yan
The unique cellular microstructure of Fe-rich Sm2Co17-type permanent magnets is closely associated with the structure of the solid solution precursor. In this article, the phase structure, magnetic properties, and mechanical behavior of B-doped Sm2Co17-type magnets with high Fe content are investigated. The doped B atoms can diffuse into the interstitial vacancy, resulting in lattice expansion and promote the homogenization of the phase organizational structure during the solid solution treatment in theory. However, the resulting second phase plays a dominant role, resulting in more microtwin structures and highly ordered 2:17R phases in the solid solution stage, which inhibits the ordering transformation of 1:7H phase during aging and affects the generation of the cellular structure, and resulting in a decrease in magnetic properties, yet the interface formed between it and the matrix phase hinders the movement of dislocations and enhances the mechanical properties. Hence, the precipitation of high flexural strain grain boundary phase induced by B element doping is also a new and effective way to improve the flexural strain of Sm2Co17-type magnets. Our study provides a new understanding of the phase structure evolution and its effect on the magnetic and mechanical properties of Sm2Co17-type magnets with high Fe content.
富铁 Sm2Co17 型永磁体独特的蜂窝状微观结构与固溶体前驱体的结构密切相关。本文研究了高铁含量的掺 B Sm2Co17 型磁体的相结构、磁性能和力学行为。在理论上,掺杂的 B 原子可以扩散到间隙空位中,导致晶格膨胀,并在固溶处理过程中促进相组织结构的均匀化。但由此产生的第二相起主导作用,在固溶阶段形成更多的微丝结构和高度有序的 2:17R 相,在老化过程中抑制了 1:7H 相的有序转变,影响了蜂窝结构的生成,导致磁性能下降,但它与基体相之间形成的界面阻碍了位错的移动,增强了力学性能。因此,B 元素掺杂诱导的高弯曲应变晶界相的析出也是改善 Sm2Co17 型磁体弯曲应变的一种新的有效方法。我们的研究为相结构演化及其对高铁元素含量的 Sm2Co17 型磁体的磁性和力学性能的影响提供了新的认识。
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引用次数: 0
Effect of antioxidant on the efficiency of jet milling and the powder characteristics of Sm2Co17 permanent magnets 抗氧化剂对喷射研磨效率和 Sm2Co17 永磁体粉末特性的影响
Pub Date : 2024-06-07 DOI: 10.1088/1674-1056/ad5537
Dashuai Xu, Lei Liu, Jianhui Yuan, Bo Zhou, Chuang-Hui Dong, Fengxi Wang, Yong Ding, Ying-Li Sun, A. Yan
This study investigated the effect of antioxidants on the grinding efficiency, magnetic powder characteristics, microstructure, and magnetic properties of 2:17 type SmCo permanent magnet materials. The results show that adding antioxidants helps improve the dispersion among magnetic powders, leading to a 33.3 % decrease in jet milling time and a 15.8 % increase in magnet powder production yield. Additionally, adding antioxidants enhances the oxidation resistance of the magnetic powders. After being stored in a constant temperature air environment at 25 ℃ for 48 h, the O content in the powder decreased by 33 % compared to samples without antioxidants. While in the magnet body, the O content decreased from 0.21 wt.% to 0.14 wt.%, which helps increase the effective Sm content and domain wall pinning uniformity in the magnet. Excellent magnetic properties were obtained in the magnet with added antioxidants: B r = 11.6 kGs, SF = 79.6 %, H cj = 16.8 kOe, and (BH) max = 32.5 MGOe.
