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Multi-elemental chemostratigraphy of Triassic mudstones in eastern Svalbard: Implications for source rock formation in front of the World’s largest delta plain 斯瓦尔巴东部三叠纪泥岩的多元素化学地层学:对世界最大三角洲平原前烃源岩形成的启示
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2022-02-03 DOI: 10.1002/dep2.182
Fredrik Wesenlund, Sten-Andreas Grundvåg, Victoria Sjøholt Engelschiøn, Olaf Thießen, Jon Halvard Pedersen

The Triassic Boreal Ocean was a shallow epicontinental basin and the sink of the World's largest delta plain known to date. Nutrient and freshwater supply from this delta have been regarded as important causes for high productivity and water mass stratification, forming Middle Triassic oil-prone source rocks. Recent studies attribute upwelling and a productivity-induced oxygen minimum zone as important factors. A multi-elemental chemostratigraphic study of a Spathian–Carnian mudstone succession exposed in eastern Svalbard was performed to investigate their formation. This includes 89 samples from three localities, from which 34 elements were acquired using combustion and X-ray fluorescence analyses. The goal is to provide a correlation framework and infer the role of productivity, redox and water mass restriction on organic matter accumulation and source rock formation. These processes had major impact on the source potential. The Spathian Vendomdalen Member suggests deposition during intermittent benthic euxinia and low productivity, corresponding with a reported deep thermocline that obstructed upwelling. The lower Anisian lower–middle Muen Member shows negligible enrichment in redox-sensitive elements but in situ phosphate nodules, consistent with developing upwelling and moderate productivity. The middle Anisian upper Muen Member formed during high productivity and phosphogenesis and is linked with basin-wide upwelling. Productivity, phosphate and redox proxies are all strongly enriched in the upper Anisian–Ladinian Blanknuten Member. In the south-western Barents Sea, the pro-deltaic environment of the emerging Triassic Boreal Ocean delta system had terminated these conditions. The upper Ladinian upper Blanknuten Member formed within intermittent euxinic bottom waters due to the shallowing sea level. The Carnian Tschermakfjellet Formation marks the dominance of the prograding delta system and the end of Triassic oil-prone source rock formation in Svalbard.

三叠纪北洋是一个浅表陆盆地,也是迄今为止已知的世界上最大的三角洲平原的汇点。该三角洲的营养和淡水供应被认为是高产和水团分层的重要原因,形成了中三叠统的易油烃源岩。最近的研究将上升流和生产力诱导的氧气最低区视为重要因素。对斯瓦尔巴群岛东部暴露的Spathian-Carnian泥岩序列进行了多元化学地层学研究,以研究其形成。这包括来自三个地区的89个样本,其中34个元素是通过燃烧和X射线荧光分析获得的。目的是提供一个相关框架,并推断生产力、氧化还原和水团限制对有机质积累和烃源岩形成的作用。这些过程对资源潜力产生了重大影响。Spathian-Vendomdalen段表明,间歇性海底euxinia沉积和低生产力,与据报道的阻碍上升流的深层温跃层相对应。下阿尼斯阶下-中穆恩段显示氧化还原敏感元素的富集程度可以忽略不计,但原位磷结核,与正在发展的上升流和中等生产力一致。中阿尼斯阶-上穆恩段形成于高生产力和磷成因期间,与全盆地上升流有关。产能、磷酸盐和氧化还原指标均在上阿尼斯-拉迪尼亚-布兰克努滕段强烈富集。在巴伦支海西南部,新生的三叠纪-北洋三角洲系统的亲三角洲环境终止了这些条件。由于海平面变浅,Ladinian上段Blanknuten段形成于间歇性的euxinic底层水中。Carnian-Tschermakfjellet组标志着斯瓦尔巴群岛前进三角洲系统的主导地位和三叠纪易油源岩组的结束。
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引用次数: 4
Sharp-based shoreface successions reconsidered in three-dimensions: A forward stratigraphic modelling perspective 在三维空间中重新考虑尖锐的滨面序列:一个正演地层模拟的视角
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2022-02-02 DOI: 10.1002/dep2.177
Brian J. Willis, Tao Sun, R. Bruce Ainsworth

