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Environmental risk assessment of agricultural discharges containing pesticides in a watershed with outflow to a Ramsar lagoon system 向拉姆萨尔泻湖系统流出的集水区含农药农业排放物的环境风险评估。
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-11 DOI: 10.1007/s10661-026-15136-0
Manuel Antonio Reyes-Prado, Leonel Ernesto Amabilis-Sosa, Blenda Ramírez-Pereda, Henri Márquez-Pacheco, Adriana Roé-Sosa, Karina Ramirez

Intensified agricultural activities increase wastewater discharge into coastal lagoon systems, with high levels of organic matter, nutrients, and pesticides. This study monitored and assessed environmental conditions at a key agricultural drainage site to assess ecological risk to a Ramsar lagoon system. The Water Pollution Index (WPI) and Risk Quotient (RQ) were applied jointly to identify priority pollutants and their potential impact on the lagoon system of international ecological importance. Sampling was conducted over 4 years in an agricultural drain in northwestern Mexico, where farming, livestock, and poultry effluents converge. Physicochemical parameters, nutrients, and pesticides were determined using standardized methods and gas chromatography coupled with mass spectrometry. The overall WPI value was 1.07, ranking the water as highly polluted. Chemical oxygen demand (1051 mg/L) and total suspended solids (155 mg/L) contributed most to the index, reflecting a high load of recalcitrant organic matter. Eighteen pesticides from different chemical groups were identified, including thiamethoxam, acetamiprid, chlorpyrifos, and diazinon, which had the highest RQ values (≥ 0.8), indicating a significant ecological risk to aquatic organisms. The coexistence of organic pollutants and nutrients suggests cumulative and synergistic effects that compromise the stability of the lagoon system. There is technical evidence of the need to implement strategies for the treatment and sustainable management of agricultural wastewater, promoting its reuse in line with the principles of the circular economy.

集约化的农业活动增加了向沿海泻湖系统排放的废水,其中含有大量的有机物、营养物和农药。本研究对一个重要的农业排水地点的环境状况进行监测和评估,以评估拉姆萨尔泻湖系统的生态风险。采用水污染指数(WPI)和风险商(RQ)联合识别具有国际生态重要性的优先污染物及其对泻湖系统的潜在影响。在墨西哥西北部的一个农业排水沟中进行了4年的采样,那里是农业、牲畜和家禽污水汇集的地方。理化参数、营养成分和农药使用标准化方法和气相色谱联用质谱测定。总体WPI值为1.07,属于重度污染。化学需氧量(1051 mg/L)和总悬浮物(155 mg/L)对该指标贡献最大,反映出难固性有机物的高负荷。鉴定出18种不同化学类群的农药,其中噻虫嗪、啶虫脒、毒死蜱和二嗪农的RQ值最高(≥0.8),表明对水生生物具有显著的生态风险。有机污染物和营养物质的共存表明,累积和协同效应损害了泻湖系统的稳定性。有技术证据表明,需要执行农业废水处理和可持续管理战略,根据循环经济原则促进其再利用。
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引用次数: 0
Soil microplastics at different depths before and after mechanical harvesting: case study in Anhui Province, China 机械收获前后不同深度土壤微塑料:以安徽省为例
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-10 DOI: 10.1007/s10661-026-15155-x
Shi-hao Zhao, Di Dai, Yu-xin Tan, Si-yao Li, Bing-yu Chen, Qian Wang, Long Chen, Ji-yue Wang, Shu-guang Zhu, Fa-zhi Xie

Although mechanical harvesting has substantially increased the efficiency of agricultural production, the manner in which it influences the abundance and distribution pattern of microplastics (MPs) in the soil remains unknown. Specially, the relationships between MPs and soil physicochemical properties are unclear. Herein, soil samples before and after mechanical harvesting in Anhui Province are collected and segmented into three layers: top (0–10 cm), middle (10–20 cm), and bottom (20–30 cm). Besides analyzing MPs, standardized tests are conducted on the soil porosity, organic carbon, total nitrogen, and moisture content. Results demonstrate that the mechanical harvesting decreases the abundance of soil MPs in the top and middle layers but increases that in bottom layer. However, a considerable positive correlation between soil MP levels before and after harvesting is identified; their distribution characteristics were compared as well. We suppose that mechanical harvesting introduces a small amount of additional MPs while facilitating the penetration capacity of existing MPs. Although the soil organic carbon, total nitrogen, and moisture content are observed to positively correlate with each other, they are not directly related to MPs. Furthermore, we assume that mechanical harvesting physically drives the connection of soil porosity with other parameters, as their positive correlations become evident after harvesting. This study provides a valuable finding: MP penetration can be facilitated by mechanical harvesting, which should be considered for the prevention of potential MP-induced ecological risks on deep soil and groundwater.

