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Materials Properties and Protection 材料特性和保护
Pub Date : 2024-02-06 DOI: 10.4028/b-ig7ktr
Oleksandr Vasiliev, Paulo Mendonça, Soon Hyung Hong, A. Sutjipto, A. D. Pramata
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引用次数: 0
Selection of Inhibitor and Recent Advances in Enhancing Corrosion Prevention 抑制剂的选择和加强防腐蚀的最新进展
Pub Date : 2024-02-06 DOI: 10.4028/p-ivxj7u
Yuli Panca Asmara, Firda Herlina, A. Sutjipto
Corrosion inhibitors are substances that protect metal surfaces by forming a protective film to prevent metallic materials in contact with corrosive environments. Inhibitors are created with capability to adsorb onto the metal surface, creating a barrier film, or neutralizing the detrimental effects of corrosive substances. Their performance are evaluated based on the ability in reducing corrosion rate. Traditionally, corrosion inhibitors made of chemical synthetic compounds. But as synthetic inhibitors have environmental impact, researchers are starting to explore compound alternatives. Currently, inhibitor technologies have demonstrated a remarkable growth in performance marked by the discovery of new types of inhibitors. Ongoing research are focusing on self-healing inhibitor, eco-friendly inhibitor, and nanostructured compounds inhibitors. This paper will comprehensively address the current challenges of advanced corrosion inhibitors. From the investigation, it has been noticed that application of innovative technologies has led to a transformative impact in producing with significant enhancement in their overall performance capabilities.
缓蚀剂是通过形成一层保护膜来保护金属表面的物质,以防止金属材料与腐蚀性环境接触。缓蚀剂能够吸附在金属表面,形成一层保护膜,或中和腐蚀性物质的有害影响。评估缓蚀剂性能的依据是其降低腐蚀速率的能力。传统的缓蚀剂由化学合成化合物制成。但由于合成抑制剂会对环境造成影响,研究人员开始探索化合物替代品。目前,以新型抑制剂的发现为标志,抑制剂技术的性能有了显著提高。目前的研究重点是自修复抑制剂、生态友好型抑制剂和纳米结构化合物抑制剂。本文将全面探讨当前先进缓蚀剂所面临的挑战。通过调查发现,创新技术的应用已对生产产生了变革性影响,显著提高了其整体性能。
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引用次数: 0
Metal Coatings Derived from Modified Silica as Anti-Corrosion 由改性二氧化硅衍生的金属防腐涂料
Pub Date : 2024-02-06 DOI: 10.4028/p-tx0n1p
S. Silviana, Candra Lukmilayani
Metal is widely used in various industrial fields such as transportation because of its physical and mechanical strength. However, during its utilization, metal materials are often damaged by corrosion due to chemical reactions between the metal surface and the surrounding environment. Coating is one way to prevent corrosion by isolating metal surfaces from the environment. Conventional anti-corrosion coatings generally use chromate and phosphate-based materials. However, this material has been banned in some countries because it is toxic to the environment. Meanwhile, other methods with the addition of more active metals such as magnesium are considered unaffordable. Therefore, the researchers developed alternative materials that are environmentally friendly and reduce costs by using metal oxide-based materials such as Silicon dioxide (SiO2). The advantage of SiO2 is that it is chemically stable and harmless. SiO2 modification produces hydrophobic properties which increase corrosion resistance. One of the methods to make SiO2 is sol-gel method. The advantages of sol-gel method are simple, affordable, capable of forming a film for attaching chemical properties, flexible for incorporation with other compounds and the coating can be applied in several ways, such as dip coating, spray coating, electrophoretic deposition (EPD), etc. As an anti-corrosion coating, products can be tested for their resistance by analyzing the corrosion rate. This paper reviews silica-based metal coatings as anti-corrosion. The scope of the discussion in this paper is the mechanism, fabrication route, application technique, characterization, and analysis of anti-corrosion ability by studying the corrosion rate of anti-corrosion silica-based coating products for metal substrates.
