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Age and Geochemistry of Basite-Ultrabasite Intrusions of Saltych Anticlinorium (West Azov) 西亚速海盐闪背斜中基岩-超基岩侵入岩年龄及地球化学特征
IF 0.2 Pub Date : 2021-01-01 DOI: 10.15407/mineraljournal.43.04.063
G. Artemenko, L. Stepanyuk, I. Samborska, B. Borodynya, I. Shvaika, K. Gogolev, L. Proskurka
In the Saltych anticlinorium of the West Azov, small intrusions of rocks of basic and ultrabasic composition are known in the middle reaches of the Obitochna, Kiltychiya and Burtychiya rivers and in the upper reaches of the Obitochna river. They are composed from amphibolized peridotites, pyroxenites, actinolithites, tremolithites, hornblendites, amphibole and other shales. These intrusions are considered "fractured intrusions", which are rooted in the already deployed rocks of the Archean age. In the stratigraphic scheme they are referred to the Novoselytske association. Intrusions break through the veins of syenites, pegmatites and aplite-like granites. Metaultrabasites, according to I.S. Usenko and G.L. Kravchenko, these are ultrabasic rocks of the normal series, which were formed, probably, because of differentiation of basaltic magma. The main and ultrabasic rocks of these intrusions have not been studied enough yet — their age, geodynamic conditions of formation have not been determined, the potential for minerals has not been fully revealed. For this purpose, we determined the microelement composition of meta-ultrabasites, metabasites and acid rocks by the ICP MS method and determined the age of monazite from veins of aplite-like granites that break through the metapyroxenites of the Kamyshuvatka intrusion. According to the obtained geochemical and mineralogical data, the vein rocks of medium and acid composition, which break through the intrusions of the ultrabasite-basite composition at the Saltych anticlinorium, have a core genesis. Zircon in them is relict, and syngenetic monazite was found only in the veins of aplite-like granites that break through the metapyroxenites of the Kamyshuvatka intrusion. According to the dating of this monazite, it has been determined that the upper age limit for the formation of intrusions of the ultrabasite-basite composition of the Novoselytske association is 2051.8±3.8 Ma. Peridotites and pyroxenites of these intrusions could be formed from melts of the depleted upper mantle, which were fractionated in intermediate magmatic chambers. In peridotites (#mg = 0.74-0.86) of the Kamyshuvatka intrusion and intrusion near the Reva farm, the Ni content (510-826 ppm) is lower than that of Clark for ultrabasic rocks, and the chromium content at the level of Clark and below it is Cr — 1250-2260 ppm. Positive anomalies of Ti and Eu indicate the processes of fractionation of the original magma of pyroxenites. The formation of intrusions of the ultrabasite-basite composition of the Saltych anticlinorium of the Azov megablock is probably connected with the activation of the Earth’s mantle about 2050 million years ago.
