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Simulating induction heating of fabric based thermoplastic composites using measured electrical conductivities 利用测得的电导率模拟织物基热塑性复合材料的感应加热
Pub Date : 2024-06-04 DOI: 10.1177/08927057241255886
Sebastiaan van den Berg, M. Luckabauer, Sebastiaan Wijskamp, R. Akkerman
A novel method for defining the measured electrical conductivity of CFRTP in induction heating simulations is presented. This method considers the electrical conductivity’s orientation dependence and accurately predicts electromagnetic and transient temperature fields. The study demonstrates that temperature predictions using the present electrical conductivity model are in good agreement with the experiments, and that it yields improved transient temperature field predictions compared to the other electrical conductivity models.
本文介绍了一种在感应加热模拟中定义 CFRTP 测量电导率的新方法。该方法考虑了电导率的方向依赖性,并能准确预测电磁场和瞬态温度场。研究表明,使用本导电率模型进行的温度预测与实验结果十分吻合,而且与其他导电率模型相比,本模型能更好地预测瞬态温度场。
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引用次数: 0
Driving towards sustainability: A review of natural fiber reinforced polymer composites for eco-friendly automotive light-weighting 推动可持续发展:用于环保型汽车轻量化的天然纤维增强聚合物复合材料综述
Pub Date : 2024-05-17 DOI: 10.1177/08927057241254324
Sifiso John Skosana, Caroline Khoathane, Thomas Malwela
The automotive industry stands at a critical juncture, compelled by the imperative of sustainability to seek innovative materials for eco-friendly light-weighting. Natural fiber reinforced polymer composites (NFRPCs) have gained popularity due to their environmentally friendly nature and excellent engineering capabilities. This review paper comprehensively examines the landscape of NFRPCs in the context of automotive applications. Beginning with an overview of the ecological urgency and regulatory framework driving sustainable automotive materials, the review navigates through key advancements in NFRPC technology. The paper delineates the diverse array of natural fibers employed as reinforcements, elucidating their intrinsic properties, sources, and processing considerations. Concurrently, an in-depth analysis of various polymer matrices showcases their compatibility with different fiber types, emphasizing the critical interplay between fiber and matrix for optimal composite performance. A pivotal facet of this review manuscript lies in the rigorous evaluation of NFRPC performance across an array of metrics, including mechanical, thermal, and environmental considerations. Studies examining the interfacial interactions between natural fibers and polymers, as well as enhancements through additives and treatments, are critically assessed. Environmental and economic considerations are paramount in the quest for sustainable automotive materials. While economic evaluations delve into the viability and cost-effectiveness of widespread adoption, life cycle assessments and environmental impact analyses are evaluated to estimate the ecological footprint of NFRPCs. The paper also surveys current trends and prospects, offering insights into forthcoming innovations and directions for research. Therefore, this review article consolidates a comprehensive body of knowledge on NFRPCs for eco-friendly automotive light-weighting. By synthesizing findings from diverse studies, it provides a holistic perspective on the potential, challenges, and future trajectory of NFRPCs in the automotive sector.
汽车行业正处于一个关键时刻,在可持续发展的要求下,必须寻求创新材料来实现环保轻量化。天然纤维增强聚合物复合材料(NFRPC)因其环保特性和卓越的工程能力而广受欢迎。本综述文件全面探讨了天然纤维增强聚合物复合材料在汽车应用中的前景。论文首先概述了推动可持续汽车材料发展的生态紧迫性和监管框架,然后介绍了 NFRPC 技术的主要进展。论文描述了用作增强材料的各种天然纤维,阐明了它们的内在特性、来源和加工注意事项。同时,还深入分析了各种聚合物基体,展示了它们与不同纤维类型的兼容性,强调了纤维与基体之间的重要相互作用,以实现最佳的复合材料性能。本综述手稿的一个重要方面是对 NFRPC 性能的一系列指标进行了严格评估,包括机械、热和环境因素。对天然纤维和聚合物之间的界面相互作用以及通过添加剂和处理方法增强性能的研究进行了严格评估。在寻求可持续汽车材料的过程中,环境和经济因素至关重要。经济评估深入探讨了广泛采用的可行性和成本效益,同时还对生命周期评估和环境影响分析进行了评估,以估算 NFRPC 的生态足迹。本文还调查了当前的趋势和前景,为即将到来的创新和研究方向提供了见解。因此,这篇综述文章整合了有关用于生态友好型汽车轻量化的 NFRPC 的全面知识。通过综合不同研究的结果,本文从整体角度阐述了非阻燃剂在汽车领域的潜力、挑战和未来发展轨迹。