本研究调查了抗氧化剂对 2:17 型钐钴永磁材料的研磨效率、磁粉特性、微观结构和磁性能的影响。结果表明,添加抗氧化剂有助于改善磁粉之间的分散性,从而使喷射研磨时间缩短 33.3%,磁粉产量提高 15.8%。此外,添加抗氧化剂还能增强磁粉的抗氧化性。在 25 ℃ 的恒温空气环境中存放 48 小时后,磁粉中的 O 含量比未添加抗氧化剂的样品减少了 33%。而在磁体中,O 的含量从 0.21 wt.% 降至 0.14 wt.%,这有助于提高磁体中的有效 Sm 含量和域壁钉扎均匀性。添加了抗氧化剂的磁体具有优异的磁性能:B r = 11.6 kGs、SF = 79.6 %、H cj = 16.8 kOe 和 (BH) max = 32.5 MGOe。
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引用次数: 0
The Effects of Air Damping on the Quality Factors of Different Probes in Tapping Mode Atomic Force Microscopy 空气阻尼对攻丝模式原子力显微镜中不同探针质量因素的影响
Pub Date : 2024-06-07 DOI: 10.1088/1674-1056/ad5539
Yu Zeng, Guolin Liu, Jinhao Liu, Zheng Wei
The AFM probe in tapping mode is a continuous process of energy dissipation, from moving away from to intermittent contact with the sample surfaces. At present, studies regarding the energy dissipation mechanism of this continuous process have only been reported sporadically, and there are no systematic explanations or experimental verifications of the energy dissipation mechanism in each stage of the continuous process. The quality factors can be used to characterize the energy dissipation in TM-AFM systems. In this study, the vibration model of the microcantilever beam was established, coupling the vibration and damping effects of the microcantilever beam. The quality factor of the vibrating microcantilever beam under damping was derived, and the air viscous damping when the probe is away from the sample and the air squeeze film damping when the probe is close to the sample were calculated. In addition, the mechanism of the damping effects of different shapes of probes at different tip-sample distances was analyzed. The accuracy of the theoretical simplified model was verified using both experimental and simulation methods. A clearer understanding of the kinetic characteristics and damping mechanism of the TM-AFM was achieved by examining the air damping dissipation mechanism of AFM probes in the tapping mode, which was very important for improving both the quality factor and the imaging quality of the TM-AFM system. This study’s research findings also provided theoretical references and experimental methods for the future study of the energy dissipation mechanism of micro-nanoelectromechanical systems.
攻丝模式下的原子力显微镜探针与样品表面从远离到间歇接触是一个连续的能量耗散过程。目前,关于这一连续过程的能量耗散机制的研究仅有零星报道,对于连续过程中各阶段的能量耗散机制还没有系统的解释或实验验证。质量因子可用于表征 TM-AFM 系统中的能量耗散。本研究建立了微悬臂梁的振动模型,耦合了微悬臂梁的振动和阻尼效应。得出了微悬臂梁在阻尼作用下振动的品质因数,并计算了探头远离样品时的空气粘性阻尼和探头靠近样品时的空气挤压膜阻尼。此外,还分析了不同形状的探针在不同针尖-样品距离下的阻尼效应机理。实验和模拟方法验证了理论简化模型的准确性。通过研究原子力显微镜探针在攻丝模式下的空气阻尼耗散机制,对 TM-AFM 的动力学特性和阻尼机制有了更清晰的认识,这对提高 TM-AFM 系统的品质因数和成像质量都非常重要。这项研究成果也为今后研究微纳机电系统的能量耗散机制提供了理论参考和实验方法。
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引用次数: 0
Two-dimensional Cr2Cl3S3 Janus Magnetic Semiconductor with large magnetic exchange interaction and high-T C 具有大磁交换相互作用和高 T C 的二维 Cr2Cl3S3 Janus 磁性半导体
Pub Date : 2024-06-07 DOI: 10.1088/1674-1056/ad5538
Lei Fu, a, Shasha Li, Xiangyan Bo, Sai Ma, Feng Li, Yong Pu
2D Janus monolayers are promising in spintronic device application due to their enhanced magnetic couplings and Curie temperatures. Van der Waals CrCl3 monolayer has been experimentally proved to have an in-plane magnetic easy axis and a low Curie temperature of 17 K, which will limit its application in spintronic devices. In this work, we propose a new Janus monolayer Cr2Cl3S3 based on the first principles calculations. The phonon dispersion and elastic constants confirm that Janus monolayer Cr2Cl3S3 is dynamically and mechanically stable. Our Monte Carlo simulation results based on magnetic exchange constants reveal that Janus monolayer Cr2Cl3S3 is an intrinsic ferromagnetic semiconductor with TC of 180 K, which is much higher than that of CrCl3 due to the enhanced ferromagnetic coupling caused by S substitution. Moreover, the magnetic easy axis of Janus Cr2Cl3S3 can be tuned to the perpendicular direction with a large magnetic anisotropy energy (MAE) of 142 μeV/Cr. Furthermore, the effect of biaxial strain on the magnetic property of Janus monolayer Cr2Cl3S3 is evaluated. It is found that the Curie temperature is more robust under tensile strain. This work indicates that the Janus monolayer Cr2Cl3S3 presents increased Curie temperature and out-of-plane magnetic easy axis, suggesting greater application potential in 2D spintronic devices.
