首页 > 最新文献

Plasma最新文献

英文 中文
Optimal Conditions for the Generation of Runaway Electrons in High-Pressure Gases 高压气体中产生失控电子的最佳条件
Pub Date : 2024-03-15 DOI: 10.3390/plasma7010013
A. Kozyrev, V. Tarasenko
Runaway electron (RAE) generation in high-pressure gases is an important physical phenomenon that significantly influences discharge shapes and properties of initiated plasma. The diffuse discharges formed due to RAEs in the air and other gases at atmospheric pressure find wide applications. In the present review, theoretical and experimental results that explain the reason for RAE occurrence at high pressures are analyzed, and recommendations are given for the implementation of conditions under which the runaway electron beam (RAEB) with the highest current can be obtained at atmospheric pressure. The experimental results were obtained using subnanosecond, nanosecond, and submicrosecond generators, including those specially developed for runaway electron generation. The RAEBs were recorded using oscilloscopes and collectors with picosecond time resolution. To theoretically describe the phenomenon of continuous electron acceleration, the method of physical kinetics was used based on the Boltzmann kinetic equation that takes into account the minimum but sufficient number of elementary processes, including shock gas ionization and elastic electron scattering. The results of modeling allowed the main factors to be established that control the RAE appearance, the most important of which is electron scattering on neutral atoms and/or molecules. Theoretical modeling has allowed the influence of various parameters (including the voltage, pressure, gas type, and geometrical characteristics of the discharge gap) to be taken into account. The results of the research presented here allow RAE accelerators with desirable parameters to be developed and the possibility of obtaining diffuse discharges to be accessed under various conditions. The review consists of the Introduction, five sections, the Conclusion, and the References.
高压气体中产生的失控电子(RAE)是一种重要的物理现象,对放电形状和引发等离子体的特性有很大影响。在大气压下的空气和其他气体中,由失控电子形成的扩散放电得到了广泛的应用。在本综述中,分析了解释高压下发生 RAE 的原因的理论和实验结果,并就在大气压下获得最大电流的失控电子束(RAEB)的实施条件提出了建议。实验结果是使用亚纳秒、纳秒和亚微秒发生器(包括专门为失控电子发生而开发的发生器)获得的。使用示波器和具有皮秒时间分辨率的收集器记录了 RAEB。为了从理论上描述连续电子加速现象,使用了基于波尔兹曼动力学方程的物理动力学方法,该方程考虑了最少但足够数量的基本过程,包括冲击气体电离和弹性电子散射。建模结果确定了控制 RAE 出现的主要因素,其中最重要的是电子对中性原子和/或分子的散射。理论建模考虑到了各种参数(包括电压、压力、气体类型和放电间隙的几何特征)的影响。本文介绍的研究成果可以开发出具有理想参数的 RAE 加速器,并在各种条件下获得扩散放电的可能性。综述包括导言、五个部分、结论和参考文献。
{"title":"Optimal Conditions for the Generation of Runaway Electrons in High-Pressure Gases","authors":"A. Kozyrev, V. Tarasenko","doi":"10.3390/plasma7010013","DOIUrl":"https://doi.org/10.3390/plasma7010013","url":null,"abstract":"Runaway electron (RAE) generation in high-pressure gases is an important physical phenomenon that significantly influences discharge shapes and properties of initiated plasma. The diffuse discharges formed due to RAEs in the air and other gases at atmospheric pressure find wide applications. In the present review, theoretical and experimental results that explain the reason for RAE occurrence at high pressures are analyzed, and recommendations are given for the implementation of conditions under which the runaway electron beam (RAEB) with the highest current can be obtained at atmospheric pressure. The experimental results were obtained using subnanosecond, nanosecond, and submicrosecond generators, including those specially developed for runaway electron generation. The RAEBs were recorded using oscilloscopes and collectors with picosecond time resolution. To theoretically describe the phenomenon of continuous electron acceleration, the method of physical kinetics was used based on the Boltzmann kinetic equation that takes into account the minimum but sufficient number of elementary processes, including shock gas ionization and elastic electron scattering. The results of modeling allowed the main factors to be established that control the RAE appearance, the most important of which is electron scattering on neutral atoms and/or molecules. Theoretical modeling has allowed the influence of various parameters (including the voltage, pressure, gas type, and geometrical characteristics of the discharge gap) to be taken into account. The results of the research presented here allow RAE accelerators with desirable parameters to be developed and the possibility of obtaining diffuse discharges to be accessed under various conditions. The review consists of the Introduction, five sections, the Conclusion, and the References.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"58 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140237408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Practical Model for the Calculation of Lateral Electromagnetic Loads in Tokamaks at Asymmetric Vertical Displacement Events (AVDEs) 非对称垂直位移事件 (AVDE) 时托卡马克侧向电磁载荷的实用计算模型
