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Introduction 介绍
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-07-01 DOI: 10.1017/S0080456800032439
Miguel Cisneros Perales
The increased prevalence of coronary artery disease (CAD) among migrant Asian Indians and individuals in the subcontinent of India is partly attributed to elevated plasma levels of homocysteine (Hcy). Hcy, a sulfur-containing amino acid, is derived from the metabolic demethylation of dietary methionine (1,2,3). Four different forms of Hcy exist: 1% is present as free thiol; 70-80% circulates as a disulphide-bound to albumin; and the remaining 20-30% forms a dimer with itself or other thiols (1). The grouping of these four forms is referred to as total plasma Hcy (tHcy) and it is the elevation of this serum component that has been noted as an independent risk factor for CAD. Total plasma Hcy within the normal range is 5 to 15 μmol/L and hyperhomocysteinemia (HHC) is categorized as moderate (16-30 μmol/L), intermediate (31100 μmol/L), and severe (>100 μmol/L) HHC (4). The concentration of tHcy is determined by genetic and nutritional factors, such as levels of dietary folate and cobalamin. Since these nutrients are essential co-factors in the metabolic pathway of Hcy, deficiencies of folate and cobalamin result in elevated Hcy levels in the Asian Indian population (2,4,5,6,7,8).
在亚洲移民印度人和印度次大陆的个人中,冠状动脉疾病(CAD)患病率的增加部分归因于血浆同型半胱氨酸(Hcy)水平的升高。Hcy是一种含硫氨基酸,来源于膳食甲硫氨酸(1,2,3)的代谢去甲基化。Hcy存在四种不同形式:1%以游离硫醇形式存在;70-80%作为与白蛋白结合的二硫化物循环;剩余的20-30%与自身或其它硫醇形成二聚体(1)。这四种形式的分组被称为总血浆Hcy(tHcy),正是这种血清成分的升高被认为是CAD的独立风险因素。正常范围内的总血浆Hcy为5至15μmol/L,高同型半胱氨酸血症(HHC)分为中度(16-30μmol/L)、中度(31100μmol/L)和重度(>100μmol/L)HHC(4)。tHcy的浓度由遗传和营养因素决定,如饮食中叶酸和钴胺素的水平。由于这些营养素是Hcy代谢途径中的重要辅助因素,叶酸和钴胺素的缺乏导致亚洲印第安人的Hcy水平升高(2,4,5,6,7,8)。
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引用次数: 0
Arsenate removal from aqueous solutions by Mg/Fe-LDH-modified biochar derived from apple tree residues 苹果树渣Mg/Fe-LDH改性生物炭去除水溶液中的砷酸盐
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-06-01 DOI: 10.1017/S1755691022000019
M. A. Shiriazar, E. Sepehr, Ramin Haji Maleki, H. Khodaverdiloo, F. Asadzadeh, B. Dovlati, Z. Rengel
ABSTRACT The development of non-toxic and inexpensive materials for arsenic removal is required due to water sources being polluted by arsenic in many countries around the world. The main aim of this study was to characterise the capacity and behaviour of Mg/Fe layered double hydroxides/biochar [Magnesium/Iron-Layered Double Hydroxide (Mg/Fe-LDH)] composite for arsenate adsorption from solution. Apple tree pruning residues were used to produce biochar at 500 °C under oxygen-limited atmosphere. Mg/Fe-LDH-biochar was synthesised using a spontaneous in situ co-precipitation method. Batch experiments were used for the assessment of the kinetics, isotherms, and the effects of initial solution pH (4, 6, 8, and 10), ionic strength (0.01, 0.1, and 0.2 mol L−1), and co-occurring anions (carbonate and phosphate) on the arsenate removal. Scanning electron microscope images showed Mg/Fe-LDH were loaded on the biochar porous structure, and X-ray diffraction analysis affirmed the presence of crystalline LDH minerals in Mg/Fe-LDH-biochar. Surface modification of biochar by Mg/Fe-LDH increased the maximum arsenate adsorption capacity (3.6 mg g−1) ten times compared to unmodified biochar (0.35 mg g−1). Arsenate removal capacity increased from 4.2 % to 54.2 % with modification of biochar by Mg/Fe-based LDH. Kinetic studies indicated that >90 % of Mg/Fe-LDH-biochar arsenate adsorption from a starting concentration of 10 mg L−1 occurred in the first 120 min. Pseudo-second order and Langmuir models described well the kinetics and isotherm of arsenate adsorption by biochar and Mg/Fe-LDH-biochar. Mg/Fe-LDH-biochar showed maximum arsenate removal capacity at pH 6. Increasing solution ionic strength and the presence of phosphate and carbonate anions suppressed arsenate removal by Mg/Fe-LDH-biochar. In summary, surface modification of biochar using Mg/Fe-LDH produced a potentially more cost-effective, locally available, reusable, and non-toxic arsenic adsorbent for decontamination of surface- and groundwater.
