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Development of a Mesoscopic Egress Model to Estimate the Evacuation on Board Ro–Ro Ships 一种估算滚装船上疏散的介观出口模型的建立
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-04-21 DOI: 10.1007/s10694-025-01734-w
A. Collin, D. Zeinali, A. Marchand, T. Gasparotto

This paper presents a new evacuation model for fast and affordable simulations of evacuation based on Togawa’s theory for multi-compartment configurations. The aim is to track the evacuee’s path and to estimate the congestion (or the queues) behind each doorway at each time step to model the evacuation process. In this approach, only two parameters drive the formation of congestion, namely the maximum out-coming people flux and the width of the doorway. For a real application, such as evacuation in a building or a boat, a geometrical configuration is considered by a “tree structure” where each doorway is connected to the others up to the main exit. The originality of this paper is in proposing a theoretical expression for the people flux feeding the congestion for people which are located just behind a given doorway. Moreover, this contribution proposes various new experimental tests to qualify and to validate the proposed model. All experimental data (146 evacuation exercises) are available in an open access database for further uses. In this communication, a sensitivity analysis is proposed on a single deck evacuation of the RMS Titanic (the best documented ship for its geometry) with 1126 people. This analysis demonstrates that, between the free walk speed and the maximum out-coming people flux per length of doorway, this latter variable is the most influential parameter of the present model, accounting for 22% of variations in evacuation time. The model has been applied to estimate evacuation times for generic Ro–Ro ships, to test some existing alternatives to abandon a ship and to propose some new perspectives to optimize the evacuation.

本文基于Togawa的多隔室疏散理论,提出了一种快速、经济的疏散模拟新模型。目的是跟踪疏散人员的路径,并估计每个时间步每个门口后面的拥堵(或排队),以模拟疏散过程。在该方法中,只有两个参数驱动拥堵的形成,即最大出入口人流和门口宽度。对于实际应用,例如建筑物或船上的疏散,几何配置被认为是“树状结构”,其中每个门与其他门相连,直到主出口。本文的创新之处在于提出了一个理论表达式,用于满足位于给定门口后面的人群的拥挤。此外,这一贡献提出了各种新的实验测试,以确定和验证所提出的模型。所有实验数据(146次疏散演习)均可在开放获取数据库中获得,以供进一步使用。在本文中,对载有1126人的皇家邮轮泰坦尼克号(RMS Titanic)(其几何形状有最佳记录的船只)的单甲板疏散进行了敏感性分析。分析表明,在自由步行速度和每长度门口最大出入口人流之间,后者是模型中影响最大的参数,占疏散时间变化的22%。应用该模型估计了一般滚装船舶的撤离时间,并对现有的弃船方案进行了测试,提出了优化撤离的新视角。
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引用次数: 0
Recognition of Forest Fire Smoke Based on Improved YOLOv8n Model 基于改进YOLOv8n模型的森林火灾烟雾识别
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-04-19 DOI: 10.1007/s10694-025-01733-x
Faying Chen, Meng Yang, Yuan Wang

To address the challenges of early forest fire smoke image recognition, including false alarms and missed reports caused by interference in complex environments, an enhanced model, named MB-YOLO, is proposed based on the YOLOv8 Nano (YOLOv8n) architecture for efficiently recognizing forest fire smoke. Firstly, to overcome detection failures of low-concentration smoke in complex backgrounds, the original Path Aggregation Network (PAN) is replaced with a bi-directional feature pyramid network (BiFPN). This substitution not only enhances multi-scale feature extraction but also simplifies the network structure, reducing the number of parameters. Secondly, to address false detections caused by cloud and mist interference, the C2f_MLCA module is developed. This module integrates a lightweight Mixed Local Attention mechanism (MLCA) into the bottleneck of the gradient flow module C2f, thereby enhancing smoke feature extraction. Lastly, to reduce sensitivity to positional offsets of small smoke targets, the Complete Intersection over Union (CIoU) loss is replaced with Inner-DIoU loss. This new loss function computes loss with auxiliary bounding boxes, accelerating convergence speed and enhancing accuracy for small smoke targets. The effectiveness of the algorithm is validated with a curated dataset containing small smoke targets, unclear backlighting, and cloud and mist interference. Experimental results demonstrate that our model achieves a mean Average Precision (mAP) of 80.1%, a frame rate of 60.6 Frames Per Second (FPS), with a total of 1.09 million parameters and 7.1 billion floating-point operations per second (FLOPs). This model offers high detection accuracy, fewer parameters, and lower GFLOPs, facilitating accurate real-time monitoring of forest fires in complex environments and all-weather conditions.