二维杰纳斯单层因其增强的磁耦合和居里温度而在自旋电子器件应用中大有可为。实验证明,范德华CrCl3单层具有面内磁易轴和17 K的低居里温度,这将限制其在自旋电子器件中的应用。在这项工作中,我们根据第一性原理计算提出了一种新的杰纳斯单层 Cr2Cl3S3。声子色散和弹性常数证实了 Janus 单层 Cr2Cl3S3 具有动态和机械稳定性。基于磁交换常数的蒙特卡罗模拟结果表明,Janus单层Cr2Cl3S3是一种本征铁磁性半导体,其TC值为180 K,远高于CrCl3的TC值,这是由于S取代引起的铁磁耦合增强所致。此外,Janus Cr2Cl3S3 的磁易轴可以调谐到垂直方向,磁各向异性能(MAE)高达 142 μeV/Cr。此外,还评估了双轴应变对 Janus 单层 Cr2Cl3S3 磁性能的影响。结果发现,在拉伸应变下居里温度更稳定。这项研究表明,Janus 单层 Cr2Cl3S3 的居里温度和面外磁易轴都有所提高,这表明它在二维自旋电子器件中具有更大的应用潜力。
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引用次数: 0
Mapping the antiparallel aligned domain rotation by microwave excitation 通过微波激发绘制反平行排列畴旋转图
Pub Date : 2024-06-07 DOI: 10.1088/1674-1056/ad5536
Jing Zhang, Yuanzhi Cui, Xiaoyu Wang, Chuang Wang, Mengchen Liu, Jie Xu, Kai Li, Yunhe Zhao, Zhenyan Lu, L. Pan, Chendong Jin, Qingfang Liu, Jianbo Wang, D. Cao
The evolution process of magnetic domains in response to external fields is crucial for the modern understanding and application of spintronics. In this study, we investigated the domain rotation in stripe domain films of varying thicknesses by examining their response to microwave excitation in four different orientations. The resonance spectra indicate that the rotation field of stripe domain film under an applied magnetic field approaches the field where the resonance mode of sample changes. The saturation field of the stripe domain film corresponds to the field where the resonance mode disappears when measured in the stripe direction parallel to the microwave magnetic field. The results are reproducible and consistent with micromagnetic simulations, providing additional approaches and techniques for comprehending the microscopic mechanisms of magnetic domains and characterizing their rotation.
磁畴对外部磁场的响应演变过程对于现代自旋电子学的理解和应用至关重要。在这项研究中,我们通过研究不同厚度的条纹畴薄膜在四个不同方向上对微波激励的响应,研究了它们的畴旋转过程。共振频谱表明,条纹畴薄膜在外加磁场下的旋转磁场接近样品共振模式发生变化的磁场。条纹畴薄膜的饱和磁场对应于平行于微波磁场的条纹方向测量时共振模式消失的磁场。研究结果具有可重复性,并且与微磁模拟结果一致,为理解磁畴的微观机制和描述其旋转特性提供了更多的方法和技术。
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引用次数: 0
Single crystal growth and characterization of 166-type magnetic Kagome metals 166 型磁性卡戈米金属的单晶生长与表征
Pub Date : 2024-06-07 DOI: 10.1088/1674-1056/ad553b
Huangyu Wu, Jinjin Liu, Yongkai Li, Peng Zhu, Liu Yang, Fuhong Chen, Deng Hu, Zhiwei Wang
Kagome magnets were predicted to be a good platform to investigate correlated topology band structure, Chern quantum phase, and geometrical frustration since their unique lattice geometry. Here we reported single crystal growth of 166-type Kagome magnetic materials, including HfMn6Sn6, ZrMn6Sn6, GdMn6Sn6 and GdV6Sn6, by using flux method with Sn as a flux. Among them, HfMn6Sn6 and ZrMn6Sn6 single crystals were grown for the first time. X-ray diffraction measurements reveal that all four samples crystallized in HfFe6Ge6-type hexagonal structure with space group of P6/mmm. All samples show metallic behavior from temperature dependence of resistivity measurements, and the dominate carrier is hole, except for GdV6Sn6 which is electron dominated. All samples have magnetic order with different transition temperature, HfMn6Sn6, ZrMn6Sn6 and GdV6Sn6 are antiferromagnetic with the T N of 541 K, 466 K and 4 K respectively, while GdMn6Sn6 is ferrimagnetic with the critical temperature about 470 K. This study will enrich the research platform of magnetic Kagome materials and help explore the novel quantum phenomenon in these interesting materials.
