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Microstructure, properties, and strengthening mechanism of laser cladding CoCrNiW0.6 medium-entropy alloy reinforced with NbC particles 激光熔覆NbC颗粒增强CoCrNiW0.6中熵合金的组织、性能及强化机理
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-12-05 DOI: 10.1007/s43452-025-01376-3
Xuanze Yang, Meiyan Feng, Guofu Lian, Zhigang Zeng, Changrong Chen

To improve the service life of AISI 1045 steel under harsh conditions, CoCrNiW0.6-xNbC composite coatings with varying NbC mass fractions were fabricated on AISI 1045 steel substrates using laser cladding. The effect of NbC on the macroscopic morphology, microstructure, and overall coating properties was systematically investigated. Results indicate that the addition of NbC promotes metallurgical bonding between the coating and the substrate. Fine NbC particles dispersed along grain boundaries significantly improve both mechanical properties and corrosion resistance. The microhardness of the coatings increases with higher NbC content, reaching a maximum average value of 469.15 HV0.5, which is 29.08% higher than that of the NbC-free coating. As the NbC proportion rises, the average friction coefficient and wear depth of the coatings decrease by 13.58% and 20.56%, respectively. Corrosion resistance initially decreases and then improves with NbC addition. The coating with 12wt% NbC demonstrates the best corrosion performance, exhibiting the highest self-corrosion potential ( – 0.434 V), the lowest self-corrosion current density (7.168 × 10–8 A/cm2), and the most compact passivation film. This work offers a new strategy for improving the wear and corrosion resistance of component surfaces via laser cladding.

为了提高AISI 1045钢在恶劣条件下的使用寿命,采用激光熔覆技术在AISI 1045钢基体上制备了不同NbC质量分数的CoCrNiW0.6-xNbC复合涂层。系统研究了NbC对涂层宏观形貌、微观结构和整体性能的影响。结果表明,NbC的加入促进了涂层与基体之间的冶金结合。沿晶界分散的NbC细颗粒显著提高了材料的力学性能和耐蚀性。随着NbC含量的增加,涂层的显微硬度逐渐升高,达到469.15 HV0.5的最大值,比不含NbC的涂层提高了29.08%。随着NbC含量的增加,涂层的平均摩擦系数和磨损深度分别降低13.58%和20.56%。加入NbC后,耐蚀性先降低后提高。含12wt% NbC的涂层具有最高的自腐蚀电位(- 0.434 V)、最低的自腐蚀电流密度(7.168 × 10-8 A/cm2)和最致密的钝化膜。这项工作为通过激光熔覆提高部件表面的耐磨性和耐腐蚀性提供了一种新的策略。
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引用次数: 0
The impact of ceramic and eggshell waste on the physical, mechanical, and freeze-thaw durability of sustainable geopolymer mortars: experimental investigation and optimization 陶瓷和蛋壳废料对可持续地聚合物砂浆物理、机械和冻融耐久性的影响:实验研究与优化
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-12-05 DOI: 10.1007/s43452-025-01367-4
Amirouche Berkouche, Ahmed Abderraouf Belkadi, Lysa Benaddache, Salima Aggoun

To address the growing need for sustainable construction materials and effective waste management, this study investigates the feasibility of incorporating ceramic waste powder (CP) and powdered eggshell (PES) as partial replacements of ground blast furnace slag (0–50% by weight) in geopolymer mortars (GPs). The experimental program employed Central Composite Design to analyze binary and ternary GPs, examining fresh properties, mechanical performance, physical characteristics, and freeze-thaw resistance. Microstructural and phase evolution were assessed using XRD, FTIR, and SEM/EDX techniques. Findings revealed that CP improved workability due to its slower reaction kinetics and sub-angular morphology. Moderate PES additions (12.5%) enhanced early-age strength (47.94 MPa), while CP incorporation up to 25% improved long-term strength (> 80 MPa). Balanced CP-PES combinations enhanced matrix density, reducing water absorption and improving ultra pulse velocity. Microstructural analysis confirmed the synthesis of C-(N)-A-S-H gels, with balanced Ca/Si and Al/Si ratios. Ternary mix (12.5% CP, 12.5% PES) exhibited superior freeze-thaw resistance, with strength and weight losses recorded at 14.52% and 1.25%, respectively. The optimized mixture (20.4% CP, 14.12% PES) achieved a desirability value of 0.91, demonstrating excellent performance across all properties. This research demonstrates the feasibility of incorporating industrial and agricultural waste into high-performance, frost-resistant geopolymer mortars, offering a sustainable alternative for cold-climate construction.

