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Cleaning of two mirrors in first mirror unit using radio frequency capacitively coupled plasma 利用射频电容耦合等离子体清洁第一反射镜单元中的两面反射镜
Pub Date : 2024-05-21 DOI: 10.1088/2058-6272/ad4e79
Chenxue Wang, Rong Yan, Yuming Liu, Su Xu, Lei Mu, Wei Zheng, Rui Ding, Junling Chen
The first mirror (FM) cleaning, using radio frequency plasma, has been proposed to recover the FM reflectivity in nuclear fusion reactors such as ITER. To investigate the influence of simultaneous cleaning of two mirrors on mirror cleaning efficiency and uniformity, experiments involving single-mirror cleaning and dual-mirror cleaning were conducted using radio frequency (RF) capacitively coupled plasma in the laboratory. For the test and simultaneous cleaning of two mirrors, the FM and second mirror (SM), both measuring 110 × 80 mm2, were placed inside the first mirror unit (FMU). They were composed of 16 mirror samples with a dimension of 27.5 × 20 mm2 each. These mirror samples consist of a titanium-zirconium-molybdenum (TZM) alloy substrate, a 500 nm molybdenum intermediate layer, and a 30 nm aluminum oxide (Al2O3) surface coating as a proxy for Be impurities. The cleaning of a single first mirror (SFM) and the simultaneous cleaning of FM and SM (DFM and DSM) were lasted for 9 h using argon (Ar) plasma at a pressure of 1 Pa. The total reflectivity of mirror samples on the DSM did not fully recover and varied with locations with a self-bias of −140 V. While with a self-bias of −300 V, the total reflectivity of mirror samples on SFM and DFM was fully recovered. The energy dispersive spectrometer (EDS) results demonstrated that the Al2O3 coating had been completely removed from these mirror samples. However, the mass loss of each mirror sample on SFM and DFM before and after cleaning varied depending on their locations, with higher mass loss observed for mirror samples located in the corners and lower for those in the center. Compared to the single mirror cleaning, the simultaneous cleaning of two mirrors reduced the difference of the mass loss between the highest and lowest. Furthermore, this mass loss for the mirror samples of DFM facing the DSM was increased. It indicated that the simultaneous cleaning of mirror samples face to face in the FMU could influence each other, highlighting the necessity for special attention in future studies.
有人提出利用射频等离子体进行第一面镜子(调频)清洗,以恢复热核实验堆等核聚变反应堆的调频反射率。为了研究同时清洗两面镜子对镜子清洗效率和均匀性的影响,在实验室使用射频电容耦合等离子体进行了单面镜子清洗和双面镜子清洗实验。在测试和同时清洗两面镜子时,将面积均为 110 × 80 平方毫米的调频镜和第二面镜子(SM)放置在第一面镜子单元(FMU)内。它们由 16 块镜子样品组成,每块尺寸为 27.5 × 20 平方毫米。这些镜子样品由钛-锆-钼(TZM)合金基板、500 nm 的钼中间层和 30 nm 的氧化铝(Al2O3)表面涂层(作为 Be 杂质的替代物)组成。在自偏压为 -140 V 时,DSM 上的镜面样品的总反射率没有完全恢复,并且随着位置的变化而变化;而在自偏压为 -300 V 时,SFM 和 DFM 上的镜面样品的总反射率完全恢复。能量色散光谱仪(EDS)的结果表明,这些镜子样品上的 Al2O3 涂层已被完全去除。但是,SFM 和 DFM 上每个镜面样品在清洁前后的质量损失因其位置而异,位于角落的镜面样品质量损失较大,而位于中心的镜面样品质量损失较小。与单面镜子清洗相比,同时清洗两面镜子减少了最高和最低质量损失之间的差异。此外,面向 DSM 的 DFM 镜面样品的质量损失有所增加。这表明,在调频装置中面对面同时清洁镜面样品可能会相互影响,因此在今后的研究中需要特别注意。
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引用次数: 0
Gyrokinetic simulations of the kinetic electron effects on the electrostatic instabilities on the ITER baseline scenario 对热核实验堆基线方案静电不稳定性的动电子效应的陀螺动力学模拟
Pub Date : 2024-05-21 DOI: 10.1088/2058-6272/ad4e78
Debing Zhang, Pengfei Zhao, Yingfeng Xu, Lei Ye, Xianmei Zhang
