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STIRRING OF METAL MELTS FOR IMPROVING THE EFFICIENCY OF THE “LADLE – FURNACE” UNITS Message 2. NEW METHOD FOR ELECTROMAGNETIC STIRRING OF METALLIC MELT IN “LADLE – FURNACE” UNIT 为了提高“钢包-熔炉”装置的效率,搅拌金属熔体。“钢包炉”装置中金属熔体电磁搅拌的新方法
Pub Date : 2023-06-01 DOI: 10.15407/plit2023.02.003
O. Smirnov, V. Osypenko, S. Semiryagin, M. Goryuk, A. Semenko, Yu.P. Skorobagatko
The features of refractory lining’s wear of “ladle – furnace” unit at work on metallurgical mini-plant with intensive stirring of liquid metal by gas and electromagnetic field is studied. It was established that the most affected areas are slag zone, ladle’s bottom, as well as side wall, near which the electromagnetic stirrer is located. The stability of these areas determines the duration of the ladle working between repairs. Recommendations for recovery of the lining’s working layer have been developed. Also, there are formulated the requirements for rationalization of melt stirring modes. Theoretical studying of influence of electromagnetic stirring on heat & mass transfer processes in liquid metal bath of metallurgical aggregates (in particular, during homogenization of alloy in free turbulence mode at input of additives) was investigated. New electromagnetic stirrer was designed in the PTIMA NASU, and it is proposed for technologies of melting and finishing of alloys. The stirrer creates the pulsating magnetic field, and its force lines spread equally intensively both in the horizontal and vertical planes. It is shown that design of developed stirrer, its power supply by industrial frequency 50 Hz, and physical nature of the generated field’s action provide the simplicity of its making and operation. So, new stirrer has essential technical, economic and technological advantages in comparison with known stirrers of travelling magnetic field at the same parameters of electromagnetic systems. Joint research performed by specialists of the PTIMA NASU and IED NASU with using mathematical modeling and experiments on aluminum melt showed the following. It is possible to realize a wide range of stirring modes, both intensity and melt movement directions. Thus, the application of developed electromagnetic stirrer in the “ladle – furnace” units will allow to significantly expand the possibilities for finishing liquid alloys on chemical composition and temperature, especially at small metallurgical plants.
研究了在气体和电磁场强烈搅拌金属液的冶金小型装置中“钢包炉”机组耐火衬磨损的特点。结果表明,受影响最大的区域是炉渣区、钢包底部以及电磁搅拌器所在的侧壁。这些区域的稳定性决定了钢包在两次修理之间工作的时间。对衬里工作层的修复提出了建议。同时,对熔体搅拌方式的合理化提出了要求。本文从理论上研究了电磁搅拌对冶金集料液态金属浴中传热传质过程的影响(特别是在添加剂输入自由湍流模式下合金的均匀化过程)。在PTIMA NASU上设计了新型电磁搅拌器,并对合金的熔炼和精加工工艺提出了建议。搅拌器产生脉动磁场,其力线在水平和垂直平面上分布均匀。研究表明,该搅拌器的设计、50hz工频供电和产生磁场作用的物理性质使其制造和操作简单。因此,在相同的电磁系统参数下,与现有的行磁场搅拌器相比,新型搅拌器具有本质的技术、经济和工艺优势。PTIMA NASU和IED NASU的专家通过对铝熔体进行数学建模和实验进行的联合研究表明:可以实现广泛的搅拌模式,无论是强度还是熔体运动方向。因此,开发的电磁搅拌器在“钢包炉”装置中的应用,将大大扩大在化学成分和温度上精加工液态合金的可能性,特别是在小型冶金厂。
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引用次数: 0
ANALYSIS OF THE STRUCTURAL-CHEMICAL MILL DUPLEX-SYSTEMS OF SILICATE-SILICIDE OF LUNG-EARTH METALS. Message 3. The mechanism of desulfurization in the smelting of blast-furnace pig iron LUNG-EARTH金属硅酸盐-硅化物的结构-化学磨双组分系统的分析。消息3。高炉生铁冶炼中的脱硫机理
Pub Date : 2023-06-01 DOI: 10.15407/plit2023.02.033
B. Belov, A. Trotsan, O. Vlasova