为了满足对可持续建筑材料和有效废物管理日益增长的需求,本研究探讨了在地聚合物砂浆(GPs)中加入陶瓷废粉(CP)和蛋壳粉(PES)作为部分替代磨碎的高炉渣(重量0-50%)的可行性。实验程序采用中央复合设计对二元和三元GPs进行分析,考察其保鲜性能、机械性能、物理特性和抗冻融性。采用XRD、FTIR和SEM/EDX技术对样品进行了显微组织和相演化分析。结果表明,CP由于其较慢的反应动力学和亚角形态而改善了可加工性。适量添加PES(12.5%)可提高早期强度(47.94 MPa),而添加25%的CP可提高长期强度(80 MPa)。平衡的CP-PES组合增强了基质密度,降低了吸水率,提高了超脉冲速度。显微结构分析证实合成了C-(N) a - s - h凝胶,Ca/Si和Al/Si比例平衡。三元混合料(12.5% CP、12.5% PES)具有较好的抗冻融性能,强度和重量损失分别为14.52%和1.25%。优化后的混合物(CP为20.4%,PES为14.12%)的理想值为0.91,各项性能均表现优异。这项研究证明了将工业和农业废物纳入高性能、抗冻地聚合物砂浆的可行性,为寒冷气候的建筑提供了一种可持续的选择。
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引用次数: 0
Enhancing freeze-thaw and sulfate resistance of expanded perlite-based alkali-activated lightweight composites with waste tire aggregates and brick powder 废轮胎骨料和砖粉增强膨胀珍珠岩基碱活化轻质复合材料的抗冻融性和抗硫酸盐性
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-12-05 DOI: 10.1007/s43452-025-01385-2
Ali Öz, Edanur Kızıloğlu, Ahmet Benli, Gökhan Kaplan

The utilization of industrial and construction wastes in binder and aggregate systems offers an effective pathway toward sustainable and eco-efficient construction materials. This study examines the mechanical and durability performance of expanded perlite-based alkali-activated lightweight composites (AALCs) incorporating waste tire aggregate (WTA) as a partial or full replacement for expanded perlite (EP) and brick powder (BP) as a supplementary binder with ground granulated blast furnace slag (GBFS). Eight mixtures were prepared with WTA at 0–100% (by volume) and BP at 0–10% (by mass), activated with 12 M NaOH and sodium silicate (SiO₂/Na₂O = 2.0). Specimens were thermally cured at 40 °C and 80 °C for 8 h, then tested for compressive and flexural strength, oven-dry density, thermal conductivity, sorptivity, freeze–thaw resistance, high-temperature stability (up to 350 °C), and 90-day sulfate resistance in 5% MgSO₄. The highest compressive strength (28.82 MPa) was obtained in the GBFS-only mix cured at 80 °C. Increasing WTA reduced strength but improved freeze–thaw and thermal performance; full EP replacement (100RB0) yielded the lowest strength (10.15 MPa at 40 °C) yet showed excellent freeze–thaw durability with only 3.84% loss. Incorporation of 10% BP enhanced sulfate resistance, with 25RB10 showing 13.63% strength loss versus 29.02% in the unmodified mix. Under thermal exposure, BP mixes retained up to 68% of strength at 250 °C, while all suffered ≥ 90% loss at 350 °C. Strong inverse correlations were observed between weight loss and compressive strength across durability tests (R² ≥ 0.90). Thermal conductivity ranged from 0.432 to 0.527 W/m·K, decreasing with WTA content. These findings confirm that optimized use of WTA and BP produces lightweight, durable, and eco-efficient AALCs, supporting circular economy goals through waste valorization.

