Poorly preserved belemnite samples are often disregarded in palaeoclimatology and palaeoceanography research within the Eastern Pontides (NE Türkiye), which is part of the Alp-Himalayan Belt that experienced extensive orogenic and magmatic activity. Late Jurassic–Early Cretaceous carbonates are widely exposed in the Eastern Pontides, having undergone a complex diagenetic history since deposition. Belemnite rostra samples from the uppermost part of the carbonate sequence (Aptian–Albian strata) exhibit diagenetic overprints. These poorly preserved belemnite samples can serve as excellent archives for basin early diagenetic evolution. However, the diagenetic evolution of these poorly preserved belemnite samples has not been fully studied within the context of the diagenetic evolution of the basin. Thus, this study presents a comprehensive dataset including isotope analyses (Sr/C/O) and trace element, including REE chemistry of these belemnite samples to elucidate the basin's early diagenetic history. The studied samples are commonly dark grey and show visible signs of diagenetic processes, including dissolution, silicification and pyrite mineralisation. These samples show high Fe (1259–5176 ppm; ave. 2859 ppm) and Mn (77–387 ppm; ave. 232 ppm), low Sr/Mn (0.63–12.33; ave. 3.47) and low Sr/Rb (42–568, ave. 200) values, consistent with a diagenetic alteration. Interestingly, carbon and strontium isotopes of belemnite samples correlate well with those from well-preserved belemnite rostra from the Aptian–Albian strata. They exhibit a diagnostic sea water REEN signature, including mildly enriched Gd/Gd* ratios of 1.04–1.48 (ave. 1.24) and high La/La* of 1.54–5.50 (ave. 2.51) and Ce/Ce* of 0.46–0.60 (ave. 0.51). However, slight LREE enrichment is observed, with La/LuN ratios ranging from 0.81 to 1.74 (average: 1.21) and La/YbN ratios from 0.9 to 1.79 (average: 1.22). A slight positive Eu anomaly is also present, with Eu/Eu* ratios between 1.15 and 1.55 (average 1.36). Y/Ho ratios range from 35.00 to 45.00 (average 39.84), and Sm/Yb ratios from 1.70 to 4.05 (average 2.42). These geochemical characteristics, along with δ18O values that deviate from typical marine carbonate signatures, suggest a subsequent low-temperature hydrothermal alteration, potentially triggered by hydrothermal activity associated with an Early Cretaceous magmatic event. This finding underscores the significance of analysing REEs in poorly preserved belemnite rostra, offering valuable insights into early diagenetic pathways, dissolution/precipitation processes and water–rock interaction.
{"title":"Trace elements, rare earth elements and isotopes of poorly preserved fossils from lower Cretaceous carbonates (Eastern Black Sea): Implications for early diagenetic alteration","authors":"Merve Özyurt","doi":"10.1002/dep2.70026","DOIUrl":"https://doi.org/10.1002/dep2.70026","url":null,"abstract":"<p>Poorly preserved belemnite samples are often disregarded in palaeoclimatology and palaeoceanography research within the Eastern Pontides (NE Türkiye), which is part of the Alp-Himalayan Belt that experienced extensive orogenic and magmatic activity. Late Jurassic–Early Cretaceous carbonates are widely exposed in the Eastern Pontides, having undergone a complex diagenetic history since deposition. Belemnite rostra samples from the uppermost part of the carbonate sequence (Aptian–Albian strata) exhibit diagenetic overprints. These poorly preserved belemnite samples can serve as excellent archives for basin early diagenetic evolution. However, the diagenetic evolution of these poorly preserved belemnite samples has not been fully studied within the context of the diagenetic evolution of the basin. Thus, this study presents a comprehensive dataset including isotope analyses (Sr/C/O) and trace element, including REE chemistry of these belemnite samples to elucidate the basin's early diagenetic history. The studied samples are commonly dark grey and show visible signs of diagenetic processes, including dissolution, silicification and pyrite mineralisation. These samples show high Fe (1259–5176 ppm; ave. 2859 ppm) and Mn (77–387 ppm; ave. 232 ppm), low Sr/Mn (0.63–12.33; ave. 3.47) and low Sr/Rb (42–568, ave. 200) values, consistent with a diagenetic alteration. Interestingly, carbon and strontium isotopes of belemnite samples correlate well with those from well-preserved belemnite rostra from the Aptian–Albian strata. They exhibit a diagnostic sea water REE<sub>N</sub> signature, including mildly enriched Gd/Gd* ratios of 1.04–1.48 (ave. 1.24) and high La/La* of 1.54–5.50 (ave. 2.51) and Ce/Ce* of 0.46–0.60 (ave. 0.51). However, slight LREE enrichment is observed, with La/LuN ratios ranging from 0.81 to 1.74 (average: 1.21) and La/YbN ratios from 0.9 to 1.79 (average: 1.22). A slight positive Eu anomaly is also present, with Eu/Eu* ratios between 1.15 and 1.55 (average 1.36). Y/Ho ratios range from 35.00 to 45.00 (average 39.84), and Sm/Yb ratios from 1.70 to 4.05 (average 2.42). These geochemical characteristics, along with δ<sup>18</sup>O values that deviate from typical marine carbonate signatures, suggest a subsequent low-temperature hydrothermal alteration, potentially triggered by hydrothermal activity associated with an Early Cretaceous magmatic event. This finding underscores the significance of analysing REEs in poorly preserved belemnite rostra, offering valuable insights into early diagenetic pathways, dissolution/precipitation processes and water–rock interaction.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 4","pages":"1107-1131"},"PeriodicalIF":2.0,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70026","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Eduardo Islas-Dominguez, Eberhard Gischler, J. Harold Hudson
