首页 > 最新文献

Journal of Chemical Crystallography最新文献

英文 中文
Synthesis, Structural Characterization and Hirshfeld Analysis of Ag(I), Au(I), Cd(II) and Hg(II) Complexes Containing Hemilabile- Ferrocenylbisphosphine [Fe{C5H4P(C6H4CH2NMe2-o)2}2] 半可降解二茂铁双膦配合物[Fe{C5H4P(C6H4CH2NMe2-o)2}2] Ag(I)、Au(I)、Cd(II)和Hg(II)的合成、结构表征和Hirshfeld分析
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-10-28 DOI: 10.1007/s10870-022-00966-w
Dipanjan Mondal, Sowmya Rao, Joel T. Mague, Maravanji S. Balakrishna
<div><p>The reaction between bis(phosphino)ferrocene, [Fe{C<sub>5</sub>H<sub>4</sub>P(C<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>NMe<sub>2</sub>-<i>o</i>)<sub>2</sub>}<sub>2</sub>] (<b>1</b>) and AgOTf resulted in disilver complex [(AgOTf)<sub>2</sub>{µ-Fe{C<sub>5</sub>H<sub>4</sub>P(C<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>}<sub>2</sub>}] (<b>2</b>) which on further treatment with 2,2′-bipyrdine yielded a mixed-ligand complex [Ag<sub>2</sub>(bipy)<sub>2</sub>{µ-Fe{C<sub>5</sub>H<sub>4</sub>P(C<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>}<sub>2</sub>}](OTf)<sub>2</sub> (<b>3</b>). Reaction of <b>1</b> with AuCl(SMe<sub>2</sub>) in 1:2 molar ratio afforded a digold complex [(AuCl)<sub>2</sub>Fe{C<sub>5</sub>H<sub>4</sub>P(C<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>}<sub>2</sub>] (<b>4</b>). Treatment of <b>4</b> with anhydrous CdCl<sub>2</sub> resulted in heterometallic complex [Fe{C<sub>5</sub>H<sub>4</sub>P(AuCl)(C<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>(CdCl<sub>2</sub>)}<sub>2</sub>] (<b>5</b>). The reactions of <b>1</b> with anhydrous CdI<sub>2</sub> and HgI<sub>2</sub> in 1:2 molar ratios yielded bimetallic complexes [Fe{C<sub>5</sub>H<sub>4</sub>P(CdI<sub>2</sub>)(C<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>}<sub>2</sub>] (<b>6</b>) and [Fe{C<sub>5</sub>H<sub>4</sub>P(HgI<sub>2</sub>)(C<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>}<sub>2</sub>] (<b>7</b>), respectively. The molecular structures of <b>3</b>, <b>4</b> and <b>7</b> were confirmed by single crystal X-ray analysis. Complexes <b>3</b> and <b>7</b> crystallized in the triclinic space group with P-1, whereas <b>4</b> crystallized in the monoclinic space group with C2/c. Single crystals suitable for X-ray crystallography were obtained using diffusion method where a solution of [Fe{C<sub>5</sub>H<sub>4</sub>P(C<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>2</sub>}<sub>2</sub>] (<b>1</b>) in dichloromethane was layered on a solution of CdI<sub>2</sub> and HgI<sub>2</sub> in methanol and stored at room temperature for 24 h, resulted in yellow plates of <b>6</b> and <b>7</b>, respectively. All complexes crystallized with the asymmetric unit containing half a molecule and with the Fe atom on an inversion centre. A Hirshfeld surface analysis indicated that the most significant contributions to the crystal packing of <b>3</b> are from H‧‧‧H (50.2%), C‧‧‧H/H‧‧‧C (8.3%), Cl‧‧‧H/H‧‧‧Cl (12.1%), O‧‧‧H/H‧‧‧O (11.3%), F‧‧‧H/H‧‧‧F (9.0%) contacts, while those for <b>4</b> are from H‧‧‧H (73.7%), C‧‧‧H/H‧‧‧C (8.9%), Cl‧‧‧H/H‧‧‧Cl (14.5%), Au‧‧‧H/H‧‧‧Au (1.8%) and N‧‧‧H/H‧‧‧N (0.8%) contacts, and those for <b>7</b> are from H‧‧‧H (65.5%), C‧‧‧H/H‧‧‧C (6.6%), I‧‧‧H/H‧‧‧I (24.1%) and I‧‧‧C/C‧‧‧I (2.9%) contacts.