尽管机械收获大大提高了农业生产的效率,但它对土壤中微塑料(MPs)的丰度和分布模式的影响方式仍然未知。特别是,MPs与土壤理化性质之间的关系尚不清楚。本文采集安徽省机械采收前后的土壤样品,并将其划分为3层:上(0-10 cm)、中(10-20 cm)、下(20-30 cm)。除分析MPs外,还对土壤孔隙度、有机碳、全氮、含水量进行了标准化测试。结果表明,机械采收降低了表层和中间层土壤MPs丰度,但增加了底层土壤MPs丰度。然而,发现收获前后土壤MP水平之间存在相当大的正相关关系;并比较了它们的分布特征。我们认为机械采收引入了少量额外的MPs,同时促进了现有MPs的穿透能力。土壤有机碳、全氮和水分三者之间存在正相关关系,但与MPs之间没有直接关系。此外,我们假设机械采收在物理上驱动了土壤孔隙度与其他参数的联系,因为它们的正相关性在采收后变得明显。该研究提供了一个有价值的发现:机械收获可以促进MP的渗透,应考虑防止潜在的MP引起的深层土壤和地下水的生态风险。
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引用次数: 0
Real-time detection for water pollutant based on triboelectric nanogenerators and machine learning 基于摩擦纳米发电机和机器学习的水污染物实时检测。
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-10 DOI: 10.1007/s10661-026-15140-4
Zhijie Zhang, Wei Long, Peiyin Liu

Water cleanliness and safety are fundamental to sustaining human activities and maintaining ecological stability. In this study, a self-powered water-quality sensing system is developed based on contact electrification and the distinct charge-transfer behaviors of different pollutants at the liquid–solid interface. When water samples containing heavy metal ions, microplastics, or rust flow through a conductive sponge, contact friction between the pollutants and the flexible porous structure generates differentiated triboelectric signals, which are continuously collected using an electrometer and a data acquisition card. By further integrating a Light Gradient Boosting Machine (Light GBM) model, a mapping relationship between signal features and pollutant types and concentrations is established for water-quality prediction. Experimental results demonstrate that the system can effectively identify heavy metal ions (Zn2+, Ba2+, and Al3+), polypropylene (PP) microplastics, and rust (Fe2O3), achieving an average classification accuracy of 86.67%. Validation experiments using municipal water samples from Kunming supplemented with quantified rust further confirm the reliability of the system. Under varying temperature (4.36–42.75 °C), pH (3–11), and turbidity conditions, the system maintains stable and accurate pollutant recognition, with detection accuracy reaching up to 100%. This study integrates liquid–solid triboelectric sensing with machine learning, providing a promising strategy for intelligent water-quality monitoring.

水的清洁和安全是维持人类活动和维持生态稳定的根本。在本研究中,基于接触通电和不同污染物在液固界面的不同电荷转移行为,开发了一种自供电水质传感系统。当含有重金属离子、微塑料或铁锈的水样流过导电海绵时,污染物与柔性多孔结构之间的接触摩擦会产生差异化的摩擦电信号,这些信号通过静电计和数据采集卡连续采集。通过进一步整合光梯度增强机(Light Gradient Boosting Machine, Light GBM)模型,建立了信号特征与污染物类型和浓度之间的映射关系,用于水质预测。实验结果表明,该系统能有效识别重金属离子(Zn2+、Ba2+、Al3+)、聚丙烯(PP)微塑料和铁锈(Fe2O3),平均分类准确率达到86.67%。昆明城市水样的验证实验进一步证实了该系统的可靠性。在不同温度(4.36 ~ 42.75℃)、pH(3 ~ 11)、浊度条件下,系统对污染物的识别稳定准确,检测准确率可达100%。本研究将液固摩擦电传感与机器学习相结合,为智能水质监测提供了一种有前途的策略。
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引用次数: 0
Bird diversity and health status of bioindicator species (Coturnix coturnix, Horsfield, 1821) in Egypt’s Manzala Lagoon: seasonal resilience monitoring 埃及Manzala泻湖生物指示物种(Coturnix Coturnix, Horsfield, 1821)鸟类多样性和健康状况:季节性恢复力监测。
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-10 DOI: 10.1007/s10661-026-15142-2
Valeria Guerretti, Mohamed Abdou Abdallah Abd-Ellatif, Rubina Vangone, Claudia Cucolo, Maria Maddalena De Vivo, Abdelraouf Abdelrahman Moustafa, Giulia Guerriero, Samira Rizk Mansour

