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Role of Interfacial Water and Applied Potential on Friction at Au(111) Surfaces 界面水和外加电位在Au(111)表面摩擦中的作用
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-06-21 DOI: 10.3389/fmech.2019.00039
Leila Pashazanusi, K. Kristiansen, Shaowei Li, Yu Tian, N. Pesika
The tribological properties between an AFM tip and a Au(111) surface in an aqueous environment is influenced by an applied electrical potential. Using lateral force microscopy, we measure the resulting friction force, while simultaneously applying a predetermined electrical potential on the Au surface via a three-electrode setup. Applying a positive potential to the Au surface forms an interfacial water layer at the Au/electrolyte interface, which sharply increases friction. However, when an anodic potential is applied, lower friction forces are measured. The potential dependent friction is observed on ultra-smooth gold surfaces as well as Au surfaces with larger roughness. An increase in the ionic strength of the electrolyte is found to lower friction. The use of an aqueous NaOH solution is found to lower the critical potential at which the friction sharply increases. Normal force curves are also measured as a function of approach velocity. The normal force linearly increases as the approach velocity increases in agreement with a drainage model. These results provide valuable insight into the effect of applied electrical potentials on the properties of water at charged surfaces and can potentially impact a wide range of fields including tribology, micro-electro-mechanical systems (MEMS), energy storage devices, fuel cells and catalysis.
在水环境中,AFM尖端与Au(111)表面之间的摩擦学性能受外加电位的影响。利用侧向力显微镜,我们测量了由此产生的摩擦力,同时通过三电极装置在金表面施加预定的电位。在Au表面施加正电位会在Au/电解质界面形成界面水层,从而急剧增加摩擦。然而,当施加阳极电位时,测量到的摩擦力较低。在超光滑的金表面和粗糙度较大的金表面上观察到电位依赖的摩擦。电解质离子强度的增加可以降低摩擦。研究发现,使用氢氧化钠水溶液可以降低摩擦急剧增加的临界电位。法向力曲线也被测量为接近速度的函数。法向力随接近速度的增加而线性增加,与排水模型一致。这些结果为应用电位对带电表面的水性质的影响提供了有价值的见解,并可能影响广泛的领域,包括摩擦学,微机电系统(MEMS),能量存储设备,燃料电池和催化。
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引用次数: 5
An Experimental Study of Intermittent Heating Frequencies From Wind-Driven Flames 风动火焰间歇加热频率的实验研究
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-06-20 DOI: 10.3389/fmech.2019.00034
Wei Tang, M. Finney, S. McAllister, M. Gollner
An experimental study was conducted to understand the intermittent heating behavior downstream of a gaseous line burner under forced flow conditions. While previous studies have addressed time-averaged properties, here measurements of the flame location and intermittent heat flux profile help to give a time-dependent picture of downstream heating from the flame, useful for understanding wind-driven flame spread. Two frequencies are extracted from experiments, the maximum flame forward pulsation frequency in the direction of the wind, which helps describe the motion of the flame, and the local flame-fuel contact frequency in the flame region, which is useful in calculating the actual heat flux that can be received by the unburnt fuel via direct flame contact. The forward pulsation frequency is obtained through video analysis using a variable interval time average (VITA) method. Scaling analysis indicates that the flame forward pulsation frequency varies as a power-law function of the Froude number and fire heat-release rate, . For the local flame-fuel contact frequency, it is found that the non-dimensional flame-fuel contact frequency remains approximately constant before the local Rix reaches 1, e.g., attached flames. When Rix>1, decreases with local as Rix flames lift up. A piece-wise function was proposed to predict the local flame-fuel contact frequency including the two Rix scenarios. Information from this study helps to shed light on the intermittent behavior of flames under wind, which may be a critical factor in explaining the mechanisms of forward flame spread in wildland and other similar wind-driven fires.
