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Effect of Ferromagnetic Particles on the Effective Mechanical Properties of Bulk Superconductor with Interfacial Effect 具有界面效应的铁磁粒子对块体超导体有效力学性能的影响
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-22 DOI: 10.1007/s10338-024-00556-7
Ping Ma, Yufeng Zhao

This study focused on investigating the effects of various factors on the mechanical properties of superconducting matrix composites reinforced with ferromagnetic particles and interface phases when exposed to external magnetic fields. A micromechanical model was created by simplifying the basic properties and composition of the interface, utilizing principles such as Eshelby’s equivalent inclusion theory and Hooke’s law, as well as applying uniform stress boundary conditions. Through the development of equations, the study predicted changes in effective mechanical properties, highlighting the significant influence of parameters like the interface phase, inclusions, and magnetic field on the effective elastic modulus and magnetostriction of the composite material. By shedding light on these relationships, the research offers valuable insights for the manufacture and application of ferromagnetic particle-reinforced superconducting matrix composites with interface phases, providing a foundation for future research in this area.

研究了外加磁场作用下,各种因素对铁磁颗粒和界面相增强超导基复合材料力学性能的影响。利用Eshelby等效包含理论和Hooke定律等原理,采用均匀应力边界条件,简化了界面的基本性质和组成,建立了微观力学模型。通过方程的建立,预测了复合材料有效力学性能的变化,突出了界面相、夹杂物、磁场等参数对复合材料有效弹性模量和磁致伸缩的显著影响。通过揭示这些关系,本研究为具有界面相的铁磁颗粒增强超导基复合材料的制造和应用提供了有价值的见解,为该领域的进一步研究奠定了基础。
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引用次数: 0
Experimental Studies on the Mechanics of Graphene: A Review 石墨烯力学实验研究综述
IF 2 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-18 DOI: 10.1007/s10338-024-00537-w
Pei Zhao

Graphene, a two-dimensional material with atomic thickness, holds significant importance in advancing the existing theories of solid mechanics. However, as an intersection of multiple scales, it poses challenges to experimental measurements of its mechanical behaviors. This review comprehensively discusses the recent achievements in experimental studies on the mechanics of graphene, focusing on sample preparation, loading design, and measurement techniques. Moreover, personal perspectives on the future development in this field are presented, aiming to provide insights and inspiration for researchers engaged in related studies.

石墨烯是一种具有原子厚度的二维材料,对推进现有的固体力学理论具有重要意义。然而,它作为一个多尺度的交叉点,对其力学行为的实验测量提出了挑战。本文综述了近年来石墨烯力学实验研究的最新成果,重点介绍了样品制备、负载设计和测量技术。并对该领域的未来发展提出了个人看法,旨在为从事相关研究的研究者提供见解和启发。
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引用次数: 0
Mechanical Properties and Plastic Deformation Mechanisms of Polycrystalline Lithium Metal 多晶锂金属的力学性能及塑性变形机理
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-18 DOI: 10.1007/s10338-024-00553-w
Jiaxuan Wang, Yaxin Fang, Junfu Gao, Feng Hao

Lithium metal batteries have been deemed one of the most promising candidates for new-generation batteries, used in mobile devices, electric vehicles, energy storage, etc. However, due to the volume change of active materials and external pressure, the electrode materials and interfaces between battery components have high stresses during the cycling process, resulting in large deformation of the lithium metal anode. Herein, we derive insights into the mechanical behaviors of polycrystalline lithium metal. Specifically, the mechanical properties of lithium metal containing Li7-xLa3Zr2-xTaxO12 (x = 0.2–0.7) (LLZTO) solid-state electrolyte impurities are experimentally investigated. It is found that its strength is governed by impurity content and impurity particle size. In addition, we explore the Hall–Petch and inverse Hall–Petch effects of nanocrystalline lithium through atomic-scale simulations, revealing the plastic deformation mechanism in polycrystalline lithium metal. This fundamental study sheds light on the impurity-modulated mechanical properties and plastic deformation mechanism of polycrystalline lithium metal.