Pub Date : 2024-03-13 DOI: 10.3390/plasma7010012
Sergey Sadakov, F. Villone, Daniel Iglesias, Luis Maqueda, Jesus Almenara-Rescalvo, G. Rubinacci, S. Ventre
This paper describes a new practical numerical model for the calculation of lateral electromagnetic (EM) loads in tokamaks during asymmetric vertical displacement events (AVDEs). The model combines key features of two recently reported trial models while avoiding their drawbacks. Their common basic feature is the superposition of two patterns of halo current: one perfectly symmetric and another perfectly anti-symmetric. This model combines the following features that have not been combined before (a) a helically distorted halo layer wrapping around core plasma, and (b) halo-to-wall interception belts slipping along plasma-facing walls. This combination almost doubles the lateral net forces. An AVDE creates significant lateral net moments. Being relatively modest at VDEs, the lateral moments become a dominant component of EM loads at AVDEs. The model carefully tracks the balance of net EM loads (zero total for the tokamak), as a necessary condition for the consequent numerical simulation of the tokamak’s dynamic response. This balance is needed as well for the development of tokamak monitoring algorithms and simulators. In order to decouple from the current uncertainties in the interpretation and simulation of AVDE physics, the model does not simulate AVDE evolution but uses it as an input assumption based on the existing interpretation and simulation of AVDE physics. This means the model is to be used in a manner of parametric study, at widely varied input assumptions on AVDE evolution and severity. Parametric results will fill a library of ready-for-use waveforms of asymmetric EM loads (distributed and total) at tokamak structures and coils, so that the physics community may point to specific variants for subsequent engineering analysis. This article presents the first practical contribution to this AVDE library.
本文介绍了一种新的实用数值模型,用于计算非对称垂直位移事件(AVDE)期间托卡马克中的横向电磁(EM)载荷。该模型结合了最近报道的两个试验模型的主要特点,同时避免了它们的缺点。它们的共同基本特征是两种晕流模式的叠加:一种是完全对称模式,另一种是完全反对称模式。该模型结合了以下以前从未结合过的特征:(a)螺旋扭曲的晕层包裹着核心等离子体;(b)晕壁拦截带沿着等离子体面壁滑动。这种组合几乎使侧向净力增加了一倍。AVDE 会产生巨大的侧向净力矩。在 VDEs 时,横向力矩相对较小,而在 AVDEs 时,横向力矩成为电磁载荷的主要组成部分。该模型仔细跟踪了净电磁载荷的平衡(托卡马克的总载荷为零),这是随后对托卡马克动态响应进行数值模拟的必要条件。开发托卡马克监测算法和模拟器也需要这种平衡。为了与当前 AVDE 物理解释和模拟中的不确定性脱钩,该模型并不模拟 AVDE 的演变,而是将其作为基于现有 AVDE 物理解释和模拟的输入假设。这意味着该模型将以参数研究的方式,在对 AVDE 演化和严重程度的不同输入假设下使用。参数化结果将为托卡马克结构和线圈的非对称电磁载荷(分布式和总计式)提供一个随时可用的波形库,这样物理学界就可以为后续的工程分析指出特定的变体。本文是对该 AVDE 库的首次实际贡献。
{"title":"Practical Model for the Calculation of Lateral Electromagnetic Loads in Tokamaks at Asymmetric Vertical Displacement Events (AVDEs)","authors":"Sergey Sadakov, F. Villone, Daniel Iglesias, Luis Maqueda, Jesus Almenara-Rescalvo, G. Rubinacci, S. Ventre","doi":"10.3390/plasma7010012","DOIUrl":"https://doi.org/10.3390/plasma7010012","url":null,"abstract":"This paper describes a new practical numerical model for the calculation of lateral electromagnetic (EM) loads in tokamaks during asymmetric vertical displacement events (AVDEs). The model combines key features of two recently reported trial models while avoiding their drawbacks. Their common basic feature is the superposition of two patterns of halo current: one perfectly symmetric and another perfectly anti-symmetric. This model combines the following features that have not been combined before (a) a helically distorted halo layer wrapping around core plasma, and (b) halo-to-wall interception belts slipping along plasma-facing walls. This combination almost doubles the lateral net forces. An AVDE creates significant lateral net moments. Being relatively modest at VDEs, the lateral moments become a dominant component of EM loads at AVDEs. The model carefully tracks the balance of net EM loads (zero total for the tokamak), as a necessary condition for the consequent numerical simulation of the tokamak’s dynamic response. This balance is needed as well for the development of tokamak monitoring algorithms and simulators. In order to decouple from the current uncertainties in the interpretation and simulation of AVDE physics, the model does not simulate AVDE evolution but uses it as an input assumption based on the existing interpretation and simulation of AVDE physics. This means the model is to be used in a manner of parametric study, at widely varied input assumptions on AVDE evolution and severity. Parametric results will fill a library of ready-for-use waveforms of asymmetric EM loads (distributed and total) at tokamak structures and coils, so that the physics community may point to specific variants for subsequent engineering analysis. This article presents the first practical contribution to this AVDE library.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"5 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140248294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plasma-Driven Sciences: Exploring Complex Interactions at Plasma Boundaries 等离子体驱动科学:探索等离子体边界的复杂相互作用
