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A review of some metal-oxide based nanocomposites for photocatalytic treatment of wastewater 金属氧化物基纳米复合材料光催化处理废水的研究进展
Q2 Engineering Pub Date : 2023-10-23 DOI: 10.1088/2043-6262/ad002b
Shivani Gupta, Himanshu Narayan, Rakesh K Jain
The photocatalytic activity of nanosized composite materials based on some common metal-oxides has been reviewed in the context of their potential application in the treatment of wastewater. A large volume of published data has been systematically analysed to understand the process of photocatalytic degradation under various combinations of the material, dye and source of excitation. The quantities taken into consideration for the analysis are the average particle size, apparent rate constant ( kobs ), and maximum percent degradation achieved. Semiconducting titanium dioxide (TiO2), zinc oxide (ZnO) and copper oxide (CuO) were identified as the three best photocatalysts that can be used after some meticulous modifications, in the treatment of wastewater under visible light irradiation. It was also concluded that the best performance can be obtained with photocatalyst nanoparticles (NPs) of average size in the range of 20 to 70 nm. Among the photocatalysts reviewed, the best degradation was produced by bismuth-sulphur co-doped TiO2 NPs of around 7 nm average particle size. With a rate constant as high as 6.08 × 10−2 min−1, this material produced nearly 100% degradation of Indigo Carmine within 40 min under visible light. The ZnO NPs of 40–70 nm average size degraded nearly 99% of Malachite green dye under ultraviolet (UV) irradiations in just 40 min with a very high rate constant of 11.10 × 10−2 min−1. CuO NPs, synthesised through green methods, produced nearly 95% degradation of Methylene blue (MB) in 2 h, with a rate constant of 2.62 × 10−2 min−1 under solar irradiation.
摘要综述了几种常见金属氧化物基纳米复合材料的光催化活性及其在废水处理中的潜在应用。系统分析了大量已发表的数据,以了解在各种材料、染料和激发源组合下的光催化降解过程。在分析中考虑的量是平均粒径、表观速率常数(k / b / s)和最大降解百分比。半导体二氧化钛(tio2)、氧化锌(ZnO)和氧化铜(CuO)是三种最好的光催化剂,经过一些细致的修饰,可以用于可见光照射下废水的处理。结果表明,平均粒径在20 ~ 70 nm的光催化剂纳米颗粒性能最好。在所综述的光催化剂中,铋-硫共掺杂tio2纳米粒子的降解效果最好,其平均粒径约为7 nm。在可见光下,该材料在40分钟内降解靛蓝胭脂红,降解速率高达6.08 × 10−2 min−1。40 ~ 70 nm的ZnO纳米粒子在紫外照射下降解了近99%的孔雀石绿染料,降解速率常数高达11.10 × 10−2 min−1。通过绿色方法合成的CuO NPs在2 h内对亚甲基蓝(MB)的降解率接近95%,在太阳照射下的速率常数为2.62 × 10−2 min−1。
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引用次数: 0
A fast fabrication technique of FTO/AuNPs electrochemical electrodes for on-site arsenic (III) detection 现场砷(III)检测用FTO/AuNPs电化学电极的快速制备技术
Q2 Engineering Pub Date : 2023-10-19 DOI: 10.1088/2043-6262/ad010a
Van Vien Nguyen, Thu Hien Hoang Nguyen, Canh Minh Thang Nguyen, Hoang Long Ngo, Thanh Tung Nguyen, Viet Hai Le, Thai Hoang Nguyen
Abstract In this study, gold nanoelectrodes were fabricated via electrical deposition of gold nanoparticles (NPs) onto FTO electrodes using cyclic voltammetry (CV) in 1 M H 3 PO 4 solution at a scan rate of 100 mV.s −1 in the potential range of 0–1.4 V and −0.5–0.6 V. The fabricated FTO/AuNP electrodes were characterised by UV–vis, scanning electron microscope, energy-dispersive X-ray spectroscopy, as well as CV and linear sweep voltammetry; the presence of gold on the electrode surface and its electrochemical properties were confirmed towards hydroquinone. The electrodes with the best electrochemical properties were chosen for arsenic(III) determination. The fabricated FTO/AuNP electrodes in the potential range of 0–1.4 V exhibited the high sensitivity with limit of detection (LOD) of 3.04 ppb and limit of quantitation (LOQ) of 9.23 ppb, whereas the FTO/AuNP electrode fabricated in the potential range of −0.5 V–0.6 V displayed the enhancement sensitivity with LOD = 0.623 ppb and LOQ = 1.89 ppb.
