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Recent progress towards smart transportation systems using triboelectric nanogenerators 利用三电纳米发电机开发智能交通系统的最新进展
Pub Date : 2024-03-06 DOI: 10.1088/2515-7655/ad307e
Minh Phuong Nguyen, N. Huynh, Thien Trung Luu, Dukhyun Choi
The field of transportation plays a crucial role in the development of society. It is vital to establish a smart transportation system (STS) to increase the convenience and security of human life. The incorporation of artificial intelligence (AI) and the Internet of Things (IoT) into the traffic system has facilitated the emergence of innovative technologies like autonomous vehicles or unmanned aerial vehicles (UAVs), which contribute to the reduction of traffic accidents and the liberation of human driving time. However, this improvement involves the use of multiple sensor devices that need external power sources. As a result, pollution occurs, as do increases in manufacturing costs. Therefore, the quest to develop sustainable energy remains a formidable obstacle. Triboelectric nanogenerators (TENG) have emerged as a possible solution for addressing this problem owing to their exceptional performance and simple design. This article explores the use of TENG-based self-power sensors and their potential applications in the field of transportation. Furthermore, the data collected for this study might aid readers in enhancing their comprehension of the benefits linked to the use of these technologies to promote their creative ability.
交通领域在社会发展中起着至关重要的作用。建立智能交通系统(STS)对于提高人类生活的便利性和安全性至关重要。将人工智能(AI)和物联网(IoT)融入交通系统,促进了自动驾驶汽车或无人机(UAV)等创新技术的出现,有助于减少交通事故,解放人类的驾驶时间。然而,这种改进需要使用多个需要外部电源的传感器设备。因此,污染随之产生,制造成本也随之增加。因此,开发可持续能源仍然是一个巨大的障碍。三电纳米发电机(TENG)以其卓越的性能和简单的设计成为解决这一问题的可能方案。本文探讨了基于 TENG 的自供电传感器的使用及其在交通领域的潜在应用。此外,为本研究收集的数据可能有助于读者更好地理解使用这些技术对提高创造能力的益处。
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引用次数: 0
Ultrasound-driven triboelectric and piezoelectric nanogenerators in biomedical application 生物医学应用中的超声波驱动三电和压电纳米发电机
Pub Date : 2024-03-06 DOI: 10.1088/2515-7655/ad307c
Fu-Cheng Kao, Shih-Feng Hung, Chang-Chi Yang, Parag Parashar, Chun-Ju Huang, M. Hsieh, Jen‐Chung Liao, Po-Liang Lai, T. Fu, Tsung-Ting Tsai, Zong-Hong Lin
Microelectronics play a crucial role in medical settings by monitoring physiological signals, treating illnesses, and enhancing human well-being. For implanted and wearable devices, a reliable and continuous energy source is essential. While conventional energy systems rely on batteries and external power connections, their drawbacks, including the need for frequent charging, limited battery lifespan, and the potential for reoperation, restrict their utility. This has spurred the exploration of self-sustaining, long-lasting power solutions. The ultrasound-driven nanogenerator, a promising energy source, harnesses biomechanical energy from activities like muscle movement, heartbeat, respiration, and gastric peristalsis. It converts this energy into electrical signals, enabling the detection of physiological and pathological markers, cardiac pacing, nerve stimulation, tissue repair, and weight management. In this review, we provide an overview of triboelectric (TENG) and piezoelectric (PENG) nanogenerator design with ultrasound and its applications in biomedicine, offering insights for the advancement of self-powered medical devices in the future. These devices hold potential for diverse applications, including wound treatment, nerve stimulation and regeneration, as well as charging batteries in implanted devices.
