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Toroidal CO2 Plasma Sources with Low- and High-Frequency Power Coupling Configurations for Improved Energy Transfer Efficiencies 具有低频和高频功率耦合配置的环形二氧化碳等离子源,可提高能量传输效率
Pub Date : 2024-07-24 DOI: 10.3390/plasma7030030
E. J. Devid, W. Bongers, P. Groen, M. van Ginkel, S. Doyle, F. M. A. Smits, C. F. A. M. van Deursen, K. Serras, S. Labeur, M. A. Gleeson, M. C. M. van de Sanden
Electrodeless Low-Frequency (LF)/Radio-Frequency (RF) plasma sources often suffer from low power coupling efficiencies due to the lack of overlapping field with the dynamic plasma load. However, the power supplies for these plasma sources typically have very high power efficiencies (>90%) and are more cost-effective compared to microwave sources. If the coupling efficiency to the plasma can be increased, these plasma sources offer a competitive technology for the sustainable electrification of the chemical industry. This work experimentally investigates five power coupling methods, applied to toroidal CO2 plasmas in a quartz vessel. The research was based on similar ferrite coupling as used in energy-efficient plasma lamps. The higher resistance of the CO2 plasma decreased the power coupling from 90% (for mercury-vapor plasma) to 66% at 1 mbar. High coupling efficiencies in LF/RF powered discharges can be achieved in two manners: either the inductance of the transformer cores can be increased, or the electromagnetic wave frequency can be increased. Furthermore, additional ferrite cores in parallel with the primary coils can be used to increase the impedance transformation. An experiment with six ferrite cores with a single primary winding in parallel, at a frequency of about 10 MHz and a power of 1 kW, showed that this frequency has a detrimental effect on the magnetic permeability and the losses in the ferrite result in a decrease of coupling to 33% at 1.5 mbar. At a frequency of 66 kHz with a nanocrystalline soft magnetic material core, a coupling of 89% was achieved in 1.5 mbar plasma for a power of 3.1 kW. This configuration exhibits decreasing coupling efficiencies at higher pressures since the plasma impedance increases, which again limits the coupling of the transformer due to a lack of inductance. The investigation of alternative coreless coil plasma configurations resulted in coupling efficiencies up to 89% decreasing to 50% at 102 mbar for a toroidal plasma enclosed by toroidally spiraling coils.
无电极低频(LF)/射频(RF)等离子体源由于缺乏与动态等离子体负载的重叠场,通常功率耦合效率较低。然而,这些等离子体源的电源通常具有非常高的功率效率(大于 90%),与微波源相比更具成本效益。如果能提高与等离子体的耦合效率,这些等离子体源将为化工行业的可持续电气化提供具有竞争力的技术。这项工作通过实验研究了五种应用于石英容器中环形二氧化碳等离子体的功率耦合方法。研究以节能等离子灯中使用的类似铁氧体耦合为基础。二氧化碳等离子体的电阻较高,在 1 毫巴时,功率耦合从 90%(汞蒸汽等离子体)降至 66%。低频/射频供电放电中的高耦合效率可以通过两种方式实现:要么增加变压器磁芯的电感,要么提高电磁波频率。此外,还可以使用与初级线圈并联的附加铁氧体磁芯来增加阻抗变换。用六个铁氧体磁芯并联一个初级线圈,频率约为 10 兆赫,功率为 1 千瓦的实验表明,该频率对磁导率有不利影响,铁氧体中的损耗导致耦合降低到 1.5 毫巴时的 33%。在频率为 66 kHz、使用纳米晶软磁材料磁芯的情况下,在 1.5 毫巴等离子体中,功率为 3.1 kW 时的耦合度达到 89%。由于等离子体阻抗增加,这种配置的耦合效率在较高压力下会下降,这又会因缺乏电感而限制变压器的耦合。通过对其他无芯线圈等离子体配置的研究,在 102 毫巴压力下,由环形螺旋线圈包围的环形等离子体的耦合效率最高可达 89%,最低为 50%。
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引用次数: 0
A Review of Experimental Investigations into the Time Evolution of Low-Pressure Capacitively Coupled Plasmas in Their Early Stages of Development 低压电容耦合等离子体早期发展阶段的时间演变实验研究综述
Pub Date : 2024-07-22 DOI: 10.3390/plasma7030029
Pietro Mandracci
Capacitively coupled plasma (CCP) discharges working at low pressure are widely used for the synthesis of thin films and the modification of the surface properties of materials. Due to their importance, considerable research was carried out over the years to understand their working mechanisms, and the physical properties of the CCP discharges were measured by many research groups, while simulations of their characteristics were often performed using both fluid and kinematic models. However, most of the simulation and characterization work found in the literature is focused on the discharge steady-state characteristics, since most of the applications rely on its properties, while less information is available on the early stages. In fact, the initial stages of CCP plasma discharges are of great importance to improve the understanding of their ignition process as well as to figure out the working mechanism of pulsed discharges, the use of which has increased in importance in recent years. In this work, a review of the results published in recent years concerning the physical mechanisms involved in the very first stages of low-pressure CCP discharges is presented, focusing on the first few microseconds of discharge time.