由于世界上许多国家的水源受到砷污染,需要开发无毒廉价的除砷材料。本研究的主要目的是表征Mg/Fe层状双氢氧化物/生物炭[镁/铁层状双氢氧化物(Mg/Fe- ldh)]复合材料对溶液中砷酸盐的吸附能力和行为。在限氧气氛下,500℃条件下,利用苹果剪枝残渣制备生物炭。采用原位共沉淀法合成了Mg/ fe - ldh生物炭。采用批量实验来评估动力学、等温线,以及初始溶液pH(4、6、8和10)、离子强度(0.01、0.1和0.2 mol L−1)和共生阴离子(碳酸盐和磷酸盐)对砷酸盐去除的影响。扫描电镜图像显示Mg/Fe-LDH被加载在生物炭的多孔结构上,x射线衍射分析证实Mg/Fe-LDH-生物炭中存在结晶LDH矿物。Mg/Fe-LDH改性生物炭的最大砷酸盐吸附量(3.6 Mg g−1)是未改性生物炭(0.35 Mg g−1)的10倍。Mg/ fe基LDH对生物炭的砷酸盐去除率由4.2%提高到54.2%。动力学研究表明,当初始浓度为10 Mg L−1时,Mg/ fe - ldh -生物炭对砷酸盐的吸附在前120 min内达到bbb90 %。拟二级模型和Langmuir模型很好地描述了生物炭和Mg/ fe - ldh -生物炭吸附砷酸盐的动力学和等温线。Mg/ fe - ldh生物炭在pH为6时脱除砷酸盐的能力最大。增加溶液离子强度和磷酸盐和碳酸盐阴离子的存在抑制了Mg/ fe - ldh生物炭对砷酸盐的去除。总之,使用Mg/Fe-LDH对生物炭进行表面改性,产生了一种可能更具成本效益、可在当地获得、可重复使用且无毒的砷吸附剂,用于地表水和地下水的净化。
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引用次数: 1
The ferns in a new Middle Jurassic locality from the Otlaltepec Formation, Puebla, Mexico 墨西哥普埃布拉Otlaltepec组中侏罗纪新地区的蕨类植物
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-06-01 DOI: 10.1017/S1755691022000093
J. MORALES-TOLEDO, Aniceto Mendoza-Ruiz, S. Cevallos-Ferriz
ABSTRACT Mesozoic ferns from Mexico have been the subject of serious academic endeavours since the beginning of the 20th Century, to understand these plants at the time of their peak diversity. Most findings have been made in a set of Middle Jurassic Basins of the Mixtec Terrain in the Oaxaca State. However, fossil ferns are scarce in other assemblages, so further identification of this group has been infrequent. Here we describe six new and recently collected fossil plants from the Middle Jurassic Otlaltepec Formation, Puebla. Based on their fertile and vegetative fronds, we propose the new genus Paralophosoria Morales-Toledo, Mendoza-Ruiz & Cevallos-Ferriz, gen. nov. in the Dicksoniaceae, represented by Paralophosoria jurassica, Morales-Toledo, Mendoza-Ruiz & Cevallos-Ferriz, sp. nov., and identify the following genera: cf. Aspidistes, Sphenopteris, Spiropteris. A fern with uncertain affinities was also described. This work contributes to the understanding of fern diversity in low latitudes during the Middle Jurassic in Mexico.