由于卡戈米磁体具有独特的晶格几何形状,因此被认为是研究相关拓扑带结构、切尔量子相和几何挫折的良好平台。在此,我们报道了以 Sn 为磁通量,采用磁通量法单晶生长出 166 种 Kagome 磁性材料,包括 HfMn6Sn6、ZrMn6Sn6、GdMn6Sn6 和 GdV6Sn6。其中,HfMn6Sn6 和 ZrMn6Sn6 单晶是首次生长出来的。X 射线衍射测量结果表明,所有四种样品都结晶为 HfFe6Ge6 型六方结构,空间群为 P6/mmm。从电阻率测量的温度依赖性来看,除 GdV6Sn6 以电子为主外,其他所有样品都表现出金属特性,主要载流子为空穴。所有样品都具有不同转变温度的磁序,HfMn6Sn6、ZrMn6Sn6 和 GdV6Sn6 具有反铁磁性,T N 分别为 541 K、466 K 和 4 K,而 GdMn6Sn6 具有铁磁性,临界温度约为 470 K。
{"title":"Single crystal growth and characterization of 166-type magnetic Kagome metals","authors":"Huangyu Wu, Jinjin Liu, Yongkai Li, Peng Zhu, Liu Yang, Fuhong Chen, Deng Hu, Zhiwei Wang","doi":"10.1088/1674-1056/ad553b","DOIUrl":"https://doi.org/10.1088/1674-1056/ad553b","url":null,"abstract":"\u0000 Kagome magnets were predicted to be a good platform to investigate correlated topology band structure, Chern quantum phase, and geometrical frustration since their unique lattice geometry. Here we reported single crystal growth of 166-type Kagome magnetic materials, including HfMn6Sn6, ZrMn6Sn6, GdMn6Sn6 and GdV6Sn6, by using flux method with Sn as a flux. Among them, HfMn6Sn6 and ZrMn6Sn6 single crystals were grown for the first time. X-ray diffraction measurements reveal that all four samples crystallized in HfFe6Ge6-type hexagonal structure with space group of P6/mmm. All samples show metallic behavior from temperature dependence of resistivity measurements, and the dominate carrier is hole, except for GdV6Sn6 which is electron dominated. All samples have magnetic order with different transition temperature, HfMn6Sn6, ZrMn6Sn6 and GdV6Sn6 are antiferromagnetic with the T\u0000 N of 541 K, 466 K and 4 K respectively, while GdMn6Sn6 is ferrimagnetic with the critical temperature about 470 K. This study will enrich the research platform of magnetic Kagome materials and help explore the novel quantum phenomenon in these interesting materials.","PeriodicalId":504421,"journal":{"name":"Chinese Physics B","volume":" 37","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141372497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-phase and out-of-phase spin pumping effects in Py/Ru/Py synthetic antiferromagnetic structures Py/Ru/Py 合成反铁磁结构中的同相和异相自旋泵效应
Pub Date : 2024-06-07 DOI: 10.1088/1674-1056/ad553d
Zhaocong Huang, Xuejian Tang, Qian Chen, Wei Jiang, Qingjie Guo, M. Jalali, Jun Du, Ya Zhai
The spin pumping effect in magnetic heterostructures and multilayers is a highly effective method for the generation and transmission of spin currents. In the increasingly prominent synthetic antiferromagnetic structures, the two ferromagnetic layers demonstrate in-phase and out-of-phase states, corresponding to acoustic and optical precession modes. Within this context, our study explores the spin pumping effect in Py/Ru/Py synthetic antiferromagnetic structures across different modes. The heightened magnetic damping resulting from the spin pumping effect in the in-phase state initially decreases with increasing Py thickness before stabilizing. Conversely, in the out-of-phase state, the amplified damping exceeds that of the in-phase state, suggesting a greater spin relaxation within this configuration, which demonstrates sensitivity to alterations in static exchange interactions. These findings contribute to advancing the application of synthetic antiferromagnetic structures in magnonic devices.