针对复杂环境下干扰导致的森林火灾烟雾图像早期识别存在误报、漏报等问题,提出了基于YOLOv8 Nano (YOLOv8n)架构的增强模型MB-YOLO,实现了森林火灾烟雾的高效识别。首先,针对复杂背景下低浓度烟雾检测失败的问题,采用双向特征金字塔网络(BiFPN)取代原有的路径聚合网络(PAN);这种替换不仅增强了多尺度特征提取,而且简化了网络结构,减少了参数的数量。其次,针对云雾干扰造成的误检问题,开发了C2f_MLCA模块。该模块在梯度流模块C2f的瓶颈中集成了轻量级的混合局部注意机制(MLCA),从而增强了烟雾特征提取。最后,为了降低对小烟雾目标位置偏移的敏感性,将CIoU (Complete Intersection over Union)损耗替换为内diou损耗。该损失函数利用辅助边界框计算损失,加快了收敛速度,提高了小烟雾目标的精度。该算法的有效性通过包含小烟雾目标、不清晰的背光和云雾干扰的精选数据集得到验证。实验结果表明,该模型的平均精度(mAP)为80.1%,帧率为60.6帧/秒(FPS),共有109万个参数和71亿次浮点运算/秒(FLOPs)。该模型检测精度高,参数少,GFLOPs低,便于在复杂环境和全天候条件下对森林火灾进行准确的实时监测。
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引用次数: 0
Advancing the Prediction of Evaporation Rate of Liquid Pool Fires in Mechanically Ventilated Compartments Using Computational Fluid Dynamics 应用计算流体力学方法推进机械通风隔间液池火灾蒸发速率预测
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-04-17 DOI: 10.1007/s10694-025-01739-5
Okorie Ukairo, Siaka Dembele, Ali Heidari, Hugues Pretrel, Konstantin Volkov

The propagation of smoke and hot gases in mechanically ventilated nuclear compartments has been highlighted as one of the main issues of significance. It may lead to the failure of several systems such as clogging of filters located in the ventilation network or electrical devices. To address this issue, the continuous improvement of the predictive capability of existing models with regards to liquid pool fires is of high importance. Computational fluid dynamics (CFD) is widely used for fire simulations. It is worth noting that most pool fire simulations in open atmosphere, under-ventilated and mechanically ventilated compartments have relied on pre-defined/prescribed fuel mass loss rate (MLR) or heat release rates (HRR) from correlations or experimental data when available. Therefore, the prediction of fuel MLR and HRR based on the specific actual fire conditions rather than prescribed data, remains a key development area for the fire community. The present work aims to provide some contribution and advances on this issue. Building on existing liquid evaporation models, the study develops an approach which in then implemented in an in-house version of the CFD code FireFOAM in which a mechanical ventilation model has been embedded, to predict the fuel MLR in both open atmosphere and mechanically ventilated compartments. Validations of the implemented model includes comparison with experimental fuel MLR and previous studies that made use of correlations and experimental data. The results show acceptable fuel MLR predictions with reasonable accuracy and provide further insights into fire behaviour in mechanically ventilated compartments.

在机械通风的核室中,烟雾和热气体的传播是一个重要的问题。它可能导致几个系统的故障,例如位于通风网络或电气设备中的过滤器堵塞。为了解决这一问题,不断提高现有模型对液池火灾的预测能力至关重要。计算流体力学(CFD)广泛应用于火灾模拟。值得注意的是,在开放气氛、通风不足和机械通风的隔间中,大多数池火模拟都依赖于预先定义/规定的燃料质量损失率(MLR)或热释放率(HRR),这些数据来自相关性或可用的实验数据。因此,基于具体实际火灾条件而非规定数据的燃料最大可燃比和最大可燃比预测仍然是消防界的一个重点发展领域。本文的工作旨在对这一问题作出一些贡献和进展。在现有液体蒸发模型的基础上,该研究开发了一种方法,然后在CFD代码FireFOAM的内部版本中实施,其中嵌入了机械通风模型,以预测开放气氛和机械通风舱内的燃料MLR。实现模型的验证包括与实验燃料MLR和先前使用相关性和实验数据的研究进行比较。结果显示出可接受的燃料MLR预测,具有合理的准确性,并为机械通风隔间的火灾行为提供了进一步的见解。
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引用次数: 0
Dynamic Risk Assessment of Wildfire-Induced Transmission Line Breakdown Based on Data Assimilation Method 基于数据同化法的野火致输电线路击穿动态风险评估
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-04-09 DOI: 10.1007/s10694-025-01728-8
Zheng Wang, Mengxia Zha, Jie Ji, Wenzhou Wu, Long Ding

