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The Effectiveness of Na2CrO4 to Inhibit Corrosion Rate of a A106 Grade Pipe in the Furnace Circulating Cooling Water with the Weight Loss Method on Pipe Lifetime Determining 用失重法测定 Na2CrO4 对熔炉循环冷却水中 A106 级管道腐蚀速率的抑制效果,以确定管道寿命
Pub Date : 2024-02-06 DOI: 10.4028/p-l7b0f7
Ika Fitriani J Palupi, Ainun Ma'wa
Pipes from industrial process flow diagrams have a predictable risk of failure or damage, so that periodic inspections are carried out. Corrosion that occurs in the pipe can cause a risk of leakage or blockage of the pipe flow which can be fatal to the fluid distribution process. This damage can be anticipated by inhibitors adding and predicting the corrosion rate. This research was conducted to determine the effective concentration of Na2CrO4 inhibitor to inhibit the corrosion rate and predict the lifetime of the furnace cooling water circulation pipe using the weight loss method. Na2CrO4 inhibitor is a type of anodic inhibitor that works by passively the anode by inhibiting corrosion on a whole metal surface. The study begins with the preparation stage, cutting the pipe into specimens of a certain size, smoothing the surface and weighing the initial weight. The testing phase was carried out by immersing the specimens at various times of 120 h, 240 h and 360 h with Na2CrO4 inhibitor variations concentration was 0%; 0,3%; 0,6%; and 0,9%. The corrosion rate was calculated by re-weighing the specimen after the immersion process. The results showed that the most effective inhibitor concentration was 0.6% with a corrosion rate of 0.3021 mmpy and the Remaining Service Lifetime (RSL) was 9.399 years.
工业流程图中的管道具有可预测的故障或损坏风险,因此需要进行定期检查。管道中发生的腐蚀会导致泄漏或管道堵塞,从而对流体分配过程造成致命影响。可以通过添加抑制剂和预测腐蚀率来预测这种损害。本研究采用失重法确定 Na2CrO4 抑制剂抑制腐蚀速率的有效浓度,并预测熔炉冷却水循环管道的使用寿命。Na2CrO4 抑制剂是一种阳极抑制剂,通过抑制整个金属表面的腐蚀而被动地作用于阳极。研究从准备阶段开始,将管道切割成一定大小的试样,磨平表面并称量初始重量。在测试阶段,将试样分别浸泡 120 小时、240 小时和 360 小时,Na2CrO4 抑制剂的浓度分别为 0%、0.3%、0.6% 和 0.9%。浸泡过程结束后,重新称重试样,计算腐蚀速率。结果表明,最有效的抑制剂浓度为 0.6%,腐蚀速率为 0.3021 mmpy,剩余使用寿命(RSL)为 9.399 年。
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引用次数: 0
Selection of Inhibitor and Recent Advances in Enhancing Corrosion Prevention 抑制剂的选择和加强防腐蚀的最新进展
Pub Date : 2024-02-06 DOI: 10.4028/p-ivxj7u
Yuli Panca Asmara, Firda Herlina, A. Sutjipto
Corrosion inhibitors are substances that protect metal surfaces by forming a protective film to prevent metallic materials in contact with corrosive environments. Inhibitors are created with capability to adsorb onto the metal surface, creating a barrier film, or neutralizing the detrimental effects of corrosive substances. Their performance are evaluated based on the ability in reducing corrosion rate. Traditionally, corrosion inhibitors made of chemical synthetic compounds. But as synthetic inhibitors have environmental impact, researchers are starting to explore compound alternatives. Currently, inhibitor technologies have demonstrated a remarkable growth in performance marked by the discovery of new types of inhibitors. Ongoing research are focusing on self-healing inhibitor, eco-friendly inhibitor, and nanostructured compounds inhibitors. This paper will comprehensively address the current challenges of advanced corrosion inhibitors. From the investigation, it has been noticed that application of innovative technologies has led to a transformative impact in producing with significant enhancement in their overall performance capabilities.