在粘合剂和骨料系统中利用工业和建筑废物为实现可持续和生态高效的建筑材料提供了有效途径。本研究考察了膨胀珍珠岩基碱活化轻质复合材料(AALCs)的机械性能和耐久性,该复合材料采用废轮胎骨料(WTA)作为部分或全部替代膨胀珍珠岩(EP)和砖粉(BP)作为补充粘结剂,与磨碎的粒状高炉渣(GBFS)结合。以12 M NaOH和硅酸钠(SiO₂/Na₂O = 2.0)为活化剂,制备了WTA为0-100%(体积),BP为0-10%(质量)的8种混合物。在40°C和80°C下进行8 h的热固化,然后测试试样的抗压和抗弯强度、烘箱干密度、导热系数、吸附性、冻融性、高温稳定性(高达350°C)以及在5%硫酸镁中90天的抗硫酸盐性。在80℃固化条件下,纯gbfs混合料的抗压强度最高,达到28.82 MPa。增加WTA降低了强度,但改善了冻融和热性能;全EP替代材料(100RB0)的强度最低(在40°C时为10.15 MPa),但冻融耐久性优异,仅损失3.84%。10% BP的掺入增强了抗硫酸盐性,其中25RB10的强度损失为13.63%,而未经改性的混合物的强度损失为29.02%。在热暴露下,BP混合物在250°C下仍能保持68%的强度,而在350°C下则损失了90%以上。在耐久性试验中,失重和抗压强度之间存在很强的负相关(R²≥0.90)。导热系数为0.432 ~ 0.527 W/m·K,随WTA含量的增加而减小。这些发现证实,优化使用WTA和BP可以生产轻质、耐用和生态高效的AALCs,通过废物增值支持循环经济目标。
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引用次数: 0
Monitoring of Ti-25Nb and Ti-25Nb-1O shape memory alloys in the initial stage of tensile deformation by combined techniques of acoustic emission and digital image correlation 用声发射和数字图像相关相结合的方法监测Ti-25Nb和Ti-25Nb- 10o形状记忆合金的拉伸变形初期
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-12-04 DOI: 10.1007/s43452-025-01387-0
Karol Marek Golasiński, Adam Brodecki, Zbigniew Ranachowski, Wataru Tasaki, Elżbieta Alicja Pieczyska, Hee Young Kim

This work concerns an experimental investigation of the Ti–25Nb and Ti–25Nb–1O (at%) SMAs in the initial stage of tensile deformation using acoustic emission (AE) and digital image correlation (DIC). The stress-strain responses of the considered SMAs are different. The Ti–25Nb SMA exhibits shape memory effect due to the stress–induced martensitic transformation from the cubic β phase to the orthorombic α″ phase. In the case of the Ti–25Nb–1O SMA, the addition of 1 at% of oxygen results in a nonlinear superelastic behavior with small hysteresis and an increased yield stress. The stress-induced phase transformation in the Ti–25Nb–1O SMA is hindered due to the addition of oxygen interstitials. The difference between the deformation mechanisms and the resulting mechanical behaviors of the SMAs was clearly reflected by the recorded AE signals and deformation fields. It was shown that the AE can serve to track the development of the stress–induced phase transformations in the Ti–25Nb and Ti–25Nb–1O SMAs during tension. The AE signals were correlated to the strain fields of the SMAs, which showed a Lüders–type deformation of the Ti–25Nb SMA and a distinct but still inhomogenous deformation of the Ti–25Nb–1O SMA. The results of this study show that DIC and AE techniques are effective tools for monitoring phase transformations of the Ti–25Nb and Ti–25Nb–1O SMAs during tensile loading.

