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Clay Adsorption Perspective on Petroleum Refining Industry 石油炼制工业对粘土吸附的展望
Pub Date : 2018-10-25 DOI: 10.11648/j.ie.20180201.13
E. Emam
Clays are the most utilized minerals and considered very efficient and economical sorbents according to their chemical and physical properties. Clays are enjoying rapid popularity in the petroleum refining industry for the various processes such as adsorption and separation. Removal of many components such as sulfur, heavy metals, colors and separation of different hydrocarbon groups of crude oil and petroleum fractions can be carried out by clay adsorption. The present review summarizes the using of clay as adsorbent in several petroleum refining processes such as desulphurization, deasphalting, waste oil recovery, bleaching, corrosion reduction, heavy metals removal and other. One of the simplest, easiest and efficient separation processes used in different industries is adsorption. Review results show that different types of clay are obtainable and used in many applications. Clay adsorption can be enhanced the treatment and finishing of crude oils and petroleum fractions through several modifications such as metals impregnation, acid and thermal activations. Bentonite clays promote the highest adsorption capacity to remove sulfur and a high bleaching potential. Attapulgite clay is effective in decolorization and neutralization any petroleum oil. Impregnation of NiO nanoparticles into kaolin improves the asphaltenes adsorption. Several modified as well as unmodified clays promote the highest removal efficiency of Ni and V from crude oil. Additionally, the adsorption pre-treatment affects the reduction in corrosion yields and the corrosion rate.
粘土是利用最多的矿物,根据其化学和物理性质被认为是非常有效和经济的吸附剂。粘土在石油炼制工业中因其吸附和分离等各种过程而迅速普及。粘土吸附可以去除原油和石油馏分中硫、重金属、颜色等多种组分,分离不同的烃类基团。综述了粘土作为吸附剂在石油炼制过程中脱硫、脱沥青、废油回收、漂白、还原腐蚀、重金属去除等方面的应用。在不同的行业中使用的最简单、最容易和最有效的分离方法之一是吸附。回顾结果表明,不同类型的粘土是可获得的,并用于许多应用。粘土吸附可以通过金属浸渍、酸活化和热活化等改性措施来增强原油和石油馏分的处理和精加工能力。膨润土具有较高的除硫吸附能力和漂白潜力。凹凸棒石粘土对任何石油都有较好的脱色中和作用。在高岭土中浸渍NiO纳米颗粒可改善沥青质吸附。几种改性和未改性粘土对原油中Ni和V的去除效果最高。此外,吸附预处理还会降低腐蚀产率和腐蚀速率。
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引用次数: 9
Fabrication and Identification of the Efficiency of a Si-Based Solar Cell 硅基太阳能电池的制备及效率鉴定
Pub Date : 2018-10-23 DOI: 10.11648/J.IE.20180201.12
Mohammad Mahmuduzzaman Tawhid, O. F. Rasel, M. Hoq, Nasrul Haque
This research represents the fabrication and characterization of a solar cell which is based on a thin p-type silicon (Si) wafer. Solar cells are the basic building blocks of Solar Panels or Modules. There are presently nine companies manufacturing solar modules in the country. Nowadays a large amount of electricity comes from solar cell. The total demand for solar cells in assembling solar modules of the nine companies are about 80-90MWp annually. Mainly, cost of solar cell depends on the Brand, type of crystal structure (Mono or Multi) and the shape or size of wafer. For the first time in the country, ‘Bangladesh Atomic Energy Commission (BAEC)’ has set up a laboratory to fabricate crystalline solar cells on a pilot basis. The method used to fabricate solar cells is the low-cost diffusion technique using POCl 3 gas source. Several solar cells of 150×150 mm 2 sizes and 200 micrometer thick are produced and characterized in the laboratory. A p-type silicon wafer is cleaned and textured to make its surface pyramid shape for absorbing more sunlight. The p-n junction used in Si-based solar cell is created after applying diffusion technique using Phosphorus-oxy-try chloride (POCl 3 ) within the silicon wafer and putting Aluminum (Al) paste on one side of the wafer. Perfectly texturing ensures the excellent pyramid height of the silicon wafers. The pyramid heights of raw, textured and doped wafers are 8233.2 A, 15222.5 A and 55654.1 A respectively. The pyramid surface shows the increasing light absorption by the solar cell that can lead to an increase in conversion efficiency of the device. The efficiency of the produced solar cell is 3.3%. The results have shown that some challenges and good opportunities in getting the high-efficient and cost effective solar cells. If the cost effective technology can be made familiar in Bangladesh then it will help in solving the power crisis in the country a great deal.