The mechanism of cast iron desulfurization through structural and chemical reactions in smelting slags corresponding to the composition of the main mineral phases is presented: monticellite (MT, SiO2MgOCaO) → mervinite (MP, 2SiO2MgO3CaO) → ockermannite (OK, 2SiO2MgO2CaO) →diopside (DP, 2SiO2MgOCaO) → rankinite (pH, 2SiO23CaO) and eutectic slags (E, 3SiO2MgO4CaO). A sequential series of adsorption capacity of slag phases with respect to sulfur (АС, mas. %) and the depth of metal desulfurization – Δ(S), ppm was determined: Е (3.54/36) → MR (4.8/49) → OK (5, 7/59) → DP (7.14/74) → MT (9.8/103) → RN (20/222). In factory conditions, the efficiency of smelting slags of eutectic composition and diopside for ladle processing of cast iron was tested. The expediency of using such blast furnace slags for ladle processing of cast iron has been established, which at a consumption of 5-10 kg/t provide a desulfurization depth of 200-400 ppm. The consumption of slag is significantly reduced with the additional deoxidation of smelting slags with carbon during the release of melt in the ditch of the foundry and in the pig iron ladle.
介绍了通过冶炼渣中与主要矿物相组成相对应的结构和化学反应进行铸铁脱硫的机理:蒙脱石(MT,SiO2MgOCaO)→ 红柱石(MP,2SiO2MgO3CaO)→ 奥氏体(OK,2SiO2MgO2CaO)→透辉石(DP,2SiO2MgOCaO)→ 钾铁矿(pH,2SiO23CaO)和共晶渣(E,3SiO2MgO4CaO)。确定了渣相对硫的吸附能力(АС,mas.%)和金属脱硫深度Δ(S),ppm的顺序序列:→ MR(4.8/49)→ 好(5/7/59)→ DP(7.14/74)→ MT(9.8/103)→ RN(20/222)。在工厂条件下,测试了共晶成分和透辉石的熔渣用于钢包铸铁加工的效率。已经建立了将这种高炉渣用于铸铁的钢包处理的方便性,其在5-10kg/t的消耗下提供200-400ppm的脱硫深度。在铸造厂的沟渠和生铁钢包中释放熔体期间,通过用碳对熔炼炉渣进行额外脱氧,显著降低了炉渣的消耗。
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引用次数: 0
THE USE OF CERAMIC FILTERS IN THE SMELTING OF WORKPIECES FROM HEAT-RESISTANT ALLOYS 陶瓷过滤器在耐热合金工件熔炼中的应用
Pub Date : 2023-06-01 DOI: 10.15407/plit2023.02.041
I. Kvasnytska, I. Maksiuta, I. Shalevska, K. Kvasnytska, V. Noga
To improve the operational characteristics of gas turbine engine blades, it is necessary to use new methods of cleaning and refining metal. Melt filtration is an effective way to improve casting quality.According to the conducted analyses, it was determined that the amount of conditioned waste generated during the smelting of products reaches 27% of the mass of the spent charge, and non-conditioned waste rejected during LUMMA control is 23%. The results of the statistical analysis show that the total amount of waste generated during the smelting of gas turbine blades is, on average, 60–70% of the weight of the loaded charge.The purpose of the work is to create a new composition of the ceramic mixture for the production of high-strength filters, as well as the development of technology for the production of gas turbine parts using them.The analysis was performed on samples of heat-resistant corrosion-resistant alloy CM88Y. The alloy for research was melted from the primary charge on the UPPF-3M foundry unit. As a result of the work carried out, a new rational composition of the mixture for the manufacture of ceramics was created, which allows to increase the characteristics of strength and heat resistance. An instruction was created for the manufacture of ceramic filters at machine-building enterprises. To eliminate damage to ceramic rods in blades under the influence of thermal shock, improved systems for filtering metal in a liquid state and filling ceramic molds are proposed. Uniform temperature distribution across the cross-section of the casting also reduces the number of defective products.
