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Numerical Study on Thermal Runaway of LFP batteries Triggered by Low Temperature Heating 低温加热引发的 LFP 电池热失控数值研究
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-07-08 DOI: 10.1007/s10694-024-01609-6
Chao An, Jiawei Zhai, Zhi Luo, Zhiguo Lei

With the wide application of electric vehicles (EVs) in cold areas, low temperature heating of battery is becoming more and more mature, and the way of battery bottom heating is also widely used in EVs. Nevertheless, the battery is not completely safe during the heating process, and there may be a risk that the heating plate trigger the battery to overheat. Firstly, a thermal runaway (TR) model of the battery is built, and the simulation results are compared with the experimental results to verify the accuracy. Subsequently, a bottom heating module is added to the TR model to simulate and analyze. Results show, when the heat flux exceeds 1500 J (m2 s)−1 and heating continuously for over 26,787 s, TR is triggered. As the heat flux increases, the TR is triggered nearly half the time earlier, and the maximum temperature reached also increases by 7.62°C. Additionally, the ambient temperature has a great effect on the time of continuous heating to TR at low temperature, and has little effect on the maximum temperature. This work provides a reference for the model study of TR in the case of low temperature heating.

随着电动汽车(EV)在寒冷地区的广泛应用,电池低温加热技术日趋成熟,电池底部加热方式也在电动汽车中得到广泛应用。然而,电池在加热过程中并不完全安全,可能存在加热板引发电池过热的风险。首先,建立了电池热失控(TR)模型,并将仿真结果与实验结果进行比较,以验证其准确性。随后,在 TR 模型中加入底部加热模块进行仿真分析。结果表明,当热流量超过 1500 J (m2 s)-1 并持续加热超过 26787 s 时,TR 被触发。随着热通量的增加,触发 TR 的时间提前了近一半,达到的最高温度也增加了 7.62°C。此外,环境温度对低温下持续加热到 TR 的时间影响很大,而对最高温度影响不大。这项工作为低温加热情况下 TR 的模型研究提供了参考。
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引用次数: 0
The Emmons Problem Revisited 埃蒙斯问题再探讨
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-07-08 DOI: 10.1007/s10694-024-01613-w
Howard R. Baum, J. G. Quintiere

The “Emmons Problem” is a foundation of fire science and gives a mathematical boundary layer solution to the burning of a vaporizing fuel from the surface of a flat plate immersed in a uniform flow of oxidizing gas. It approximates the Navier–Stokes equations assuming infinitely fast chemistry and ignores differential diffusion and thermal radiation. This allows “similarity” solutions to be developed and expressed in terms of the classic Blasius function. The current paper extends the solution, in mathematical form, to the entire domain far from the boundary layer and upstream of the leading edge. The introduction of conformal parabolic coordinates and use of the Howarth transformation allows the solution for the stream function to be expressed in exactly the same form as that found by Emmons and furnishes an explicit recipe for the pressure perturbation. The same coordinate transformations allow the exact solution of the full elliptic mixture fraction equation to be obtained, and the representation of the velocity components in terms of the stream function guarantees that the continuity equation is also satisfied exactly. Further, an exact solution to the transverse momentum equation is also displayed permitting the introduction of a crossflow into the spectrum of results obtained. In short, an analytic solution is found for the Emmons problem in the entire elliptic domain - upstream and in the far field.

埃蒙斯问题 "是火灾科学的基础,它给出了从浸没在均匀氧化气体流中的平板表面汽化燃料燃烧的数学边界层解决方案。它近似于纳维-斯托克斯方程,假设化学反应无限快,并忽略了微分扩散和热辐射。这使得 "相似性 "解得以开发,并用经典的布拉修斯函数来表示。本文以数学形式将该解法扩展到远离边界层和前缘上游的整个域。通过引入共形抛物线坐标和使用 Howarth 变换,流函数的解可以用与 Emmons 所发现的完全相同的形式表示,并为压力扰动提供了明确的公式。通过相同的坐标变换,还可以获得全椭圆混合物分数方程的精确解,而用流函数来表示速度分量则保证了连续性方程也能得到精确满足。此外,横向动量方程的精确解也得到了显示,从而可以将横流引入所获得的结果谱中。总之,我们找到了埃蒙斯问题在整个椭圆域--上游和远场--的解析解。
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引用次数: 0
Influence of Cathode Materials on the Characteristics of Lithium-Ion Battery Gas Generation During Thermal Runaway 阴极材料对热失控期间锂离子电池气体生成特性的影响
IF 3.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-07-07 DOI: 10.1007/s10694-024-01611-y
Ying Zhang, Hong Wang, Hang Yu, Teng Jia, Chuyuan Ma