本研究代表了一种基于薄p型硅(Si)晶圆的太阳能电池的制造和特性。太阳能电池是太阳能电池板或组件的基本组成部分。目前国内有9家公司生产太阳能组件。现在大量的电力来自太阳能电池。九家公司在组装太阳能组件时,每年对太阳能电池的总需求约为80-90MWp。太阳能电池的成本主要取决于品牌、晶体结构类型(单晶还是多晶)以及晶圆的形状或尺寸。孟加拉国原子能委员会(BAEC)在该国首次建立了一个实验室,在试点基础上制造晶体太阳能电池。利用POCl 3气源制备太阳能电池的方法是低成本扩散技术。生产了几种尺寸为150×150 mm 2,厚度为200微米的太阳能电池,并在实验室中进行了表征。p型硅片经过清洗和纹理处理,使其表面呈金字塔形,以吸收更多的阳光。硅基太阳能电池中使用的p-n结是在硅片内应用扩散技术,在硅片的一侧涂上铝(Al)浆料制成的。完美的纹理保证了硅片的金字塔高度。原始晶圆、织构晶圆和掺杂晶圆的金字塔高度分别为8233.2 A、15222.5 A和55654.1 A。金字塔表面显示了太阳能电池对光的吸收增加,从而提高了设备的转换效率。所生产的太阳能电池的效率为3.3%。结果表明,在获得高效、低成本的太阳能电池方面存在一些挑战和良好的机遇。如果这种低成本的技术能够在孟加拉国普及,那么它将极大地帮助解决该国的电力危机。
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引用次数: 0
Risk Assessment and Control for Main Hazards in Reverse Osmosis Desalination Plants 反渗透海水淡化厂主要危害因素的风险评估与控制
Pub Date : 2018-06-28 DOI: 10.11648/j.ie.20180201.11
A. Awwad, M. H. Gobran, R. M. Kamal, M. A. Boraey
As the manpower is the most valuable and important element for production in any industrial plant or organisation, so their health and safety must be managed to protect them against the reasonably foreseeable risks. In this paper risk assessment is carried out for five Reverse Osmosis desalination plants to detect the main hazards in such type of plants. Health safety executive -five steps to risk assessment model is used including 5×5 risk matrix to rank the risk level and then represented by color code to clarify the priority. The materials, equipment, working place and peoples included in the operation are considered while assessing the risk and working activities are monitored and analyzed. The most common hazards are found in working at height, working inside confined spaces or under water, exposure to noise, contacting with uncovered rotating equipment, electricity, high pressurized fluid and fire. The control measures are introduced to mitigate the level of identified risks to an acceptable level like developing a permit to work system and procedures for confined space entry or working under water, lock out and tag out of the power supply while dealing with electrical equipment, guarding all rotating parts of the machines, provide the right equipment for working at height, reduce the exposure time to noise and providing sufficient training, information and safety instructions to the employees. This paper can be used as a safety booklet for RO desalination plants operators.
