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Protein recovery from sweet potato starch wastewater using modified chitosan 改性壳聚糖回收甘薯淀粉废水中的蛋白质
IF 1.2 Q4 WATER RESOURCES Pub Date : 2022-03-08 DOI: 10.1080/23249676.2022.2031321
T. Karchiyappan, Rekha Pachaiappan
This study reports an effective method to explore the significant role of modified chitosan in recovering a protein from starch wastewater of sweet potato. Fourier transform infrared (FT-IR) spectroscopy, energy dispersive X-ray analysis (EDX), polarizing optical microscopy (POM), and scanning electron microscope analysis (SEM) are used to characterize modified chitosan. Parameters, such as agitation time, chitosan dose, initial pH, and settling time, are monitored over the protein recovery process. Also, the second-order polynomial model was developed with Box Behnken design (BBD). 3-D response surface contour graphs are plotted to learn about the interactive effects of process parameters on protein recovery. The optimum operating conditions are determined by using the desired function methodology. Under these optimal conditions, 95% of the protein was recovered. An artificial neural network (ANN)-based model was developed for simulating protein recovery. Electrophoresis analysis has shown that recovered protein can be used as livestock feed ingredients.
本研究报道了一种有效的方法来探索改性壳聚糖在从甘薯淀粉废水中回收蛋白质中的重要作用。利用傅立叶变换红外光谱(FT-IR)、能量色散X射线分析(EDX)、偏振光学显微镜(POM)和扫描电子显微镜(SEM)对改性壳聚糖进行了表征。在蛋白质回收过程中监测参数,如搅拌时间、壳聚糖剂量、初始pH和沉淀时间。同时,利用Box-Behnken设计(BBD)建立了二阶多项式模型。绘制了三维响应面轮廓图,以了解工艺参数对蛋白质回收的交互影响。通过使用期望的函数方法来确定最佳操作条件。在这些最佳条件下,蛋白质回收率达到95%。建立了一个基于人工神经网络的蛋白质回收模拟模型。电泳分析表明,回收的蛋白质可以作为家畜饲料的原料。
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引用次数: 0
Extreme streamflow time series analysis: trends, record length, and persistence 极端流时间序列分析:趋势,记录长度和持久性
IF 1.2 Q4 WATER RESOURCES Pub Date : 2022-01-29 DOI: 10.1080/23249676.2022.2030254
Leandro José Isensee, D. H. M. Detzel, A. Pinheiro, G. A. Piazza
Trends can be detected in time series of extreme hydrological events. However, persistence and record length are often ignored in those analyses resulting in contradicting conclusions. The aim of this study is to evaluate their influence on trend detection in extreme streamflow time series. In this study, 108 time series of maximum and minimum streamflow in Brazil were analysed, with a minimum length of 60 years and an average of 76 years. Mann-Kendall (MK), Spearman’s rho, and Pettitt statistical tests were applied to assess trends. Portmanteau and Hurst’s autocorrelation tests were adopted to assess the persistence. Modifications of the MK test were used to remove the persistence effects. We found a strong persistence in the studied time series. Even after removing it, several time series remained non-stationary. Record length significantly affected the results of the analyses, with an increase in the number of trends according to the period analysed.
