Glass Physics and Chemistry最新文献

Thulium/holmium co-doped bismuth borotellurite glass have been prepared using melt quenching technique. All the prepared glasses characterized using X-ray Diffraction (XRD) and Fourier-transform infrared (FTIR) spectroscopy at room temperature. There is no distinct peak in the XRD patterns over the observed range of 10° to 90°, indicating that all prepared glasses are amorphous. FTIR study reveals that the glass structure is composed of by TeO₃, TeO₄, BO₄, BO₃, BiO₃, and BiO₆ structural units. According to the bridging and non-bridging oxygen, the impact of the Ho₂O₃ addition was demonstrated by the calculated ratio of BO₄ to TeO₄ in the structural network. Bridging oxygen formation was proposed by the calculated ratio of BO₄ to TeO₄ increasing in along with the increase in Ho₂O₃ concentration (x = 0 to 1.0 mol %). Additionally, the declining ratio of BO₄ to TeO₄ (x = 1.5 to 2.5 mol %) explains the formation of non-bridging oxygen.

The synthesis of lithium lead borosilicate bismuth vanadate glasses with varying Tl₂O₃ concentrations (between 0 to 5.0 mol %) was achieved through the implementation of the melt quenching technique. A comprehensive analysis has been conducted to examine the electrical and dielectric properties over a broad spectrum of frequencies (10²–10⁶ Hz) and temperatures (303–573 K). According to the findings of conductivity studies, mixed conduction (both electronic and ionic) occurs in the produced glasses. As the concentration of Tl₂O₃ increases in the base glass, the dielectric properties, including dielectric loss, dielectric constant, and ac conduction, exhibit a decreasing trend. An increasing number of V⁵⁺ ions has been identified as being involved in the formation of networks near crystal structures of VO₅. The quantitative study of ac conductivity and dielectric property data revealed that increasing the concentration of Tl₂O₃ in the glass network increases the insulating character of the glass. In the glass structure, the migration of thallium ions to tetrahedral coordination from octahedral coordination occurs, accompanied by a de-clustering effect of these ions.

Production of porcelain tiles has been increasing rapidly with the increasing demand for both technological and aesthetic features for years. Especially tiles produced with digital applications attract much more attention. Digital glazes (glass-ceramic) can be matte or glossy features. In this study, the effect of the SiO₂/Al₂O₃ ratio on technological properties was examined by keeping other oxide ratios constant in matte glaze compositions for digital applications. Seven glass ceramic compositions were prepared and trials were carried out under industrial conditions. The microstructure was measured with the use of a SEM, phases were determined by XRD, and sintering behavior was characterized by heating microscopy. The color and gloss of glazes were measured using a spectrophotometer and a gloss meter. As the SiO₂/Al₂O₃ ratio decreased, especially the amount of anorthite crystal increased, which resulted in the formation of more matte glaze surfaces. Glaze whiteness and hardness increased due to the crystal formation. As the amount of Al₂O₃ increased, the softening and melting temperature points of the glazes also increased. It has been determined that surface properties can be modified for digital applications by changing the SiO₂/Al₂O₃ ratio.

Compositions of heat-resistant organosilicate cold-curing composites for nuclear power plants based on OS 51-03 are developed. Deactivation coefficients are determined.

The possibility of synthesizing supramolecular composite organo-inorganic materials based on cobalt(II) ferrite and biochars from rice husk and sunflower husk is studied. It is established that the morphology of the biochar determines the structural characteristics of the composite. The synthesized materials are characterized by X-ray phase analysis, BET, and scanning electron microscopy. Cobalt(II) ferrites crystallize on the surface of the carbon carrier in the form of a film, whose crystallite size is 80–96 nm, which is lower than for CoFe₂O₄, obtained using sol-gel technology. It is established that the synthesized composites exhibit significant catalytic activity in the process of decomposition of hydrogen peroxide and sorption of chromium(VI) compounds from an aqueous solution. The increase in the sorption capacity is associated with the formation of the Fenton system Fe³⁺/Fe²⁺. The obtained results can be used for the synthesis of innovative products from agricultural waste and their use in water treatment processes.

