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Trace elements, rare earth elements and isotopes of poorly preserved fossils from lower Cretaceous carbonates (Eastern Black Sea): Implications for early diagenetic alteration 黑海东部下白垩统碳酸盐岩中保存较差化石的微量元素、稀土元素和同位素:早期成岩蚀变的意义
IF 2 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-07-03 DOI: 10.1002/dep2.70026
Merve Özyurt

Poorly preserved belemnite samples are often disregarded in palaeoclimatology and palaeoceanography research within the Eastern Pontides (NE Türkiye), which is part of the Alp-Himalayan Belt that experienced extensive orogenic and magmatic activity. Late Jurassic–Early Cretaceous carbonates are widely exposed in the Eastern Pontides, having undergone a complex diagenetic history since deposition. Belemnite rostra samples from the uppermost part of the carbonate sequence (Aptian–Albian strata) exhibit diagenetic overprints. These poorly preserved belemnite samples can serve as excellent archives for basin early diagenetic evolution. However, the diagenetic evolution of these poorly preserved belemnite samples has not been fully studied within the context of the diagenetic evolution of the basin. Thus, this study presents a comprehensive dataset including isotope analyses (Sr/C/O) and trace element, including REE chemistry of these belemnite samples to elucidate the basin's early diagenetic history. The studied samples are commonly dark grey and show visible signs of diagenetic processes, including dissolution, silicification and pyrite mineralisation. These samples show high Fe (1259–5176 ppm; ave. 2859 ppm) and Mn (77–387 ppm; ave. 232 ppm), low Sr/Mn (0.63–12.33; ave. 3.47) and low Sr/Rb (42–568, ave. 200) values, consistent with a diagenetic alteration. Interestingly, carbon and strontium isotopes of belemnite samples correlate well with those from well-preserved belemnite rostra from the Aptian–Albian strata. They exhibit a diagnostic sea water REEN signature, including mildly enriched Gd/Gd* ratios of 1.04–1.48 (ave. 1.24) and high La/La* of 1.54–5.50 (ave. 2.51) and Ce/Ce* of 0.46–0.60 (ave. 0.51). However, slight LREE enrichment is observed, with La/LuN ratios ranging from 0.81 to 1.74 (average: 1.21) and La/YbN ratios from 0.9 to 1.79 (average: 1.22). A slight positive Eu anomaly is also present, with Eu/Eu* ratios between 1.15 and 1.55 (average 1.36). Y/Ho ratios range from 35.00 to 45.00 (average 39.84), and Sm/Yb ratios from 1.70 to 4.05 (average 2.42). These geochemical characteristics, along with δ18O values that deviate from typical marine carbonate signatures, suggest a subsequent low-temperature hydrothermal alteration, potentially triggered by hydrothermal activity associated with an Early Cretaceous magmatic event. This finding underscores the significance of analysing REEs in poorly preserved belemnite rostra, offering valuable insights into early diagenetic pathways, dissolution/precipitation processes and water–rock interaction.

东庞德斯(东北基耶)是阿尔卑斯-喜马拉雅带的一部分,经历了广泛的造山和岩浆活动,在古气候学和古海洋学研究中,保存较差的钙辉石样品经常被忽视。晚侏罗世—早白垩世碳酸盐岩广泛出露于东塘地区,自沉积以来经历了复杂的成岩历史。箭石嘴样本的部分碳酸盐岩成岩序列(Aptian-Albian地层)展览一色。这些保存较差的蛭石样品可作为研究盆地早期成岩演化的优良档案。然而,这些保存较差的蛭石样品的成岩演化尚未在盆地成岩演化的背景下得到充分的研究。为此,本研究建立了包括同位素分析(Sr/C/O)和微量元素分析(包括REE化学)在内的综合数据集,以阐明盆地的早期成岩历史。所研究的样品通常是深灰色的,并显示出成岩过程的明显迹象,包括溶解、硅化和黄铁矿矿化。高铁(1259 ~ 5176 ppm,平均值为2859 ppm)和高锰(77 ~ 387 ppm,平均值为232 ppm),低Sr/Mn(0.63 ~ 12.33,平均值为3.47)和低Sr/Rb(42 ~ 568,平均值为200),与成岩蚀变相一致。有趣的是,铍石样品的碳和锶同位素与阿普提安-阿尔比安地层中保存完好的铍石柱的同位素具有很好的相关性。其中Gd/Gd*轻度富集,为1.04 ~ 1.48(均值1.24),La/La*高,为1.54 ~ 5.50(均值2.51),Ce/Ce*高,为0.46 ~ 0.60(均值0.51)。LREE富集,La/LuN比值为0.81 ~ 1.74(平均为1.21),La/YbN比值为0.9 ~ 1.79(平均为1.22)。也存在轻微的正Eu异常,Eu/Eu*比值在1.15和1.55之间(平均为1.36)。Y/Ho比率为35.00至45.00(平均为39.84),Sm/Yb比率为1.70至4.05(平均为2.42)。这些地球化学特征,以及偏离典型海相碳酸盐岩特征的δ18O值,表明了随后的低温热液蚀变,可能是由早白垩世岩浆事件相关的热液活动引发的。这一发现强调了在保存较差的菱铁矿中分析稀土元素的重要性,为早期成岩途径、溶解/沉淀过程和水岩相互作用提供了有价值的见解。
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引用次数: 0
Holocene development of submerged keep-up patch reefs on Bermuda without acroporids: A model of future reef accretion 百慕达群岛全新世水下维持型斑块礁的发育:一个未来珊瑚礁增生的模式
IF 2 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-24 DOI: 10.1002/dep2.70023
Eduardo Islas-Dominguez, Eberhard Gischler, J. Harold Hudson