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引用次数: 0
Physicochemical and antimicrobial characteristics of polypropylene-based nanocomposite containing SiO2-Ag nanoparticles prepared by gamma irradiation 伽马辐照法制备的含 SiO2-Ag 纳米粒子的聚丙烯基纳米复合材料的理化和抗菌特性
Pub Date : 2024-05-15 DOI: 10.1177/08927057241255013
E. Fathy, Sobhy S. Abdel-Fatah, M. Bekhit
This article evaluates the physicochemical and antimicrobial properties when silver-coated silica (SiO2-Ag) nanoparticles as active nanofiller are incorporated into the polypropylene (PP) thermoplastic matrix. The silica (SiO2) nanoparticles were prepared by precipitation method using sodium silicate. After that, silver-coated silica (SiO2-Ag) nanoparticles were synthesized by gamma radiation technique. X-ray diffraction (XRD), Infrared spectroscopy analysis (FTIR) and Transmission electron microscopy (TEM) analysis clarified the formation of SiO2-Ag nanoparticles. SiO2-Ag nanoparticles has a particle size with an average of 70 nm. The melt mixing procedure operated to fabricate PP thermoplastic nanocomposites with various ratios of 1.0, 2.0, and 3.0 part per hundred resin (phr) of the SiO2-Ag nanoparticles. To examine the effect of ionizing radiation on the prepared PP/SiO2-Ag nanocomposites, the samples were exposed to 20 kGy of gamma-irradiation. FTIR, XRD, mechanical analysis, thermogravimetric analysis (TGA), and scanning electron microscope (SEM) were utilized to characterize the physico-chemical alterations of the PP when loaded with SiO2-Ag nanoparticles. It is found that PP/1.0 phr SiO2-Ag nanocomposite revealed superior physico-chemical characteristics than the other two components. The irradiated specimens revealed superior tensile strength (TS) and elastic modulus (EM) over unirradiated ones, whereas inverse effects were predominant in case elongation at break (E%). Tmax of the native PP increased from 335°C to nearly 370°C of PP/1.0 phr SiO2-Ag nanocomposite. It is established that the fabricated PP/SiO2-Ag nanocomposites exhibited potent antimicrobial activity and can be a good candidate for food packaging applications.
本文评估了在聚丙烯(PP)热塑性基体中加入银涂层二氧化硅(SiO2-Ag)纳米粒子作为活性纳米填料时的物理化学和抗菌性能。纳米二氧化硅(SiO2)颗粒是用硅酸钠沉淀法制备的。然后,利用伽马射线辐射技术合成了银涂层二氧化硅(SiO2-Ag)纳米粒子。X 射线衍射(XRD)、红外光谱分析(FTIR)和透射电子显微镜(TEM)分析明确了 SiO2-Ag 纳米粒子的形成。SiO2-Ag 纳米粒子的平均粒径为 70 纳米。在熔融混合过程中,SiO2-Ag 纳米粒子与 PP 热塑性纳米复合材料的比例分别为 1.0、2.0 和 3.0。为了研究电离辐射对制备的 PP/SiO2-Ag 纳米复合材料的影响,对样品进行了 20 kGy 的伽马辐照。利用傅立叶变换红外光谱(FTIR)、X射线衍射(XRD)、机械分析、热重分析(TGA)和扫描电子显微镜(SEM)来表征聚丙烯负载二氧化硅-银纳米粒子后的物理化学变化。结果发现,PP/1.0 phr SiO2-Ag 纳米复合材料的物理化学特性优于其他两种成分。辐照试样的拉伸强度(TS)和弹性模量(EM)优于未辐照试样,而在断裂伸长率(E%)方面,反向效应占主导地位。原生 PP 的最高温度从 335°C 上升到 PP/1.0 phr SiO2-Ag 纳米复合材料的 370°C。由此可见,所制备的 PP/SiO2-Ag 纳米复合材料具有很强的抗菌活性,是食品包装应用的理想材料。
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引用次数: 0
Influence of surface treatments and addition of a reactive agent on the properties of PLA/flax and PLA/bamboo composites 表面处理和添加反应剂对聚乳酸/亚麻和聚乳酸/竹复合材料性能的影响
Pub Date : 2024-02-14 DOI: 10.1177/08927057241231733
Hervé Nlandu-Mayamba, A. Taguet, Didier Perrin, Sébastien Joannès, Florence Delor-Jestin, H. Askanian, J. Lopez‐Cuesta
Polylactic acid (PLA) composites reinforced with 10 wt% of flax (FF) or bamboo (BF) fibers were prepared via an internal mixer and/or twin-screw extrusion. Alkali pretreated fibers were soaked in silane to improve adhesion between fibers and matrix. 