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An Online Visualization Model of the Slag Crust Thickness on the Copper Staves of the Blast Furnace 高炉铜棒渣壳厚度在线可视化模型
IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-08-06 DOI: 10.1007/s11837-024-06803-z
Dongliang Liu, Chunhui Song, Chengzhi Li, Zhengliang Xue

The slag crust thickness on the hot surface of the copper cooling staves in the high thermal load areas of a blast furnace is crucial for the safe operation and long campaign of the blast furnace. In this study, a heat transfer model for the slag crust and the copper cooling staves in a blast furnace is established. The temperature distribution in the slag crust and copper cooling staves is calculated and the temperature variation in the copper cooling stave with the change of slag crust thickness is also studied. The temperature measurement data of the copper cooling staves are fitted with the corresponding slag crust thicknesses, and an online model for calculating the slag crust thickness is established. The slag crust thickness is displayed in the form of a contour map by unfolding the slag crust and the copper cooling staves along the circumferential direction of blast furnace, by which the visualization of slag crust thickness distribution and the variation in slag crust thickness with time can be achieved. This online visualization model can help operators accurately judge the locations where the slag crust thickness fluctuates severely, and take timely and effective measures to guarantee the normal operation condition.

高炉高热负荷区铜冷却板热表面的渣壳厚度对高炉的安全运行和长期运行至关重要。本研究建立了高炉内渣壳和铜冷却条的传热模型。计算了渣壳和铜冷却条的温度分布,并研究了铜冷却条的温度随渣壳厚度变化的情况。将铜冷却条的温度测量数据与相应的渣壳厚度进行拟合,建立了在线计算渣壳厚度的模型。通过沿高炉圆周方向展开渣壳和铜冷却棒,以等高线图的形式显示渣壳厚度,从而实现渣壳厚度分布和渣壳厚度随时间变化的可视化。这种在线可视化模型可以帮助操作人员准确判断渣壳厚度波动严重的位置,并及时采取有效措施保证正常的操作状态。
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引用次数: 0
Effect of Cu Addition on Abnormal Grain Growth in a FeMnAlNi-Based Superelastic Alloy 添加铜对铁锰铝镍超弹性合金异常晶粒长大的影响
IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-08-06 DOI: 10.1007/s11837-024-06776-z
Zhenxin Li, Yang Zhang, Haosheng Wang, Pengfei Dai, Guangda Zhao, Zhongwu Zhang

Grain size has a significant impact on the superelasticity of alloys. Large-sized grains show superior superelastic properties because the grain boundaries are minimized and the grain constraints caused by triple junctions are reduced. Cyclic heat treatment (CHT) is commonly employed to generate subgrains, whose energy can be consumed to induce abnormal grain growth (AGG) and obtain large-sized grains. In this paper, the effects of adding Cu on the subgrain characteristics during AGG and microstructural evolution of FeMnAlNi-based superelastic alloys were systematically investigated. The addition of Cu reduced the temperature at which the γ phase precipitates and altered the morphology of the γ phase. After the dissolution of the refined γ phases, the average subgrain size became smaller and misorientation increased. These characteristic subgrain changes improved the driving force for AGG and accelerated the grain boundary migration rate. Due to the addition of Cu, the maximum grain size reached 28.2 mm. This study provides a new method for the preparation of FeMnAlNi-based superelastic alloys with large-sized grains.

晶粒大小对合金的超弹性有重大影响。大尺寸晶粒显示出优异的超弹性特性,因为晶界最小化,三重交界造成的晶粒约束减少。循环热处理(CHT)通常用于产生亚晶粒,其能量可用于诱导异常晶粒长大(AGG)并获得大尺寸晶粒。本文系统研究了添加 Cu 对 AGG 期间亚晶粒特征的影响以及铁锰铝镍基超弹性合金的微观结构演变。Cu 的加入降低了 γ 相析出的温度,并改变了 γ 相的形态。精炼的 γ 相溶解后,平均亚晶粒尺寸变小,错向度增加。这些特征性亚晶粒变化提高了 AGG 的驱动力,并加快了晶界迁移率。由于加入了铜,最大晶粒尺寸达到了 28.2 毫米。这项研究为制备具有大尺寸晶粒的铁锰铝镍基超弹性合金提供了一种新方法。
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引用次数: 0
Microstructure and Tensile Properties of Hot Isostatically Pressed Nickel-base Superalloy CM247LC 热等静压镍基超级合金 CM247LC 的显微结构和拉伸性能
IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-08-06 DOI: 10.1007/s11837-024-06796-9
S. Behera, V. P Shivran, Dibyendu Chatterjee, Mithun Palit