Pub Date : 2024-02-27 DOI: 10.3390/plasma7010011
K. Ishikawa, K. Koga, Noriyasu Ohno
Plasma-driven science is defined as the artificial control of physical plasma-driven phenomena based on complex interactions between nonequilibrium open systems. Recently, peculiar phenomena related to physical plasma have been discovered in plasma boundary regions, either naturally or artificially. Because laboratory plasma can be produced under nominal conditions around atmospheric pressure and room temperature, phenomena related to the interaction of plasma with liquid solutions and living organisms at the plasma boundaries are emerging. Currently, the relationships between these complex interactions should be solved using science-based data-driven approaches; these approaches require a reliable and comprehensive database of dynamic changes in the chemical networks of elementary reactions. Consequently, the elucidation of the mechanisms governing plasma-driven phenomena and the discovery of the latent actions behind these plasma-driven phenomena will be realized through plasma-driven science.
等离子体驱动科学的定义是,基于非平衡开放系统之间复杂的相互作用,对物理等离子体驱动现象进行人工控制。最近,人们在等离子体边界区域发现了与物理等离子体有关的自然或人工奇特现象。由于实验室等离子体可在大气压和室温左右的额定条件下产生,等离子体与液态溶液和生物体在等离子体边界的相互作用现象正在出现。目前,这些复杂的相互作用之间的关系应采用以科学为基础的数据驱动方法来解决;这些方法需要一个可靠而全面的基本反应化学网络动态变化数据库。因此,阐明等离子体驱动现象的机理和发现这些等离子体驱动现象背后的潜在作用将通过等离子体驱动科学来实现。
{"title":"Plasma-Driven Sciences: Exploring Complex Interactions at Plasma Boundaries","authors":"K. Ishikawa, K. Koga, Noriyasu Ohno","doi":"10.3390/plasma7010011","DOIUrl":"https://doi.org/10.3390/plasma7010011","url":null,"abstract":"Plasma-driven science is defined as the artificial control of physical plasma-driven phenomena based on complex interactions between nonequilibrium open systems. Recently, peculiar phenomena related to physical plasma have been discovered in plasma boundary regions, either naturally or artificially. Because laboratory plasma can be produced under nominal conditions around atmospheric pressure and room temperature, phenomena related to the interaction of plasma with liquid solutions and living organisms at the plasma boundaries are emerging. Currently, the relationships between these complex interactions should be solved using science-based data-driven approaches; these approaches require a reliable and comprehensive database of dynamic changes in the chemical networks of elementary reactions. Consequently, the elucidation of the mechanisms governing plasma-driven phenomena and the discovery of the latent actions behind these plasma-driven phenomena will be realized through plasma-driven science.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"14 11","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140424643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Physical Metric for Inertial Confinement Fusion Capsules 惯性约束聚变舱的物理度量标准
Pub Date : 2024-02-21 DOI: 10.3390/plasma7010010
B. Cheng, Paul A. Bradley
The performance of fusion capsules on the National Ignition Facility (NIF) is strongly affected by the physical properties of the hot deuterium–tritium (DT) fuel, such as the mass, areal density, and pressure of the hot spot at the stagnation time. All of these critical quantities depend on one measured quantity, which is the ratio of the specific peak implosion energy to the specific internal energy of the hot spot. This unique physical quantity not only can measure the incremental progress of the inertial confinement fusion capsules towards ignition but also measures the conversion of the peak implosion kinetic energy of the pusher shell into the internal energy of the hot fuel in a capsule. Analysis of existing NIF shots to date are performed. The ratio metric is compared quantitatively with the ignition criterion. Results provide new perspectives on the NIF experiments by which the performance of the burning plasma can be determined and controlled through the fine tune of the implosion parameters, which improves future designs and predictions of the ignition capsules.