0.8 wt% of Joncryl™, a grafted copolymer acting as PLA chain extender, was also used alone or in combination with silane treatment of fibers to improve interfacial adhesion. The influence of silane treatment and/or Joncryl on the composite materials on mechanical, thermal and thermomechanical properties of materials processed through injection molding was investigated. Improved adhesion of the fibers to the matrix was shown using a scanning electron microscope. Fourier Transform Infrared Spectroscopy indicated that chemical bonds were formed between the silane coupling agent and fibers. X-ray Photo-electron Spectroscopy confirmed that fibers and silane derivatives were effectively coupled. XPS also highlighted that silane coupling agent reacted in higher amounts on bamboo than flax fibers, probably due to a higher amount of lignin in the case of bamboo fibers. Thermogravimetric analyses indicated that silane-treated flax and bamboo increased the thermal stability of the corresponding composites (PLA-SFF and PLA-SFB) compared to non-treated fiber composites. The incorporation of Joncryl alone entailed a degradation of the thermal stability of the corresponding composites (PLAJ-FF and PLAJ-FB) but enhanced the PLA/fibers interfacial adhesion. The combination of Joncryl and silane treatment resulted in strong improvements of thermal stability and interfacial adhesion for the PLAJ-SFF and PLAJ-SBF composites. Increase in tensile moduli and decrease in tensile strengths with the incorporation of the pristine fibers were noted. For silane-treated fibers, the tensile modulus and the strength of the corresponding composites were improved when adding Joncryl alone or in combination with silane. From also rheological and molar weight measurements, it could be concluded that Joncryl acts both as PLA chain extender and coupling agent.
通过内部混合器和/或双螺杆挤压法制备了用 10 wt% 的亚麻(FF)或竹(BF)纤维增强的聚乳酸(PLA)复合材料。碱预处理纤维浸泡在硅烷中,以提高纤维与基体之间的粘附性。还单独使用或结合硅烷处理纤维使用 0.8 wt% 的接枝共聚物 Joncryl™(聚乳酸链延伸剂)来改善界面粘附性。研究了硅烷处理和/或 Joncryl 对通过注塑成型加工的复合材料的机械、热和热机械性能的影响。扫描电子显微镜显示纤维与基体的粘附性得到了改善。傅立叶变换红外光谱显示,硅烷偶联剂与纤维之间形成了化学键。X 射线光电子能谱证实,纤维和硅烷衍生物已有效耦合。X 射线光电子能谱还显示,硅烷偶联剂在竹纤维上的反应量高于亚麻纤维,这可能是由于竹纤维中的木质素含量较高。热重分析表明,与未经处理的纤维复合材料相比,经过硅烷处理的亚麻和竹纤维提高了相应复合材料(聚乳酸-SFF 和聚乳酸-SFB)的热稳定性。单独加入 Joncryl 会降低相应复合材料(PLAJ-FF 和 PLAJ-FB)的热稳定性,但会增强聚乳酸/纤维的界面粘附性。结合使用 Joncryl 和硅烷处理可显著提高 PLAJ-SFF 和 PLAJ-SBF 复合材料的热稳定性和界面粘附性。加入原始纤维后,拉伸模量增加,拉伸强度降低。对于硅烷处理过的纤维,单独添加或与硅烷一起添加 Joncryl 时,相应复合材料的拉伸模量和强度都有所提高。从流变学和摩尔重量测量结果也可以得出结论,Joncryl 既是聚乳酸的扩链剂,也是偶联剂。
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引用次数: 0
Biodegradable starch-polyvinyl alcohol composite films by the incorporation of lignin for packaging applications 通过加入木质素实现可生物降解的淀粉-聚乙烯醇复合薄膜在包装中的应用
Pub Date : 2024-02-14 DOI: 10.1177/08927057241233566
Shihui Wang, Yanling Hao, Qixiang He, Qiqi Gao
In this work, firstly, the optimal performance ratio of potato starch and polyvinyl alcohol (PVA) was selected, and then the sustainable high-grade food packaging film was developed by adding different amounts (0, 5, 10, 15, 20, and 25 wt% based on the starch mass) of functional additive lignin into the starch - PVA film matrix. Starch - PVA based films with different amounts of lignin were studied from the aspects of morphology, physical and chemical properties, barrier properties, mechanical properties and antioxidant properties. Mechanical tests showed that lignin significantly improved the tensile strength (TS) of the film and effectively blocked the passage of water vapor. Lignin, starch and PVA were linked by hydrogen bond to form polymer network structure, which improved the interfacial compatibility between polymers. The interaction between polymer molecules and the distribution of lignin particles were confirmed by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The high content of phenolic hydroxyl in lignin undergoes proton coupled electron transfer mechanism, which endows the composite film with high antioxidant activity, which is proved by DPPH radical scavenging activity experiment. At the same time, it also gives the film excellent UV barrier and antibacterial properties. The introduction of lignin in this study provides a valuable way for the preparation of multifunctional composite films using biomass as raw materials, and has a potential application prospect in food packaging.