</p><h3>Graphical Abstract</h3><p> Crystal structures of silver(I), gold(I) and mercury(II) complexes containing [Fe{C<sub>5</sub>H<s
二茂铁,(Fe {C5H4P (C6H4CH2NMe2-o) 2} 2](1)和AgOTf导致disilver复杂[(AgOTf) 2{µFe {C5H4P (C6H4CH2NMe2) 2} 2}](2)与2进一步治疗,2》-bipyrdine产生mixed-ligand复杂[银2 (bipy) 2{µFe {C5H4P (C6H4CH2NMe2) 2} 2}](传递)2(3),反应1 AuCl (SMe2) 1:2摩尔比率提供digold复杂[(AuCl) 2菲{C5H4P (C6H4CH2NMe2) 2} 2](4)。治疗与无水4 CdCl2导致heterometallic复杂(Fe {C5H4P (AuCl) (C6H4CH2NMe2) 2 (CdCl2)} 2](5) 1的反应无水CdI2和HgI2以1:2的摩尔比分别得到[Fe{C5H4P(CdI2)(C6H4CH2NMe2)2}2](6)和[Fe{C5H4P(HgI2)(C6H4CH2NMe2)2}2](7)。单晶x射线分析证实了3、4和7的分子结构。配合物3和7与P-1在三斜空间群中结晶,而配合物4与C2/c在单斜空间群中结晶。用扩散法将二氯甲烷中的[Fe{C5H4P(C6H4CH2NMe2)2}2](1)溶液层置在甲醇中的CdI2和HgI2溶液上,室温保存24 h,得到适合x射线晶体学的单晶,分别得到黄板6和黄板7。所有的配合物都以含有半分子的不对称单元和在反转中心的铁原子结晶。Hirshfeld表面分析表明晶体包装最重要的贡献的3 H‧‧‧H(50.2%)、C / H‧‧‧‧‧‧H C(8.3%)、Cl / H‧‧‧‧‧‧H Cl (12.1%), O / H‧‧‧‧‧‧H O(11.3%)、F / H‧‧‧‧‧‧H F(9.0%)接触,而从H‧‧‧H 4(73.7%)、C / H‧‧‧‧‧‧H C(8.9%)、Cl / H‧‧‧‧‧‧H Cl(14.5%),非盟H / H‧‧‧‧‧‧盟(1.8%)和N / H‧‧‧‧‧‧H N(0.8%)接触,和那些7 H‧‧‧H(65.5%)、C / H‧‧‧‧‧‧H C(6.6%),我‧‧‧H / H‧‧‧我(24.1%)和C / C‧‧‧‧‧‧我接触(2.9%)。描述了含[Fe{C5H4P(C6H4CH2NMe2)2}2](1)的银(I)、金(I)和汞(II)配合物的晶体结构。
{"title":"Synthesis, Structural Characterization and Hirshfeld Analysis of Ag(I), Au(I), Cd(II) and Hg(II) Complexes Containing Hemilabile- Ferrocenylbisphosphine [Fe{C5H4P(C6H4CH2NMe2-o)2}2]","authors":"Dipanjan Mondal,&nbsp;Sowmya Rao,&nbsp;Joel T. Mague,&nbsp;Maravanji S. Balakrishna","doi":"10.1007/s10870-022-00966-w","DOIUrl":"10.1007/s10870-022-00966-w","url":null,"abstract":"&lt;div&gt;&lt;p&gt;The reaction between bis(phosphino)ferrocene, [Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;P(C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NMe&lt;sub&gt;2&lt;/sub&gt;-&lt;i&gt;o&lt;/i&gt;)&lt;sub&gt;2&lt;/sub&gt;}&lt;sub&gt;2&lt;/sub&gt;] (&lt;b&gt;1&lt;/b&gt;) and AgOTf resulted in disilver complex [(AgOTf)&lt;sub&gt;2&lt;/sub&gt;{µ-Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;P(C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NMe&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;}&lt;sub&gt;2&lt;/sub&gt;}] (&lt;b&gt;2&lt;/b&gt;) which on further treatment with 2,2′-bipyrdine yielded a mixed-ligand complex [Ag&lt;sub&gt;2&lt;/sub&gt;(bipy)&lt;sub&gt;2&lt;/sub&gt;{µ-Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;P(C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NMe&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;}&lt;sub&gt;2&lt;/sub&gt;}](OTf)&lt;sub&gt;2&lt;/sub&gt; (&lt;b&gt;3&lt;/b&gt;). Reaction of &lt;b&gt;1&lt;/b&gt; with AuCl(SMe&lt;sub&gt;2&lt;/sub&gt;) in 