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An Analysis of the Chemical Stress Field Under Potentiostatic Intermittent Titration Techniques for Interfacial Reaction-Controlled Systems 界面反应控制体系恒电位间歇滴定技术下的化学应力场分析
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-16 DOI: 10.1007/s10338-024-00578-1
Kaikai Li, Shichen Wang, Xiuling Shi, Yan Huang

The potentiostatic intermittent titration technique (PITT) is widely used to determine the diffusion coefficient of ions in electrode materials for rechargeable batteries such as lithium-ion or sodium-ion batteries, predicated on the assumption that the insertion/extraction of ions in the host materials is governed by diffusion. However, in practical scenarios, the electrochemical process might be dominated by interfacial reaction kinetics rather than diffusion. The present work derives analytical equations for electric current by considering the finite interfacial reaction kinetics and small overpotentials during PITT measurements and further studies the chemical stress field induced by the interfacial reaction-controlled ion insertion. The exchange current density (({j}_{0})) can be ascertained using the analytical equation, which dictates the magnitude and decay rate of the electric current during a PITT process. The electric current decays more rapidly, and consequently, the lithium concentration reaches equilibrium faster for larger values of ({j}_{0}). The magnitude of the chemical stress is independent of ({j}_{0}) but depends on the overpotential.

恒电位间歇滴定技术(PITT)被广泛用于确定锂离子或钠离子电池等可充电电池电极材料中离子的扩散系数,该技术基于离子在主材料中的插入/提取受扩散控制的假设。然而,在实际情况下,电化学过程可能是由界面反应动力学而不是扩散动力学主导的。本文考虑了PITT测量过程中有限的界面反应动力学和小过电位,推导了电流的解析方程,并进一步研究了界面反应控制离子插入引起的化学应力场。交换电流密度(({j}_{0}))可以用解析方程确定,它决定了在PITT过程中电流的大小和衰减率。电流衰减更快,因此,当({j}_{0})值较大时,锂浓度达到平衡的速度更快。化学应力的大小与({j}_{0})无关,但取决于过电位。
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引用次数: 0
A Numerical and Theoretical Study on the Perforation of Aluminum Plates Struck by Flat-Nosed Projectiles 扁头弹丸击中铝板穿孔的数值与理论研究
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-07 DOI: 10.1007/s10338-024-00557-6
L. F. Yang, H. M. Wen

It has been experimentally observed that, in the perforation of metal plates by a flat-nosed projectile, there exists a plateau phenomenon where the ballistic limit increases slightly with increasing plate thickness, which is related to a change in the mode of failure. No theoretical model has so far explained this phenomenon satisfactorily. This paper presents a combined numerical and theoretical study on the perforation of 2024-T351 aluminum plates struck by flat-nosed projectiles. First, numerical simulations are performed to investigate the failure mechanisms/deformation modes of the aluminum plates. Then, a theoretical model is proposed based on the numerical results and the experimental observations within a unified framework. The model takes into account the main energy absorbing mechanisms and the corresponding energies absorbed are determined analytically. In particular, a dimensionless equation is suggested to describe the relationship between global deformations and impact velocity. It transpires that the model predictions are in good agreement with the test data and the numerical results for the perforation of 2024-T351 aluminum plates struck by rigid flat-nosed projectiles in terms of residual velocity, ballistic limit, relationship between global deformations and impact velocity, and transition of failure modes. It also transpires that the present model can predict the “plateau” phenomenon, which shows a slight increase in ballistic limit as plate thickness increases. Furthermore, the energy absorption mechanisms are discussed on the basis of the theoretical analysis.

实验观察到,扁头弹在金属板的穿孔过程中,存在一个平台现象,随着板厚的增加,弹道极限略有增加,这与破坏模式的改变有关。到目前为止,还没有理论模型能令人满意地解释这一现象。本文对2024-T351铝板在扁头弹丸作用下的穿孔进行了数值与理论相结合的研究。首先,对铝板的破坏机制和变形模式进行了数值模拟研究。在此基础上,结合数值结果和实验观测,提出了统一框架下的理论模型。该模型考虑了主要的吸能机制,并解析确定了相应的吸能。特别提出了一个无量纲方程来描述整体变形与冲击速度之间的关系。结果表明,在剩余速度、弹道极限、整体变形与冲击速度的关系以及破坏模式的转变等方面,模型预测与2024-T351铝板受刚性扁头弹丸冲击穿孔的试验数据和数值结果吻合较好。该模型还可以预测“平台”现象,即随着板厚的增加,弹道极限略有增加。在理论分析的基础上,对能量吸收机理进行了探讨。
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引用次数: 0
Fracture Mechanics Analysis of Piezoelectric Materials Using an Efficient Collocation Element Differential Method 基于有效配置元微分法的压电材料断裂力学分析
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-03 DOI: 10.1007/s10338-024-00566-5
Jun Lv, Yi Yang, Miao Cui, Huayu Liu, Bingbing Xu, Xiaowei Gao