The linear and nonlinear simulations are carried out using the gyrokinetic code NLT for the electrostatic instabilities in the core region of a deuterium plasma based on the ITER baseline scenario. The kinetic electron effects on the linear frequency and nonlinear transport are studied by adopting the adiabatic electron (ae) model and the fully drift-kinetic electron (ke) model in the NLT code, respectively. The linear simulations focus on the dependence of linear frequency on the plasma parameters, such as the ion and electron temperature gradients κT i,e≡R/LTi,e , the density gradient κn≡R/Ln, and the ion-electron temperature ratio τ=Te/Ti with Te and Ti the electron and ion temperatures, respectively. Here, R is the major radius, LA=(-∂rln A)-1 denotes the gradient scale length. In the ke model, the ion temperature gradient (ITG) instability and the trapped electron mode (TEM) dominate in the small and large kθ region, respectively, where kθ is the poloidal wavenumber. The TEM-dominant region becomes wider by increasing (decreasing) κT e (κT i) or by decreasing κn. For the nominal parameters of ITER baseline scenario, the maximum growth rate of dominant ITG instability in the ke model is about 3 times larger than that in the ae model. The normalized linear frequency depends on the value of τ, instead of the value of Te or Ti in both the ae and ke models. The nonlinear simulation results show that the ion heat diffusivity in the ke model is quite larger than that in the ae model, the radial structure is finer and the time oscillation is more rapid. Besides, the magnitude of fluctuated potential at the saturated stage peaks in the ITG-dominated region, contributions from the TEM dominated in higher kθ region to the nonlinear transport can be neglected. The zonal radial electric field is found to be mainly driven by the turbulent energy flux, the contribution of turbulent poloidal Reynolds stress is quite small due to the toroidal shielding effect. The mechanism of turbulence-driven zonal radial electric field is not affected by the kinetic electron effects.
根据热核实验堆基线方案,使用陀螺动力学代码 NLT 对氘等离子体核心区域的静电不稳定性进行了线性和非线性模拟。通过在 NLT 代码中分别采用绝热电子(ae)模型和全漂移动能电子(ke)模型,研究了动能电子对线性频率和非线性传输的影响。线性模拟的重点是线性频率与等离子体参数的关系,如离子和电子温度梯度κT i,e≡R/LTi,e,密度梯度κn≡R/Ln,以及离子-电子温度比τ=Te/Ti,其中Te和Ti分别为电子和离子温度。这里,R 是主半径,LA=(-∂rln A)-1 表示梯度尺度长度。在 ke 模型中,离子温度梯度(ITG)不稳定性和受困电子模式(TEM)分别在小 kθ 和大 kθ 区域占主导地位,其中 kθ 是极波波长。随着 κT e (κT i) 的增大(减小)或 κn 的减小,TEM 主导区域会变得更宽。对于热核实验堆基线方案的标称参数,ke 模型中主导 ITG 不稳定性的最大增长率约为 ae 模型的 3 倍。在 ae 和 ke 模型中,归一化线性频率取决于 τ 值,而不是 Te 或 Ti 值。非线性模拟结果表明,ke 模型中的离子热扩散率比 ae 模型中的大,径向结构更精细,时间振荡更迅速。此外,饱和阶段的波动电势在 ITG 主导区域达到峰值,可以忽略高 kθ 区域的 TEM 主导对非线性输运的贡献。带状径向电场主要由湍流能量通量驱动,由于环形屏蔽效应,湍流极性雷诺应力的贡献很小。湍流驱动的带状径向电场机制不受电子动力学效应的影响。
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引用次数: 0
Analysis of application range of simplified models for field to thermo-field to thermionic emission processes from the cathode 分析从阴极场发射到热场发射再到热离子发射过程的简化模型的应用范围
Pub Date : 2024-05-16 DOI: 10.1088/2058-6272/ad4cad
Li Sun, Zhuo Dai, Ming Xu, Wei Wang, Zeng-Yao Li
Electrons can escape from the cathode surface by acquiring enough energy greater than the work function or weakening the potential barrier at the cathode surface through tunneling effects in gas discharges, which plays a dominant role in the plasma-cathode interactions and is a key factor in many plasma phenomena and industrial applications. It is necessary to illustrate the various electron emission mechanisms and corresponding applicable description models to evaluate the impacts on discharge properties, especially for numerical simulation studies. However, most current researches usually rely on previous experience to select the appropriate simplified formula to calculate the electron emission current density, and