自20世纪初以来,学术界对墨西哥中生代蕨类植物进行了认真的研究,以了解这些植物多样性高峰时期的情况。大多数发现都是在瓦哈卡州米斯特克地形的一套中侏罗世盆地中发现的。然而,在其他组合中,蕨类植物的化石很少,因此对这一组的进一步鉴定很少。在这里,我们描述了六种新的和最近收集的来自普埃布拉中侏罗世Otlaltepec组的化石植物。根据其肥沃的营养叶片,我们提出了以jurassica, Morales-Toledo, Mendoza-Ruiz & Cevallos-Ferriz, sp. nov.为代表的diksoniaceae新属parophosoria Morales-Toledo, Mendoza-Ruiz & Cevallos-Ferriz, gen11 .,并确定了以下属:参考Aspidistes, Sphenopteris, Spiropteris。还描述了一种亲和性不确定的蕨类植物。这项工作有助于了解墨西哥中侏罗世低纬度地区蕨类植物的多样性。
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引用次数: 2
Response model of fluid–rock ratio to reservoir space in primary formation of shale oil during hydrous pyrolysis 页岩油初生层含水热解流岩比与储层空间响应模型
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-06-01 DOI: 10.1017/S175569102200007X
Lina Sun, Deliang Fu, Qi Zhang, Yuandong Wu
ABSTRACT Due to the presence of geological fluid under actual geological conditions, water–rock interaction will occur between the fluid and reservoir. Thus, to analyse the influence of the water–rock interaction on storage space during the organic matter evolution stages, this study conducted a series of simulation experiments on shales by using a closed autoclave: four temperatures, 250°C, 300°C, 350°C, 400°C, and five fluid–rock ratios (FRRs), 0:20, 4:20, 10:20, 15:20, and 20:20. Low pressure N2 adsorption measurement was conducted on the solid residues. The experimental results show that the effect of temperature on the yield and pore structure of oil shale was the same as the result when the FRR was = 0:20, 4:20 and = 10:20, 15:20, 20:20, respectively. This result showed that temperature remained the main factor that affected the thermal evolution of hydrocarbon generation. Additionally, temperature was beneficial to the generation and storage of shale oil within a certain range, but only occupied the storage space of shale oils or connected a certain storage space beyond a certain range. The variation trend of shale oil yield with increasing FRR under the same simulated temperatures, 250°C and 400°C, was most affected by the FRR, but little change occurred at 300°C and 350°C. This further proved that the ratio of fluid to rock was an indirect acting factor, which affected the evolution of organic matters and then the development of pore structures. Before the oil window (350°C), the lower evolution degree, the higher water content and the more significant effect. In the higher evolution stage, the higher the water content, and the more complete the kerogen reaction, which was also more conducive to the development of pore structures. Therefore, this study promotes the establishment of linear equations on FRR to the gas adsorption capacity, which further provides a theoretical basis and guidance for the exploration and development of shale oil.