This paper presents a novel element differential method for modeling cracks in piezoelectric materials, aiming to simulate fracture behaviors and predict the fracture parameter known as the J-integral accurately. The method leverages an efficient collocation technique to satisfy traction and electric charge equilibrium on the crack surface, aligning internal nodes with piezoelectric governing equations without needing integration or variational principles. It combines the strengths of the strong form collocation and finite element methods. The J-integral is derived analytically using the equivalent domain integral method, employing Green's formula and Gauss's divergence theorem to transform line integrals into area integrals for solving two-dimensional piezoelectric material problems. The accuracy of the method is validated through comparison with three typical examples, and it offers fracture prevention strategies for engineering piezoelectric structures under different electrical loading patterns.

本文提出了一种新型的压电材料裂纹单元微分建模方法,旨在模拟压电材料的断裂行为并准确预测断裂参数j积分。该方法利用一种有效的配点技术来满足裂纹表面的牵引平衡和电荷平衡,使内部节点与压电控制方程对齐,而不需要积分或变分原理。它结合了强形式搭配法和有限元法的优点。采用等效域积分法,利用格林公式和高斯散度定理将线积分转化为面积积分,解析导出了二维压电材料问题的j积分。通过三个典型实例的对比,验证了该方法的准确性,并为工程压电结构在不同电载荷模式下的断裂预防策略提供了依据。
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引用次数: 0
Inverse Design of a NURBS-Based Chiral Metamaterial Via Machine Learning for Programmable Mechanical Deformation 基于可编程机械变形的nurbs手性超材料机器学习反设计
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-03 DOI: 10.1007/s10338-024-00569-2
Xiuhui Hou, Wenhao Zhao, Kai Zhang, Zichen Deng

Chiral metamaterials are manmade structures with extraordinary mechanical properties derived from their special geometric design instead of chemical composition. To make the mechanical deformation programmable, the non-uniform rational B-spline (NURBS) curves are taken to replace the traditional ligament boundaries of the chiral structure. The Neural networks are innovatively inserted into the calculation of mechanical properties of the chiral structure instead of finite element methods to improve computational efficiency. For the problem of finding structure configuration with specified mechanical properties, such as Young’s modulus, Poisson’s ratio or deformation, an inverse design method using the Neural network-based proxy model is proposed to build the relationship between mechanical properties and geometric configuration. To satisfy some more complex deformation requirements, a non-homogeneous inverse design method is proposed and verified through simulation and experiments. Numerical and test results reveal the high computational efficiency and accuracy of the proposed method in the design of chiral metamaterials.

手性超材料是由其特殊的几何设计而非化学成分而产生的具有非凡机械性能的人造结构。为了使机械变形可编程,采用非均匀有理b样条(NURBS)曲线代替传统的手性结构韧带边界。创新性地将神经网络引入手性结构力学性能的计算中,取代了传统的有限元方法,提高了计算效率。针对寻找具有杨氏模量、泊松比或变形等特定力学性能的结构构型问题,提出了一种基于神经网络的代理模型反设计方法,建立了力学性能与几何构型之间的关系。为满足较为复杂的变形要求,提出了一种非均匀反设计方法,并通过仿真和实验进行了验证。数值和试验结果表明,该方法在手性超材料设计中具有较高的计算效率和精度。
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引用次数: 0
The Scanning Secondary Moiré Method with Atomic-Level Resolution and Large Micrometer-Scale Field of View 具有原子级分辨率和大微米视场的扫描二次成像方法
IF 2 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-02 DOI: 10.1007/s10338-024-00525-0
Yao Zhao, Yueyue Xu, Zhanwei Liu, Jiangfan Zhou, Han Liu, Jianxin Nie, Jinzhao Zhao

