Environmental Monitoring and Assessment最新文献

Metals and metalloids are persistent environmental pollutants with the potential for bioaccumulation, posing significant health risks, including genotoxicity. These contaminants are prevalent in industrial and agricultural runoff. This study utilizes Trachemys dorbigni, an aquatic reptile, as a bioindicator to assess environmental contamination by metals and metalloids in both rural and urban settings in Pelotas, Rio Grande do Sul, Brazil. We captured specimens using pit-type traps with barriers (fyke nets), dividing them into two groups: 15 from a rural area and 15 from an urban area. Each animal underwent physical evaluations, and biometric data (weight, total carapace length and width) were recorded to calculate body condition indices. Biological samples were collected via manual restraint, with blood samples drawn from the supraoccipital venous sinus and linear carapace fragments obtained through manual scraping. Water samples from each location were also analyzed. Using atomic absorption spectrophotometry, concentrations of Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb and Zn were measured in the water, carapace fragments, and blood samples. Cellular damage was assessed through flow cytometry and microscopy, examining erythrocyte disruption, reactive oxygen species, membrane fluidity, DNA fragmentation and micronucleus formation. Urban area samples showed concentrations of As, Cd, Cu, Fe, Hg and Ni exceeding national standards set by the Conselho Nacional do Meio Ambiente (CONAMA), with rural areas also showing elevated levels of As, Cd, Hg and Ni. Biometric analysis revealed that rural reptiles had significantly higher weight and carapace dimensions, whereas urban tortoises displayed a higher body condition index and significantly elevated blood levels of Al, Cr, Ni, Pb and Zn. The urban tortoises also exhibited higher concentrations of all tested metal(loid) in carapace samples (p < 0.05) and more pronounced cellular damage (p < 0.05), highlighting severe bioaccumulation and associated deleterious effects. Elevated reactive oxygen species levels were noted in rural specimens. This study underscores the impact of water degradation and metal(loid) pollution in urban environments on T. dorbigni, suggesting that carapace tissue analysis can serve as a chronic exposure indicator to these harmful contaminants.

Tunisia is currently faced with the extremely delicate problem of managing the millions of tons of phosphogypsum (PG) discharges which is already causing considerable environmental damage. The research carried out in this work is part of a geochemical assessment of the level of heavy metal contamination in phosphogypsum waste from the Mdhilla region (Gafsa, southern Tunisia). The assessment of ETM contamination/pollution is based on the relatively simple principles of measuring concentrations, calculating indices, and comparing them with established standards, which vary according to the nature of the element, its toxicity, and the receiving environment. Six PG samples are taken from the storage heaps right next to the chemical group’s plant. Our investigations to assess the level of heavy metals contamination focused on: zinc (Zn), chromium (Cr), copper (Cu), nickel (Ni), and cadmium (Cd). These metallic elements are measured by atomic absorption spectrometry. To achieve our objectives, we calculated several indices, such as the geo-accumulation index (Igeo), the contamination factor (FC), the degree of contamination (DC), and the sediment pollution index (IPS). The index approach enables us to predict the extent of heavy metal pollution in these PG discharges from the Mdhilla region. The Mdhilla region’s PG heavy metals contents show the following order of abundance: Zn > Ni > Cr > Cd > Cu. Calculation of contamination/pollution indices reveals in principle polymetallic contamination dominated by three elements: cadmium, nickel, and copper.

Olive mill wastewater (OMWW) was used in ferti-irrigation due to its high water content, as well as its organic and mineral richness. However, this by-product also contains elevated levels of polyphenols, which may pose phytotoxic risks to soil microbiota and plants over time. To address this concern, we conducted a thorough examination of the phenolic composition of OMWW and the phenolic content of amended soils using HPLC analysis. Additionally, we assessed the residual phytotoxicity of OMWW across various soil rhizospheric layers (0–30 cm, 30–60 cm, and 60–90 cm). Standard germination tests were performed using soil extracts with sorghum (Sorghum bicolor) and tomato (Solanum lycopersicum) seeds. We also measured α-amylase activities in the germinated seeds for both species, comparing them to raw OMWW and control soil extracts. HPLC analysis revealed that tyrosol, ferulic acid, and hydroxytyrosol were the predominant phenolic compounds in crude OMWW, while no detectable compounds were found in the soil extracts. Germination tests indicated minimal toxicity in the topsoil amended with OMWW, with a noticeable reduction in residual phytotoxicity at greater depths. These results aligned with the α-amylase activity assessments, which demonstrated significantly higher enzyme activity in the deeper soil layers (30–60 cm and 60–90 cm), with no substantial differences compared to control extracts.