The cover of living reef-building corals has declined due to ocean warming, acidification, pollution and disease outbreaks. This decline endangers future reef development relying on acroporid corals, which are highly sensitive to environmental changes. Given these threats, there is a need for accretion models that do not rely on species dominance. To assess the potential of non-acroporid framework and identify the key variables controlling their accretion, we reconstructed the internal structure and Holocene development of Bermuda patch reefs, lacking acroporids. Four rotary drill cores and two vibrocores recovered sequences composed of five facies in decreasing abundance: a framework of massive, stress-tolerant corals, unconsolidated skeletal sand and gravel, coralline-algal bindstone, Halimeda floatstone and peat. Radiocarbon dating of corals and peat shows that patch reefs developed in two stages. From 7 to 4 kyr B.P., during a sustained sea-level rise, the coral framework facies accreted vertically, while the unconsolidated facies filled interstitial sand pockets in intermediate water depths. From 4 kyr B.P. onwards, during a reduced rate of sea-level rise, vertical accretion has continued with a decline in coral diversity. Accretion was primarily controlled by massive coral framework construction and variation in environmental energy, turbidity and bioerosion, which collectively shaped the size, diversity and preservation of the framework. This led to a suppressed, steady vertical accretion rate of 2.18 ± 0.66 m/kyr on average. Although lower than that of acroporid reefs in the western Atlantic, the accretion rate did not decline throughout the Holocene, even as sea-level rise slowed over the last 4 ka. The suppressed accretion rate resulted in submerged keep-up reefs thriving in several metres of water during the mid-late Holocene. This growth mode highlights the potential of coral reefs to develop under different controls beyond coral species dominance, a mode that could be applied to current and future coral reef development.
{"title":"Holocene development of submerged keep-up patch reefs on Bermuda without acroporids: A model of future reef accretion","authors":"Eduardo Islas-Dominguez, Eberhard Gischler, J. Harold Hudson","doi":"10.1002/dep2.70023","DOIUrl":"https://doi.org/10.1002/dep2.70023","url":null,"abstract":"<p>The cover of living reef-building corals has declined due to ocean warming, acidification, pollution and disease outbreaks. This decline endangers future reef development relying on acroporid corals, which are highly sensitive to environmental changes. Given these threats, there is a need for accretion models that do not rely on species dominance. To assess the potential of non-acroporid framework and identify the key variables controlling their accretion, we reconstructed the internal structure and Holocene development of Bermuda patch reefs, lacking acroporids. Four rotary drill cores and two vibrocores recovered sequences composed of five facies in decreasing abundance: a framework of massive, stress-tolerant corals, unconsolidated skeletal sand and gravel, coralline-algal bindstone, <i>Halimeda</i> floatstone and peat. Radiocarbon dating of corals and peat shows that patch reefs developed in two stages. From 7 to 4 kyr B.P., during a sustained sea-level rise, the coral framework facies accreted vertically, while the unconsolidated facies filled interstitial sand pockets in intermediate water depths. From 4 kyr B.P. onwards, during a reduced rate of sea-level rise, vertical accretion has continued with a decline in coral diversity. Accretion was primarily controlled by massive coral framework construction and variation in environmental energy, turbidity and bioerosion, which collectively shaped the size, diversity and preservation of the framework. This led to a suppressed, steady vertical accretion rate of 2.18 ± 0.66 m/kyr on average. Although lower than that of acroporid reefs in the western Atlantic, the accretion rate did not decline throughout the Holocene, even as sea-level rise slowed over the last 4 ka. The suppressed accretion rate resulted in submerged keep-up reefs thriving in several metres of water during the mid-late Holocene. This growth mode highlights the potential of coral reefs to develop under different controls beyond coral species dominance, a mode that could be applied to current and future coral reef development.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 5","pages":"1517-1541"},"PeriodicalIF":2.0,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70023","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145572295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. A. Wyman-Feravich, M. Ingalls, J. L. Conroy, R. He, S. Lusk
Carbonate clumped isotopes are a powerful tool for paleoclimate reconstruction due to the ability to reconstruct past changes in both temperature and precipitation-evaporation balance. Here we test the utility of this method on last millennium carbonate lagoonal sediments from Kiritimati, a coral atoll where modern climate variability is driven by interannual changes in the El Niño-Southern Oscillation. We find last millennium lagoonal temperatures from clumped isotopes are cooler than anticipated compared to modern measurements and other paleoclimate reconstructions. This discrepancy is probably due to sediments containing a mixture of high-magnesium calcite derived from primary precipitates and benthic foraminifera and aragonite derived from warm water corals. We employed an inverse mixing model to minimise the impact of vital effects related to coral growth on clumped isotope compositions and found an increasing difference between modelled and measured T(Δ47) values through time. This potentially indicates that the composition of lagoon water became increasingly unique from the coral carbonate formation waters through the last millennium. This study highlights the necessity of detailed understanding of carbonate mineralogy, sedimentology and provenance in interpreting clumped isotope temperature reconstructions.