Wildfires pose an escalating threat to critical infrastructure, particularly transmission lines, leading to severe power outages and significant economic impacts. While existing studies have primarily focused on static risk assessment methods, this research introduces a novel dynamic risk assessment framework that addresses the rapidly evolving nature of wildfire dynamics through advanced data assimilation techniques, utilizing a real-world wildfire case study. Unlike previous approaches that rely on single-parameter updates or static fire line predictions, our framework integrates observational data into the wildfire simulation tool FARSITE using an ensemble transform Kalman filter, enabling multi-parameter updates that significantly enhance the predictive accuracy of fire line positions and their associated uncertainties. Furthermore, a Monte Carlo simulation-based approach is developed to dynamically calculate wildfire arrival probabilities, combined with a robust quantitative framework for assessing transmission line failure likelihood under fire scenarios. The fire line intensity, determined under the worst-case scenario principle, serves as the input for the quantitative assessment framework. By integrating wildfire arrival probabilities and transmission line failure risks, this study provides a comprehensive and dynamic risk assessment tool, offering a transformative perspective on managing the interface between wildfires and critical infrastructure.

野火对关键基础设施,特别是输电线路构成了不断升级的威胁,导致严重的停电和重大的经济影响。虽然现有的研究主要集中在静态风险评估方法上,但本研究引入了一种新的动态风险评估框架,通过先进的数据同化技术,利用真实世界的野火案例研究,解决了野火动态快速演变的本质。与以往依赖于单参数更新或静态火线预测的方法不同,我们的框架使用集成变换卡尔曼滤波器将观测数据集成到野火模拟工具FARSITE中,从而实现多参数更新,从而显著提高火线位置及其相关不确定性的预测精度。此外,开发了一种基于蒙特卡罗模拟的方法来动态计算野火到达概率,并结合了一个强大的定量框架来评估火灾情景下输电线路故障的可能性。根据最坏情况原则确定的火线强度作为定量评估框架的输入。通过整合野火到达概率和输电线路故障风险,本研究提供了一个全面和动态的风险评估工具,为管理野火与关键基础设施之间的接口提供了一个变革性的视角。
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引用次数: 0
Numerical and Design Analysis of Protected Steel Columns in Standard Fire 标准火灾中防护钢柱的数值与设计分析
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-04-03 DOI: 10.1007/s10694-025-01716-y
Pegah Aghabozorgi, Luís Laím, Aldina Santiago

The high thermal conductivity of steel, combined with its rapid degradation in mechanical properties with increasing temperature, makes it vulnerable to fire. Fire protection materials are effectively designed to control the temperature rise within steel members. This paper is a companion to a previous numerical analysis study on protected square hollow section (SHS) steel columns using thermally enhanced gypsum-based mortars. It offers a more detailed numerical investigation into the thermal performance of different gypsum-based mortar compositions used as a passive fire protection material for different types of steel columns. Firstly, finite element models for SHS steel columns were developed and verified against data from previous fire resistance tests. Then, a parametric study was conducted to explore how factors like fire protection thickness and composition, cross-section (square, rectangular, and H-shaped sections), steel tube thickness, column slenderness, and applied load level (serviceability load states) affect their fire performance under the ISO-834 standard fire curve. Comparisons were made between numerical results and current design methods from Eurocodes. It was observed that existing design methods excessively underestimate the actual fire resistance of protected columns, particularly for class-4 cross-sections especially when mortars with highest thermal insulation capacity are used. Moreover, the thermal properties of fire protection mortars should be considered in the structural steel temperature prediction as a function of temperature during fire conditions. Based on the study’s findings, modifications to current design methods for predicting the temperature evolution of columns as a function of the cross-sections and fire protection compositions, were presented with enhanced accuracy. These proposed modifications can potentially contribute to future development in Eurocode and improved fire resistance predictions.