锂金属电池被认为是最有前途的新一代电池之一,可用于移动设备、电动汽车、储能等领域。然而,由于活性材料的体积变化和外界压力,在循环过程中,电极材料和电池组件之间的界面具有很高的应力,导致锂金属阳极变形较大。在此,我们对多晶锂金属的力学行为有了深入的了解。具体来说,实验研究了含有Li7-xLa3Zr2-xTaxO12 (x = 0.2-0.7) (LLZTO)固态电解质杂质的金属锂的力学性能。发现其强度与杂质含量和杂质粒度有关。此外,我们通过原子尺度模拟探索了纳米晶锂的Hall-Petch和逆Hall-Petch效应,揭示了多晶锂金属的塑性变形机制。这一基础性研究揭示了多晶金属锂的杂质调制力学性能和塑性变形机理。
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引用次数: 0
Molecular Dynamics Study on the Interactions of 1/2[110] Edge Dislocations with Voids and Ni3Al Precipitates in FCC Ni FCC Ni中1/2[110]边位错与孔洞和Ni3Al相相互作用的分子动力学研究
IF 2 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-11 DOI: 10.1007/s10338-024-00531-2
Wendong Cui, Junfeng Nie, Pandong Lin, Lei He

Nickel-based alloys are the primary structural materials in steam generators of high-temperature gas reactors. To understand the irradiation effect of nickel-based alloys, it is necessary to examine dislocation movement and its interaction with irradiation defects at the microscale. Hardening due to voids and Ni3Al precipitates may significantly impact irradiation damage in nickel-based alloys. This paper employs the molecular dynamics method to analyze the interaction between edge dislocations and irradiation defects (void and Ni3Al precipitates) in face-centered cubic nickel. The effects of temperature and defect size on the interaction are also explored. The results show that the interaction process of the edge dislocation and irradiation defects can be divided into four stages: dislocation free slip, dislocation attracted, dislocation pinned, and dislocation unpinned. Interaction modes include the formation of stair-rod dislocations and the climbing of extended dislocation bundles for voids, as well as the generation of stair-rod dislocation and dislocation shear for precipitates. Besides, the interactions of edge dislocations with voids and Ni3Al precipitates are strongly influenced by temperature and defect size.

镍基合金是高温气体反应堆蒸汽发生器的主要结构材料。为了了解镍基合金的辐照效应,有必要在微观尺度上研究位错运动及其与辐照缺陷的相互作用。空洞和Ni3Al析出引起的硬化对镍基合金的辐照损伤有重要影响。本文采用分子动力学方法分析了面心立方镍中边缘位错与辐照缺陷(空洞和Ni3Al析出)的相互作用。探讨了温度和缺陷尺寸对相互作用的影响。结果表明,边缘位错与辐照缺陷的相互作用过程可分为位错自由滑移、位错吸引、位错钉住和位错不钉住四个阶段。相互作用模式包括阶梯位错的形成和扩展位错束对空洞的攀爬,以及阶梯位错的产生和析出相的位错剪切。此外,边缘位错与空洞和Ni3Al析出相的相互作用受温度和缺陷尺寸的强烈影响。
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引用次数: 0
Adhesion of 2D Materials: Measurement and Modulation 二维材料的附着力:测量和调制
IF 2 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-11 DOI: 10.1007/s10338-024-00552-x
Na Li, Hongrong Wu, Changwei Sun, Junhua Zhao

Two-dimensional (2D) materials are promising for next-generation electronic devices and systems due to their unique physical properties. The interfacial adhesion plays a vital role not only in the synthesis, transfer and manipulation of 2D materials but also in the manufacture, integration and performance of the functional devices. However, the atomic thickness and limited lateral dimensions of 2D materials make the accurate measurement and modulation of their interfacial adhesion energy challenging. In this review, the recent advances in the measurement and modulation of the interfacial adhesion properties of 2D materials are systematically combed. Experimental methods and relative theoretical models for the adhesion measurement of 2D materials are summarized, with their scope of application and limitations discussed. The measured adhesion energies between 2D materials and various substrates are described in categories, where the typical adhesion modulation strategies of 2D materials are also introduced. Finally, the remaining challenges and opportunities for the interfacial adhesion measurement and modulation of 2D materials are presented. This paper provides guidance for addressing the adhesion issues in devices and systems involving 2D materials.