The cover of living reef-building corals has declined due to ocean warming, acidification, pollution and disease outbreaks. This decline endangers future reef development relying on acroporid corals, which are highly sensitive to environmental changes. Given these threats, there is a need for accretion models that do not rely on species dominance. To assess the potential of non-acroporid framework and identify the key variables controlling their accretion, we reconstructed the internal structure and Holocene development of Bermuda patch reefs, lacking acroporids. Four rotary drill cores and two vibrocores recovered sequences composed of five facies in decreasing abundance: a framework of massive, stress-tolerant corals, unconsolidated skeletal sand and gravel, coralline-algal bindstone, Halimeda floatstone and peat. Radiocarbon dating of corals and peat shows that patch reefs developed in two stages. From 7 to 4 kyr B.P., during a sustained sea-level rise, the coral framework facies accreted vertically, while the unconsolidated facies filled interstitial sand pockets in intermediate water depths. From 4 kyr B.P. onwards, during a reduced rate of sea-level rise, vertical accretion has continued with a decline in coral diversity. Accretion was primarily controlled by massive coral framework construction and variation in environmental energy, turbidity and bioerosion, which collectively shaped the size, diversity and preservation of the framework. This led to a suppressed, steady vertical accretion rate of 2.18 ± 0.66 m/kyr on average. Although lower than that of acroporid reefs in the western Atlantic, the accretion rate did not decline throughout the Holocene, even as sea-level rise slowed over the last 4 ka. The suppressed accretion rate resulted in submerged keep-up reefs thriving in several metres of water during the mid-late Holocene. This growth mode highlights the potential of coral reefs to develop under different controls beyond coral species dominance, a mode that could be applied to current and future coral reef development.

由于海洋变暖、酸化、污染和疾病爆发,造礁珊瑚的覆盖面积下降。这种下降危及未来依赖于对环境变化高度敏感的甲状珊瑚的珊瑚礁发展。考虑到这些威胁,我们需要一种不依赖于物种优势的增长模型。为了评估非肢似体框架的潜力,确定控制其增生的关键变量,我们重建了缺乏肢似体的百慕大斑块礁的内部结构和全新世发育。4个旋转岩心和2个振动岩心回收了由5个丰度递减的相组成的层序:块状、耐应力珊瑚、未固结的骨架砂和砾石、珊瑚-藻类结合岩、哈利米达浮石和泥炭。珊瑚和泥炭的放射性碳测年表明,斑礁的发育分为两个阶段。7 ~ 4 kyr b.p.,在海平面持续上升的过程中,珊瑚格架相在垂直方向上增生,而松散相则在中水深填满间隙砂袋。从4kyr B.P.开始,在海平面上升速度减缓期间,垂直增长继续,珊瑚多样性下降。大量珊瑚骨架的形成和环境能量、浊度和生物侵蚀的变化共同决定了骨架的大小、多样性和保存。这导致了一个被抑制的、稳定的垂直吸积速率,平均为2.18±0.66 m/kyr。尽管比西大西洋的acroporid礁要低,但在整个全新世,即使海平面上升在过去4ka减慢,其增长速度也没有下降。在全新世中晚期,受抑制的沉积速率导致水下维持珊瑚礁在几米深的水中茁壮成长。这种生长模式突出了珊瑚礁在珊瑚物种优势之外的不同控制下发展的潜力,这种模式可以应用于当前和未来的珊瑚礁发展。
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引用次数: 0
Anomalously cool clumped isotope temperatures in tropical lagoon carbonates 热带泻湖碳酸盐异常冷的团块同位素温度
IF 2 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-24 DOI: 10.1002/dep2.70024
D. A. Wyman-Feravich, M. Ingalls, J. L. Conroy, R. He, S. Lusk