由于人力是任何工业工厂或组织生产中最宝贵和最重要的因素,因此必须管理他们的健康和安全,以保护他们免受合理可预见的风险。本文对5家反渗透海水淡化厂进行了风险评估,以发现反渗透海水淡化厂存在的主要危害。使用健康安全执行五步风险评估模型,包括5×5风险矩阵对风险级别进行排名,然后用颜色代码表示以明确优先级。在评估风险时,考虑到作业中的材料、设备、工作场所和人员,并对工作活动进行监测和分析。最常见的危害是在高处工作,在密闭空间或水下工作,暴露于噪音,接触未覆盖的旋转设备,电力,高压流体和火灾。引入控制措施是为了将已识别的风险水平降低到可接受的水平,例如制定工作许可系统和进入密闭空间或在水下工作的程序,在处理电气设备时锁定和标记电源,保护机器的所有旋转部件,为高空工作提供合适的设备,减少暴露于噪音的时间,并提供足够的培训。向员工提供信息和安全指导。本文可作为反渗透海水淡化厂操作人员的安全手册。
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引用次数: 1
Assessment of Aflatoxins and Aflatoxigenic Fungi Associated with Dried Vegetables from Selected Markets with in Kaduna Metropolis 卡杜纳大都市选定市场中与干蔬菜有关的黄曲霉毒素和产黄曲霉毒素真菌的评估
Pub Date : 2017-08-07 DOI: 10.11648/j.ie.20170102.14
A. Nafisa, Mohammed Sani Sambo Datsugwai, Ladan Zakari
Vegetable are considered as the leafy outgrowth of plants shoot used as food. These include those plants or plant part used in making soup or served as an integral part of main meal they are sources of nutrients, vitamins and minerals. Drying is a cheap means of preserving vegetables because they are prone to fungi contamination. The assessment of aflatoxigenic fungi associated with dried vegetables (Baobab, Red chilli pepper, Okro and Tomatoes) from selected markets within Kaduna metropolis were investigated. A total of forty (40) samples (ten samples each) of the dried vegetables were analyzed for fungi and total aflatoxin. Fungi were identified and characterized using the conventional and Molecular technique and Total Aflatoxin were identified using Enzyme linked immune-sorbent assay (ELISA). The fungi identified were Aspergillus flavus and Aspergillus niger . The result of the total aflatoxin revealed that Baobab from Sabo (SB 001) had the highest aflatoxin of 31.6μg/kg while Baobab from Barnawa (BRW 001), with aflatoxin content of 18.80μg/kg. Baobab from Tudun wada (TW 001) with aflatoxin content of 15.00μg/kg, Baobab from Malali (MLL 001) had aflatoxin content of 12.10μg/kg is higher while Baobab from Central Market had aflatoxin of 1.60μg/kg. The vegetable with the highest aflatoxin content is Baobab from Sabo (SB 001) had aflatoxin content of 31.6μg/kg, while Okra from kamazou (KMZ 003) with aflatoxin content of 27.00μg/kg and Red Chilli Pepper from Malali (MLL004) had aflatoxin content of 26.40μg/kg, Tomatoes from Malali (MLL 002) had the lowest aflatoxin content of 6.50μg /kg. These result can serve as baseline for enacting laws and observing the critical control point as the ingestion of such mycotoxins contaminated vegetables have enormous health significance. Because these toxins are capable of causing diseases in man and animals.