摘要在实际地质条件下,由于地质流体的存在,流体与储层之间会发生水-岩相互作用。因此,为了分析有机质演化阶段水-岩石相互作用对储存空间的影响,本研究使用封闭高压釜对页岩进行了一系列模拟实验:四个温度,250°C、300°C、350°C、400°C和五个流体-岩石比(FRR),0:20、4:20、10:20、15:20和20:20。对固体残留物进行低压N2吸附测量。实验结果表明,温度对油页岩产量和孔隙结构的影响与FRR分别为0:20、4:20和=10:20、15:20、20:20时的结果相同。这一结果表明,温度仍然是影响生烃热演化的主要因素。此外,温度在一定范围内有利于页岩油的生成和储存,但只占用了页岩油的储存空间或在一定范围外连接了一定的储存空间。在相同的模拟温度(250°C和400°C)下,页岩油产量随FRR的增加而变化的趋势受FRR的影响最大,但在300°C和350°C时变化不大。这进一步证明了流体与岩石的比例是一个间接作用因素,它影响有机质的演化,进而影响孔隙结构的发展。在油窗(350°C)之前,演化程度越低,含水量越高,影响越显著。在较高的演化阶段,含水量越高,干酪根反应越完全,也更有利于孔隙结构的发育。因此,本研究促进了FRR对天然气吸附能力线性方程的建立,进一步为页岩油勘探开发提供了理论依据和指导。
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引用次数: 0
TRE volume 113 issue 2 Cover and Front matter TRE第113卷第2期封面和封面问题
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-06-01 DOI: 10.1017/S1755691022000147
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引用次数: 0
Silicification of feathers in a modern hot spring in New Zealand 新西兰现代温泉中的羽毛硅化
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-04-22 DOI: 10.1017/S1755691022000068
Tao Zhao, Liang Hu, Yan-Hong Pan
ABSTRACT Fossil feathers have greatly improved our understanding of the evolutionary transition from non-avian dinosaurs to birds and the evolution of feathers, and may be the only evidence for their source animals in the fossil record. Hot spring environments have been demonstrated to be conducive to the preservation of fossils, but internal silicification of feathers was not observed in the only avian carcass so far discovered in ancient hot spring deposits. To determine whether feathers can be internally silicified, here we analyse feathers sampled from a modern hot spring vent pool – Champagne Pool – in New Zealand. Our results of scanning electron microscopy (SEM)-energy dispersive X-ray spectrometry elemental mapping show that the sampled feathers are silicified to different degrees, and one of them is pervasively silicified. SEM observations show that feathers can be silicified at the cellular level. Degradation is involved in the silicification of feathers, as indicated by the reduction of the abundance of carbon and the loss of keratin fibrils. Our findings suggest that ancient deposits of hot spring vent pools are promising targets in search for fossil feathers.
羽毛化石极大地提高了我们对非鸟类恐龙向鸟类进化过渡以及羽毛进化的认识,可能是化石记录中唯一的羽毛来源动物的证据。研究表明,温泉环境有利于化石的保存,但迄今为止在古温泉沉积物中发现的唯一一具鸟类尸体中未观察到羽毛的内部硅化。为了确定羽毛是否可以内部硅化,我们分析了从新西兰一个现代温泉喷口池——香槟池——取样的羽毛。扫描电镜(SEM)-能量色散x射线能谱元素图分析结果表明,样品羽毛具有不同程度的硅化,其中一种为普遍硅化。扫描电镜观察表明,羽毛可以在细胞水平上硅化。降解与羽毛的硅化有关,如碳丰度的减少和角蛋白原纤维的损失所表明的那样。我们的发现表明,温泉喷口池的古代沉积物是寻找羽毛化石的有希望的目标。
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引用次数: 0
Volcanic landscape controls on pre-rift to syn-rift volcano sedimentary systems: the Prestfjall Formation eruptive hiatus, Faroe Islands Basalt Group, northeast Atlantic 火山景观对裂谷前至同裂谷火山沉积系统的控制:大西洋东北部法罗群岛玄武岩群Prestfjall组喷发间断
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-04-19 DOI: 10.1017/S1755691022000056
D. Jolley, S. Passey, H. Vosgerau, E. V. Sørensen
ABSTRACT The Paleogene lava flows of the Faroe Islands Basalt Group are divided into three relatively thick formations. The oldest, the Beinisvørð Formation is separated from the second lava flow succession, the Malinstindur Formation, by two formations composed primarily of volcaniclastic rocks. The oldest of these, the Prestfjall Formation has been interpreted as a period of eruptive quiescence and linked to changes in mantle melting. It is characterised in the south by the occurrence of coals, while the overlying Hvannhagi Formation is a