为了改善燃气轮机叶片的运行特性,有必要使用新的金属清洁和精炼方法。熔体过滤是提高铸件质量的有效途径。根据所进行的分析,确定在产品熔炼过程中产生的调节废物的量达到废钢质量的27%,而在LUMMA控制过程中拒绝的未调节废物为23%。统计分析结果表明,燃气轮机叶片熔炼过程中产生的废物总量平均为装料重量的60-70%。这项工作的目的是创造一种新的陶瓷混合物成分,用于生产高强度过滤器,以及开发使用它们生产燃气轮机零件的技术。对耐热耐腐蚀合金CM88Y的样品进行了分析。用于研究的合金是在UPPF-3M铸造装置上从一次装料中熔化的。作为所进行的工作的结果,创造了一种用于制造陶瓷的新的合理混合物成分,它可以提高强度和耐热性的特性。为机械制造企业的陶瓷过滤器制造制定了一项指令。为了消除热冲击对叶片中陶瓷棒的损坏,提出了一种改进的液态金属过滤和陶瓷模具填充系统。铸件横截面上均匀的温度分布也减少了缺陷产品的数量。
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引用次数: 0
TECHNOLOGICAL FEATURES OF MANUFACTURING ALLOY AK7h STRENGTHENED WITH ZIRCONIUM INTRODUCED WITH ZIRCONIUM TETRAFLUORIDE 四氟化锆引入锆强化AK7h合金的工艺特点
Pub Date : 2023-06-01 DOI: 10.15407/plit2023.02.016
D. Ivanchenko, M. Yamshinskij
The paper considers the important features of the technology of strengthening AK7ch aluminum alloy with zirconium introduced with its tetrafluoride. The choice of a complex flux containing zirconium tetrafluoride in its composition is justified. It is indicated that in order to recover zirconium from its tetrafluoride in the aluminum melt, it is first of all necessary to ensure the formation of sodium or potassium fluorozirconate in the strengthening mixture. The mechanism of recovery of zirconium from tetrafluoride is presented. Technological recommendations for obtaining AK7ch alloy are given. It has been established that the complex flux intended to the alloy, which is modified, must be injected into liquid aluminum before the introduction of other alloying elements, namely silicon and magnesium. The maximum appropriate temperature for injecting zirconium into the aluminum melt from the complex flux is indicated. The maximum amount of zirconium that was recovered is 0.4%. The microstructure and mechanical properties of an alloy strengthened by zirconium from its tetrafluoride, which was injected into the alloy in the amount from 0.8 to 1.2%, were studied. As a result of the modification of aluminum alloy AK7ch with zirconium, the grains of silicon solution in aluminum (α-phase) are grind. No other structural changes are observed. The value of tensile strength and relative elongation of the alloy increases by 1.3 and 1.7 times, respectively.