Gas generation of Lithium-ion batteries(LIB) during the process of thermal runaway (TR), is the key factor that causes battery fire and explosion. Thus, the TR experiments of two types of 18,650 LIB using LiFePO4 (LFP) and LiNi0.6Co0.2Mn0.2O2 (NCM622) as cathode materials with was carried out with different state of charging (SOC) of 0%, 50% and 100%.The temporal variation of battery vent gas (BVG) during the TR process by a multi-component gas measuring instrument and a gas chromatograph. Results showed that both the BVG compositions of LFP battery and NCM622 battery were CO2, H2, CO and alkane. The evolution process of BVG in TR can be divided into four stages: gas gestation stage, safety valve opening, accelerated jet and jet termination.The main combustible gases appeared in the order of H2 > CH4 > VOC > CO. The order of gas concentrations were CH4 > H2 > VOC > CO. For LFP batteries, the concentrations of CH4, H2, VOC and CO increase with SOC, and no combustion behaviors were observed during the three cases of SOC is 0%, 50% and 100%. While for NCM622 batteries, fire occurred at the case of 100% SOC, and the jet sparks brought a sharp rise of the concentrations of H2, VOC and CO in BVG. The results of battery gas production provide a basis for battery safety monitoring and a new idea for the analysis of battery TR ignition behavior.

锂离子电池(LIB)在热失控(TR)过程中产生的气体是导致电池起火和爆炸的关键因素。因此,以磷酸铁锂(LFP)和镍钴锰酸锂(NCM622)为正极材料,在 0%、50% 和 100% 的不同充电状态(SOC)下,对两种类型的 18,650 LIB 进行了热失控实验。结果表明,LFP 电池和 NCM622 电池的放空气体成分均为 CO2、H2、CO 和烷烃。TR 中 BVG 的演变过程可分为四个阶段:气体酝酿阶段、安全阀打开、加速喷射和喷射终止。气体浓度的顺序为 CH4 > H2 > VOC > CO。对于 LFP 电池,CH4、H2、VOC 和 CO 的浓度随着 SOC 的增加而增加,在 SOC 为 0%、50% 和 100%的三种情况下均未观察到燃烧行为。而 NCM622 电池在 SOC 为 100%时发生了燃烧,喷射的火花导致 BVG 中 H2、VOC 和 CO 的浓度急剧上升。电池气体产生的结果为电池安全监控提供了依据,也为分析电池 TR 点火行为提供了新思路。
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引用次数: 0
Smoke Control Strategy and Design Criterion in Tunnel Fire Hazards Using Point Extraction Ventilation: Experimental Analysis and Theoretical Modeling 使用点抽风的隧道火灾烟雾控制策略和设计标准:实验分析与理论建模
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-07-04 DOI: 10.1007/s10694-024-01605-w
Peng Zhao, Zhongyuan Yuan, Chenchen Liang, Yanping Yuan, Rui Wang

The hot and toxic smoke is a major reason for deaths and injuries in tunnel fire hazards, therefore, it is of vital importance for safe evacuation to effectively control the smoke. This paper proposed a smoke control strategy, i.e., completing smoke extraction, and developed the design criterion of exhaust rate based on small-scale experiments and theoretical analysis. The heat release rate (HRR), damper length, and interval were considered. Experimental results showed the critical exhaust rate for completing smoke extraction rose with the increase in HRR and declined with a growing damper interval. Besides, it first rapidly decreased and then turned to be smooth with rising damper length. Subsequently, the ratio of the suction force, Fd to the force, Fs was adopted to determine the completing smoke extraction using force analysis. The results illustrated that the HRR and damper interval barely affect the relative magnitude between the suction force, Fd, and the force, Fs. It was linearly dependent on the dimensionless damper length and then exponentially grew. The critical length of the damper was 0.1 m. Finally, a prediction model was established, and the evaluated results deviated from the experimental data within 15%.