{"title":"Anomalously cool clumped isotope temperatures in tropical lagoon carbonates","authors":"D. A. Wyman-Feravich, M. Ingalls, J. L. Conroy, R. He, S. Lusk","doi":"10.1002/dep2.70024","DOIUrl":"https://doi.org/10.1002/dep2.70024","url":null,"abstract":"<p>Carbonate clumped isotopes are a powerful tool for paleoclimate reconstruction due to the ability to reconstruct past changes in both temperature and precipitation-evaporation balance. Here we test the utility of this method on last millennium carbonate lagoonal sediments from Kiritimati, a coral atoll where modern climate variability is driven by interannual changes in the El Niño-Southern Oscillation. We find last millennium lagoonal temperatures from clumped isotopes are cooler than anticipated compared to modern measurements and other paleoclimate reconstructions. This discrepancy is probably due to sediments containing a mixture of high-magnesium calcite derived from primary precipitates and benthic foraminifera and aragonite derived from warm water corals. We employed an inverse mixing model to minimise the impact of vital effects related to coral growth on clumped isotope compositions and found an increasing difference between modelled and measured T(Δ<sub>47</sub>) values through time. This potentially indicates that the composition of lagoon water became increasingly unique from the coral carbonate formation waters through the last millennium. This study highlights the necessity of detailed understanding of carbonate mineralogy, sedimentology and provenance in interpreting clumped isotope temperature reconstructions.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 5","pages":"1479-1496"},"PeriodicalIF":2.0,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70024","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145581382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Deyan Zhang, François-Nicolas Krencker, Stefan Huck, Ulrich Heimhofer
This study represents a detailed analysis of a stratigraphic section of Oxfordian (Late Jurassic) age with the aim to reconstruct the facies pattern and sequence-stratigraphic evolution, followed by a discussion of the dominant controls on shallow marine carbonate platform sedimentation in the Lower Saxony Basin (LSB). During the Oxfordian, the LSB was covered by a shallow epicontinental sea, in which a thick succession of marine limestones and marls was deposited. The stratiform Oxfordian carbonate bodies hold significant economic potential due to their ability to form hydrocarbon reservoirs or targets for future geothermal exploration. The scarcity of open-marine biostratigraphic marker fossils and the presence of numerous sedimentary gaps pose significant challenges for establishing reliable correlations with Oxfordian deposits globally. This study focuses on the Oxfordian Korallenoolith Formation, which is well exposed in the Bisperode section located ~40 km SW of Hannover. The ~126 m thick section was described bed-by-bed during fieldwork and complemented by 73 petrographic thin sections that were analysed for carbonate microfacies. Based on differences in grain and mud composition and primary sedimentary fabrics, an integrated log of the Bisperode quarry was constructed. Seven facies types (FTs) and 13 microfacies types (MFs) are characterised upon which a reef-bearing carbonate ramp model was built. Following the magnitude of the transgressive/regressive trends concept, three low-order sequences are recognised, which are composed of eight higher order sequences. The low-order sequences correlate well to the established sequence-stratigraphic model and the higher order sequences point to a possible control of their stacking pattern by Milankovitch long eccentricity cycles. This study is important because it helps to better understand the link between the stacking pattern of Oxfordian strata in the LSB and allocyclic processes. It thus provides a foundation for basinwide and inter-basin sequence-stratigraphic correlation, allowing future global chemostratigraphic comparisons and providing valuable insights into the synchronicity of geological events.