介绍了四氟化锆对AK7ch铝合金的强化工艺的重要特点。选择含有四氟化锆的复合熔剂是合理的。结果表明,为了从铝熔体中的四氟化锆中回收锆,首先必须确保在强化混合物中形成氟锆酸钠或氟锆酸钾。介绍了从四氟化锆中回收锆的机理。给出了获得AK7ch合金的工艺建议。已经确定,在引入其他合金元素,即硅和镁之前,必须将改性后的合金用复合熔剂注入液态铝中。指出了从复合熔剂向铝熔体中注入锆的最高合适温度。回收的锆的最大含量为0.4%。研究了用四氟化锆增强合金的微观结构和力学性能,四氟化锆以0.8%至1.2%的量注入合金中。用锆对铝合金AK7ch进行变质处理,使硅溶液在铝(α相)中的晶粒得以磨削。未观察到其他结构变化。合金的抗拉强度和相对伸长率分别提高了1.3倍和1.7倍。
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引用次数: 0
THE WORLD MARKET OF METAL CASTINGS 2019―2021: COUNTRIES, ALLOYS, TECHNOLOGIES 2019-2021年世界金属铸件市场:国家、合金、技术
Pub Date : 2023-06-01 DOI: 10.15407/plit2023.02.056
V. Gnatush
The analysis of the world market of metal castings in 2019–2021 is presented. Due to the fact that as of January 2022 the publication of the world statistics of the production of metal castings did not take place, an analysis of information was carried out regarding the results in the countries that are part of the global Top-10. Among them are China, India, USA, Germany, Japan, Turkey and Brazil. It is noted that in 2021 in China, 54.05 million tons of castings were produced, which is 4.0% more than in 2020. In terms of cast alloys: gray cast iron (share 41.7%), cast iron with nodular graphite (29.5%), aluminum and magnesium alloys (13.3%) and steel (12.2%). In India, the export of metal castings in terms of value for the period from 2016/2017 financial year (FY) to 2020/2021 F. increased from 2.366 to 2.865 billion USD, i.e. with a CAGR of 3.9%. In the USA for the period from 2013 to 2019 the income of the foundry industry increased from 38.7 to 44.3 billion USD, that is, with an average annual growth rate (CAGR) of 1.9%. Under the influence of the COVID-19 pandemic and the slowdown of the economy in 2020. industry revenue decreased to USD 36.7 billion (-17.1% vs. 2019). However, in 2021 the situation improved somewhat ― 43.4 billion USD (18.3% against 2020). In Germany, the production of castings from ferrous metal alloys (gray cast iron, with nodular graphite, malleable and steel) in 2021. amounted to 3.2 million tons, which is 16.4% more than in 2020. At the same time, for the period 2019-2021 production of the specified castings decreased at an average annual rate (CAGR) of -6.0%, and their export ― by -7.0%. In Japan, as a result of the changing economic situation in the world, which was formed after 2019, the production of castings during 2019-2021. is characterized by a downward trend. The production of castings from copper alloys decreased with an average annual rate (CAGR) of -5.6%, castings from aluminum alloys ― -5.1% and castings from iron alloys ― -1.5%. In Turkey in 2021 1.108 million tons of nodular cast iron castings (by 29.6% vs. 2020), 0.921 million tons of gray iron castings (by 49.1%) and 0.279 million tons of steel castings (by 45, 4%). In general, during 2019–2021 the production of castings from ferrous metal alloys in the country increased at an average annual rate (CAGR) of 9.9%. In Brazil, in 2021, foundry enterprises produced 2.5 million tons of castings, which is 21.1% higher than in 2020. At the same time, the production of castings from cast iron increased by 25.5%, from non-ferrous metal alloys ― by 7.0%, and steel ― by 3.9%. In general, during 2019–2021 the production of castings in the country increased at an average annual rate (CAGR) of 3.1%. The presented data indicate that in 2021 the global foundry industry developed in a positive trend. Estimated global production of castings from ferrous and non-ferrous metals by the end of 2021. may amount to 109.2...118.5 million tons against 105.5 million tons in 2020.