为了了解强制流动条件下气体管路燃烧器下游的间歇加热行为,进行了实验研究。虽然以前的研究已经解决了时间平均特性,但这里对火焰位置和间歇性热流分布的测量有助于给出火焰下游加热的时间依赖图,有助于理解风驱动的火焰传播。从实验中提取了两个频率,一个是火焰在风方向的最大前向脉动频率,这有助于描述火焰的运动,另一个是火焰区域的局部火焰-燃料接触频率,这有助于计算未燃烧的燃料通过火焰直接接触可以接收的实际热流密度。利用可变间隔时间平均(VITA)方法对视频进行分析,得到前向脉动频率。尺度分析表明,火焰前向脉动频率与弗劳德数和火焰放热率成幂律函数关系。对于局部火焰-燃料接触频率,发现在局部Rix达到1之前,无量纲火焰-燃料接触频率保持近似恒定,例如附着火焰。当Rix>1时,随Rix火焰上升,随局部减小。提出了一种分段函数来预测包括两种Rix情景的局部火焰-燃料接触频率。这项研究的信息有助于揭示风下火焰的间歇性行为,这可能是解释野火和其他类似风驱动火灾中火焰向前蔓延机制的关键因素。
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引用次数: 5
Influence of MHD Lubrication and Textured Surface in EHL Line Contact MHD润滑和织构表面对EHL线接触的影响
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-06-20 DOI: 10.3389/fmech.2019.00033
Suresh Jadhav, G. D. Thakre, Satish C. Sharma
The present numerical study investigates the combined effect of micro-texture and magneto hydrodynamic lubrication behaviour on the performance of EHL line contact. Micro-textures are provided in the inlet zone of contacting surface has been studied. Modified Reynolds equation, elasticity equation and load balance equation has been solved using FEA and Generalized Minimal Residual Method (GMRES). A parametric study has been performed to optimize the micro-texture shapes in the contacting surfaces for different values of magneto hydrodynamic lubricant parameters The numerical results show that increasing externally applied magnetic field and micro- texture shapes enhances the values of performance parameter of EHL line contact. Finally, the variation in the steady-state EHL characteristics pertaining to unidirectional pure sliding contacts due to an artificially produced IZMTS is investigated numerically. The enhancement in central and minimum film thickness is found to be upto 38% and 28% respectively along with 33.28% reduction in coefficient of friction.
本文研究了微织构和磁流体动力润滑特性对EHL线接触性能的综合影响。研究了接触面入口区存在的微织构。利用有限元分析和广义最小残差法(GMRES)求解了修正的雷诺方程、弹性方程和负载平衡方程。对不同磁流体动力润滑参数值下接触面微织构形状的优化进行了参数化研究。数值结果表明,增加外加磁场和微织构形状可以提高EHL线接触的性能参数值。最后,对单向纯滑动触点稳态EHL特性的变化进行了数值研究。中心膜厚度和最小膜厚度分别增大38%和28%,摩擦系数减小33.28%。
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引用次数: 3
Passive and Active Control on 3D Convective Flow of Viscoelastic Nanofluid With Heat Generation and Convective Heating 热生成与对流加热粘弹性纳米流体三维对流的被动与主动控制
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-06-20 DOI: 10.3389/fmech.2019.00036
S. Eswaramoorthi, M. Bhuvaneswari
The present article addresses the impact of passive control (PC) and active control(AC) on 3D flow of a viscoelastic nanofluid upon a stretching plate including heat generation and convective heating. The system of appearing non-linear PDE’s are converted into a couple of ODE’s by using suitable similarity transformations. Convergent series solutions are derived using homotopy analysis method (HAM). Graphical results of velocity, nanoparticle volume fraction and temperature of different pertinent physical parameters with notable discussions are pointed with their physical significance
本文讨论了被动控制(PC)和主动控制(AC)对粘弹性纳米流体在拉伸板上的三维流动的影响,包括热量产生和对流加热。通过适当的相似变换,将出现非线性偏微分方程的系统转化为一对偏微分方程。利用同伦分析法(HAM)导出了收敛级数解。给出了速度、纳米粒子体积分数和温度在不同相关物理参数下的图形结果,并对其物理意义进行了讨论
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引用次数: 4
Firebrand Generation From Thermally-Degraded Cylindrical Wooden Dowels 由热降解圆柱木销子产生的火种
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-06-14 DOI: 10.3389/fmech.2019.00032
Sara E. Caton-Kerr, A. Tohidi, M. Gollner
During wildland fires, firebrands form once they break off of burning vegetation or structures. Many are then lofted into the fire plume where they are transported long distances ahead of the fire front, igniting new “spot” fires as they land. To date, very few studies have been conducted on the breakage mechanism of thermally-degraded vegetative elements. Knowledge of these mechanisms is needed to feed mathematical models of firebrand transport from traditional wildfires as well as those that spread into communities. First, a framework to understand the behavior of thermally-degraded wooden elements under simultaneous external loading is presented. A set of experiments were designed such that cylindrical wooden dowels of different species are exposed to different heating conditions similar to wildland fires, in order to model the breakage mechanisms of these elements in the absence of wind. The thermally-degraded elements are subjected to the three-point bending test to obtain the mechanical response of the materials after combustion. Assuming Hookean Orthotropic behavior for combusted dowels, dimensional analysis of the results reveals that the ultimate strength of the dowels is affected by the recoverable elastic strain during loading, which is found to occur under two distinct regimes. These results are not only important for better understanding of the breakage mechanisms but also are advantageous for developing a failure theory of thermally degrading wooden elements under simultaneous wind loading conditions.