Sea-level fall is commonly inferred to generate a sharp-based shoreface succession that displays an abrupt vertical transition from heterolithic, lower shoreface to sandy, upper shoreface deposits across a marine erosion surface. Three-dimensional, process physics-based, coupled hydrodynamic-morphodynamic models are constructed to compare bedding architecture and facies patterns of wave-dominated delta deposits preserved during normal (static sea level) and forced (falling sea level) regression and then transgression during subsequent sea-level rise. The models suggest that wave-dominated deltas will develop a sandy shoreface inner clinoform dipping from the subaerial delta plain to a relatively flat wave-scoured subaqueous delta top, which is laterally separated from a delta front outer clinoform that dips from the subaqueous delta top edge to the shelf floor. As these systems prograde, deposits of these dual-clinoforms will become vertically stacked and will be separated by a regressive surface of marine erosion. Significant grain-size contrasts between these vertically stacked clinoform deposits reflect differences in sediment-transport directions and sorting under river and wave-driven littoral currents along the coast, and cannot be related uniquely to sea-level changes. The marine erosion surface under a sharp-based shoreface deposit records abrupt facies shift across a kilometres-wide, wave-eroded surface and defines a discontinuity in the preserved vertical succession. The continuity of a regressive surface of marine erosion mapped over many tens to hundreds of kilometres across mid-shelf regions of some stratigraphic sequences reflects a gradual lateral shift in the position of littoral current erosion on a subaqueous delta top. Timelines cross such vertical lithic discontinuities throughout the extent of a prograding deposit, and the regressive surface of marine erosion thus has little chronostratigraphic significance. The results of these models suggest caution in inferring sea-level changes from the character of vertical facies changes observed in individual well logs and isolated outcrop exposures.

海平面下降通常被推断为产生了一个尖锐的海岸面序列,该序列显示出从异石器时代的下海岸面到沙质的上海岸面沉积物在海洋侵蚀表面的突然垂直过渡。构建了基于过程物理学的三维耦合流体动力学-形态动力学模型,以比较在正常(静态海平面)和强迫(下降海平面)回归期间以及随后海平面上升期间海侵期间保存的波浪主导三角洲沉积物的层理结构和相模式。模型表明,波浪主导的三角洲将形成从陆上三角洲平原倾斜到相对平坦的波浪冲刷水下三角洲顶部的砂质滨面内斜坡,该斜坡与从水下三角塔顶部边缘倾斜到陆架底部的三角洲前缘外斜坡横向分离。随着这些系统的推进,这些双斜坡形式的沉积物将垂直堆积,并将被海蚀的退积面分隔开。这些垂直堆叠的斜坡状沉积物之间的显著粒度差异反映了沿岸河流和波浪驱动的沿岸流下沉积物输移方向和分选的差异,并且不能与海平面变化唯一相关。陡峭海岸面沉积物下的海蚀表面记录了数公里宽的波浪侵蚀表面上的突然相移,并定义了保留的垂直序列中的不连续性。在一些地层序列的中陆架区域,绘制了数十至数百公里的海蚀退水面的连续性,反映了水下三角洲顶部沿岸流侵蚀位置的逐渐横向变化。时间线在进积矿床的整个范围内穿过这种垂直的岩屑间断,因此海蚀的退积面几乎没有年代地层意义。这些模型的结果表明,从单个测井和孤立露头暴露中观察到的垂直相变化特征推断海平面变化时要谨慎。
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引用次数: 1
Resolving stratigraphic architecture and constraining ages of paralic strata in a low-accommodation setting, Firebag Tributary, McMurray Formation, Canada 加拿大McMurray组Firebag支流低可容纳环境下近海相地层构型解析及约束年龄
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2022-02-02 DOI: 10.1002/dep2.181
Lucian Rinke-Hardekopf, Shahin E. Dashtgard, James A. MacEachern, Murray K. Gingras

The McMurray Formation in McMurray Depocentre, Canada, is typically subdivided into stratigraphic units based on regionally mappable marine mudstones, the bases of which define flooding surfaces (bottom to top: Lower McMurray, C2, C1, B2, B1, A2, A1 depositional unit). However, the McMurray Formation comprises a variety of palaeoenvironments, with the north-eastern Firebag Tributary hosting significant delta-plain deposits in the Lower McMurray and B1 depositional units. Facies analysis of 60 cores and 4763 wireline logs was used to resolve the palaeoshoreline trajectory and stratigraphic architecture in Firebag Tributary. Of 14 identified facies, three delta-plain facies reveal: (1) eluviated palaeosols, interpreted as shrublands and woodlands formed during base-level fall; (2) gleyed palaeosols, interpreted as tidal marshes; and (3) coals formed in coastal mires, the two latter facies are interpreted to accumulate during base-level rise. Eluviated palaeosols occur below the Lower McMurray coal seam, implying valley incision and a maximum regressive surface. Gleyed palaeosols underlying the coal seam atop the B1 depositional unit do not record base-level fall. Wetting-upward coals overlying either palaeosol facies indicate base-level rise (i.e. major flooding surface). B1 depositional unit coals and gleyed palaeosols are overlain by shallow-marine facies or are eroded by wave ravinement during transgression. Consequently, the tops of coals or gleyed palaeosols correlate to the bases of regional marine mudstones elsewhere in McMurray Depocentre. Stratigraphic cross sections showcase palaeoshoreline regression and transgression. During the Lower McMurray and B1 depositional units, widespread coals and palaeosols indicate the palaeoshoreline resided near the western edge of Firebag Tributary. Regression during C2 through B2 depositional units and A2 and A1 depositional units resulted in palaeoshorelines near the Alberta–Saskatchewan border. To complement a previously dated Lower McMurray ash (121.39 ± 0.2 Ma), a new high-confidence maximum depositional age from ash in the B1 coal seam (115.09 ± 0.16 Ma) allows an estimate to be made of depositional duration, indicating depositional units represent ca 0.16 Myr.