高温有毒烟雾是隧道火灾中造成人员伤亡的主要原因,因此有效控制烟雾对安全疏散至关重要。本文提出了一种烟气控制策略,即完成排烟,并在小规模实验和理论分析的基础上制定了排烟率设计标准。考虑了热释放率(HRR)、风门长度和间隔。实验结果表明,完成排烟的临界排烟率随着 HRR 的增加而上升,并随着风门间隔的增大而下降。此外,随着风门长度的增加,临界排烟率先是迅速下降,然后趋于平稳。随后,采用吸力 Fd 与力 Fs 的比值,通过受力分析来确定完成排烟量。结果表明,HRR 和风门间隔几乎不影响吸力 Fd 与力 Fs 的相对大小。它与无量纲阻尼器长度呈线性关系,然后呈指数增长。最后,建立了一个预测模型,评估结果与实验数据的偏差在 15%以内。
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引用次数: 0
An Empirical Correlation for Burning of Spruce Wood in Cone Calorimeter for Different Heat Fluxes 不同热通量下云杉木材在锥形量热计中燃烧的经验相关性
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-07-03 DOI: 10.1007/s10694-024-01603-y
Paul Lardet, Alain Coimbra, Lucas Terrei, ElMehdi Koutaiba, Renato Mole-Antoniazza, Gabriel Giovannelli

This article proposes an empirical expression to describe the pyrolysis and charring of spruce wood in bench-scale experiments for a wide range of incident heat fluxes. Spruce wood samples were exposed to a cone radiant heater oriented vertically with varying intensities, ranging from (dot{q}_{text {cone}}^{''}) = 22 kW m(^{-2}) to 93.5 kW m(^{-2}) over 53 test samples. The mass loss rate (MLR), the position of the char front and a preliminary additional heat source from smoldering or flaming combustion were experimentally determined. The experimental data were processed to express the burning rate as a function of heat flux and char front position. A grouping of the experimental curves was obtained, allowing to predict the MLR outcome over time regardless of the incident heat flux. A linear regression at the quasi-steady state regime allowed the determination of the fitting coefficients of the correlation, which ultimately correspond to the mass of volatiles produced per unit of energy input into the material. A comparison was made with theoretical analysis of the pyrolysis of charring materials from the literature, and the discrepancies with the proposed approach and its limitations were finally discussed. The main advantage of this approach is that it provides a generalized expression, requiring minimal input of material properties, which predicts the MLR change over time for any heat flux within engineering accuracy.

本文提出了一种经验表达式,用于描述在台架实验中云杉木材在各种入射热通量下的热解和炭化过程。在 53 个测试样品中,云杉木材样品暴露在垂直方向的锥形辐射加热器中,强度从 (dot{q}_{text {cone}}^{''}) = 22 kW m(^{-2}) 到 93.5 kW m(^{-2}) 不等。通过实验确定了质量损失率(MLR)、炭化前沿的位置以及来自烟熏或火焰燃烧的初步附加热源。对实验数据进行处理后,将燃烧速率表示为热通量和炭前位置的函数。通过对实验曲线的分组,可以预测 MLR 随时间变化的结果,而与入射热通量无关。在准稳定状态下进行线性回归,可以确定相关的拟合系数,这些系数最终与输入材料的每单位能量产生的挥发物质量相对应。与文献中关于炭化材料热解的理论分析进行了比较,最后讨论了与所提议方法的差异及其局限性。这种方法的主要优点是提供了一个通用表达式,只需输入极少的材料属性,就能在工程精度范围内预测任何热通量随时间变化的 MLR。
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引用次数: 0
Deep Fundamental Diagram Network for Fast Pedestrian Dynamics Estimation 用于快速行人动态估计的深度基本图网络
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-07-01 DOI: 10.1007/s10694-024-01598-6
Ruolong Yi, Qing Ma, Weiguo Song, Jun Zhang

