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Development of Aqueous Organic Flow Battery Using SPEEK Membrane and Eco-Friendly Electrolytes 使用 SPEEK 膜和环保型电解质开发水有机液流电池
Pub Date : 2024-02-15 DOI: 10.55003/cast.2024.258288
Sanphop Dumkrang, Kang Li, L. Intakhuen, Konlayutt Punyawudho, S. Koonaphapdeelert
Aqueous organic redox flow batteries (AORFBs) are a type of flow battery that offers a promising solution for energy storage, and one of the main issues is selecting low-cost membranes with high ion conductivity to enhance performance and efficiency. In this study, low-cost sulfonated poly ether ether ketone (SPEEK) membranes were fabricated using the casting method, with the polymer/solvent ratios of SPEEK and N,N'-dimethylformamide (DMF) being varied. The Nafion 117 membrane was used as a benchmark for comparison. The performance of aqueous organic redox flow batteries employing anthraquinone-2-sulfonic acid (AQS) and 1,2-benzoquinone-3,5-disulfonic acid (BQDS) as electrolytes was evaluated. The SPEEK membranes were determined to have dense, homogeneous surfaces with no flaws and a thickness of 60 microns. In addition, their physicochemical properties, such as water uptake, swelling ratio, ion exchange capacity, and degree of sulfonation, were investigated. The results showed that the SPEEK membranes had better rate performance and cycle stability when compared to the Nafion117 membrane during charge-discharge cycles. Additionally, the SPEEK membranes exhibited slower potential drops and higher power density during constant current mode operation, despite showing no significant differences in energy efficiency and power density. These findings demonstrate the potential of SPEEK membranes for use in AORFBs and as a benchmark for future research and development.
水性有机氧化还原液流电池(AORFBs)是液流电池的一种,它为能量存储提供了一种前景广阔的解决方案,其中一个主要问题是选择具有高离子传导性的低成本膜,以提高性能和效率。本研究采用浇铸法制造了低成本磺化聚醚醚酮(SPEEK)膜,并改变了 SPEEK 和 N,N'-二甲基甲酰胺(DMF)的聚合物/溶剂比例。Nafion 117 膜被用作比较基准。评估了采用蒽醌-2-磺酸(AQS)和 1,2-苯醌-3,5-二磺酸(BQDS)作为电解质的水有机氧化还原液流电池的性能。经测定,SPEEK 膜表面致密、均匀、无缺陷,厚度为 60 微米。此外,还研究了它们的物理化学特性,如吸水率、膨胀率、离子交换能力和磺化程度。结果表明,与 Nafion117 膜相比,SPEEK 膜在充放电循环中具有更好的速率性能和循环稳定性。此外,尽管在能量效率和功率密度方面没有明显差异,但在恒流模式运行期间,SPEEK 膜表现出更慢的电位下降速度和更高的功率密度。这些发现证明了 SPEEK 膜在 AORFB 中的应用潜力,并可作为未来研发的基准。
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引用次数: 0
A Review of Laser-Induced Breakdown Spectroscopy (LIBS) for Document Examination: Fundamentals, Mechanism, and Application 用于文件检验的激光诱导击穿光谱法 (LIBS) 综述:基本原理、机理和应用
Pub Date : 2024-02-15 DOI: 10.55003/cast.2024.257203
Adlina Syafura Ahmad Sabri, Hamizah Md Rasid, Reena Abd Rashid, Umi Kalsum Abdul Karim, Mohamed Sazif Mohamed Subri, Mohamed Izzharif Abdul Halim
Document examination is one of the main types of investigations in forensic science, particularly in cases involving questioned documents. These documents include assorted forms of written or printed texts on different substrates (paper, banknotes, etc.) with uncertain authenticity. Ink analysis plays a vital role in document examination. It is often focused on understanding the chemical composition of the ink, which can be colorants, solvents, vehicles, and additives. Document examiners utilize several analytical tools including laser-induced breakdown spectroscopy (LIBS). The use of this instrument has gained prominence for its ability to detect multiple elements, offer straightforward sample preparation, minimize sample destruction, and provide fast and accurate readings. This paper reviews previous research that employed LIBS for document examination, highlighting its modern applications and approaches in analysing various types of documents. Furthermore, this paper discusses the strengths and weaknesses of this instrument as a viable technique in the field of document examination.