Manzala Lagoon, the largest coastal wetland of Egypt, lies within the Nile Delta and serves as an essential sanctuary for both resident and migratory birds. Despite its importance for regional biodiversity, the ecosystem faces significant anthropogenic pressures, with recent dredging activities constituting a major disturbance. This study aimed to evaluate dredging impacts on bird diversity and environmental health in the Ashtoum El-Gamil Protected Area. Seasonal monitoring in 2024, combining camera-based morphological identification with molecular barcoding of feathers (n = 13; cytochrome oxidase 1 gene), documented 123 species across 11 orders and 23 families, with 51 species consistently observed year-round. Health assessments in the endemic Coturnix coturnix (common quail) were conducted by measuring genotoxic damage, DNA repair capacity (via poly(ADP)-ribosylation), and total antioxidant capacity (TAC) in the gut, liver, and gonads. Results revealed reduced DNA recovery, elevated antioxidant capacity, and a prominent 40 kDa PARP immunoreactive band, particularly in gut and gonads. These oxidative stress indicators were independent of low heavy metal loads, implicating factors like rising temperatures may be the primary drivers. These findings highlight dredging’s limited immediate effects on species diversity but underscore subtle health risks, advocating sustained, long-term monitoring and targeted management to safeguard wetland biodiversity.

Manzala泻湖是埃及最大的沿海湿地,位于尼罗河三角洲,是候鸟和留鸟的重要避难所。尽管它对区域生物多样性很重要,但生态系统面临着巨大的人为压力,最近的疏浚活动构成了一个主要的干扰。本研究旨在评估疏浚对Ashtoum El-Gamil保护区鸟类多样性和环境健康的影响。在2024年的季节监测中,将基于相机的形态学鉴定与羽毛分子条形码(n = 13;细胞色素氧化酶1基因)相结合,记录了11目23科123种,其中51种全年均有观察。通过测量遗传毒性损伤、DNA修复能力(通过聚(ADP)-核糖基化)和总抗氧化能力(TAC),对常见鹌鹑(Coturnix)进行健康评估。结果显示DNA恢复减少,抗氧化能力提高,PARP免疫反应带明显,特别是在肠道和性腺。这些氧化应激指标与低重金属负荷无关,暗示气温上升等因素可能是主要驱动因素。这些发现强调了疏浚对物种多样性的直接影响有限,但强调了微妙的健康风险,提倡持续、长期的监测和有针对性的管理,以保护湿地的生物多样性。
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引用次数: 0
Fecal Contamination in Drinking Water: A review of detection techniques, pathogen dynamics, and sustainable remediation approaches 饮用水中的粪便污染:检测技术、病原体动力学和可持续修复方法的综述。
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-10 DOI: 10.1007/s10661-026-15135-1
Nisha Gaur, Shiv Shankar, Rakshita Chaudhary, Nahid Akhtar, Ashish Vyas

Fecal contamination poses a persistent global threat to drinking water safety, especially in low- and middle-income countries with limited sanitation and treatment infrastructure. Fecal matter transmits a wide array of enteric pathogens like bacteria (Escherichia coli, Vibrio cholerae, Salmonella, Shigella), viruses (norovirus, rotavirus, adenoviruses), protozoa (Giardia, Cryptosporidium), and occasionally fungi and helminths—driving outbreaks of diarrheal diseases, cholera, and other waterborne illnesses that cause substantial morbidity and childhood mortality. This review synthesizes current knowledge on the sources, environmental survival, and transmission behavior of fecal-associated microbes in drinking water systems, including persistence in biofilms, seasonal fluctuations, and distribution network dynamics. It critically compares detection methods, from conventional culture-based techniques to advanced molecular tools that provide greater speed, specificity, and field applicability. The paper also evaluates remediation approaches, contrasting established physical-chemical treatments (coagulation–sedimentation, filtration, UV disinfection, chlorination) with sustainable, eco-friendly alternatives such as bioremediation, phytoremediation, bacteriophage therapy, predatory bacteria, and biosurfactant use, which offer low-cost, chemical-free pathogen control. Effective integration of sensitive detection technologies with targeted, sustainable remediation strategies supported by quantitative microbial risk assessment is essential to reduce fecal pollution risks and protect public health. The review calls for adaptive, multi-barrier water management frameworks to achieve safer drinking water globally.