二维(2D)材料由于其独特的物理性质,在下一代电子设备和系统中很有前景。界面粘附不仅在二维材料的合成、转移和操作中起着至关重要的作用,而且在功能器件的制造、集成和性能中也起着至关重要的作用。然而,二维材料的原子厚度和有限的横向尺寸使得其界面粘附能的精确测量和调制具有挑战性。本文系统地梳理了二维材料界面粘附性能的测量和调制的最新进展。综述了二维材料黏附测量的实验方法和相关理论模型,讨论了它们的适用范围和局限性。测量的二维材料和各种衬底之间的粘附能分类描述,其中还介绍了典型的二维材料的粘附调制策略。最后,提出了二维材料界面粘附测量和调制的挑战和机遇。本文为解决涉及2D材料的设备和系统中的粘附问题提供了指导。
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引用次数: 0
Modeling of Coupling Between Free Volume Evolution and Diffusion in Silicon Electrodes of Lithium-Ion Batteries 锂离子电池硅电极自由体积演化与扩散耦合建模
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-08 DOI: 10.1007/s10338-024-00551-y
Kai Zhang, Junwu Zhou, Yinan He, Bailin Zheng, Yong Li

Silicon, a leading candidate for electrode material for lithium-ion batteries, has garnered significant attention. During the initial lithiation process, the alloying reaction between silicon and lithium transforms the pristine silicon microstructure from crystalline to amorphous, resulting in plastic deformation of the amorphous phase. This study proposes the free volume theory to develop a fully coupled Cahn–Hilliard phase-field model that integrates viscoplastic deformation, free volume evolution, and diffusion. This model investigates the chemophysical phenomenon of self-limiting behavior occurring during the initial lithiation of silicon anodes. Unlike most existing models, the proposed model considers free volume-dependent diffusion using a physically-based approach. The model’s temporal variation in the lithiated phase thickness aligns well with experimental results, confirming the model’s accuracy. Stress field calculations reveal the coexistence of compressive and tensile stresses within the lithiated phase, which may not cause the limiting effect under the frame of the stress-induced diffusion. Analyses indicate that high effective stress increases free volume, enhancing lithium diffusion and augmenting the diffusion coefficient. Reducing the diffusion coefficient in the lithiated phase due to free volume evolution is the primary cause of self-limiting lithiation.

硅是锂离子电池电极材料的主要候选材料,引起了人们的极大关注。在初始锂化过程中,硅与锂的合金化反应使原始硅微观结构由晶态转变为非晶态,导致非晶态发生塑性变形。本研究提出了自由体积理论,建立了一个集粘塑性变形、自由体积演化和扩散为一体的全耦合Cahn-Hilliard相场模型。该模型研究了硅阳极初始锂化过程中发生的自限行为的化学物理现象。与大多数现有模型不同,该模型使用基于物理的方法考虑自由体积相关扩散。模型的岩化相厚度随时间的变化与实验结果吻合较好,证实了模型的准确性。应力场计算结果表明,岩化相内存在压应力和拉应力共存,在应力诱导扩散框架下可能不会产生限制作用。分析表明,高有效应力增大了自由体积,增强了锂的扩散,增大了扩散系数。自由体积演化导致的岩化相扩散系数的降低是自限岩化的主要原因。
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引用次数: 0
Thermal Torsion Effect of Twisted Polymer Actuators 扭曲聚合物致动器的热扭转效应
IF 2 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1007/s10338-024-00547-8
Jiongjiong Hu, Lei Liu, Hao Liu, Dabiao Liu

Twisted polymer artificial muscles activated by thermal heating represent a new class of soft actuators capable of generating torsional actuation. The thermal torsion effect, characterized by the reversible untwisting of twisted fibers as temperature increases due to greater radial than axial thermal expansion, is crucial to the actuation performance of these artificial muscles. This study explores the thermal torsion effect of polymer muscles made of twisted Nylon 6 fibers in experimental and theoretical aspects, focusing on the interplay between material properties and temperature. It is revealed that the thermal torsion effect enhances the actuation performance of the twisted polymer actuator while the thermal softening effect diminishes it. A thermal–mechanical model incorporating both the thermal torsion effect and thermal softening effect is used to predict the recovered torque of the twisted polymer actuators. An optimal bias angle and operating temperature are identified to maximize the recovered torque. Analysis of strain and stress distributions in the cross-section of the twisted polymer fiber shows that the outer layers of the fiber predominantly contribute to the torsional actuation. This work aids in the precise control and structural optimization of the thermally-activated twisted polymer actuators.