微电子技术通过监测生理信号、治疗疾病和提高人类福祉,在医疗领域发挥着至关重要的作用。对于植入式和可穿戴设备来说,可靠、持续的能源是必不可少的。虽然传统的能源系统依赖电池和外部电源连接,但它们的缺点,包括需要频繁充电、电池寿命有限以及可能需要重新操作,限制了它们的实用性。因此,人们开始探索可自我维持的长效电源解决方案。超声波驱动的纳米发电机是一种前景广阔的能源,它能利用肌肉运动、心跳、呼吸和胃蠕动等活动产生的生物力学能量。它能将这种能量转化为电信号,从而实现生理和病理标记检测、心脏起搏、神经刺激、组织修复和体重管理。在这篇综述中,我们将概述利用超声波设计的三电(TENG)和压电(PENG)纳米发电机及其在生物医学中的应用,为未来自供电医疗设备的发展提供启示。这些设备具有多种应用潜力,包括伤口治疗、神经刺激和再生,以及为植入设备中的电池充电。
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引用次数: 0
Enhancing the indoor performance of organic photovoltaic devices: interface engineering with an aminobenzoic-acid-based self-assembled monolayer 增强有机光伏器件的室内性能:使用氨基苯甲酸基自组装单层的界面工程
Pub Date : 2024-03-06 DOI: 10.1088/2515-7655/ad307d
Seunghyun Oh, Ye Lim Kang, Tae Hyuk Kim, Seon Joong Kim, Min Jong Lee, Gyeong Min Lee, M. A. Saeed, Jae Won Shim
Significant advances in the performance of organic photovoltaic (OPV) devices can facilitate their use in Internet of Things applications. However, achieving excellent photostability and high efficiency using stable, efficient OPV devices in indoor settings is considerably difficult. To address this issue, a zinc oxide (ZnO) electron transport layer (ETL) was modified with a self-assembled monolayer (SAM) of 4-aminobenzoic acid (ABA) in the present study, and the impact of this modification was correlated with the indoor performance of an OPV device with the PM6:L8-BO photoactive layer. The ABA-treated ZnO ETL exhibited a significant reduction in the work function (from 4.51 to 4.04 eV), surface roughness (from 0.201 to 0.177 nm), and hydrophilicity of an indium-tin-oxide electrode; this aided in selectively extracting charge carriers from the device and minimizing trap-assisted recombination losses. Additionally, the ABA treatment of the ZnO ETL considerably enhanced the electron mobility and recombination resistance. It reduced the trap density, thereby enabling the ZnO/ABA-based device to achieve improved performance. Consequently, the ZnO/ABA-based device exhibited a noteworthy 14.68% higher maximum power output than that of the device without any ZnO surface modification under 1000 lx halogen (HLG) illumination (Pout, max = 354.48 and 309 µA cm−2, respectively). Moreover, under thermal illumination conditions (1000 lx HLG lighting), the ZnO/ABA-based device sustained ~74% of its initial power conversion efficiency over 120 h, significantly higher than its ABA-free equivalent (~55%).
有机光伏(OPV)器件的性能取得了长足进步,可促进其在物联网应用中的使用。然而,要在室内环境中使用稳定、高效的 OPV 器件实现出色的光稳定性和高效率却相当困难。为了解决这个问题,本研究用 4- 氨基苯甲酸(ABA)自组装单层(SAM)修饰了氧化锌(ZnO)电子传输层(ETL),并将这种修饰的影响与带有 PM6:L8-BO 光活性层的 OPV 器件的室内性能进行了关联。经 ABA 处理的氧化锌 ETL 的功函数(从 4.51 eV 降至 4.04 eV)、表面粗糙度(从 0.201 nm 降至 0.177 nm)和氧化铟锡电极的亲水性显著降低;这有助于从器件中选择性地提取电荷载流子,并最大限度地减少陷阱辅助重组损耗。此外,氧化锌 ETL 的 ABA 处理大大提高了电子迁移率和抗重组能力。它降低了陷阱密度,从而使基于氧化锌/ABA 的器件实现了更高的性能。因此,在 1000 lx 卤素(HLG)照明条件下(Pout, max = 354.48 和 309 µA cm-2),基于 ZnO/ABA 的器件的最大功率输出比未进行任何 ZnO 表面修饰的器件高出 14.68%。此外,在热照明条件下(1000 lx HLG 照明),基于氧化锌/ABA 的器件在 120 小时内保持了约 74% 的初始功率转换效率,明显高于不含 ABA 的同等器件(约 55%)。
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引用次数: 0
2024 Roadmap on membrane desalination technology at the water-energy nexus 2024 年水与能源关系中的膜淡化技术路线图
Pub Date : 2024-02-26 DOI: 10.1088/2515-7655/ad2cf2
Antonio Politano, Raed A. Al-Juboori, Sultan Alnajdi, A. Alsaati, A. Athanassiou, Maya Bar-Sadan, Ali Naderi Beni, Davide Campi, A. Cupolillo, Gianluca D’Olimpio, Giuseppe D'Andrea, Humberto Estay, D. Fragouli, L. Gurreri, Norredine Ghaffour, Jack Gilron, Nidal Hilal, Jessica Occhiuzzi, Mateo Roldan Carvajal, Avner Ronen, Sergio Santoro, Michele Tedesco, R. A. Tufa, Mathias Ulbricht, D. Warsinger, D. Xevgenos, Guillermo Zaragoza, Yong-Wei Zhang, Ming Zhou, E. Curcio