加拿大McMurray Depocentre的McMurray组通常根据区域可绘制的海相泥岩细分为地层单元,其底部定义了洪泛面(自下而上:下McMurray、C2、C1、B2、B1、A2、A1沉积单元)。然而,McMurray组包含多种古环境,东北Firebag支流在下McMurray和B1沉积单元中拥有重要的三角洲平原沉积物。通过对60个岩心和4763条测井电缆的相分析,确定了Firebag支流的古海岸线轨迹和地层结构。在已确定的14个相中,有三个三角洲平原相显示:(1)淋溶古土壤,解释为基准面下降期间形成的灌木丛和林地;(2) 潜育的古土壤,被解释为潮汐沼泽;和(3)在海岸淤泥中形成的煤,后两个相被解释为在基准面上升期间积累。冲积古土壤出现在下McMurray煤层下方,意味着山谷切口和最大后退面。B1沉积单元顶部煤层下方的疏松古土壤没有记录到基准面下降。上覆任一古溶胶相的向上润湿煤表明基准面上升(即主要洪泛面)。B1沉积单元煤和潜育古土壤被浅海相覆盖,或在海侵过程中被波浪沟侵蚀。因此,煤的顶部或潜育的古土壤与McMurray Depocentre其他地方的区域海洋泥岩的底部相关。地层剖面展示了古海岸线的回归和海侵。在Lower McMurray和B1沉积单元期间,广泛分布的煤炭和古土壤表明古海岸线位于Firebag支流的西边缘附近。C2至B2沉积单元以及A2和A1沉积单元期间的回归导致阿尔伯塔省-萨斯喀彻温省边界附近的古海岸线。为了补充先前测得的Lower McMurray火山灰(121.39±0.2 Ma),B1煤层火山灰的新的高置信度最大沉积年龄(115.09±0.16 Ma)允许对沉积持续时间进行估计,表明沉积单元代表约0.16 Myr。
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引用次数: 3
Channel incision into a submarine landslide on a Carboniferous basin margin, San Juan, Argentina: Evidence for the role of knickpoints 阿根廷圣胡安石炭纪盆地边缘海底滑坡的河道切口:凿点作用的证据
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2022-01-31 DOI: 10.1002/dep2.178
Charlotte Allen, Luz E. Gomis-Cartesio, David M. Hodgson, Jeff Peakall, Juan-Pablo Milana

Emplacement of submarine landslides, or mass-transport deposits, can radically reshape the physiography of continental margins, and strongly influence subsequent sedimentary processes and dispersal patterns. Typically, progressive healing of the complicated relief generated by the submarine landslide occurs prior to progradation of sedimentary systems. However, subsurface and seabed examples show that submarine channels can incise directly into submarine landslides. Here, the evolution of a unique exhumed example of two adjacent, and partially contemporaneous, submarine channel-fills is documented. The channels show deep incision (>75 m), and steep lateral margins (up to 70°), cut into a >200 m thick submarine landslide. The stepped basal erosion surface, and multiple terrace surfaces, are mantled by clasts (gravels to cobbles) reflecting periods of bedload-derived sedimentation, punctuated by phases of downcutting and sediment bypass. The formation of multiple terrace surfaces in a low aspect ratio confinement is consistent with the episodic migration of knickpoints during entrenchment on the dip slope of the underlying submarine landslide. Overlying sandstone-rich channel-fills mark a change to aggradation. Laterally stacked channel bodies coincide with steps in the original large-scale erosion surface, recording widening of the conduit; this is followed by tabular, highly aggradational fill. The upper fill, above a younger erosional surface, shows an abrupt change to partially confined tabular sandstones with normally graded caps, interpreted as lobe fringe deposits, which formed due to down-dip confinement, followed by prograding lobe deposits. Overlying this, an up-dip avulsion induced lobe switching and back-stepping, and subsequent failure of a sandstone body up-dip led to emplacement of a sandstone-rich submarine landslide within the conduit. Collectively, this outcrop represents episodic knickpoint-generated incision, and later infill, of a slope adjusting to equilibrium. The depositional signature of knickpoints is very different from existing models, but is probably reflective of other highly erosional settings undergoing large-scale slope adjustment.