蔬菜被认为是植物的叶状分枝,用作食物。这些包括那些植物或植物部分用于制作汤或作为主餐的组成部分,它们是营养物质,维生素和矿物质的来源。干燥是一种廉价的保存蔬菜的方法,因为它们容易受到真菌的污染。对卡杜纳市选定市场的干蔬菜(猴面包树、红辣椒、秋葵和番茄)相关的黄曲霉毒素真菌进行了调查。对40份干蔬菜样品(各10份)进行了真菌和总黄曲霉毒素分析。采用常规技术和分子技术鉴定真菌,采用酶联免疫吸附试验(ELISA)鉴定总黄曲霉毒素。鉴定的真菌为黄曲霉和黑曲霉。黄曲霉毒素总含量测定结果显示,Sabo猴面包树(sb001)黄曲霉毒素含量最高,为31.6μg/kg,而Barnawa猴面包树(BRW 001)黄曲霉毒素含量最高,为18.80μg/kg。土顿和田猴面包树(TW 001)黄曲霉毒素含量为15.00μg/kg,马拉里猴面包树(MLL 001)黄曲霉毒素含量较高,为12.10μg/kg,中央市场猴面包树黄曲霉毒素含量为1.60μg/kg。黄曲霉毒素含量最高的蔬菜为萨波猴面包树(sb001),黄曲霉毒素含量为31.6μg/kg,卡马祖秋葵(kmz003)黄曲霉毒素含量为27.00μg/kg,马拉里红辣椒(MLL004)黄曲霉毒素含量为26.40μg/kg,马拉里番茄(mll002)黄曲霉毒素含量最低,为6.50μg /kg。这些结果可作为制定法律和观察关键控制点的基础,因为食用这些真菌毒素污染的蔬菜具有重大的健康意义。因为这些毒素能够引起人类和动物的疾病。
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引用次数: 2
Upgrading of Egyptian Oil Shale Using Enhanced Gravity Separation 埃及油页岩强化重力分离提质
Pub Date : 2017-05-24 DOI: 10.11648/J.IE.20170101.14
A. Yehia, F. El-hosiny, S. Ibrahim, M. A. Khalek, Rasha Amin, A. H. El-Menshawy
Egyptian oil shale from Wadii El-Nakhil, Red sea region was upgraded using enhanced gravity separation. The oil shale sample was characterized physically and chemically to determine its mineral content and characteristics. The sample includes quartz, siderite, apatite, anhydrite and calcite. The clay mineral is mainly represented by kaolinite while the organic matter is 30%. The ground sample (less than 50 microns) was classified into two fractions. The coarser was higher than 25 µm while the finer was less than 25 µm. The lower and upper levels of both the centrifugal force and water pressure have been suggested to construct the design for Falcon Concentrator type SB-40. The coarse concentrate of 42% kerogen with 94.35% recovery was achieved at 60 Hz (equivalent to G-force 176) and water pressure of 4 Psi from feed of 29% kerogen. The fine concentrate of 38.46% kerogen with 85.4% recovery was achieved at 70 Hz (equivalent to G-force 243) and water pressure of 2 Psi from feed of 33% kerogen.
采用强化重力分离技术对红海地区Wadii El-Nakhil的埃及油页岩进行了升级改造。对油页岩样品进行了物理和化学表征,确定了其矿物含量和特征。样品包括石英、菱铁矿、磷灰石、硬石膏和方解石。粘土矿物以高岭石为主,有机质占30%。地面样品(小于50微米)被分为两部分。粗的大于25µm,细的小于25µm。提出了SB-40型猎鹰选矿厂离心力和水压的上下两级设计方案。在60 Hz(相当于重力176)和4 Psi的水压下,从含29%干酪根的原料中获得了含42%干酪根的粗精矿,回收率为94.35%。以33%的干酪根为原料,在70 Hz(相当于重力243)和2 Psi的水压下,获得了干酪根含量为38.46%、回收率为85.4%的细精矿。
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引用次数: 4
The Role of Biotechnology in Food Production and Processing 生物技术在食品生产和加工中的作用
Pub Date : 2017-05-15 DOI: 10.11648/J.EAS.20170206.14
B. Maryam, Mohammed Sani Sambo Datsugwai, Idris Shehu
Biotechnology is the use of living systems and organisms to develop or make useful products, or any technological applications that uses biological systems, living organisms or derivatives thereof, to make or modify products or processes for specific use. Depending on the tools and applications, it often overlaps with the fields of bioengineering and biomedical engineering. Some of the applications were identified in this paper to include biotechnology in food fermentation to enhance properties such as the taste, aroma, shelf-life, texture and nutritional value of food. Biotechnology in the production of enzymes to bring about desirable changes in food, biotechnology in the production of food ingredients; flavours, fragrances, food additives and a range of other high valued-added products, genetically modified starter cultures, genetically modified foods, the use of all these modern technologies in diagnostics for food testing, the role of biotechnology in food production by increasing food production, improved harvesting, storage and nutritional value, better raw materials, better flavour and the production of food containing vaccines, the safety of food produced with biotechnology as well as the risks and benefits of biotechnology in food production.