国家点火装置(NIF)上核聚变舱的性能受到热氘氚燃料(DT)物理性质的强烈影响,例如停滞时热点的质量、等密度和压力。所有这些临界量都取决于一个测量量,即特定内爆峰值能量与热点特定内能之比。这个独特的物理量不仅可以测量惯性约束聚变胶囊在点火过程中的增量,还可以测量推壳的内爆动能峰值转化为胶囊中热燃料内能的情况。对迄今为止现有的 NIF 发射进行了分析。将比值指标与点火标准进行了定量比较。结果为 NIF 实验提供了新的视角,通过微调内爆参数可以确定和控制燃烧等离子体的性能,从而改进点火胶囊的未来设计和预测。
{"title":"A Physical Metric for Inertial Confinement Fusion Capsules","authors":"B. Cheng, Paul A. Bradley","doi":"10.3390/plasma7010010","DOIUrl":"https://doi.org/10.3390/plasma7010010","url":null,"abstract":"The performance of fusion capsules on the National Ignition Facility (NIF) is strongly affected by the physical properties of the hot deuterium–tritium (DT) fuel, such as the mass, areal density, and pressure of the hot spot at the stagnation time. All of these critical quantities depend on one measured quantity, which is the ratio of the specific peak implosion energy to the specific internal energy of the hot spot. This unique physical quantity not only can measure the incremental progress of the inertial confinement fusion capsules towards ignition but also measures the conversion of the peak implosion kinetic energy of the pusher shell into the internal energy of the hot fuel in a capsule. Analysis of existing NIF shots to date are performed. The ratio metric is compared quantitatively with the ignition criterion. Results provide new perspectives on the NIF experiments by which the performance of the burning plasma can be determined and controlled through the fine tune of the implosion parameters, which improves future designs and predictions of the ignition capsules.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"21 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140444848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rapid Access to Empirical Impact Ionization Cross Sections for Atoms and Ions across the Periodic Table 快速获取元素周期表中原子和离子的经验撞击电离截面
Pub Date : 2024-01-30 DOI: 10.3390/plasma7010008
S. Fritzsche, Liguang Jiao, Giorgio Visentin
Electron-impact ionization (EII) processes are essential for modelling high-temperature plasma in quite different research areas, from astrophysics to material science to plasma and fusion research and in several places elsewhere. In most, if not all, of these fields, partial and total EII cross sections are required, and often for a good range of electron energies, in order to determine, for instance, the level population of ions and spectral line intensities in plasma under both local and non-local thermodynamic equilibrium conditions. To obey these needs, various kinds of semi-empirical EII cross sections have been applied in practice, often simply because of the large computational demands in dealing explicitly with two free electrons within the continuum. Here, we expand Jac, the Jena Atomic Calculator, to provide such empirical EII cross sections for (most) atoms and ions across the periodic table. Five empirical models from the recent literature have been implemented to support a simple and rapid access to the partial EII cross sections for electrons from a (partly filled) shell (nℓ)q as well as the total ionization cross sections. We here restrict ourselves to the direct part of the EII cross section, whereas the impact excitation of electrons with subsequent autoionization and the resonant electron capture with double autoionization have been left aside in this first implementation. Rapid access to the (direct) EII cross sections will help already to better understand the role of electron-impact processes in the diagnostics of fusion plasma or the interpretation of astrophysical spectra.
电子撞击电离(EII)过程对于不同研究领域的高温等离子体建模至关重要,这些领域包括天体物理学、材料科学、等离子体和核聚变研究以及其他一些领域。在这些领域中的大多数(如果不是全部的话),都需要部分和总的 EII 截面,而且往往是在相当大的电子能量范围内,以便在局部和非局部热力学平衡条件下确定等离子体中的离子水平群和光谱线强度等。为了满足这些需求,在实践中应用了各种半经验 EII 截面,这通常只是因为明确处理连续体中的两个自由电子需要大量计算。在这里,我们扩展了耶拿原子计算器 Jac,为周期表中的(大多数)原子和离子提供这种经验 EII 截面。我们采用了近期文献中的五个经验模型,以支持简单快速地获取来自(部分填充)外壳 (nℓ)q 的电子的部分 EII 截面以及总电离截面。我们在这里只讨论 EII 截面的直接部分,而电子的撞击激发和随后的自电离以及共振电子俘获和双重自电离在首次实现中都被搁置了。快速获取(直接)EII 截面将有助于更好地理解电子撞击过程在核聚变等离子体诊断或天体物理光谱解释中的作用。
{"title":"Rapid Access to Empirical Impact Ionization Cross Sections for Atoms and Ions across the Periodic Table","authors":"S. Fritzsche, Liguang Jiao, Giorgio Visentin","doi":"10.3390/plasma7010008","DOIUrl":"https://doi.org/10.3390/plasma7010008","url":null,"abstract":"Electron-impact ionization (EII) processes are essential for modelling high-temperature plasma in quite different research areas, from astrophysics to material science to plasma and fusion research and in several places elsewhere. In most, if not all, of these fields, partial and total EII cross sections are required, and often for a good range of electron energies, in order to determine, for instance, the level population of ions and spectral line intensities in plasma under both local and non-local thermodynamic equilibrium conditions. To obey these needs, various kinds of semi-empirical EII cross sections have been applied in practice, often simply because of the large computational demands in