How to effectively guide occupants to use different evacuation routes under fire situations is the key to improving fire safety and ensuring successful evacuation. Evacuation analysis for fire safety in surveillance videos plays a crucial role in understanding and mitigating risks. The fundamental diagram of pedestrian flow, which illustrates the relationship between pedestrian velocity and crowd density, is a valuable tool for analyzing evacuation dynamics and enhancing fire safety measures. Traditional methods rely on trajectory files obtained from manually tracking each pedestrian in video recordings to construct fundamental diagrams. However, these methods have limitations in accurately representing crowd density and cannot provide real-time analysis, making them unsuitable for surveillance camera analysis in fire safety scenarios. To address this challenge, we propose a novel convolutional neural network-based framework called the deep fundamental diagram network, which is specifically designed for fire safety applications. This framework consists of two modules: the multi-level dilated convolutional neural network (MLD-Net) and the optical flow module. The MLD-Net learns the mapping relationship between input images and density maps, enabling accurate estimation of pedestrian density. Simultaneously, the optical flow module calculates pedestrian movement speed, providing crucial information for evacuation planning. By aligning the density map with the speed map, the fundamental diagram is derived, which aids in understanding evacuation dynamics. The experimental results demonstrate that our method achieves good consistency with traditional approaches while significantly reducing the computational time. Additionally, our framework enables anomaly detection and pedestrian line counting, further enhancing fire safety measures. This work is expected to have good prospects in the fields of fire safety, evacuation dynamics analysis, and real-time crowd analysis systems for fire situations.

如何在火灾情况下有效引导住户使用不同的疏散路线,是提高消防安全和确保成功疏散的关键。监控视频中的消防安全疏散分析在了解和降低风险方面发挥着至关重要的作用。行人流基本图说明了行人速度与人群密度之间的关系,是分析疏散动态和加强消防安全措施的重要工具。传统方法依赖于视频记录中手动跟踪每个行人所获得的轨迹文件来构建基本图。然而,这些方法在准确表示人群密度方面存在局限性,而且无法提供实时分析,因此不适合用于消防安全场景中的监控摄像机分析。为了应对这一挑战,我们提出了一种基于卷积神经网络的新型框架,称为深度基本图网络,它是专为消防安全应用而设计的。该框架由两个模块组成:多级扩张卷积神经网络(MLD-Net)和光流模块。MLD-Net 可学习输入图像与密度图之间的映射关系,从而准确估计行人密度。同时,光流模块还能计算行人的移动速度,为疏散规划提供重要信息。通过将密度图与速度图对齐,可以得出基本图,这有助于理解疏散动态。实验结果表明,我们的方法与传统方法具有良好的一致性,同时大大减少了计算时间。此外,我们的框架还能进行异常检测和行人线路计数,从而进一步加强消防安全措施。这项工作有望在消防安全、疏散动态分析和火灾情况下的实时人群分析系统等领域产生良好的应用前景。
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引用次数: 0
Research on Mine Smoke Detection Technology Based on Multi-Feature Fusion Analysis 基于多特征融合分析的地雷烟雾探测技术研究
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-06-28 DOI: 10.1007/s10694-024-01602-z
Xiankang Huang, Zuzhi Tian, Chusen Wang, Fangwei Xie, Jinjie Ji

Traditional smoke detection sensors are characterized by low sensitivity, poor stability, etc. In this study, we propose a coal mine smoke detection technique based on multi-feature fusion analysis. Detection of smoke on belt conveyors is realized by machine vision technology. Firstly, the inter-frame difference method is used to capture the motion region of the smoke. And the suspected smoke region is obtained. Then, the color features of smoke are obtained by RGB color histogram. The motion direction features of smoke are obtained by smoke optical flow vector extraction. The irregular contour features of smoke are obtained by smoke contour irregularity criterion statistics. Based on obtaining the suspected smoke area, the above three features are used to determine whether the belt conveyor produces smoke. This study collected four video images of the belt surface smoke, stand smoke, light samples, and dust samples. The final combined diagnostic rate was 94.19% by testing the above detection models. This study proposes a stable and effective smoke detection technique for coal mine safety production.