磁性异质结构和多层膜中的自旋泵效应是产生和传输自旋电流的一种非常有效的方法。在日益突出的合成反铁磁结构中,两个铁磁层呈现出同相和异相状态,对应于声学和光学前驱模式。在此背景下,我们的研究探讨了 Py/Ru/Py 合成反铁磁结构中不同模式的自旋泵效应。在同相态中,自旋泵效应导致的磁阻尼增强最初会随着 Py 厚度的增加而减弱,然后趋于稳定。相反,在离相态中,放大的阻尼超过了同相态,这表明在这种构型中存在更大的自旋弛豫,从而显示了对静态交换相互作用变化的敏感性。这些发现有助于推动合成反铁磁结构在磁性器件中的应用。
{"title":"In-phase and out-of-phase spin pumping effects in Py/Ru/Py synthetic antiferromagnetic structures","authors":"Zhaocong Huang, Xuejian Tang, Qian Chen, Wei Jiang, Qingjie Guo, M. Jalali, Jun Du, Ya Zhai","doi":"10.1088/1674-1056/ad553d","DOIUrl":"https://doi.org/10.1088/1674-1056/ad553d","url":null,"abstract":"\u0000 The spin pumping effect in magnetic heterostructures and multilayers is a highly effective method for the generation and transmission of spin currents. In the increasingly prominent synthetic antiferromagnetic structures, the two ferromagnetic layers demonstrate in-phase and out-of-phase states, corresponding to acoustic and optical precession modes. Within this context, our study explores the spin pumping effect in Py/Ru/Py synthetic antiferromagnetic structures across different modes. The heightened magnetic damping resulting from the spin pumping effect in the in-phase state initially decreases with increasing Py thickness before stabilizing. Conversely, in the out-of-phase state, the amplified damping exceeds that of the in-phase state, suggesting a greater spin relaxation within this configuration, which demonstrates sensitivity to alterations in static exchange interactions. These findings contribute to advancing the application of synthetic antiferromagnetic structures in magnonic devices.","PeriodicalId":504421,"journal":{"name":"Chinese Physics B","volume":" 80","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141374636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interfacial stress engineering toward enhancement of ferroelectricity in Al doped HfO2 thin films 掺铝 HfO2 薄膜中增强铁电性的界面应力工程
Pub Date : 2024-05-24 DOI: 10.1088/1674-1056/ad4ff4
Chen S X, Chen M M, Liu Y, Cao D W, Chen G J
Ferroelectric HfO2 have attracted much attention owing to their superior ferroelectricity at an ultra-thin thickness and good compatibilities with Si-based complementary-metal-oxide-semiconductor (CMOS) technology. However, the crystallization of polar orthorhombic phase (o-phase) HfO2 is less competitive, which greatly limits the ferroelectricity of as-obtained ferroelectric HfO2 thin films. Fortunately, the crystallization of o-phase HfO2 can be thermodynamically modulated via interfacial stress engineering. In this paper, the growth of improved ferroelectric Al doped HfO2 (HfO2:Al) thin films on (111)-oriented Si substrate have been reported. Structural analysis has suggested that non-polar monoclinic HfO2:Al grown on (111)-oriented Si substrate suffered from a strong compressive strain, which promoted the crystallization of (111)-oriented o-phase HfO2 in the as-grown HfO2:Al thin films. In addition, the in-plane lattice of (111)-oriented Si substrate matches well with that of (111)-oriented o-phase HfO2, which further thermally stabilized the o-phase HfO2. Accordingly, an improved ferroelectricity with a remnant polarization (2P r) of 26.7 μC/cm2 has been obtained. The results shown in this work provide a simple way toward the preparation of improved ferroelectric HfO2 thin films.