The measurement field of view of the conventional transmission electron microscopy (TEM) nano-moiré and scanning transmission electron microscopy (STEM) nano-moiré methods is limited to the hundred-nanometer scale, unable to meet the deformation field measurement requirements of micrometer-scale materials such as transistors and micro-devices. This paper proposed a novel measurement method based on scanning secondary moiré, which can realize cross-scale deformation field measurement from nanometers to micrometers and solve the problem of insufficient measurement accuracy when using only the TEM moiré method. This method utilized the electron wave in the TEM passing through the atomic lattice of two layers of different materials to generate TEM moiré. On this basis, the TEM was tuned to the STEM mode, and by adjusting parameters such as the amount of defocusing, magnification, scanning angle, etc., the electron beam was focused on the position near the interface of the two layers of materials, and at the same time, the scanning line was made approximately parallel to the direction of one of the TEM moiré fringes. The scanning secondary moiré patterns were generated when the scanning spacing was close to the TEM moiré spacing. Through this method, the deformation field, mechanical properties, and internal defects of crystals can be detected by a large field of view with high sensitivity and high efficiency. Compared to traditional methods, the advantages of scanning secondary moiré method lie in significantly improving the measurement field of TEM moiré and STEM moiré methods, realizing the cross-scale visualization measurement from nanometers to micrometers, and possessing atomic-level displacement measurement sensitivity. It can also simplify and efficiently identify dislocations, offering a new method for large-area visualization observation of dislocation density in broad application prospects.

传统透射电子显微镜(TEM)纳米莫尔法和扫描透射电子显微镜(STEM)纳米莫尔法的测量视场局限于百纳米尺度,无法满足晶体管、微器件等微米尺度材料的变形场测量要求。本文提出了一种基于扫描二次涡流的测量方法,可以实现从纳米到微米的跨尺度变形场测量,解决了仅使用瞬变电磁法测量精度不足的问题。该方法利用透射电子波穿过两层不同材料的原子晶格,产生透射电子波。在此基础上,将TEM调至STEM模式,通过调整离焦量、放大倍率、扫描角度等参数,使电子束聚焦在两层材料界面附近的位置,同时使扫描线近似平行于其中一条TEM条纹的方向。当扫描间距与瞬变电磁法扫描间距接近时,产生扫描二次波纹图。通过该方法,可以在大视场范围内检测晶体的变形场、力学性能和内部缺陷,具有高灵敏度和高效率。与传统方法相比,扫描二次涡流法的优势在于显著改善了TEM涡流法和STEM涡流法的测量领域,实现了从纳米到微米的跨尺度可视化测量,具有原子级位移测量灵敏度。它还可以简化和高效地识别位错,为大面积可视化观察位错密度提供了一种新的方法,具有广阔的应用前景。
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引用次数: 0
A Feasible Experimental Method to Measure the Adhesive Strength of Brittle Adherends 一种测定脆性粘结材料粘结强度的可行实验方法
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-13 DOI: 10.1007/s10338-024-00565-6
Qiuhong Liu, Shuo Sun, Xiang Wu, Zhiqiang Chen, Hongjie Guo, Chen Duan, Zhengjin Wang

Brittle materials, such as silicon, glass, and ceramics, are widely used in engineering via adhesive bonding. The assessment of adhesive strength of brittle materials to other adherends is essential for their applications. Compared with metals and composites, for which standard testing methods have been established, the experimental method for brittle adherends has been much less explored. During the adhesive strength test, the brittleness of these materials makes them prone to failure, rather than the interface. It remains a challenge to measure the adhesive strength of brittle adherends. Here we develop an experimental method to address this issue by using a strap joint specimen with a backing layer. We use a single crystal silicon wafer and two PCB (printed circuit board) strips as adherends to make a strap joint specimen. A steel backing layer is glued to the silicon wafer to prevent the failure of silicon. This method enables the measurement of adhesive strength up to 35 MPa. In contrast, that without backing layer can only measure the adhesive strength below 10 MPa. It is found that the backing layer can reduce the stress in the silicon remarkably, while it has much less effect on the stress in the adhesive layer. We confirm that the backing layer has a negligible effect on the measured adhesive strength but expands the working space greatly. Combining finite element analysis and experiments, we establish the phase diagram for the failure modes. This work provides guidance for the measurement of adhesive strength of brittle materials.