本研究首先选择了马铃薯淀粉和聚乙烯醇(PVA)的最佳性能配比,然后通过在淀粉-PVA 薄膜基体中添加不同量(0、5、10、15、20 和 25 wt%,基于淀粉质量)的功能添加剂木质素,开发了可持续的高档食品包装薄膜。研究人员从形态、物理和化学特性、阻隔特性、机械特性和抗氧化特性等方面对添加了不同量木质素的淀粉-PVA 薄膜进行了研究。机械测试表明,木质素大大提高了薄膜的拉伸强度(TS),并有效阻止了水蒸气的通过。木质素、淀粉和 PVA 通过氢键连接形成聚合物网络结构,改善了聚合物之间的界面相容性。傅立叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)证实了聚合物分子之间的相互作用和木质素颗粒的分布。木质素中高浓度的酚羟基发生质子耦合电子转移机制,使复合薄膜具有很高的抗氧化活性,DPPH 自由基清除活性实验证明了这一点。同时,它还赋予了薄膜优异的紫外线阻隔性和抗菌性。本研究中木质素的引入为以生物质为原料制备多功能复合薄膜提供了一条重要途径,在食品包装领域具有潜在的应用前景。
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引用次数: 0
Biodegradable starch-polyvinyl alcohol composite films by the incorporation of lignin for packaging applications 通过加入木质素实现可生物降解的淀粉-聚乙烯醇复合薄膜在包装中的应用
Pub Date : 2024-02-14 DOI: 10.1177/08927057241233566
Shihui Wang, Yanling Hao, Qixiang He, Qiqi Gao
In this work, firstly, the optimal performance ratio of potato starch and polyvinyl alcohol (PVA) was selected, and then the sustainable high-grade food packaging film was developed by adding different amounts (0, 5, 10, 15, 20, and 25 wt% based on the starch mass) of functional additive lignin into the starch - PVA film matrix. Starch - PVA based films with different amounts of lignin were studied from the aspects of morphology, physical and chemical properties, barrier properties, mechanical properties and antioxidant properties. Mechanical tests showed that lignin significantly improved the tensile strength (TS) of the film and effectively blocked the passage of water vapor. Lignin, starch and PVA were linked by hydrogen bond to form polymer network structure, which improved the interfacial compatibility between polymers. The interaction between polymer molecules and the distribution of lignin particles were confirmed by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The high content of phenolic hydroxyl in lignin undergoes proton coupled electron transfer mechanism, which endows the composite film with high antioxidant activity, which is proved by DPPH radical scavenging activity experiment. At the same time, it also gives the film excellent UV barrier and antibacterial properties. The introduction of lignin in this study provides a valuable way for the preparation of multifunctional composite films using biomass as raw materials, and has a potential application prospect in food packaging.