金属因其物理和机械强度而被广泛应用于运输等各种工业领域。然而,在使用过程中,由于金属表面与周围环境发生化学反应,金属材料往往会被腐蚀损坏。涂层是将金属表面与环境隔离以防止腐蚀的一种方法。传统的防腐蚀涂层一般使用铬酸盐和磷酸盐材料。然而,由于这种材料对环境有毒,在一些国家已被禁止使用。同时,添加镁等活性更强金属的其他方法也被认为难以负担。因此,研究人员通过使用二氧化硅(SiO2)等基于金属氧化物的材料,开发出了既环保又能降低成本的替代材料。二氧化硅的优点是化学性质稳定且无害。二氧化硅改性后具有疏水性,可提高耐腐蚀性。溶胶-凝胶法是制造二氧化硅的方法之一。溶胶-凝胶法的优点是简单、经济实惠、能形成附着化学性质的薄膜、可灵活地与其他化合物结合,而且涂层可采用多种方式,如浸涂、喷涂、电泳沉积(EPD)等。作为一种防腐蚀涂层,可以通过分析腐蚀率来测试产品的耐腐蚀性。本文综述了硅基金属防腐蚀涂层。本文讨论的范围包括机理、制造路线、应用技术、表征,以及通过研究金属基底防腐蚀硅基涂层产品的腐蚀速率来分析其防腐蚀能力。
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引用次数: 0
Radiative MHD Boundary Layer Flow and Heat Transfer Characteristics of Fe-Casson Base Nanofluid over Stretching/Shrinking Surface 拉伸/收缩表面上 Fe-Casson Base 纳米流体的辐射 MHD 边界层流动和传热特性
Pub Date : 2024-02-06 DOI: 10.4028/p-ha0zud
M. A. Memon, Kavikumar Jacob, H. B. Lanjwani, A. Obalalu, D. Nagarajan
In this paper, there is considered MHD boundary layer flow and heat transfer characteristics of Fe-Casson base nanofluid over an exponentially stretching/shrinking surface along the heat source/sink and Newtonian heating effects. In this regard, to develop the system of the governing equations, the one phase model named as Tiwari and Das model is considered with iron nanoparticles. The non-linear governing PDEs are first changed into the system of ODEs using suitable similarity transformations. Later on, the equations are solved numerically by using bvp4c in Matlab software. Effects of certain physical parameters on skin friction coefficient and the local Nusselt number are illustrated graphically. Moreover, the velocity and temperature profiles are examined to observe the influence of various physical parameters such as, Casson, magnetic, suction, radiation, Newtonian heating, heat source/sink and the nanoparticles volume fractions. It is seen that an increase in Casson, magnetic, suction and the nanoparticle volume fractions decrease the velocity profiles for both shrinking and shrinking cases of surface. The temperature profile recedes due to augmentation of Prandlt number and the suction parameter for both stretching/shrinking case while increases with increase in Magnetic, radiation and nanoparticles volume fractions.
本文考虑了铁-卡森基纳米流体在沿热源/沉降和牛顿加热效应的指数拉伸/收缩表面上的 MHD 边界层流动和传热特性。在这方面,为了建立控制方程系统,考虑了带有铁纳米颗粒的单相模型,即 Tiwari 和 Das 模型。首先使用适当的相似变换将非线性控制 PDE 变为 ODE 系统。随后,使用 Matlab 软件中的 bvp4c 对方程进行数值求解。某些物理参数对表皮摩擦系数和局部努塞尔特数的影响用图表说明。此外,还研究了速度和温度曲线,以观察各种物理参数的影响,如卡松、磁性、吸力、辐射、牛顿加热、热源/沉降和纳米颗粒体积分数。结果表明,卡松、磁力、吸力和纳米颗粒体积分数的增加会降低表面收缩和缩小情况下的速度曲线。在拉伸和收缩两种情况下,由于普朗特数和吸力参数的增加,温度曲线下降,而随着磁力、辐射和纳米颗粒体积分数的增加,温度曲线上升。
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引用次数: 0
Low-Temperature Elastic Properties of Molybdenum Doped Non-Equiatomic High Entropy Alloys of the Fe-Co-Ni-Cr System 铁-铜-镍-铬体系掺钼非等原子高熵合金的低温弹性特性
Pub Date : 2024-02-06 DOI: 10.4028/p-brt7wl
Yuri Semerenko, Elena Tabachnikova, T. Hryhorova, S. Shumilin, Viktor Zoryansky
The mechanical properties and microstructural evolution of a medium-entropy alloy Co17.5Cr12.5Fe55Ni10Mo5 (at%) in a low temperature range (including the record low temperatures region down to 0.5 K) were investigated. It has been established that low-temperature plastic deformation initiates martensitic phase transformations in this alloy, and the values of the dynamic modulus of elasticity correlate with the degree of phase transformations.