传统的烟雾探测传感器具有灵敏度低、稳定性差等特点。本研究提出了一种基于多特征融合分析的煤矿烟雾检测技术。通过机器视觉技术实现对带式输送机上烟雾的检测。首先,利用帧间差分法捕捉烟雾的运动区域。得到疑似烟雾区域。然后,通过 RGB 颜色直方图获得烟雾的颜色特征。通过烟雾光流向量提取获得烟雾的运动方向特征。烟雾的不规则轮廓特征由烟雾轮廓不规则准则统计获得。在获得疑似烟雾区域的基础上,利用上述三个特征来判断皮带输送机是否产生烟雾。本研究收集了皮带表面烟雾、支架烟雾、光线样本和灰尘样本四种视频图像。通过测试上述检测模型,最终综合诊断率为 94.19%。本研究为煤矿安全生产提出了一种稳定有效的烟雾检测技术。
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引用次数: 0
Experimental Study of Fire Containment Using Fabric Curtains in a Reduced-Scale Deck of a Ro–Ro Ship 在滚装船缩比甲板上使用织物帘幕阻隔火灾的实验研究
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-06-24 DOI: 10.1007/s10694-024-01600-1
Rabah Mehaddi, Davood Zeinali, Gilles Parent, Zoubir Acem, Anthony Collin, Pascal Boulet

The possibility to subdivide a deck of a ro-ro ship to contain heat and smoke by means of a fabric curtain descending from the ceiling (i.e., the deckhead) is studied experimentally using a reduced-scale experimental setup. As an important part of the study, the requirements of the international convention of Safety of Life at Sea (SOLAS) are investigated for so-called ‘open ro-ro decks’ in comparison with ‘closed ro-ro decks’. To analyse the experiments, sensors are used to measure the opacity levels as well as the gas temperatures and concentrations. These measurements helped quantify the degree of stratification of the smoke, its concentration of soot, and carbon monoxide levels, making it possible to analyze the effects of containment induced by the fabric curtain. The results show that the fabric curtain considerably reduces the gas temperatures and the soot concentration upstream of the curtain if it descends completely (i.e., to the floor level), while it does not disturb the stratification of smoke. The containment of smoke is more enhanced when multiple fabric curtains are used, and a comparison with a water curtain shows that the fabric curtain offers better smoke containment. Finally, the most optimal containment effect is achieved using a system that combines a fabric curtain with a water curtain.

我们利用一个缩小规模的实验装置,通过从天花板(即甲板头)上垂下来的织物帘幕,对滚装船甲板进行细分以控制热量和烟雾的可能性进行了实验研究。作为研究的一个重要部分,对所谓的 "开放式滚装甲板 "与 "封闭式滚装甲板 "进行了比较,研究了国际海上人命安全公约(SOLAS)的要求。为了对实验进行分析,使用了传感器来测量不透明度水平以及气体温度和浓度。这些测量结果有助于量化烟雾的分层程度、烟尘浓度和一氧化碳含量,从而可以分析织物帘幕的阻隔效果。结果表明,如果布帘完全下降(即下降到地面),则布帘上游的气体温度和烟尘浓度会大大降低,同时不会干扰烟雾的分层。当使用多个纤维帘时,烟雾阻隔效果会更好,与水帘相比,纤维帘的烟雾阻隔效果更好。最后,使用织物帘和水帘相结合的系统可以达到最佳的防烟效果。
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引用次数: 0
Research on Quantitative Assessment Method for Fire Spread Risk in Enclosed Buildings 封闭式建筑火灾蔓延风险定量评估方法研究
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-06-19 DOI: 10.1007/s10694-024-01588-8
Haodong Sun, Jihong Ye