Graphical Abstract

粪便污染对饮用水安全构成持续的全球威胁,特别是在卫生和处理基础设施有限的低收入和中等收入国家。粪便会传播多种肠道病原体,如细菌(大肠杆菌、霍乱弧菌、沙门氏菌、志贺氏菌)、病毒(诺如病毒、轮状病毒、腺病毒)、原生动物(贾第鞭毛虫、隐孢子虫),偶尔还会传播真菌和蠕虫,导致腹泻病、霍乱和其他水媒疾病的爆发,导致大量发病率和儿童死亡率。这篇综述综合了目前关于饮用水系统中粪便相关微生物的来源、环境生存和传播行为的知识,包括生物膜的持久性、季节波动和分布网络动态。它批判性地比较了检测方法,从传统的基于培养的技术到提供更高速度、特异性和现场适用性的先进分子工具。本文还评估了修复方法,将现有的物理化学处理方法(混凝沉淀、过滤、紫外线消毒、氯化)与可持续的、环保的替代方法(如生物修复、植物修复、噬菌体治疗、掠食性细菌和生物表面活性剂的使用)进行了对比,这些方法提供了低成本、无化学物质的病原体控制。在定量微生物风险评估的支持下,将敏感检测技术与有针对性的可持续补救战略有效结合,对于减少粪便污染风险和保护公众健康至关重要。该报告呼吁建立适应性的多屏障水管理框架,以在全球实现更安全的饮用水。
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引用次数: 0
Total column ozone from ground-based spectral radiometric measurements at the Colombian Andes 哥伦比亚安第斯山脉地面光谱辐射测量的总臭氧柱。
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-10 DOI: 10.1007/s10661-026-15163-x
Lina Puerta, Miguel-Ángel Garrido-Tamayo, Daniel Nisperuza

Remote sensing techniques for total ozone (O₃) quantification have not been extensively explored in Colombia; most investigations rely on in situ measurements from ground-based networks or satellite observations. In topographically constrained urban areas, complex atmospheric dynamics present considerable challenges to conducting remote sensing measurements from ground-based systems. Nevertheless, in this study, the Dobson methodology was employed to estimate the total column O₃ from ground-based ultraviolet solar spectral radiometric measurements in the urban area of a polluted valley in the Colombian Andes. Two measurement campaigns, undertaken in 2020 and 2022 under slightly different atmospheric conditions, were conducted. The findings indicated that even minor variations in local atmospheric pollution levels, associated with air quality and climatological variability, directly influence total ozone estimation. The results were compared with total column O₃ retrieved from the Ozone Monitoring Instrument (OMI) aboard the Aura satellite of the National Aeronautics and Space Administration (NASA). Under partly clear-sky conditions, approximately 50% ((r = 0.55)) of the ozone retrieved from ground-based measurements exhibited a linear relationship with ozone values from OMI. Under partly cloudy-sky and heavily polluted conditions, a lack of correlation was observed.

哥伦比亚还没有广泛探索臭氧总量(O₃)量化的遥感技术;大多数调查依赖于地面网络或卫星观测的现场测量。在地形受限的城市地区,复杂的大气动力学对从地面系统进行遥感测量提出了相当大的挑战。然而,在这项研究中,Dobson方法被用来估计哥伦比亚安第斯山脉污染山谷城市地区的地面紫外线太阳光谱辐射测量的总柱O₃。分别于2020年和2022年在略有不同的大气条件下进行了两次测量活动。研究结果表明,即使与空气质量和气候变率有关的当地大气污染水平的微小变化,也会直接影响臭氧总量的估算。研究结果与美国国家航空航天局(NASA)“Aura”卫星上的臭氧监测仪(OMI)采集的总柱O₃进行了比较。在部分晴空条件下,大约50% (r = 0.55)的地面测量臭氧与OMI臭氧值呈线性关系。在部分多云和严重污染条件下,观察到缺乏相关性。
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引用次数: 0
Assessing two decades (2000–2020) of agricultural and mining-driven land-cover change through spatial analysis and social perceptions in Sonsón, Antioquia, Colombia 通过空间分析和社会认知评估哥伦比亚安蒂奥基亚Sonsón地区20年(2000-2020年)农业和矿业驱动的土地覆盖变化
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-10 DOI: 10.1007/s10661-026-15046-1
Natalia Alvear Goyes, Joaquín Guillermo Ramírez Gil, Paulo J. Murillo Sandoval