本研究首先选择了马铃薯淀粉和聚乙烯醇(PVA)的最佳性能配比,然后通过在淀粉-PVA 薄膜基体中添加不同量(0、5、10、15、20 和 25 wt%,基于淀粉质量)的功能添加剂木质素,开发了可持续的高档食品包装薄膜。研究人员从形态、物理和化学特性、阻隔特性、机械特性和抗氧化特性等方面对添加了不同量木质素的淀粉-PVA 薄膜进行了研究。机械测试表明,木质素大大提高了薄膜的拉伸强度(TS),并有效阻止了水蒸气的通过。木质素、淀粉和 PVA 通过氢键连接形成聚合物网络结构,改善了聚合物之间的界面相容性。傅立叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)证实了聚合物分子之间的相互作用和木质素颗粒的分布。木质素中高浓度的酚羟基发生质子耦合电子转移机制,使复合薄膜具有很高的抗氧化活性,DPPH 自由基清除活性实验证明了这一点。同时,它还赋予了薄膜优异的紫外线阻隔性和抗菌性。本研究中木质素的引入为以生物质为原料制备多功能复合薄膜提供了一条重要途径,在食品包装领域具有潜在的应用前景。
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引用次数: 0
Nanocomposites of thermoplastic matrices with non-covalent fullerene reinforcement—Structural diversity, physical impact and potential 热塑性基质与非共价富勒烯增强材料的纳米复合材料--结构多样性、物理影响和潜力
Pub Date : 2024-02-12 DOI: 10.1177/08927057241233568
Ayesha Kausar, Ishaq Ahmad
Fullerene has been acknowledged as a significant nanocarbon nanofiller enhancing the imperative polymer characteristics. Since, thermoplastic polymers constitute a large group of polymeric materials, fullerene has been used as reinforcement in these matrices mostly via non-covalent means. This state-of-the-art review article summarizes thermoplastic polymer nanocomposites reinforced with fullerene nano-additives without involving any covalent interactions. Accordingly, thermoplastic polymer/fullerene nanocomposites of interest have non-covalent or physical interactions in the matrix-nanofiller such as van der Waals forces, electrostatic interactions, hydrogen bonding, and aromatic stacking interactions. Number of thermoplastic polymers including polyamide, polyurethanes, and block copolymers have been non-covalently or physically reinforced with the fullerene molecules. Ensuing high performance thermoplastic polymer/fullerene nanocomposites exhibited improved microstructure, electrical, mechanical, thermal, and other physical properties. Enhancements in the thermal, mechanical, and electrical properties of the thermoplastic/fullerene nanomaterials were found dependent upon the nanofiller contents, orientations, interfacial effects, and processing. Consequently, the polyamide/fullerene systems were found efficient to enhance the glass transition up to 260°C, in addition to optimum mechanical properties. Polyurethane/fullerene systems performed better for improved tensile strength and young’s modulus features up to 90 MPa and 48 GPa, respectively. System based on poly (methyl methacrylate) and fullerene has resulted in high thermal degradation temperature in the range of 501-633°C with fine electrical conductivity of 1.3 Scm−1. Using combination of fullerene and graphene nanofiller (due to synergistic effects) has been found to improve the electrical conductivity considerably in the range of 1.8–2.5 Scm−1 for a polystyrene and block copolymer system. However, attaining fine fullerene nanoparticle dispersion of non-covalently reinforced matrices have been found important affecting the final nanocomposite properties. Consequently, processability and essential characteristics of non-covalently fullerene filled nanocomposites can be influenced due to nanoparticle aggregation. Hence, the physical property enhancement potential of physical linking between the non-covalently linked thermoplastics-fullerene has been portrayed in this article. Research on non-covalently interacted thermoplastic polymer/fullerene nanocomposites revealed technical potential ranging from energy/electronic devices to engineering and biomedical sectors. This review article can be a useful guide for the field researchers towards the development of advanced systems using non-covalently linked polymer/fullerene nanomaterials for future technical applications.