文件检验是法医学调查的主要类型之一,尤其是在涉及可疑文件的案件中。这些文件包括在不同基质(纸张、钞票等)上书写或印刷的各种形式的文本,其真实性无法确定。墨水分析在文件检验中起着至关重要的作用。它通常侧重于了解油墨的化学成分,包括着色剂、溶剂、载体和添加剂。文件检验人员使用多种分析工具,包括激光诱导击穿光谱仪 (LIBS)。这种仪器能够检测多种元素,提供直接的样品制备方法,最大限度地减少样品破坏,并提供快速、准确的读数,因此得到了广泛的使用。本文回顾了以前利用 LIBS 进行文件检测的研究,重点介绍了它在分析各类文件时的现代应用和方法。此外,本文还讨论了该仪器作为文件检验领域一种可行技术的优缺点。
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引用次数: 0
Evaluation of Growth, Chlorophyll Content, and Photosynthesis Rate of Curcuma xanthorrhiza With Different Shade Levels 不同遮荫程度下莪术生长、叶绿素含量和光合作用速率的评估
Pub Date : 2024-02-12 DOI: 10.55003/cast.2024.256871
Zelvy Amelia Murwani, I. Artika, Syaefudin, W. Nurcholis
Curcuma xanthorrhiza RoxB. is a medicinal plant found in Indonesia and is often cultivated for therapeutic purposes. Curcuma xanthorrhiza typically thrives in shaded, low-light environments. In this study, plant growth, photosynthetic rate, and chlorophyll content of C. xanthorrhiza in the same growing environment with different shade treatments were evaluated. The level of shade was adjusted using paranet at 0%, 25%, 50%, and 75%. Growth observations of C. xanthorrhiza were carried out from 1 to 6 months after planting (MAP). Chlorophyll content was measured using a UV-Vis spectrophotometer at 649 and 665 nm. The photosynthetic rate was measured using Li-Cor 6400 at 5 MAP. The results revealed that 50% shade gave the best response for plant height at 2 MAP. However, the highest number of leaves was found at 25% shade at 4 and 5 MAP. The shade level of 25% produced a significant response for C. xanthorrhiza rhizome biomass. The highest photosynthetic rate was found at 0% shade (26.69 µmol CO2 m-2s-1) and the lowest at 75% shade (15.12 µmol CO2 m-2s-1). Meanwhile, the chlorophyll content and number of tillers of C. xanthorrhiza leaves were unaffected by shade treatment. This study shows that shade treatments at 25%-50% levels gave the best growth responses in the C. xanthorrhiza plants.
莪术(Curcuma xanthorrhiza RoxB.)是印度尼西亚的一种药用植物,通常用于治疗目的。Curcuma xanthorrhiza 通常在阴暗、光照不足的环境中生长。本研究评估了同一生长环境中不同遮荫处理下莪术的植株生长、光合速率和叶绿素含量。遮荫程度用遮阳网调节为 0%、25%、50% 和 75%。种植后 1 至 6 个月期间(MAP),对 C. xanthorrhiza 的生长情况进行了观察。使用紫外可见分光光度计在 649 和 665 纳米波长下测量叶绿素含量。在 5 MAP 时,使用 Li-Cor 6400 测量光合速率。结果表明,在 2 MAP 时,50% 遮光对植株高度的响应最好。然而,在 4 和 5 MAP 时,遮光率为 25% 的叶片数量最多。25% 的遮荫度对黄柏根茎生物量有显著影响。0% 遮荫度时光合速率最高(26.69 µmol CO2 m-2s-1),75% 遮荫度时光合速率最低(15.12 µmol CO2 m-2s-1)。同时,叶绿素含量和分蘖数量不受遮荫处理的影响。这项研究表明,25%-50%的遮荫处理对黄花菜的生长反应最好。
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引用次数: 0
Extraction and Characterization of Fish Collagen for Enhanced Wound Healing Activity on A549 Cell Lines 提取鱼胶原蛋白并确定其特性以增强 A549 细胞株的伤口愈合活性
Pub Date : 2024-02-12 DOI: 10.55003/cast.2024.258572
Vimal Arasan Anbuselvan, Bliss Shiny Nelson, Bhavya Karunaharan, Sivakumar Kandhasamy
Collagen is a proteinaceous material that is present abundantly in animal tissues and gives physical strength and stability to the tissues. Collagen extracted from animal tissues has been applied in the biomedical and healthcare sectors. In recent days, aquatic organisms have shown great potential for collagen extraction and purification. In the present study, we selected three fish species: Naucrates ductor, Oreochromis mossambicus and Cyprinus carpiofor collagen extraction from both their skin and scales. The biomass was pre-treated to remove any non-collagenous matter and fat. Acid-soluble collagen was extracted using acetic acid and a maximum extraction of 51.55±1.02% was reported. The total protein fractions and the denaturation temperatures of the collagen extractswere measured. The molecular weights and the subunit compositions of the collagen extracts were analyzed using SDS-PAGE and the presence of two α chains, one β, and one γ chain. Amino acid profiling was done in an amino acid analyzer after hydrolysis and about one third of the total amino acid content was glycine. The solubility characteristics of the collagenextracts were analyzed at different ranges of pH and salinity. The antimicrobial activities of the collagen extracts were examined against four bacterial species, and it was proven that skin-derived collagens had greater antibacterial potential than extracts of the scales. In vitro studies on the wound healing capacity of the extracted collagen were performed using A549 cell line cultured in F-12K medium, and 95% of cell regeneration was observed in collagen-supplemented dispersed cell lines. 