这项工作涉及使用声发射(AE)和数字图像相关(DIC)对Ti-25Nb和Ti-25Nb - 10 (at%) sma在拉伸变形初始阶段的实验研究。所考虑的sma的应力应变响应是不同的。应力诱导下,Ti-25Nb SMA从立方β相转变为正交α″相,表现出形状记忆效应。在ti - 25nb - 10o SMA的情况下,添加1 at%的氧会导致非线性超弹性行为,具有小的迟滞和增加的屈服应力。氧隙的加入阻碍了ti - 25nb - 10o SMA的应力诱导相变。记录的声发射信号和变形场清楚地反映了sma的变形机制和力学行为之间的差异。结果表明,声发射可以用于跟踪Ti-25Nb和Ti-25Nb - 10o sma在拉伸过程中应力诱导相变的发展。声发射信号与SMA的应变场相关,表明Ti-25Nb SMA的变形为l型变形,Ti-25Nb - 10sma的变形明显但仍不均匀。研究结果表明,DIC和AE技术是监测Ti-25Nb和Ti-25Nb - 10o sma在拉伸加载过程中相变的有效工具。
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引用次数: 0
Nonlinear damped vibrations of functionally graded graphene origami-enabled metamaterial beams with Kelvin-Voigt damping 具有开尔文-沃伊特阻尼的功能梯度石墨烯折纸超材料梁的非线性阻尼振动
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-12-03 DOI: 10.1007/s43452-025-01364-7
Jinlong Yang, Liangteng Guo, Shaoyu Zhao, Jie Yang

Functionally graded (FG) graphene origami-enabled auxetic metamaterial (GOEAM) structures have gained significant attention in recent years owing to their exceptional mechanical properties. This paper presents an analysis of nonlinear vibration characteristics of FG-GOEAM beams, focusing on the influence of the coupling between damping and graphene origami (GOri) parameters. The effective material properties of the FG-GOEAM beams are determined using the genetic programming (GP)-assisted micromechanical model. The Kelvin-Voigt damping model is introduced, and the governing equations of the damped beam are derived using Timoshenko beam theory and von Kármán nonlinearity. Differential quadrature (DQ) method is employed to solve the nonlinear kinematic equations. A comprehensive parametric study is conducted to analyze the effects of GOri content, folding degree, temperature, and damping on the nonlinear vibration behavior of the FG-GOEAM beams. Numerical results demonstrate that damping alters the nonlinear vibration behavior of the FG-GOEAM beam by weakening the effects of GOri parameters. The dominant factor differs by FG distribution, with GOri content dominating in X-WGr distribution, whereas GOri folding degree dominates in U-WGr distribution. In X-WGr beams, increasing the damping coefficient reduces the enhancement of the nonlinear frequency caused by GOri content, with a maximum reduction of 7.81%. For U-WGr beams, damping weakens the frequency suppression associated with GOri folding degree, with the reduction declining to 4.57% at 100% folding degree. Additionally, when the bending and shear proportional constants are less than 2.5 × 10–5 s, the maximum reduction in linear and nonlinear frequencies is approximately 2%, indicating that damping can be neglected under this condition.

近年来,功能梯度(FG)石墨烯折纸辅助超材料(GOEAM)结构因其优异的力学性能而受到广泛关注。本文分析了FG-GOEAM梁的非线性振动特性,重点研究了阻尼和石墨烯折纸(GOri)参数之间耦合的影响。利用遗传规划(GP)辅助微力学模型确定了FG-GOEAM梁的有效材料特性。引入了Kelvin-Voigt阻尼模型,利用Timoshenko梁理论和von Kármán非线性推导了阻尼梁的控制方程。采用微分正交(DQ)法求解非线性运动方程。通过综合参数研究,分析了GOri含量、折叠度、温度和阻尼对FG-GOEAM梁非线性振动性能的影响。数值结果表明,阻尼通过减弱GOri参数的影响来改变FG-GOEAM梁的非线性振动特性。不同FG分布的主导因素不同,X-WGr分布以GOri含量为主,U-WGr分布以GOri折叠度为主。在X-WGr梁中,增大阻尼系数可降低由GOri含量引起的非线性频率增强,最大降低幅度为7.81%。对于U-WGr梁,阻尼削弱了与GOri折叠度相关的频率抑制,在100%折叠度时,衰减率降至4.57%。此外,当弯曲和剪切比例常数小于2.5 × 10-5 s时,线性和非线性频率的最大降幅约为2%,表明在此条件下阻尼可以忽略。
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引用次数: 0
Effect of different butt gaps on laser-CMT hybrid welding of aluminum alloy 6082-T6: forming quality, microstructure and mechanical properties 不同对接间隙对6082-T6铝合金激光- cmt复合焊接的影响:成形质量、显微组织和力学性能
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-12-03 DOI: 10.1007/s43452-025-01391-4
Haoquan Zhang, Qingmian Ni, Xiaoquan Yu, Siwei Du, Yulei Feng, Shuquan Zhang