可以在极端水文事件的时间序列中检测到趋势。然而,在这些分析中,持久性和记录长度往往被忽视,从而导致矛盾的结论。本研究的目的是评估它们对极端流量时间序列中趋势检测的影响。在这项研究中,分析了巴西108个最大和最小流量的时间序列,最小长度为60年,平均76年。Mann-Kendall(MK)、Spearman的rho和Pettitt统计检验用于评估趋势。采用Portmanteau和Hurst的自相关检验来评估持续性。MK测试的修改被用来消除持久性效应。我们在所研究的时间序列中发现了很强的持久性。即使在去除它之后,几个时间序列仍然是非平稳的。记录长度对分析结果产生了重大影响,根据所分析的时期,趋势数量有所增加。
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引用次数: 0
Laser induced fluorescence detection of R6G dye adsorbed on Fe3O4 nanomaterials Fe3O4纳米材料吸附R6G染料的激光诱导荧光检测
IF 1.2 Q4 WATER RESOURCES Pub Date : 2022-01-13 DOI: 10.1080/23249676.2021.2017805
Yasmin El-Dakrory, M. Sliem, Maha Abdelkreem, S. H. Hassab Elnaby, R. Rezk
This study investigates the comparison between magnetite nanoparticles loaded tea waste (MNLTW) and magnetite nanoparticles loaded reduced graphene oxide nanosheets (MNPs@rGO), as effective adsorbents for the removal of R6G dye from effluents. XRD, TEM, and SEM techniques were used to characterize the proposed adsorbents. The adsorption process was optimized under the parameters of initial concentration, contact time, pH, and the quantity of adsorbents. An amount of 0.15 g of both adsorbents removed about 87% of R6G by MNLTW and 65% by (MNPs@rGO) from 100 ml of a 23.95 mg/l concentrated solution in 40 and 60 min for MNLTW and (MNPs@rGO), respectively at pH 7. LIF measurements have developed better results than those of spectrophotometer. The isothermal analysis according to Langmuir isotherm was (R2  = 0.98) for (MNPs@rGO) and Temkin isotherm (R2 =  0.89) for MNLTW. The kinetic study is well described with a pseudo-second order model.
本研究考察了负载茶渣(MNLTW)的纳米磁铁矿和负载还原氧化石墨烯纳米片(MNPs@rGO)的纳米磁铁矿作为去除废水中R6G染料的有效吸附剂。采用XRD、TEM和SEM等技术对所制备的吸附剂进行了表征。在初始浓度、接触时间、pH、吸附剂用量等条件下,对吸附过程进行了优化。在pH为7的条件下,两种吸附剂用量均为0.15 g, MNLTW和(MNPs@rGO)分别在40分钟和60分钟内从100 ml 23.95 mg/l的浓溶液中去除约87%的R6G, (MNPs@rGO)去除65%的R6G。LIF测量取得了比分光光度计更好的结果。(MNPs@rGO)采用Langmuir等温线(R2 = 0.98), MNLTW采用Temkin等温线(R2 = 0.89)进行等温分析。用拟二阶模型很好地描述了动力学研究。
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引用次数: 0
Validation and pilot assessment of Tanzania water supply resilience measures 坦桑尼亚供水弹性措施的验证和试点评估
IF 1.2 Q4 WATER RESOURCES Pub Date : 2022-01-09 DOI: 10.1080/23249676.2021.2017804
Lukuba N. Sweya, S. Wilkinson
Water supply systems (WSSs) face constant water contamination and breakdown risks during disasters. Several studies develop resilience metrics without validation processes to ascertain their suitability and applicability. The current study examines the validity of existing qualitative resilience tools developed through a pre-assessment of the variables, a three-round Delphi process, and tested in three cases for applicability and generality. Validation applied the tools development data through a six-stage assessment process: (1) Group opinions, (2) Convergency of opinions, (3) Reliability analysis, (4) Inter-items correlations, (5) Level of agreements, (6) Applicability and generality. The tool encompasses 47 indicators in technical, organisational, social, economic, and environmental dimensions. The variables show better content validity with strong group opinions, significant convergence of opinions, high reliability, adequate relationship pattern, and excellent agreement in about 98% of indicators. Besides, there is adequate applicability and generality, thus, the variables are considered valid for Tanzania WSSs and in other developing countries.