there is little work that can explicitly give the application range of the simplified formulas for describing electron emission. In this work, the detailed expressions of the simplified formulas valid for field emission to thermo-field emission to thermionic emission typically used in the numerical simulation are proposed, and corresponding application ranges are determined in the framework of the Murphy-Good theory, which is commonly regarded as the general model and to be accurate in the full range of conditions of validity of the theory. The dimensionless parametrization is used to evaluate the emission current density of the Murphy-Good formula and a deviation factor is defined to obtain the application ranges for different work functions (2.5~5 eV), different cathode temperatures (300~6000 K), and different emitted electric field (105 ~1010 V‧m-1). The deviation factor is shown to be a non-monotonic function of the three parameters. A comparative study of particle number densities in atmospheric gas discharge with tungsten cathode is performed based on the one-dimensional implicit particle-in-cell with the Monte Carlo Collision (PIC-MCC) method according to the above application ranges. It is found that small differences in emission current density can lead to variation in the distributions of particle number density due to the change of collisional environment. This present work can provide a theoretical basis to select emission models for the subsequent numerical simulation.
在气体放电中,电子可以通过获得大于功函数的足够能量或通过隧道效应削弱阴极表面的势垒而从阴极表面逃逸,这在等离子体与阴极的相互作用中起着主导作用,是许多等离子体现象和工业应用中的关键因素。有必要说明各种电子发射机制和相应的适用描述模型,以评估其对放电特性的影响,尤其是对数值模拟研究而言。然而,目前大多数研究通常依靠以往的经验选择合适的简化公式来计算电子发射电流密度,很少有研究能明确给出描述电子发射的简化公式的应用范围。在这项工作中,提出了数值模拟中通常使用的场发射到热场发射再到热离子发射的简化公式的详细表达式,并在墨菲-古德理论的框架内确定了相应的应用范围,该理论通常被认为是通用模型,在理论的全部有效条件范围内都是准确的。利用无量纲参数来评估 Murphy-Good 公式的发射电流密度,并定义了一个偏差因子,从而得出不同功函数(2.5~5 eV)、不同阴极温度(300~6000 K)和不同发射电场(105 ~1010 V‧m-1)下的应用范围。结果表明,偏差因子是这三个参数的非单调函数。根据上述应用范围,基于一维隐式粒子入室与蒙特卡罗碰撞(PIC-MCC)方法,对钨阴极大气气体放电中的粒子数密度进行了比较研究。研究发现,由于碰撞环境的变化,发射电流密度的微小差异会导致粒子数密度分布的变化。本研究可为后续数值模拟选择发射模型提供理论依据。
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引用次数: 0
Coated boron layers by boronization and a real-time boron coating using impurity powder dropper in LHD 硼化硼涂层和在 LHD 中使用杂质粉末滴管进行实时硼涂层
Pub Date : 2024-05-09 DOI: 10.1088/2058-6272/ad495f
Naoko Ashikawa, R. Lunsford, Federico Nespoli, E. Gilson, S. Kado, Jiansheng Hu, Yaowei Yu
In Large Helical Device (LHD), diborane (B2H6) is used as a standard boron source for boronization, which is assisted by helium glow discharges. In 2019, a new Impurity Powder Dropper (IPD) system has been installed and is under evaluation as a real-time wall conditioning technique. In LHD), which is a large size heliotron device, an additional helium (He) glow discharge cleaning (GDC) after boronization has been operated for a reduction of hydrogen recycling from coated boron layers, and this operational time of 3 h was determined by spectroscopic data during glow discharges. A flat hydrogen profile is obtained on the top surface of coated boron on the specimen exposed to boronization, the result suggests a reduction of hydrogen at the top surface by He-GDC. Trapped oxygen in coated boron was obtained by boronization, and the coated boron, which has boron-oxide, on the first wall by B-IPD was also shown. Considering the difference in coating areas between B2H6 boronization and B-IPD operation, it would be most effective to use the IPD and B2H6 boronization coating together for optimized wall conditioning.