生物技术是指利用生命系统和生物体开发或制造有用的产品,或利用生物系统、生物体或其衍生物制造或修改特定用途的产品或过程的任何技术应用。根据工具和应用的不同,它经常与生物工程和生物医学工程领域重叠。本文列举了生物技术在食品发酵中的一些应用,以提高食品的口感、香气、保质期、质地和营养价值。生物技术在生产酶方面给食品带来理想的变化,生物技术在生产食品配料方面;香精、香料、食品添加剂和一系列其他高附加值产品、转基因发酵剂、转基因食品、所有这些现代技术在食品检测诊断中的应用、生物技术在食品生产中的作用,包括增加粮食产量、改进收获、储存和营养价值、更好的原料、更好的风味和生产含有疫苗的食品;生物技术生产食品的安全性以及生物技术在食品生产中的风险和收益。
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引用次数: 6
G 2 EDPS's First Module & Its First Extension Modules g2edps的第一个模块及其第一个扩展模块
Pub Date : 2017-05-15 DOI: 10.11648/J.AJASR.20170304.13
Burak Omer Saracoglu
100% renewable worldwide power grid (Global Grid) system needs a Global Grid Electricity Demand Prediction System (G2EDPS) with very short, short, medium and long term forecasting consoles. This paper presents the 1st core module and its 10 extension modules in the long term prediction console. A type 1 Mamdani like Fuzzy Inference System (FIS) with 7 triangle membership functions and 49 rules is designed for 2 input and 1 output variables for a 100 year forecasting period. The maximum absolute percentage errors (MAP), the mean absolute percentage errors (MAPE), and the Symmetric MAPE (SMAPE) of the best core module and its extension modules are respectively 0, 24; 0, 08; 0, 05 and 0, 22; 0, 07; 0, 05.
100%可再生全球电网(Global grid)系统需要一个具有极短期、短期、中期和长期预测控制台的全球电网电力需求预测系统(G2EDPS)。本文介绍了长期预测控制台的第一个核心模块及其10个扩展模块。1类Mamdani模糊推理系统(FIS)具有7个三角隶属函数和49条规则,为100年预测周期的2个输入和1个输出变量设计。最佳核心模块及其扩展模块的最大绝对百分比误差(MAP)、平均绝对百分比误差(MAPE)和对称绝对百分比误差(SMAPE)分别为0、24;0, 08年;0,05和0,22;0, 07年;0 05。
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引用次数: 11
The Effect of Extraction Method, Bleaching and Clarification Processes on Quality Second Grade Siwi Date Dibs 提取方法、漂白和澄清工艺对二级四维枣渣品质的影响
Pub Date : 2017-05-15 DOI: 10.11648/J.AJASR.20170306.13
H. Hashem, Hasan H. Abd El-Daym, G. El-Sharnouby, S. A. Farghal, Hossameldin A. Badr
Second grade Siwi date palm fruits in Baharia Oasis were used forproduction of high quality date syrup (Dibs). Physical and chemical characteristics of Siwi date fruits (second grade) as well as quality parameters of Siwi date extract as affected by bleaching and clarification treatments were investigated. Also, quality parameters of the obtained dibs by different methods and treatments were examined. Physical and chemical characteristics of Siwi date illustrated that, fruit weight, flesh/pit ratio, fruit length, fruit diameter, T.S.S, total and reducing sugars, crude protein, ash, soluble pectin and tannins were 10.0g, 6.40, 3.46 cm, 2.22 cm, 81.40%, 91.41%, 86.78%, 2.76%, 0.83%, 1.55% and 0.27%, respectively. Granular activated charcoal (G.A.C) is more effective bleaching treatment than powder activated charcoal (P.A.C), Also, liming phosphatation is more effective clarification treatment than centrifugation with filtration. Quality dibs results indicated that, the highest values of T.S.S, total and reducing sugars and date syrup yield were recorded for the dibs samples extracted at 75°C and 96°C and concentrated under vacuum while the lowest values were recorded for commercial sample(except yield), also, clarification processed sample recorded the lowest browning index, ash and pectin contents, while the highest values of these parameter were recorded for commercial sample. Sensory quality parameters demonstrated that, the highest taste and flavor scores were recorded for the extracted sample at 96°C with bleaching by GAC then concentrated under vacuum while the extracted sample by blender at room temperature (with or without clarification treatment) had the highest color scores. In relation to microbial quality, results showed that, microwave extraction followed by concentration at 100% power level recorded the highest microbial quality (the lowest counts of bacteria, yeast and mould, and coliform group) followed by sample extracted at 96°C and then concentrated under vacuum.