在灾害中,供水系统(wss)面临着持续的水污染和故障风险。一些研究开发弹性指标没有验证过程,以确定其适用性和适用性。目前的研究考察了现有的定性弹性工具的有效性,这些工具是通过对变量的预评估、三轮德尔菲过程开发的,并在三个案例中测试了适用性和普遍性。验证通过六个阶段的评估过程应用工具开发数据:(1)群体意见,(2)意见的收敛性,(3)可靠性分析,(4)项目间相关性,(5)协议水平,(6)适用性和普遍性。该工具包括技术、组织、社会、经济和环境方面的47项指标。变量的内容效度较好,群体意见强,意见趋同显著,信度高,关系模式充分,约98%的指标一致性良好。此外,有足够的适用性和普遍性,因此,变量被认为是有效的坦桑尼亚wss和其他发展中国家。
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引用次数: 0
The feasibility of reusing highway runoff for fabric dyeing: a proof of concept 再利用公路径流进行织物染色的可行性:概念验证
IF 1.2 Q4 WATER RESOURCES Pub Date : 2022-01-04 DOI: 10.1080/23249676.2021.2017806
Muhammad Arslan, I. Shaikh
Urbanization transforms many natural catchments into urban areas with highly impervious surfaces creating considerable amounts of rainfall-runoff due to reduced infiltration rate of soil. Stormwater, previously infiltrated to recharge the aquifers, is now stormwater run-off rapidly draining into receiving waters. In this research work, an attempt is made to reuse the stormwater run-off in the textile industry for sustainable development and to avoid degradation of the ecosystem of receiving water bodies. Twenty-four stormwater samples were collected from an urban highway and analyzed for pH, Temperature, Total Dissolved Solids (TDS), Total Suspended Solids (TSS), Electrical Conductivity (Ec), Hardness, Calcium (Ca), Magnesium Mg), Chloride (Cl) and Sulphate (SO4) to determine physiochemical properties of highway run-off water. After analyzing physiochemical parameters, three reactive dyes, Remazol brilliant red 6B, Remazol navy blue GG, and Remazol yellow GR, were prepared using stormwater. Washing fastness and crocking/ rubbing fastness tests were performed for performance evaluation.
城市化将许多自然集水区转变为具有高度不透水表面的城市地区,由于土壤的渗透率降低,产生了大量的降雨径流。雨水以前是渗透到含水层中补给的,现在是雨水径流,迅速排入受纳水体。在这项研究工作中,试图将纺织业的雨水径流重新用于可持续发展,并避免接收水体的生态系统退化。从城市公路上采集了24个雨水样本,并对其pH、温度、总溶解固体(TDS)、总悬浮固体(TSS)、电导率(Ec)、硬度、钙(Ca)、镁(Mg)、氯化物(Cl)和硫酸盐(SO4)进行了分析,以确定公路径流水的理化性质。在分析理化参数的基础上,利用雨水制备了三种活性染料:瑞玛唑艳红6B、瑞玛唑海军蓝GG和瑞玛唑黄GR。进行了洗涤牢度和摩擦/摩擦牢度试验以进行性能评价。
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引用次数: 0
Periodic autoregressive models in flow regulating reservoirs design 调流水库设计中的周期自回归模型
IF 1.2 Q4 WATER RESOURCES Pub Date : 2021-10-26 DOI: 10.1080/23249676.2021.1980124
M. Coser, M. S. Mendes, J. A. T. Reis, A. Mendonça
Historical streamflow series may not present critical drought periods. As a result, volumes of flow regulating reservoirs estimated from historical data can lead to reservoirs design underestimation. Periodic stochastic models can be used to generate multiple different sequences of flows that present statistical properties close to those corresponding to the historical series but including more critical dry periods. The different volume values estimates allow probabilistic analysis and definition of regulating reservoir volumes based on periodic flows synthetic sequences occurrence risks. This study aims at assessing the performance of different periodic autoregressive models in generating sequences of flows and reproducing regulating reservoirs volumes. Periodic multiplicative autoregressive moving average models (PMIX), complete or parsimonious, showed better performances than traditional periodic autoregressive and autoregressive moving average models, for most historical streamflow series considered. The consideration of synthetic series generated by using PMIX multiplicative models can reduced risks of underestimation of reservoirs volumes.