对2019-2021年世界金属铸件市场进行了分析。由于截至2022年1月尚未公布世界金属铸件生产统计数据,因此对全球排名前10位的国家的结果进行了信息分析。其中包括中国、印度、美国、德国、日本、土耳其和巴西。值得注意的是,2021年中国铸件产量为5405万吨,比2020年增长4.0%。在铸造合金方面:灰口铸铁(占41.7%)、球墨铸铁(29.5%)、铝镁合金(13.3%)和钢(12.2%)。在印度,从2016/2017财政年度(FY)到2020/2021 f期间,金属铸件的出口额从23.66亿美元增加到28.65亿美元,即复合年增长率为3.9%。在美国,从2013年到2019年,铸造行业的收入从387亿美元增加到443亿美元,即平均年增长率(CAGR)为1.9%。在新冠肺炎疫情和2020年经济放缓的影响下。行业收入下降至367亿美元(比2019年下降17.1%)。然而,2021年情况有所改善,为434亿美元(比2020年增长18.3%)。在德国,到2021年将生产黑色金属合金(灰铸铁,含球墨,可锻铸和钢)铸件。总量320万吨,比2020年增长16.4%。与此同时,在2019-2021年期间,特定铸件的产量以平均年增长率(CAGR)下降-6.0%,出口下降-7.0%。在日本,由于2019年之后形成的世界经济形势的变化,2019-2021年期间的铸件生产。呈下降趋势。铜合金铸件产量以年均5.6%的速度下降,铝合金铸件产量下降5.1%,铁合金铸件产量下降1.5%。在土耳其,2021年球墨铸铁铸件为110.8万吨(比2020年增长29.6%),灰铁铸件为0.921万吨(增长49.1%),钢铸件为0.279万吨(增长45.4%)。总体而言,在2019-2021年期间,该国黑色金属合金铸件的产量以年均9.9%的速度增长。在巴西,2021年铸造企业生产铸件250万吨,比2020年增长21.1%。与此同时,铸铁铸件产量增长25.5%,有色金属合金增长7.0%,钢铁增长3.9%。总体而言,在2019-2021年期间,该国铸件产量的平均年增长率(CAGR)为3.1%。数据表明,2021年全球铸造行业呈现积极发展趋势。预计到2021年底,全球黑色和有色金属铸件产量。2020年为1.055亿吨,可能达到1.092亿吨…1.185亿吨。然而,由于俄罗斯和乌克兰之间的战争,出现了一些负面因素,这些因素将导致2022-2023年铸造生产放缓。该评论还介绍了世界领先的铸造公司的信息,以及美国和英国在铸造生产中使用3d打印的例子。
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引用次数: 0
CASTING OF COMBINED POLYMER PATTERNS THAT ARE GASIFIED 气化的组合聚合物模型的铸造
Pub Date : 2023-06-01 DOI: 10.15407/plit2023.02.049
P. Kaliuzhnyi, V. Doroshenko, O. Neima
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引用次数: 0
PHYSICO-CHEMICAL METHODS OF INCREASING THE CRACK RESISTANCE OF ALLOY AM4.5Cd (VAL10). NOTICE 1: EXPERIENCE OF USING AN RING SAMPLE 提高AM4.5Cd (VAL10)合金抗裂性能的物理化学方法。注意事项1:使用环形样品的经验
Pub Date : 2023-06-01 DOI: 10.15407/plit2023.02.024
V. Bielik, A. Prigunova, V. Shaіgam, A. Vernydub
On the example of the AM4.5Kd (VAL10) alloy treated in the liquid state with hydrogen, the efficiency of using the well-known ring test for the study of physicochemical methods of influencing the crack resistance of wide-range aluminum alloys, which are prone to the formation of hot cracks during solidification, was studied. To achieve this goal, an annular mold mold was made according to the recommended dimensions, experiments were carried out on the effect of hydrogen treatment of the melt on the crack resistance of castings. Saturation with hydrogen was carried out by blowing the melt with water vapor, the degree of gas saturation was estimated from the porosity of the castings, calculated from the change in their density compared to the control sample obtained in a mold with sufficient power. Despite the measures taken to increase the sensitivity of the annular sample and obtain stable results, which consisted in adjusting the dimensions of the mold, in particular, the size of the central rod, during compression of which the hardening melt creates tensile stresses leading to the formation of a hot crack, as well as optimizing the thermal regime for obtaining a casting by increasing the initial mold temperature from 22 0С to 217-249 0С, the sensitivity of this sample under the experimental conditions remained too low. In 60 % of cases, gas saturation of the melt contributed to a reduction in the crack propagation process when using a mold at room temperature and up to 100 % when the mold was heated to a temperature of 228 0C to 260 0C. However, in both the first and second cases, 28 % of similar data were obtained on castings from the initial melt not saturated with hydrogen. This casts doubt on the reliability of the positive effect of hydrogen treatment and became the basis for the conclusion that it is inappropriate to use this type of sample in studies of physical and chemical effects on the melt in order to increase the crack resistance of the AM4.5Kd (VAL10) alloy due to a possible error in assessing the effectiveness of their impact, and also to decide on the need to develop a new sample, devoid of the identified shortcomings.