CM247LC alloy has been processed through two different routes, viz. investment casting and powder metallurgical route. The powder metallurgical route involves production of powder through inert gas atomization followed by consolidation using hot isostatic pressing (HIP). A comparative study has been carried out on microstructure and mechanical properties of the material processed through both routes to assess the efficacy of the powder metallurgical process as a viable alternative to the investment casting route. The HIPed material is free from deleterious prior particle boundaries and coarse primary γ′ and has finer grain size compared to cast material. The HIPed material exhibits higher strength and ductility at room temperature, whereas ductility of HIPed alloy at 760°C is less than for the cast alloy. Detailed microstructural analysis and thermodynamic calculation reveal that network of carbides at the grain boundary of HIPed material causes lower ductility although HIPed material exhibits better strength than cast material, even at higher temperature. This study establishes the potential of HIP process to manufacture near net shape components of complex configuration through powder metallurgy route.

CM247LC 合金是通过两种不同的途径加工而成的,即熔模铸造和粉末冶金。粉末冶金工艺包括通过惰性气体雾化生产粉末,然后使用热等静压(HIP)固结。我们对通过这两种途径加工的材料的微观结构和机械性能进行了比较研究,以评估粉末冶金工艺作为熔模铸造工艺的可行替代工艺的有效性。与铸造材料相比,HIP 化材料没有有害的先行颗粒边界和粗糙的原始 γ′,晶粒尺寸更细。HIPed 材料在室温下具有更高的强度和延展性,但在 760°C 时的延展性低于铸造合金。详细的微观结构分析和热力学计算显示,HIPed 材料晶界处的碳化物网络导致延展性较低,尽管 HIPed 材料即使在较高温度下也比铸造材料具有更好的强度。这项研究证实了 HIP 工艺通过粉末冶金工艺制造复杂构型的近净形部件的潜力。
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引用次数: 0
Formation Mechanism and Structural Characterization of NaAl11O17 Based on Solid-State Reaction 基于固态反应的 NaAl11O17 形成机理与结构表征
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-08-06 DOI: 10.1007/s11837-024-06801-1
Jihao Zhang, Xiaolin Pan, Zhongyang Lv, Haiyan Yu, Ganfeng Tu

As an aluminum rich mineral, NaAl11O17 is widely found in the by-products of the metallurgical industry, and it can be used as an alkali solidification phase in the harmless treatment of alkali-containing solid wastes due to its low formation temperature and strong stability. The formation mechanism, kinetics and structural characterization of NaAl11O17 were systemically studied based on the solid-state reaction in Na2CO3-Al2O3 system, and the reaction conditions that prevent the formation of NaAl11O17 were also established. The results show that NaAl11O17 is more feasible to form than NaAlO2 when the Al2O3-to-Na2O molar ratio (A/N) is > 11.0, and it almost completely transforms into NaAlO2 when the A/N ratio decreases to 1.0. The formation kinetics of NaAl11O17 corresponds to the diffusion-controlled model of a 3D Ginstling-Brounstein model in the temperature range of 1000–1200°C. The conversion efficiency of NaAl11O17 is controlled by the phase boundary reaction model. Furthermore, the apparent activation energy and corresponding kinetic equation of NaAl11O17 formation were determined to be 46.89 kJ/mol and k = 1 × exp[–46.89/RT], respectively. The crystal structure characterization reveals that NaAl11O17 is formed by the doping of Na+ into [AlO4] tetrahedron to form a solid solution.