Water and energy are two strategic drivers of sustainable development, intimately interlaced and vital for a secure future of humanity. Given that water resources are limited, whereas global population and energy demand are exponentially growing, the competitive balance between these resources, referred to as the water-energy nexus – is receiving renewed focus. The desalination industry alleviates water stress by producing freshwater from saline sources, such as seawater, brackish or groundwater. Since the last decade, the market has been dominated by membrane desalination technology, offering significative advantages over thermal processes, such as lower energy demand, easy process control and scale-up, modularity for flexible productivity, and feasibility of synergic integration of different membrane operations. The exciting new frontier of sustainable mining of seawater concentrates is accelerating the appearance of a plethora of innovative membrane materials and methods for brine dehydration and selective extraction of trace ions, although under the sword of Damocles represented by cost feasibility for reliable commercial application. On the other hand, among several emerging technologies, reverse electrodialysis (SGP-RED) was already proven capable – at least at the kW scale–of turning the chemical potential difference between river water, brackish water, and seawater into electrical energy. Efforts to develop a next generation of Ion Exchange Membranes exhibiting high perm-selectivity (especially toward monovalent ions) and low electrical resistance, to improve system engineering and to optimize operational conditions, pursue the goal of enhancing the low power density so far achievable (in the order of a few W per m2). This Roadmap takes the form of a series of short contributions written independently by worldwide experts in the topic. Collectively, such contributions provide a comprehensive picture of the current state of the art in membrane science and technology at the water-energy nexus, and how it is expected to develop in the future
水和能源是可持续发展的两大战略驱动力,两者紧密相连,对人类未来的安全至关重要。鉴于水资源有限,而全球人口和能源需求却呈指数级增长,这些资源之间的竞争平衡,即所谓的水与能源的关系,正重新受到人们的关注。海水淡化行业通过从海水、咸水或地下水等含盐资源中生产淡水来缓解水资源压力。自过去十年以来,膜法海水淡化技术一直在市场上占据主导地位,与热法工艺相比,膜法海水淡化技术具有明显的优势,如能源需求低、工艺控制和放大容易、模块化生产灵活、不同膜操作的协同整合可行等。可持续开采海水浓缩物这一令人兴奋的新领域,正在加速出现大量创新的膜材料和方法,用于盐水脱水和微量离子的选择性提取,尽管在可靠的商业应用方面存在成本可行性这一达摩克利斯之剑。另一方面,在几项新兴技术中,反向电渗析(SGP-RED)已被证明能够将河水、苦咸水和海水之间的化学势差转化为电能,至少在千瓦级规模上是如此。目前正在努力开发下一代离子交换膜,使其具有高过电选择性(特别是对单价离子)和低电阻,改进系统工程和优化运行条件,以实现提高迄今可达到的低功率密度(每平方米几瓦)的目标。本路线图采用一系列简短文稿的形式,由该领域的全球专家独立撰写。总体而言,这些文章全面介绍了水与能源之间的膜科学技术的现状,以及未来的发展方向。
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引用次数: 0
Bifacial flexible CIGS thin-film solar cells with nonlinearly graded-bandgap photon-absorbing layers 具有非线性渐变带隙光子吸收层的双面柔性 CIGS 薄膜太阳能电池
Pub Date : 2024-02-16 DOI: 10.1088/2515-7655/ad29fd
Faiz Ahmad, P. Monk, A. Lakhtakia
The building sector accounts for 36% of energy consumption and 39% of energy-related greenhouse-gas emissions. Integrating bifacial photovoltaic solar cells in buildings could significantly reduce energy consumption and related greenhouse gas emissions. Bifacial solar cells should be flexible, bifacially balanced for electricity production, and perform reasonably well under weak-light conditions. Using rigorous optoelectronic simulation software and the differential evolution algorithm, we optimized symmetric/asymmetric bifacial CIGS solar cells with either (i) homogeneous or (ii) graded-bandgap photon-absorbing layers and a flexible central contact layer of aluminum-doped zinc oxide to harvest light outdoors as well as indoors. Indoor light was modeled as a fraction of the standard sunlight. Also, we computed the weak-light responses of the CIGS solar cells using LED illumination of different light intensities. The optimal bifacial CIGS solar cell with graded-bandgap photon-absorbing layers is predicted to perform with 18–29% efficiency under 0.01– 1.0-sun illumination; furthermore, efficiencies of 26.08% and 28.30% under weak LED light illumination of 0.0964 mW cm^{-2} and 0.22 mW cm^{-2} intensities, respectively, are predicted.