在西亚速河的Saltych背斜中,在Obitochna河、Kiltychiya河和Burtychiya河中游和Obitochna河上游发现了基性和超基性组成的小侵入岩。它们由角闪橄榄岩、辉石岩、放光岩、透闪岩、角闪岩、角闪洞等页岩组成。这些侵入体被认为是“断裂侵入体”,它们根植于太古宙已经部署的岩石中。在地层学方案中,它们被称为新塞利茨克组合。侵入体突破了正长岩、伟晶岩和类长晶花岗岩的脉体。变质超基岩,根据I.S. Usenko和G.L. Kravchenko的说法,这些是正常系列的超基性岩石,可能是由于玄武岩岩浆的分化而形成的。这些侵入岩的主岩和超基性岩尚未得到充分的研究——它们的年龄、形成的地球动力学条件尚未确定,矿物潜力尚未完全揭示。为此,我们采用ICP质谱法测定了变质超基岩、变质基岩和酸性岩石的微量元素组成,并从突破Kamyshuvatka岩体变质辉长岩的阿长石样花岗岩脉脉中确定了独居石的年龄。根据获得的地球化学和矿物学资料,该中酸性脉岩突破了盐西背斜超基岩-基岩组成的侵入,具有岩心成因。其中锆石为残余物,同生单独居石仅在突破Kamyshuvatka岩体变质辉长岩的阿长石样花岗岩脉体中发现。根据该独居石的年代测定,确定了新塞利茨克组合超基岩-基岩组成侵入体形成的年龄上限为2051.8±3.8 Ma。这些侵入体的橄榄岩和辉石岩可能是由衰竭的上地幔熔体在中间岩浆室中分馏形成的。在Kamyshuvatka侵入体和Reva农场附近侵入体的橄榄岩(#mg = 0.74 ~ 0.86)中,超基性岩的Ni含量(510 ~ 826 ppm)低于Clark水平,而在Clark水平及以下的铬含量为Cr - 1250 ~ 2260 ppm。钛、铕正异常指示辉石岩原岩浆分馏过程。亚速海巨型陆块盐碱地背斜的超基岩-基岩组成侵入物的形成可能与约2050万年前的地幔活化有关。
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引用次数: 0
Distribution of Arsene and Mercury in the Coal Seam k5 of the Kapitalna Mine, Donbas 顿巴斯Kapitalna矿k5煤层中砷和汞的分布
IF 0.2 Pub Date : 2021-01-01 DOI: 10.15407/mineraljournal.43.04.073
V. Ishkov, Ye.S. Kozii
The aim of the research is to establish the characteristics of the As and Hg distribution, which belong to the main toxic elements of coal, in the coal seam k5 of the minefield Kapitalna (Krasnoarmiiskyi geological and industrial area of Donbas) and their main genetic factors. The applied methods include sampling coal from mine workings and from core-samples duplicates of wells from 1981 to 2014; identification of the inorganic part of the coal seam, macroscopically diagnosed by standard mineralogical methods as sulfide, silicate and carbonate fractions. According to textural and structural features, they are divided into groups of syngenetic and epigenetic origin; the mineral composition of these two groups was determined by optical microscopy using MIN-8 and MBS-9 microscopes and by X-ray diffraction analysis. Fractional analysis of the density of coal from duplicates of the original samples was carried out to identify the substance of the inorganic part of the coal seam; Arsenic and Hg contents were determined by atomic absorption analysis in the substance of all initial and final samples; normalization of all values of Hg and As concentrations and technological parameters of coal; statistical processing of all geochemical information using Excel 2016 and Statistica 11.0, which included correlation and regression analysis; calculation of the coefficients of affinity of Hg and As with organic matter, the coefficients of the reduced concentration of the investigated elements, the coefficients of the reduced extraction of these elements in the fraction of different densities; construction of maps of normalized isoconcentrates; changes in the regional component of normalized content and gradient of normalized content were performed using the program Surfer 11. We found a genetic link between high concentrations of As and Hg in the coal seam k5 of the minefield Kapitalna with tectonic features, the Central overthrust and associated zones of increased fracturing. The accumulation of As and Hg in the coal seam k5 of the minefield Kapitalna, bound to the organic component of the coal seam, is epigenetic. The practical significance of the work is that their high concentration in the high-density fractions of coal will lead to their gravitational accumulation in the waste.