dealing explicitly with two free electrons within the continuum. Here, we expand Jac, the Jena Atomic Calculator, to provide such empirical EII cross sections for (most) atoms and ions across the periodic table. Five empirical models from the recent literature have been implemented to support a simple and rapid access to the partial EII cross sections for electrons from a (partly filled) shell (nℓ)q as well as the total ionization cross sections. We here restrict ourselves to the direct part of the EII cross section, whereas the impact excitation of electrons with subsequent autoionization and the resonant electron capture with double autoionization have been left aside in this first implementation. Rapid access to the (direct) EII cross sections will help already to better understand the role of electron-impact processes in the diagnostics of fusion plasma or the interpretation of astrophysical spectra.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"134 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140483307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plasma Treatment of Different Biodegradable Polymers: A Method to Enhance Wettability and Adhesion Properties for Use in Industrial Packaging 不同生物可降解聚合物的等离子处理:增强工业包装中的润湿性和粘合性的方法
Pub Date : 2024-01-26 DOI: 10.3390/plasma7010007
E. Vassallo, M. Pedroni, Marco Aloisio, Silvia Maria Pietralunga, Riccardo Donnini, F. Saitta, Dimitrios Fessas
Biodegradable polymers (poly(butylene succinate (PBS)), poly(butylene adipate terephthalate (PBAT)) and poly(lactic acid)/poly(butylene adipate terephthalate (PLA/PBAT)) blend) were treated in radiofrequency (13.56 MHz) low-pressure (10 Pa) oxygen with argon post-crosslinking plasma to enhance wettability and adhesion properties. Surface morphology and roughness modification caused by plasma exposure were observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Surface chemical modifications of plasma-treated samples were evaluated by Fourier Transform infrared spectroscopy (FTIR). Due to the limited durability of plasma activation, the hydrophobic recovery was evaluated by water contact angle (WCA) measurements. The ageing effect was measured over 15 days in order to assess this kind of treatment as a potential industrial scalable method to increase biodegradable polymers hydrophilic properties for food packaging applications. The effects of polymer activation on its weight loss were also determined. Differential scanning calorimetry (DSC) analysis was used to study the effect of plasma treatment on the thermal properties of the polymers, while the crystallinity was investigated by X-ray diffraction (XRD).
在射频(13.56 MHz)低压(10 Pa)氧气与氩气交联后等离子体中处理可生物降解聚合物(聚丁二酸丁二醇酯(PBS)、聚己二酸丁二醇酯(PBAT)和聚乳酸/聚己二酸丁二醇酯(PLA/PBAT)混合物),以增强其润湿性和粘附性。通过扫描电子显微镜(SEM)和原子力显微镜(AFM)观察了等离子曝光引起的表面形貌和粗糙度改变。傅立叶变换红外光谱(FTIR)对等离子体处理过的样品的表面化学改性进行了评估。由于等离子活化的持久性有限,疏水性的恢复通过水接触角(WCA)测量进行评估。对 15 天的老化效果进行了测量,以评估这种处理方法是否可作为一种潜在的工业扩展方法,增加可生物降解聚合物在食品包装应用中的亲水性能。此外,还测定了聚合物活化对其失重的影响。差示扫描量热法(DSC)分析用于研究等离子处理对聚合物热性能的影响,而结晶度则通过 X 射线衍射(XRD)进行了研究。
{"title":"Plasma Treatment of Different Biodegradable Polymers: A Method to Enhance Wettability and Adhesion Properties for Use in Industrial Packaging","authors":"E. Vassallo, M. Pedroni, Marco Aloisio, Silvia Maria Pietralunga, Riccardo Donnini, F. Saitta, Dimitrios Fessas","doi":"10.3390/plasma7010007","DOIUrl":"https://doi.org/10.3390/plasma7010007","url":null,"abstract":"Biodegradable polymers (poly(butylene succinate (PBS)), poly(butylene adipate terephthalate (PBAT)) and poly(lactic acid)/poly(butylene adipate terephthalate (PLA/PBAT)) blend) were treated in radiofrequency (13.56 MHz) low-pressure (10 Pa) oxygen with argon post-crosslinking plasma to enhance wettability and adhesion properties. Surface morphology and roughness modification caused by plasma exposure were observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Surface chemical modifications of plasma-treated samples were evaluated by Fourier Transform infrared spectroscopy (FTIR). Due to the limited durability of plasma activation, the hydrophobic recovery was evaluated by water contact angle (WCA) measurements. The ageing effect was measured over 15 days in order to assess this kind of treatment as a potential industrial scalable method to increase biodegradable polymers hydrophilic properties for food packaging applications. The effects of polymer activation on its weight loss were also determined. Differential scanning calorimetry (DSC) analysis was used to study the effect of plasma treatment on the thermal properties of the polymers, while the crystallinity was investigated by X-ray diffraction (XRD).","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"75 6-7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140494392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal Plasma Spheroidization and Characterization of Stainless Steel Powders Using Direct Current Plasma Technology 利用直流等离子体技术对不锈钢粉末进行热等离子体球化和表征
Pub Date : 2024-01-23 DOI: 10.3390/plasma7010006