加热激活的扭曲聚合物人造肌肉是一类能够产生扭转驱动的新型软致动器。热扭转效应的特点是,由于径向热膨胀大于轴向热膨胀,当温度升高时,扭曲的纤维可逆解扭,这对这些人造肌肉的驱动性能至关重要。本研究从实验和理论两方面探讨了尼龙6纤维捻制聚合物肌肉的热扭转效应,重点研究了材料性能与温度的相互作用。结果表明,热扭转效应提高了扭曲聚合物作动器的致动性能,而热软化效应降低了其致动性能。采用结合热扭转效应和热软化效应的热-力学模型预测了扭转聚合物作动器的恢复扭矩。确定了最佳偏置角和工作温度,以最大限度地提高恢复扭矩。对扭曲聚合物纤维截面的应变和应力分布分析表明,纤维的外层对扭转驱动起主要作用。这项工作有助于热激活扭曲聚合物致动器的精确控制和结构优化。
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引用次数: 0
Data-Enhanced Low-Cycle Fatigue Life Prediction Model Based on Nickel-Based Superalloys 基于数据增强的镍基高温合金低周疲劳寿命预测模型
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1007/s10338-024-00541-0
Luopeng Xu, Lei Xiong, Rulun Zhang, Jiajun Zheng, Huawei Zou, Zhixin Li, Xiaopeng Wang, Qingyuan Wang

To overcome the challenges of limited experimental data and improve the accuracy of empirical formulas, we propose a low-cycle fatigue (LCF) life prediction model for nickel-based superalloys using a data augmentation method. This method utilizes a variational autoencoder (VAE) to generate low-cycle fatigue data and form an augmented dataset. The Pearson correlation coefficient (PCC) is employed to verify the similarity of feature distributions between the original and augmented datasets. Six machine learning models, namely random forest (RF), artificial neural network (ANN), support vector machine (SVM), gradient-boosted decision tree (GBDT), eXtreme Gradient Boosting (XGBoost), and Categorical Boosting (CatBoost), are utilized to predict the LCF life of nickel-based superalloys. Results indicate that the proposed data augmentation method based on VAE can effectively expand the dataset, and the mean absolute error (MAE), root mean square error (RMSE), and R-squared (R2) values achieved using the CatBoost model, with respective values of 0.0242, 0.0391, and 0.9538, are superior to those of the other models. The proposed method reduces the cost and time associated with LCF experiments and accurately establishes the relationship between fatigue characteristics and LCF life of nickel-based superalloys.

为了克服实验数据有限的挑战,提高经验公式的准确性,提出了一种基于数据增强的镍基高温合金低周疲劳寿命预测模型。该方法利用变分自编码器(VAE)生成低周疲劳数据并形成增广数据集。使用Pearson相关系数(PCC)来验证原始数据集和增强数据集之间特征分布的相似性。采用随机森林(RF)、人工神经网络(ANN)、支持向量机(SVM)、梯度增强决策树(GBDT)、极限梯度增强(XGBoost)和分类增强(CatBoost)等6种机器学习模型对镍基高温合金LCF寿命进行了预测。结果表明,基于VAE的数据增强方法能够有效扩展数据集,且CatBoost模型的平均绝对误差(MAE)、均方根误差(RMSE)和r平方(R2)值分别为0.0242、0.0391和0.9538,均优于其他模型。该方法降低了LCF试验的成本和时间,准确地建立了镍基高温合金的疲劳特性与LCF寿命之间的关系。
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引用次数: 0
Stress Waves Propagation Along the Frictional Interface with a Micro-contact 应力波沿微接触摩擦界面的传播
IF 2 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1007/s10338-024-00540-1
Lingyan Shen, Yonggui Liu, Keyan Li, Xiaofei Ji, Xiangyu Jin

The stress wave profile at the frictional interface is crucial for investigating the frictional process. This study modeled a brittle material interface with a micro- contact to analyze the fine stress wave structure associated with frictional slip. Employing the finite element simulation alongside the related wave theory and experiments, two new wave structures were indentified: A Mach cone symmetric to the frictional interface associated with incident plane wave propagation, and a new plane longitudinal wave generated across the entire frictional interface at the moment when the incident wave began to propagate. The time and space of its appearance implies that the overall response of the frictional interface precedes the local wave response of the medium. Consequently, a model involving characteristic line theory and the idea of Green’s function has been proposed for its occurrence. The analysis results show that these two new wave phenomena are independent of the fracture of micro-contacts at the interface; instead, the frictional interface effect may be responsible for the generation of such new wave structures. The measured wave profiles provide a proof for the existence of the new wave structures. These results display new wave phenomena, and suggest a wave profile for investigating the dynamic mechanical properties of the frictional interface.