海底滑坡或物质搬运沉积物的就位可以从根本上重塑大陆边缘的地貌,并对随后的沉积过程和扩散模式产生强烈影响。通常,海底滑坡产生的复杂地形的逐渐愈合发生在沉积体系的进积之前。然而,地下和海底的例子表明,海底通道可以直接切入海底滑坡。在这里,一个独特的两个相邻的、部分同时期的海底通道填充物的出土例子的演变被记录下来。河道切口深(> ~ 75 m),侧缘陡(70°),切成> ~ 200 m厚的海底滑坡。阶梯式基底侵蚀面和多个阶地面被碎屑(砾石到鹅卵石)覆盖,反映了层载沉积的时期,穿插着向下切割和沉积物绕道的阶段。在低纵横比约束下形成的多个阶地面与下伏海底滑坡倾斜坡上堑壕过程中裂缝点的幕式迁移相一致。上覆富含砂岩的河道填充物标志着沉积的变化。横向堆积的沟道体与原始大规模侵蚀面的台阶重合,记录了沟道的加宽;接下来是表格式的、高度分层的填充。上部填充物位于较年轻的侵蚀面之上,显示出部分受限的板状砂岩的突变,具有通常分级的盖层,被解释为叶状条纹沉积,这是由于下倾限制而形成的,随后是递进的叶状沉积。在此之上,一个上倾的崩裂引起了叶瓣开关和后退,随后一个上倾的砂岩体的破坏导致了一个富含砂岩的海底滑坡在管道内的侵位。总的来说,这个露头代表了阶段性的裂缝点产生的切口和后来的充填,斜坡调整到平衡状态。裂缝点的沉积特征与现有模式非常不同,但可能反映了其他经历大规模坡度调整的高度侵蚀环境。
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引用次数: 2
Salt dissolution tectonism and origin of lacustrine carbonate beds: Mn-Fe-calcite and Mn-siderite micro-spherulite fabrics of the Lower Cretaceous McMurray Formation, Athabasca Oil Sands deposit, western Canada 加拿大西部阿萨巴斯卡油砂矿床下白垩统McMurray组Mn - Fe -方解石和Mn -菱铁矿微球晶结构的盐溶构造和湖相碳酸盐层成因
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2022-01-31 DOI: 10.1002/dep2.179
Paul L. Broughton

Several lacustrine carbonate beds, each a metre-thick interval of densely packed Mn-rich sideritic micro-spherulites or Mn-rich ferroan calcite micro-spherulites, are recorded for the first time within strata of the Lower Cretaceous McMurray Formation of the northern Athabasca Oil Sands deposit, western Canada. A lower McMurray lacustrine carbonate deposit is characterised by a metre-thick bed fabric of Mn-rich siderite micro-spherulites. The middle and upper interval McMurray beds developed fabrics of Mn2+-rich ferroan calcite micro-spherulites. These carbonate beds represent saline lacustrine depositional environments that resulted from the lake bottom sediments ingressed from below by Mn2+-Fe2+-rich carbonate-saturated brines. These up-section migrations of Devonian formation water were sourced from dissolution trends developed in limestone and halite-anhydrite beds of the underlying Devonian Prairie Evaporite during Cordilleran deformation of the Alberta Basin foreland. These brines ascended to the overlying McMurray Formation sediments along dissolution-collapse structures such as breccia pipes, sinkholes and margins of differentially subsided Upper Devonian fault blocks. The up-section migration of a sulphate-saturated Fe2+ and Mn2+-rich brine resulted in the ingress of a lower McMurray lacustrine bottom sediment at a site associated with the development of a peat mire terrain. Microbial redox of the lake bottom sediment resulted in a carbonate bed of micro-spherulitic fabrics of Mn-rich siderite interwoven with pyrite laminae. Subsequent salt dissolution events and up-section migrations of Devonian brine during deposition of the middle and upper McMurray intervals resulted in similar carbonate-saturated but sulphate-poor chemistry. These saline flows also ingressed lacustrine bottom sediments below, and resulted in limestone beds of densely packed spherulitic fabrics of Mn-ferroan calcite, not siderite. These deposits provide insight into largely unknown dispositions of voluminous brine resulting from salt dissolution trends below the Athabasca Oil Sands and further our understanding of controversial McMurray depositional processes.