以液态氢处理的AM4.5Kd(VAL10)合金为例,研究了利用众所周知的环试验研究影响宽范围铝合金抗裂性的物理化学方法的效率,这些合金在凝固过程中容易形成热裂纹。为了实现这一目标,根据推荐的尺寸制作了一个环形模具,并对熔体的氢处理对铸件抗裂性的影响进行了实验。氢气饱和是通过用水蒸气吹制熔体来进行的,气体饱和程度是根据铸件的孔隙率来估计的,与在具有足够功率的模具中获得的对照样品相比,根据铸件密度的变化来计算。尽管采取了措施来提高环形样品的灵敏度并获得稳定的结果,包括调整模具的尺寸,特别是中心棒的尺寸,在压缩过程中,硬化熔体产生拉伸应力,导致热裂纹的形成,以及通过将初始模具温度从22 0С提高到217-249 0С来优化获得铸件的热状态,该样品在实验条件下的灵敏度仍然过低。在60%的情况下,当在室温下使用模具时,熔体的气体饱和度有助于减少裂纹扩展过程,当模具加热到228 0C至260 0C的温度时,气体饱和度高达100%。然而,在第一种和第二种情况下,28%的类似数据是从未被氢气饱和的初始熔体中获得的。这使人们对氢处理的积极作用的可靠性产生了怀疑,并成为结论的基础,即为了提高AM4.5Kd(VAL10)合金的抗裂性,在研究熔体的物理和化学作用时使用这种类型的样品是不合适的,并决定是否需要开发一个没有已发现缺陷的新样本。
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引用次数: 1
ACTORS INFLUENCING ON A DISTRIBUTION OF VANADIUM PARTICLES IN Cu-V CAST COMPOSITES, OBTAINED BY OF THE ELECTRON-BEAM CASTING TECHNOLOGY 利用电子束铸造技术获得了影响Cu-V复合材料中钒颗粒分布的因素
Pub Date : 2023-01-01 DOI: 10.15407/plit2023.03.061
R. Likhatskyi, M. Voron, Ye. Matviets, V. Perekhoda
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引用次数: 0
PHYSICO-CHEMICAL METHODS OF INCREASING THE CRACKING RESISTANCE OF ALLOY AM4.5KD (VAL10). NOTICE 2: DEVELOPMENT OF THE CRACK RESISTANCE TEST 提高am4.5kd (val10)合金抗裂性能的理化方法。注意事项2:抗裂试验的发展
Pub Date : 2023-01-01 DOI: 10.15407/plit2023.03.018
V. Bielik
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引用次数: 0
DEPENDENCES OF THE INFLUENCE OF OVERHEATING TEMPERATURE ON CRYSTAL GENERATION IN METAL MELTS 金属熔体中过热温度对晶体生成影响的依赖性
Pub Date : 2023-01-01 DOI: 10.15407/plit2023.03.034
A. Nuradinov, O. Nogovitsyn, V. Shkolyarenko, I. Baranov, I. Nuradinov
{"title":"DEPENDENCES OF THE INFLUENCE OF OVERHEATING TEMPERATURE ON CRYSTAL GENERATION IN METAL MELTS","authors":"A. Nuradinov, O. Nogovitsyn, V. Shkolyarenko, I. Baranov, I. Nuradinov","doi":"10.15407/plit2023.03.034","DOIUrl":"https://doi.org/10.15407/plit2023.03.034","url":null,"abstract":"","PeriodicalId":52779,"journal":{"name":"Protsessy lit''ia","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67138252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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