{"title":"Carbonate microfacies and transgressive-regressive sequences of Oxfordian shallow-water limestones (Korallenoolith, Lower Saxony Basin)","authors":"Deyan Zhang, François-Nicolas Krencker, Stefan Huck, Ulrich Heimhofer","doi":"10.1002/dep2.70022","DOIUrl":"https://doi.org/10.1002/dep2.70022","url":null,"abstract":"<p>This study represents a detailed analysis of a stratigraphic section of Oxfordian (Late Jurassic) age with the aim to reconstruct the facies pattern and sequence-stratigraphic evolution, followed by a discussion of the dominant controls on shallow marine carbonate platform sedimentation in the Lower Saxony Basin (LSB). During the Oxfordian, the LSB was covered by a shallow epicontinental sea, in which a thick succession of marine limestones and marls was deposited. The stratiform Oxfordian carbonate bodies hold significant economic potential due to their ability to form hydrocarbon reservoirs or targets for future geothermal exploration. The scarcity of open-marine biostratigraphic marker fossils and the presence of numerous sedimentary gaps pose significant challenges for establishing reliable correlations with Oxfordian deposits globally. This study focuses on the Oxfordian Korallenoolith Formation, which is well exposed in the Bisperode section located ~40 km SW of Hannover. The ~126 m thick section was described bed-by-bed during fieldwork and complemented by 73 petrographic thin sections that were analysed for carbonate microfacies. Based on differences in grain and mud composition and primary sedimentary fabrics, an integrated log of the Bisperode quarry was constructed. Seven facies types (FTs) and 13 microfacies types (MFs) are characterised upon which a reef-bearing carbonate ramp model was built. Following the magnitude of the transgressive/regressive trends concept, three low-order sequences are recognised, which are composed of eight higher order sequences. The low-order sequences correlate well to the established sequence-stratigraphic model and the higher order sequences point to a possible control of their stacking pattern by Milankovitch long eccentricity cycles. This study is important because it helps to better understand the link between the stacking pattern of Oxfordian strata in the LSB and allocyclic processes. It thus provides a foundation for basinwide and inter-basin sequence-stratigraphic correlation, allowing future global chemostratigraphic comparisons and providing valuable insights into the synchronicity of geological events.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 4","pages":"1084-1106"},"PeriodicalIF":2.0,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70022","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Eberhard Gischler, Dominik Schmitt, Annika Wiegand, Hermann Behling, Lyudmila Shumilovskikh, Martin Melles, Volker Wennrich, Elija Nolte, Jozef Grego, Flavio S. Anselmetti, Hendrik Vogel, Daniel Birgel, Jörn Peckmann
The Great Blue Hole is a prominent flooded karst sinkhole, located in the lagoon of Lighthouse Reef atoll off the coast of Belize. Short cores recovered from varved bottom sediments have been used in previous studies as climate and cyclone archives covering as much as the past ca 1.7 ka BP. A new 30 m long sediment core, encompassing the entire Holocene and the latest Pleistocene, allows a reconstruction of the development of this geoscientifically significant site in the light of the postglacial and Holocene sea-level rise. The sedimentary succession in the core is tripartite. The lowermost sedimentary unit A (30.0–28.6 m) comprises grey-brown to black organic-rich carbonate sediments, which contain freshwater snails (Pyrgophorus), tropical forest pollen (Myrtaceae) and a low-diversity dinocyst assemblage. The intermediate unit B (28.6–24.65 m) is a dark greyish-green to greyish-brown, weakly laminated carbonate silt, which comprises marine fossils, that is, euryhaline foraminifera (Elphidium) and Halimeda (codiacean algal) platelets. Unit B contains abundant red mangrove (Rhizophora) pollen and a dinocyst assemblage indicating high productivity in surface waters. The uppermost unit C (24.65–0 m) is an annually layered buff and light green carbonate silt with abundant marine fossils. A total of 574 intercalated, coarser-grained and lighter-coloured event (storm) beds usually rich in Halimeda and coral fragments were identified in unit C. Fully marine conditions, including trophic seasonality, are also indicated by the dinocyst spectrum. The pollen spectrum derives from a variety of trees (largely pine, oak, podocarp), shrubs and herbs. The sedimentary succession represents the transition from an initial terrestrial cenote phase on a vegetated limestone island (unit A: 12.5–7.2 ka BP), via a subsequent restricted marine phase on an initially flooded carbonate platform with mangrove swamps (unit B: 7.2–5.7 ka BP), to a fully marine phase in an open, well-circulated atoll lagoon (unit C: 5.7–0 ka BP).