P. Iovane, C. Borriello, Giuseppe Pandolfi, S. Portofino, Gabriella Rametta, Loredana Tammaro, Nicola Fedele, S. Galvagno
The production of spherical powders has recently registered a boost due to the need to fabricate new printing materials for Additive Manufacturing applications, from polymers and resins to metals and ceramics. Among these materials, stainless steels powders play a leading role, since they are widely used in industry and everyday life; indeed, micron-sized spherical stainless steel powders have specific characteristics and are considered as one of the best candidates for Additive Manufacturing systems and for application in a wide range of sectors. In this paper, stainless steel 316 L powders were used to explore and identify the best process parameters of a thermal plasma process able to produce spherical powders for Additive Manufacturing applications. X-ray Diffraction, Scanning Electron Microscopy, Particle Size Distribution and Flowability analysis were performed to characterize reagents and products. Powders with a high circularity (>0.8) and improved flowability (<30 s/50 g) were successfully obtained. The collected results were compared with data available from the literature to identify the potential use of the spherical produced powders.
由于需要为快速成型制造应用制造从聚合物和树脂到金属和陶瓷的新型打印材料,球形粉末的生产最近得到了迅猛发展。在这些材料中,不锈钢粉末起着主导作用,因为它们被广泛应用于工业和日常生活中;事实上,微米大小的球形不锈钢粉末具有特殊的特性,被认为是增材制造系统的最佳候选材料之一,可广泛应用于各个领域。本文使用 316 L 不锈钢粉末来探索和确定热等离子工艺的最佳工艺参数,该工艺能够为快速成型制造应用生产球形粉末。对试剂和产品进行了 X 射线衍射、扫描电子显微镜、粒度分布和流动性分析。成功获得了圆度高(>0.8)、流动性更好(<30 s/50 g)的粉末。收集的结果与文献中的数据进行了比较,以确定球形粉末的潜在用途。
{"title":"Thermal Plasma Spheroidization and Characterization of Stainless Steel Powders Using Direct Current Plasma Technology","authors":"P. Iovane, C. Borriello, Giuseppe Pandolfi, S. Portofino, Gabriella Rametta, Loredana Tammaro, Nicola Fedele, S. Galvagno","doi":"10.3390/plasma7010006","DOIUrl":"https://doi.org/10.3390/plasma7010006","url":null,"abstract":"The production of spherical powders has recently registered a boost due to the need to fabricate new printing materials for Additive Manufacturing applications, from polymers and resins to metals and ceramics. Among these materials, stainless steels powders play a leading role, since they are widely used in industry and everyday life; indeed, micron-sized spherical stainless steel powders have specific characteristics and are considered as one of the best candidates for Additive Manufacturing systems and for application in a wide range of sectors. In this paper, stainless steel 316 L powders were used to explore and identify the best process parameters of a thermal plasma process able to produce spherical powders for Additive Manufacturing applications. X-ray Diffraction, Scanning Electron Microscopy, Particle Size Distribution and Flowability analysis were performed to characterize reagents and products. Powders with a high circularity (>0.8) and improved flowability (<30 s/50 g) were successfully obtained. The collected results were compared with data available from the literature to identify the potential use of the spherical produced powders.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"9 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139604355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spatial Distribution Analyses of Axially Long Plasmas under a Multi-Cusp Magnetic Field Using a Kinetic Particle Simulation Code KEIO-MARC 利用动力学粒子模拟代码 KEIO-MARC 分析多尖顶磁场下轴向长等离子体的空间分布情况
Pub Date : 2024-01-22 DOI: 10.3390/plasma7010005
Ryota Nishimura, T. Seino, Keigo Yoshimura, Hiroyuki Takahashi, Akinobu Matsuyama, Kazuo Hoshino, Tetsutarou Oishi, Kenji Tobita
To realize the development of a long plasma source with a uniform electron density distribution in the axial direction, the spatial distribution of plasma under a multi-cusp magnetic field was analyzed using a KEIO-MARC code. Considering a cylindrical plasma source with an axial length of 3000 mm and a cross-sectional diameter of 100 mm, in which the filament electrode was the electron source, the electron density distribution was calculated using the residual magnetic flux density, Bres, and the number of permanent magnets installed at different locations surrounding the device, Nmag, as design parameters. The results show that both Bres and Nmag improved the uniformity of the electron density distribution in the axial direction. The maximum axial electron density decreased with increasing Nmag and increased with increasing Bres. These trends can be explained by considering the nature of the multi-cusp field, where particles are mainly confined to the field-free region (FFR) near the center of the plasma column, and the loss of particles due to radial particle transport. The use of multiple filaments at intervals shorter than the plasma decay length dramatically improved axial uniformity. To further improve axial uniformity, the filament length and FFR must be properly set so that electrons are emitted inside the FFR.