The study object is borosilicate glass with separate and combined inclusion of Cs and/or Sr oxides in amounts of 5, 10 and 15 wt %. This can be used in the fractionation scheme of liquid high-level waste from the spent nuclear fuel reprocessing. The main attention was paid to their compliance with the quality criteria established in the regulatory document NP-019-15, when studying the physicochemical, thermophysical and mechanical properties of synthesized glass. The glass structure changes slightly relative to the structure of the initial glass frit according to Raman spectroscopy. The exception was glass containing 15 wt % Cs₂O, which contained new bands in the Raman spectra, in addition there were an increase in its molar volume and a decrease in the glass transition temperature. However, these changes had virtually no effect on the thermophysical and mechanical characteristics. The obtained data showed that the glass properties in the studied range of Cs and/or Sr oxides concentrations satisfy the current quality criteria for the product in the form of ¹³⁷Cs and ⁹⁰Sr vitrified concentrates after fractionation of liquid HLW.

The temperature dependence of the microhardness of Ag₂S is measured in the temperature range of the transition from the monoclinic to the cubic crystalline modification. The obtained experimental data are discussed, taking into account the anomalously high plasticity of this compound and the superionic nature of its cubic modification.

Fly ash is the most abundantly produced waste material from thermal power plants and steel industries. Management of this fly ash is a tedious task as it creates economic and environmental problems for society. One popular way to recycle fly ash is to produce fly ash-based bricks for construction. However, as the binding capacity of fly ash is significantly less, it pollutes the surrounding environment of the working site. Fly ash brick is usually made using cement as a binder by cold compaction technique. Cement manufacturing is an expensive industrial process that releases carbon dioxide into the atmosphere. Therefore, the scrap glass powder is used here as an alternate binder. The glass powder is mixed with the fly ash to prepare glass-ceramic brick to reduce the brick firing temperature and trap the pollutants within the silica-rich glassy phase. The glass used in this work was the scrap glass collected from the chemical laboratory of the ceramic department (NIT Rourkela). Different batches were studied concerning the glass percentage and fly ash percentage. The fabricated green bodies were sintered at 900 and 1000°C for 2 h. X-ray diffraction study revealed the presence of mullite and cristobalite phases in the sintered brick. FESEM microstructure confirms the presence of the glassy phase in the sintered brick. It is found that with an increase in glass content, the bulk density increases, and apparent porosity decreases. The mechanical properties of the glass-ceramic composite bricks are also superior to the fly ash brick.

The kinetics of silicon dioxide shell formation on metal nanoparticles by tetraethoxysilane hydrolysis in the absence of catalysts is studied. The possibility of stabilizing Au–Ag alloy nanoparticles by coating with a 5 nm thick silicon dioxide shell is shown. A model of core–shell nanoparticles consisting of a metal core and a multilayer SiO₂ shell, having a phosphor based on water-soluble porphyrin encapsulated between its layers, is proposed. It is shown that encapsulation in a multilayer SiO₂ shell leads to an increase in the intensity of porphyrin luminescence.

Research on PbSb₂Te₄ composite material samples, obtained by the Czochralski method, is continued. The multiphase structure of the material is confirmed. Based on the analysis of X-ray studies, the predominance of PbSb₂Te₄ (70–80%) and Sb₂Te₃ (20–30%) phases is found. Traces of (CuSb)Te₂ phases with a rhombohedral structure and a hexagonal phase of Sb₂Te₂ are detected. The carrier concentration is reduced by doping the samples with copper; the impurity atoms are located in the Van der Waals gap between the layers of the main phases. With the copper content in the initial charge increasing from 0.5 to 1 at %, the carrier concentration does not decrease further.