作为一种富铝矿物,NaAl11O17广泛存在于冶金工业的副产品中,由于其形成温度低、稳定性强,可作为碱固相用于含碱固体废弃物的无害化处理。基于 Na2CO3-Al2O3 体系中的固态反应,系统研究了 NaAl11O17 的形成机理、动力学和结构特征,并建立了阻止 NaAl11O17 形成的反应条件。结果表明,当 Al2O3 与 Na2O 的摩尔比(A/N)为 11.0 时,NaAl11O17 比 NaAlO2 更容易形成,当 A/N 比降至 1.0 时,NaAl11O17 几乎完全转化为 NaAlO2。在 1000-1200°C 的温度范围内,NaAl11O17 的形成动力学符合三维 Ginstling-Brounstein 模型的扩散控制模型。NaAl11O17 的转化效率由相界反应模型控制。此外,还确定了 NaAl11O17 形成的表观活化能和相应的动力学方程分别为 46.89 kJ/mol 和 k = 1 × exp[-46.89/RT]。晶体结构表征表明,NaAl11O17 是由 Na+ 掺杂到[AlO4]四面体中形成的固溶体。
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引用次数: 0
Oxidation Kinetics in Ni-Cr Alloys Through Comprehensive Analysis of Parabolic and Cubic Grain Growth Dynamics and Their Implications on High-Temperature Oxidative Stability 通过全面分析抛物线晶粒和立方晶粒生长动力学及其对高温氧化稳定性的影响研究镍铬合金的氧化动力学
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-08-02 DOI: 10.1007/s11837-024-06773-2
Nan Zou, Yun Peng Zhang, Jia Hui Xu, Xiaohu Wang, MengYa Wang, Mouhamadou A. Diop

This study delves into the oxidation kinetics of Ni-Cr alloys, emphasizing the transition between parabolic and cubic grain growth dynamics under high-temperature conditions. Employing advanced numerical and analytical models, we elucidate the mechanisms driving oxide layer formation and stability, which are crucial for enhancing material longevity in oxidative environments. Our findings reveal significant insights into the diffusion behavior and defect dynamics within the oxide layers, proposing a model that integrates both grain boundary and volumetric diffusion processes. These results not only refine our understanding of oxidation resistance but also pave the way for the development of more robust high-temperature alloys. The study’s implications extend to improving industrial applications where high oxidation resistance is critical.

本研究深入探讨了镍铬合金的氧化动力学,强调了高温条件下抛物线和立方晶粒生长动力学之间的转变。利用先进的数值和分析模型,我们阐明了氧化层形成和稳定性的驱动机制,这对于提高材料在氧化环境中的使用寿命至关重要。我们的研究结果揭示了氧化层内的扩散行为和缺陷动态,并提出了一种将晶界和体积扩散过程整合在一起的模型。这些结果不仅完善了我们对抗氧化性的理解,还为开发更坚固的高温合金铺平了道路。这项研究的意义还将扩展到对抗氧化性要求较高的工业应用领域。
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引用次数: 0
On the Interactions Between γ–Al2O3 Nanoparticles and Primary or Eutectic Al2Cu in Hypereutectic Al-Cu Alloy 关于共晶铝铜合金中 γ-Al2O3 纳米粒子与原生或共晶铝铜之间的相互作用
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-08-02 DOI: 10.1007/s11837-024-06787-w
Jingyi Hu, Jingbin Liu, Yang Yang, Zuoshan Wei, Mengyu Li, Guiliang Liu, Tong Gao, Shushuai Liu, Xiangfa Liu

Numerous studies have extensively documented models aimed at predicting the likelihood of nanoparticles (NPs) being either pushed away or engulfed by the liquid-solid interface of Al dendrites in Al melts, such as those found in hypoeutectic Al-Si and Al-Cu alloys. However, these models often do not consider the effect of the solid-phase growth style on the interaction between NPs and the liquid-solid interface, given that Al dendrites typically only exhibit a continuous growth style attributed to a non-faceted growth mechanism. Yet, what occurs when the solid phase exhibits different growth styles? In this work, the behaviors were found to be different when γ–Al2O3 NPs came across eutectic non-faceted Al2Cu or primary faceted Al2Cu in a hypereutectic Al-Cu alloy. Specifically, the NPs can be engulfed by eutectic Al2Cu but be pushed away by primary Al2Cu. It is supposed that the Jackson alpha factor should be considered when building theoretical models to predict the interactions between nanoparticles and liquid-solid interfaces.