Carbonate clumped isotopes are a powerful tool for paleoclimate reconstruction due to the ability to reconstruct past changes in both temperature and precipitation-evaporation balance. Here we test the utility of this method on last millennium carbonate lagoonal sediments from Kiritimati, a coral atoll where modern climate variability is driven by interannual changes in the El Niño-Southern Oscillation. We find last millennium lagoonal temperatures from clumped isotopes are cooler than anticipated compared to modern measurements and other paleoclimate reconstructions. This discrepancy is probably due to sediments containing a mixture of high-magnesium calcite derived from primary precipitates and benthic foraminifera and aragonite derived from warm water corals. We employed an inverse mixing model to minimise the impact of vital effects related to coral growth on clumped isotope compositions and found an increasing difference between modelled and measured T(Δ47) values through time. This potentially indicates that the composition of lagoon water became increasingly unique from the coral carbonate formation waters through the last millennium. This study highlights the necessity of detailed understanding of carbonate mineralogy, sedimentology and provenance in interpreting clumped isotope temperature reconstructions.

碳酸盐团块同位素是重建古气候的有力工具,因为它能够重建过去的温度和降水-蒸发平衡的变化。在这里,我们测试了这种方法在基里蒂玛蒂(Kiritimati)的上一千年碳酸盐泻湖沉积物上的有效性,基里蒂玛蒂是一个珊瑚环礁,在那里,现代气候变化是由El Niño-Southern振荡的年际变化驱动的。我们发现,与现代测量和其他古气候重建相比,上一千年的泻湖温度比预期的要低。这种差异可能是由于沉积物中含有来自原生沉淀物的高镁方解石和来自温水珊瑚的底栖有孔虫和文石的混合物。我们采用了一个反向混合模型,以尽量减少与珊瑚生长有关的重要影响对团块同位素组成的影响,并发现随着时间的推移,模型和测量的T值之间的差异越来越大(Δ47)。这可能表明,在过去的一千年里,泻湖水的组成与珊瑚碳酸盐地层水越来越不同。该研究强调了详细了解碳酸盐矿物学、沉积学和物源在解释团块同位素温度重建中的必要性。
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引用次数: 0
Carbonate microfacies and transgressive-regressive sequences of Oxfordian shallow-water limestones (Korallenoolith, Lower Saxony Basin) 下萨克森盆地牛津期浅水灰岩碳酸盐微相及海侵退层序
IF 2 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-24 DOI: 10.1002/dep2.70022
Deyan Zhang, François-Nicolas Krencker, Stefan Huck, Ulrich Heimhofer

This study represents a detailed analysis of a stratigraphic section of Oxfordian (Late Jurassic) age with the aim to reconstruct the facies pattern and sequence-stratigraphic evolution, followed by a discussion of the dominant controls on shallow marine carbonate platform sedimentation in the Lower Saxony Basin (LSB). During the Oxfordian, the LSB was covered by a shallow epicontinental sea, in which a thick succession of marine limestones and marls was deposited. The stratiform Oxfordian carbonate bodies hold significant economic potential due to their ability to form hydrocarbon reservoirs or targets for future geothermal exploration. The scarcity of open-marine biostratigraphic marker fossils and the presence of numerous sedimentary gaps pose significant challenges for establishing reliable correlations with Oxfordian deposits globally. This study focuses on the Oxfordian Korallenoolith Formation, which is well exposed in the Bisperode section located ~40 km SW of Hannover. The ~126 m thick section was described bed-by-bed during fieldwork and complemented by 73 petrographic thin sections that were analysed for carbonate microfacies. Based on differences in grain and mud composition and primary sedimentary fabrics, an integrated log of the Bisperode quarry was constructed. Seven facies types (FTs) and 13 microfacies types (MFs) are characterised upon which a reef-bearing carbonate ramp model was built. Following the magnitude of the transgressive/regressive trends concept, three low-order sequences are recognised, which are composed of eight higher order sequences. The low-order sequences correlate well to the established sequence-stratigraphic model and the higher order sequences point to a possible control of their stacking pattern by Milankovitch long eccentricity cycles. This study is important because it helps to better understand the link between the stacking pattern of Oxfordian strata in the LSB and allocyclic processes. It thus provides a foundation for basinwide and inter-basin sequence-stratigraphic correlation, allowing future global chemostratigraphic comparisons and providing valuable insights into the synchronicity of geological events.

