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On the use of LIBS data for mineralogical investigations – constraints and application of a clustering method 关于使用LIBS数据进行矿物学调查——聚类方法的限制和应用
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-03-01 DOI: 10.1144/geochem2023-003
F. Fontana, B. van der Hoek, Jessica Stromberg, C. Tiddy, N. Francis, S. Tassios, Y. Uvarova
This study examines how LIBS data collected using a downhole deployable LIBS prototype for geochemical analysis in a fashion that imitates downhole deployment may be used for mineralogical investigations. Two chemically and mineralogically practically identical felsic rocks, namely granite and microgranite are used to assess the effects of rock texture on mineral classification and high-resolution SEM-TIMA mineral maps are used to reveal mineralogical composition of each LIBS ablation crater. Additionally, in order to extend the LIBS application for fast mineralogical studies to a greenfield scenario (i.e., no previous knowledge) a clustering methodology is presented for mineralogical classification from LIBS data. Results indicate that most LIBS spot analyses sample mineral mixtures, 91.2% and 100% for granite and microgranite, respectively, which challenges mineralogical classification, particularly for fine-grained rocks. Positive identification and classification of minerals of slightly different compositions relative to the bulk rock (i.e., fluorite and biotite in granitic rocks) demonstrates how minerals or minerals groups of distinct and interesting chemical compositions (e.g., sulphides or oxides in silicate dominated rocks) can be rapidly recognised in a mineral exploration scenario. Strategies for overcoming mineral mixture issues are presented and recommendations are given for effective workflows for mineralogical analysis using LIBS data in different mineral exploration stages. Supplementary material: https://doi.org/10.6084/m9.figshare.c.6444482
本研究考察了使用井下可部署LIBS原型以模拟井下部署的方式进行地球化学分析所收集的LIBS数据如何用于矿物学调查。使用两种化学和矿物学上几乎相同的长英质岩石,即花岗岩和微重力岩石,来评估岩石结构对矿物分类的影响,并使用高分辨率SEM-IMA矿物图来揭示每个LIBS烧蚀坑的矿物学组成。此外,为了将LIBS在快速矿物学研究中的应用扩展到绿地场景(即,以前没有知识),提出了一种从LIBS数据中进行矿物学分类的聚类方法。结果表明,大多数LIBS点分析对矿物混合物进行了采样,花岗岩和微重力分别为91.2%和100%,这对矿物学分类提出了挑战,尤其是对细粒岩石。相对于大块岩石,成分略有不同的矿物(即花岗岩中的萤石和黑云母)的积极识别和分类表明,在矿物勘探场景中,如何快速识别具有不同和有趣化学成分的矿物或矿物组(如硅酸盐为主的岩石中的硫化物或氧化物)。提出了克服矿物混合物问题的策略,并提出了在不同矿产勘探阶段使用LIBS数据进行矿物学分析的有效工作流程建议。补充材料:https://doi.org/10.6084/m9.figshare.c.6444482
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引用次数: 0
Comparison of main and accompanying metals distribution patterns in newly documented deposits of the Northern Copper Belt in Poland 波兰北部铜带新记录矿床中主要金属和伴生金属分布模式的比较
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-02-17 DOI: 10.1144/geochem2022-046
A. Pietrzela, T. Bieńko
Three new world-class sediment-hosted stratiform copper deposits have recently been documented in SW Poland, in the deep parts of the Fore-Sudetic Monocline: Nowa Sól, Sulmierzyce North and Mozów. Along with the adjacent prognostic areas, these deposits form an extensive W-E trending belt, distant from the well-known deposits of the Sieroszowice-Lubin area and referred to as the Northern Copper Belt. This major discovery was a result of an exploration program performed by the Canadian Miedzi Copper Corporation, which involved studies of archival data and the company's own drilling program. Investigation of the core material included microscopic observations of thin sections and chemical analyzes using the ICP-MS and/or ICP-OES method. The aim of this study was to compare available geochemical data from the documented deposits and determine the distribution patterns of the main and accompanying metals. Particular attention was paid to Cu, Ag, Pb, Zn, Co, Ni, Mo, V and Au. Each of the studied deposits is characterized by a different position of the ore mineralization in the lithological profile. Average concentrations of analyzed elements and their distribution in the ore series, both vertically and laterally, indicate that distinct mineralizing systems were responsible for the formation of each orebody. Among the main factors influencing metal distribution in analyzed deposits are: the spatial range of the epigenetic, oxidized Rote Fäule facies; composition and thickness of the source rocks for the mineralizing brines; tectonics.