在大型螺旋装置(LHD)中,二硼烷(B2H6)被用作硼化的标准硼源,由氦辉光放电辅助。2019 年,安装了一个新的杂质粉末滴管(IPD)系统,作为一种实时壁面调节技术正在接受评估。在大尺寸日辐射器(LHD)中,硼化后的额外氦(He)辉光放电清洗(GDC)已投入运行,以减少涂层硼层的氢回收,3 小时的运行时间是通过辉光放电期间的光谱数据确定的。在暴露于硼化的试样上,镀层硼的顶面获得了平坦的氢曲线,结果表明氦-GDC 减少了顶面的氢。通过硼化在涂层硼中获得了捕获的氧,同时还显示了通过 B-IPD 在第一壁上获得的具有氧化硼的涂层硼。考虑到 B2H6 化硼和 B-IPD 操作在涂层面积上的差异,将 IPD 和 B2H6 化硼涂层结合使用以优化壁调节将最为有效。
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引用次数: 0
Machine learning for parameters diagnosis of spark discharge by electro-acoustic signal 利用机器学习对电声信号进行火花放电参数诊断
Pub Date : 2024-05-09 DOI: 10.1088/2058-6272/ad495e
Jun Xiong, Shiyu Lu, Xiaoming Liu, Wenjun Zhou, Xiaoming Zha, Xuekai Pei
Discharge plasma parameter measurement is a key focus in low-temperature plasma research. Traditional diagnostics often require costly equipment, whereas electro-acoustic signals provide a rich, non-invasive, and less complex source of discharge information. This study harnesses machine learning to decode these signals. It establishes links between electro-acoustic signals and gas discharge parameters, such as power and distance, thus streamlining the prediction process. By building a spark discharge platform to collect electro-acoustic signals and implementing a series of acoustic signal processing techniques, the Mel-Frequency Cepstral Coefficients (MFCCs) of the acoustic signals are extracted to construct the predictors. Three machine learning models (Linear Regression, k-Nearest Neighbors, and Random Forest) are introduced and applied to the predictors to achieve real-time rapid diagnostic measurement of typical spark discharge power and discharge distance. All models display impressive performance in prediction precision and fitting abilities. Among them, the k-Nearest Neighbors model shows the best performance on discharge power prediction with the lowest mean square error (MSE=0.00571) and the highest R-squared value (R^2=0.93877). The experimental results show that the relationship between the electro-acoustic signal and the gas discharge power and distance can be effectively constructed based on the machine learning algorithm, which provides a new idea and basis for the online monitoring and real-time diagnosis of plasma parameters.
放电等离子体参数测量是低温等离子体研究的重点。传统的诊断方法通常需要昂贵的设备,而电声信号则提供了丰富、非侵入性且不太复杂的放电信息源。这项研究利用机器学习来解码这些信号。它在电声信号和气体放电参数(如功率和距离)之间建立了联系,从而简化了预测过程。通过构建火花放电平台来收集电声信号,并采用一系列声学信号处理技术,提取声学信号的梅尔-频率倒频谱系数(MFCC)来构建预测器。在预测器中引入并应用了三种机器学习模型(线性回归、k-近邻和随机森林),以实现对典型火花放电功率和放电距离的实时快速诊断测量。所有模型在预测精度和拟合能力方面都表现出色。其中,k-近邻模型在放电功率预测方面表现最佳,均方误差(MSE=0.00571)最小,R 平方值(R^2=0.93877)最高。实验结果表明,基于机器学习算法可以有效构建电声信号与气体放电功率和距离之间的关系,为等离子体参数的在线监测和实时诊断提供了新的思路和依据。
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引用次数: 0
Effect of toroidal mode coupling on explosive dynamics of m/n=3/1 double tearing mode 环模耦合对 m/n=3/1 双撕裂模式爆炸动力学的影响
Pub Date : 2024-05-08 DOI: 10.1088/2058-6272/ad48cf
Xingqiang Lu, Ge Gao, Zhiwei Ma, Wei Guo, X. Li
The CLT code is used to quantitatively study the impact of toroidal mode coupling on the explosive dynamics of m/n = 3/1 double tearing mode. This work focuses on the explosive reconnection processes in which energy bursts and the main mode no longer dominates when the separation between two rational surfaces is relatively large in the medium range. The development of higher m and n modes is facilitated by a relatively large separation between two rational surfaces, a small qmin (the minimum value of safety factor), or a low resistivity. The relationships between the higher m and n modes development, explosive reconnection rate and the position exchange of 3/1 islands are summarized for the first time. The separation plays a more important role than qmin on enhancing the development of higher m and n modes. At a relatively large separation, the well development of higher m and n modes greatly reduces the reconnection rate, and suppresses the development of the main mode, resulting in the main mode not being able to develop sufficiently large to generate the position changes of 3/1 islands.