The main objective of this research is to establish a quantitative risk assessment method for fire spread in enclosed building scenarios. The enclosed building fire spread process is divided into three stages: fire fully developed in the fire compartment, failure of weak barrier, and combustibles ignited in the target compartment. The calculation method for fire spread is established, where the time for fire fully developed is calculated based on the t2 fire, the barrier failure time is calculated based on the finite difference method, and the combustible ignition time is calculated based on the zone model. The linear regression model is formulated to ensure computational efficiency for fire spread time prediction. The enclosed building fire spread quantitative risk assessment method is proposed based on the Probit model. The effectiveness of the risk assessment method is validated through the enclosed building fire spread experiment, and the method is applied to assess the risk of fire spread in an office. The results demonstrate that the method could quantitatively assess fire spread risk under different conditions with high computational efficiency and excellent versatility, and it could provide guidance for fire prevention, building fire design, and fire rescue.

这项研究的主要目的是建立封闭式建筑火灾蔓延的定量风险评估方法。封闭式建筑的火势蔓延过程分为三个阶段:起火隔间内火势完全蔓延、薄弱隔墙失效、目标隔间内可燃物被点燃。建立了火灾蔓延的计算方法,其中火灾完全发展时间根据 t2 火灾计算,屏障失效时间根据有限差分法计算,可燃物点燃时间根据区域模型计算。为确保火灾蔓延时间预测的计算效率,制定了线性回归模型。基于 Probit 模型,提出了封闭式建筑火灾蔓延定量风险评估方法。通过封闭式建筑火灾蔓延实验验证了风险评估方法的有效性,并将该方法应用于评估办公室火灾蔓延风险。结果表明,该方法可定量评估不同条件下的火灾蔓延风险,计算效率高,通用性强,可为火灾预防、建筑消防设计和消防救援提供指导。
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引用次数: 0
The Tube Furnace with Online Mass Loss Measurement as a New Bench Scale Test for Pyrolysis 带有在线质量损失测量功能的管式炉作为热解的新基准试验
IF 2.3 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-06-18 DOI: 10.1007/s10694-024-01590-0
Karen De Lannoye, Alexander Belt, Ernst-Arndt Reinecke, Lukas Arnold

In this paper, a new gram scale experiment with well characterised boundary conditions is proposed for pyrolysis experiments. The set-up consists of a tube furnace, based on ISO19700, with a newly designed concept for a balance within the oven, allowing for online mass loss measurements. Samples with a length up to 50 cm can be investigated in this apparatus. The oven allows for experiments at fixed temperatures or at fixed heating rates, under controlled atmosphere, w.r.t. gas composition and flow rate. A thorough characterisation of the set-up is presented, including aspects like reproducibility of the heating rate or the precision of the balance. The functionality of the balance has been demonstrated with calcium carbonate (CaCO(_{3})) experiments. This material was chosen because it decomposes in a single reaction, which only releases CO(_{2}). This allows for comparison between the mass loss rate of the balance and the CO(_{2}) production rate, measured by a gas analyser. Results for two different heating rates: 3 K/min and 5 K/min and for different masses (25 g and 8.5 g) are presented. The two measurement methods are in excellent agreement. Finally, the data obtained from the new experimental set-up is compared to results from thermogravimetric analyser (TGA) experiments.

本文为热解实验提出了一种新的克级实验,其边界条件特性良好。该装置由一个基于 ISO19700 标准的管式炉组成,炉内的天平采用了新设计的概念,可进行在线质量损失测量。在该设备中可研究长度达 50 厘米的样品。烘箱可在固定温度或固定加热速率下进行实验,并对气体成分和流速进行控制。对该装置进行了全面的特性分析,包括加热速率的可重复性或天平的精度等方面。碳酸钙 (CaCO(_{3})) 实验证明了天平的功能。之所以选择这种材料,是因为它在单一反应中分解,只释放出 CO(_{2})。这样就可以比较天平的质量损失率和气体分析仪测量的 CO (_{2})产生率。两种不同加热速率的结果:3 K/min 和 5 K/min 以及不同质量(25 g 和 8.5 g)的结果。两种测量方法非常一致。最后,将新实验装置获得的数据与热重分析仪(TGA)的实验结果进行了比较。
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引用次数: 0
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