胶原蛋白是一种蛋白质物质,大量存在于动物组织中,能增强组织的物理强度和稳定性。从动物组织中提取的胶原蛋白已被应用于生物医学和保健领域。近年来,水生生物在提取和纯化胶原蛋白方面显示出巨大的潜力。在本研究中,我们选择了三种鱼类:从它们的皮肤和鳞片中提取胶原蛋白。生物质经过预处理,以去除任何非胶原物质和脂肪。使用乙酸提取酸溶性胶原蛋白,最大提取率为 51.55±1.02%。测量了胶原提取物的总蛋白组分和变性温度。使用 SDS-PAGE 分析了胶原蛋白提取物的分子量和亚基组成,发现存在两条 α 链、一条 β 链和一条 γ 链。水解后在氨基酸分析仪中进行了氨基酸分析,结果显示氨基酸总含量中约有三分之一是甘氨酸。在不同的 pH 值和盐度范围内,对胶原蛋白提取物的溶解特性进行了分析。研究了胶原提取物对四种细菌的抗菌活性,结果证明皮肤提取的胶原比鳞片提取物具有更强的抗菌潜力。使用在 F-12K 培养基中培养的 A549 细胞系对提取的胶原蛋白的伤口愈合能力进行了体外研究,结果表明添加胶原蛋白的分散细胞系的细胞再生率达到 95%。
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引用次数: 0
Evaluation of Growth, Chlorophyll Content, and Photosynthesis Rate of Curcuma xanthorrhiza With Different Shade Levels 不同遮荫程度下莪术生长、叶绿素含量和光合作用速率的评估
Pub Date : 2024-02-12 DOI: 10.55003/cast.2024.256871
Zelvy Amelia Murwani, I. Artika, Syaefudin, W. Nurcholis
Curcuma xanthorrhiza RoxB. is a medicinal plant found in Indonesia and is often cultivated for therapeutic purposes. Curcuma xanthorrhiza typically thrives in shaded, low-light environments. In this study, plant growth, photosynthetic rate, and chlorophyll content of C. xanthorrhiza in the same growing environment with different shade treatments were evaluated. The level of shade was adjusted using paranet at 0%, 25%, 50%, and 75%. Growth observations of C. xanthorrhiza were carried out from 1 to 6 months after planting (MAP). Chlorophyll content was measured using a UV-Vis spectrophotometer at 649 and 665 nm. The photosynthetic rate was measured using Li-Cor 6400 at 5 MAP. The results revealed that 50% shade gave the best response for plant height at 2 MAP. However, the highest number of leaves was found at 25% shade at 4 and 5 MAP. The shade level of 25% produced a significant response for C. xanthorrhiza rhizome biomass. The highest photosynthetic rate was found at 0% shade (26.69 µmol CO2 m-2s-1) and the lowest at 75% shade (15.12 µmol CO2 m-2s-1). Meanwhile, the chlorophyll content and number of tillers of C. xanthorrhiza leaves were unaffected by shade treatment. This study shows that shade treatments at 25%-50% levels gave the best growth responses in the C. xanthorrhiza plants.