本文对牛津(晚侏罗世)地层剖面进行了详细分析,旨在重建相模式和层序地层演化,然后讨论了下萨克森州盆地(LSB)浅海碳酸盐台地沉积的主要控制因素。在牛津纪期间,LSB被一个浅陆表海覆盖,其中沉积了一系列厚厚的海相石灰石和泥灰岩。牛津层状碳酸盐岩具有巨大的经济潜力,因为它们具有形成油气藏或未来地热勘探目标的能力。开放海洋生物地层标志化石的缺乏和大量沉积间隙的存在为建立与全球牛津沉积物的可靠相关性带来了重大挑战。研究对象为位于汉诺威西南约40 km的Bisperode剖面的牛津Korallenoolith组。在野外工作中逐层描述了~126 m厚的剖面,并辅以73个岩石薄片进行了碳酸盐岩微相分析。根据颗粒和泥浆组成及原生沉积组构的差异,构建了Bisperode采石场的综合测井曲线。在7种相类型和13种微相类型的基础上,建立了含礁碳酸盐斜坡模型。根据海侵/海退趋势的大小,可以识别出3个低阶层序,它们由8个高阶层序组成。低阶层序与已建立的层序-地层模式吻合良好,高阶层序表明其叠置模式可能受到米兰科维奇长偏心旋回的控制。这项研究有助于更好地理解牛津地层的堆积方式与非同旋过程之间的联系。因此,它为全盆地和盆地间层序地层对比提供了基础,使未来的全球化学地层比较成为可能,并为地质事件的共时性提供了有价值的见解。
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引用次数: 0
Late Pleistocene to Holocene sedimentation in the Great Blue Hole (Lighthouse Reef, Belize): Results from a 30 m long core 大蓝洞(伯利兹灯塔礁)的晚更新世至全新世沉积:来自30米长的岩心的结果
IF 2 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-06-12 DOI: 10.1002/dep2.70021
Eberhard Gischler, Dominik Schmitt, Annika Wiegand, Hermann Behling, Lyudmila Shumilovskikh, Martin Melles, Volker Wennrich, Elija Nolte, Jozef Grego, Flavio S. Anselmetti, Hendrik Vogel, Daniel Birgel, Jörn Peckmann

The Great Blue Hole is a prominent flooded karst sinkhole, located in the lagoon of Lighthouse Reef atoll off the coast of Belize. Short cores recovered from varved bottom sediments have been used in previous studies as climate and cyclone archives covering as much as the past ca 1.7 ka BP. A new 30 m long sediment core, encompassing the entire Holocene and the latest Pleistocene, allows a reconstruction of the development of this geoscientifically significant site in the light of the postglacial and Holocene sea-level rise. The sedimentary succession in the core is tripartite. The lowermost sedimentary unit A (30.0–28.6 m) comprises grey-brown to black organic-rich carbonate sediments, which contain freshwater snails (Pyrgophorus), tropical forest pollen (Myrtaceae) and a low-diversity dinocyst assemblage. The intermediate unit B (28.6–24.65 m) is a dark greyish-green to greyish-brown, weakly laminated carbonate silt, which comprises marine fossils, that is, euryhaline foraminifera (Elphidium) and Halimeda (codiacean algal) platelets. Unit B contains abundant red mangrove (Rhizophora) pollen and a dinocyst assemblage indicating high productivity in surface waters. The uppermost unit C (24.65–0 m) is an annually layered buff and light green carbonate silt with abundant marine fossils. A total of 574 intercalated, coarser-grained and lighter-coloured event (storm) beds usually rich in Halimeda and coral fragments were identified in unit C. Fully marine conditions, including trophic seasonality, are also indicated by the dinocyst spectrum. The pollen spectrum derives from a variety of trees (largely pine, oak, podocarp), shrubs and herbs. The sedimentary succession represents the transition from an initial terrestrial cenote phase on a vegetated limestone island (unit A: 12.5–7.2 ka BP), via a subsequent restricted marine phase on an initially flooded carbonate platform with mangrove swamps (unit B: 7.2–5.7 ka BP), to a fully marine phase in an open, well-circulated atoll lagoon (unit C: 5.7–0 ka BP).