大蓝洞是一个突出的被水淹没的喀斯特天坑,位于伯利兹海岸外灯塔礁环礁的泻湖上。在以前的研究中,从破碎的底部沉积物中恢复的短岩心被用作覆盖过去约1.7 ka BP的气候和气旋档案。一个新的30米长的沉积物岩心,包含了整个全新世和最新更新世,允许在冰川后和全新世海平面上升的情况下重建这个具有地球科学意义的地点的发展。岩心内的沉积演替为三方演替。最下面的沉积单元A (30.0 ~ 28.6 m)为灰褐色至黑色富有机质碳酸盐沉积物,包含淡水蜗牛(Pyrgophorus)、热带森林花粉(myrtacae)和低多样性的dinocyst组合。中间单元B (28.6 ~ 24.65 m)为深灰绿色~灰褐色的弱层状碳酸盐淤泥,由海相化石组成,即广盐有孔虫(Elphidium)和halimmeda (codiacian藻类)。单元B含有丰富的红树(根草)花粉和一个二囊组合,表明在地表水具有很高的生产力。最上层C单元(24.65 ~ 0 m)为浅绿色浅绿色碳酸盐岩粉砂,呈浅绿色年层状,具有丰富的海相化石。在c单元共发现了574个间插、粗粒和浅色的事件(风暴)床,通常富含海藻和珊瑚碎片。生物囊谱也表明了完全的海洋条件,包括营养季节性。花粉谱来自各种树木(主要是松树、橡树、足足树)、灌木和草本植物。沉积演替代表了从植被覆盖的石灰岩岛屿上的初始陆生天然井阶段(单元a: 12.5-7.2 ka BP),通过随后在具有红树林沼泽的初始淹没碳酸盐台地上的有限海相阶段(单元B: 7.2-5.7 ka BP),到开放的、循环良好的环礁泻湖的完全海相阶段(单元C: 5.7-0 ka BP)的过渡。
{"title":"Late Pleistocene to Holocene sedimentation in the Great Blue Hole (Lighthouse Reef, Belize): Results from a 30 m long core","authors":"Eberhard Gischler, Dominik Schmitt, Annika Wiegand, Hermann Behling, Lyudmila Shumilovskikh, Martin Melles, Volker Wennrich, Elija Nolte, Jozef Grego, Flavio S. Anselmetti, Hendrik Vogel, Daniel Birgel, Jörn Peckmann","doi":"10.1002/dep2.70021","DOIUrl":"https://doi.org/10.1002/dep2.70021","url":null,"abstract":"<p>The Great Blue Hole is a prominent flooded karst sinkhole, located in the lagoon of Lighthouse Reef atoll off the coast of Belize. Short cores recovered from varved bottom sediments have been used in previous studies as climate and cyclone archives covering as much as the past <i>ca</i> 1.7 ka BP. A new 30 m long sediment core, encompassing the entire Holocene and the latest Pleistocene, allows a reconstruction of the development of this geoscientifically significant site in the light of the postglacial and Holocene sea-level rise. The sedimentary succession in the core is tripartite. The lowermost sedimentary unit A (30.0–28.6 m) comprises grey-brown to black organic-rich carbonate sediments, which contain freshwater snails (<i>Pyrgophorus</i>), tropical forest pollen (Myrtaceae) and a low-diversity dinocyst assemblage. The intermediate unit B (28.6–24.65 m) is a dark greyish-green to greyish-brown, weakly laminated carbonate silt, which comprises marine fossils, that is, euryhaline foraminifera (<i>Elphidium</i>) and <i>Halimeda</i> (codiacean algal) platelets. Unit B contains abundant red mangrove (<i>Rhizophora</i>) pollen and a dinocyst assemblage indicating high productivity in surface waters. The uppermost unit C (24.65–0 m) is an annually layered buff and light green carbonate silt with abundant marine fossils. A total of 574 intercalated, coarser-grained and lighter-coloured event (storm) beds usually rich in <i>Halimeda</i> and coral fragments were identified in unit C. Fully marine conditions, including trophic seasonality, are also indicated by the dinocyst spectrum. The pollen spectrum derives from a variety of trees (largely pine, oak, podocarp), shrubs and herbs. The sedimentary succession represents the transition from an initial terrestrial cenote phase on a vegetated limestone island (unit A: 12.5–7.2 ka BP), via a subsequent restricted marine phase on an initially flooded carbonate platform with mangrove swamps (unit B: 7.2–5.7 ka BP), to a fully marine phase in an open, well-circulated atoll lagoon (unit C: 5.7–0 ka BP).</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 5","pages":"1376-1398"},"PeriodicalIF":2.0,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70021","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145572400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The Palaeogene Kumugeliemu Group in the Kuqa Depression of the Tarim Basin of western China is characterised by a thick and massive sequence of evaporites, with a maximum thickness of up to 1000 m. The formation mechanism of such thick evaporite deposits remains unclear. In this study, sedimentological and geochemical research methods were employed to investigate the sedimentary characteristics and sources of halite. Sedimentary fabrics in halite, mudstone, sandstone, gypsum and carbonate indicate that halite was formed in a shallow water environment. Results of X-ray diffraction of halite and mudstone show that there is no tachyhydrite in halite and there is no pyrite in mudstone, which differs in the characteristics of deep-water salt and hydrothermal salt, respectively, indicating that halite was not formed in a deep-water environment. Rare earth elements indicate that sea water was the main source material for salt deposition. The colour of mudstone, Sr/Cu ratio and Rb/Sr ratio indicate that palaeoclimate was characterised by dry and hot conditions. The distribution characteristics of lithologic succession and the thickness of halite in Mbr 2 of the Kumugleiemu Group indicate that the halite was formed in restricted environments. According to above evidence, a ‘multistage marine transgression’ salt formation model was established, which suggests that, in a restricted paleogeographic environment, multiple transgressions brought sea water that, under dry and hot climate conditions, underwent repeated evaporation and concentration to form thick evaporite deposits.