最近,在波兰西南部,在前-南部单斜构造的深处,发现了三个新的世界级沉积层状铜矿床:Nowa Sól、Sulmierzyce North和Mozów。与相邻的预测区一起,这些矿床形成了一个广泛的W-E走向带,远离Sieroszowice Lubin地区的著名矿床,被称为北部铜矿带。这一重大发现是加拿大Miedzi铜矿公司实施的勘探计划的结果,该计划涉及对档案数据的研究和该公司自己的钻探计划。核心材料的研究包括薄片的显微镜观察和使用ICP-MS和/或ICP-OES方法的化学分析。本研究的目的是比较记录矿床的可用地球化学数据,并确定主要金属和伴生金属的分布模式。特别关注Cu、Ag、Pb、Zn、Co、Ni、Mo、V和Au。所研究的矿床在岩性剖面中的矿化位置不同。所分析元素的平均浓度及其在矿系中的垂直和横向分布表明,不同的矿化系统是每个矿体形成的原因。影响所分析矿床中金属分布的主要因素有:表观遗传学、氧化Rote Fäule相的空间范围;矿化卤水的烃源岩成分和厚度;构造学
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引用次数: 0
Introduction to the thematic collection: a review of continental-scale geochemical mapping projects in Australia, Europe, and the conterminous United States 专题集简介:澳大利亚、欧洲和毗邻的美国大陆规模地球化学测绘项目综述
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-02-02 DOI: 10.1144/geochem2022-067
David B. Smith, P. de Caritat, C. Reimann
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引用次数: 0
Distribution and attribute analysis of soil selenium in Hebei Province, China 河北省土壤硒的分布及属性分析
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-02-01 DOI: 10.1144/geochem2022-055
Liting Zhang, Weiming Xie, Wenlong Yu, Li Zhang, Shicong Zhang, Xi Wang, Xiaoyang Xie, Hangxin Cheng
From 2004 to 2018, approximately 73% of the land area in Hebei province was surveyed by a 1:250,000 land quality geochemical survey of the National Geochemistry Survey of Land Quality project (NGSLQ). Based on the topsoil (0-20 cm) datasets (50724 analysis samples) and attribute analysis of the key area with a semivariance function model, geographic detector model and random forest model, the content and spatial distribution of soil selenium (Se) in Hebei province and the influencing factors of the distribution of Se in the Shijiazhuang-Xingtai-Handan area were obtained. The soil Se content in Hebei Province is low, ranging from 0.02 to 3.23 mg/kg, with an average of 0.20 mg/kg. The spatial distribution of soil Se was heterogeneous, and the marginal Se (0.125-0.175mg/kg) area and the sufficient Se (0.175-0.40 mg/kg) area were widely distributed, but the acreage of the Se-rich (0.40-3.0 mg/kg) area was very limited, accounting for only 2.43% of the total survey area. However, the Shijiazhuang-Xingtai-Handan area was a significant Se enrichment area. The spatial distribution of Se in the Shijiazhuang-Xingtai-Handan area was restricted by natural factors and socioeconomic factors. Soil organic matter (SOM) was the most influential factor and showed good coordination with Se. Coal burning superimposed on natural factors promotes the spatial differentiation of soil Se to a certain extent.