在加拿大西部阿萨巴斯卡油砂矿床北部的下白垩统麦克默里组地层中,首次发现了几个湖相碳酸盐岩层,每个层厚达1米,由密集排列的富锰菱铁矿微球粒或富锰铁方解石微球粒组成。下麦克默里湖相碳酸盐矿床以一米厚的富锰菱铁矿微球晶为特征。中上部McMurray层发育富锰方解石微球粒结构。这些碳酸盐层代表了盐碱化湖泊沉积环境,是由湖底沉积物由富含Mn2+ - Fe2+的碳酸盐饱和盐水从下面侵入而形成的。这些泥盆纪地层水的上剖面迁移来自于阿尔伯塔盆地前陆科迪勒拉变形期间下伏泥盆纪草原蒸发岩的灰岩和盐硬石膏层的溶解趋势。这些盐水沿着角砾岩管道、陷落孔和不同沉降的上泥盆统断块边缘等溶蚀崩塌构造上升到上覆的McMurray组沉积物中。硫酸盐饱和的富Fe2+和Mn2+盐水的向上迁移导致McMurray湖底沉积物进入与泥炭沼泽地形发育有关的地点。湖底沉积物的微生物氧化还原作用形成了由富锰菱铁矿和黄铁矿层状交织而成的微球粒结构碳酸盐层。随后的盐溶解事件和泥盆纪盐水在McMurray中上段沉积期间的上剖面迁移导致了类似的碳酸盐饱和但硫酸盐缺乏的化学性质。这些盐水流也进入了湖底沉积物,形成了由锰铁方解石而不是菱铁矿组成的密集球状结构的石灰岩床。这些沉积物提供了对阿萨巴斯卡油砂下方盐溶解趋势导致的大量盐水分布的深入了解,并进一步加深了我们对有争议的麦克默里沉积过程的理解。
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引用次数: 0
Blood, lead and spheres: A hindered settling equation for sedimentologists based on metadata analysis 血、铅和球体:沉积学家基于元数据分析的阻碍沉降方程
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2022-01-31 DOI: 10.1002/dep2.176
Jaco H. Baas, Megan L. Baker, Patricia Buffon, Lorna J. Strachan, Helen C. Bostock, David Hodgson, Joris T. Eggenhuisen, Yvonne T. Spychala

A revision of the popular equation of Richardson and Zaki (1954a, Transactions of the Institute of Chemical Engineering, 32, 35–53) for the hindered settling of suspensions of non-cohesive particles in fluids is proposed, based on 548 data sets from a broad range of scientific disciplines. The new hindered settling equation enables predictions of settling velocity for a wide range of particle sizes and densities, and liquid densities and viscosities, but with a focus on sediment particles in water. The analysis of the relationship between hindered settling velocity and particle size presented here shows that the hindered settling effect increases as the particle size decreases, for example, a 50% reduction in settling velocity is reached for 0.025 mm silt and 4 mm pebbles at particle concentrations of 13% and 25% respectively. Moreover, hindered settling starts to influence the settling behaviour of sediment particles at volumetric concentrations of merely a few per cent. For example, the particle settling velocity in flows that carry 5% silt is reduced by at least 22%. These observations suggest that hindered settling greatly increases the efficiency of natural flows to transport sediment particles, but also particulate carbon and pollutants, such as plastics, over large distances.

基于来自广泛科学学科的548个数据集,提出了对Richardson和Zaki (1954a,化学工程研究所学报,32,35-53)的流行方程的修正,该方程用于流体中非粘性颗粒悬浮物的阻碍沉降。新的阻碍沉降方程可以预测大范围颗粒尺寸和密度、液体密度和粘度的沉降速度,但重点是水中的沉积物颗粒。本文对阻碍沉降速度与粒径关系的分析表明,阻碍沉降效果随着粒径的减小而增大,如0.025 mm粉土和4 mm卵石在粒径浓度分别为13%和25%时,沉降速度降低50%。此外,在体积浓度仅为百分之几时,阻碍沉降就开始影响泥沙颗粒的沉降行为。例如,在携带5%泥沙的水流中,颗粒沉降速度至少降低22%。这些观察结果表明,阻碍沉降大大提高了自然水流的效率,使泥沙颗粒、颗粒碳和污染物(如塑料)能够远距离运输。
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引用次数: 4
Customised display of large mineralogical (XRD) data: Geological advantages and applications 大型矿物学(XRD)数据的定制显示:地质优势和应用
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2022-01-10 DOI: 10.1002/dep2.174
Rute Coimbra, Kilian B. Kemna, Fernando Rocha, Maurits Horikx