在野火中,一旦它们从燃烧的植被或建筑物上脱落,就会形成火种。然后许多被抛入火羽中,在那里它们被运送到火场前面很远的地方,在它们着陆时点燃新的“点”火。迄今为止,对热降解植物元素的破坏机制的研究还很少。我们需要了解这些机制,以建立传统野火以及蔓延到社区的野火的火种传播的数学模型。首先,提出了一个框架来理解同时外部载荷下热降解木制构件的行为。我们设计了一组实验,将不同种类的圆柱形木钉暴露在类似于野火的不同加热条件下,以模拟这些元素在没有风的情况下的破坏机制。对热降解材料进行三点弯曲试验,得到材料燃烧后的力学响应。假设燃烧销钉的Hookean正交各向异性行为,量纲分析结果表明,销钉的极限强度受到加载过程中可恢复弹性应变的影响,这种影响发生在两种不同的情况下。这些结果不仅对更好地理解断裂机制具有重要意义,而且有利于发展同时风荷载条件下热降解木制构件的破坏理论。
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引用次数: 17
A Concept of the Effective Surface Profile to Predict the Roughness Parameters of Worn Surface 预测磨损表面粗糙度参数的有效表面轮廓概念
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-06-06 DOI: 10.3389/fmech.2019.00031
A. Kovalev, Yazhao Zhang, Cao Hui, Y. Meng
A new concept of the effective surface profile is proposed to facilitate the prediction of the wear texture on a surface under linear sliding conditions. The effective surface profile is a 2D phenomenological height characteristic that consist of the asperities of surface superimposed on a plane perpendicular both to the mean surface plane and to the direction of sliding. We hope to present a clear and compelling argument favoring the use of the effective surface profile as a versatile tool for characterization of rough surface subjected to an abrasive wear, calculation of contact characteristic at the sliding friction and for prediction of evolution of roughness parameters from virgin to the worn surfaces that being formed due to the mechanical wear. The effective surface profile can be successfully applied as for investigations of sliding abrasive wear under dry or lubricated conditions.
为了预测线性滑动条件下表面的磨损织构,提出了有效表面轮廓的新概念。有效表面轮廓是一个二维现象高度特征,由表面的凹凸不平叠加在垂直于平均表面和滑动方向的平面上组成。我们希望提出一个清晰而令人信服的论点,支持使用有效表面轮廓作为一种通用工具,用于表征受磨料磨损的粗糙表面,计算滑动摩擦时的接触特性,以及预测由于机械磨损而形成的从原始表面到磨损表面的粗糙度参数的演变。有效表面轮廓可以成功地应用于研究在干燥或润滑条件下的滑动磨料磨损。
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引用次数: 9
Ragone Relations for Thermal Energy Storage Technologies 热储能技术的Ragone关系
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-06-04 DOI: 10.3389/fmech.2019.00029
K. Yazawa, P. Shamberger, T. Fisher
The Ragone relation is a facile approach to assess and compare electro-chemical battery performance in terms of two critical performance parameters: power density and energy density. This power and energy nexus is equally relevant for thermal energy storage materials for thermal management applications that require a balance between energy storage capacity and on-demand cooling or heating rates. Here, thermal energy storage is evaluated for sensible heating and for phase-change materials (PCMs). We propose an analytic expression using a lumped mass model for thermal storage through an analogy with heat diffusion that allows for intuitive mapping of materials and components in power-energy space. In addition, a previously proposed figure-of-merit, $eta_q$, describing the intrinsic capability of PCMs to rapidly absorb or discharge heat is placed in the context of the thermal Ragone (power-energy) relation. This figure of merit serves as a proxy for the cooling power of PCMs and single-phase materials to store thermal energy. Thus, $eta_q$ plotted against energy density can serve graphically to illustrate performance tradeoffs between different thermal storage materials, as well as composites composed of different materials.
Ragone关系是根据两个关键性能参数(功率密度和能量密度)来评估和比较电化学电池性能的一种简便方法。这种功率和能量联系同样适用于热管理应用的热能储存材料,这些应用需要在能量储存能力和按需冷却或加热速率之间取得平衡。本文对感热和相变材料(PCMs)的热能储存进行了评估。我们提出了一个使用集中质量模型的解析表达式,通过与热扩散的类比,可以直观地映射功率-能量空间中的材料和组件。此外,先前提出的一个描述pcm快速吸收或释放热量的内在能力的品质图$eta_q$被置于热Ragone(功率-能量)关系的背景下。这个数值可以作为pcm和单相材料储存热能的冷却能力的代表。因此,根据能量密度绘制的$eta_q$可以图形化地说明不同储热材料之间的性能权衡,以及由不同材料组成的复合材料。
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引用次数: 13
Artificial Neural Networks (ANNs) as a Novel Modeling Technique in Tribology 人工神经网络(ANNs)作为一种新的摩擦学建模技术
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-05-29 DOI: 10.3389/fmech.2019.00030
I. Argatov
In the present paper, artificial neural networks (ANNs) are considered from a mathematical modelling point of view. A short introduction to feedforward neural networks is outlined, including multilayer perceptrons (MLPs) and radial basis function (RBF) networks. Examples of their applications in tribological studies are given, and important features of the data-driven modelling paradigm are discussed.