摘要本研究采用循环伏安法(CV)在100 mV扫描速率下,在1 M h3po4溶液中电沉积金纳米粒子(NPs)到FTO电极上制备金纳米电极。在0-1.4 V和- 0.5-0.6 V的电位范围内,s−1。采用紫外可见光谱、扫描电镜、能量色散x射线能谱、CV和线性扫描伏安法对制备的FTO/AuNP电极进行了表征;实验证实了金在电极表面的存在及其对对苯二酚的电化学性能。选择电化学性能最好的电极进行砷(III)的测定。在0 ~ 1.4 V电位范围内制备的FTO/AuNP电极灵敏度高,检出限(LOD)为3.04 ppb,定量限(LOQ)为9.23 ppb,而在- 0.5 V ~ 0.6 V电位范围内制备的FTO/AuNP电极灵敏度增强,LOD = 0.623 ppb, LOQ = 1.89 ppb。
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引用次数: 0
Preparation of LiNbO3 nanoparticles by green synthesis laser ablation in water 水中绿色合成激光烧蚀制备纳米LiNbO3
Q2 Engineering Pub Date : 2023-10-18 DOI: 10.1088/2043-6262/ad0106
Marwa S Alwazny, Raid A Ismail, Evan T Salim
Abstract The use of LiNbO 3 nanoparticles in nonlinear applications is attractive and promising. The particle size and morphology of LiNbO 3 are the key parameters affecting their application. In this study, spherical nanoparticles of lithium niobate were synthesised by nanosecond Nd:YAG laser ablation in water. The polycrystalline, rhombohedral structure of the synthesised LiNbO 3 nanoparticles with x-ray diffraction experiments was verified. The bandgap energy of colloidal LiNbO 3 nanoparticles varied between 4.25 and 4.9 eV based on the laser fluence, according to the optical characteristics. The photoluminescence (PL) reveals that the emission peaks are centered at 293, 300, 305, and 309 nm for samples prepared at 1.3, 1.6, 2.0, and 2.2 J cm −2 /pulse, respectively. The transmission electron microscope investigation confirmed the formation of spherical nanoparticles with an average size ranging from 18 to 34 nm. Raman studies on nanoparticles synthesised at various laser fluences are being conducted.
摘要纳米linbo3在非线性领域的应用前景广阔。linbo3的粒度和形貌是影响其应用的关键参数。在本研究中,采用纳秒Nd:YAG激光烧蚀在水中合成了球形铌酸锂纳米颗粒。通过x射线衍射实验验证了合成的linbo3纳米颗粒的多晶、菱形结构。根据光学特性,胶体linbo3纳米颗粒的带隙能量随激光通量变化在4.25 ~ 4.9 eV之间。在1.3、1.6、2.0和2.2 J cm−2 /脉冲下制备的样品的光致发光峰分别集中在293、300、305和309 nm处。透射电子显微镜观察证实形成了平均尺寸为18 ~ 34 nm的球形纳米颗粒。在各种激光影响下合成纳米粒子的拉曼研究正在进行。
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引用次数: 0
Two–step pulsed laser ablation for preparation NiO@ZnO core-shell nanostructure and evaluation of their antibacterial activity 两步脉冲激光烧蚀法制备NiO@ZnO核壳纳米结构及其抗菌活性评价
Q2 Engineering Pub Date : 2023-10-18 DOI: 10.1088/2043-6262/ad010c
Hadeel J Imran, Kadhim A Aadim, Kadhim A Hubeatir
Abstract The excessive use of antibiotics led to the appearance of many strains of resistant bacteria, so it became necessary to use new antibacterial techniques. The aim of this work is the synthesis of novel core–shell NPs (NiO@ZnO) for antibacterial applications. A novel NiO@ZnO core–shell nanomaterial with a nanosize and uniform shape has been synthesised using the two-step pulsed laser ablation in liquid (PLAL) method. The first step is the laser ablation of the nickel target and the production of NiO NPs (core) colloidal, followed by the second step, the ablation of ZnO (shell) inside NiO NPs colloidal. The transmission electron microscopy results approve the formation of NiO@ZnO core–shell NPs with an average particle size of 54.4 nm for NiO particles and 60.7 nm for the NiO@ZnO core–shell. The antibacterial activity was examined against the pathogenic bacterial strains E. coli and S. aureus . We found that in the case of NiO, the inhibition rates were 62.4 and 59.2% for E. coli and S. aureus , respectively. While with NiO@ZnO NPs, this result was improved to 74.8% for E. coli and 71.2% for S. aureus . So, it was found that using the core–shell NPs increased the antibacterial activity of NPs, and the use of NiO NPs and core approved their effect as antibacterial agents due to their special properties. This behaviour is primarily because of the accumulation of the NiO@ZnO NPs on the surface of the bacteria, which leads to cytotoxic bacteria and a relatively increased ZnO, causing cell death. Furthermore, the use of a NiO@ZnO core–shell material will inhibit the bacteria from nourishing themselves on the culture medium. Therefore, core shelling metal oxides with another metal oxide or other material improves their antibacterial activity compared with using them alone.