缓蚀剂是通过形成一层保护膜来保护金属表面的物质,以防止金属材料与腐蚀性环境接触。缓蚀剂能够吸附在金属表面,形成一层保护膜,或中和腐蚀性物质的有害影响。评估缓蚀剂性能的依据是其降低腐蚀速率的能力。传统的缓蚀剂由化学合成化合物制成。但由于合成抑制剂会对环境造成影响,研究人员开始探索化合物替代品。目前,以新型抑制剂的发现为标志,抑制剂技术的性能有了显著提高。目前的研究重点是自修复抑制剂、生态友好型抑制剂和纳米结构化合物抑制剂。本文将全面探讨当前先进缓蚀剂所面临的挑战。通过调查发现,创新技术的应用已对生产产生了变革性影响,显著提高了其整体性能。
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引用次数: 0
Application of CALPHAD Method for Predicting of Concentration Range of Amorphization of Transition Metals Melts 应用 CALPHAD 方法预测过渡金属熔体的非晶化浓度范围
Pub Date : 2024-02-06 DOI: 10.4028/p-lvl7lu
P. Agraval, M. Turchanin, L. Dreval, A. Vodopyanova
Early, the efficiency of the CALPHAD (Calculation of Phase Diagrams) method to a targeted search for compositions of amorphous alloys has been shown. The method for predicting the ranges of amorphization is based on the calculation of diagrams of metastable phase transformations between supercooled melts and boundary solid solutions on the base of pure elements. In this work, the model parameters for thermodynamic properties of liquid alloys and boundary solid solutions were summarized in a self-consistent database for the multicomponent Cu–Fe–Ni–Ti–Zr–Hf system. Such database for the multicomponent system is based on a common set of model parameters for boundary binary and ternary systems. This database was used to predict the concentration ranges of amorphization for the quinary Cu–Fe–Ni–Ti–Zr, Cu–Fe–Ni–Ti–Hf and boundary ternary and quaternary systems. The results of calculations are presented along sections in quaternary and quinary systems. The ternary and quaternary equiatomic alloys along with high entropy CuFeNiTiZr and CuFeNiTiHf alloys are trapped into prognosed composition ranges of amorphization. Predicted composition space of amorphization for melts of the Fe–Ni–Ti–Zr system is shown on the concentration tetrahedron. Based on the obtained results, a new criterion for predicting the concentration regions of amorphization of multicomponent melts is proposed, according to which the presence of a sufficient content of metals that are electron acceptors and donors is a chemical factor that affects the thermodynamic stability of melts and determines their glass-forming ability. For multicomponent melts of the Cu–Fe–Ni–Ti–Zr–Hf system the concentration ranges of amorphization correspond to the simultaneous fulfillment of the conditions xFe + xNi + xCu > 0.25 and xTi + xZr + xHf > 0.15, where Fe, Ni, and Cu are electron acceptors and Ti, Zr, and Hf are electron donors.
早些时候,CALPHAD(相图计算)方法在有针对性地寻找非晶合金成分方面的效率已经得到证明。这种预测非晶化范围的方法是以纯元素为基础,计算过冷熔体和边界固溶体之间的蜕变相图。在这项工作中,液态合金和边界固溶体热力学性质的模型参数被汇总到多组分 Cu-Fe-Ni-Ti-Zr-Hf 系统的自洽数据库中。这种多组分系统数据库是基于边界二元和三元系统的一套通用模型参数。该数据库用于预测二元 Cu-Fe-Ni-Ti-Zr、Cu-Fe-Ni-Ti-Hf 以及边界三元和四元体系的非晶化浓度范围。计算结果沿着四元和二元体系的剖面呈现。三元和四元等原子合金以及高熵 CuFeNiTiZr 和 CuFeNiTiHf 合金被困在预测的非晶化成分范围内。Fe-Ni-Ti-Zr体系熔体的预测非晶化成分空间显示在浓度四面体上。根据获得的结果,提出了预测多组分熔体非晶化浓度区域的新标准,根据该标准,作为电子受体和供体的金属的足够含量是影响熔体热力学稳定性并决定其玻璃形成能力的化学因素。对于 Cu-Fe-Ni-Ti-Zr-Hf 系统的多组分熔体,非晶化的浓度范围相当于同时满足 xFe + xNi + xCu > 0.25 和 xTi + xZr + xHf > 0.15 这两个条件,其中 Fe、Ni 和 Cu 为电子受体,Ti、Zr 和 Hf 为电子供体。
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引用次数: 0
Important of Slip Effects in Non-Newtonian Nanofluid Flow with Heat Generation for Enhanced Heat Transfer Devices 非牛顿纳米流体流动中的滑动效应与热量生成对增强型传热设备的重要性
Pub Date : 2024-02-06 DOI: 10.4028/p-baacr1
Olayinka Akeem Oladapo, A. Akindele, A. Obalalu, O. Ajala
In various fields such as engineering, nanotechnology, and biomedical sciences, the study of non-Newtonian nanofluid flow with heat generation is becoming increasingly important. However, it is challenging to accurately model such flows due to their complex behavior and slip effects at the fluid-solid interface. This research investigates the impact of first and second-order slip conditions on the flow and heat transfer properties of a non-Newtonian nanofluid using a power law model to describe the fluid's non-Newtonian behavior and numerical methods to solve the resulting equations. To determine the influence of various parameters such as slip parameters, Brinkman number, power law index, and Eckert number on the velocity, temperature, and concentration profiles, which this study examines. The study shows that slip parameters significantly determine the flow and heat transfer properties of non-Newtonian nanofluids, the study also reveals that slip parameters are a crucial factor in understanding the flow and heat transfer characteristics of nanofluids, with the second-order slip condition having a greater impact on velocity and temperature profiles than the first-order slip condition. These findings are valuable for developing and optimizing heat transfer devices that involve non-Newtonian nanofluids with heat generation, which is essential for technological advancements in today's industry.