本文从数学建模的角度考虑了人工神经网络。简要介绍了前馈神经网络,包括多层感知器(mlp)和径向基函数(RBF)网络。给出了它们在摩擦学研究中的应用实例,并讨论了数据驱动建模范式的重要特征。
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引用次数: 49
Are There Limits to Superlubricity of Graphene in Hard, Rough Contacts? 石墨烯在坚硬粗糙接触中的超润滑性是否存在限制?
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-05-22 DOI: 10.3389/fmech.2019.00028
M. Müser
Yes, there are. They result from the splitting of a large correlated contact into many small patches. When the lubricant consists of thin solid sheets, like graphene, the patches are expected to act independently from each other. Crude estimates for the friction forces between hard, stiff solids with randomly rough surfaces are given, which apply to surfaces with Hurst roughness exponents H > 0.5. The estimates are obtained by combining realistic contact-patch-size distributions with friction-load relations deduced for isolated contact patches. The analysis reveals that load is carried predominantly by large patches, while most frictional forces stem from small contact patches. Low friction is favored when the root-mean-square height gradients are small, while a large roll-off wavelength and thus large root-mean-square roughness is predicted to lead to small friction. Moreover, friction is found to increase sublinearly with load in a nominally flat, structurally lubric contact.
是的,有。它们是由一个大的相关接触分裂成许多小块造成的。当润滑剂由像石墨烯这样的薄固体片组成时,这些小块预计会相互独立地起作用。给出了具有随机粗糙表面的坚硬固体之间摩擦力的粗略估计,该估计适用于Hurst粗糙度指数H > 0.5的表面。该估计是通过结合实际接触贴片尺寸分布和孤立接触贴片的摩擦载荷关系得到的。分析表明,载荷主要由大的接触片承载,而大部分摩擦力来自小的接触片。当均方根高度梯度小时,摩擦力小,而滚转波长大,均方根粗糙度大,摩擦力小。此外,在名义上平坦的、结构上光滑的接触中,摩擦力随载荷呈次线性增加。
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引用次数: 3
Controlling Friction With External Electric or Magnetic Fields: 25 Examples 用外部电场或磁场控制摩擦:25个例子
IF 2.3 Q2 ENGINEERING, MECHANICAL Pub Date : 2019-05-21 DOI: 10.3389/fmech.2019.00022
J. Krim
Studies of the fundamental origins of friction have undergone rapid progress in recent years, providing valuable information on the relative contributions of electronic, magnetic, electrostatic and phononic dissipative mechanisms. They are now evolving into methods that allow active control of nano and/or meso scale friction through tuning of magnetic and electric fields external to the contact. These methods constitute an area of rapidly growing interest, as they address one of tribology’s present day grand challenges: achieving in situ control of friction levels without removing and replacing lubricant materials situated within inaccessible confines of a contact. In this minireview, 25 examples of electromagnetic tuning of friction are overviewed, with examples spanning atomic to macro scale systems to demonstrate the variety and versatility of approaches that have been reported in the literature. Applications include, but are not limited to triboelectric generators, geological drilling, automotive braking and efficiency, spacecraft systems, biological systems and magnetic spintronics. Experimental methods for measuring the impact of electric or magnetic fields on friction include AFM, SFA, QCM, pin-on-disk, hard disk head- substrate, MEMS and NEMS based tribometers, and optical spectroscopies. Computational and theoretical approaches include analytic, equilibrium and nonequilbrium Monte Carlo simulations.
近年来,对摩擦基本起源的研究取得了快速进展,为电子、磁性、静电和声子耗散机制的相对贡献提供了有价值的信息。它们现在正在演变成通过调节接触面外部的磁场和电场来主动控制纳米和/或中尺度摩擦的方法。这些方法构成了一个快速增长的兴趣领域,因为它们解决了摩擦学目前面临的重大挑战之一:实现摩擦水平的原位控制,而无需移除和更换位于接触范围内的润滑剂材料。在这篇小型综述中,概述了25个摩擦电磁调谐的例子,其中包括从原子到宏观尺度系统的例子,以展示文献中报道的方法的多样性和多功能性。应用包括但不限于摩擦发电机、地质钻探、汽车制动和效率、航天器系统、生物系统和磁自旋电子学。用于测量电场或磁场对摩擦影响的实验方法包括AFM, SFA, QCM, pin-on-disk,硬盘头-衬底,MEMS和NEMS摩擦计,以及光谱学。计算和理论方法包括解析、平衡和非平衡蒙特卡罗模拟。
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引用次数: 31
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Frontiers in Mechanical Engineering
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