X-ray diffraction mineralogical analysis of geological sequences is a well-established procedure in both academia and industry, rendering a large volume of data in short-analytical time. Yet, standard data treatment and resulting interpretations present limitations related to the inherent complexities of natural geological materials (e.g. compositional variety, structural ordering), and are often time consuming and focussed on a very detailed inspection. Several alternatives were evaluated in terms of advantages and disadvantages to the main goal of generating a user-friendly, fast and intuitive way of processing a large volume of X-ray diffraction data. The potential of using raw X-ray diffraction data to interpret mineralogical diversity and relative phase abundances along sedimentary successions is explored here. A Python based program was tailored to assist in raw data organisation. After this automated step, a 3D surface computation renders the final result within minutes. This single-image representation can also be integrated with complementary information (sedimentary logs or other features of interest) for contrast and/or comparison in multi-proxy studies. The proposed approach was tested on a set of 81 bulk and clay-fraction diffractograms (intensity in counts per second—cps and respective angle—º2Ɵ) obtained from a Cenomanian mixed carbonate–siliciclastic stratigraphic succession, here explored by combining mineralogical (XY) and stratigraphic/geological information (Z). The main goal is to bypass preliminary data treatment, avoid time-consuming interpretation and unintended, but common, user-induced bias. Advantages of 3D modelling include fast processing and single-image solutions for large volumes of XRD data, combining mineralogical and stratigraphic information. This representation adds value by incorporating field (stratigraphic/sedimentological) information that complements and contextualises obtained mineralogical data. Limitations of using raw intensity data were evaluated by comparison with the results obtained via other standard data interpretation methods (e.g. semi-quantitative estimation). A visual and statistical contrast comparison confirmed a good equilibrium between computation speed and precision/utility of the final output.

地质序列的X射线衍射矿物学分析是学术界和工业界公认的程序,可以在短时间内提供大量数据。然而,标准数据处理和由此产生的解释存在与自然地质材料固有复杂性(如成分多样性、结构有序性)相关的局限性,并且往往耗时且侧重于非常详细的检查。评估了几种替代方案的优缺点,以实现生成一种用户友好、快速直观的方式来处理大量X射线衍射数据的主要目标。这里探索了使用原始X射线衍射数据来解释沉积序列的矿物学多样性和相对相丰度的潜力。一个基于Python的程序是为帮助原始数据组织而定制的。在这个自动化步骤之后,3D表面计算将在几分钟内呈现最终结果。这种单图像表示也可以与互补信息(沉积测井或其他感兴趣的特征)相结合,用于多代理研究中的对比和/或比较。所提出的方法在一组81个体积和粘土部分衍射图上进行了测试(强度以每秒计数为单位——cps和各自的角度——º2Ɵ),这些衍射图是从Cenomanian混合碳酸盐-硅碎屑地层序列中获得的,这里通过结合矿物学(XY)和地层/地质信息(Z)进行探索。主要目标是绕过初步数据处理,避免耗时的解释和意外但常见的用户引发的偏见。3D建模的优势包括快速处理和大量XRD数据的单图像解决方案,结合矿物学和地层信息。这种表示通过结合现场(地层/沉积学)信息来增加价值,这些信息补充并结合了所获得的矿物学数据。通过与其他标准数据解释方法(如半定量估计)获得的结果进行比较,评估了使用原始强度数据的局限性。视觉和统计对比比较证实了计算速度和最终输出的精度/实用性之间的良好平衡。
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引用次数: 1
Earth’s oldest tsunami deposit? Early Archaean high-energy sediments in the ca 3.48 Ga Dresser Formation (Pilbara, Western Australia) 地球上最古老的海啸沉积物?约3.48 Ga Dresser组中的早太古代高能沉积物(西澳大利亚皮尔巴拉)
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2022-01-06 DOI: 10.1002/dep2.175
Eric A. Runge, Jan-Peter Duda, Martin J. Van Kranendonk, Joachim Reitner