研究的目的是确定Kapitalna矿区(顿巴斯Krasnoarmiiskyi地质和工业区)k5煤层中煤中主要有毒元素As和Hg的分布特征及其主要成因。应用的方法包括1981 ~ 2014年采场煤样和井芯样副本煤样采样;鉴定了煤层的无机部分,用标准矿物学方法在宏观上诊断为硫化物、硅酸盐和碳酸盐组分。根据构造和构造特征,将其分为同生和表观生成因组;采用MIN-8和MBS-9光学显微镜及x射线衍射分析测定两组样品的矿物组成。对原始样品的复制件进行了煤的密度分数分析,以确定煤层中无机部分的物质;用原子吸收法测定了样品中砷和汞的含量;煤中汞、砷各浓度值及工艺参数归一化;利用Excel 2016和Statistica 11.0对所有地球化学信息进行统计处理,包括相关分析和回归分析;计算Hg和As与有机质的亲和系数、所研究元素的还原浓度系数、不同密度分数中这些元素的还原萃取系数;归一化等浓缩图的构造使用Surfer 11程序执行归一化内容的区域分量和归一化内容的梯度的变化。研究发现,Kapitalna矿区k5煤层中砷、汞的富集与构造特征、中央逆冲构造及相关的压裂加重带有一定的成因联系。Kapitalna矿区k5煤层中砷、汞的富集与煤层的有机成分结合,为表观成因。该研究的实际意义在于,它们在煤的高密度馏分中的高浓度会导致它们在废煤中的重力积累。
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引用次数: 8
Why Ukraine? 为什么乌克兰?
IF 0.2 Pub Date : 2020-11-12 DOI: 10.1093/wentk/9780197532102.003.0001
S. Yekelchyk
Why did Ukraine become a key reference point of American political struggles? In recent years, Ukraine has emerged as the most prominent test case of American support for democracy and liberal economic reforms worldwide. A combination of several factors has made Ukraine and the...
为什么乌克兰会成为美国政治斗争的关键参照点?近年来,乌克兰已成为美国在全球范围内支持民主和自由经济改革的最突出的测试案例。几个因素的结合使得乌克兰和…
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引用次数: 0
The Land and the People 土地与人民
IF 0.2 Pub Date : 2020-11-12 DOI: 10.1093/wentk/9780197532102.003.0002
S. Yekelchyk
What is Ukraine’s geographical location, and what natural resources and industry does it possess? Ukraine is located in southeastern Europe. Its longest land border, in the east and north, is with Russia; another northern neighbor is Belarus, a post-Soviet state and Russia’s close ally....
乌克兰的地理位置如何?它拥有哪些自然资源和工业?乌克兰位于欧洲东南部。其东部和北部最长的陆地边界与俄罗斯接壤;另一个北方邻国是白俄罗斯,一个后苏联国家,也是俄罗斯的亲密盟友....
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引用次数: 0
GEOLOGY IN ENVIRONMENTAL MANAGEMENT ISSUES OF THE DONBAS WITHIN THE CONTEXT OF ITS FORTHCOMING RESTORATION 顿巴斯即将恢复的环境管理地质学问题
IF 0.2 Pub Date : 2020-01-01 DOI: 10.15407/mineraljournal.42.01.076
V. Pryvalov, O. Panova, A. Pryvalov
Цитування: квасниця в.м. Імпактні алмази з неогенового розсипу самоткань (середнє Придніпров’я). Міне­ рал. журн. 2020. 42, No 1. с. 00—00. https://doi.org/10.15407/mineraljournal.41.04.003 : Pryvalov V.O., Panova O.A., Pryvalov а.V. Geology in Environmental Management Issues of the Donbas Within the Context of Its Forthcoming Restorat on. Mineral. Jour . (Ukrai e), 42, No. 1, Kyiv, UA, pp. 76-85. https:// doi.org/10.15407/mineraljournal.42.01.076 https://doi.org/10.15407/mineraljournal.42.01.076 uDC 658.56: 622.8.012.2:519.71 V.O. Pryvalov, DrSc (Geology), Prof., Leading Researcher M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of ukraine 34, Acad. Palladin Ave., kyiv, ukraine, 03142 E-mail: vitaliy.privalov@gmail.com http://orcid.org/0000-0002-1429-6960 O.A. Panova, PhD (Geology & Mineralogy), Senior Research Fellow, Leading Researcher. M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of ukraine 34, Acad. Palladin Ave., kyiv, ukraine, 03142 E-mail: olena.panova@gmail.com http://orcid.org/0000-0002-3813-5125 А.V. Pryvalov, BSc (Environmental Geosciences), MSc student Czech university of Life Sciences kamýcká 129, 165 00 Praha-Suchdol E-mail: andriy.privalov@gmail.com https://orcid.org/0000-0002-3045-7111