In Latin America, efforts to accelerate economic growth through agriculture and mining often generate strong tensions with environmental sustainability. We examine this dynamic in Sonsón (Antioquia, Colombia), a municipality at the epicenter of simultaneous agricultural intensification and mineral extraction. To characterize the forces reshaping this landscape from 2000 to 2020, we combined wall-to-wall satellite analysis with evidence from local stakeholders. Annual land-cover trajectories were mapped with the Continuous Change Detection and Classification (CCDC) algorithm using the Landsat archive. In parallel, we surveyed 55 respondents from agricultural, mining, commercial, environmental authority, and other sectors to elicit perceptions of drivers, impacts, and governance. Although most of the territory (≈90.8%) remained stable, this apparent stability masks two distinct waves of transformation: a first wave (2000–2005) concentrated in the Magdalena Medio lowlands with grassland and mining expansion, and a second wave (2015–2020) in the high-altitude “Zona Fria” with the intensification of export-oriented crops and grasslands. Environmental authorities and commerce consistently identified mining as a key driver, a role that industry representatives tended to downplay, while farmers emphasized the shift toward export crops. Taken together, these trends provide an anticipatory warning: despite limited widespread deforestation to date, growing pressures from agriculture and mining threaten forest ecosystems, water quality, and social stability. Strengthened spatial planning, proactive conservation, and cross-sector collaboration are urgently needed to align economic ambitions with ecological integrity. This integrated approach demonstrates how combining long-term Earth observation with social data can strengthen environmental monitoring and land-use assessment in heterogeneous mountain regions.

在拉丁美洲,通过农业和采矿业加速经济增长的努力往往与环境可持续性产生强烈的矛盾。我们在Sonsón(哥伦比亚安蒂奥基亚)研究了这种动态,这是一个同时处于农业集约化和矿物开采中心的城市。为了描述从2000年到2020年重塑这一景观的力量,我们将墙到墙的卫星分析与当地利益相关者的证据结合起来。利用Landsat存档数据,利用连续变化检测和分类(CCDC)算法绘制了年土地覆盖轨迹。同时,我们调查了来自农业、矿业、商业、环境部门和其他部门的55名受访者,以了解驱动因素、影响和治理的看法。尽管大部分地区(≈90.8%)保持稳定,但这种明显的稳定掩盖了两波明显的转型浪潮:第一波(2000-2005年)集中在马格达莱纳中河低地,草原和矿业扩张;第二波(2015-2020年)在高海拔的“Zona Fria”,出口导向型作物和草原的发展加强。环保部门和商业部门一直认为采矿是一个关键的驱动因素,但行业代表往往会淡化这一作用,而农民则强调向出口作物的转变。综上所述,这些趋势提供了一个预先的警告:尽管迄今为止广泛的森林砍伐有限,但农业和采矿业日益增长的压力威胁着森林生态系统、水质和社会稳定。迫切需要加强空间规划、积极保护和跨部门合作,使经济目标与生态完整性保持一致。这种综合方法展示了如何将长期地球观测与社会数据相结合,加强异质性山区的环境监测和土地利用评价。
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引用次数: 0
Integrating pesticide molecular, soil, and electrolyte features through tree-based ensemble learning for accurate sorption prediction 通过基于树的集成学习,整合农药分子、土壤和电解质特征,实现准确的吸附预测
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1007/s10661-026-15138-y
Mariem Khouni