在工程学、纳米技术和生物医学科学等各个领域,对带有热量产生的非牛顿纳米流体流动的研究正变得越来越重要。然而,由于此类流动的复杂行为和流固界面的滑移效应,对其进行精确建模具有挑战性。本研究采用幂律模型描述流体的非牛顿行为,并采用数值方法求解所得方程,研究一阶和二阶滑移条件对非牛顿纳米流体的流动和传热特性的影响。为了确定滑移参数、布林克曼数、幂律指数和埃克特数等各种参数对速度、温度和浓度曲线的影响,本研究对这些参数进行了研究。研究表明,滑移参数极大地决定了非牛顿纳米流体的流动和传热特性,研究还揭示了滑移参数是了解纳米流体流动和传热特性的关键因素,二阶滑移条件比一阶滑移条件对速度和温度曲线的影响更大。这些发现对于开发和优化涉及非牛顿纳米流体的传热设备非常有价值,这对于当今工业的技术进步至关重要。
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引用次数: 0
On the Analysis of Power Law Fluid over a Diamond Shaped Cylindrical Surface with Screen Boundary Conditions at High Reynolds Number 关于高雷诺数下菱形圆柱表面上的幂律流体与筛网边界条件的分析
Pub Date : 2024-02-06 DOI: 10.4028/p-udyqe2
A. Memon, M. A. Memon, G. Shaikh, A. Obalalu
This study analyses physical aspects of power-law fluid flow over a diamond shaped cylinder under the impact of a movable screen fixed in the middle of a channel keeping an aspect ratio as 0.5 with height of the channel. The perforated plate is a screen at the middle especially settled at orientation of π/6, π/4 or π/3 degrees. The Reynolds number (Re) has been kept in the range of 1000-10,000 with power-law index in the range 0.8-1.2. For the corresponding two-dimensional problem, the governing momentum equations coupled with energy equation have been solved numerically using non-isothermal laminar fluid flow interface in the software COMSOL Multiphysics 5.4. The dimensionless velocity magnitude and the non-dimensional temperature on the diamond shaped cylinder along the vertical non-dimensional length are expressed via fixing any two parameters from (Re), angle of screen θ and power-law index. The heat transfer coefficient, effective thermal conductivity and the Nusselt number are also expressed besides the dimonsionless length of the surface of the chosen cylinder. In conclusion, we will be going to suggest points to increase the dynamics and thermal variables with the use of selected parameters Re, θ, and power law index n.
本研究分析了菱形圆柱体上的幂律流体在固定于通道中间的活动滤网(与通道高度的长宽比为 0.5)的冲击下流动的物理方面。穿孔板是位于中间的滤网,特别是以 π/6、π/4 或 π/3 度的方向固定。雷诺数 (Re) 保持在 1000-10,000 之间,幂律指数保持在 0.8-1.2 之间。对于相应的二维问题,利用 COMSOL Multiphysics 5.4 软件中的非等温层流流体流动界面,对动量方程和能量方程进行了数值求解。菱形圆柱体上沿垂直无量纲长度方向的无量纲速度大小和无量纲温度可通过固定(Re)、筛网角 θ 和幂律指数中的任意两个参数来表示。除了所选圆柱体表面的无二维长度外,传热系数、有效导热系数和努塞尔特数也会被表示出来。最后,我们将就如何利用所选参数 Re、θ 和幂律指数 n 来增加动力学和热学变量提出建议。
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引用次数: 0
Structure and Properties of Melt-Quenched Al4CoCrCuFeNi High-Entropy Alloy 熔淬 Al4CoCrCuFeNi 高熵合金的结构与性能
Pub Date : 2024-02-06 DOI: 10.4028/p-4gvjbc
O. Kushnerov, V. F. Bashev, S. I. Ryabtsev
The structure and mechanical properties of a multicomponent high-entropy Al4CoCrCuFeNi alloy in the as-cast and melt-quenched states were investigated. The alloy composition was analyzed based on the literature criteria for predicting the phase formation in high-entropy alloys, which considered the entropy and enthalpy of mixing, valence electron concentration as well as the atomic size difference of the components. The alloy films were synthesized by quenching from the melt using a splat-quenching technique. The cooling rate of the films was estimated to be ~ 106 K/s based on the film thickness. The X-ray diffraction analysis revealed that both as-cast and melt-quenched Al4CoCrCuFeNi alloy samples had an ordered B2 phase in their structure. The microhardness of the as-cast alloy was 6500 MPa, while the microhardness of the melt-quenched film was significantly higher and reached 9400 MPa.