引文:Kvasnitsia V.M.从新基因染色自织物(中间)中提取的钻石。我不知道。新闻。2020. 42, No 1. C.国际合作00—00. https://doi.org/10.15407/mineraljournal.41.04.003:Pryvalov V.O.,Panova O.A.,Pryvalov A.V.Geology in Environmental Management Issues of the Donbas within the context of its forthcoming restorat on mineral.Jour . (Ukrai e), 42, No. 1, Kyiv, UA, pp. 76-85. https:// doi.org/10.15407/mineraljournal.42.01.076 https://doi.org/10.15407/mineraljournal.42.01.076 uDC 658.56: 622.8.012.2:519.71 V.O. Pryvalov, DrSc (Geology), Prof., Leading Researcher M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of ukraine 34, Acad. Palladin Ave., kyiv, ukraine, 03142 E-mail: vitaliy.privalov@gmail.com http://orcid.org/0000-0002-1429-6960 O.A. Panova, PhD (Geology & Mineralogy), Senior Research Fellow, Leading Researcher. M.P. Semenenko Institute of Geochemistry, Mineralogy and Ore Formation of the NAS of ukraine 34, Acad. Palladin Ave., kyiv, ukraine, 03142 E-mail: olena.panova@gmail.com http://orcid.org/0000-0002-3813-5125A.V.Pryvalov,BSC(Environmental Geosciences),MSC Student Czech University of Life Sciences Kamýcká129,165 00 Praha-Suchdol e-mail:andriy.privalov@gmail.com https://orcid.org/0000-0002-3045-7111
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引用次数: 1
Diamonds from Terrigenous Deposits of Dniester and Southern Bug River Basins 德涅斯特和南布格河盆地陆源矿床中的钻石
IF 0.2 Pub Date : 2020-01-01 DOI: 10.15407/mineraljournal.42.03.003
V. Kvasnytsya
{"title":"Diamonds from Terrigenous Deposits of Dniester and Southern Bug River Basins","authors":"V. Kvasnytsya","doi":"10.15407/mineraljournal.42.03.003","DOIUrl":"https://doi.org/10.15407/mineraljournal.42.03.003","url":null,"abstract":"","PeriodicalId":53834,"journal":{"name":"Mineralogical Journal-Ukraine","volume":null,"pages":null},"PeriodicalIF":0.2,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67124588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Pyritization of the Middle Carboniferous Sandstones of the Donbas 顿巴斯中石炭统砂岩的黄铁矿化作用
IF 0.2 Pub Date : 2020-01-01 DOI: 10.15407/mineraljournal.42.02.014
L. F. Mametova, A. Mirek, Ye.S. Kozii
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引用次数: 8
NEW ASPECTS OF FLUID INCLUSIONS application for reconstruction OF MINERAL formation PT-CONDITIONS 流体包裹体在矿物地层pt条件重建中的应用新进展
IF 0.2 Pub Date : 2020-01-01 DOI: 10.15407/mineraljournal.42.01.024
D. Voznyak, V. Syomka, V. Belskyi
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引用次数: 0
GEOCHRONOLOGY OF MAGMATIC ROCKS OF OSNITSK BLOCK (UKRAINIAN SHIELD) ON ZIRCON AND TITANITE 奥斯尼茨克地块(乌克兰盾)岩浆岩的锆石和钛矿年代学研究
IF 0.2 Pub Date : 2020-01-01 DOI: 10.15407/mineraljournal.42.01.066
L. Stepanyuk, O. Vysotsky, T. Dovbush, O. Bilan, N. A. Kovalenko
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引用次数: 1
The Petrology of Gabbroids of the Anagram Islands (Wilhelm Archipelago, West Antarctica) 南极西部威廉群岛(Anagram Islands, Wilhelm Archipelago, West Antarctica)长石斛的岩石学
IF 0.2 Pub Date : 2020-01-01 DOI: 10.15407/mineraljournal.42.04.069