富勒烯已被公认为一种重要的纳米碳纳米填料,可增强聚合物的必要特性。热塑性聚合物是一大类聚合物材料,富勒烯主要通过非共价方式用作这些基质的增强剂。这篇最新综述文章总结了富勒烯纳米添加剂在不涉及任何共价作用的情况下增强热塑性聚合物纳米复合材料的情况。因此,相关的热塑性聚合物/富勒烯纳米复合材料在基体-纳米填料中具有非共价或物理相互作用,如范德华力、静电作用、氢键和芳香堆积相互作用。包括聚酰胺、聚氨酯和嵌段共聚物在内的许多热塑性聚合物都与富勒烯分子进行了非共价或物理增强。随之而来的高性能热塑性聚合物/富勒烯纳米复合材料显示出更好的微观结构、电气、机械、热和其他物理性能。热塑性塑料/富勒烯纳米材料的热性能、机械性能和电性能的提高取决于纳米填料的含量、取向、界面效应和加工过程。因此,聚酰胺/富勒烯系统除了具有最佳的机械性能外,还能有效提高玻璃化转变温度,最高可达 260°C。聚氨酯/富勒烯体系在提高拉伸强度和杨氏模量方面表现更佳,拉伸强度和杨氏模量分别高达 90 兆帕和 48 千兆帕。基于聚(甲基丙烯酸甲酯)和富勒烯的系统具有较高的热降解温度(501-633°C)和良好的导电性(1.3 Scm-1)。在聚苯乙烯和嵌段共聚物体系中,富勒烯和石墨烯纳米填料的组合(由于协同效应)可显著提高导电率,范围在 1.8-2.5 Scm-1 之间。然而,在非共价增强基质中实现精细的富勒烯纳米粒子分散对最终的纳米复合材料性能有重要影响。因此,非共价富勒烯填充纳米复合材料的加工性和基本特性可能会受到纳米粒子聚集的影响。因此,本文阐述了非共价连接热塑性塑料-富勒烯之间的物理连接对提高物理性能的潜力。非共价作用热塑性聚合物/富勒烯纳米复合材料的研究揭示了从能源/电子设备到工程和生物医学领域的技术潜力。这篇综述文章可为该领域的研究人员提供有用的指导,帮助他们开发出使用非共价连接聚合物/富勒烯纳米材料的先进系统,用于未来的技术应用。
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引用次数: 0
Nanocomposites of thermoplastic matrices with non-covalent fullerene reinforcement—Structural diversity, physical impact and potential 热塑性基质与非共价富勒烯增强材料的纳米复合材料--结构多样性、物理影响和潜力
Pub Date : 2024-02-12 DOI: 10.1177/08927057241233568
Ayesha Kausar, Ishaq Ahmad
Fullerene has been acknowledged as a significant nanocarbon nanofiller enhancing the imperative polymer characteristics. Since, thermoplastic polymers constitute a large group of polymeric materials, fullerene has been used as reinforcement in these matrices mostly via non-covalent means. This state-of-the-art review article summarizes thermoplastic polymer nanocomposites reinforced with fullerene nano-additives without involving any covalent interactions. Accordingly, thermoplastic polymer/fullerene nanocomposites of interest have non-covalent or physical interactions in the matrix-nanofiller such as van der Waals forces, electrostatic interactions, hydrogen bonding, and aromatic stacking interactions. Number of thermoplastic polymers including polyamide, polyurethanes, and block copolymers have been non-covalently or physically reinforced with the fullerene molecules. Ensuing high performance thermoplastic polymer/fullerene nanocomposites exhibited improved microstructure, electrical, mechanical, thermal, and other physical properties. Enhancements in the thermal, mechanical, and electrical properties of the thermoplastic/fullerene nanomaterials were found dependent upon the nanofiller contents, orientations, interfacial effects, and processing. Consequently, the polyamide/fullerene systems were found efficient to enhance the glass transition up to 260°C, in addition to optimum mechanical properties. Polyurethane/fullerene systems performed better for improved tensile strength and young’s modulus features up to 90 MPa and 48 GPa, respectively. System based on poly (methyl methacrylate) and fullerene has resulted in high thermal degradation temperature in the range of 501-633°C with fine electrical conductivity of 1.3 Scm−1. Using combination of fullerene and graphene nanofiller (due to synergistic effects) has been found to improve the electrical conductivity considerably in the range of 1.8–2.5 Scm−1 for a polystyrene and block copolymer system. However, attaining fine fullerene nanoparticle dispersion of non-covalently reinforced matrices have been found important affecting the final nanocomposite properties. Consequently, processability and essential characteristics of non-covalently fullerene filled nanocomposites can be influenced due to nanoparticle aggregation. Hence, the physical property enhancement potential of physical linking between the non-covalently linked thermoplastics-fullerene has been portrayed in this article. Research on non-covalently interacted thermoplastic polymer/fullerene nanocomposites revealed technical potential ranging from energy/electronic devices to engineering and biomedical sectors. This review article can be a useful guide for the field researchers towards the development of advanced systems using non-covalently linked polymer/fullerene nanomaterials for future technical applications.