钢的高导热性,加上其机械性能随着温度的升高而迅速退化,使其容易受到火灾的影响。防火材料的设计有效地控制了钢构件内部的温升。本文是对热增强石膏基砂浆保护方空心截面钢柱数值分析研究的补充。它提供了一个更详细的数值研究不同石膏基砂浆组合物作为被动防火材料用于不同类型的钢柱的热性能。首先,建立了SHS钢柱的有限元模型,并根据先前的耐火试验数据进行了验证。然后,在ISO-834标准火灾曲线下,进行参数化研究,探讨防火厚度和组成、截面(方形、矩形和h形截面)、钢管厚度、柱长细比、外加荷载等级(可使用荷载状态)等因素对其火灾性能的影响。将数值计算结果与现行欧洲规范的设计方法进行了比较。研究发现,现有的设计方法过分低估了受保护柱的实际耐火性能,特别是对于4类截面,特别是当使用具有最高保温能力的砂浆时。此外,防火砂浆的热性能在火灾条件下应考虑作为温度函数的结构钢温度预测。根据研究结果,修改了当前设计方法,以预测柱的温度演变作为截面和防火成分的函数,提出了更高的准确性。这些提议的修改可能有助于欧洲规范的未来发展,并改善防火预测。
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引用次数: 0
Correction to: An Interpretability Analysis Framework to Enhance Deep Learning Model Transparency: With a Study Case on Flashover Prediction Using Time-Series Sensor Data 修正:提高深度学习模型透明度的可解释性分析框架:使用时间序列传感器数据进行闪络预测的研究案例
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-04-02 DOI: 10.1007/s10694-025-01732-y
Linhao Fan, Qi Tong, Hongqiang Fang, Wei Zhong, Wai Cheong Tam, Tianshui Liang
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引用次数: 0
On the Performance of Damper-Optimised Demand-Controlled Ventilation Systems During a Fire 火灾中阻尼优化需求控制通风系统的性能研究
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-04-01 DOI: 10.1007/s10694-025-01724-y
Christoph Meraner, Janne Siren Fjærestad, Anne-Marit Haukø

Modern heating, ventilation, and air conditioning (HVAC) systems are complex, interconnected systems optimised to be energy efficient. Damper-optimised demand-controlled ventilation systems (DCV) minimise energy consumption by using a dedicated control unit that calculates the optimal fan speed based on room sensors and the feedback from all DCV dampers, which each measures the airflow rate and adjusts its damper angle accordingly. In buildings that do not use a compartmentation strategy in the event of a fire, it is crucial that the ventilation system is pressurised and provides balanced ventilation in order to prevent smoke from spreading via the ventilation system and to avoid creating pressure imbalances, which may impair evacuation. In the present study, two full-scale fire tests from a series of 14 tests in a mock-up building equipped with a damper-optimised DCV system are presented, and the ventilation system’s performance during the fire is assessed. The tests revealed various failure mechanisms caused by heat exposure, leading to individual damper uncontrolled opening or closing or the building management system losing contact with all dampers. Furthermore, it was shown that the failure of individual dampers and the gradual clogging of the extraction filter can affect the pressure balance in other parts of the building outside the fire room and increase the risk of smoke spreading through the ventilation ducts.

现代供暖、通风和空调(HVAC)系统是复杂的、相互关联的系统,经过优化后具有节能效果。阻尼器优化的需求控制通风系统(DCV)通过使用专用控制单元来最大限度地减少能耗,该控制单元根据房间传感器和所有DCV阻尼器的反馈计算最佳风扇速度,每个阻尼器测量气流速率并相应地调整其阻尼器角度。在发生火灾时不使用隔层策略的建筑物中,至关重要的是通风系统是加压的,并提供平衡的通风,以防止烟雾通过通风系统扩散,并避免造成压力不平衡,这可能会影响疏散。在本研究中,给出了在配备阻尼优化DCV系统的实体建筑中进行的一系列14次全尺寸火灾试验中的两次试验,并评估了通风系统在火灾中的性能。试验揭示了由热暴露引起的各种失效机制,导致单个阻尼器不受控制地打开或关闭,或建筑物管理系统与所有阻尼器失去联系。此外,个别阻尼器的失效和抽取过滤器的逐渐堵塞会影响火灾室以外建筑物其他部分的压力平衡,并增加烟雾通过通风管道蔓延的风险。
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引用次数: 0
Deep Residual Multi-resolution Features and Optimized Kernel ELM for Forest Fire Image Detection Using Imbalanced Database 基于非平衡数据库的森林火灾图像检测的深度残差多分辨率特征和优化核ELM
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-03-31 DOI: 10.1007/s10694-025-01729-7
Roohum Jegan, Gajanan K. Birajdar, Sangita Chaudhari