O. Mytrokhyn, V. Bakhmutov, A. Aleksieienko, T. Mytrokhina
The Anagram Islands are located near the Graham Coast of West Antarctica not far from the Ukrainian Antarctic Station "Akademik Vernadsky". Gabbroids that are probably Cretaceous in age predominate in the geological structure of the Anagram Islands. New data on the mode of occurrence of the Anagram gabbroids and their layering were obtained during the seasonal field works of the Ukrainian Antarctic Expeditions in 2017, 2019-2020 years. Samples of the gabbroids were examined by optical microscopy, electron microscopy and microprobe analysis as well as by measuring of anisotropy of magnetic susceptibility of rocks. The goal of the research was to clarify the geological position and petrographic features of the Anagram gabbroids, to determine the typomorphic features of rock-forming minerals, and to clarify the origin of the layering in gabbroids. It was determined that the bottom part of a large layered gabbroid intrusion is fragmentarily exposed on the Anagram Islands. The continuation of the intrusion is expected in the northeastern and southeastern directions. It was established that primary magmatic textures and mineral composition are preserved in the gabbroids despite the development of metamorphic amphibolization. The gabbroids show typical cumulative textures of magmatic origin. The main cumulative phases are plagioclase (An70-95), clinopyroxene (Wo41-49En34-47), orthopyroxene (Wo2-4En49-71), olivine (Fo67-69), Ti-magnetite and ilmenite. It is proved that the fine rhythmic-gradational layering in the gabbroids was formed by gravitational precipitation of the cumulative minerals on the bottom of the magma chamber and their further sorting by specific gravity due to convection currents. Cryptic layering is firstly discovered in the Anagram gabbroids and is explained by the processes of crystallization differentiation. The latter caused the accumulation of the most calcium plagioclases and the most magnesian mafic minerals in the layered gabbroids forming the bottom part of the intrusion. The present subvertical position of layering is explained by tectonic deformation that resulted in the tilting of the investigated section of the Anagram gabbroid intrusion. This confirmed by the studying of magnetic texture of the gabbroids (by the anisotropy of magnetic susceptibility data).
Anagram群岛位于南极洲西部的格雷厄姆海岸附近,距离乌克兰南极站“Akademik Vernadsky”不远。阿格拉姆群岛的地质构造以白垩纪时期的辉长岩为主。在2017年、2019-2020年乌克兰南极考察队的季节性野外工作中,获得了Anagram辉长岩的产状模式及其分层的新数据。通过光学显微镜、电子显微镜、探针分析和岩石磁化率各向异性测量对辉长岩样品进行了研究。研究的目的是明确变形辉长岩的地质位置和岩石学特征,确定造岩矿物的标型特征,明确辉长岩的分层成因。结果表明,在阿格拉姆群岛上,一大型层状辉长岩侵入体的底部是破碎暴露的。预计东北和东南方向的入侵将继续。结果表明,尽管发育变质角闪作用,但辉长岩中仍保留了原始岩浆结构和矿物组成。辉长岩具有典型的岩浆成因累积结构。主要沉积相为斜长石(An70-95)、斜辉石(Wo41-49En34-47)、正辉石(Wo2-4En49-71)、橄榄石(Fo67-69)、钛磁铁矿和钛铁矿。证明了辉长岩中的精细韵律级配是由岩浆库底部积聚的矿物重力沉淀和对流作用下的比重分选作用形成的。隐层是在变位辉长岩中首次发现的,并用结晶分异过程来解释。后者在侵入体底部的层状辉长岩中聚集了最多的钙斜长石和最多的镁质矿物。构造变形导致了变位辉长岩侵入剖面的倾斜,解释了目前的亚垂向分层位置。对辉长岩磁性结构的研究(磁化率数据的各向异性)证实了这一点。
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引用次数: 1
期刊
Mineralogical Journal-Ukraine
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