大蓝洞是一个突出的被水淹没的喀斯特天坑,位于伯利兹海岸外灯塔礁环礁的泻湖上。在以前的研究中,从破碎的底部沉积物中恢复的短岩心被用作覆盖过去约1.7 ka BP的气候和气旋档案。一个新的30米长的沉积物岩心,包含了整个全新世和最新更新世,允许在冰川后和全新世海平面上升的情况下重建这个具有地球科学意义的地点的发展。岩心内的沉积演替为三方演替。最下面的沉积单元A (30.0 ~ 28.6 m)为灰褐色至黑色富有机质碳酸盐沉积物,包含淡水蜗牛(Pyrgophorus)、热带森林花粉(myrtacae)和低多样性的dinocyst组合。中间单元B (28.6 ~ 24.65 m)为深灰绿色~灰褐色的弱层状碳酸盐淤泥,由海相化石组成,即广盐有孔虫(Elphidium)和halimmeda (codiacian藻类)。单元B含有丰富的红树(根草)花粉和一个二囊组合,表明在地表水具有很高的生产力。最上层C单元(24.65 ~ 0 m)为浅绿色浅绿色碳酸盐岩粉砂,呈浅绿色年层状,具有丰富的海相化石。在c单元共发现了574个间插、粗粒和浅色的事件(风暴)床,通常富含海藻和珊瑚碎片。生物囊谱也表明了完全的海洋条件,包括营养季节性。花粉谱来自各种树木(主要是松树、橡树、足足树)、灌木和草本植物。沉积演替代表了从植被覆盖的石灰岩岛屿上的初始陆生天然井阶段(单元a: 12.5-7.2 ka BP),通过随后在具有红树林沼泽的初始淹没碳酸盐台地上的有限海相阶段(单元B: 7.2-5.7 ka BP),到开放的、循环良好的环礁泻湖的完全海相阶段(单元C: 5.7-0 ka BP)的过渡。
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引用次数: 0
Insights into the genesis of thick halite in the Kuqa Depression (Tarim Basin, China): New mineralogical, lithological and geochemical evidence 塔里木盆地库车坳陷厚岩盐成因研究:新的矿物学、岩性和地球化学证据
IF 2 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-25 DOI: 10.1002/dep2.70019
Peng Qin, Dakang Zhong, Zhonggui Hu

The Palaeogene Kumugeliemu Group in the Kuqa Depression of the Tarim Basin of western China is characterised by a thick and massive sequence of evaporites, with a maximum thickness of up to 1000 m. The formation mechanism of such thick evaporite deposits remains unclear. In this study, sedimentological and geochemical research methods were employed to investigate the sedimentary characteristics and sources of halite. Sedimentary fabrics in halite, mudstone, sandstone, gypsum and carbonate indicate that halite was formed in a shallow water environment. Results of X-ray diffraction of halite and mudstone show that there is no tachyhydrite in halite and there is no pyrite in mudstone, which differs in the characteristics of deep-water salt and hydrothermal salt, respectively, indicating that halite was not formed in a deep-water environment. Rare earth elements indicate that sea water was the main source material for salt deposition. The colour of mudstone, Sr/Cu ratio and Rb/Sr ratio indicate that palaeoclimate was characterised by dry and hot conditions. The distribution characteristics of lithologic succession and the thickness of halite in Mbr 2 of the Kumugleiemu Group indicate that the halite was formed in restricted environments. According to above evidence, a ‘multistage marine transgression’ salt formation model was established, which suggests that, in a restricted paleogeographic environment, multiple transgressions brought sea water that, under dry and hot climate conditions, underwent repeated evaporation and concentration to form thick evaporite deposits.

中国西部塔里木盆地库车坳陷古近系库木格列木群具有厚而块状的蒸发岩层序,最大厚度可达1000 m。如此厚的蒸发岩矿床的形成机制尚不清楚。本文采用沉积学和地球化学研究方法,探讨了该区岩盐岩的沉积特征和来源。岩盐、泥岩、砂岩、石膏和碳酸盐的沉积组构表明岩盐形成于浅水环境。岩盐和泥岩的x射线衍射结果表明,岩盐中不含速水岩,泥岩中不含黄铁矿,其深水盐和热液盐的特征不同,表明岩盐不是在深水环境中形成的。稀土元素表明海水是盐沉积的主要来源物质。泥岩颜色、Sr/Cu比值和Rb/Sr比值表明古气候具有干热特征。库穆列木群二段岩盐岩的岩性演替特征和岩盐岩厚度特征表明,该岩盐岩形成于有限环境。根据上述证据,建立了“多期海侵”成盐模式,表明在有限的古地理环境下,多次海侵带来的海水在干热气候条件下反复蒸发浓缩,形成厚的蒸发岩沉积。
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引用次数: 0
Contributions of arid climate and hydrothermal fluid flow on sedimentation in saline-alkaline lakes: Insight from the Ibar intramontane basin (Southern Serbia) 干旱气候和热液流动对盐碱湖沉积的贡献:来自塞尔维亚南部伊巴尔山间盆地的认识
IF 2 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-23 DOI: 10.1002/dep2.70017
Nevena Andrić-Tomašević, Benjamin F. Walter, Vladimir Simić, Mohsin Raza, Dragana Životić, Željana Novković, Jochen Kolb, Axel Gerdes, Aratz Beranoaguirre