The growing incidence of wildfires, intensified by changing climate patterns, poses risks to human lives and the environment, leading to catastrophic impacts on agricultural and forest ecosystems. Consequently, timely wildfire detection becomes imperative to implement effective mitigation strategies. This article presents a new forest fire image detection technique to address a class imbalance problem using ResNet-18 multi-resolution features and kernel extreme learning machine (KELM). Shallow and deep layer ResNet-18 features are extracted and fused to create a comprehensive feature set that represents local and global characterization of the forest fire image data. The multi-resolution feature fusion effectively captures lower-level visual patterns and complex and abstract representations of the input image. The fused feature set is subsequently input into a kernel extreme learning machine, which effectively handles nonlinear data patterns for binary classification tasks like fire detection. However, the performance of the KELM heavily relies on its hyperparameters, which are optimized using the Newton–Raphson-Based Optimizer (NRBO) algorithm. The hyperparameters fine-tuning process ensures that the KELM operates with optimal settings, ultimately enhancing the accuracy and reliability of the fire detection process. The proposed algorithm is evaluated using two publicly available databases, Forest Fire and Flame, with a detection accuracy of 97.88% and 99.88%, respectively. Moreover, the contribution of each feature to the model’s predictions to interpret decisions is elaborated using SHAP (SHapley Additive exPlanations).

随着气候模式的变化,野火的发生率不断增加,对人类生命和环境构成威胁,对农业和森林生态系统造成灾难性影响。因此,及时探测野火对于实施有效的减灾战略至关重要。本文提出了一种利用ResNet-18多分辨率特征和核极限学习机(KELM)来解决类不平衡问题的森林火灾图像检测新技术。提取和融合浅层和深层ResNet-18特征,创建一个综合特征集,代表森林火灾图像数据的局部和全局特征。多分辨率特征融合可以有效捕获较低层次的视觉模式和输入图像的复杂抽象表示。随后将融合的特征集输入到核极限学习机中,该机器可以有效地处理非线性数据模式,用于火灾探测等二元分类任务。然而,KELM的性能很大程度上依赖于它的超参数,这些超参数是使用基于newton - raphson的优化器(NRBO)算法进行优化的。超参数微调过程确保KELM在最佳设置下运行,最终提高火灾探测过程的准确性和可靠性。使用两个公开的数据库Forest Fire和Flame对该算法进行了评估,检测准确率分别为97.88%和99.88%。此外,每个特征对模型预测的贡献是使用SHAP (SHapley加性解释)来解释决策的。
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引用次数: 0
Study of Fire Resilience Challenges to Promote the Structural Use of Load-Bearing Composite Timber-Glass Walls: Experimental and Numerical Analysis 促进承重复合材料-玻璃墙体结构使用的防火挑战研究:实验和数值分析
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-03-29 DOI: 10.1007/s10694-025-01727-9
Nikola Perković, Chiara Bedon, Jure Barbalić, Vlatka Rajčić

Fire accidents are a critical design condition for load-bearing elements in general. Among others, ordinary glass and composite glass materials are even more susceptible to fire and require the use or definition of specific test protocols, simulation strategies, performance indicators and validation methods. In this paper, the structural performance of a full-scale composite timber-glass composite wall (consisting of a perimetral timber frame and a double thin insulating glass unit (IGU)) under the effects of sustained mechanical loads (25 kN/m, as in a typical two-story building) and fire exposure is investigated based on a standard test furnace. The mechanical concept uses a laminated system that can cover an area of up to 3.2 × 2.7 square meters, with a relatively low thickness (63.52 mm for the double insulating glass unit (IGU), including cavity). A great advantage to evaluate the potential and critical points of the composite timber-glass composite system comes from experimental and finite element (FE) thermomechanical investigations. A pilot test is being conducted on a prototype prefabricated timber-glass module, which is expected to function as an efficient load-bearing system in buildings, withstanding the typical mechanical loads from normal or extreme actions, but also providing adequate resistance to fire accidents. The laboratory investigation was carried out on the basis of conventional recommendations for the experimental assessment of building components in the event of fire, with the main focus on estimating fire resistance. It has been shown that the overall load-bearing capacity and the corresponding fire resistance are mainly determined by the intrinsic properties of the glass components, which may need to be protected or optimized to ensure adequate residual capacity.