巴哈利亚绿洲的二级Siwi枣椰树果实用于生产高品质的枣糖浆。研究了漂白和澄清处理对二级四维枣物理、化学特性及提取液质量参数的影响。并对不同处理方法所得到的质量参数进行了检验。结果表明,四维枣的果重、果核比、果长、果径、总糖和还原糖、粗蛋白质、灰分、可溶性果胶和单宁含量分别为10.0g、6.40、3.46 cm、2.22 cm,分别为81.40%、91.41%、86.78%、2.76%、0.83%、1.55%和0.27%。颗粒活性炭(G.A.C)是比粉状活性炭(P.A.C)更有效的漂白处理方法,石灰磷化是比过滤离心更有效的澄清处理方法。质量点的结果表明,75°C和96°C真空浓缩提取的样品的T.S.S、总糖、还原糖和枣糖浆得率最高,除得率外,商品样品的ts.s、总糖、还原糖和枣糖浆得率最低,澄清处理的样品褐变指数、灰分和果胶含量最低,商品样品的这些参数均最高。感官质量参数表明,96°C GAC漂白后真空浓缩提取的样品口感和风味得分最高,室温(有或没有澄清处理)混合提取的样品颜色得分最高。微生物品质方面,结果表明:微波提取后100%功率浓缩,96℃提取后真空浓缩,微生物品质最高(细菌、酵母菌、霉菌和大肠菌群数量最低);
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引用次数: 3
Unsteady MHD Free Convective Flow Past an Inclined Parabolic Accelerated Plate with Hall Current, Radiation Effects and Variable Temperature in a Porous Medium 多孔介质中具有霍尔电流、辐射效应和变温的斜抛物面加速板非定常MHD自由对流
Pub Date : 2017-04-25 DOI: 10.11648/J.IE.20170101.13
G. Nalisi, J. A. Okello, J. Sigey, M. Kimathi
We analyze the effects of hall current and radiation on unsteady hydro magnetic free convection flow of a viscous incompressible electrically conducting fluid past an inclined parabolic accelerated plate in a porous medium by applying a transverse magnetic field which makes an angle α to the inclined plate. The fluid is assumed to be viscous, incompressible and electrically conducting with a strong magnetic field. Using the modified Ohm’s law and the Bossinesq approximation the governing equations of the problem are reduced to local non-similarity boundary layer equations using suitable transformation. The dimensionless governing equations of flow field are solved numerically by Crank-Nicolson finite difference method for different values of governing flow parameters. The velocity and temperature profiles are shown through graphs.
本文通过对倾斜抛物面加速板施加角度为α的横向磁场,分析了霍尔电流和辐射对多孔介质中粘性不可压缩导电流体通过倾斜抛物面加速板的非定常水磁自由对流流动的影响。假定流体是粘性的、不可压缩的、具有强磁场的导电流体。利用修正的欧姆定律和Bossinesq近似,通过适当的变换将问题的控制方程化为局部非相似边界层方程。采用Crank-Nicolson有限差分法对不同控制参数值的流场无量纲控制方程进行数值求解。速度和温度曲线用图形表示。
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引用次数: 2
The budgeting process 预算编制过程
Pub Date : 2010-10-01 DOI: 10.1002/9781118268391.ch7
P. Engle
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引用次数: 6
期刊
Industrial Engineer
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