研究了中熵合金 Co17.5Cr12.5Fe55Ni10Mo5(at%)在低温范围(包括低至 0.5 K 的创纪录低温区域)内的力学性能和微观结构演变。研究证实,低温塑性变形引发了该合金的马氏体相变,而动态弹性模量值与相变程度相关。
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引用次数: 0
An Algorithm for Detecting Surface Defects in Steel Strips Based on an Improved Lightweight Network 基于改进型轻量级网络的钢带表面缺陷检测算法
Pub Date : 2024-02-06 DOI: 10.4028/p-foi56w
Dao Hua Zhan, Han Wang, Xiu Ding Yang, Wei Cheng Ou, Ren Bin Huang, Jian Lin, Kunran Yi, Bei Zhou
In recent years, surface defect detection methods based on deep learning have been widely applied to steel plate surface defect detection. By locating and classifying defects on the surface of steel plates, production efficiency can be improved. However, there is still a conflict between speed and accuracy in the defect detection process. To address this issue, we propose a high-precision, low-latency surface defect detection algorithm called the GhostConv-ECA-YOLOv5 Network (GEA-Net). The GEA-Net model can predict defect categories without compromising classification and detection accuracy. Experimental results show that our proposed improved model has higher performance compared to other comparative models, achieving a 75.6% mAP on the NEU-DET dataset.
近年来,基于深度学习的表面缺陷检测方法被广泛应用于钢板表面缺陷检测。通过对钢板表面缺陷进行定位和分类,可以提高生产效率。然而,在缺陷检测过程中,速度与精度之间仍存在矛盾。针对这一问题,我们提出了一种高精度、低延迟的表面缺陷检测算法,即 GhostConv-ECA-YOLOv5 网络(GEA-Net)。GEA-Net 模型可以在不影响分类和检测精度的情况下预测缺陷类别。实验结果表明,与其他比较模型相比,我们提出的改进模型具有更高的性能,在 NEU-DET 数据集上实现了 75.6% 的 mAP。
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引用次数: 0
Estimation of the Lattice Parameter and Lattice Distortion Based on the Results of Ab Initio Study of Structural Fragments of TiVZrNbMo, TiVZrNbHf, and TiVZrNbTa Multicomponent Alloys 基于 TiVZrNbMo、TiVZrNbHf 和 TiVZrNbTa 多组分合金结构碎片的 Ab Initio 研究结果对晶格参数和晶格畸变的估计
Pub Date : 2024-02-06 DOI: 10.4028/p-4am5dm
Nataliia Rozhenko, Liubov Ovsiannikova, Valery Kartuzov
Isolated clusters, fragments of the bcc structure of the compounds of the TiVZrNbMo, TiVZrNbHf and TiVZrNbTa systems, have been constructed and studied from the first principles. An approach has been developed and applied to predicting the lattice parameter and its distortion in solid-state structures based on the results of an Ab initio study of fragments of their structure. It has been established that the predicted values of the lattice constant of the equiatomic compounds TiVZrNbMo, TiVZrNbTa, TiVZrNbHf agree with the available experimental values with high reliability. The developed approach, together with the constructed models of isolated clusters, can be recommended for predicting the lattice parameter and its distortion in new predictive multicomponent metalic compounds.