This study employs laser-cold metal transfer (CMT) hybrid welding technology (with laser power accounting for 89.94%) to weld aluminum alloy 6082-T6 (AA6082-T6), and systematically investigates the effect of different butt gaps (0–0.15 mm) on weld forming quality, microstructure, and mechanical properties. Results show that 0.15 mm gap achieves optimal forming quality, with a porosity of only 1.64% (satisfying ISO 13919–2 Grade B). This is because although the melt pool mode at this gap is a keyhole mode, its Rayleigh jet instability is the weakest. Microstructure that as the butt gap increases to 0.15 mm, the partially melted zone (PMZ) decreases to 39.84 μm, the secondary dendrite arm spacing (SDAS) decreases to 5.01 μm, and partially equiaxed crystals form. These results are related to the increase in the cooling rate (CR). Additionally, scanning electron microscope (SEM) analysis shows that the Si element segregation and oxide inclusion phenomena are weakest under the 0.15 mm gap, which is consistent with the decreasing trend of SDAS. Mechanical properties show that the weld with a 0.15 mm butt gap has the best performance. Its average microhardness is 78.72 HV, ultimate tensile strength (UTS) is 213.83 MPa, elongation (EL) is 6.32%. Compared with the 0 mm gap weld, its UTS and EL increase by about 8% and 85%, respectively. And only the 0.15 mm gap weld achieves a UTS approaching 70% of the base material’s UTS. Fractographic analysis shows brittle-ductile fracture in the 0.15 mm gap weld, while other gap sizes show brittle fracture.

本研究采用激光-冷金属转移(CMT)复合焊接技术(激光功率占89.94%)焊接6082-T6铝合金(AA6082-T6),系统研究了不同对接间隙(0-0.15 mm)对焊缝成形质量、显微组织和力学性能的影响。结果表明:0.15 mm间隙达到最佳成形质量,孔隙率仅为1.64%(满足ISO 13919-2 B级)。这是因为虽然该间隙处的熔池模式为锁孔模式,但其瑞利射流不稳定性是最弱的。当对接间隙增大到0.15 mm时,部分熔化区(PMZ)减小到39.84 μm,二次枝晶臂间距(SDAS)减小到5.01 μm,形成部分等轴晶。这些结果与冷却速率(CR)的增加有关。扫描电镜(SEM)分析表明,在0.15 mm间隙下,Si元素偏析和氧化物夹杂现象最弱,这与SDAS减小的趋势一致。力学性能表明,对接间隙为0.15 mm时焊缝性能最佳。平均显微硬度为78.72 HV,极限抗拉强度(UTS)为213.83 MPa,延伸率(EL)为6.32%。与0 mm间隙焊缝相比,其UTS和EL分别提高了约8%和85%。仅0.15 mm间隙焊缝的UTS就接近母材的70%。断口分析表明,0.15 mm间隙焊缝为脆性-韧性断裂,其他间隙尺寸焊缝为脆性断裂。
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引用次数: 0
Thickness-dependent spalling characteristics of sandstone with thin spray-on liners under dynamic loading 动载下薄喷淋衬层砂岩剥落特性随厚度变化
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-12-01 DOI: 10.1007/s43452-025-01373-6
Wentao Long, Shiming Wang, Yunfan Bai, Yang Zou, Qiuhong Wu