摘要抗生素的过度使用导致了许多耐药菌的出现,因此有必要采用新的抗菌技术。这项工作的目的是合成新的核-壳NPs (NiO@ZnO)抗菌应用。采用两步脉冲激光烧蚀(PLAL)方法合成了一种具有纳米尺寸和均匀形状的新型NiO@ZnO核壳纳米材料。第一步是激光烧蚀镍靶,制备NiO NPs(核)胶体,第二步是烧蚀NiO NPs胶体内部的ZnO(壳)。透射电镜结果证实了NiO@ZnO核壳NPs的形成,NiO颗粒的平均粒径为54.4 nm, NiO@ZnO核壳NPs的平均粒径为60.7 nm。对病原菌大肠杆菌和金黄色葡萄球菌进行了抑菌活性测定。我们发现在NiO的情况下,对大肠杆菌和金黄色葡萄球菌的抑制率分别为62.4%和59.2%。而使用NiO@ZnO NPs时,大肠杆菌和金黄色葡萄球菌的这一结果分别提高到74.8%和71.2%。因此,我们发现使用核-壳NPs可以提高NPs的抗菌活性,并且NiO NPs和核的使用由于其特殊的性能而证实了它们作为抗菌剂的效果。这种行为主要是由于NiO@ZnO NPs在细菌表面的积累,导致细胞毒性细菌和相对增加的ZnO,导致细胞死亡。此外,使用NiO@ZnO核壳材料将抑制细菌在培养基上滋养自己。因此,与另一种金属氧化物或其他材料一起使用核壳金属氧化物比单独使用核壳金属氧化物提高了核壳金属氧化物的抗菌活性。
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引用次数: 0
Green synthesis of recyclable reduced graphene oxide-gold nanocatalyst using Alstonia scholaris: Applications in waste water purification and microbial field 绿色合成可回收还原型氧化石墨烯-金纳米催化剂:在废水净化和微生物领域的应用
Q2 Engineering Pub Date : 2023-10-18 DOI: 10.1088/2043-6262/ad0109
Piu Das, Bapan Bairy, Sanjukta Ghosh, Raktim Ghosh, Somasri Dam, Avijit Ghorai, Moni Baskey Sen
Abstract The green synthetic approaches are the alternative methods for the preparation of various types of nanoparticles to keep sustainable evolution. A novel green synthesis of gold- reduced graphene oxide nanocomposites was conducted through simple heating method using Alstonia scholaris (A. scholaris) bark extract. There are several techniques that confirm the formation of the nanocomposites for synthesis of gold nanoparticles on reduced graphene oxide (RGO), such as X-ray diffraction (XRD), UV–visible spectroscopy (UV–vis) and Fourier transformed infrared spectroscopy (FT-IR). The size distributions of the gold nanoparticles (Au NPs) grown on RGO surface was measured using two different methods: particle distribution study and transmission electron microscopy (TEM) image. These two methods provided similar size distribution which is around 5–8 nm. Subsequently, the catalytic performance was evaluated by 4-nitro aniline (4-NA). The photocatalytic activities were investigated using different organic hazardous dyes, such as methylene blue (MB), methyl orange (MO) and the change of photocatalytic behaviour was shown by varying the catalyst amount and pH. The chemical oxygen demand (COD) analyses for complete removal of organic dye were carried out using the two nanocomposite samples. To perceive the effect on different bacterial strains, antibacterial and antiprotozoal studies have been carried out with this nanocomposite.