从第一原理出发,构建并研究了TiVZrNbMo、TiVZrNbHf和TiVZrNbTa系统化合物的bcc结构片段--孤立团簇。根据对其结构片段的 Ab initio 研究结果,开发并应用了一种方法来预测固态结构中的晶格参数及其畸变。结果表明,等原子化合物 TiVZrNbMo、TiVZrNbTa、TiVZrNbHf 的晶格常数预测值与现有实验值高度吻合。所开发的方法与所构建的孤立团簇模型一起,可推荐用于预测新的预测性多组分金属化合物的晶格参数及其畸变。
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引用次数: 0
Investigation of Austempering Effect on Fatigue Crack Growth of AISI 4140 Steel 奥氏体化对 AISI 4140 钢疲劳裂纹生长影响的研究
Pub Date : 2024-02-06 DOI: 10.4028/p-5jjqqo
M. Badaruddin, Reza Annisa Ainnayah, Rizqy Nurully Wijaya, Slamet Sumardi
The compact tension (CT) and tensile specimens of the AISI 4140 steel in cold rolling condition (untreated steel) were austempered by immersing it into the salt bath at 362°C for 60 minutes. The tensile strength properties and the fatigue crack growth (FCG) resistance were performed to investigate the effect of the austempering process in AISI 4140 steel. A significant increase in the yield strength for austempered steel is about 8.7 % and the elastic strain energy increases by 55.7 %. Austempered steel's fatigue crack cycle is longer than that of untreated steel. Data of stress intensity factor range (ΔK, MPa.m1/2) and FCG rate (da/dN, m/cycle) was constructed in double log plot x-y axes for determining the materials constants m and C according to Paris’s law equation using a linear regression method. From the curve of ΔK versus da/dN, the constant m value for austempered steel (m = 3.45) shows better resistance than untreated steel (m = 3.77). On the other hand, the constant C value of 1.409×10-12 for austempered steel is one order magnitude higher than that of untreated steel (C = 4.151×10-13). The resistance of austempered steel against fatigue crack growth can be attributed to the formation of a bainite structure.
将冷轧状态下的 AISI 4140 钢(未处理钢)浸入 362°C 盐浴中 60 分钟,对其进行奥氏体化处理,以获得紧凑拉伸 (CT) 和拉伸试样。为了研究奥氏体化工艺对 AISI 4140 钢的影响,对其拉伸强度性能和抗疲劳裂纹生长(FCG)性能进行了测试。奥氏体回火钢的屈服强度大幅提高了约 8.7%,弹性应变能增加了 55.7%。奥氏体回火钢的疲劳开裂周期比未处理钢长。应力强度因子范围(ΔK,MPa.m1/2)和 FCG 率(da/dN,m/周期)的数据在双对数图 x-y 轴上构建,以便根据帕里斯定律方程,采用线性回归方法确定材料常数 m 和 C。从 ΔK 与 da/dN 的关系曲线来看,奥氏体回火钢的常数 m 值(m = 3.45)比未经处理的钢(m = 3.77)显示出更好的抗性。另一方面,奥氏体回火钢的常数 C 值为 1.409×10-12,比未经处理的钢(C = 4.151×10-13)高一个数量级。奥氏体回火钢对疲劳裂纹生长的抵抗力可归因于贝氏体结构的形成。
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引用次数: 0
Thermal Misfit and Diffusion Induced Stresses of Cu-Al Intermetallics in Microelectronics Wire Bonding 微电子导线键合中铜铝金属间化合物的热错位和扩散诱导应力
Pub Date : 2024-02-06 DOI: 10.4028/p-bdlco4
Sharir Shariza, T. Anand
The thermosonic bonding technique is a widely used method for Cu wire interconnections. However, issues arise due to volumetric changes in intermetallic compounds (IMCs) formed at the Cu-Al bonding interface, leading to voids in the Cu-Al IMC layer. This problem is exacerbated after annealing, such as in high-temperature Storage (HTS). In this study, a statistical modelling approach was employed to quantitatively analyse stress, studying the evolution and characteristics of the interfacial microstructure in the thermosonic Cu wire-Al bond pad system. Microstructural analysis focused on Cu-Al IMC crystallography and compositional classification. A stress model was proposed, considering both thermal misfit and diffusion-induced stresses. Results showed that interfacial stress generally increased with higher bonding temperatures. The influence of forming gas supply was relatively minor, with oxide layers minimally impeding Cu-Al interdiffusion during Cu-Al IMC formation. This stress modelling technique hold potential as a valuable failure analysis tool for implementing Cu wire in various industries.