为了开发轴向电子密度分布均匀的长等离子体源,我们使用 KEIO-MARC 代码分析了多尖角磁场下等离子体的空间分布。以一个轴向长度为3000毫米、横截面直径为100毫米的圆柱形等离子体源(其中灯丝电极为电子源)为例,以残余磁通密度Bres和装置周围不同位置安装的永久磁铁数量Nmag为设计参数,计算了电子密度分布。结果表明,Bres 和 Nmag 都改善了轴向电子密度分布的均匀性。最大轴向电子密度随着 Nmag 的增加而降低,随着 Bres 的增加而升高。考虑到多尖锥场的性质(粒子主要被限制在等离子体柱中心附近的无场区(FFR))以及粒子径向传输造成的粒子损失,可以解释这些趋势。使用间隔短于等离子体衰变长度的多丝可显著改善轴向均匀性。为了进一步提高轴向均匀性,必须适当设置灯丝长度和 FFR,以便电子在 FFR 内发射。
{"title":"Spatial Distribution Analyses of Axially Long Plasmas under a Multi-Cusp Magnetic Field Using a Kinetic Particle Simulation Code KEIO-MARC","authors":"Ryota Nishimura, T. Seino, Keigo Yoshimura, Hiroyuki Takahashi, Akinobu Matsuyama, Kazuo Hoshino, Tetsutarou Oishi, Kenji Tobita","doi":"10.3390/plasma7010005","DOIUrl":"https://doi.org/10.3390/plasma7010005","url":null,"abstract":"To realize the development of a long plasma source with a uniform electron density distribution in the axial direction, the spatial distribution of plasma under a multi-cusp magnetic field was analyzed using a KEIO-MARC code. Considering a cylindrical plasma source with an axial length of 3000 mm and a cross-sectional diameter of 100 mm, in which the filament electrode was the electron source, the electron density distribution was calculated using the residual magnetic flux density, Bres, and the number of permanent magnets installed at different locations surrounding the device, Nmag, as design parameters. The results show that both Bres and Nmag improved the uniformity of the electron density distribution in the axial direction. The maximum axial electron density decreased with increasing Nmag and increased with increasing Bres. These trends can be explained by considering the nature of the multi-cusp field, where particles are mainly confined to the field-free region (FFR) near the center of the plasma column, and the loss of particles due to radial particle transport. The use of multiple filaments at intervals shorter than the plasma decay length dramatically improved axial uniformity. To further improve axial uniformity, the filament length and FFR must be properly set so that electrons are emitted inside the FFR.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"26 19","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139608930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water 空气中与聚苯乙烯(PS)/水接触的纳秒放电引起的聚苯乙烯(PS)降解
Pub Date : 2024-01-16 DOI: 10.3390/plasma7010004
Aurélie Zamo, Catherine Rond, A. Hamdan
Water pollution with microplastics has become a significant concern. Conventional treatment methods have proven ineffective, and alternatives are being explored. Herein, we assess the degradation efficiency of polystyrene (PS) by measuring its nanosecond discharge in air in contact with water. Its discharge is characterized during processing, and a transition from streamer-like to spark-like discharge occurs due to the increased electrical conductivity of water. Experiments are conducted at different frequencies, and the highest degradation is achieved at 10 kHz; an 83% polystyrene weight loss is recorded after 5 min of processing. The optical spectra of the discharge show no evidence of C-species, and an FTIR analysis of the processed polystyrene reveals no structural modifications. An NMR analysis shows the presence of ethylbenzene in water. Finally, a mechanism of PS degradation is proposed.