2004年至2018年,国家土地质量地球化学调查项目(NGSLQ)对河北省约73%的土地面积进行了1:250000的土地质量地球化调查。采用半方差函数模型、地理检测器模型和随机森林模型对河北省重点区域表层土(0-20cm)数据集(50724个分析样本)进行属性分析,得到了河北省石家庄-邢台-邯郸地区土壤硒含量和空间分布,以及硒分布的影响因素。河北省土壤硒含量较低,在0.02~3.23mg/kg之间,平均为0.20mg/kg。土壤硒的空间分布是不均匀的,边缘硒(0.125-0.175mg/kg)区和充足硒(0.175-0.40mg/kg)区分布广泛,但富硒(0.40-3.0mg/kg)区的面积非常有限,仅占总调查面积的2.43%。而石家庄-邢台-邯郸地区是一个硒富集程度较高的地区。石家庄-邢台-邯郸地区硒的空间分布受到自然因素和社会经济因素的制约。土壤有机质(SOM)是影响土壤Se的主要因子,与Se表现出良好的协同作用。燃煤与自然因子的叠加在一定程度上促进了土壤Se空间分化。
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引用次数: 0
Thallium isotopes as indicators of ore mineralization at the Zn-rich sediment-hosted massive sulfide TL Deposit, British Columbia, Canada 加拿大不列颠哥伦比亚省富含锌沉积物的块状硫化物TL矿床中铊同位素作为成矿指标
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-01-09 DOI: 10.1144/geochem2022-042
D. Knaack, K. Sullivan, M. Leybourne, C. Dunn, D. Layton-Matthews
Few studies have focused on the application of the Tl isotopic system for geochemical exploration. We report ε 205 Tl values of rock samples from the TL Deposit, British Columbia, Canada - a sediment-hosted massive sulfide (SHMS) deposit with characteristics of a Broken Hill-type deposit - and investigate relationships with major and trace element geochemistry. Maps generated using Tl isotope and trace element data indicate that ε 205 Tl values can potentially be used to fingerprint ore mineralization at the TL Deposit. The sources of Tl and other metals (Ag, Pb, Zn) are assessed using Tl isotope data. Measured ε 205 Tl values exhibit positive correlations with Pb, sedimentary exhalative (SEDEX) metal index (Zn+100*Pb+100*Tl), and the redox proxy, U/Th, and negative correlations with Be, Cd, Ce, La, Ni, and Th. Individual lithologies have distinct Tl isotopic compositions. Metal-rich heavily altered samples have relatively high ε 205 Tl values (-5.0 to -2.5 ε -units) reflecting the euxinic conditions of the global Paleoproterozoic ocean and hydrothermal influence. Samples with lower ε 205 Tl values (-15 to -7.6 ε -units) reflect a combination of their mineralogy (phyllosilicate minerals such as biotite and clinochlore), Tl from sediments reflecting the Tl isotopic composition of modern seawater, and possible low-temperature alteration processes. Samples with high Pb and Ag contents have high ε 205 Tl values, indicating a hydrothermal origin of these metals, whereas Zn is highest in samples with low ε 205 Tl values, indicating a low-temperature or sedimentary origin. Thallium isotopes, paired with conventional geochemical data, show promise as a useful tool for exploration of SHMS deposits with Broken Hill-type characteristics. Thematic collection: This article is part of the Geochemical processes related to mined, milled, or natural metal deposits collection available at: https://www.lyellcollection.org/topic/collections/geochemical-processes-related-to-mined-milled-or-natural-metal-deposits Supplementary material: https://doi.org/10.6084/m9.figshare.c.6370671
在地球化学勘探中应用Tl同位素系统的研究很少。本文报道了加拿大不列颠哥伦比亚省Tl矿床岩石样品的ε 205 Tl值,并研究了其与主微量元素地球化学的关系。Tl矿床是一个具有破碎山型矿床特征的沉积型块状硫化物矿床。利用Tl同位素和微量元素数据生成的图表明,ε 205 Tl值有可能用于Tl矿床的矿化指纹。利用Tl同位素资料评估了Tl和其他金属(Ag、Pb、Zn)的来源。实测ε 205 Tl值与Pb、沉积呼气(SEDEX)金属指数(Zn+100*Pb+100*Tl)和氧化还原代理U/Th呈正相关,与Be、Cd、Ce、La、Ni、Th呈负相关。个别岩性具有不同的Tl同位素组成。富金属重蚀变样品具有较高的ε 205 Tl值(-5.0 ~ -2.5 ε -单位),反映了全球古元古代海洋的缺氧条件和热液影响。ε 205 Tl值较低的样品(-15至-7.6 ε -单位)反映了它们的矿物学(黑云母和斜长石等层状硅酸盐矿物),沉积物中的Tl反映了现代海水的Tl同位素组成,以及可能的低温蚀变过程。Pb和Ag含量高的样品ε 205 Tl值高,表明这些金属的热液成因;而Zn含量低的样品ε 205 Tl值最高,表明这些金属的低温或沉积成因。铊同位素与常规地球化学数据相结合,有望成为寻找具有破碎山型特征的SHMS矿床的有效工具。专题收集:本文是与开采、研磨或天然金属矿床收集相关的地球化学过程的一部分,可在:https://www.lyellcollection.org/topic/collections/geochemical-processes-related-to-mined-milled-or-natural-metal-deposits补充材料:https://doi.org/10.6084/m9.figshare.c.6370671
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引用次数: 0
Introduction to the thematic collection: Applications of innovations in geochemical data analysis 专题汇编简介:创新在地球化学数据分析中的应用
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-12-09 DOI: 10.1144/geochem2022-058
Wenlei Wang, S. Xie, E. Carranza