在低压下工作的电容耦合等离子体(CCP)放电被广泛用于合成薄膜和改变材料的表面特性。由于其重要性,多年来人们开展了大量研究以了解其工作机制,许多研究小组测量了 CCP 放电的物理特性,并经常使用流体模型和运动模型对其特性进行模拟。然而,文献中的大多数模拟和表征工作都集中在放电稳态特性上,因为大多数应用都依赖于其特性,而关于早期阶段的信息则较少。事实上,CCP 等离子体放电的初始阶段对于更好地理解其点火过程以及弄清脉冲放电的工作机制非常重要,近年来脉冲放电的使用越来越重要。本研究综述了近年来发表的有关低压 CCP 放电最初阶段物理机制的研究成果,重点是放电时间的最初几微秒。
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引用次数: 0
Analysis of ICRF Heating Schemes in ITER Non-Active Plasmas Using PION+ETS Integrated Modeling 利用 PION+ETS 集成建模分析国际热核实验堆非活动等离子体中的 ICRF 加热方案
Pub Date : 2024-07-19 DOI: 10.3390/plasma7030028
Tomas Bensadon, Mervi Mantsinen, Thomas Jonsson, D. Gallart, Xavier Sáez, J. Manyer
The PION code has been integrated into the European Transport Solver (ETS) transport workflow, and we present the first application to model Ion Cyclotron Resonance Frequency (ICRF) heating scenarios in the next-step fusion reactor ITER. We present results of predictive, self-consistent and time-dependent simulations where the resonant ion concentration is varied to study its effects on the performance, with a special emphasis on the resulting bulk ion heating and thermal ion temperature. We focus on two ICRF heating schemes, i.e., fundamental H minority heating in a 4He plasma at 2.65 T/7.5 MA and a three-ion ICRF scheme consisting of fundamental 3He heating in a H-4He plasma at 3.3 T/ 8.8 MA. The H minority heating scenario is found to result in strong absorption by resonant H ions as compared to competing absorption mechanisms and dominant background electron heating for H concentrations up to 10%. The highest H absorption of ∼80% of the applied ICRF power and highest ion temperature of ∼15 keV are obtained with an H concentration of 10%. For the three-ion scheme in 85%:15% H:4He plasma, PION+ETS predicts 3He absorption in the range of 21–65% for 3He concentrations in the range of 0.01–0.20%, with the highest 3He absorption at a 3He concentration of 0.20%.
PION 代码已被集成到欧洲传输求解器(ETS)传输工作流程中,我们首次将其应用于模拟下一步聚变反应堆 ITER 中的离子回旋共振频率(ICRF)加热情况。我们介绍了预测性、自洽性和随时间变化的模拟结果,其中共振离子浓度的变化研究了其对性能的影响,特别强调了由此产生的体离子加热和热离子温度。我们重点研究了两种 ICRF 加热方案,即在 2.65 T/7.5 MA 的 4He 等离子体中进行基本 H 少数加热,以及在 3.3 T/8.8 MA 的 H-4He 等离子体中进行由基本 3He 加热组成的三离子 ICRF 方案。研究发现,在 H 浓度高达 10%的情况下,与其他吸收机制和占主导地位的背景电子加热相比,H 少数加热方案会导致共振 H 离子的强烈吸收。当 H 浓度为 10%时,H 吸收率最高,达到所应用 ICRF 功率的 80%,离子温度最高,达到 15 keV。对于 85%:15% H:4He 等离子体中的三离子方案,PION+ETS 预测 3He 吸收率在 21-65% 之间,3He 浓度在 0.01-0.20% 之间,3He 吸收率在 0.20% 时最高。
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引用次数: 0
Advanced Diagnostics of Electrons Escaping from Laser-Produced Plasma 激光产生的等离子体中逸散电子的先进诊断技术
Pub Date : 2024-05-13 DOI: 10.3390/plasma7020021
Josef Krása, Michal Krupka, Shubham Agarwal, Vincenzo Nassisi, Sushil Singh
This article provides an up-to-date overview of the problems associated with the detection of hot electrons escaping from laser-produced plasma and corresponding return current flowing from the ground to the target, which neutralises the positive charge occurring on the target due to the escaped electrons. In addition, the target holder system acts as an antenna emitting an electromagnetic pulse (EMP), which is powered by the return target. If the amount of positive charge generated on the target is equal to the amount of charge carried away from the plasma by the escaping electrons, the measurement of the return current makes it possible to determine this charge, and thus also the number of escaped electrons. Methods of return current detection in the mA–10 kA range is presented, and the corresponding charge is compared to the charge determined using calibrated magnetic electron energy analysers. The influence of grounded and insulated targets on the number of escaped electrons and EMP intensity is discussed. In addition to EMP detection, mapping of the electrical potential near the target is mentioned.