CLT 代码用于定量研究环模耦合对 m/n = 3/1 双撕裂模式爆炸动力学的影响。这项工作的重点是爆炸性再连接过程,在这个过程中,当两个有理面之间的距离在中等范围内相对较大时,能量爆发,主模式不再占主导地位。两个有理面之间相对较大的间隔、较小的 qmin(安全系数的最小值)或较低的电阻率,都有利于较高 m 和 n 模式的发展。本文首次总结了高m模和高n模的发展、爆炸重联率和3/1岛位置交换之间的关系。在促进高m模和n模的发展方面,分离度比qmin起着更重要的作用。在相对较大的分离度下,高m模和高n模的良好发展会大大降低重联率,并抑制主模的发展,导致主模无法发展到足够大的程度以产生3/1岛的位置变化。
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引用次数: 0
Particle-in-cell simulations of EUV-induced hydrogen plasma in the vicinity of a reflective mirror 反射镜附近超紫外诱导氢等离子体的粒子间模拟
Pub Date : 2024-05-08 DOI: 10.1088/2058-6272/ad48d0
Yuqiang Zhang, Xingang Yu, Zongbiao Ye
Particle-In-Cell (PIC) simulations were performed in this work to study the dynamics of the EUV induced hydrogen plasma. Monte-Carlo Collision (MCC) model was employed to deal with the collisions between charged particles and background gas molecules. The dynamic evolution of the plasma sheath, as well as the flux and energy distribution of ions impact on the mirror surface, was discussed. It was found that the emission of secondary electrons under the EUV irradiation on the ruthenium coating of mirrors creates a positively charged wall and then prevents the ion from impacting onto the mirror and therefore changes the flux and energy distribution of ions reach the mirror. Furthermore, gas pressure has notable effect on the plasma sheath and the characteristics of the ions impinging on the mirrors. With greater gas pressure, the sheath potential decreases more rapidly. The flux of ions received by the mirror grows approximately linearly and the energy corresponding to the peak flux decreases slightly in the meantime. Meanwhile, EUV source intensity barely changes the sheath potential and its influence on the ion impact is mainly limited to the approximate linear increase of ion flux.
在这项工作中,我们进行了 "粒子池内"(PIC)模拟,以研究超紫外诱导氢等离子体的动力学。蒙地卡罗碰撞(MCC)模型用于处理带电粒子与背景气体分子之间的碰撞。讨论了等离子体鞘的动态演化以及离子撞击镜面的通量和能量分布。研究发现,在超紫外辐照下,二次电子在反射镜的钌涂层上发射,形成带正电的壁,从而阻止离子撞击反射镜,因此改变了离子到达反射镜的通量和能量分布。此外,气体压力对等离子鞘和离子撞击反射镜的特性也有显著影响。气体压力越大,鞘电位下降得越快。反射镜接收到的离子通量近似线性增长,而与峰值通量相对应的能量则略有下降。同时,EUV 源强度几乎不会改变鞘势,其对离子撞击的影响主要局限于离子通量的近似线性增长。
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引用次数: 0
A first spectroscopic study of HFRC plasma 高频等离子体的首次光谱研究
Pub Date : 2024-05-06 DOI: 10.1088/2058-6272/ad47df
An Mao, Zhifeng Cheng, Bo Rao, Jingmin Yang, Ming Zhang
An advanced spectral diagnostic system has been developed to measure the electron temperature (Te), elec-tron density (Ne), and ion temperature (Ti) for the Huazhong University of Science and Technology (HUST) field-reversed configuration (HFRC) plasma. The system consists of an optic fiber spectrometer with a wide spectral band and a 670 mm focal length high throughout Czerny-Turner (C-T) monochromator equipped with both a 3600 g/ mm−1 grating and a 2400 g /mm−1 grating to achieve the measurement of line spectrum. Accompanying these components is an Electron-Multiplying Charge-coupled Device (EMCCD) camera to capture the spectral data. The relative intensity of the optical fiber spectrometer has been calibrated using a standard luminance source, and the spectrometer’'s wavelength calibration