脆性材料,如硅、玻璃和陶瓷,通过胶粘接广泛应用于工程中。脆性材料与其他附着物的粘接强度评估是其应用的必要条件。与已经建立了标准测试方法的金属和复合材料相比,脆性粘着物的实验方法探索较少。在粘接强度测试中,这些材料的脆性使其容易失效,而不是界面失效。脆性粘接材料的粘接强度测量一直是一个难题。在这里,我们开发了一种实验方法来解决这个问题,通过使用带衬底层的带状连接试样。我们使用单晶硅片和两个PCB(印刷电路板)条作为附着物来制作带状连接试样。在硅片上粘上一层钢衬底以防止硅的失效。这种方法可以测量高达35mpa的粘接强度。无底衬层只能测量10 MPa以下的粘接强度。研究发现,衬底层对硅中的应力有明显的抑制作用,而对粘接层中的应力影响较小。我们证实,衬底层对测量的粘接强度的影响可以忽略不计,但极大地扩大了工作空间。结合有限元分析和试验,建立了失效模式的相图。该工作为脆性材料粘接强度的测定提供了指导。
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引用次数: 0
Inflation of a Circular Hyperelastic Membrane: A Numerical Analysis 圆形超弹性膜的膨胀:数值分析
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-10 DOI: 10.1007/s10338-024-00562-9
Zike Chen, Lingrui Zhu, Lin Zhan, Rui Xiao

The inflation tests of rubbery membranes have been widely employed as an efficient method to characterize the stress response as biaxial loading states. However, most of the previous theoretical works have employed classic hyperelastic models to analyze the deformation behaviors of inflated membranes. The classic models have been demonstrated to lack the ability to capturing the biaxial deformation of rubbers. To address this issue, we have combined the analytical method and the finite element simulation to investigate the deformation response of soft membranes with different constitutive relationships. For the analytical method, the governing ordinary differential equations have been set up for the boundary value problem of inflation tests and further solved using the shooting method. The analytical results are consistent with those obtained from finite element simulation. The results show that the deformation belongs to the unequal biaxial condition rather than the equi-biaxial state unless a neo-Hookean model is adopted. We also perform a parameter study using the extended eight-chain model, which shows that a change in different parameters affects the mechanical response of inflation tests variously. This work may shed light on the future experimental characterization of soft materials using inflation experiments.

橡胶膜的膨胀试验作为表征双轴加载状态下应力响应的有效方法已被广泛采用。然而,以往的理论工作大多采用经典的超弹性模型来分析膨胀膜的变形行为。经典模型已被证明缺乏捕捉橡胶双轴变形的能力。为了解决这一问题,我们将解析法与有限元模拟相结合,研究了不同本构关系下软膜的变形响应。对于解析方法,建立了膨胀试验边值问题的控制常微分方程,并用射击法进一步求解。分析结果与有限元模拟结果一致。结果表明,除非采用新hookean模型,否则变形属于不等双轴状态,而不是等双轴状态。采用扩展八链模型进行了参数研究,结果表明不同参数的变化对膨胀试验的力学响应有不同的影响。这项工作可能对未来利用膨胀实验表征软材料的实验特性有所启发。
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引用次数: 0
Developments and Future Perspectives in Nanowires Mechanics 纳米线力学的发展与展望
IF 2 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-29 DOI: 10.1007/s10338-024-00558-5
Junxiang Xiang, Heyi Wang, Jingzhuo Zhou, Yang Lu

With the advancement of micro- and nano-scale devices and systems, there has been growing interest in understanding material mechanics at small scales. Nanowires, as fundamental one-dimensional building blocks, offer significant advantages for constructing micro/nano-electro-mechanical systems (MEMS/NEMS) and serve as an ideal platform for studying their size-dependent mechanical properties. This paper reviews the development and current state of nanowire mechanical testing over the past decade. The first part introduces the related issues of nanowire mechanical testing. The second section explores several key topics and the latest research progress regarding the mechanical properties of nanowires, including ultralarge elastic strain, large plastic strain, ‘smaller is stronger’, cold welding, and ductile-to-brittle transition. Finally, the paper envisions future development directions, identifying possible research hotspots and application prospects.