莪术(Curcuma xanthorrhiza RoxB.)是印度尼西亚的一种药用植物,通常用于治疗目的。Curcuma xanthorrhiza 通常在阴暗、光照不足的环境中生长。本研究评估了同一生长环境中不同遮荫处理下莪术的植株生长、光合速率和叶绿素含量。遮荫程度用遮阳网调节为 0%、25%、50% 和 75%。种植后 1 至 6 个月期间(MAP),对 C. xanthorrhiza 的生长情况进行了观察。使用紫外可见分光光度计在 649 和 665 纳米波长下测量叶绿素含量。在 5 MAP 时,使用 Li-Cor 6400 测量光合速率。结果表明,在 2 MAP 时,50% 遮光对植株高度的响应最好。然而,在 4 和 5 MAP 时,遮光率为 25% 的叶片数量最多。25% 的遮荫度对黄柏根茎生物量有显著影响。0% 遮荫度时光合速率最高(26.69 µmol CO2 m-2s-1),75% 遮荫度时光合速率最低(15.12 µmol CO2 m-2s-1)。同时,叶绿素含量和分蘖数量不受遮荫处理的影响。这项研究表明,25%-50%的遮荫处理对黄花菜的生长反应最好。
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引用次数: 0
Extraction and Characterization of Fish Collagen for Enhanced Wound Healing Activity on A549 Cell Lines 提取鱼胶原蛋白并确定其特性以增强 A549 细胞株的伤口愈合活性
Pub Date : 2024-02-12 DOI: 10.55003/cast.2024.258572
Vimal Arasan Anbuselvan, Bliss Shiny Nelson, Bhavya Karunaharan, Sivakumar Kandhasamy
Collagen is a proteinaceous material that is present abundantly in animal tissues and gives physical strength and stability to the tissues. Collagen extracted from animal tissues has been applied in the biomedical and healthcare sectors. In recent days, aquatic organisms have shown great potential for collagen extraction and purification. In the present study, we selected three fish species: Naucrates ductor, Oreochromis mossambicus and Cyprinus carpiofor collagen extraction from both their skin and scales. The biomass was pre-treated to remove any non-collagenous matter and fat. Acid-soluble collagen was extracted using acetic acid and a maximum extraction of 51.55±1.02% was reported. The total protein fractions and the denaturation temperatures of the collagen extractswere measured. The molecular weights and the subunit compositions of the collagen extracts were analyzed using SDS-PAGE and the presence of two α chains, one β, and one γ chain. Amino acid profiling was done in an amino acid analyzer after hydrolysis and about one third of the total amino acid content was glycine. The solubility characteristics of the collagenextracts were analyzed at different ranges of pH and salinity. The antimicrobial activities of the collagen extracts were examined against four bacterial species, and it was proven that skin-derived collagens had greater antibacterial potential than extracts of the scales. In vitro studies on the wound healing capacity of the extracted collagen were performed using A549 cell line cultured in F-12K medium, and 95% of cell regeneration was observed in collagen-supplemented dispersed cell lines. 
胶原蛋白是一种蛋白质物质,大量存在于动物组织中,能增强组织的物理强度和稳定性。从动物组织中提取的胶原蛋白已被应用于生物医学和保健领域。近年来,水生生物在提取和纯化胶原蛋白方面显示出巨大的潜力。在本研究中,我们选择了三种鱼类:从它们的皮肤和鳞片中提取胶原蛋白。生物质经过预处理,以去除任何非胶原物质和脂肪。使用乙酸提取酸溶性胶原蛋白,最大提取率为 51.55±1.02%。测量了胶原提取物的总蛋白组分和变性温度。使用 SDS-PAGE 分析了胶原蛋白提取物的分子量和亚基组成,发现存在两条 α 链、一条 β 链和一条 γ 链。水解后在氨基酸分析仪中进行了氨基酸分析,结果显示氨基酸总含量中约有三分之一是甘氨酸。在不同的 pH 值和盐度范围内,对胶原蛋白提取物的溶解特性进行了分析。研究了胶原提取物对四种细菌的抗菌活性,结果证明皮肤提取的胶原比鳞片提取物具有更强的抗菌潜力。使用在 F-12K 培养基中培养的 A549 细胞系对提取的胶原蛋白的伤口愈合能力进行了体外研究,结果表明添加胶原蛋白的分散细胞系的细胞再生率达到 95%。
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