sequence of primary and remobilised volcaniclastic strata. Field, laboratory, palynology, and photogrammetry studies have been used to investigate variations in facies and architecture within these volcaniclastic formations. The data reveal significantly different depositional systems in the Prestfjall and Hvannhagi formations over the ~40 km from the island of Vágar in the north to the island of Suðuroy in the south. Facies distribution in both the Prestfjall and Hvannhagi formations was found to have been controlled by a complex interaction of regional paleoslope, pre-existing topography, the eruption and local collapse of low-angle shield volcanoes, and minor brittle deformation. Lithological data and photogrammetry have enabled the identification of a > 180 m thick succession of volcaniclastic conglomerates deposited by lahars reworking a low-angle shield sector collapse. Co-occurrence of facies characteristic of the Prestfjall, Hvannhagi and Malinstindur formations indicate that volcanic eruption continued at a lower tempo throughout the Prestfjall Formation interval. Identification of a Beinisvørð Formation low-angle volcano shield northwest of the Faroe Islands alters the previous eruption model for this extensive lava field.
法罗群岛玄武岩群古近系熔岩流被划分为三个相对较厚的地层。最古老的Beinisvørð组由两个主要由火山碎屑岩组成的组与第二个熔岩流序列Malinstindur组分开。其中最古老的Prestfjall组被解释为一个火山喷发静止的时期,并与地幔融化的变化有关。它在南部以产煤为特征,而上覆的Hvannhagi组是一个原生和再活动的火山碎屑地层序列。野外、实验室、孢粉学和摄影测量学研究已被用于研究这些火山碎屑地层中相和结构的变化。数据显示,从北部Vágar岛到南部su - ðuroy岛约40 km范围内,Prestfjall组和Hvannhagi组的沉积体系存在显著差异。Prestfjall组和Hvannhagi组的相分布受区域古斜坡、先存地形、低角盾状火山喷发和局部崩塌以及少量脆性变形的复杂相互作用控制。岩石学数据和摄影测量已经确定了一个bbb - 180 m厚的火山碎屑砾岩序列,这些砾岩是由火山泥流改造低角度盾构扇区崩塌形成的。Prestfjall组、Hvannhagi组和Malinstindur组相特征的共现表明,在Prestfjall组段,火山以较低的速度持续喷发。法罗群岛西北部的Beinisvørð组低角度火山盾的发现改变了之前对这一广阔熔岩场的喷发模式。
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引用次数: 0
Geochemical characteristics of terrigenous saline lacustrine shale in the Qianjiang Depression, Jianghan Basin, China: implications for controls on the formation of the inter-salt organic-rich shale 江汉盆地潜江凹陷陆相盐湖页岩地球化学特征及其对盐间富有机质页岩形成的控制意义
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-04-18 DOI: 10.1017/S1755691022000020
Nan Jia, Zixiang Wang, Lina Sun
ABSTRACT The inter-salt shale of the Qianjiang Formation in Jianghan Basin is a typical and important continental saline lake shale oil system in China. To achieve a better understanding of the formation of the inter-salt organic-rich shale, the mineral, major and trace elements and organic geochemical characteristics (total organic carbon (TOC) and biomarkers) of the Eq34-10 shale (high TOC) and the Eq40-5 shale (low TOC) were studied. The results suggest that (a) the organic matter in the inter-salt shale was predominantly derived from endogenous lower aquatic organisms, algae and bacteria; (b) there was a hot arid palaeoclimate and a low degree of chemical weathering conditions during the deposition of the inter-salt shale; (c) the inter-salt shale deposited in an extreme restriction hyper-saline lacustrine and reducing environment, and the salinity of the palaeolake decreases with the increase of the input of terrigenous clastic materials; and (d) the inter-salt shale deposited under an arid and semi-arid climate condition with an intermittent warm and humid climate. In summary, lake palaeoproductivity under the control of palaeoclimate change is the key and direct factor controlling the development of inter-salt organic-rich shale of Qianjiang Formation in Jianghan Basin.