历史径流序列可能不会出现关键干旱期。因此,根据历史数据估计的流量调节水库的容量可能导致水库设计低估。周期性随机模型可用于生成多个不同的流量序列,这些流量序列具有与历史序列相似的统计特性,但包括更关键的干旱期。不同的体积值估计允许基于周期流合成序列发生风险对调节储层体积进行概率分析和定义。本研究旨在评估不同周期自回归模型在生成流量序列和重现调节水库容量方面的性能。对于所考虑的大多数历史流量序列,周期乘性自回归移动平均模型(PMIX),无论是完整的还是简约的,都比传统的周期自回归和自回归移动均值模型表现出更好的性能。考虑使用PMIX乘法模型生成的合成序列可以降低低估储层体积的风险。
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引用次数: 0
Development of a CFD model and procedure for flows through in-stream structures 流中流动结构CFD模型和程序的开发
IF 1.2 Q4 WATER RESOURCES Pub Date : 2021-10-04 DOI: 10.1080/23249676.2021.1964388
Y. Lai, David L. Smith, David J. Bandrowski, Yuncheng Xu, C. Woodley, Kaitlin E. Schnell
Large wood (LW) has been widely used in river restoration projects due to its ecological benefit. 3D modeling has rarely been conducted. In this study, a 3D modeling procedure is proposed and a new 3D model is developed. The model incorporates advanced CFD techniques and is easy to apply. An engineered log jam (ELJ) is constructed and an experiment is conducted. The data are used to demonstrate the procedure and validate the CFD model. A comparison of the predicted and measured velocity shows that agreement is good with the Nash-Sutcliffe coefficient about 0.4 and index of agreement about 0.85. The model is further applied to a curved channel with ELJ on the outer bank, demonstrating the use of the 3D model to guide the proper representation of ELJs in a 2D model. The 3D model may be used to reveal complex flow patterns generated by LW for ecological benefit analysis.
大型木材因其生态效益而被广泛应用于河流修复工程中。很少进行三维建模。在本研究中,提出了一种三维建模程序,并开发了一种新的三维模型。该模型采用了先进的CFD技术,易于应用。构造了一种工程测井堵塞器(ELJ),并进行了实验。这些数据用于演示该程序并验证CFD模型。预测速度和测量速度的比较表明,Nash-Sutcliffe系数约为0.4,一致性指数约为0.85。该模型进一步应用于外堤ELJ的弯曲河道,演示了使用3D模型来指导在2D模型中正确表示ELJ。3D模型可用于揭示LW产生的复杂流型,用于生态效益分析。
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引用次数: 4
Multi-layer groundwater flow simulation in Al-Khoud lower catchment in Oman 阿曼Al Khoud下游集水区的多层地下水流动模拟
IF 1.2 Q4 WATER RESOURCES Pub Date : 2021-10-03 DOI: 10.1080/23249676.2021.1982027
Al-Mundhar Al-Nasri, L. Gunawardhana, G. Al-Rawas, M. Baawain, A. Sana
Sustainable groundwater resource management requires a better understanding of multilayer interactions, caused by the heterogeneous formations and enhanced by the groundwater withdrawal in aquifers. This phenomenon was studied in Al-Khoud lower catchment in Oman. Water exchange between different layers was observed by measuring piezometric heads of wells located at the same place with screen intervals placed in different layers. In addition, groundwater levels from 8 more wells and pumping rates from 60 wells were used for developing a numerical model in a 156 km2 area. Lithological data from 23 boreholes were used for defining three subsurface layers. Model results under different conditions indicated that 1.9–3.8 m head difference could be attributed to the pumping, while 2.1–6.0 m groundwater-level variations were accounted for the heterogeneity and anisotropic effects. Further analysis showed that the increased pumping rate increased the piezometric head difference between the layers, which enhances the multi-layer interactions.