一般来说,火灾事故是承载元件设计的关键条件。其中,普通玻璃和复合玻璃材料更容易受到火灾的影响,需要使用或定义特定的测试协议、模拟策略、性能指标和验证方法。本文在标准试验炉上研究了全尺寸复合木-玻璃复合墙(由外围木框架和双层薄中空玻璃单元(IGU)组成)在持续机械载荷(25 kN/m,如典型的两层建筑)和火灾暴露作用下的结构性能。机械概念使用层压系统,可覆盖面积达3.2 × 2.7平方米,厚度相对较低(双层中空玻璃单元(IGU),包括腔)为63.52毫米)。实验和有限元热力学研究是评价复合材料体系的潜力和临界点的一大优势。目前正在对一个预制木玻璃模块原型进行试点测试,该模块预计将作为建筑物的有效承重系统,承受正常或极端行动的典型机械负荷,但也提供足够的防火事故抵抗力。实验室调查是在火灾情况下对建筑构件进行实验评估的传统建议的基础上进行的,主要侧重于估计防火性。研究表明,整体承载能力和相应的耐火性能主要取决于玻璃构件的内在特性,可能需要对其进行保护或优化,以确保足够的剩余容量。
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引用次数: 0
Contaminations from Lithium-Ion Battery Fires—Per- and Polyfluoroalkyl Substances (PFAS) in Soot 烟灰中锂离子电池火焰和多氟烷基物质(PFAS)的污染
IF 2.4 3区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2025-03-26 DOI: 10.1007/s10694-025-01708-y
Ola Willstrand, Maria Quant, Jonna Hynynen

Fluorinated substances are widely used in the different components of the lithium-ion battery cell, such as electrode binders, electrolyte, additives and separator materials. To date, most studies regarding the fluorinated contaminations from lithium-ion battery fires are focused on the gases formed, whereas the solids produced are not as well characterized. Here, we present an experimental study investigating the occurrence of per- and polyfluoroalkyl substances, in soot and particulates formed after thermal runaway in lithium-ion battery cells. Per- and polyfluoroalkyl substances were detected in every battery cell test performed in this study. The concentration of per- and polyfluoroalkyl substances ranged between 20 to 130 ng/gsoot. Extrapolation of data gives an estimated release of 10 to 60 µg of per- and polyfluoroalkyl substances per kg battery cells. Among the 22 per- and polyfluoroalkyl substances analyzed, perfluorobutanesulfonic acid and perfluorobutanoic acid were found in the highest concentrations for all samples. Interestingly, perfluorooctanoic acid was detected in all tests, in concentrations ranging between 0.05 to 0.62 ng/gsoot. These findings are of importance not only for the purpose of decontamination after thermal runaway events, but also when it comes to the lithium-ion battery recycling processes.

氟化物质广泛应用于锂离子电池电芯的不同组成部分,如电极粘结剂、电解质、添加剂和隔膜材料。迄今为止,大多数关于锂离子电池火灾产生的氟化污染物的研究都集中在形成的气体上,而产生的固体并没有得到很好的表征。在这里,我们提出了一项实验研究,调查了锂离子电池电池热失控后形成的烟尘和颗粒中全氟烷基和多氟烷基物质的发生。在本研究中进行的每个电池测试中都检测到全氟烷基和多氟烷基物质。全氟烷基和多氟烷基物质的浓度在20至130纳克/克烟灰之间。根据数据外推,估计每千克电池芯每氟烷基和多氟烷基物质的释放量为10至60微克。在分析的22种全氟烷基和多氟烷基物质中,全氟丁烷磺酸和全氟丁酸在所有样品中浓度最高。有趣的是,在所有测试中都检测到全氟辛酸,浓度在0.05至0.62纳克/克烟灰之间。这些发现不仅对热失控事件后的净化具有重要意义,而且对于锂离子电池的回收过程也具有重要意义。
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Fire Technology
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