随着微纳米级器件和系统的发展,人们对小尺度材料力学的理解越来越感兴趣。纳米线作为基本的一维构件,为构建微纳米机电系统(MEMS/NEMS)提供了显著的优势,是研究其尺寸相关力学性能的理想平台。本文综述了近十年来纳米线力学测试的发展和现状。第一部分介绍了纳米线力学测试的相关问题。第二部分探讨了纳米线力学性能的几个关键主题和最新研究进展,包括超大弹性应变、大塑性应变、“小即强”、冷焊和韧脆转变。最后,展望了未来的发展方向,确定了可能的研究热点和应用前景。
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引用次数: 0
Nonlinear Resonance Response of Suspended Cables Under Multi-Frequency Excitations and Time-Delayed Feedback 多频激励和时滞反馈下悬索的非线性共振响应
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-29 DOI: 10.1007/s10338-024-00555-8
Jian Peng, Hui Xia, Lianhua Wang, Xiaoyu Zhang, Xianzhong Xie

This study investigates the nonlinear resonance responses of suspended cables subjected to multi-frequency excitations and time-delayed feedback. Two specific combinations and simultaneous resonances are selected for detailed examination. Initially, utilizing Hamilton’s variational principle, a nonlinear vibration control model of suspended cables under multi-frequency excitations and longitudinal time-delayed velocity feedback is developed, and the Galerkin method is employed to obtain the discrete model. Subsequently, focusing solely on single-mode discretization, analytical solutions for the two simultaneous resonances are derived using the method of multiple scales. The frequency response equations are derived, and the stability analysis is presented for two simultaneous resonance cases. The results demonstrate that suspended cables exhibit complex nonlinearity under multi-frequency excitations. Multiple solutions under multi-frequency excitation can be distinguished through the frequency–response and the detuning-phase curves. By adjusting the control gain and time delay, the resonance range, response amplitude, and phase of suspended cables can be modified.

研究了悬索在多频激励和时滞反馈作用下的非线性共振响应。选择两种特定的组合和同时共振进行详细检查。首先,利用Hamilton变分原理,建立了多频激励和纵向时滞速度反馈作用下悬索非线性振动控制模型,并采用伽辽金方法得到离散模型。随后,仅关注单模离散化,采用多尺度方法推导了两个同时共振的解析解。推导了频率响应方程,并对两种同步谐振情况进行了稳定性分析。结果表明,悬索在多频激励下表现出复杂的非线性特性。通过频率响应和失谐相位曲线可以区分多频激励下的多个解。通过调节控制增益和延时,可以改变悬索的谐振范围、响应幅度和相位。
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引用次数: 0
Bending Characteristics of Folded Multi-celled Tubes with Square and Circular Section Geometries 方形和圆形截面折叠多胞管的弯曲特性
IF 2 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-22 DOI: 10.1007/s10338-024-00533-0
Rui Liang, Fengxiang Xu, Zhen Zou, Xiaoqiang Niu, Xuebang Tang, Tingpeng Li

This research investigates the bending response of folded multi-celled tubes (FMTs) fabricated by folded metal sheets. A three-point bending test for FMTs with circular and square sections is designed and introduced. The base numerical models are correlated with physical experiments and a static crashworthiness analysis of six FMT configurations to assess their energy absorption characteristics. The influences of thickness, sectional shape, and load direction on the bending response are studied. Results indicate that increasing the thickness of the tube and radian of the inner tube enhances the crashworthiness performance of FMT, yielding a 20.50% increase in mean crushing force, a 55.53% increase in specific energy absorption, and an 18.05% decrease in peak crushing force compared to traditional multi-celled tubes (TMTs). A theoretical analysis of the specific energy absorption indicates that FMTs outperform TMTs, particularly when the peak crushing force is prominent. This study highlights the innovative and practical potential of FMTs to improve the crashworthiness of thin-walled structures.

本文研究了由金属薄片制成的折叠多胞管的弯曲响应。设计并介绍了圆截面和方截面FMTs的三点弯曲试验。将基本数值模型与物理实验和六种FMT结构的静态耐撞性分析相关联,以评估其能量吸收特性。研究了厚度、截面形状和荷载方向对弯曲响应的影响。结果表明,增加管厚和内管弧度可以提高FMT的耐撞性能,与传统的多胞管相比,平均破碎力提高20.50%,比能吸收提高55.53%,峰值破碎力降低18.05%。比能吸收的理论分析表明,FMTs优于TMTs,特别是当峰值破碎力突出时。该研究突出了FMTs在提高薄壁结构耐撞性方面的创新和实用潜力。
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引用次数: 0
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Acta Mechanica Solida Sinica
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