微塑料造成的水污染已成为一个重大问题。传统的处理方法已被证明无效,人们正在探索替代方法。在这里,我们通过测量聚苯乙烯(PS)在空气中与水接触时的纳秒级放电来评估其降解效率。在加工过程中,由于水的导电性增强,聚苯乙烯的放电会从流线型过渡到火花型。实验在不同频率下进行,在 10 千赫时降解程度最高;处理 5 分钟后记录到聚苯乙烯重量减少 83%。放电的光学光谱显示没有 C 种的迹象,对处理过的聚苯乙烯进行的傅立叶变换红外分析显示没有结构改变。核磁共振分析显示水中存在乙苯。最后,提出了聚苯乙烯降解的机理。
{"title":"Polystyrene (PS) Degradation Induced by Nanosecond Electric Discharge in Air in Contact with PS/Water","authors":"Aurélie Zamo, Catherine Rond, A. Hamdan","doi":"10.3390/plasma7010004","DOIUrl":"https://doi.org/10.3390/plasma7010004","url":null,"abstract":"Water pollution with microplastics has become a significant concern. Conventional treatment methods have proven ineffective, and alternatives are being explored. Herein, we assess the degradation efficiency of polystyrene (PS) by measuring its nanosecond discharge in air in contact with water. Its discharge is characterized during processing, and a transition from streamer-like to spark-like discharge occurs due to the increased electrical conductivity of water. Experiments are conducted at different frequencies, and the highest degradation is achieved at 10 kHz; an 83% polystyrene weight loss is recorded after 5 min of processing. The optical spectra of the discharge show no evidence of C-species, and an FTIR analysis of the processed polystyrene reveals no structural modifications. An NMR analysis shows the presence of ethylbenzene in water. Finally, a mechanism of PS degradation is proposed.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":" 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139618602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Tutorial on the One-Dimensional Theory of Electron-Beam Space-Charge Effect and Steady-State Virtual Cathode 电子束空间电荷效应和稳态虚拟阴极的一维理论教程
Pub Date : 2024-01-05 DOI: 10.3390/plasma7010003
Weihua Jiang
The space-charge effects of pulsed high-current electron beams are very important to high-power particle beam accelerators and high-power microwave devices. The related physical phenomena have been studied for decades, and a large number of informative publications can be found in numerous scientific journals over many years. This review article is aimed at systematically summarizing most of the previous findings in a logical manner. Using a normalized one-dimensional mathematical model, analytical solutions have been obtained for the space-charge-limited current of both planar diode and drifting space. In addition, in the case of a beam current higher than the space-charge-limited current, the virtual cathode behavior and beam current reflection are quantitively studied. Furthermore, the criteria of steady-state virtual cathode formation are investigated, which leads to the physical understanding of the unstable nature of the virtual cathode. This review article is expected to serve as an integrated source of related information for young researchers and students working on high-power microwaves and pulsed particle beams.
脉冲大电流电子束的空间电荷效应对大功率粒子束加速器和大功率微波设备非常重要。对相关物理现象的研究已有数十年历史,多年来在众多科学杂志上发表了大量翔实的文章。这篇综述文章旨在以逻辑的方式系统地总结之前的大部分研究成果。通过归一化一维数学模型,我们获得了平面二极管和漂移空间的空间电荷限制电流的解析解。此外,在束流大于空间电荷限制电流的情况下,对虚拟阴极行为和束流反射进行了定量研究。此外,还研究了稳态虚拟阴极形成的标准,从而从物理角度理解了虚拟阴极的不稳定性。这篇综述文章有望成为从事高功率微波和脉冲粒子束研究的年轻研究人员和学生的相关信息综合来源。
{"title":"A Tutorial on the One-Dimensional Theory of Electron-Beam Space-Charge Effect and Steady-State Virtual Cathode","authors":"Weihua Jiang","doi":"10.3390/plasma7010003","DOIUrl":"https://doi.org/10.3390/plasma7010003","url":null,"abstract":"The space-charge effects of pulsed high-current electron beams are very important to high-power particle beam accelerators and high-power microwave devices. The related physical phenomena have been studied for decades, and a large number of informative publications can be found in numerous scientific journals over many years. This review article is aimed at systematically summarizing most of the previous findings in a logical manner. Using a normalized one-dimensional mathematical model, analytical solutions have been obtained for the space-charge-limited current of both planar diode and drifting space. In addition, in the case of a beam current higher than the space-charge-limited current, the virtual cathode behavior and beam current reflection are quantitively studied. Furthermore, the criteria of steady-state virtual cathode formation are investigated, which leads to the physical understanding of the unstable nature of the virtual cathode. This review article is expected to serve as an integrated source of related information for young researchers and students working on high-power microwaves and pulsed particle beams.","PeriodicalId":509984,"journal":{"name":"Plasma","volume":"26 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139383736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Plasma
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1