许多研究都广泛记录了一些模型,这些模型旨在预测铝熔体(如在次共晶铝硅合金和铝铜合金中发现的那些熔体)中的纳米粒子(NPs)被铝树枝状晶的液固界面推开或吞噬的可能性。然而,这些模型往往没有考虑固相生长方式对 NPs 与液固界面之间相互作用的影响,因为铝枝晶通常只表现出一种归因于非刻面生长机制的连续生长方式。然而,当固相表现出不同的生长方式时会发生什么呢?在这项研究中,我们发现当γ-Al2O3 NP 穿过共晶非刻面 Al2Cu 或超共晶 Al-Cu 合金中的原生刻面 Al2Cu 时,会出现不同的行为。具体来说,NPs 可被共晶 Al2Cu 吞噬,但会被原生 Al2Cu 推走。据推测,在建立预测纳米粒子与液固界面相互作用的理论模型时,应考虑杰克逊α因子。
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引用次数: 0
Ambient Dual Cross-Linked Interpenetrating Polymer Hydrogel Networks: Synthesis, Characterization, and Potential for Wearable Biosensing Devices 环境双交联互穿聚合物水凝胶网络:可穿戴生物传感设备的合成、表征和潜力
IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-08-01 DOI: 10.1007/s11837-024-06770-5
Ashwin Velraj, Audri Yasmin Dara, Abhishek Pachauri, Mia Marie Schmidt, Jeffrey Scott Bates

Interpenetrating polymer hydrogel networks (IPNs) present a significant advancement in the role of biomaterials with tailored properties for wearable sensors, particularly in developing non-invasive real-time monitoring devices for healthcare and fitness. This study investigates the synthesis processing and characterization of highly stretchable and elastomeric hydrogel IPNs, focusing on simplifying the synthesis by dual cross-linking of ionic and covalent polymeric backbones in ambient conditions. The hydrogels were tested for their rheological properties, mechanical behavior, and analyte sensitivity. Integrating these hydrogels into wearable sensors offers novel opportunities for continuous monitoring of physiological parameters and early detection of changes in health conditions. Rheology reveals shear thinning behavior and successful ambient cross-linking capabilities, while mechanical testing demonstrated remarkable stretchability and resilience even under cyclic tensile stress. The hydrogel's sensitivity and selectivity for biosensing were showcased with distinct responses to various analytes such as glucose, saline, and ion gradients. Further exploration and optimization of the synthesis parameters are essential for unlocking the full potential of these materials in biomedical and sensing applications, advancing personalized healthcare and disease monitoring.

互穿聚合物水凝胶网络(IPNs)是一种具有定制特性的生物材料,在可穿戴传感器的作用方面取得了重大进展,特别是在开发用于医疗保健和健身的无创实时监测设备方面。本研究调查了高伸展性和高弹性水凝胶 IPN 的合成工艺和表征,重点是在环境条件下通过离子和共价聚合物骨架的双重交联简化合成。对这些水凝胶的流变特性、机械性能和分析灵敏度进行了测试。将这些水凝胶集成到可穿戴传感器中,为连续监测生理参数和早期检测健康状况的变化提供了新的机会。流变学显示了剪切稀化行为和成功的环境交联能力,而机械测试则表明,即使在循环拉伸应力下,水凝胶也具有显著的伸展性和弹性。水凝胶对各种分析物(如葡萄糖、生理盐水和离子梯度)的独特反应展示了它在生物传感方面的灵敏度和选择性。进一步探索和优化合成参数对于释放这些材料在生物医学和传感应用中的全部潜力、推进个性化医疗保健和疾病监测至关重要。
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引用次数: 0
Simulation of Ladle Steelmaking Process: Effective Equilibrium Reaction Zone Model Using FactSage Macro Processing 钢包炼钢过程模拟:使用 FactSage 宏处理的有效平衡反应区模型
IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-07-31 DOI: 10.1007/s11837-024-06766-1
Prasenjit Singha, Abhishek Tiwari