研究了一种多组分高熵 Al4CoCrCuFeNi 合金在铸造态和熔淬态下的结构和机械性能。根据文献中预测高熵合金相形成的标准分析了合金成分,该标准考虑了混合熵和混合焓、价电子浓度以及各成分的原子尺寸差。合金薄膜是采用溅射淬火技术从熔体中淬火合成的。根据薄膜厚度估算,薄膜的冷却速度约为 106 K/s。X 射线衍射分析表明,原铸和熔淬的 Al4CoCrCuFeNi 合金样品在结构上都具有有序的 B2 相。铸态合金的显微硬度为 6500 兆帕,而熔淬薄膜的显微硬度明显更高,达到 9400 兆帕。
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引用次数: 0
Thermophysical Properties of Cu-Based Subsystems of High-Entropy Alloys 高熵合金铜基子系统的热物理性质
Pub Date : 2024-02-06 DOI: 10.4028/p-gl7mcs
Yuriy Plevachuk, L. Romaka, I. Janotová, P. Svec, D. Janičkovič, R. Novakovic, V. Poverzhuk
According to the well-known concept of multicomponent high-entropy alloys, high entropy of mixing can stabilize the formation of solid solutions (simple bcc or fcc crystal structure) during solidification. Stabilization of the solid solution and prevention of the formation of intermetallic phases during solidification is provided by the high entropy of mixing in the solid and liquid states. High-entropy alloys have increased strength, high hardness, thermal stability in combination with good resistance to oxidation and corrosion. These properties allow to significantly expand the scope of these alloys. In this work, the electrical resistivity, thermoelectric power and surface tension of binary Cu–Sn, Cu–Ga and Cu–Bi alloys, which are the sub-system components of model low-temperature high-entropy Bi–Cu–Ga–Pb–Sn alloys, have been studied in a wide temperature range including solid and liquid states. The lack of the surface tension data of the above-mentioned alloys is compensated by the model predicted values.
根据众所周知的多组分高熵合金概念,高混合熵可在凝固过程中稳定固溶体(简单的 bcc 或 fcc 晶体结构)的形成。固态和液态的高混合熵可在凝固过程中稳定固溶体并防止金属间相的形成。高熵合金具有更高的强度、硬度、热稳定性以及良好的抗氧化性和抗腐蚀性。这些特性大大扩展了这些合金的应用范围。在这项工作中,研究了二元铜-锡、铜-镓和铜-铋合金(模型低温高熵铋-铜-镓-铅-锡合金的子系统成分)在包括固态和液态在内的宽温度范围内的电阻率、热电功率和表面张力。模型预测值弥补了上述合金表面张力数据的不足。
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引用次数: 0
An Algorithm for Detecting Surface Defects in Steel Strips Based on an Improved Lightweight Network 基于改进型轻量级网络的钢带表面缺陷检测算法
Pub Date : 2024-02-06 DOI: 10.4028/p-foi56w
Dao Hua Zhan, Han Wang, Xiu Ding Yang, Wei Cheng Ou, Ren Bin Huang, Jian Lin, Kunran Yi, Bei Zhou
In recent years, surface defect detection methods based on deep learning have been widely applied to steel plate surface defect detection. By locating and classifying defects on the surface of steel plates, production efficiency can be improved. However, there is still a conflict between speed and accuracy in the defect detection process. To address this issue, we propose a high-precision, low-latency surface defect detection algorithm called the GhostConv-ECA-YOLOv5 Network (GEA-Net). The GEA-Net model can predict defect categories without compromising classification and detection accuracy. Experimental results show that our proposed improved model has higher performance compared to other comparative models, achieving a 75.6% mAP on the NEU-DET dataset.