Geochemistry: Exploration, Environment, Analysis (GEEA) as the scientific journal of the AAG focuses on the use of geochemistry in mineral exploration/resource development. Since the first issue of GEEA was published in 2001, there have been hundreds of papers regarding methodologies for geochemical data analysis. In 2017, a thematic issue: analysis of exploration geochemical data for mapping of anomalies (Carranza and Zuo, 2017) was published on the development of methods and techniques for exploration geochemical data analysis. As a successor, this current thematic set of papers introduces some new progress and advancements in geochemical data analysis, e.g., nonlinear, fractal/multifractal, multi-statistical, machine learning methods and their applications in mineral exploration. Twelve papers from Professor Qiuming Cheng's colleagues in China and Canada are organized in this thematic set in honor of his Gold Medal Award. Thematic collection: This article is part of the Applications of Innovations in Geochemical Data Analysis collection available at: https://www.lyellcollection.org/topic/collections/applications-of-innovations-in-geochemical-data-analysis
《地球化学:勘探、环境、分析》(GEEA)是澳大利亚地质学会的科学期刊,重点介绍地球化学在矿物勘探/资源开发中的应用。自2001年第一期GEEA出版以来,已经有数百篇关于地球化学数据分析方法的论文。2017年,在勘探地球化学数据分析方法与技术的发展方面发表专题论文《异常填图中的勘探地球化学数据分析》(Carranza and Zuo, 2017)。本文介绍了地球化学数据分析的一些新进展和新进展,如非线性、分形/多重分形、多重统计、机器学习等方法及其在矿产勘查中的应用。程秋明教授在中国和加拿大的同事们的12篇论文被整理成这个主题集,以纪念他获得金奖。专题合集:本文是地球化学数据分析创新应用合集的一部分,可在https://www.lyellcollection.org/topic/collections/applications-of-innovations-in-geochemical-data-analysis获得
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引用次数: 2
Lithogeochemistry in exploration for intrusion-hosted magmatic Ni-Cu-Co deposits 侵入型岩浆型镍铜钴矿床勘探中的岩石地球化学
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-30 DOI: 10.1144/geochem2022-025
S. Barnes
Magmatic Ni-Cu-Co-PGE deposits are notoriously difficult exploration targets owing to a lack of alteration haloes or other extended distal footprints. Success requires prediction of prospective terranes, followed by identification of suitable host intrusions and deposition sites within those intrusions. At the regional scale, potential ore-hosting magmas tend to have lithophile trace element trends falling on mixing lines between primitive or slightly depleted source mantle and typical upper continental crust, with several significant exceptions. Most known deposits have parent magmas that are in the upper range of FeO content for given MgO compared with baseline data sets for continental LIP magmas. At the scale of individual intrusions, the presence of cumulate rocks, both mafic and ultramafic, is key. These can be recognised in regional datasets using combinations of magnesium number (molar MgO/(MgO+FeO), Al 2 O 3 , TiO 2 and Zr contents. Combinations of alteration-resistant element ratios between Ni, Cr and Ti are also useful and can also be applied to moderately weathered samples. Concentrations and ratios of Cu and Zr are useful in discriminating chalcophile-enriched and depleted magmas suites. In combination, these approaches can be combined to discriminate highly prospective cumulate-dominated magmatic suites and individual intrusions from non-cumulate suites with limited potential. Supplementary material: https://doi.org/10.6084/m9.figshare.c.6267664
岩浆Ni-Cu-Co-PGE矿床由于缺乏蚀变晕或其他延伸的远端足迹,是出了名的难以勘探的目标。成功需要预测未来的地层,然后确定合适的宿主侵入体和这些侵入体中的沉积地点。在区域尺度上,潜在的含矿岩浆倾向于亲石微量元素倾向,落在原始或轻度衰竭源地幔与典型上大陆地壳的混合线上,但有几个明显的例外。与大陆LIP岩浆的基线数据集相比,大多数已知矿床的母岩浆的FeO含量在给定MgO的上限范围内。在单个侵入的尺度上,基性和超基性的堆积岩的存在是关键。这些可以在区域数据集中通过镁含量(摩尔MgO/(MgO+FeO))、al2o3、tio2和Zr含量的组合来识别。Ni, Cr和Ti之间抗蚀变元素比率的组合也很有用,也可以应用于中等风化的样品。Cu和Zr的浓度和比值对判别富铜矿和贫铜矿岩浆组有重要意义。将这些方法结合起来,可以将具有高度远景的以累积层为主的岩浆层和单个侵入层与潜力有限的非累积层区分开来。补充资料:https://doi.org/10.6084/m9.figshare.c.6267664
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引用次数: 1
The National Geochemical Survey of Australia: review and impact 澳大利亚国家地球化学调查:回顾和影响
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-22 DOI: 10.1144/geochem2022-032
P. de Caritat