{"title":"Insights into the genesis of thick halite in the Kuqa Depression (Tarim Basin, China): New mineralogical, lithological and geochemical evidence","authors":"Peng Qin, Dakang Zhong, Zhonggui Hu","doi":"10.1002/dep2.70019","DOIUrl":"https://doi.org/10.1002/dep2.70019","url":null,"abstract":"<p>The Palaeogene Kumugeliemu Group in the Kuqa Depression of the Tarim Basin of western China is characterised by a thick and massive sequence of evaporites, with a maximum thickness of up to 1000 m. The formation mechanism of such thick evaporite deposits remains unclear. In this study, sedimentological and geochemical research methods were employed to investigate the sedimentary characteristics and sources of halite. Sedimentary fabrics in halite, mudstone, sandstone, gypsum and carbonate indicate that halite was formed in a shallow water environment. Results of X-ray diffraction of halite and mudstone show that there is no tachyhydrite in halite and there is no pyrite in mudstone, which differs in the characteristics of deep-water salt and hydrothermal salt, respectively, indicating that halite was not formed in a deep-water environment. Rare earth elements indicate that sea water was the main source material for salt deposition. The colour of mudstone, Sr/Cu ratio and Rb/Sr ratio indicate that palaeoclimate was characterised by dry and hot conditions. The distribution characteristics of lithologic succession and the thickness of halite in Mbr 2 of the Kumugleiemu Group indicate that the halite was formed in restricted environments. According to above evidence, a ‘multistage marine transgression’ salt formation model was established, which suggests that, in a restricted paleogeographic environment, multiple transgressions brought sea water that, under dry and hot climate conditions, underwent repeated evaporation and concentration to form thick evaporite deposits.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 4","pages":"1063-1083"},"PeriodicalIF":2.0,"publicationDate":"2025-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70019","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nevena Andrić-Tomašević, Benjamin F. Walter, Vladimir Simić, Mohsin Raza, Dragana Životić, Željana Novković, Jochen Kolb, Axel Gerdes, Aratz Beranoaguirre
Saline-alkaline lakes are common in tectonically active, semi-arid regions, resulting from the interplay between tectonic, hydrothermal, surface processes and climate. This study investigates their contribution to the evolution of the saline-alkaline succession in the intramontane Ibar Basin (Southern Serbia). The succession is investigated using detailed sedimentological analysis, in situ U–Pb geochronology of carbonates acquired by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), major and trace element geochemistry and fluid inclusion analysis. Dominantly clastic sedimentation is represented by alluvial fan, flood plain, delta and marginal and profundal lake facies associations. Microbialite and littoral to sublittoral oil shales formed in the areas protected from clastic input. The stratigraphic succession shows a transition from alluvia to a hydrologically open and closed lacustrine environment. U–Pb geochronology of microbialite of a close lake phase (~17 Ma) suggests basin evolution during the Early to Middle Miocene age. The hydrologically closed lake phase is marked by borate-rich facies, which comprise mainly colemanite overgrown by secondary ulexite within profundal lake facies associations. The textural features suggest that colemanite initially precipitated at or below the sediment/water interface. The subsequent growth, as observed from the primary fluid inclusions in colemanite and calcite, indicates precipitation from the evolving bittern brine under evaporitic, redox conditions, which during diagenesis reached temperatures of 200–220°C. High Ca2+/Na+ ratios in the brine favour colemanite precipitation. Gradual Ca2+ depletion and clay breakdown (dewatering) lead to ulexite and borax precipitates. The results imply that B, Ca and Na were mobilised and transported into the basin by hydrothermal fluids that previously leached bedrock and/or by streams carrying products of the volcanic rocks' weathering. However, brine saturation and syndepositional precipitation were initiated by an arid climate through evaporation, while further growth was driven by reflux of fluids during diagenesis. This study highlights the importance of the tectonics of the collisional orogens and associated processes, arid climate and basin hydrological regime on the deposition of B, Ca-rich deposits in saline-alkaline lakes.
{"title":"Contributions of arid climate and hydrothermal fluid flow on sedimentation in saline-alkaline lakes: Insight from the Ibar intramontane basin (Southern Serbia)","authors":"Nevena Andrić-Tomašević, Benjamin F. Walter, Vladimir Simić, Mohsin Raza, Dragana Životić, Željana Novković, Jochen Kolb, Axel Gerdes, Aratz Beranoaguirre","doi":"10.1002/dep2.70017","DOIUrl":"https://doi.org/10.1002/dep2.70017","url":null,"abstract":"<p>Saline-alkaline lakes are common in tectonically active, semi-arid regions, resulting from the interplay between tectonic, hydrothermal, surface processes and climate. This study investigates their contribution to the evolution of the saline-alkaline succession in the intramontane Ibar Basin (Southern Serbia). The succession is investigated using detailed sedimentological analysis, in situ U–Pb geochronology of carbonates acquired by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), major and trace element geochemistry and fluid inclusion analysis. Dominantly clastic sedimentation is represented by alluvial fan, flood plain, delta and marginal and profundal lake facies associations. Microbialite and littoral to sublittoral oil shales formed in the areas protected from clastic input. The stratigraphic succession shows a transition from alluvia to a hydrologically open and closed lacustrine environment. U–Pb geochronology of microbialite of a close lake phase (~17 Ma) suggests basin evolution during the Early to Middle Miocene age. The hydrologically closed lake phase is marked by borate-rich facies, which comprise mainly colemanite overgrown by secondary ulexite within profundal lake facies associations. The textural features suggest that colemanite initially precipitated at or below the sediment/water interface. The subsequent growth, as observed from the primary fluid inclusions in colemanite and calcite, indicates precipitation from the evolving bittern brine under evaporitic, redox conditions, which during diagenesis reached temperatures of 200–220°C. High Ca<sup>2+</sup>/Na<sup>+</sup> ratios in the brine favour colemanite precipitation. Gradual Ca<sup>2+</sup> depletion and clay breakdown (dewatering) lead to ulexite and borax precipitates. The results imply that B, Ca and Na were mobilised and transported into the basin by hydrothermal fluids that previously leached bedrock and/or by streams carrying products of the volcanic rocks' weathering. However, brine saturation and syndepositional precipitation were initiated by an arid climate through evaporation, while further growth was driven by reflux of fluids during diagenesis. This study highlights the importance of the tectonics of the collisional orogens and associated processes, arid climate and basin hydrological regime on the deposition of B, Ca-rich deposits in saline-alkaline lakes.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 4","pages":"1029-1062"},"PeriodicalIF":2.0,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70017","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Çiğdem Saydam Eker, Uğur Volkan Arı, Selçuk Alemdağ
This study assesses the organic matter (OM) content, kerogen type, maturity, depositional environment conditions and sedimentation model of Early Cretaceous (Berriasian–Aptian) black limestones in NE Turkey using geochemical analyses, including Rock-Eval/total organic carbon (TOC), gas chromatography–mass spectrometry, gas chromatography, major and trace elements and stable carbon isotope of OM measurements. The investigated black limestones' TOC, hydrogen index and potential yield values range from 0.07 to 2.91 wt%, 76 to 636 mg HC/g TOC and 0.15 to 11.17 mg HC/g rock, respectively. These results indicate that the examined limestones have variable source rock potential, ranging from low to high. Tmax values, calculated saturated biomarkers and aromatic components suggest that the OM contained in the black limestones varies between thermally immature and mature, consistent with the potential index values. The OM found in the black limestone contained kerogen varying between type I and III. It is a composition of marine and terrigenous OM, as shown by the δ13C isotope values, biomarker components and n-alkane distributions and their parameters. This OM was deposited in a salinity water environment with marine–terrigenous (transitional) surroundings under oxic, suboxic to anoxic and arid–hot climate conditions. These findings provide critical insights for assessing the hydrocarbon potential of carbonate platforms in similar geological settings.
