Chemie Der Erde-Geochemistry最新文献

In the Nanling tectono-magmatic belt of South China, the geodynamic settings and tectonic style of Indosinian and Yanshanian magmatism remain debatable. Hereby, an integrated study of zircon U-Pb ages and Lu-Hf isotopes as well as whole-rock elemental and Sr-Nd isotopic compositions was carried out on the Yunlougang (Late Permian) and the Wucun (Late Jurassic) granitic plutons in the Hetai area, located to southwest of the Nanling region. Zircon U-Pb dating yielded emplacement ages of 255 Ma for the Yunlougang biotite monzogranite, 240 Ma for the Yunlougang granodiorite as dyke crosscutting the former, and 155 Ma for the Wucun two-mica granite. The biotite monzogranite and the two-mica granite are strongly peraluminous S-type granites (A/CNK ratios of 1.06–1.21) with a relatively low zircon saturation temperature (631–741 °C). The high initial ⁸⁷Sr/⁸⁶Sr ratios (0.71733 to 0.73383) and low ε_Nd(t) values (−14.6 to −8.69) suggest a crustal protolith. However, the Wucun biotite granite is highly fractionated I-type one (most samples are metaluminous with A/CNK < 1.1) with a relatively high zircon saturation temperature (762–770 °C). Additionally, they exhibit less radiogenic ⁸⁷Sr/⁸⁶Sr_i ratios (0.70724–0.70786) and higher ε_Nd(t) values (−5.34 to −4.94) as well as zircon ε_Hf(t) values of −5.67 to −2.44, suggesting an origin of a crustal source with extra input from mantle. Based on the tectonic history of South China, we infer that the Yunlougang granite occurred in a compressive setting and might be produced by partial melting of a thickened ancient crust during the collision between the South China and the Indochina blocks, while the Wucun complex granites generated in an extensional environment that was influenced by the paleo-Pacific tectonic regime. Combined with previous studies, a NE-oriented I-type granite belt probably existed along the juncture belt of the Yangtze and Cathaysia blocks, which was respond to the foundering rather than rollback of the paleo-Pacific plate that led to the rapid change of the temperature of granite precursor and the involvement of mantle components into the Hetai region.

Geochemical survey data play a critical role in geological studies, mineral exploration, and environmental applications by providing information on geological events and processes such as mineralization and pollution. A typical geochemical survey dataset contains the analysis of multiple elements. For example, the National Geochemical Mapping Project of China comprises 39 major and trace element concentrations. Multiple geochemical maps can be generated by interpolating geochemical samples into raster maps to constitute a geochemical survey data cube in which elements are sorted by their atomic numbers. A geochemical spectrum can be created using these geochemical maps in which each pixel that records geochemical characteristics. In this study, a convolutional neural network (CNN) that considers the geochemical spectrum and spatial pattern of geological objects was employed to mine a geochemical survey data cube, aiming of geological mapping and geochemical anomalies identification associated with mineralization in the eastern part of Hubei Province of China. The results showed that (1) a geochemical survey data cube which built based on various geochemical exploration data provided vital information on mineralization process and the formation of geological features; and (2) a CNN had a strong ability to recognize high-level features in the geochemical survey data cube, and it showed excellent performance in mineral exploration and related geological studies.

The Huxingshan W deposit (0.21 Mt. WO₃ @ 0.3 %) in northeastern Hunan province is located at the western margin of the Jiangnan tungsten belt (JNB), South China. It consists of a series of magma-derived scheelite-quartz-muscovite (SQM) veins in the F1 fault (which contains over 60 % of the W resource), beneath Niutitang Formation (Fm.) carbonate rocks, and above Yijiaqiao Fm. slate (sub-economic), distal from the concealed two-mica granite, which is thought to be responsible for the tungsten mineralization. In this study, we employ LA-ICP-MS zircon and monazite UPb, and muscovite ⁴⁰Ar/³⁹Ar dating to constrain the timing of magmatism and W mineralization at the Huxingshan deposit. Monazite and zircon dating yield coeval ages of 137.6 ± 0.5 Ma and 138.0 ± 0.5 Ma, respectively. Our muscovite ⁴⁰Ar/³⁹Ar dating yielded well plateau ages of 132.9 ± 0.6 Ma, 132.2 ± 0.6 Ma, 130.7 ± 0.5 Ma, and 129.7 ± 0.6 Ma for four representative SQM vein ore samples occurring in the Niutitang Fm. carbonate, F1 fault, and Yijiaqiao Fm. slate, indicating multiple pulses of ore-forming fluid infiltration at Huxingshan. Our age data demonstrate that the two-mica granite emplaced at ∼137.6 Ma, significantly earlier than the pulsed W mineralization at ca. 132.9–129.7 Ma. The lack of spatial and temporal association precludes any genetic link between them. Thus, we infer that the ore-forming fluids likely originated from undiscovered deep plutons and ascended through the F1 fault. Besides, our reliable ages coincide with the two periods of large-scale Mesozoic magmatism and W mineralization phases in the JNB, with the 137.6 Ma magmatism falling within the first phase (150–135 Ma), while the W mineralization (ca.132.9–129.7 Ma) falls within the second phase (130–125 Ma). Of which, the second phase, including the Huxingshan, Xianglushang, Dongping, and Jianfengpo deposits, are situated in the western JNB and show further potential in this region.