富勒烯已被公认为一种重要的纳米碳纳米填料,可增强聚合物的必要特性。热塑性聚合物是一大类聚合物材料,富勒烯主要通过非共价方式用作这些基质的增强剂。这篇最新综述文章总结了富勒烯纳米添加剂在不涉及任何共价作用的情况下增强热塑性聚合物纳米复合材料的情况。因此,相关的热塑性聚合物/富勒烯纳米复合材料在基体-纳米填料中具有非共价或物理相互作用,如范德华力、静电作用、氢键和芳香堆积相互作用。包括聚酰胺、聚氨酯和嵌段共聚物在内的许多热塑性聚合物都与富勒烯分子进行了非共价或物理增强。随之而来的高性能热塑性聚合物/富勒烯纳米复合材料显示出更好的微观结构、电气、机械、热和其他物理性能。热塑性塑料/富勒烯纳米材料的热性能、机械性能和电性能的提高取决于纳米填料的含量、取向、界面效应和加工过程。因此,聚酰胺/富勒烯系统除了具有最佳的机械性能外,还能有效提高玻璃化转变温度,最高可达 260°C。聚氨酯/富勒烯体系在提高拉伸强度和杨氏模量方面表现更佳,拉伸强度和杨氏模量分别高达 90 兆帕和 48 千兆帕。基于聚(甲基丙烯酸甲酯)和富勒烯的系统具有较高的热降解温度(501-633°C)和良好的导电性(1.3 Scm-1)。在聚苯乙烯和嵌段共聚物体系中,富勒烯和石墨烯纳米填料的组合(由于协同效应)可显著提高导电率,范围在 1.8-2.5 Scm-1 之间。然而,在非共价增强基质中实现精细的富勒烯纳米粒子分散对最终的纳米复合材料性能有重要影响。因此,非共价富勒烯填充纳米复合材料的加工性和基本特性可能会受到纳米粒子聚集的影响。因此,本文阐述了非共价连接热塑性塑料-富勒烯之间的物理连接对提高物理性能的潜力。非共价作用热塑性聚合物/富勒烯纳米复合材料的研究揭示了从能源/电子设备到工程和生物医学领域的技术潜力。这篇综述文章可为该领域的研究人员提供有用的指导,帮助他们开发出使用非共价连接聚合物/富勒烯纳米材料的先进系统,用于未来的技术应用。
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引用次数: 0
A correlation study on piezo-embedded carbon fibre reinforced polylactic acid composite: Experimental and numerical modelling 压电嵌入式碳纤维增强聚乳酸复合材料的相关性研究:实验和数值建模
Pub Date : 2024-02-09 DOI: 10.1177/08927057241231715
Jerold John Britto John Peter Antony, Vasanthanathan Arunachalam, S. Krishnasamy, Sanjay Mavinkere Rangappa, S. Siengchin
In this research work, a piezoelectric sensor and actuator model was designed. Carbon fibre-reinforced polylactic acid (CF/PLA) composites were fabricated using the fused deposition modelling (FDM) technique using many parameters to achieve this goal. For instance, the primary key parameters were 0.1 mm (layer height) and 25 mm/s (print head). Besides, the fabricated samples were subjected to a tensile study. Besides, MATLAB® Partial Differential Equation (PDE) tool was used to develop a finite element analysis (FEA) model for the piezoelectric actuator using the experimentally tested results. The MATLAB® was also used to examine the geometry and tip deflection. The experimental works were carried out to measure the sample’s strain using piezoelectric sensors. This approach could be used to establish the accuracy of the model. The CF/PLA composites were fabricated using 20 wt.% of reinforcements. The experimental results and finite element simulation were good agreement on results. Results reported that the deflections of 6.5765 mm, 5.197 mm, and 7.6328 mm, respectively embedded with PZT 5J, PZT 5H, and PZT 5A.