Saline-alkaline lakes are common in tectonically active, semi-arid regions, resulting from the interplay between tectonic, hydrothermal, surface processes and climate. This study investigates their contribution to the evolution of the saline-alkaline succession in the intramontane Ibar Basin (Southern Serbia). The succession is investigated using detailed sedimentological analysis, in situ U–Pb geochronology of carbonates acquired by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), major and trace element geochemistry and fluid inclusion analysis. Dominantly clastic sedimentation is represented by alluvial fan, flood plain, delta and marginal and profundal lake facies associations. Microbialite and littoral to sublittoral oil shales formed in the areas protected from clastic input. The stratigraphic succession shows a transition from alluvia to a hydrologically open and closed lacustrine environment. U–Pb geochronology of microbialite of a close lake phase (~17 Ma) suggests basin evolution during the Early to Middle Miocene age. The hydrologically closed lake phase is marked by borate-rich facies, which comprise mainly colemanite overgrown by secondary ulexite within profundal lake facies associations. The textural features suggest that colemanite initially precipitated at or below the sediment/water interface. The subsequent growth, as observed from the primary fluid inclusions in colemanite and calcite, indicates precipitation from the evolving bittern brine under evaporitic, redox conditions, which during diagenesis reached temperatures of 200–220°C. High Ca2+/Na+ ratios in the brine favour colemanite precipitation. Gradual Ca2+ depletion and clay breakdown (dewatering) lead to ulexite and borax precipitates. The results imply that B, Ca and Na were mobilised and transported into the basin by hydrothermal fluids that previously leached bedrock and/or by streams carrying products of the volcanic rocks' weathering. However, brine saturation and syndepositional precipitation were initiated by an arid climate through evaporation, while further growth was driven by reflux of fluids during diagenesis. This study highlights the importance of the tectonics of the collisional orogens and associated processes, arid climate and basin hydrological regime on the deposition of B, Ca-rich deposits in saline-alkaline lakes.

盐碱湖常见于构造活跃的半干旱区,是构造、热液、地表作用和气候相互作用的结果。本研究探讨了它们对伊巴尔盆地(塞尔维亚南部)山内盐碱演替演化的贡献。通过详细的沉积学分析、激光烧蚀电感耦合等离子体质谱(LA-ICP-MS)获取的碳酸盐U-Pb原位年代学、主微量元素地球化学和流体包裹体分析,研究了该序列。碎屑沉积以冲积扇、冲积平原、三角洲和边缘湖盆相组合为主。微生物岩和沿海至沿海下油页岩形成于不受碎屑输入保护的地区。地层演替表现为冲积区向水文开闭湖环境的过渡。近湖期(~17 Ma)微生物岩U-Pb年代学表明盆地演化发生在中新世早期至中期。水文封闭湖相以富硼酸盐岩相为标志,主要由深湖相组合内的闪石岩为主,次生无闪石为主。其结构特征表明,colemanite最初沉积于沉积物/水界面或其下方。从柱幔岩和方解石的原生流体包裹体中观察到,随后的生长表明,在蒸发和氧化还原条件下,卤水在成岩过程中达到200-220℃的温度,形成了卤水的沉淀。盐水中Ca2+/Na+比值高有利于柱闪石的沉淀。Ca2+的逐渐耗尽和粘土的分解(脱水)导致无辉石和硼砂沉淀。结果表明,B、Ca和Na是通过之前浸出基岩的热液和/或携带火山岩风化产物的溪流被动员和输送到盆地的。然而,盐水饱和和同沉积降水是由干旱气候通过蒸发引起的,而进一步的生长是由成岩过程中流体的回流驱动的。该研究强调了碰撞造山带构造及其相关过程、干旱气候和盆地水文状况对盐碱湖富钙、B矿床沉积的重要性。
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引用次数: 0
Geochemical evaluation of black limestones in the Early Cretaceous platform carbonates of Gümüşhane (NE Turkey): An insight into petroleum source rock potential and palaeoenvironment conditions 土耳其东北部g<s:1>姆<e:1> <e:1>哈内早白垩世台地碳酸盐岩黑色灰岩地球化学评价:油气源岩潜力与古环境条件
IF 1.9 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-19 DOI: 10.1002/dep2.70012
Çiğdem Saydam Eker, Uğur Volkan Arı, Selçuk Alemdağ