Dynamic sedimentary processes are a key parameter for establishing the habitability of planetary surface environments on Earth and beyond and thus critical for reconstructing the early evolution of life on our planet. This paper presents a sedimentary section from the ca 3.48 Ga Dresser Formation (Pilbara Craton, Western Australia) that contains high-energy reworked sediments, possibly representing the oldest reported tsunami deposit on Earth to date. Field and petrographic evidence (e.g. up to 20 cm large imbricated clasts, hummocky bedding, Bouma-type graded sequences) indicate that the high-energy deposit represents a bi-directional succession of two debrite–turbidite couplets. This succession can best be explained by deposition related to passage and rebound of tsunami waves. Sedimentary processes were possibly influenced by highly dense silica-rich seawater. The tsunami was probably triggered by local fault-induced seismic activity since the Dresser Formation was deposited in a volcanic caldera basin that experienced syndepositional extensional growth faulting. However, alternative triggers (meteorite impact, volcanic eruption) or a combination thereof cannot be excluded. The results of this work indicate a subaquatic habitat that was subject to tsunami-induced high-energy disturbance. Potentially, this was a common situation on the early Archaean Earth, which experienced frequent impacts of extraterrestrial bodies. This study thus adds to the scarce record of early Archaean high-energy deposits and stresses the relevance of high-energy depositional events for the early evolution of life on Earth.

动态沉积过程是确定地球内外行星表面环境宜居性的关键参数,因此对重建地球上生命的早期进化至关重要。本文介绍了约3.48 Ga Dresser组(西澳大利亚皮尔巴拉火山口)的沉积剖面,该剖面包含高能改造沉积物,可能是迄今为止地球上最古老的海啸沉积物。现场和岩相证据(例如高达20 cm的大型叠瓦状碎屑、丘状层理、Bouma型分级序列)表明,高能矿床代表了两个碎屑岩-浊积岩对的双向序列。这种连续性最好用与海啸波通过和反弹有关的沉积来解释。沉积过程可能受到高密度富硅海水的影响。海啸可能是由局部断层引发的地震活动引发的,因为Dresser组沉积在经历同沉积伸展生长断层作用的火山口盆地中。然而,不能排除其他触发因素(陨石撞击、火山喷发)或其组合。这项工作的结果表明,水下栖息地受到海啸引发的高能干扰。这可能是早期太古代地球上的常见情况,那里经常受到地外天体的撞击。因此,这项研究增加了早期太古代高能沉积的稀少记录,并强调了高能沉积事件与地球生命早期进化的相关性。
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引用次数: 1
On the delimitation of the carbonate burial realm 论碳酸盐岩埋藏领域的划分
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-11-14 DOI: 10.1002/dep2.173
Adrian Immenhauser

Over the past decades, the burial realm, the most prolonged and arguably the least well-understood diagenetic environment, has received significant research attention. Despite remarkable progress driven by exploratory drilling, outcrop analogue studies and experimental work, the scientific theories defining the burial sub-domains are inconsistently presented in the literature. This paper reviews the concepts, processes and products that characterise the burial realm from the viewpoint of the carbonate geoscientist. Typical features of carbonate burial (fluid types, porosity evolution, diagenetic fabrics, patterns in isotope geochemistry) in epicontinental and marine basins are presented and discussed. A step towards an improved conceptual delimitation and a subdivision of the carbonate burial realm is taken, and an intuitive terminology is proposed. The very shallow limit of the burial realm is placed within the upper sediment column (redox boundary; centimetres to tens of metres). In the shallow (marine) burial domain (down to depths of many hundreds of metres), carbonate dissolution and reprecipitation, sediment dewatering and grain reorganisation take place. Interstitial waters are mainly marine (and subordinate meteoric) in origin and the system is fluid-dominated. Under ongoing burial, physical and chemical compaction reduces pore space. At burial depths of ca 750 m, initial sediment porosities (40–80%) are reduced to about 30%. The intermediate burial domain (hundreds of metres to about 2 km; T < 100°C) is characterised by the transition from fluid-buffered to rock-buffered diagenesis. In the deep-burial domain (ca 2–12 km; T > 100°C), marine formation fluids are increasingly modified by rock–fluid interaction and replaced by saline brines. The transition from the deep burial to the very low-grade metamorphic domain is placed at depths of 12–15 km (T > 250°C). Here, carbonates undergo recrystallisation into meta-carbonate and equigranular marble fabrics.