绿色合成途径是制备各种类型纳米粒子以保持可持续进化的替代方法。以金楸树皮提取物为原料,通过简单的加热法制备了一种新型的金还原性氧化石墨烯纳米复合材料。有几种技术可以证实在还原氧化石墨烯(RGO)上合成金纳米颗粒的纳米复合材料的形成,如x射线衍射(XRD),紫外可见光谱(UV-vis)和傅里叶变换红外光谱(FT-IR)。采用颗粒分布研究和透射电子显微镜(TEM)成像两种不同的方法测量了生长在还原氧化石墨烯表面的金纳米颗粒(Au NPs)的尺寸分布。两种方法的尺寸分布相似,均在5 ~ 8 nm左右。随后,用4-硝基苯胺(4-NA)评价了催化性能。考察了亚甲基蓝(MB)、甲基橙(MO)等不同有机有害染料对纳米复合材料光催化活性的影响,并通过催化剂用量和ph的变化考察了纳米复合材料光催化性能的变化。为了了解这种纳米复合材料对不同细菌菌株的影响,研究人员利用这种纳米复合材料进行了抗菌和抗原虫研究。
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引用次数: 1
Simple single reactor synthesis of nickel (II)-cobalt (II) ferrite composites with biochar and their photocatalytic properties 生物炭镍(II)-钴(II)铁氧体复合材料的单反应器合成及其光催化性能
Q2 Engineering Pub Date : 2023-10-17 DOI: 10.1088/2043-6262/ad0107
N P Shabelskaya, A V Arzumanova, Yu A Gaidukova, S I Sulima, E V Vasileva, E A Yakovenko
Abstract The paper proposes a simple one-stage synthesis of ferrite/biochar composites based on oxide compounds of Ni x Co 1-x Fe 2 O 4 ( х = 0, 0.5, and 1). The obtained materials were characterised using x-ray diffraction patterns, Fourier transform infrared (FTIR) spectrometry, electron microscopy, Scherrer and Williamson-Hall methods. The high photocatalytic activity of the synthesised materials in the process of methyl orange oxidative degradation at hydrogen peroxide presence has been established. It is noted that the highest catalytic activity is exhibited by the composite material based on cobalt (II) ferrite and sunflower biochar: in their presence, it is possible to achieve 100% removal of the dye after 120 and 90 min, respectively. A possible mechanism of the dye decomposition process is discussed.
摘要:本文提出了一种简单的一步合成基于Ni x Co 1-x fe2o (x = 0,0.5和1)氧化物的铁氧体/生物炭复合材料的方法。采用x射线衍射图,傅里叶变换红外光谱(FTIR),电子显微镜,Scherrer和Williamson-Hall方法对所得材料进行了表征。合成的材料在过氧化氢存在下对甲基橙氧化降解过程具有较高的光催化活性。值得注意的是,基于钴(II)铁氧体和向日葵生物炭的复合材料表现出最高的催化活性:在它们存在的情况下,分别在120分钟和90分钟后可以实现100%的染料去除。讨论了染料分解过程的可能机理。
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引用次数: 0
Potential of nanotheranostic zeolitic imidazolate frameworks in cancer management 纳米治疗咪唑分子筛框架在癌症治疗中的潜力
Q2 Engineering Pub Date : 2023-10-17 DOI: 10.1088/2043-6262/ad002a
Abduladheem Turki Jalil, Mohanad Ali Abdulhadi, Lubna R Al-Ameer, Doaa Saadi Kareem, Muna S Merza, Rahman S Zabibah, Ibrahem Galib
Abstract Cancer is a major threat to human health, and it is still the leading cause of death from disease. Due to how quickly nanomedicine is developing, it is thought that nanoscale metal–organic frameworks (MOF) could be used in the treatment and biomedical imaging of many types of cancer. More and more researchers are interested in zeolite imidazole framework (ZIF)−8 because it has a high porosity, a large specific surface area, and reacts to changes in pH. Understanding the properties of nanomaterials and how tumour works requires a complex and thorough look at how ZIF-8 nanoparticles (NPs) are made, how they can be changed, and how drugs are loaded into them. We mostly looked at the research that came out in the last three years, summed up how their use in imaging and treating tumour has changed, and talked about the pros and cons of using ZIF-8 NPs for cancer theranostic now and in the future. As a MOF material with a lot of potentials, ZIF-8 is likely to be used in more therapeutic systems in the future and to continue to help with all parts of tumour therapy and diagnosis.