This study assesses the organic matter (OM) content, kerogen type, maturity, depositional environment conditions and sedimentation model of Early Cretaceous (Berriasian–Aptian) black limestones in NE Turkey using geochemical analyses, including Rock-Eval/total organic carbon (TOC), gas chromatography–mass spectrometry, gas chromatography, major and trace elements and stable carbon isotope of OM measurements. The investigated black limestones' TOC, hydrogen index and potential yield values range from 0.07 to 2.91 wt%, 76 to 636 mg HC/g TOC and 0.15 to 11.17 mg HC/g rock, respectively. These results indicate that the examined limestones have variable source rock potential, ranging from low to high. Tmax values, calculated saturated biomarkers and aromatic components suggest that the OM contained in the black limestones varies between thermally immature and mature, consistent with the potential index values. The OM found in the black limestone contained kerogen varying between type I and III. It is a composition of marine and terrigenous OM, as shown by the δ13C isotope values, biomarker components and n-alkane distributions and their parameters. This OM was deposited in a salinity water environment with marine–terrigenous (transitional) surroundings under oxic, suboxic to anoxic and arid–hot climate conditions. These findings provide critical insights for assessing the hydrocarbon potential of carbonate platforms in similar geological settings.

利用岩石-总有机碳(TOC)、气相色谱-质谱、气相色谱、主微量元素和稳定碳同位素测量等地球化学分析方法,对土耳其东北部早白垩世(Berriasian-Aptian)黑色灰岩的有机质含量、干酪根类型、成熟度、沉积环境条件和沉积模式进行了评价。黑灰岩的TOC、氢指数和潜在产率分别为0.07 ~ 2.91 wt%、76 ~ 636 mg HC/g TOC和0.15 ~ 11.17 mg HC/g rock。结果表明,所测灰岩具有由低到高不等的烃源岩潜力。Tmax值、饱和生物标志物和芳香组分表明,黑灰岩有机质在热未成熟和成熟之间变化,与潜在指标值一致。在黑石灰岩中发现的OM含有I型和III型干酪根。δ13C同位素值、生物标志组分、正构烷烃分布及其参数均表明其为海相和陆源有机质组成。该OM沉积于含氧、缺氧至缺氧、干热气候条件下的海陆(过渡性)咸水环境。这些发现为评估类似地质环境下碳酸盐岩台地的油气潜力提供了重要见解。
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引用次数: 0
Water pathways and ancient lakes: Flowing towards new models to unravel the past 水道和古老的湖泊:流向新的模式来解开过去
IF 2 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-14 DOI: 10.1002/dep2.70016
Cecilia A. Benavente, Kevin M. Bohacs, Sila Pla-Pueyo

Significant progress has been made in understanding lake basin evolution through climatic and tectonic changes using sedimentology, sequence stratigraphy, geochemistry, hydrology and watershed characteristics to interpret three main lake basin types: overfilled, balanced-fill and underfilled, including fluvio-lacustrine systems. Groundwater constraints, however, have been mostly overlooked, especially as they affect the formation and preservation of climate-sensitive indicators (‘proxies’). The incorporation of subsurface water flow factors into lake basin analysis has led to the realisation that more diverse and complex facies associations can result from its influence, particularly in balanced-fill and underfilled lake basins. Better understanding of palaeohydrogeology of lacustrine systems results from integrated analysis, including sediment and water delivery pathways, components of potential accommodation and conditions in the lake water column studied in modern lakes and ancient lake strata representing deep-time lacustrine basins. This special issue intends to act as a pivotal point for future studies on limnogeology. Our goal is to improve our understanding of water delivery pathways (precipitation, overland, groundwater) into fluvio-lacustrine basins, their influences on such systems and their record of climate and tectonics and to update the existing models for them. The integration of the full range of variables holds great promise to help us better constrain controls and factors affecting the evolution of inland water systems through time and space, to Mars and beyond.

利用沉积学、层序地层学、地球化学、水文学和流域特征来解释三种主要的湖盆类型:过充型、平衡充型和欠充型,包括河流-湖泊系统,在了解气候和构造变化对湖盆演化的影响方面取得了重大进展。然而,地下水的限制大多被忽视了,特别是当它们影响气候敏感指标(“代理”)的形成和保存时。将地下水流因素纳入湖盆分析使人们认识到,地下水的影响可能导致更多样化和复杂的相组合,特别是在平衡填充和欠填充的湖盆中。对代表深时湖盆的现代湖泊和古湖泊地层进行综合分析,包括沉积和输水途径、潜在容纳成分和湖盆水柱条件,有助于更好地了解湖泊系统的古水文地质。这期特刊旨在成为今后湖沼地质学研究的一个关键点。我们的目标是提高我们对水输送途径(降水、陆地、地下水)进入河流-湖泊盆地、它们对这些系统的影响以及它们的气候和构造记录的理解,并更新现有的模型。将各种变量整合在一起,很有希望帮助我们更好地限制影响内陆水系统在时间和空间、火星和更远地方演变的控制和因素。
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引用次数: 0
Shifting baselines of coral-reef species composition from the Late Pleistocene to the present in the Florida Keys 佛罗里达群岛珊瑚礁物种组成基线从晚更新世到现在的变化
IF 1.9 3区 地球科学 Q1 GEOLOGY Pub Date : 2025-05-13 DOI: 10.1002/dep2.70009
Lauren T. Toth, Anastasios Stathakopoulos, Scarlette Hsia, David Weinstein