本文概述了与探测从激光产生的等离子体中逸出的热电子以及从地面流向目标的相应回流电流有关的最新问题,回流电流中和了目标上因逸出的电子而产生的正电荷。此外,目标支架系统还充当发射电磁脉冲(EMP)的天线,由返回目标供电。如果靶上产生的正电荷量等于逸出电子从等离子体带走的电荷量,则通过测量返回电流可以确定电荷量,从而确定逸出电子的数量。本文介绍了毫安-10 千安范围内的返回电流检测方法,并将相应的电荷与使用校准磁电子能量分析仪测定的电荷进行了比较。讨论了接地和绝缘目标对逸出电子数和电磁脉冲强度的影响。除了电磁脉冲检测之外,还提到了目标附近的电势映射。
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引用次数: 0
Shock–Discharge Interaction Model Extended into the Third Dimension 扩展到三维空间的冲击-放电相互作用模型
Pub Date : 2024-05-11 DOI: 10.3390/plasma7020020
Anna Markhotok
This work is an addition to the previously developed two-dimensional model of the shock–plasma interaction, extending it into the third dimension. The model can trace the evolution of the state of the hypersonic flow and the shock front refracted at a thermal discontinuity. The advantages of using the spherical coordinate system for this type of problem include increased transparency in interpreting the solution and a shortened calculation procedure, because all the changes to the front are reduced to one distortion component. Although the vorticity generation triggered at the interface is a consequence of the refraction and tied to the steep changes in the front, it is shown here that this is not because of an instant parameter jump at the interface due to refraction itself.
这项工作是对之前开发的冲击-等离子体相互作用二维模型的补充,将其扩展到了三维空间。该模型可以追踪高超音速流状态的演变以及在热不连续处折射的冲击前沿。使用球面坐标系来处理这类问题的优点包括提高了解释解法的透明度和缩短了计算程序,因为前沿的所有变化都被简化为一个扭曲分量。虽然在界面处引发的涡度产生是折射的结果,并与锋面的急剧变化有关,但本文显示,这并不是因为折射本身在界面处造成的瞬间参数跃迁。
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引用次数: 0
Determination of Highly Transient Electric Field in Water Using the Kerr Effect with Picosecond Resolution 利用具有皮秒分辨率的克尔效应测定水中的高瞬态电场
Pub Date : 2024-04-22 DOI: 10.3390/plasma7020018
P. Hoffer, V. Prukner, G. Arora, R. Mušálek, Milan Šimek
This study utilizes the Kerr effect in the analysis of a pulsed electric field (intensity ~108 V/m, limited by the liquid dielectric strength) in deionized water at the sub-nanosecond time scale. The results provide information about voltage waveforms at the field-producing anode (160 kV peak, du/dt > 70 kV/ns). The analysis is based on detecting the phase shifts between measured and reference pulsed laser beams (pulse width, 35 ps; wavelength, 532 nm) using a Mach–Zehnder interferometer. The signal-to-noise ratio of the detected phase shift is maximized by an appropriate geometry of the field-producing anode, which creates a correctly oriented strong electric field along the interaction path and simultaneously does not electrically load the feeding transmission line. The described method has a spatial resolution of ~1 μm, and its time resolution is determined by the laser pulse duration.