建筑行业占能源消耗的 36%,占能源相关温室气体排放的 39%。在建筑物中集成双面光伏太阳能电池可以大大减少能源消耗和相关的温室气体排放。双面太阳能电池应具有灵活性、双面平衡发电,并在弱光条件下具有良好的性能。利用严格的光电模拟软件和微分演化算法,我们对对称/非对称双面 CIGS 太阳能电池进行了优化,这些电池具有 (i) 均质或 (ii) 梯度带隙光子吸收层和柔性掺铝氧化锌中央接触层,既可在室外采光,也可在室内采光。室内光被模拟为标准太阳光的一部分。此外,我们还利用不同光强的 LED 照明计算了 CIGS 太阳能电池的弱光响应。根据预测,在 0.01-1.0 太阳光照射下,具有梯度带隙光子吸收层的最佳双面 CIGS 太阳能电池的效率为 18-29%;此外,在 0.0964 mW cm^{-2} 和 0.22 mW cm^{-2} 强度的 LED 弱光照射下,效率分别为 26.08% 和 28.30%。
{"title":"Bifacial flexible CIGS thin-film solar cells with nonlinearly graded-bandgap photon-absorbing layers","authors":"Faiz Ahmad, P. Monk, A. Lakhtakia","doi":"10.1088/2515-7655/ad29fd","DOIUrl":"https://doi.org/10.1088/2515-7655/ad29fd","url":null,"abstract":"\u0000 The building sector accounts for 36% of energy consumption and 39% of energy-related greenhouse-gas emissions. Integrating bifacial photovoltaic solar cells in buildings could significantly reduce energy consumption and related greenhouse gas emissions. Bifacial solar cells should be flexible, bifacially balanced for electricity production, and perform reasonably well under weak-light conditions. Using rigorous optoelectronic simulation software and the differential evolution algorithm, we optimized symmetric/asymmetric bifacial CIGS solar cells with either (i) homogeneous or (ii) graded-bandgap photon-absorbing layers and a flexible central contact layer of aluminum-doped zinc oxide to harvest light outdoors as well as indoors. Indoor light was modeled as a fraction of the standard sunlight. Also, we computed the weak-light responses of the CIGS solar cells using LED illumination of different light intensities. The optimal bifacial CIGS solar cell with graded-bandgap photon-absorbing layers is predicted to perform with 18–29% efficiency under 0.01– 1.0-sun illumination; furthermore, efficiencies of 26.08% and 28.30% under weak LED light illumination of 0.0964 mW cm^{-2} and 0.22 mW cm^{-2} intensities, respectively, are predicted.","PeriodicalId":509250,"journal":{"name":"Journal of Physics: Energy","volume":"30 41","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139962394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effectiveness of Poly(methyl methacrylate) spray encapsulation for perovskite solar cells 聚(甲基丙烯酸甲酯)喷雾封装在过氧化物太阳能电池中的应用效果
Pub Date : 2024-01-22 DOI: 10.1088/2515-7655/ad20f5
Declan Hughes, Michael Spence, Suzanne K. Thomas, Rokas Apanavicius, Chris Griffiths, Matthew J. Carnie, W. C. Tsoi
For commercial applications, Perovskite Solar Cells (PSCs) need to be well encapsulated to improve long term stability. The most common method, glass-glass encapsulation, uses edge sealant materials to encapsulate the device between sheets of glass. Glass-Glass encapsulation, while providing provide adequate protection from the ambient environment, limits the use of flexible substrates for thin film solar cells due to its rigidity. Additionally, the added weight of glass encapsulation reduces the specific power (W/kg) of PSCs, which is an important factor when designing solar cells for aerospace applications. Here we demonstrate that commercially available acrylic spray encapsulation offers efficient and robust stability for PSCs. It is shown that applying the encapsulation via this method does not degrade the PSCs, unlike other literature and glass-glass encapsulation methods. Additionally, it is shown that 1 coat of acrylic spray encapsulation has an effective thickness of ~1.77 µm and a weight of ~6 mg. For stability measurements, PSCs with acrylic coating show a 4% increase in performance after ~730 hours under dark storage conditions and retain 88% of their initial power conversion efficiency after 288 hours under 85% relative humidity 25°C. We anticipate our assay to be a starting point for further studies into spray encapsulation materials and methods not just for terrestrial applications, but for aerospace applications as well