在这项研究工作中,设计了一个压电传感器和致动器模型。为实现这一目标,采用熔融沉积建模(FDM)技术,使用多种参数制造了碳纤维增强聚乳酸(CF/PLA)复合材料。例如,主要关键参数为 0.1 毫米(层高)和 25 毫米/秒(打印头)。此外,还对制作的样品进行了拉伸研究。此外,还使用 MATLAB® 偏微分方程 (PDE) 工具,利用实验测试结果为压电致动器开发了有限元分析 (FEA) 模型。MATLAB® 还用于检查几何形状和尖端挠度。实验工作使用压电传感器测量样品的应变。这种方法可用于确定模型的准确性。使用 20 wt.% 的增强材料制作了 CF/PLA 复合材料。实验结果和有限元模拟结果一致。结果表明,嵌入 PZT 5J、PZT 5H 和 PZT 5A 的挠度分别为 6.5765 毫米、5.197 毫米和 7.6328 毫米。
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引用次数: 0
A correlation study on piezo-embedded carbon fibre reinforced polylactic acid composite: Experimental and numerical modelling 压电嵌入式碳纤维增强聚乳酸复合材料的相关性研究:实验和数值建模
Pub Date : 2024-02-09 DOI: 10.1177/08927057241231715
Jerold John Britto John Peter Antony, Vasanthanathan Arunachalam, S. Krishnasamy, Sanjay Mavinkere Rangappa, S. Siengchin
In this research work, a piezoelectric sensor and actuator model was designed. Carbon fibre-reinforced polylactic acid (CF/PLA) composites were fabricated using the fused deposition modelling (FDM) technique using many parameters to achieve this goal. For instance, the primary key parameters were 0.1 mm (layer height) and 25 mm/s (print head). Besides, the fabricated samples were subjected to a tensile study. Besides, MATLAB® Partial Differential Equation (PDE) tool was used to develop a finite element analysis (FEA) model for the piezoelectric actuator using the experimentally tested results. The MATLAB® was also used to examine the geometry and tip deflection. The experimental works were carried out to measure the sample’s strain using piezoelectric sensors. This approach could be used to establish the accuracy of the model. The CF/PLA composites were fabricated using 20 wt.% of reinforcements. The experimental results and finite element simulation were good agreement on results. Results reported that the deflections of 6.5765 mm, 5.197 mm, and 7.6328 mm, respectively embedded with PZT 5J, PZT 5H, and PZT 5A.
在这项研究工作中,设计了一个压电传感器和致动器模型。为实现这一目标,采用熔融沉积建模(FDM)技术,使用多种参数制造了碳纤维增强聚乳酸(CF/PLA)复合材料。例如,主要关键参数为 0.1 毫米(层高)和 25 毫米/秒(打印头)。此外,还对制作的样品进行了拉伸研究。此外,还使用 MATLAB® 偏微分方程 (PDE) 工具,利用实验测试结果为压电致动器开发了有限元分析 (FEA) 模型。MATLAB® 还用于检查几何形状和尖端挠度。实验工作使用压电传感器测量样品的应变。这种方法可用于确定模型的准确性。使用 20 wt.% 的增强材料制作了 CF/PLA 复合材料。实验结果和有限元模拟结果一致。结果表明,嵌入 PZT 5J、PZT 5H 和 PZT 5A 的挠度分别为 6.5765 毫米、5.197 毫米和 7.6328 毫米。
{"title":"A correlation study on piezo-embedded carbon fibre reinforced polylactic acid composite: Experimental and numerical modelling","authors":"Jerold John Britto John Peter Antony, Vasanthanathan Arunachalam, S. Krishnasamy, Sanjay Mavinkere Rangappa, S. Siengchin","doi":"10.1177/08927057241231715","DOIUrl":"https://doi.org/10.1177/08927057241231715","url":null,"abstract":"In this research work, a piezoelectric sensor and actuator model was designed. Carbon fibre-reinforced polylactic acid (CF/PLA) composites were fabricated using the fused deposition modelling (FDM) technique using many parameters to achieve this goal. For instance, the primary key parameters were 0.1 mm (layer height) and 25 mm/s (print head). Besides, the fabricated samples were subjected to a tensile study. Besides, MATLAB® Partial Differential Equation (PDE) tool was used to develop a finite element analysis (FEA) model for the piezoelectric actuator using the experimentally tested results. The MATLAB® was also used to examine the geometry and tip deflection. The experimental works were carried out to measure the sample’s strain using piezoelectric sensors. This approach could be used to establish the accuracy of the model. The CF/PLA composites were fabricated using 20 wt.% of reinforcements. The experimental results and finite element simulation were good agreement on results. Results reported that the deflections of 6.5765 mm, 5.197 mm, and 7.6328 mm, respectively embedded with PZT 5J, PZT 5H, and PZT 5A.","PeriodicalId":508178,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":" 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139787726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of Thermoplastic Composite Materials
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