{"title":"Geochemical evaluation of black limestones in the Early Cretaceous platform carbonates of Gümüşhane (NE Turkey): An insight into petroleum source rock potential and palaeoenvironment conditions","authors":"Çiğdem Saydam Eker, Uğur Volkan Arı, Selçuk Alemdağ","doi":"10.1002/dep2.70012","DOIUrl":"https://doi.org/10.1002/dep2.70012","url":null,"abstract":"<p>This study assesses the organic matter (OM) content, kerogen type, maturity, depositional environment conditions and sedimentation model of Early Cretaceous (Berriasian–Aptian) black limestones in NE Turkey using geochemical analyses, including Rock-Eval/total organic carbon (TOC), gas chromatography–mass spectrometry, gas chromatography, major and trace elements and stable carbon isotope of OM measurements. The investigated black limestones' TOC, hydrogen index and potential yield values range from 0.07 to 2.91 wt%, 76 to 636 mg HC/g TOC and 0.15 to 11.17 mg HC/g rock, respectively. These results indicate that the examined limestones have variable source rock potential, ranging from low to high. <i>T</i><sub>max</sub> values, calculated saturated biomarkers and aromatic components suggest that the OM contained in the black limestones varies between thermally immature and mature, consistent with the potential index values. The OM found in the black limestone contained kerogen varying between type I and III. It is a composition of marine and terrigenous OM, as shown by the δ<sup>13</sup>C isotope values, biomarker components and <i>n</i>-alkane distributions and their parameters. This OM was deposited in a salinity water environment with marine–terrigenous (transitional) surroundings under oxic, suboxic to anoxic and arid–hot climate conditions. These findings provide critical insights for assessing the hydrocarbon potential of carbonate platforms in similar geological settings.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 3","pages":"917-953"},"PeriodicalIF":1.9,"publicationDate":"2025-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70012","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144292788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cecilia A. Benavente, Kevin M. Bohacs, Sila Pla-Pueyo
Significant progress has been made in understanding lake basin evolution through climatic and tectonic changes using sedimentology, sequence stratigraphy, geochemistry, hydrology and watershed characteristics to interpret three main lake basin types: overfilled, balanced-fill and underfilled, including fluvio-lacustrine systems. Groundwater constraints, however, have been mostly overlooked, especially as they affect the formation and preservation of climate-sensitive indicators (‘proxies’). The incorporation of subsurface water flow factors into lake basin analysis has led to the realisation that more diverse and complex facies associations can result from its influence, particularly in balanced-fill and underfilled lake basins. Better understanding of palaeohydrogeology of lacustrine systems results from integrated analysis, including sediment and water delivery pathways, components of potential accommodation and conditions in the lake water column studied in modern lakes and ancient lake strata representing deep-time lacustrine basins. This special issue intends to act as a pivotal point for future studies on limnogeology. Our goal is to improve our understanding of water delivery pathways (precipitation, overland, groundwater) into fluvio-lacustrine basins, their influences on such systems and their record of climate and tectonics and to update the existing models for them. The integration of the full range of variables holds great promise to help us better constrain controls and factors affecting the evolution of inland water systems through time and space, to Mars and beyond.