Although machine learning (ML) has been increasingly used to predict pesticide sorption, most existing models rely primarily on molecular and soil descriptors and rarely account for the influence of solution chemistry. This limitation reduces their relevance for environmental monitoring, particularly under variable water quality conditions, such as salinity. In this study, an interpretable ensemble ML framework was developed to predict the soil–water sorption coefficient (K) by integrating pesticide molecular properties, soil characteristics, and electrolyte descriptors. A dataset of 975 laboratory-derived batch sorption observations, covering 65 pesticides, 23 soils, and multiple electrolyte types and concentrations, was compiled from peer-reviewed studies. Six tree-based ensemble models were trained and evaluated, with XGB achieving the best predictive performance (R2 = 0.938; RMSE = 0.248) on an independent test set. Model interpretation using SHAP revealed that electrolyte parameters were the dominant predictors, with electrolyte molecular mass (MME, 28%) and electrolyte concentration (CE, 25%) contributing more than traditional descriptors such as octanol water coefficient (KOW, 18%) and soil organic carbon (OC, 12%). Nonlinear response patterns were consistent with ionic strength effects and cation-bridging mechanisms, supporting the learned relationships’ mechanistic plausibility. External validation under unseen conditions confirmed robust generalization (R2 = 0.950). This cost-effective, interpretable framework enables regulators and agronomists to simulate pesticide mobility across varying water quality conditions, thereby supporting sustainable pesticide management and targeted risk assessment.

尽管机器学习(ML)已越来越多地用于预测农药吸收,但大多数现有模型主要依赖于分子和土壤描述符,很少考虑溶液化学的影响。这种限制降低了它们对环境监测的相关性,特别是在水质条件多变的情况下,例如盐度。在这项研究中,开发了一个可解释的集合ML框架,通过整合农药分子特性、土壤特征和电解质描述符来预测土壤-水吸收系数(K)。从同行评议的研究中汇编了975个实验室衍生的批量吸附观测数据集,涵盖65种农药、23种土壤和多种电解质类型和浓度。对6个基于树的集成模型进行了训练和评估,其中XGB在独立测试集上的预测性能最好(R2 = 0.938; RMSE = 0.248)。使用SHAP的模型解释显示,电解质参数是主要的预测因子,电解质分子质量(MME, 28%)和电解质浓度(CE, 25%)比辛醇水系数(KOW, 18%)和土壤有机碳(OC, 12%)等传统描述因子贡献更大。非线性响应模式与离子强度效应和阳离子桥接机制一致,支持学习关系的机制合理性。未知条件下的外部验证证实了稳健性泛化(R2 = 0.950)。这种具有成本效益、可解释的框架使监管机构和农学家能够模拟农药在不同水质条件下的流动性,从而支持可持续的农药管理和有针对性的风险评估。
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引用次数: 0
Vertical profiling of micro-plastics in agricultural soils: polymer types, metal interactions, and implication on crop rooting zones 农业土壤中微塑料的垂直剖面:聚合物类型、金属相互作用和对作物生根区的影响
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1007/s10661-026-15148-w
Akanksha Kumari, Sukalyan Chakraborty

Microplastics are emerging pollutants of interest in agricultural soils, as they are persistent and may have significant ecological effects. The paper examined the occurrence, properties, and distribution of microplastics in peri-urban agricultural soils in Ranchi, Jharkhand. Soil samples (n = 165; 11 sites × 3 depths × 5 replicates) were collected from ten agricultural fields and one control area at three depths (0–15 cm, 15–30 cm, and 30–45 cm). Microplastics were isolated using density separation and oxidation methods, and then morphologically categorized. FTIR spectroscopy was employed to analyze the polymer composition. Quantification of associated metals was performed using atomic absorption spectrophotometry (AAS) after acid digestion, while physicochemical parameters of the soils were measured following the protocols of APHA to establish their relationships with the presence of microplastic. The findings showed that fibers had the highest prevalence at all depths (80 ± 8 to 3320 ± 36 particles kg−1 dry soil) with the highest concentration in the surface layers. Fragments, films, and microbeads were found to decrease significantly with depth, suggesting a lack of vertical migration, except in finer fibers. Polymers were mainly polypropylene (34.3%), polyethylene (16.7%), polypropylene diene rubber (14.7%), LDPE and polyethylene-based foaming material (11.8% each), and polypropylene copolymer (10.8%). The Microplastic Pollution Load Index (MPPLI) was used to identify pollution hotspots associated with the intensive use of plastics. The interrelations between microplastic abundance and soil organic matter, as well as electrical conductivity, suggest the potential impact of microplastic on soil quality and properties (Supplementary Figs. 1, 2, and 3). Vertical distribution of microplastics shows that shallow-rooted crops face surface microplastics, while deep-rooted crops interact with finer particles in soil highlighting the need to enhance the management of plastic waste to protect soil health and sustainability in agriculture.