The National Geochemical Survey of Australia (NGSA) is Australia's first national-scale geochemical survey. It was delivered to the public on 30 June 2011, after almost five years of stakeholder engagement, strategic planning, sample collection, preparation and analysis, quality assurance/quality control, and preliminary data analytics. The project was comprehensively documented in seven initial open-file reports and six data and map sets, followed over the next decade by more than 70 well-cited scientific publications. This review compiles the body of work and knowledge that emanated from the project to-date as an indication of the impact the NGSA had over the decade 2011-2021. The geochemical fabric of Australia as never seen before has been revealed by the NGSA. This has spurred further research and stimulated the mineral exploration industry. This paper also critically looks at operational decisions taken at project time (2007-2011) that were good and perhaps – with the benefit of hindsight – not so good, with the intention of providing experiential advice for any future large-scale geochemical survey of Australia or elsewhere. We conclude that the NGSA was a low-cost, high-benefit project that delivered scientific excellence, promoted stakeholder engagement, demonstrated national leadership, and contributed to enhanced national resource wealth. Thematic collection: This article is part of the Continental-scale geochemical mapping collection available at: https://www.lyellcollection.org/topic/collections/continental-scale-geochemical-mapping
澳大利亚国家地球化学调查(NGSA)是澳大利亚第一次全国范围的地球化学调查。经过近五年的利益相关者参与、战略规划、样本收集、准备和分析、质量保证/质量控制以及初步数据分析,该报告于2011年6月30日向公众发布。该项目在七份最初的公开文件报告和六套数据和地图中得到了全面的记录,随后在接下来的十年里,又有70多份被广泛引用的科学出版物。本次审查汇集了迄今为止该项目产生的大量工作和知识,以表明NGSA在2011-2021十年中产生的影响。澳大利亚地质调查局揭示了前所未有的澳大利亚地球化学结构。这刺激了进一步的研究,刺激了矿产勘探行业。本文还批判性地审视了项目时(2007-2011年)做出的良好且可能(事后来看)不太好的操作决策,旨在为澳大利亚或其他地方未来的任何大规模地球化学调查提供经验建议。我们得出的结论是,NGSA是一个低成本、高效益的项目,它提供了卓越的科学成果,促进了利益相关者的参与,展示了国家领导力,并为增加国家资源财富做出了贡献。专题集:本文是大陆尺度地球化学制图集的一部分,可在以下网站获取:https://www.lyellcollection.org/topic/collections/continental-scale-geochemical-mapping
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引用次数: 5
Study on the direction effect of terrane accretive orogeny and biological evolution during the Jinning-Chengjiang period in the northwestern margin of the Yangtze block 扬子地块西北缘晋宁—澄江期地体增生造山运动方向效应及生物演化研究
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-15 DOI: 10.1144/geochem2021-044
Rui Yan, Zuanyun Yang, Yuanjun Wang, Shaoping Yang
In the various stages from life chemistry to biological evolution, major geological events are usually accompanied by the extinction of species and the gestation of new life, which are important factors that determine the direction of ecological evolution. The study of the terrane accretive orogeny during the Jinning-Chengjiang period has had a great impact on the crustal rock composition, the atmospheric environment, and the water circulation system, etc. The living environment of the primitive biological community has undergone tremendous changes, the crust to produce superimposed contraction and extensional rift effect, resulting in collisional magmatic activity and strong earthquakes, and a large number of species have been extinct. In turn, biological activities and organic matter also contributed significantly to the migration. With the periodic cycle of geological processes and being fully utilized by nature, the origin and evolution of life grow in a spiral. Based on the analysis of the petrochemical composition characteristics of metamorphic volcanic-sedimentary rock series and intermediate-acid intrusive rocks in Pengguan terrane, this article believes that the subduction mechanism of oceanic crust in the study area is formed by the northwest subduction of the Longmenshan-Anning oceanic crust on the southeast side. The relationship among the average change of chemical composition of the diabase in Masongling and Xinkaidong area and around the world, ion radius and compressibility shows that when the element ion compressibility is less than 4.46, compared with the average chemical composition of the diabase in the world, the oxide content such as Si, Ti, Al and P is obviously lower, while when the ion compressibility is equal to or greater than 4.46, the content of oxide of Fe, Mn, Mg and K increases obviously except Ca and Na.