This study aims to detect REE geochemical anomalies in relationship to Iron-apatite ores utilizing an image Fusion based on Deep Learning (FDL). The geochemical data was modeled for elements related to Iron-apatite mineralization using multi b Spline B. The results were fusioned in applying the Deep learning method based on pre-trained networks. Wavelet-Number (WN) fractal model classified the best results based on the combination of a two-dimensional Discrete Wavelet Transformation (DWT) signal analysis and a Concentration-Area (C-A) fractal modeling. Sym8 carried the DWT as a selected wavelet pattern for REE based on Stream sediment samples collected from the Tarom region (NW Iran). In addition, the DWT was decomposed by wavelet coefficients at five levels. Furthermore, the DWT data were classified using a fractal-wavelet model to delineate REE anomalies from background levels in this region. Overlayed with the catchment basins model and weighted using the upstream and downstream parts. As a result, the prominent REE source anomalies are located in the southern parts of the study area. The results obtained by the proposed fractal-wavelet modeling are in connection with field check anomaly samples and the rock samples collected from the Iron-Apatite ore deposits.

The Bou Azzer El Grara inlier belongs to the Central Anti-Atlas range, renowned for its mineral deposits. The study carried out on the inlier aims to identify potential areas of cobalt mineralization based on a multi-source methodology of radiometric and remote sensing data processing. The data used includes hydrothermal alteration minerals (argillic, phyllic, propylitic, iron oxides) mapped with Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) imagery using band ratio and principal component analysis (PCA) techniques, potassium enrichment zones through K/eTh and K/eU ratios calculated from radiometric data, as well as geological data (serpentinite outcrops and geological faults). The analytic hierarchy process (AHP) was used to combine the various thematic layers. Validation was carried out through the field studies in several anomalous zones. The mineral prospectivity map generated highlights nine major zones that appear the most favorable for mineralization, some of which coincide with zones in production and others requiring further exploration.

Khajeh-Nezam area is situated within the Bam 1:100,000 geological sheet, SE Iran. The area was the subject of silt geochemical studies and consists of highly prospective Cu, Pb, Ba, and Fe veins and veinlets that demonstrate a northwest-southeast trend. A total of 149 silt samples were collected from the area and analyzed for 7 elements (As, Cu, Mo, Pb, Zn, Sb, Ba) using Inductively Coupled Plasma-Optical Emission Spectrometry. Univariate-multivariate statistical analysis the majority of variables demonstrate a distribution that is slightly too moderately positively skewed, which can be accurately explained using a log-normal model. Only Cu, Zn, and Pb demonstrate a normal distribution. The number-size (N-S) fractal model show that. The variables can be classified into two main groups. The first group comprises the main ore-forming elements, namely Cu, Ba, As, and Sb, which are associated with the epithermal system. On the other hand, Mo, Pb, and Zn demonstrate a stronger affiliation with vein and veinlet mineralization that could be linked to the margin of a possible hidden porphyry system. The geochemical halo in the southwestern part of the study area, which overlaps with volcanic rocks, has experienced significant alterations attributed to local intrusions, leading to a level of modification. A secondary weak anomaly, of relatively lesser significance, is observed in Pb, Zn, and Mo. Although these elements are not the primary constituents of the ore, they serve as pathfinder elements in marginal copper porphyry. The results obtained from the study have been utilized to identify concealed ore bodies using the classes defined by N-S classification model. Fieldwork conducted in the area confirms the presence of Fe oxide veins and veinlets that contain copper mineralization, along with carbonate Pb and Cu minerals. Various types of alteration have been identified, including argillic alteration accompanied by quartz and hematite in the vicinity of the veins and veinlets. The findings serve as probable evidence for the existence of a new copper porphyry system in the study area.