摩擦界面处的应力波分布对研究摩擦过程至关重要。本研究模拟了具有微接触的脆性材料界面,以分析与摩擦滑移相关的精细应力波结构。采用有限元模拟结合相关的波动理论和实验,确定了两种新的波结构:与入射平面波传播相关的摩擦界面对称的马赫锥,以及入射波开始传播时在整个摩擦界面上产生的新的平面纵波。其出现的时间和空间表明,摩擦界面的整体响应先于介质的局部波响应。因此,我们提出了一个包含特征线理论和格林函数思想的模型。分析结果表明,这两种新波现象与界面处微接触断裂无关;相反,摩擦界面效应可能是产生这种新波结构的原因。实测波浪剖面为新波结构的存在提供了证据。这些结果显示了新的波现象,并为研究摩擦界面的动态力学特性提供了一种波剖面。
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引用次数: 0
Design Insights for Bilayer Electrode Batteries in In-Situ Curvature Measurement Based upon Mechanical-Electrochemical Coupling Simulation 基于机械-电化学耦合模拟的双层电极电池原位曲率测量设计见解
IF 2.7 3区 工程技术 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-10-29 DOI: 10.1007/s10338-024-00538-9
Guoxing Zhang, Huibing Liu, Dawei Li, Bo Lu, Junqian Zhang

The largely bending bilayer electrode model battery has been widely used to measure the mechanical properties of composite electrode materials. The assumption used in the method that lithium is uniformly distributed in the active layer lacks quantitative evaluation, and the uniformity of concentration distribution is crucial for accurate in-situ measurements of concentration-related material properties and stress in bilayer electrodes. Therefore, this paper proposes a mechanical-electrochemical coupled model to study the lithium concentration distribution in the active layer during lithiation. This model includes lithium concentration diffusion and active layer deformation. By comparing experimental and simulated curvature evolution of the active layer during lithiation and delithiation, the reliability of this simulation model is verified. We then derive the precise concentration distribution inside the active layer and suggest using relative error to quantitatively evaluate the uniformity of lithium concentration in the active layer. Results show that a low relative error in lithium concentration can be achieved in the middle region of the active layer. Additionally, the effects of different rates and geometric parameters on the lithium concentration distribution in the active layer are discussed. Results indicate that reduced rates, thinner active layers, shorter active layer lengths, and increased spacing between the working and counter electrodes can lead to a more uniform distribution of lithium concentration in the active layer. These insights help improve experimental methods and equipment, promoting uniform distribution of lithium in the active layer and enhancing measurement accuracy.

大弯曲双层电极模型电池已被广泛应用于复合电极材料的力学性能测量。该方法中使用的锂均匀分布在活性层的假设缺乏定量评价,而浓度分布的均匀性对于准确地原位测量与浓度相关的双层电极材料性能和应力至关重要。因此,本文提出了一种机械-电化学耦合模型来研究锂化过程中活性层中锂离子浓度的分布。该模型包括锂离子浓度扩散和活动层变形。通过对比岩化和剥蚀过程中活动层曲率演化的实验与模拟结果,验证了该模拟模型的可靠性。推导出活性层内锂离子浓度的精确分布,并建议采用相对误差定量评价活性层内锂离子浓度的均匀性。结果表明,在活性层中部区域,锂离子浓度的相对误差较小。此外,还讨论了不同速率和几何参数对活性层锂离子浓度分布的影响。结果表明,降低速率、降低活性层厚度、缩短活性层长度以及增加工作电极与反电极之间的间距,可以使锂离子浓度在活性层中分布更加均匀。这些见解有助于改进实验方法和设备,促进锂在有源层中的均匀分布,提高测量精度。
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引用次数: 0
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