Spalling is a common dynamic damage phenomenon during blasting and excavation of underground projects, and the use of supporting structures is still the most effective engineering measure to control this type of disaster. This study investigates the spalling characteristics of Thin Spray-on Liner (TSL)-supported sandstone under dynamic loading using a Hopkinson pressure bar. Results demonstrate that increasing TSL thickness enhances impact resistance, necessitating higher impact pressures (0.30 MPa to 0.40 MPa) to induce spalling. TSL effectively attenuates reflected wave amplitudes, reducing spalling strength from 8.81 MPa to 7.20 MPa with increasing thickness. Furthermore, TSL reduces spalling events from two in unsupported specimens to one at 5 mm and 10 mm thicknesses, despite elevated impact pressures, and shifts spalling locations away from the free end, with distances increasing by 0%, 12%, and 65% for 5 mm, 10 mm, and 20 mm TSL, respectively. Both experimental and numerical simulation results reveal that the TSL has energy absorption properties under dynamic loading conditions, and the effect is most significant when the thickness reaches 10 mm; the enhancement of the energy absorption effect is gradually weakened with the further increase of the thickness. Compared to mortar support, TSL, at one-tenth the thickness, maintains structural integrity and superior adhesion, preventing interface failure and yielding greater spalling distances. These findings underscore TSL’s efficacy as a dynamic support material, offering significant potential for engineering applications.

剥落是地下工程爆破开挖中常见的动力损伤现象,支护结构的使用仍然是控制这类灾害最有效的工程措施。采用霍普金森压杆研究了动载荷作用下薄喷衬板(TSL)支撑砂岩的剥落特性。结果表明,随着TSL厚度的增加,其抗冲击能力增强,需要更高的冲击压力(0.30 ~ 0.40 MPa)才能诱发剥落。TSL有效地衰减反射波振幅,随着厚度的增加,剥落强度从8.81 MPa降低到7.20 MPa。此外,尽管冲击压力升高,但TSL可以将无支撑试样中的两个剥落事件减少到5mm和10mm厚度下的一个剥落事件,并使剥落位置远离自由端,5mm, 10mm和20mm TSL的距离分别增加0%,12%和65%。实验和数值模拟结果均表明,在动载荷条件下,TSL具有吸能特性,且当厚度达到10 mm时效果最为显著;随着厚度的进一步增加,能量吸收效果的增强逐渐减弱。与砂浆支架相比,TSL的厚度只有砂浆的十分之一,可以保持结构的完整性和优异的附着力,防止界面破坏,并产生更大的剥落距离。这些发现强调了TSL作为动态支撑材料的功效,为工程应用提供了巨大的潜力。
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引用次数: 0
Specimen size effect on fracture toughness of Pyrowear 53 steel for planetary gears 试样尺寸对行星齿轮用Pyrowear 53钢断裂韧性的影响
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-11-26 DOI: 10.1007/s43452-025-01375-4
Kamil Majchrowicz, Barbara Romelczyk-Baishya, Monika Wieczorek-Czarnocka, Krzysztof Raga, Ryszard Filip, Zbigniew Pakieła

A fracture toughness is one of the critical parameters for Pyrowear 53 steel which is widely used in planetary gears of aircraft vehicles. Due to a limited volume of planetary gears, it is impossible to directly assess their plain strain fracture toughness KIc. Therefore, the main aim of this study was to determine a formula correlating the plain strain fracture toughness KIc obtained for laboratory compact tension (CT) specimens having a thickness of B = 50 mm with smaller specimens (B = 10 mm) which can be prepared directly from planetary gears. For this reason, different force-based approaches were utilized considering conditional fracture toughness (KQ), size-insensitive conditional fracture toughness (KQsi) and specimen strength ratio (Rsc) values calculated according to ASTM E399 standard. Four different sizes of CT specimens were analyzed, i.e. B = 50, 25, 16 and 10 mm. The KIC value obtained for the B = 50 mm specimen was 101.7 ± 4.5 MPa m1/2, while for the smaller specimen sizes, the KQ value gradually decreased from 125.4 ± 10.0 MPa m1/2 for B = 25 mm to 101.1 ± 3.0 and 86.6 ± 1.3 MPa m1/2 for B = 16 and 10 mm, respectively. This trend was opposite to the commonly observed relation that the fracture toughness value increases for smaller specimen size with a higher plain stress region. The specimen size effect observed in the current work resulted from the methodology of determining the KQ value based on a force PQ defined at a point of 5% deviation from linearity of load-displacement curve. It has been shown that the fracture toughness of the Pyrowear 53 steel specimens exhibiting a rising R curve was more dependent on a ligament size.