The ongoing global-scale reassembly of modern coral reefs is unprecedented compared with the observed stability of most late Quaternary reef assemblages. One notable exception is the marine isotope stage (MIS) 5e (ca 130–116 thousand years ago [ka]) reefs in the Florida Keys, where the ubiquitous shallow-water coral, Acropora palmata, was near absent. Little is known, however, about reefs that grew during MIS5d–a (ca 116–74 ka), between MIS5e and the Holocene. It is therefore unclear whether Florida's unique MIS5e coral assemblages represent a geologically brief anomaly or a more persistent departure from the western Atlantic coral-reef archetype. We addressed that question by reconstructing the composition of MIS5d–a reefs within 29 coral-reef cores collected throughout the Florida Keys. We then compared the relative composition of corals during MIS5d–a to existing datasets from MIS5e, Holocene and modern (1996 and 2022) reefs to evaluate how far today's reef assemblages have diverged from geological baselines. We show that although the proportion of reef frameworks built by corals was remarkably consistent (ca 38%), species composition changed significantly through time. Acropora palmata was rare throughout MIS5, which we hypothesise was due to greater cold-temperature stress in Florida's subtropical reefs compared with the more climatically stable tropics. In contrast, the massive reef-building coral, Orbicella spp., was regionally dominant throughout the late Quaternary, but has become increasingly rare on modern reefs. By 2022, reefs in the Florida Keys were characterised by a truly novel coral assemblage dominated by Porites astreoides and Siderastrea siderea. In many ways, Florida's reefs defy the concept of a natural baseline; instead, their most persistent characteristic since the Late Pleistocene is their uniqueness. Yet, as reefs are increasingly subjected to unprecedented levels of environmental change, the exceptions to what was normal in the past could, paradoxically, provide the best geological analogues for the future.

与大多数观察到的晚第四纪珊瑚礁组合的稳定性相比,正在进行的全球范围内的现代珊瑚礁重组是前所未有的。一个值得注意的例外是佛罗里达群岛的海洋同位素阶段(MIS) 5e(大约13万至11.6万年前)珊瑚礁,那里几乎没有无处不在的浅水珊瑚,棕榈Acropora palmata。然而,人们对MIS5d-a(约116-74 ka)期间生长的珊瑚礁知之甚少,MIS5e和全新世之间。因此,尚不清楚佛罗里达独特的MIS5e珊瑚组合是否代表了地质上短暂的异常,还是与西大西洋珊瑚礁原型的持久偏离。我们通过重建在佛罗里达群岛收集的29个珊瑚礁核心中的MIS5d-a珊瑚礁的组成来解决这个问题。然后,我们将MIS5d-a期间珊瑚的相对组成与MIS5e、全新世和现代(1996年和2022年)珊瑚礁的现有数据集进行比较,以评估今天的珊瑚礁组合偏离地质基线的程度。我们发现,虽然珊瑚构建的珊瑚礁框架的比例非常一致(约38%),但物种组成随着时间的推移发生了显著变化。棕榈Acropora palmata在MIS5中很少见,我们假设这是由于与气候稳定的热带地区相比,佛罗里达亚热带珊瑚礁的寒冷温度压力更大。相比之下,在整个晚第四纪,巨大的造礁珊瑚Orbicella spp.在区域内占主导地位,但在现代珊瑚礁上越来越罕见。到2022年,佛罗里达群岛的珊瑚礁以一种真正新颖的珊瑚组合为特征,主要是Porites astreoides和Siderastrea siderea。在许多方面,佛罗里达的珊瑚礁违背了自然基线的概念;相反,它们自晚更新世以来最持久的特征是它们的独特性。然而,随着珊瑚礁越来越多地受到前所未有的环境变化的影响,过去正常情况下的例外可能会为未来提供最好的地质类似物,这是自相矛盾的。
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引用次数: 0
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Depositional Record
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