在商业应用中,需要对 Perovskite 太阳能电池 (PSC) 进行良好封装,以提高其长期稳定性。最常见的方法是玻璃-玻璃封装,使用边缘密封材料将器件封装在玻璃片之间。玻璃-玻璃封装虽然能提供足够的保护,使其免受周围环境的影响,但由于其刚性,限制了薄膜太阳能电池对柔性基板的使用。此外,玻璃封装增加的重量降低了 PSC 的比功率(瓦/千克),而这是设计航空航天应用太阳能电池时的一个重要因素。在这里,我们证明了市场上销售的丙烯酸喷涂封装技术可为 PSC 提供高效、坚固的稳定性。与其他文献和玻璃-玻璃封装方法不同的是,通过这种方法进行封装不会使 PSC 退化。此外,研究还表明,一层丙烯酸喷雾封装的有效厚度约为 1.77 微米,重量约为 6 毫克。在稳定性测量方面,带有丙烯酸涂层的 PSC 在黑暗储存条件下经过约 730 小时后,性能提高了 4%,在相对湿度为 85% 的 25°C 条件下经过 288 小时后,其初始功率转换效率保持了 88%。我们预计,我们的试验将成为进一步研究喷雾封装材料和方法的起点,不仅适用于陆地应用,也适用于航空航天应用。
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引用次数: 0
Natural rubber based elastocaloric solid-state refrigeration device: design and performances of a single stage system 基于天然橡胶的弹性固态制冷装置:单级系统的设计与性能
Pub Date : 2024-01-22 DOI: 10.1088/2515-7655/ad20f4
Marianne Sion, Jacques Jay, G. Coativy, Atsuki Komiya, G. Sebald
The elastocaloric effect denotes the ability of a material to release or absorb heat when the material is stretched and released respectively. This effect may be used to design an alternative cooling device. This work focuses on the development of a cooling device using natural rubber as the elastocaloric material. It consists of a solid-solid heat exchange between a cyclically stretched elastocaloric material and two exchangers, respectively put in contact with the elastocaloric material when it is stretched or released. An experimental device was designed and tested in order to assess the temperature span and cooling power achievable by natural rubber based single stage device. The effect of the thickness of the natural rubber is also discussed. It is shown that it was possible to transfer nearly 60% of the heat absorption potential of the natural rubber from the cold heat exchanger. From the measurements, the highest cooling power was found to be 390 mW (430 W/kg) for a 600 µm thick sample, and 305 mW (540W/kg) for a 400 µm thick sample. The temperature span was found to be similar for both materials, ranging 1.5°C ~ 1.9°C.
弹性热效应是指材料在拉伸和释放时分别释放或吸收热量的能力。这种效应可用于设计替代冷却装置。这项工作的重点是开发一种使用天然橡胶作为弹性材料的冷却装置。该装置由周期性拉伸的弹性材料与两个交换器之间的固-固热交换组成,当弹性材料拉伸或释放时,两个交换器分别与弹性材料接触。为了评估基于天然橡胶的单级装置所能达到的温度跨度和冷却功率,我们设计并测试了一个实验装置。此外,还讨论了天然橡胶厚度的影响。实验结果表明,冷热交换器可以传递天然橡胶近 60% 的吸热潜能。测量发现,600 微米厚的样品的最高冷却功率为 390 毫瓦(430 瓦/千克),400 微米厚的样品的最高冷却功率为 305 毫瓦(540 瓦/千克)。两种材料的温度跨度相似,均为 1.5°C ~ 1.9°C。
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引用次数: 0
A compatibility study of protective coatings for temperature sensor integration into sodium-ion battery cells 用于将温度传感器集成到钠离子电池电池中的保护涂层的兼容性研究
Pub Date : 2024-01-12 DOI: 10.1088/2515-7655/ad1e38
T. Vincent, Faduma Maddar, Sheng Chao, Erdogan Guk, J. Sansom, B. Gulsoy, M. Copley, Ivana Hasa, J. Marco
Instrumented battery cells (i.e., those containing sensors) and smart cells (with integrated control and communication circuitry) are essential for the development of the next-generation battery technologies, such as Sodium-ion Batteries (SIBs). The mapping and monitoring of parameters, for example the quantification of temperature gradients, helps improve cell designs and optimise management systems. Integrated sensors must be protected against the harsh cell electrolytic environment. State-of-the-art coatings include the use of Parylene polymer (our reference case). We applied three new types of coatings (acrylic, polyurethane and epoxy based) to thermistor arrays mounted on flexible printed circuit board (PCBs). We systematically analyse the coatings: (i) PCB submersion within electrolyte