断裂韧性是热磨损53钢的关键参数之一,热磨损53钢广泛用于飞行器行星齿轮。由于行星齿轮的体积有限,不可能直接评估其平应变断裂韧性KIc。因此,本研究的主要目的是确定一个公式,将厚度为B = 50 mm的实验室致密拉伸(CT)试样与可直接由行星齿轮制备的较小的试样(B = 10 mm)的平面应变断裂韧性KIc相关联。因此,考虑到根据ASTM E399标准计算的条件断裂韧性(KQ)、尺寸不敏感条件断裂韧性(KQsi)和试样强度比(Rsc)值,采用了不同的基于力的方法。分析了4种不同尺寸的CT标本,即B = 50、25、16和10 mm。B = 50 mm试样的KIC值为101.7±4.5 MPa m1/2,而较小尺寸试样的KQ值从B = 25 mm时的125.4±10.0 MPa m1/2逐渐降低到B = 16和10 mm时的101.1±3.0和86.6±1.3 MPa m1/2。这一趋势与通常观察到的试样尺寸越小、平面应力区域越大的断裂韧性值越高的关系相反。在当前工作中观察到的试样尺寸效应源于确定KQ值的方法,该方法基于在偏离载荷-位移曲线线性度5%的点上定义的力PQ。结果表明,热磨损53钢试样的断裂韧性随韧带尺寸的增大而呈上升的R曲线。
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引用次数: 0
Experimental characterization and numerical simulation of the thermoforming behavior of AA6061-T6 round bars at high temperatures AA6061-T6圆棒高温热成形行为的实验表征与数值模拟
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-11-20 DOI: 10.1007/s43452-025-01365-6
Thamer Sami Alhalaybeh, Yanshan Lou

Plasticity modeling at elevated temperatures is highly nonlinear and multivariate in nature; the accurate prediction of the strain hardening behavior is challenging. To address this issue, this study investigates the mechanical properties of AA6061-T6 round bars when exposed to high temperatures to assess their plastic behavior and thermal stability. Tensile tests over 25–250 °C were performed at a fixed strain rate of 0.001/s to avoid confounding between temperature and strain rate; constitutive parameters were calibrated at this reference rate. The Johnson–Cook (JC), Zerilli-Armstrong (ZA), Khan-Huang-Liang (KHL), Lim-Huh (LH), and artificial neural network (ANN) models were utilized to model the true stress-plastic strain behavior at different temperatures. Finite element analyses were conducted to compute the reaction force using ABAQUS/Explicit VUMAT subroutines with all the analytical and ANN models. These models were evaluated for their accuracy in replicating experimental tensile behavior under high temperature. The analytical results showed that the ANN model has higher prediction accuracy, achieving a determination coefficient of 0.99998, whereas those of the JC, ZA, KHL, and LH models were found to be 0.9608, 0.7351, 0.9129, and 0.9614, respectively. The FEA results showed that the ANN model accurately illustrates the load capability, with the best agreement among the analytical models. The results highlight the robustness and predictive capability of the ANN model, making it a reliable tool for modeling intricate stress–strain relationships under high temperature.