热固性键合技术是一种广泛用于铜线互连的方法。然而,由于铜铝键合界面上形成的金属间化合物(IMC)的体积变化,导致铜铝 IMC 层出现空隙,从而产生了一些问题。退火后,例如在高温存储 (HTS) 中,这一问题会更加严重。本研究采用统计建模方法对应力进行定量分析,研究热声铜线-铝键合垫系统中界面微结构的演变和特征。微观结构分析侧重于铜-铝 IMC 晶体学和成分分类。考虑到热错位和扩散引起的应力,提出了一个应力模型。结果表明,界面应力通常随着粘合温度的升高而增加。成型气体供应的影响相对较小,在铜铝 IMC 形成过程中,氧化层对铜铝相互扩散的阻碍很小。这种应力建模技术可作为一种有价值的失效分析工具,应用于各行各业的铜线。
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引用次数: 0
On the Analysis of Power Law Fluid over a Diamond Shaped Cylindrical Surface with Screen Boundary Conditions at High Reynolds Number 关于高雷诺数下菱形圆柱表面上的幂律流体与筛网边界条件的分析
Pub Date : 2024-02-06 DOI: 10.4028/p-udyqe2
A. Memon, M. A. Memon, G. Shaikh, A. Obalalu
This study analyses physical aspects of power-law fluid flow over a diamond shaped cylinder under the impact of a movable screen fixed in the middle of a channel keeping an aspect ratio as 0.5 with height of the channel. The perforated plate is a screen at the middle especially settled at orientation of π/6, π/4 or π/3 degrees. The Reynolds number (Re) has been kept in the range of 1000-10,000 with power-law index in the range 0.8-1.2. For the corresponding two-dimensional problem, the governing momentum equations coupled with energy equation have been solved numerically using non-isothermal laminar fluid flow interface in the software COMSOL Multiphysics 5.4. The dimensionless velocity magnitude and the non-dimensional temperature on the diamond shaped cylinder along the vertical non-dimensional length are expressed via fixing any two parameters from (Re), angle of screen θ and power-law index. The heat transfer coefficient, effective thermal conductivity and the Nusselt number are also expressed besides the dimonsionless length of the surface of the chosen cylinder. In conclusion, we will be going to suggest points to increase the dynamics and thermal variables with the use of selected parameters Re, θ, and power law index n.
本研究分析了菱形圆柱体上的幂律流体在固定于通道中间的活动滤网(与通道高度的长宽比为 0.5)的冲击下流动的物理方面。穿孔板是位于中间的滤网,特别是以 π/6、π/4 或 π/3 度的方向固定。雷诺数 (Re) 保持在 1000-10,000 之间,幂律指数保持在 0.8-1.2 之间。对于相应的二维问题,利用 COMSOL Multiphysics 5.4 软件中的非等温层流流体流动界面,对动量方程和能量方程进行了数值求解。菱形圆柱体上沿垂直无量纲长度方向的无量纲速度大小和无量纲温度可通过固定(Re)、筛网角 θ 和幂律指数中的任意两个参数来表示。除了所选圆柱体表面的无二维长度外,传热系数、有效导热系数和努塞尔特数也会被表示出来。最后,我们将就如何利用所选参数 Re、θ 和幂律指数 n 来增加动力学和热学变量提出建议。
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引用次数: 0
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Defect and Diffusion Forum
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