本研究利用克尔效应对去离子水中的脉冲电场(强度约为 108 V/m,受液体介电强度限制)进行了亚纳秒时间尺度的分析。结果提供了产生电场的阳极的电压波形信息(峰值 160 kV,du/dt > 70 kV/ns)。分析的基础是使用马赫-泽恩德干涉仪检测测量激光束和参考脉冲激光束(脉宽 35 ps;波长 532 nm)之间的相移。场产生阳极的适当几何形状可最大限度地提高检测到的相移信噪比,该阳极可沿着相互作用路径产生方向正确的强电场,同时不会对馈电传输线造成电负荷。所述方法的空间分辨率为 ~1 μm,时间分辨率由激光脉冲持续时间决定。
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引用次数: 0
Short-Term Oxidation of HfB2-SiC Based UHTC in Supersonic Flow of Carbon Dioxide Plasma 基于 HfB2-SiC 的 UHTC 在二氧化碳等离子体超音速流中的短期氧化作用
Pub Date : 2024-04-19 DOI: 10.3390/plasma7020017
A. Chaplygin, E. Simonenko, M. Kotov, Vladimir I. Sakharov, I. Lukomskii, Semen S. Galkin, A. F. Kolesnikov, A. Lysenkov, I. A. Nagornov, A. S. Mokrushin, N. Simonenko, N. T. Kuznetsov, M. Yakimov, A. Shemyakin, N. Solovyov
The short-term (5 min) exposure to the supersonic flow of carbon dioxide plasma on ultrahigh-temperature ceramics of HfB2-30vol.%SiC composition has been studied. It was shown that, when established on the surface at a temperature of 1615–1655 °C, the beginning of the formation of an oxidized layer takes place. Raman spectroscopy and scanning electron microscopy studies showed that the formation of a porous SiC-depleted region is not possible under the HfO2-SiO2 surface oxide layer. Numerical modeling based on the Navier–Stokes equations and experimental probe measurements of the test conditions were performed. The desirability of continuing systematic studies on the behavior of ultrahigh-temperature ZrB2/HfB2-SiC ceramics, including those doped with various components under the influence of high-enthalpy gas flows, was noted.
对 HfB2-30vol.%SiC 超高温陶瓷在超音速二氧化碳等离子体流中的短期(5 分钟)暴露进行了研究。结果表明,当表面温度达到 1615-1655 ℃ 时,氧化层开始形成。拉曼光谱和扫描电子显微镜研究表明,在 HfO2-SiO2 表面氧化层下不可能形成多孔的碳化硅贫化区。研究人员根据纳维-斯托克斯方程建立了数值模型,并对测试条件进行了实验探针测量。指出了继续系统研究超高温 ZrB2/HfB2-SiC 陶瓷(包括在高焓气流影响下掺杂各种成分的陶瓷)行为的可取性。
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引用次数: 0
Recent Developments in the Use of Plasma in Medical Applications 在医疗应用中使用等离子体的最新进展
Pub Date : 2024-04-10 DOI: 10.3390/plasma7020016
Fiona O’Neill, Liam O’Neill, Paula Bourke
A detailed review of the scientific literature was undertaken to examine the most recent developments in plasma processing in the field of medicine. The first part of the review includes a detailed breakdown of the different types of coatings that can be applied onto medical devices using plasma, with a specific focus on antimicrobial surfaces. The developments in plasma-deposited biocompatibles, drug delivery and adhesive coatings in 2023 are described, and specific applications in additive manufacturing are highlighted. The use of plasma and plasma-activated liquids as standalone therapeutics continues to evolve, and pertinent advances in this field are described. In addition, the combination of plasma medicine with conventional pharmaceutical interventions is reviewed, and key emerging trends are highlighted, including the use of plasma to enhance drug delivery directly into tissue. The potential synergies between plasma medicine and chemotherapeutics for oncology and infection treatment are a growing area, and recent advancements are noted. Finally, the use of plasma to control excess antibiotics and to intentionally degrade such materials in waste streams is described.