高温下的塑性建模是高度非线性和多元的;应变硬化行为的准确预测具有一定的挑战性。为了解决这一问题,本研究研究了AA6061-T6圆棒在高温下的力学性能,以评估其塑性行为和热稳定性。25-250°C的拉伸试验以0.001/s的固定应变速率进行,以避免温度和应变速率之间的混淆;本构参数在此参考速率下校准。采用Johnson-Cook (JC)、zerili - armstrong (ZA)、Khan-Huang-Liang (KHL)、Lim-Huh (LH)和人工神经网络(ANN)模型模拟了不同温度下的真应力-塑性应变行为。利用ABAQUS/Explicit VUMAT子程序对所有解析模型和人工神经网络模型进行有限元分析,计算反作用力。对这些模型在高温下模拟实验拉伸行为的准确性进行了评价。分析结果表明,ANN模型具有较高的预测精度,其决定系数为0.99998,而JC、ZA、KHL和LH模型的决定系数分别为0.9608、0.7351、0.9129和0.9614。有限元分析结果表明,人工神经网络模型能较好地反映结构的承载能力,且各分析模型的一致性最好。结果表明,人工神经网络模型具有较强的鲁棒性和预测能力,是模拟高温条件下复杂应力-应变关系的可靠工具。
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引用次数: 0
Microstructure and corrosion resistance of hafnium-doped aluminide layers deposited on IN 713C nickel alloy using CVD method: experimental and ab initio studies CVD法沉积IN 713C镍合金上掺铪铝化物层的显微组织和耐蚀性:实验和从头算研究
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-11-20 DOI: 10.1007/s43452-025-01350-z
R. Sitek, J. Kamiński, A. Wadowski, M. Kopec, B. Adamczyk-Cieślak, P. Bazarnik, M. Drajewicz, W. J. Nowak, J. S. Wróbel

In this paper, the effect of hafnium, titanium, and molybdenum addition on the microstructure and properties of the aluminide layers deposited by using a chemical vapor deposition process on IN 713C nickel superalloy substrate was discussed. A multi-component aluminide diffusion layer containing Ni–Al, Al–Ti–Ni, and hafnium-rich phases was successfully formed by aluminizing IN 713C nickel superalloy. Subsequently performed corrosion resistance tests confirmed the beneficial effect of the aluminide layer deposited on IN 713C as compared to substrate material. Anticipating improved mechanical response of coated material, density functional theory calculations were performed. It was found that a single Hf/Ti/Mo atom prefers to be positioned within the Al sublattice in the NiAl, and Ni3Al phases. This justifies the presence of the experimentally observed Ni3Hf phase in the Hf-enriched IN 713C. The Hf modification effects on the NiAl, and Ni3Al were further discussed based on the changes of the elastic constants Cij, bulk modulus B, and shear modulus G. The presence of Hf in NiAl causes a decrease of phase’s C12 and C44 values, and increase in the C11 value. It was found that Hf modification of the Ni3Al causes a decrease in the Cij values and a slight decrease of phase’s B/G ratio, indicating a less ductile character of modified phase decohesion.

本文讨论了添加铪、钛和钼对In 713C镍高温合金基板化学气相沉积铝化物层组织和性能的影响。通过对IN 713C镍高温合金进行渗铝处理,成功形成了含Ni-Al、Al-Ti-Ni和富铪相的多组分铝化物扩散层。随后进行的耐腐蚀试验证实了与衬底材料相比,沉积在IN 713C上的铝化物层的有益效果。预测涂层材料力学响应的改善,进行了密度泛函理论计算。在NiAl和Ni3Al相中,单个Hf/Ti/Mo原子更倾向于定位在Al亚晶格内。这证明了实验观察到的Ni3Hf相存在于富hf的in 713C中。基于弹性常数Cij、体积模量B和剪切模量g的变化,进一步讨论了Hf对NiAl和Ni3Al改性的影响。NiAl中Hf的存在导致相C12和C44值降低,C11值升高。结果表明,Hf对Ni3Al的改性使Ni3Al的Cij值降低,相的B/G比略有降低,表明改性相脱粘的延展性降低。
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Archives of Civil and Mechanical Engineering
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