在过去的几十年里,埋藏领域,这个最漫长、也可以说是最不为人所知的成岩环境,受到了重要的研究关注。尽管勘探钻探、露头模拟研究和实验工作取得了显著进展,但文献中定义埋藏子域的科学理论并不一致。本文从碳酸盐岩地球科学家的角度综述了埋藏领域的概念、过程和产物。介绍并讨论了陆缘和海相盆地碳酸盐岩埋藏的典型特征(流体类型、孔隙演化、成岩组构、同位素地球化学模式)。朝着改进碳酸盐岩埋藏领域的概念划界和细分迈出了一步,并提出了直观的术语。埋藏区的极浅边界位于上部沉积物柱内(氧化还原边界;厘米至数十米)。在浅(海洋)埋藏域(深达数百米),发生碳酸盐溶解和再沉淀、沉积物脱水和颗粒重组。间质水主要来源于海洋(以及次要的大气),系统以流体为主。在正在进行的埋藏中,物理和化学压实减少了孔隙空间。在约750米的埋深处,初始沉积物孔隙率(40–80%)降至约30%。中间埋藏域(数百米至约2公里;T<100°C)的特征是从流体缓冲成岩作用过渡到岩石缓冲成岩。在深埋藏域(约2–12 km;T>100°C),岩石-流体相互作用越来越多地改变了海洋地层流体,并被盐水所取代。从深埋到极低级变质域的过渡位于12–15 km的深度(T>250°C)。在这里,碳酸盐经过再结晶,形成偏碳酸盐和等粒大理石结构。
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引用次数: 19
The Steptoean Positive Carbon Isotope Excursion (SPICE), inorganic aragonite precipitation and sea water chemistry: Insights from the Middle–Late Cambrian Port au Port Group, Newfoundland 阶阶正碳同位素偏移(SPICE)、无机文石沉淀和海水化学:来自纽芬兰中晚寒武世Port au Port群的启示
IF 2.4 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-10-29 DOI: 10.1002/dep2.172
Joyce E. Neilson, Rosalia Barili, Alexander Brasier, Luiz F. De Ros, Sarah Ledingham

The Late Cambrian Steptoean Positive Carbon Isotope Excursion marks a time of significant change in ocean chemistry and trilobite faunas. On the lead up to the carbon isotope excursion and at the excursion itself, there is global evidence from Laurentia and Gondwana of cementation by primary aragonite in shallow subtidal environments accompanied by deposition of aragonitic ooids. However, this occurred at a time widely considered to have been characterised by ‘calcite seas’ when the primary inorganic phases (marine cements and ooids) are normally presumed calcitic. This study has investigated the chemostratigraphy of the Middle–Late Cambrian Port au Port Group, Newfoundland, including the early marine cements. Here, the marine cements contain increasing concentrations of strontium towards the peak carbon isotope excursion (up to 5500 ppm at the peak excursion) before dropping off post-peak excursion, consistent with the original cements having been aragonitic. This trend is accompanied by relict oomouldic porosity, again suggesting an aragonitic precursor. Primary inorganic mineralogy is largely controlled by the Mg/Ca ratio of sea water but estimates of the Mg/Ca ratio of Late Cambrian oceans are variable (0.8–2). At this level, other factors such as water temperature and pCO2 have been shown to affect mineralogy with warm waters and high levels of CO2 favouring aragonite. It is possible that the warm waters and anoxia that caused the carbon isotope excursion created conditions favourable for the precipitation of aragonite at the same time as major trilobite faunal turnover.

晚寒武世阶梯阶正碳同位素偏移标志着海洋化学和三叶虫动物群发生重大变化的时期。在碳同位素漂移之前和漂移本身,Laurentia和Gondwana的全球证据表明,在浅海潮下环境中,原生文石胶结伴随着文石卵体的沉积。然而,这发生在一个被广泛认为具有“方解石海”特征的时期,当时的初级无机相(海洋胶结物和流体)通常被认为是方解石相。研究了纽芬兰中晚寒武统Port au Port群的化学地层学,包括早期海相胶结物。在这里,海洋胶结物中锶的浓度在碳同位素峰值偏移时增加(峰值偏移时达到5500 ppm),然后在峰后偏移时下降,这与原始胶结物为文石相一致。这种趋势伴随着残余的模塑孔隙,再次表明文石前体。原生无机矿物学在很大程度上受海水Mg/Ca比值的控制,但对晚寒武世海洋Mg/Ca比值的估计是可变的(0.8-2)。在这个水平上,水温和二氧化碳分压等其他因素已被证明会影响矿物学,温暖的海水和高水平的二氧化碳有利于文石。在三叶虫主要区系更替的同时,引起碳同位素偏移的暖水和缺氧可能为文石的降水创造了有利条件。
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引用次数: 3
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Depositional Record
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