has been accomplished by a mercury argon lamp. This diagnostic setup has been configured to measure the electron density based on the Stark effect of Hγ (n = 5 → n = 2, 434.04 nm). Doppler broadening of an O III (2s22p(2P°)3p → 2s22p(2P°)3s, 375.988 nm) emission line is measured and analyszed to obtain the ion temperature, electron temperatures can be estimated from the relative strength of Hβ (n = 4 → n = 2, 486.14 nm) (Dβ) and Hγ (Dγ) spectral lines when the electron density is obtained from Stark effect measurements. Initial experimental results indicate that the highest electron temperature of the formation region is around 8 eV; the electron density of the col-liding-and-merging region is approaching 1020 m−-3 and the ion temperature reaches about 40 eV.
为测量华中科技大学(HUST)场反转配置(HFRC)等离子体的电子温度(Te)、电子-电子密度(Ne)和离子温度(Ti),我们开发了一套先进的光谱诊断系统。该系统由一个宽光谱带光纤光谱仪和一个焦距为 670 毫米的高贯穿蔡尼-特纳(C-T)单色仪组成,蔡尼-特纳单色仪配备了 3600 克/毫米-1 光栅和 2400 克/毫米-1 光栅,以实现线光谱测量。与这些组件配套的是一台电子多重电荷耦合器件(EMCCD)照相机,用于捕捉光谱数据。光纤光谱仪的相对强度使用标准光源进行校准,光谱仪的波长校准则由汞氩灯完成。该诊断装置的配置是为了测量基于 Hγ 的斯塔克效应的电子密度(n = 5 → n = 2,434.04 nm)。测量并分析了 O III (2s22p(2P°)3p → 2s22p(2P°)3s, 375.988 nm) 发射线的多普勒展宽,以获得离子温度,当通过斯塔克效应测量获得电子密度时,可根据 Hβ (n = 4 → n = 2, 486.14 nm) (Dβ) 和 Hγ (Dγ) 光谱线的相对强度估算电子温度。初步的实验结果表明,形成区的最高电子温度约为 8 eV;结盖合并区的电子密度接近 1020 m--3,离子温度达到约 40 eV。
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引用次数: 0
Efficient activation of Co/SBA-15 catalyst by high-frequency AC-DBD plasma thermal effect for toluene removal 利用高频 AC-DBD 等离子体热效应高效活化 Co/SBA-15 催化剂以去除甲苯
Pub Date : 2024-05-06 DOI: 10.1088/2058-6272/ad47db
Yue Li, Nan Jiang, Zhengyan Liu, Liang Qin, Bangfa Peng, Ronggang Wang, Yurong Sun, Jie Li
Dielectric barrier discharge (DBD) plasma excited by high-frequency alternating-current (AC) power supply is widely employed for the degradation of volatile organic compounds (VOCs). However, the thermal effect generated during the discharge process leads to energy waste and low energy utilization efficiency. In this work, an innovative DBD thermal-conducted catalysis (DBD-TCC) system, integrating high-frequency AC-DBD plasma and its generated thermal effect to activate the Co/SBA-15 catalyst, was employed for toluene removal. Specifically, Co/SBA-15 catalysts are closely positioned to the ground electrode of the plasma zone and can be heated and activated by the thermal effect when the voltage exceeds 10 kV. At 12.4 kV, the temperature in the catalyst zone could reach 261 °C in the DBD-TCC system, resulting in an increase in toluene degradation efficiency of 17%, CO2 selectivity of 21.2%, and energy efficiency of 27%, respectively, compared to the DBD system alone. In contrast, the DBD thermal-unconducted catalysis (DBD-TUC) system fails to enhance toluene degradation due to insufficient heat absorption and catalytic activation, highlighting the crucial role of AC-DBD generated heat in activating the catalyst. Furthermore, the degradation pathway and mechanism of toluene in the DBD-TCC system were hypothesized. This work is expected to provide an energy-efficiency approach for high-frequency AC-DBD plasma removal of VOCs.