铁电二氧化铪以其超薄厚度和与硅基互补金属氧化物半导体(CMOS)技术的良好兼容性而备受关注。然而,极性正交相(邻相)HfO2 的结晶竞争力较弱,这大大限制了所获得的铁电 HfO2 薄膜的铁电性。幸运的是,邻相 HfO2 的结晶可以通过界面应力工程进行热力学调控。本文报道了在取向(111)硅基底上生长改进型铁电掺铝 HfO2(HfO2:Al)薄膜的情况。结构分析表明,在(111)取向硅衬底上生长的非极性单斜HfO2:Al受到了很强的压应变,这促进了(111)取向邻相HfO2在生长的HfO2:Al薄膜中结晶。此外,(111)取向硅衬底的面内晶格与(111)取向邻相 HfO2 的面内晶格非常吻合,这进一步对邻相 HfO2 起到了热稳定作用。因此,获得了更好的铁电性,残余极化(2P r)达到 26.7 μC/cm2。这项研究成果为制备更好的铁电性 HfO2 薄膜提供了一种简单的方法。
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引用次数: 0
Step-edge-guided nucleation and growth mode transition of α-Ga2O3 heteroepitaxy on vicinal sapphire 沧桑蓝宝石上α-Ga2O3异质外延的阶跃边引导成核和生长模式转变
Pub Date : 2024-05-24 DOI: 10.1088/1674-1056/ad4ff6
Jinggang Hao, Yanfang Zhang, Yijun Zhang, Ke Xu, Genquan Han, Jiandong Ye
Controlling the epitaxial growth mode of semiconductor layers is crucial for optimizing material properties and device performance. In this work, the growth mode of α-Ga2O3 heteroepitaxial layers was modulated by tuning miscut angles (θ) from 0° to 7° off the (10-10) direction of sapphire (0002) substrate. On flat sapphire surfaces, the growth undergoes a typical three-dimensional (3D) growth mode due to the random nucleation on wide substrate terraces, as evidenced by the hillock morphology and high dislocation densities. As the miscut angle increases to θ=5°, the terrace width of sapphire substrate is comparable to the distance between neighboring nuclei, and consequently, the nucleation is guided by terrace edges, which energetically facilitates the growth mode transition into the desirable two-dimensional coherent growth. Consequently, the mean surface roughness decreases to only 0.62 nm, accompanied by a significant reduction in screw and edge dislocations to 0.16×107 cm-2 and 3.58×109 cm-2, respectively. However, the further increment of miscut angles to θ=7° shrink the terrace width less than nucleation distance, and the step-bunching growth mode is dominant. In this circumstance, the misfit strain is released in the initial growth stage, resulting in surface morphology degradation and increased dislocation densities.
控制半导体层的外延生长模式对于优化材料特性和器件性能至关重要。在这项工作中,通过调整蓝宝石(0002)衬底偏离(10-10)方向 0° 至 7° 的误切角 (θ),调制了 α-Ga2O3 异质外延层的生长模式。在平坦的蓝宝石表面上,由于在宽基底台阶上的随机成核,生长经历了典型的三维(3D)生长模式,表现为丘陵形态和高位错密度。当误切角增大到 θ=5° 时,蓝宝石衬底的台阶宽度与相邻晶核之间的距离相当,因此晶核由台阶边缘引导,这在能量上促进了生长模式向理想的二维相干生长过渡。因此,平均表面粗糙度下降到只有 0.62 nm,同时螺旋位错和边缘位错也显著减少,分别为 0.16×107 cm-2 和 3.58×109 cm-2。然而,当误切角进一步增大到 θ=7° 时,台阶宽度缩小到小于成核距离,阶梯式打捆生长模式占主导地位。在这种情况下,错配应变会在生长初期释放,导致表面形貌退化和位错密度增加。
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引用次数: 0
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Chinese Physics B
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