我们对科学文献进行了详细审查,以研究等离子体处理在医学领域的最新发展。综述的第一部分详细介绍了可利用等离子体应用于医疗设备的不同类型涂层,特别关注抗菌表面。介绍了 2023 年等离子体沉积生物复合材料、给药和粘合涂层的发展情况,并重点介绍了增材制造中的具体应用。等离子体和等离子体活化液体作为独立疗法的应用在不断发展,该领域的相关进展也将得到介绍。此外,还综述了等离子体医学与传统药物干预的结合,并重点介绍了主要的新兴趋势,包括利用等离子体加强直接向组织输送药物。血浆医学与化疗药物在肿瘤和感染治疗方面的潜在协同作用是一个不断增长的领域,最近的进展也有所提及。最后,还介绍了利用等离子体控制过量抗生素和有意降解废物流中的此类物质。
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引用次数: 0
About the Data Analysis of Optical Emission Spectra of Reactive Ion Etching Processes—The Method of Spectral Redundancy Reduction 关于反应离子蚀刻过程的光学发射光谱数据分析--光谱冗余还原法
Pub Date : 2024-03-20 DOI: 10.3390/plasma7010015
Micha Haase, Mudassir Ali Sayyed, Jan Langer, Danny Reuter, Harald Kuhn
In this study, we present the Method of Spectral Redundancy Reduction (MSRR) for analyzing OES (optical emission spectroscopy) data of dry etching processes based on the principles of spectral clustering. To achieve this, the OES data are transformed into abstract graph matrices whose associated eigenvectors directly indicate anomalies in the data set. We developed an approach that allows for the reduction in temporally resolved optical emission spectra from plasma structuring processes in such a way that individual emission lines can be algorithmically detected, which exhibit a temporal behavior different from the collective behavior of the temporally resolved overall spectrum. The proportion of emission lines that behave consistently throughout the entire process duration is not considered. Our work may find applications in which OES is used as a process-monitoring technique, especially for low-pressure plasma processing. The major benefit of the developed method is that the scale of the original data is kept, making physical interpretations possible despite data reductions.
在本研究中,我们介绍了基于光谱聚类原理的光谱冗余减少法(MSRR),用于分析干法蚀刻过程中的 OES(光学发射光谱)数据。为此,我们将 OES 数据转换为抽象图形矩阵,其相关特征向量可直接显示数据集中的异常情况。我们开发了一种方法,可以还原等离子体结构化过程产生的时间分辨光学发射光谱,从而可以通过算法检测到单个发射线,这些发射线的时间行为与时间分辨整体光谱的集体行为不同。我们没有考虑在整个过程中表现一致的发射线比例。我们的工作可能会应用于将 OES 用作过程监控技术,特别是低压等离子体加工。所开发方法的主要优点是保持了原始数据的比例,因此尽管数据有所减少,但仍可进行物理解释。
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引用次数: 0
Cold Atmospheric Plasma Medicine: Applications, Challenges, and Opportunities for Predictive Control 冷大气等离子体医学:预测控制的应用、挑战和机遇
Pub Date : 2024-03-16 DOI: 10.3390/plasma7010014
Ali Kazemi, McKayla J. Nicol, Sven Bilén, Girish S. Kirimanjeswara, Sean D. Knecht
Plasma medicine is an emerging field that applies the science and engineering of physical plasma to biomedical applications. Low-temperature plasma, also known as cold plasma, is generated via the ionization of atoms in a gas, generally via exposure to strong electric fields, and consists of ions, free radicals, and molecules at varying energy states. Plasmas generated at low temperatures (approximately room temperature) have been used for applications in dermatology, oncology, and anti-microbial strategies. Despite current and ongoing clinical use, the exact mechanisms of action and the full range of effects of cold plasma treatment on cells are only just beginning to be understood. Direct and indirect effects of plasma on immune cells have the potential to be utilized for various applications such as immunomodulation, anti-infective therapies, and regulating inflammation. In this review, we combine diverse expertise in the fields of plasma chemistry, device design, and immunobiology to cover the history and current state of plasma medicine, basic plasma chemistry and their implications, the effects of cold atmospheric plasma on host cells with their potential immunological consequences, future directions, and the outlook and recommendations for plasma medicine.
等离子体医学是一个新兴领域,它将物理等离子体的科学和工程应用于生物医学。低温等离子体,也称为冷等离子体,是通过气体中原子的电离产生的,通常是通过暴露在强电场中产生的,由不同能量状态的离子、自由基和分子组成。在低温(约室温)下产生的等离子体已被用于皮肤病学、肿瘤学和抗微生物策略。尽管目前正在进行临床应用,但人们对冷等离子体处理的确切作用机制和对细胞的全面影响才刚刚开始了解。血浆对免疫细胞的直接和间接影响有可能被用于各种用途,如免疫调节、抗感染治疗和调节炎症。在这篇综述中,我们结合了等离子体化学、设备设计和免疫生物学领域的各种专业知识,介绍了等离子体医学的历史和现状、基本等离子体化学及其影响、冷大气等离子体对宿主细胞的影响及其潜在的免疫学后果、未来发展方向以及等离子体医学的前景和建议。
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引用次数: 0
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