vials (8-weeks); (ii) analysis of sample inserted into coin cell; (iii) analysis of sensor and cell performance data for 1Ah pouch SIBs. Sodium-based liquid electrolyte was selected, consisting of a 1M solution of sodium hexafluorophosphate (NaPF6) dissolved in a mixture of ethylene carbonate (EC) and diethylene carbonate (DEC) in a ratio of 3:7 (v/v%). Our novel experiments revealed that the epoxy based coated sensors offered reliable temperature measurements; superior performance observed compared to the Parylene sensors (erroneous results from one sample were reported, under 5 days submersed in electrolyte). Nuclear magnetic resonance (NMR) spectroscopy revealed in the case of most coatings tested, formation of additional species occurred during exposure to the different coatings applied to the PCBs. The epoxy-based coating demonstrated resilience to the electrolytic-environment, as well as minimal effect on cell performance (capacity degradation compared to unmodified-reference, within 2% for the coin cell, and within 3.4% for pouch cell). The unique methodology detailed in this work allows sensor coatings to be trialled in a realistic and repeatable cell environment. This study demonstrated for the first time that this epoxy-based coating enables scalable, affordable, and resilient sensors to be integrated towards next-generation Smart SIBs.
带仪器的电池单元(即包含传感器的电池单元)和智能电池单元(集成控制和通信电路)对于下一代电池技术(如钠离子电池)的发展至关重要。绘制和监测参数,例如量化温度梯度,有助于改进电池设计和优化管理系统。集成传感器必须受到保护,以抵御恶劣的电池电解环境。最先进的涂层包括使用 Parylene 聚合物(我们的参考案例)。我们在安装在柔性印刷电路板 (PCB) 上的热敏电阻阵列上使用了三种新型涂层(丙烯酸、聚氨酯和环氧基)。我们对涂层进行了系统分析:(i) 将印刷电路板浸入电解液瓶(8 周);(ii) 分析插入纽扣电池的样品;(iii) 分析 1Ah 袋 SIB 的传感器和电池性能数据。我们选择了钠基液体电解质,它由溶解在碳酸乙烯酯 (EC) 和碳酸二乙烯酯 (DEC) 混合物中的 1M 六氟磷酸钠 (NaPF6) 溶液组成,碳酸乙烯酯 (EC) 和碳酸二乙烯酯 (DEC) 的比例为 3:7(v/v%)。我们的新实验表明,基于环氧树脂涂层的传感器可提供可靠的温度测量;与聚对二甲苯传感器相比,其性能更优越(有报告称一个样品在电解液中浸泡 5 天后出现错误结果)。核磁共振(NMR)光谱显示,在大多数测试涂层中,在接触应用于多氯联苯的不同涂层时会形成额外的物种。基于环氧树脂的涂层对电解环境的适应性很强,对电池性能的影响也很小(与未修改的参考相比,纽扣电池的容量衰减在 2% 以内,袋装电池的容量衰减在 3.4% 以内)。这项工作中详细介绍的独特方法使传感器涂层能够在真实和可重复的电池环境中进行试验。这项研究首次证明,这种基于环氧树脂的涂层能够将可扩展、经济实惠且具有弹性的传感器集成到下一代智能 SIB 中。
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引用次数: 0
Sustainable additive manufacturing of polysulfone membranes for liquid separations 用于液体分离的聚砜膜的可持续增材制造
Pub Date : 2024-01-09 DOI: 10.1088/2515-7655/ad1ccc
Brian Leonard, Harrison A. Loh, David Lu, Ebuka A. Ogbuoji, Isabel C Escobar, Konstantinos Sierros, Oishi Sanyal
Membranes serve as important components for modern manufacturing and purification processes but are conventionally associated with excessive solvent usage. Here, for the first time, a procedure for fabricating large area polysulfone membranes is demonstrated via the combination of direct ink writing with non-solvent induced phase inversion. The superior control and precision of this process allows for complete utilization of the polymer dope solution during membrane fabrication, thus enabling a significant reduction in wasted material. Compared to doctor blade fabrication, a 63% reduction in dope solution volume was achieved using the direct ink writing technique for fabricating similarly sized membranes. Cross flow filtration analysis revealed that, independent of the manufacturing method (direct ink writing vs. doctor blade), the membranes exhibited near identical separation properties. The separation properties were assessed in terms of bovine serum albumin (BSA) rejection and permeances (pressure normalized flux) of pure water and BSA solution. This new manufacturing strategy allows for the reduction of material and solvent usage while providing a large toolkit of tunable parameters which can aid in advancing membrane technology.