癌症是人类健康的主要威胁,也是导致人类疾病死亡的首要原因。由于纳米医学的快速发展,人们认为纳米金属有机框架(MOF)可以用于多种类型癌症的治疗和生物医学成像。越来越多的研究人员对沸石咪唑框架(ZIF) -8感兴趣,因为它具有高孔隙率,大比表面积,并对ph变化作出反应。了解纳米材料的性质以及肿瘤如何工作需要对ZIF-8纳米颗粒(NPs)的制造方式,如何改变以及如何将药物装载到其中进行复杂而彻底的研究。我们主要看了过去三年的研究,总结了它们在成像和治疗肿瘤方面的应用是如何变化的,并讨论了现在和未来使用ZIF-8 NPs进行癌症治疗的利弊。作为一种潜力巨大的MOF材料,ZIF-8在未来很有可能在更多的治疗系统中得到应用,并继续在肿瘤治疗和诊断的各个方面发挥作用。
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引用次数: 0
Recent developments in phycosynthesis of zinc oxide nanoparticles for biomedicine and environmental applications 生物医学和环境应用中氧化锌纳米颗粒藻合成的最新进展
Q2 Engineering Pub Date : 2023-10-12 DOI: 10.1088/2043-6262/acf2ef
Shrutika Chaudhary, Navneeta Bharadvaja
Abstract Nanoparticles are becoming integral components in every sector considering their unmatched properties with their counter bulk material. However, in the last couple of decades, several reports suggested metal nanoparticles are toxic to biological systems either directly or indirectly. Zinc oxide nanoparticles (ZnO NPs) possess excellent optical, electrical, food packaging properties, etc. Although, the use of chemically toxic reducing agents for the synthesis of ZnO NPs induces toxicity. Therefore, biogenic synthesis of ZnO NPs has been exploited using different sources such as plant leaves, stems, fungi algae, etc NPs synthesised via these methods are biodegradable, biocompatible, low toxic, and highly effective in different applications. Algae being widely available and easy to harvest becomes a suitable candidate for ZnO NPs synthesis. Algae mediated/phycosynthesis is a technique where algae accumulate zinc oxides and reduce them to zinc ions to form ZnO NPs. The ease of synthesis of ZnO NPs using this method produces NPs in abundant quantity and of variable sizes. Intracellular and extracellular syntheses are two mechanisms of phycosynthesis of ZnO NPs. These ZnO NPs have several beneficial properties like antimicrobial, anti-cancerous, antioxidant, larvicidal, antidiabetic, etc. Additionally, it has low scale-up cost, and low energy input. This article provides detailed information about the routes of phycosynthesis of ZnO NPs using different algal strains, properties, and their potential application in the biomedical field and environmental remediation.
纳米粒子正成为每个领域不可或缺的组成部分,因为它们具有与它们的反块材料无与伦比的性能。然而,在过去的几十年里,一些报告表明金属纳米颗粒对生物系统有直接或间接的毒性。氧化锌纳米颗粒(ZnO NPs)具有优异的光学、电学、食品包装等性能。虽然使用化学毒性还原剂合成ZnO NPs会引起毒性。因此,利用植物叶片、茎、真菌、藻类等不同来源的生物源合成ZnO纳米粒子具有可生物降解、生物相容性好、低毒、高效等特点。藻类资源丰富,易于收获,是合成ZnO NPs的理想材料。藻类介导/藻合成是藻类积累氧化锌并将其还原为锌离子形成ZnO纳米粒子的一种技术。该方法制备的ZnO纳米粒子数量丰富,尺寸多变。胞内合成和胞外合成是氧化锌NPs的两种植物合成机制。这些ZnO NPs具有抗菌、抗癌、抗氧化、杀幼虫、抗糖尿病等多种有益特性。此外,它具有低规模成本和低能源投入。本文详细介绍了不同藻类菌株合成ZnO NPs的途径、性质及其在生物医学领域和环境修复中的潜在应用。
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引用次数: 0
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Advances in Natural Sciences: Nanoscience and Nanotechnology
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