Graphical abstract

The present study was aimed at investigating the source, quality, and quantity of organic matter and labile fraction of biochemical constituents in the surficial sediments of Arabian Sea Shoreline at Kollam, India, which gives an input into the processes associated with the subsurface geochemistry pattern. About 15 surface sediment samples were collected from the five beaches for this study during January 2021. The samples were analyzed for CHN, total organic carbon (TOC), and labile fraction such as carbohydrates (CHO), proteins (PRO), and lipids (LIP). The TOC/TN ratio revealed that the source organic matter (OM) in the samples was primarily of marine origin and autochthonous, except TM3 at Thirumullavaram. Thirumullavaram is a sheltered beach, and it has low hydrodynamic process. The high organic matter content in TM3 (13.9) may be the originated from the terrestrial input. The hierarchical cluster analysis revealed that TM3 indicate that unique character to other stations. Principal component analysis revealed that three components accounted for 78% of the total variance. PC1 variance was associated with carbon-based organic compounds. PC2 was predominantly influenced by CHO and LOM, suggesting that PC2 may encompass variability associated with these nutritional profiles. PC3 was influenced by LIP and LIP/CHO, showing it may be a lipid-related component. The PRO to CHO ratio is < 1, exhibiting old aged organic matter deposited in sediments and the meso-oligotrophic status. The LIP to CHO ratio, recorded as < 1, exhibits the poor quality of energetic (food) OM in sediments. The sediment samples exhibit the following trend CHO > PRO > LIP.

The interconnected systems of lakes of Bengaluru, India, experience tremendous stress due to unsustainable urbanisation. Traditional lake-centric research approach struggles to capture and address this issue due to the cascaded nature of impacts in interconnected lake systems. Hence, this study assesses the impact of urbanisation on a lake series scale, focusing on the Yele Mallappa Shetty Lake series (YMSLS). Land use land cover change analysis (1993–2023) showed that in 1993, the YMSLS catchment area was dominated by open spaces (53.4%) and agriculture land and vegetation (35%), with built-up areas covering only 7.2%. By 2023, the built-up area has expanded to 34.6% and became the dominant land use. This rapid urbanisation has led to increased water surface area from wastewater influx, causing significant weed growth and water pollution in the lakes. Lake water quality assessment showed that faecal coliform, total coliform, dissolved oxygen, and biochemical oxygen demand levels exceeded standard limits with spatio-temporal variations driven by interconnectivity. Pollutant flushing during monsoon reduced pollution load in upstream lakes, but high wastewater inflow made downstream lakes, particularly the end lake, highly polluted but perennial. Increased water availability expanded the user base of the end lake, but traditional uses have declined and coping strategies of users, such as wastewater lift irrigation from the lake, became unsustainable. The study indicates that spatial interdependence and cascading effects necessitate a lake series approach for assessing the impacts of urbanisation on interconnected lake system, which is crucial for enhancing water security and preparedness for future extreme events.

Clarifying the nonlinear impacts of vegetation cover on production-living-ecological function (PLEF) coordination is essential to ecological restoration regulation and sustainable land use. However, the threshold effect of vegetation cover on PLEF coordination, particularly in major function-oriented zones (MFZs), has yet to receive attention. This study selected Xiangyang City, China, as the case area to identify the impact threshold of vegetation cover on PLEF coordination from the perspectives of the region as a whole and MFZ, respectively. The results showed that the PLEF coordination was high in the center and east while low in the west. For production-ecological function, 51.46% of the area was primarily coordinated and above, while for production-living function, 61.35% of the city area was severely uncoordinated. Vegetation cover was high in the west and low in the east. A negative correlation existed between vegetation cover and PLEF coordination. Urban built-up areas with lower vegetation cover showed higher levels of PLEF coordination, whereas western mountainous regions with higher vegetation cover demonstrated lower levels of PLEF coordination. Furthermore, vegetation cover exhibited a pronounced threshold effect on PLEF coordination, featuring conspicuous regional variations. The identified thresholds of vegetation cover for PLEF coordination in key development, agricultural production, and key ecological function zones were 0.3896, 0.2272, and 0.8161, respectively. Our study provides scientific references for the impact assessment of ecological restoration and the synergistic enhancement of land functions.

The removal of nickel from wastewater is a significant environmental concern because of its potential hazards to environment. Adsorption is known as an efficient water treatment strategy and there is a growing interest in the development of new adsorbent materials providing rapid adsorption kinetics, cost-effectiveness, and high adsorption capacity. In this study, the feasibility of Mn₃O₄–MnOOH nanocomposites was evaluated as the adsorbent material for the removal of nickel ions from wastewater. The nanocomposites were prepared using a modified sonochemical method and characterized by XRD analysis and SEM images. Batch adsorption experiments were carried out under different experimental conditions obtained by varying solution pH, adsorbent amount, and contact period. Under the optimum adsorption conditions, the %RE value was recorded around 80% for 10 mg/L Ni(II) ions. The adsorption characteristics were investigated with respect to adsorption isotherms and kinetics. Langmuir and Freundlich isotherm models were used to fit the adsorption data and the results indicated that adsorption of nickel ions onto nanocomposite could be complex and obey both monolayer adsorption and heterogeneous surface. Accordingly, maximum adsorption capacity of nanocomposites were calculated as 12.387 mg/g. Research works comparing the kinetic models of pseudo-first-order, pseudo-second-order, and Elovich revealed that chemical sorption plays an important role as the rate-limiting step in the adsorption of nickel ions.