微塑料是农业土壤中令人感兴趣的新兴污染物,因为它们具有持久性并可能具有显著的生态影响。本文研究了贾坎德邦兰契市城郊农业土壤中微塑料的发生、性质和分布。在10个农田和1个对照区3个深度(0-15 cm、15-30 cm和30-45 cm)采集土壤样品(n = 165, 11个点× 3个深度× 5个重复)。采用密度分离法和氧化法分离微塑料,并对其进行形态分类。用FTIR光谱分析了聚合物的组成。酸消化后使用原子吸收分光光度法(AAS)对相关金属进行定量,同时根据APHA协议测量土壤的理化参数,以建立它们与微塑料存在的关系。结果表明,纤维在各深度(80±8 ~ 3320±36粒kg−1干土)中含量最高,其中表层含量最高。碎片、薄膜和微珠随着深度的增加而明显减少,这表明除了在更细的纤维中,没有垂直迁移。聚合物主要为聚丙烯(34.3%)、聚乙烯(16.7%)、聚丙烯二烯橡胶(14.7%)、LDPE和聚乙烯基发泡材料(各占11.8%)和聚丙烯共聚物(10.8%)。微塑料污染负荷指数(MPPLI)用于识别与塑料集约使用相关的污染热点。微塑料丰度与土壤有机质以及电导率之间的相互关系表明,微塑料对土壤质量和性质的潜在影响(补充图1、2和3)。微塑料的垂直分布表明,浅根作物面临表面微塑料,而深根作物与土壤中更细的颗粒相互作用,这突出表明需要加强塑料废物管理,以保护土壤健康和农业可持续性。
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引用次数: 0
Spatial distribution and ecological risks of microplastics in agricultural soils near a solid waste dumpsite in southwest Bangladesh 孟加拉国西南部固体废物倾倒场附近农业土壤中微塑料的空间分布和生态风险。
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-07 DOI: 10.1007/s10661-026-15111-9
Md Asaduzzaman Nur, Mahci Al Bashera, Md Sabbir Hasan, Md Samrat Mohay Menul Islam, Md Selim Reza, Sonia Nasrin, Durjoy Biswas, Faridul Islam, Milton Halder

Microplastics (MPs) accumulation can potentially influence soil fertility and plant productivity. MP pollution and spatial distribution in terrestrial environments, particularly in agricultural soils surrounding the municipal solid waste (MSW) dumping site in southwest Bangladesh, is still not investigated. The objective of this study was to quantify, characterize, and assess the ecological risks of MPs in agricultural soils surrounding the MSW dumpsite of Khulna City Corporation (KCC) in southwest Bangladesh. Ten (10) composite agricultural soil samples surrounding the MSW dumping site were collected and processed for MPs and trace metals analysis. We investigated the abundance, spatial distribution, characteristics, polymer types, and ecological risk of observed MPs. The results exhibited that the mean abundance of MPs was 5567 items kg−1 (range from 1667 to 11,000 items kg−1), and the dominant shape, size, and color were found in fibers (~ 43%), < 1 mm, and blue, respectively. Polyvinyl chloride (PVC) was the dominant polymer followed by HDPE and nylon among the 14 identified polymer types across the study site’s soils. Spatial analysis showed that the old dumpsite, along with agricultural soils in the vicinity of the active dumpsite, was polluted with the MPs and heavy metals. The investigated sites were classified as risk category I due to MP pollution, and the findings indicate a decrease in MP abundance as the distance from the dumping site increases. Principal component and correlation analysis indicate different anthropogenic sources of MPs and heavy metals pollution, namely the solid waste dumpsite and improper agricultural activities (p < 0.05). The findings highlight the need for integrated management strategies to prevent microplastic pollution in agricultural soils to ensure soil health and crop productivity.

微塑料(MPs)的积累可能会影响土壤肥力和植物生产力。在陆地环境中,特别是在孟加拉国西南部城市固体废物(MSW)倾倒场周围的农业土壤中,MP污染和空间分布仍未进行调查。本研究的目的是量化、表征和评估孟加拉国西南部库尔纳城市公司(KCC)垃圾倾倒场周围农业土壤中MPs的生态风险。收集了城市生活垃圾倾倒场周围的10个复合农业土壤样品,并对其进行了MPs和微量金属分析。我们调查了观察到的MPs的丰度、空间分布、特征、聚合物类型和生态风险。结果表明,MPs的平均丰度为5567个项目kg-1(范围为1667 ~ 11000个项目kg-1),主要存在于纤维中(约43%)。
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引用次数: 0
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Environmental Monitoring and Assessment
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