In this study, a new process of pre-flotation decarbonization‑lead flotation‑zinc flotation was proposed to recover valuable metals from a lead‑zinc ore in Guizhou by beneficiation and to determine a reasonable and economic beneficiation process. The results of the study demonstrate that the novel process aids in the flotation of lead and zinc ores in two ways: (1) pre-decarbonization using MIBC (methyl isobutyl carbinol) and kerosene synergistically achieved the lowest loss of lead recovery of 1.94 % and zinc recovery of 1.14 % in the decarbonized product. (2) the successful separation and retrieval of lead and zinc metals were accomplished via a preferential flotation technique, using several combinations of reagents. This procedure yielded a lead recovery rate of 87.64 % and a zinc recovery rate of 94.09 %.

The South China Block (SCB) and Proto-Japan (includes Honshu, Kyushu, and Shikoku) are the important geological units in Eastern Eurasia. Their relationship in the Early Mesozoic is contentious, understanding it is crucial for understanding East Asia's evolutionary history and reconstructing the paleo-continent. We present a detrital zircon and provenances study of the Late Triassic Xiaoping Formation, the Genkou Group, and the Wenbinshan Formation on the southeast margin of the SCB. All have similar detrital zircon UPb age distributions, and three main age groups: 200–300 Ma, 400–500 Ma, and 700–1000 Ma. The primary provenances of the study area are the Yunkai Massif to the west, Hainan Island to the south, and northern Fujian, eastern Hunan, Wuyi Terrane, and Jiangnan Orogen to the north. The distribution of detrital zircons in the southeast margin of the SCB and Proto-Japan is further compared by applying various methods such as multidimensional scaling and Chi-square tests, which shows significant differences in the age distribution patterns of detrital zircons between the two areas. Further provenance analysis reveals significant differences between the southeast margin of the SCB and Proto-Japan during the Late Triassic, suggesting a lack of affinity between the two regions. Therefore, the Late Triassic Proto-Japan likely not located to the southeast margin of the SCB and moving closer to its current position.

The tectonic settings and petrogenesis of Neoproterozoic gabbroic rocks are critical to understand the formation and evolution of the Arabian-Nubian accretionary orogen. We present the whole-rock chemistry and amphibole chemistry of the Gattar gabbro in the northern Eastern Desert of Egypt to better understand the formation of this part of the orogen. The Gattar gabbro is composed of variable proportions of amphibole and plagioclase, which imply the hydrous nature of its parent magma. Trace element patterns of the gabbro and the calculated liquids in equilibrium with its amphibole show enrichment in large ion lithophile elements relative to high field strength elements, which indicate that the Gattar magma formed above a subduction zone. The low abundances of high field strength element in the gabbro are consistent with a depleted mantle source similar to intra-oceanic island arc rocks. However, the high Nb/La ratio of the Gattar gabbro (0.46–10.71) is reminiscent to Nb-enriched mafic rocks from subduction settings. The amphibole chemistry suggests that the hydrous magma of the gabbro crystallized at temperature and pressure estimates of 930 °C and 8 kbar and under oxidizing conditions. The Gattar gabbro is affiliated with the Tonian-Cryogenian arc-related mafic gabbro, which is rarely recorded in this northernmost segment of the Arabian-Nubian orogen. In terms of comparison with the Ediacaran post-orogenic gabbros from the northern Eastern Desert, the Gattar gabbro shows lower concentrations of incompatible elements and Ti/V ratio.

The mantle section of the Late Neoproterozoic Tays ophiolite in the Arabian Shield consists principally of thoroughly serpentinized peridotite with characteristics typical of depleted mantle protoliths from a fore-arc environment. The serpentinite is altered along shear zones and thrust planes to gold-bearing listvenite bodies of various sizes. These bodies are divided into carbonate listvenite and silica‑carbonate listvenite; they may be dyke-like or lenticular in form, and are yellowish-brown, reddish-brown, or greyish in outcrop. Carbonate listvenite expresses schistose deformation fabrics concordant to fabric in the host serpentinite, whereas silica‑carbonate listvenite is undeformed at field scale and contains a generation of undeformed minerals at thin-section scale. Silica‑carbonate listvenite contains Cr-rich muscovite (fuchsite) and base-metal sulfides and is enriched in Zn, Pb, Cu, Ag, and Au along with SiO₂. The transformation of serpentinite along shear zones to different types of listvenite reflects successive episodes of fluid-mediated metasomatism. Carbonate listvenite develops first, driven by infiltration of CO₂–bearing fluids during serpentinization of the original fore-arc peridotite. Silica‑carbonate listvenite marks a later episode associated with infiltration of K-bearing, SiO₂-saturated fluids released during emplacement of the ophiolite. Listvenitization in the Tays serpentinite concentrated gold in sub-economic to economic extents, with concentrations increasing from host serpentinite (2–4 ng/g) to carbonate listvenite (267–937 ng/g) to silica‑carbonate listvenite (1717–3324 ng/g).