在从生命化学到生物进化的各个阶段,重大地质事件往往伴随着物种的灭绝和新生命的孕育,是决定生态进化方向的重要因素。晋宁—澄江时期地体增生造山作用的研究对地壳岩石组成、大气环境、水循环系统等方面产生了重大影响。原始生物群落的生存环境发生了巨大的变化,地壳产生叠加的收缩和伸展裂谷作用,导致岩浆碰撞活动和强烈地震,大量物种已经灭绝。反过来,生物活动和有机质也对迁移有重要贡献。在地质作用的周期性循环和大自然的充分利用下,生命的起源和演化呈螺旋式增长。通过对彭观地体变质火山岩-沉积岩系和中酸性侵入岩的石油化学成分特征的分析,认为研究区洋壳的俯冲机制是由龙门山-安宁洋壳在东南侧的西北俯冲形成的。之间的关系在Masongling辉绿岩的平均化学成分的变化和Xinkaidong区域和世界各地,离子半径和压缩系数表明,当元素离子压缩系数小于4.46,与辉绿岩的平均化学成分相比,氧化内容如硅、钛、铝和P明显降低,而当离子压缩系数等于或大于4.46,氧化物的含量的铁、锰、除Ca和Na外,Mg和K明显升高。
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引用次数: 0
Modeling spatial uncertainty of geochemical anomalies using fractal and sequential indicator simulation methods 利用分形和序贯指标模拟方法模拟地球化学异常空间不确定性
IF 2.4 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2022-11-15 DOI: 10.1144/geochem2022-029
Haicheng Wang, R. Zuo, E. Carranza, N. Madani
Mapping of geochemical anomalies is crucial to exploration and environmental geochemistry. The complex geochemical landscape, multiple geological sources and various secondary surficial processes impose a certain degree of spatial uncertainty in mapping of geochemical anomalies. Quantifying such uncertainty is significant for improving the efficiency of environmental monitoring or mineral prospecting. In this paper, sequential indicator simulation (SISIM) was used to assess local and spatial uncertainties of geochemical anomalies, and the concentration–area (C–A) fractal model was employed to determine geochemical threshold prior to SISIM analysis. To illustrate uncertainty of Ag geochemical anomalies, Ag concentration data of 1,880 soil samples collected from northeast of Dong Ujimqin Banner district of Inner Mongolia, North China, was used in this study. Based on a set of simulation realizations of Ag concentrations, it was concluded that areas with low local (i.e., single location) uncertainty of Ag concentrations have low risk for mineral exploration. However, the spatial uncertainty for multi-locations showed that the joint probability statistics were stricter than local uncertainty. Therefore, combining local probability and spatial joint probability for delineating geochemical anomalies of Ag is more acceptable and reliable. The hybrid approach using C–A fractal model and SISIM provides a new way to delineate anomalous areas considering uncertainty of spatial distributions of geochemical elements. Thematic collection: This article is part of the Applications of Innovations in Geochemical Data Analysis collection available at: https://www.lyellcollection.org/topic/collections/applications-of-innovations-in-geochemical-data-analysis
地球化学异常填图是勘探和环境地球化学的重要内容。复杂的地球化学景观、多样的地质源和多样的地表次生过程,给地球化学异常填图带来了一定的空间不确定性。量化这种不确定性对于提高环境监测或矿产勘查的效率具有重要意义。本文采用顺序指标模拟(SISIM)方法评估地球化学异常的局部和空间不确定性,并在SISIM分析前采用浓度-面积(C-A)分形模型确定地球化学阈值。为了说明银地球化学异常的不确定性,本文利用内蒙古东乌金沁旗东北部1880个土壤样品的银浓度数据进行了研究。基于一组银浓度模拟实现,得出银浓度局部(即单一地点)不确定性低的地区具有较低的找矿风险。然而,多地点的空间不确定性表明联合概率统计比局部不确定性更严格。因此,结合局部概率和空间联合概率对银地球化学异常的圈定更为可行和可靠。考虑到地球化学元素空间分布的不确定性,将C-A分形模型与siisim相结合的方法为异常区圈定提供了新的思路。专题合集:本文是地球化学数据分析创新应用合集的一部分,可在https://www.lyellcollection.org/topic/collections/applications-of-innovations-in-geochemical-data-analysis获得
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引用次数: 1
期刊
Geochemistry-Exploration Environment Analysis
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