{"title":"Water pathways and ancient lakes: Flowing towards new models to unravel the past","authors":"Cecilia A. Benavente, Kevin M. Bohacs, Sila Pla-Pueyo","doi":"10.1002/dep2.70016","DOIUrl":"https://doi.org/10.1002/dep2.70016","url":null,"abstract":"<p>Significant progress has been made in understanding lake basin evolution through climatic and tectonic changes using sedimentology, sequence stratigraphy, geochemistry, hydrology and watershed characteristics to interpret three main lake basin types: overfilled, balanced-fill and underfilled, including fluvio-lacustrine systems. Groundwater constraints, however, have been mostly overlooked, especially as they affect the formation and preservation of climate-sensitive indicators (‘proxies’). The incorporation of subsurface water flow factors into lake basin analysis has led to the realisation that more diverse and complex facies associations can result from its influence, particularly in balanced-fill and underfilled lake basins. Better understanding of palaeohydrogeology of lacustrine systems results from integrated analysis, including sediment and water delivery pathways, components of potential accommodation and conditions in the lake water column studied in modern lakes and ancient lake strata representing deep-time lacustrine basins. This special issue intends to act as a pivotal point for future studies on limnogeology. Our goal is to improve our understanding of water delivery pathways (precipitation, overland, groundwater) into fluvio-lacustrine basins, their influences on such systems and their record of climate and tectonics and to update the existing models for them. The integration of the full range of variables holds great promise to help us better constrain controls and factors affecting the evolution of inland water systems through time and space, to Mars and beyond.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 5","pages":"1554-1562"},"PeriodicalIF":2.0,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70016","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145572336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lauren T. Toth, Anastasios Stathakopoulos, Scarlette Hsia, David Weinstein
The ongoing global-scale reassembly of modern coral reefs is unprecedented compared with the observed stability of most late Quaternary reef assemblages. One notable exception is the marine isotope stage (MIS) 5e (ca 130–116 thousand years ago [ka]) reefs in the Florida Keys, where the ubiquitous shallow-water coral, Acropora palmata, was near absent. Little is known, however, about reefs that grew during MIS5d–a (ca 116–74 ka), between MIS5e and the Holocene. It is therefore unclear whether Florida's unique MIS5e coral assemblages represent a geologically brief anomaly or a more persistent departure from the western Atlantic coral-reef archetype. We addressed that question by reconstructing the composition of MIS5d–a reefs within 29 coral-reef cores collected throughout the Florida Keys. We then compared the relative composition of corals during MIS5d–a to existing datasets from MIS5e, Holocene and modern (1996 and 2022) reefs to evaluate how far today's reef assemblages have diverged from geological baselines. We show that although the proportion of reef frameworks built by corals was remarkably consistent (ca 38%), species composition changed significantly through time. Acropora palmata was rare throughout MIS5, which we hypothesise was due to greater cold-temperature stress in Florida's subtropical reefs compared with the more climatically stable tropics. In contrast, the massive reef-building coral, Orbicella spp., was regionally dominant throughout the late Quaternary, but has become increasingly rare on modern reefs. By 2022, reefs in the Florida Keys were characterised by a truly novel coral assemblage dominated by Porites astreoides and Siderastrea siderea. In many ways, Florida's reefs defy the concept of a natural baseline; instead, their most persistent characteristic since the Late Pleistocene is their uniqueness. Yet, as reefs are increasingly subjected to unprecedented levels of environmental change, the exceptions to what was normal in the past could, paradoxically, provide the best geological analogues for the future.
{"title":"Shifting baselines of coral-reef species composition from the Late Pleistocene to the present in the Florida Keys","authors":"Lauren T. Toth, Anastasios Stathakopoulos, Scarlette Hsia, David Weinstein","doi":"10.1002/dep2.70009","DOIUrl":"https://doi.org/10.1002/dep2.70009","url":null,"abstract":"<p>The ongoing global-scale reassembly of modern coral reefs is unprecedented compared with the observed stability of most late Quaternary reef assemblages. One notable exception is the marine isotope stage (MIS) 5e (<i>ca</i> 130–116 thousand years ago [ka]) reefs in the Florida Keys, where the ubiquitous shallow-water coral, <i>Acropora palmata</i>, was near absent. Little is known, however, about reefs that grew during MIS5d–a (<i>ca</i> 116–74 ka), between MIS5e and the Holocene. It is therefore unclear whether Florida's unique MIS5e coral assemblages represent a geologically brief anomaly or a more persistent departure from the western Atlantic coral-reef archetype. We addressed that question by reconstructing the composition of MIS5d–a reefs within 29 coral-reef cores collected throughout the Florida Keys. We then compared the relative composition of corals during MIS5d–a to existing datasets from MIS5e, Holocene and modern (1996 and 2022) reefs to evaluate how far today's reef assemblages have diverged from geological baselines. We show that although the proportion of reef frameworks built by corals was remarkably consistent (<i>ca</i> 38%), species composition changed significantly through time. <i>Acropora palmata</i> was rare throughout MIS5, which we hypothesise was due to greater cold-temperature stress in Florida's subtropical reefs compared with the more climatically stable tropics. In contrast, the massive reef-building coral, <i>Orbicella</i> spp., was regionally dominant throughout the late Quaternary, but has become increasingly rare on modern reefs. By 2022, reefs in the Florida Keys were characterised by a truly novel coral assemblage dominated by <i>Porites astreoides</i> and <i>Siderastrea siderea</i>. In many ways, Florida's reefs defy the concept of a natural baseline; instead, their most persistent characteristic since the Late Pleistocene is their uniqueness. Yet, as reefs are increasingly subjected to unprecedented levels of environmental change, the exceptions to what was normal in the past could, paradoxically, provide the best geological analogues for the future.</p>","PeriodicalId":54144,"journal":{"name":"Depositional Record","volume":"11 3","pages":"893-916"},"PeriodicalIF":1.9,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/dep2.70009","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144292210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}