Microplastics are minute plastic particles ranging from 1 µm to 5 mm in size. Mangroves are crucial ecosystems with roles in carbon sequestration, shoreline protection, and habitat for diverse species. Despite their significance, the extent of microplastic pollution in mangroves, especially in India, remains inadequately understood. To address this gap, we conducted a seasonal sampling in the Kota mangrove ecosystem at different water column depths. Our analysis revealed average microplastic abundances of 0.93 (monsoon), 3.71 (post-monsoon), and 2.92 MPs/L (pre-monsoon). The average microplastic abundances were 19.88 and 15.86 microplastics/individual for Gerres filamentosus and Sillago sihama, respectively. Fibrous microplastics smaller than 1 mm were dominant. Transparent microplastics dominated the water column (28.57% in monsoon, 77.45% in post-monsoon, and 49.24% in pre-monsoon), and they were also prevalent in S. sihama (49.55%) and G. filamentosus (41.51%). This points towards greater bioavailability and suggests that transparent microplastics are often mistaken for prey. Anthropogenic influence is a major factor that governs microplastic distribution than season in Kota mangroves. Fourier transform infrared spectroscopy revealed that polypropylene was the dominant polymer in both water column as well as in S. sihama and G. filamentosus. We identified aquaculture, tourism, and local activities as probable sources of microplastic pollution. The monitoring data is crucial as it provides insights into microplastics pollution in two economically important fish species that are largely consumed by the local population. Exposure to microplastics from the consumption of these fish may cause serious health issues for human beings.

This study is an inventory analysis and environmental life cycle assessment of hotel food waste management that seeks to inform efforts towards the development of bio circular economy in Zimbabwe. An audit of food waste generation and an inventory analysis of the prevailing food waste management practices at three selected hotels was undertaken. The greenhouse gas emissions from the prevailing disposal of food waste at dumpsites and the proposed biological treatment of food waste were evaluated using the Tier 1 FOD method and Tier 1 method of biological treatment using the 2019 refined 2006 Intergovernmental Panel on Climate Change guidelines. Environmental life cycle assessment was also conducted for the open dumping, composting, and anaerobic digestion. The average food waste generation within the Zimbabwean hospitality industry was estimated at 1.63 kg/guest/day, with a minimum and maximum of 1.01 and 2.25 kg/guest/day, respectively. Source-separated food waste is currently being collected indiscriminately by municipal waste collection trucks for final disposal at the official landfills or dumpsites. This calls for the need for an offtake system of the source-separated food waste in the form of composting or anaerobic digestion. Study results showed that the disposal of food waste at solid waste disposal sites contributes to the highest greenhouse gas emissions, followed by composting with a 75% reduction in greenhouse emissions. Anaerobic digestion brings about a maximum reduction in greenhouse emissions of 97%. Environmental life cycle assessment results also show that anaerobic digestion is the best method leading to net negative environmental impacts.

The aim of this study is to assess the spatiotemporal variation, sources, and health impacts of the carbonyl compounds (carbonyls) in Ho Chi Minh City (HCMC), the third-most populous city in Southeast Asia. Sampling was conducted according to the US.EPA Method TO-11A, from 2012 to 2016 in both the dry and the rainy seasons at twelve sites. The result shows that the carbonyl mixing ratios are high when compared to typical cities. Formaldehyde, acetaldehyde, and acetone are the most abundant carbonyls together accounting for 89% of the measured carbonyls. The carbonyl mixing ratio in rainy (46.0 ± 32.2 ppb) is about twofold higher than that in dry (23.7 ± 10.3 ppb). An inverse distance weighting method was adopted to map the spatial distribution of carbonyls across the city. The result shows that the carbonyl levels tended to be high in the city center. Three carbonyl sources are resolved by the PCA/APCS method: industrial sources and solvent usage (54%), vehicle exhausts (24%), cooking emissions (11%). Both lifetime cancer risk (LCR) and non-cancer hazard index (HIs) were calculated to estimate the health impacts on the community due to inhalation exposure to current carbonyl levels. The LCR values vary from 5.31 × 10⁻⁶ to 5.75 × 10⁻⁵ for formaldehyde higher than those of 6.61 × 10⁻⁷ to 1.36 × 10⁻⁵ for acetaldehyde, which mostly exceeded the US.EPA recommendation for five age groups. The hazard quotient values are 12.0 to 68.4 for acrolein, 0.44 to 2.84 for acetaldehyde, 0.55 to 1.85 for formaldehyde, and 0.13 to 0.89 for propionaldehyde.