江汉盆地潜江组盐间页岩是我国典型而重要的陆相盐湖页岩油系统。为了更好地了解盐间富有机页岩的形成,研究了Eq34-10页岩(高TOC)和Eq40-5页岩(低TOC)的矿物、主微量元素和有机地球化学特征(总有机碳(TOC)和生物标志物)。结果表明:(a)盐间页岩中的有机质主要来源于内源性低等水生生物、藻类和细菌;(b) 盐间页岩沉积过程中,古气候炎热干旱,化学风化程度低;(c) 盐间页岩沉积在极端限制性的高盐湖和还原环境中,古湖的盐度随着陆源碎屑物质输入的增加而降低;和(d)在干旱和半干旱气候条件下沉积的盐间页岩,气候间歇性温暖潮湿。综上所述,古气候变化控制下的湖泊古生产力是控制江汉盆地潜江组盐间富有机质页岩发育的关键和直接因素。
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引用次数: 0
Case Report: Getting a Peek at the Angle of a Patient with Severe Keratoconus. 病例报告:窥视严重角膜炎患者的视角
4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-03-02 eCollection Date: 2022-01-01 DOI: 10.3389/fopht.2022.843224
Rumi Kawashima, Kenji Matsushita, Kazuhiko Ohnuma, Naoyuki Maeda, Shizuka Koh, Kohji Nishida

Visualization of the iridocorneal angle, which contains the aqueous humor circulatory system and controls intraocular pressure, is important for diagnosing and managing glaucoma; however, the presence of keratoconus, keratoglobus, or severe myopia may enable direct angle visualization without gonioscopy contact lenses or applying a coupling gel. We present the first report of a case in which the iridocorneal angle was viewed directly in an eye with keratoconus using the RetCam without applying gel to the cornea. This method overcame the inability to view the angle directly in a normal eye because of the total internal reflection.

虹膜角膜角包含房水循环系统并控制眼内压,对诊断和治疗青光眼非常重要;但是,如果存在角膜炎、角膜黄斑或严重近视,则无需佩戴角膜接触镜或涂抹耦合凝胶即可直接观察虹膜角膜角。我们首次报道了使用 RetCam 无需在角膜上涂抹凝胶就能直接观察角膜炎患者虹膜角膜角的病例。这种方法克服了由于全内反射而无法在正常眼睛中直接观察虹膜角膜的缺陷。
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引用次数: 0
Index 指数
IF 1.2 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2022-02-15 DOI: 10.1515/9781501761812-013
Barometer, Diurnal Range of, in Fine and Cloudy Weather, 448. in Clear and Foggy Weather at Ben Nevis, 471. Influence of High Winds on, 490. Mean Hourly Values, 436. —— Reduction to Sea-level of Ben Nevis, 496, 506, 546. Barometers, Difference at Sea-level of Ben Nevis and Fort-William, 513. Temperature Correction of, 541. Ben Xevis in Clear and Foggy Weather, Meteorology of, 465. Black Bulb Readings, 519. Bossekop, 462. Braemar, Low Temperature at, 532. BUCHAN (ALEXANDER), 448, 490, 496. BUCHANAN (J. Y.), 465.
气压计,晴天多云时的日较差,448。本尼维斯晴朗多雾的天气,471。大风对490年的影响。平均小时值,436。----本尼维斯海平面下降,496506546。气压计,本尼维斯和威廉堡的海平面差,513。541的温度修正。Ben Xevis在《晴朗多雾的天气》,465年气象。黑灯泡读数,519。Bossekop,462。Braemar,低温,532。布坎(亚历山大),448490496。布查南(J.Y.),465。
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引用次数: 0
期刊
Earth and Environmental Science Transactions of the Royal Society of Edinburgh
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