膜是现代制造和净化工艺的重要组成部分,但传统上与溶剂的过度使用有关。在这里,我们首次展示了一种通过将直接油墨书写与非溶剂诱导相反转相结合来制造大面积聚砜膜的工艺。这种工艺的控制能力和精确度都非常高,可以在制膜过程中完全利用聚合物掺杂溶液,从而显著减少材料浪费。与刮刀制造相比,使用直接油墨书写技术制造类似尺寸的膜时,掺杂溶液的用量减少了 63%。横流过滤分析表明,无论采用哪种制造方法(直接涂墨法与刮刀法),膜的分离性能几乎完全相同。分离性能是根据纯水和 BSA 溶液的牛血清白蛋白(BSA)排斥率和渗透率(压力归一化通量)来评估的。这种新的制造策略可以减少材料和溶剂的用量,同时提供大量可调整参数的工具包,有助于推动膜技术的发展。
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引用次数: 0
Rotating magnetocaloric effect in polycrystals – harnessing the demagnetizing effect 多晶体中的旋转磁致效应--利用消磁效应
Pub Date : 2024-01-09 DOI: 10.1088/2515-7655/ad1c61
R. Almeida, S. C. Freitas, C. R. Fernandes, R. Kiefe, J. P. Araújo, J. S. Amaral, J. Ventura, J. H. Belo, D. Silva
Climate change and the increasing demand for energy globally has motivated the search for a more sustainable heat pumping technology. Magnetic refrigeration stands as one of the most promising alternative technologies for clean and efficient heat pumps of the future. Materials with a rotating magnetocaloric effect (RMCE) based on magnetocrystalline anisotropy have previously been explored as refrigerants with the potential to drastically improve device design by requiring a single magnetic field region. It has been shown previously that by exploiting the demagnetizing effect, an RMCE is in fact attainable in any polycrystalline magnetocaloric sample with an asymetric shape, without requiring magnetocrystalline anisotropy. Using gadolinium as a case study, we provide a theoretical framework for computing the demagnetizing field-induced RMCE indirectly, and present thorough experimental verification for different magnetic field intensities and a wide temperature range. Direct measurements of the RMCE in gadolinium reveal that a significant adiabatic temperature difference (1.2 K) and refrigerant capacity (7.44 J kg-1) are attained within low magnetic field amplitudes (0.4 T). By employing low field intensities in a magnetocaloric heat pump, the amount of permanent magnet material can be drastically reduced, lowering the overall weight and cost, making devices more viable for mass production.
气候变化和全球日益增长的能源需求促使人们寻找更具可持续性的热泵技术。磁制冷是未来清洁高效热泵最有前途的替代技术之一。基于磁晶各向异性而具有旋转磁致冷效应(RMCE)的材料曾被探索用作制冷剂,这种材料只需要一个磁场区域,因此有可能极大地改进设备设计。以前的研究表明,通过利用退磁效应,RMCE 实际上可以在任何具有非对称形状的多晶磁致样品中实现,而不需要磁晶各向异性。以钆为例,我们提供了间接计算退磁场诱导的 RMCE 的理论框架,并针对不同的磁场强度和较宽的温度范围进行了全面的实验验证。钆中 RMCE 的直接测量结果表明,在低磁场幅值(0.4 T)范围内可达到显著的绝热温差(1.2 K)和制冷剂容量(7.44 J kg-1)。通过在磁致热泵中采用低磁场强度,可以大幅减少永磁材料的用量,从而降低整体重量和成本,使设备更适合大规模生产。
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Journal of Physics: Energy
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