近年来,基于深度学习的表面缺陷检测方法被广泛应用于钢板表面缺陷检测。通过对钢板表面缺陷进行定位和分类,可以提高生产效率。然而,在缺陷检测过程中,速度与精度之间仍存在矛盾。针对这一问题,我们提出了一种高精度、低延迟的表面缺陷检测算法,即 GhostConv-ECA-YOLOv5 网络(GEA-Net)。GEA-Net 模型可以在不影响分类和检测精度的情况下预测缺陷类别。实验结果表明,与其他比较模型相比,我们提出的改进模型具有更高的性能,在 NEU-DET 数据集上实现了 75.6% 的 mAP。
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引用次数: 0
Comparative Analysis of Structural Reinforcement with Viscoelastic Energy Dissipators, Friction and Metal Creep in Tall Buildings 高层建筑结构加固与粘弹性消能材料、摩擦和金属蠕变的对比分析
Pub Date : 2024-02-06 DOI: 10.4028/p-4btbzq
Eddie J. Lipa, Jhon O. Pomasoncco, Joan R. Casas, R. Delgadillo
Seismic risk is a challenging problem in tall buildings due to the possibility of loss of human life and economic caused by seismic events. Peru is located at the interaction of the South American plate and the Nazca plate, which is why various seismic events of moderate to large magnitude occur. Today there are many ways to solve these problems and it is a very challenging case to reinforce tall buildings. In addition, technological advances in software facilitate and help through programmed models in tall buildings that analyze their structure characteristics such as drift, shear and others. This article proposes a comparative analysis of three types of dissipators: viscous fluid, friction, and metal creep through a Time-History analysis in a 15-story high-rise building located in Peru. The proposed methodology considers three stages: (i) definition of the characteristics and properties of the structure in accordance with Peruvian Standard E.030, in addition three accelerograms are used for the dynamic time-history analysis and maximum displacements and drifts are determined by ETABS software. (ii) calculate the design drift of the tall building and the properties of the viscous fluid, friction, and creep dissipator. In addition, calculations are made for the design parameters of each dissipator, and it is modeled as required for the case study. (iii) the new drifts and the damping values that the building presents for each dissipator are analyzed. According to the results obtained, the dissipator with the best results is of the flow type, since it has better performance in drifts and manages to produce an average damping of 96.87% for tall buildings. While the viscous dissipators obtain a 57.85% damping and the friction ones are estimated at 81.57%.
地震风险是高层建筑面临的一个挑战性问题,因为地震事件可能造成人员伤亡和经济损失。秘鲁位于南美板块和纳斯卡板块的交汇处,因此会发生各种中等至大震级的地震事件。如今,解决这些问题的方法有很多,而加固高层建筑则是一项极具挑战性的工作。此外,软件技术的进步也促进和帮助了高层建筑通过程序模型分析其结构特征,如漂移、剪切等。本文通过对位于秘鲁的一栋 15 层高层建筑进行时间-历史分析,提出了三种耗散器的比较分析方法:粘性流体、摩擦和金属蠕变。建议的方法分为三个阶段:(i) 根据秘鲁标准 E.030 确定结构的特性和属性,此外,使用三个加速度图进行动态时史分析,并通过 ETABS 软件确定最大位移和漂移。(ii) 计算高层建筑的设计漂移以及粘性流体、摩擦和蠕变耗散器的特性。此外,对每个耗散器的设计参数进行计算,并根据案例研究的要求建立模型。(iii) 分析了每个耗散器对建筑物产生的新漂移和阻尼值。根据得到的结果,效果最好的耗散器是流动型的,因为它在漂移方面有更好的表现,并能为高层建筑产生 96.87% 的平均阻尼。而粘性耗散器的阻尼为 57.85%,摩擦耗散器的阻尼估计为 81.57%。
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引用次数: 0
Low-Temperature Elastic Properties of Molybdenum Doped Non-Equiatomic High Entropy Alloys of the Fe-Co-Ni-Cr System 铁-铜-镍-铬体系掺钼非等原子高熵合金的低温弹性特性
Pub Date : 2024-02-06 DOI: 10.4028/p-brt7wl
Yuri Semerenko, Elena Tabachnikova, T. Hryhorova, S. Shumilin, Viktor Zoryansky
The mechanical properties and microstructural evolution of a medium-entropy alloy Co17.5Cr12.5Fe55Ni10Mo5 (at%) in a low temperature range (including the record low temperatures region down to 0.5 K) were investigated. It has been established that low-temperature plastic deformation initiates martensitic phase transformations in this alloy, and the values of the dynamic modulus of elasticity correlate with the degree of phase transformations.
研究了中熵合金 Co17.5Cr12.5Fe55Ni10Mo5(at%)在低温范围(包括低至 0.5 K 的创纪录低温区域)内的力学性能和微观结构演变。研究证实,低温塑性变形引发了该合金的马氏体相变,而动态弹性模量值与相变程度相关。
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引用次数: 0
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