高频交流电源激发的介质阻挡放电(DBD)等离子体被广泛用于降解挥发性有机化合物(VOC)。然而,放电过程中产生的热效应会导致能源浪费和能源利用效率低下。在这项工作中,采用了一种创新的 DBD 热导催化(DBD-TCC)系统来去除甲苯,该系统集成了高频交流-DBD 等离子体及其产生的热效应来激活 Co/SBA-15 催化剂。具体来说,Co/SBA-15 催化剂紧贴等离子体区的接地电极,当电压超过 10 kV 时,催化剂可被加热并通过热效应激活。在 12.4 千伏电压下,DBD-TCC 系统中催化剂区的温度可达 261 ℃,与单独的 DBD 系统相比,甲苯降解效率提高了 17%,二氧化碳选择性提高了 21.2%,能效提高了 27%。相比之下,DBD 热不导催化(DBD-TUC)系统由于吸热和催化活化不足,未能提高甲苯降解效率,这凸显了 AC-DBD 产生的热量在活化催化剂方面的关键作用。此外,还假设了 DBD-TCC 系统中甲苯的降解途径和机制。这项研究有望为高频 AC-DBD 等离子体去除挥发性有机化合物提供一种节能方法。
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引用次数: 0
The effects of inner electrode shape on the performance of dielectric barrier discharge reactor for oxidative removal of NO and SO2 内电极形状对氧化去除 NO 和 SO2 的介质阻挡放电反应器性能的影响
Pub Date : 2024-04-12 DOI: 10.1088/2058-6272/ad3e47
Yunkai Cai, Bingfeng Huang, Fei Dong, Neng Zhu
Seagoing vessels are responsible for more than 90% of global freight traffic, but meanwhile, emission pollutants (NOx and SOx) of seagoing vessels also cause serious air pollution. Nonthermal plasma (NTP) combined with wet scrubbing technology is considered to be a promising technology. In order to improve the oxidation efficiency and energy efficiency of the NTP reactor, the screw and rod inner electrodes of dielectric barrier discharge (DBD) reactor were investigated. To analyze the mechanism, the optical emission spectra (OES) of NTP was measured and numerical calculation was applied. The experiment results show that the NO oxidation removal efficiency of screw electrode is lower than that of rod electrode. However, the SO2 removal efficiency of screw electrode is higher. According to the OES experiment and numerical calculation, the electric field intensity of the screw electrode surface is much higher than that of the rod electrode surface, and it is easier to generate N radicals to form NO. For the same energy density condition, the OH radical generation efficiency of the screw electrode reactor is similar to that of the rod electrode, but the gas temperature in the discharge gap is higher. Therefore, the SO2 oxidation efficiency of the thread electrode is higher. This study provides guidance for the optimization of oxidation efficiency and energy consumption of DBD reactor.
海轮承担着全球 90% 以上的货运量,但与此同时,海轮排放的污染物(氮氧化物和硫氧化物)也造成了严重的空气污染。非热等离子体(NTP)与湿式洗涤技术相结合被认为是一种前景广阔的技术。为了提高 NTP 反应器的氧化效率和能效,研究人员对介质阻挡放电(DBD)反应器的螺杆和杆内电极进行了研究。为分析其机理,测量了 NTP 的光发射光谱(OES)并进行了数值计算。实验结果表明,螺旋电极的 NO 氧化去除效率低于棒状电极。然而,螺旋电极对二氧化硫的去除效率较高。根据 OES 实验和数值计算,螺旋电极表面的电场强度远高于棒状电极表面,更容易产生 N 自由基生成 NO。在相同能量密度条件下,螺旋电极反应器的 OH 自由基生成效率与棒状电极相似,但放电间隙中的气体温度更高。因此,螺纹电极的 SO2 氧化效率更高。这项研究为优化 DBD 反应器的氧化效率和能耗提供了指导。
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Plasma Science and Technology
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