Approximately 10–15% of the world’s steel production is derived from small industries. While ladle furnaces contribute to maintaining a generally good quality of refined steel, new challenges arise, especially when striving for very low sulfur percentages in steel. To address this, the study explores the impact of process parameters such as aluminum, silicon, and basicity in reducing sulfur content. Three interconnected equilibrium/adiabatic stoichiometric-reactor-based approaches describe the overall ladle steel-making process. The macro-programming facility of FactSage™ software was used to determine the refining behaviors of the ladle steel-making processes. The model’s predicted endpoint, manganese, sulfur, oxygen, and aluminum content, agreed with plant data. This efficient model is a valuable guiding tool for ladle steelmaking industries with a 10–15 ton capacity.

全球约有 10-15% 的钢铁产量来自小型企业。虽然钢包炉有助于保持精炼钢的总体良好质量,但新的挑战也随之而来,尤其是在努力降低钢中硫含量时。为此,本研究探讨了铝、硅和碱性等工艺参数对降低硫含量的影响。基于平衡/绝热化学计量反应器的三种相互关联的方法描述了整个钢包炼钢过程。FactSage™ 软件的宏编程功能用于确定钢包炼钢过程的精炼行为。模型预测的终点、锰、硫、氧和铝含量与工厂数据一致。这一高效模型对于产能为 10-15 吨的钢包炼钢行业来说是一个宝贵的指导工具。
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引用次数: 0
Effect of Electropulsing on the Microstructure and Mechanical Properties of AZ31 Alloys Manufactured by Cold Drawing 电脉冲对冷拔法制造的 AZ31 合金微观结构和机械性能的影响
IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-07-31 DOI: 10.1007/s11837-024-06772-3
Zhaohui Shan, Yixia Zhang, Yulin Liu, Qiang Zhang, Jianfeng Fan, Binshan Wang, Xiaoyan Yun, Bingshe Xu

A fine-diameter AZ31 magnesium alloy wire was treated with cold drawing and electropulsing treatment (EPT) to explore the influence of processing conditions on microstructural evolution and mechanical properties. An ultrafine-grained structure accompanied by the development of a weak basal texture was formed because of static recrystallization originating from the cold-drawn samples under EPT processing. The AZ31 alloy wires exhibited a good combination of tensile strength and ductility in tensile tests at room temperature. In particular, the highest ultimate tensile strength of 390 MPa was achieved in the specimen EPT-processed at 30 μs–5 min. In addition to such high strength, elongation reaches 29.5% in the specimen. This substantially improved strength and ductility were attributed to the fine-grain strengthening effects and weakening of the basal texture component. Finally, it is proposed that cold drawing and EPT are promising ways to produce high strength, high ductility Mg alloy wire products.

对一种细直径 AZ31 镁合金线材进行了冷拔和电脉冲处理(EPT),以探索加工条件对微观结构演变和机械性能的影响。在 EPT 处理过程中,由于冷拔样品产生了静态再结晶,形成了超细晶粒结构,并伴有弱基底纹理的发展。在室温下进行的拉伸试验中,AZ31 合金丝表现出拉伸强度和延展性的良好结合。特别是在 30 μs-5 min 下进行 EPT 加工的试样达到了 390 MPa 的最高极限拉伸强度。除了如此高的强度外,试样的伸长率也达到了 29.5%。强度和延展性的大幅提高归因于细晶粒强化效应和基底纹理成分的削弱。最后,我们提出冷拔和 EPT 是生产高强度、高延展性镁合金线材产品的可行方法。
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引用次数: 0
Preview the TMS Fall Meeting at MS&T24 在 MS&T24 上预览 TMS 秋季会议
IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
JOM
Pub Date : 2024-07-31 DOI: 10.1007/s11837-024-06781-2
Kelly Zappas
{"title":"Preview the TMS Fall Meeting at MS&T24","authors":"Kelly Zappas","doi":"10.1007/s11837-024-06781-2","DOIUrl":"10.1007/s11837-024-06781-2","url":null,"abstract":"","PeriodicalId":605,"journal":{"name":"JOM","volume":"76 9","pages":"4764 - 4765"},"PeriodicalIF":2.1,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142415347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
JOM
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