可持续的地下水资源管理需要更好地了解多层相互作用,这种相互作用是由非均质地层引起的,并因含水层中的地下水抽取而得到加强。这一现象在阿曼Al Khoud下游流域进行了研究。通过测量位于同一位置的井的测压头,观察不同层之间的水交换。此外,还利用另外8口井的地下水位和60口井的抽水率,在156平方公里的区域内建立了一个数值模型。23个钻孔的岩性数据用于确定三个地下层。不同条件下的模型结果表明,1.9–3.8 m水头差可归因于抽水,而2.1–6.0 m地下水位的变化解释了非均质性和各向异性效应。进一步的分析表明,泵送速率的增加增加了层间的压差,从而增强了多层相互作用。
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引用次数: 2
Diffusion–advection process modeling of organochlorine pesticides in rivers 有机氯农药在河流中的扩散-平流过程模拟
IF 1.2 Q4 WATER RESOURCES Pub Date : 2021-10-03 DOI: 10.1080/23249676.2021.1982029
S. Cardenas, A. Marquez, E. Guevara
This paper deals with the diffusion–advection process modeling of organochlorine pesticides (OCPs) dissolved in a topical river. The novelty consists of proposing mathematical expressions to estimate the physical coefficients (molecular diffusion, advective diffusion, partition) and biochemical coefficients (substrate utilization rate) of OCPs advection–diffusion processes combined to OCPs biochemical transformation processes. The OCPs involved were DDTs (p.p’-DDT, o.p’-DDT, p.p’-DDD, p.p’-DDE, o.p’-DDE) and DRINs (Aldrin, Dieldrin and Endrin). Four scenarios for simulating the OCPs transport were calibrated: (1) molecular diffusion, (2) biochemical transformation, (3) advection–diffusion and (4) a combination of advection–diffusion, biochemical transformation and sorption/desorption processes. The evaluated scenarios predicted with a good approach to the OCPs’s spatio-temporal distribution with a prediction capability within an interval until 1.5 standard deviation with respect to the mean of difference between observed and simulated OCPs The scenario N°4 associated to a coupled model offered a suitable prediction of processes for a tropical river.
本文研究了局部河流中有机氯农药的扩散-平流过程模型。新颖之处在于提出了计算OCPs平流-扩散过程与OCPs生化转化过程相结合的物理系数(分子扩散、平流扩散、分配)和生化系数(底物利用率)的数学表达式。所涉及的ocp是ddt (p.p ' -DDT, o.p ' -DDT, p.p ' -DDD, p.p ' -DDE, o.p ' -DDE)和DRINs (Aldrin, Dieldrin和Endrin)。校准了四种情景来模拟OCPs的传输:(1)分子扩散,(2)生化转化,(3)平流-扩散和(4)平流-扩散、生化转化和吸附/脱附的组合过程。评估情景对ocp的时空分布有较好的预测能力,预测能力在观测值与模拟值之差均值1.5标准差范围内。与耦合模式相关的情景N°4对热带河流过程提供了较好的预测。
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引用次数: 7
Nitrate removal from agricultural effluent using sugarcane bagasse active nanosorbent 甘蔗渣活性纳米吸附剂去除农业废水中硝酸盐的研究
IF 1.2 Q4 WATER RESOURCES Pub Date : 2021-10-03 DOI: 10.1080/23249676.2021.1982030
Parisa Mehrabinia, Elham Ghanbari-Adivi, R. Fattahi, Heshmatollah Samimi-Shalamzari, Jalil Kermanezhad
The increase in population and the growth of agricultural activities, and consequently the increase in demand for safe water, has made the use of unconventional water to solve the problems of water scarcity very efficient. Here to investigate the removal of nitrate from agricultural drains, sugarcane bagasse biochar was used as an adsorbent. This study includes the effect of three parameters: heating time in the microwave, microwave power and weight ratio of KOH to biochar (KBC) to remove nitrate from contaminated wastewater. First, the optimal conditions for the preparation of sugarcane bagasse sorbent were investigated, which includes 0.2 g of sorbent in 150 ml of nitrate solution, biochar production time of 2 h at 600°C and pH equal to 7. According to the results, the microwave power of 400 W, activation time of 10 min and weight ratio (KBC) had the highest percentage of nitrate absorption (equal 75.3%).
人口的增加和农业活动的增长,以及对安全用水需求的增加,使得使用非常规水来解决缺水问题变得非常有效。本文以甘蔗渣生物炭为吸附剂,对农业排水中硝酸盐的去除进行了研究。本研究包括三个参数:微波加热时间、微波功率和KOH与生物炭(KBC)的重量比对去除污染废水中硝酸盐的影响。首先,研究了甘蔗渣吸附剂的最佳制备条件,该条件包括0.2 150中的吸附剂g ml硝酸盐溶液,生物炭生产时间为2 h,温度为600°C,pH等于7。根据结果,微波功率为400 W、 激活时间为10 分钟和重量比(KBC)的硝酸盐吸收率最高(等于75.3%)。
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引用次数: 5
期刊
Journal of Applied Water Engineering and Research
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