1:2 molar ratio afforded a digold complex [(AuCl)&lt;sub&gt;2&lt;/sub&gt;Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;P(C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NMe&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;}&lt;sub&gt;2&lt;/sub&gt;] (&lt;b&gt;4&lt;/b&gt;). Treatment of &lt;b&gt;4&lt;/b&gt; with anhydrous CdCl&lt;sub&gt;2&lt;/sub&gt; resulted in heterometallic complex [Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;P(AuCl)(C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NMe&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;(CdCl&lt;sub&gt;2&lt;/sub&gt;)}&lt;sub&gt;2&lt;/sub&gt;] (&lt;b&gt;5&lt;/b&gt;). The reactions of &lt;b&gt;1&lt;/b&gt; with anhydrous CdI&lt;sub&gt;2&lt;/sub&gt; and HgI&lt;sub&gt;2&lt;/sub&gt; in 1:2 molar ratios yielded bimetallic complexes [Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;P(CdI&lt;sub&gt;2&lt;/sub&gt;)(C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NMe&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;}&lt;sub&gt;2&lt;/sub&gt;] (&lt;b&gt;6&lt;/b&gt;) and [Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;P(HgI&lt;sub&gt;2&lt;/sub&gt;)(C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NMe&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;}&lt;sub&gt;2&lt;/sub&gt;] (&lt;b&gt;7&lt;/b&gt;), respectively. The molecular structures of &lt;b&gt;3&lt;/b&gt;, &lt;b&gt;4&lt;/b&gt; and &lt;b&gt;7&lt;/b&gt; were confirmed by single crystal X-ray analysis. Complexes &lt;b&gt;3&lt;/b&gt; and &lt;b&gt;7&lt;/b&gt; crystallized in the triclinic space group with P-1, whereas &lt;b&gt;4&lt;/b&gt; crystallized in the monoclinic space group with C2/c. Single crystals suitable for X-ray crystallography were obtained using diffusion method where a solution of [Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;P(C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;CH&lt;sub&gt;2&lt;/sub&gt;NMe&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;}&lt;sub&gt;2&lt;/sub&gt;] (&lt;b&gt;1&lt;/b&gt;) in dichloromethane was layered on a solution of CdI&lt;sub&gt;2&lt;/sub&gt; and HgI&lt;sub&gt;2&lt;/sub&gt; in methanol and stored at room temperature for 24 h, resulted in yellow plates of &lt;b&gt;6&lt;/b&gt; and &lt;b&gt;7&lt;/b&gt;, respectively. All complexes crystallized with the asymmetric unit containing half a molecule and with the Fe atom on an inversion centre. A Hirshfeld surface analysis indicated that the most significant contributions to the crystal packing of &lt;b&gt;3&lt;/b&gt; are from H‧‧‧H (50.2%), C‧‧‧H/H‧‧‧C (8.3%), Cl‧‧‧H/H‧‧‧Cl (12.1%), O‧‧‧H/H‧‧‧O (11.3%), F‧‧‧H/H‧‧‧F (9.0%) contacts, while those for &lt;b&gt;4&lt;/b&gt; are from H‧‧‧H (73.7%), C‧‧‧H/H‧‧‧C (8.9%), Cl‧‧‧H/H‧‧‧Cl (14.5%), Au‧‧‧H/H‧‧‧Au (1.8%) and N‧‧‧H/H‧‧‧N (0.8%) contacts, and those for &lt;b&gt;7&lt;/b&gt; are from H‧‧‧H (65.5%), C‧‧‧H/H‧‧‧C (6.6%), I‧‧‧H/H‧‧‧I (24.1%) and I‧‧‧C/C‧‧‧I (2.9%) contacts.&lt;/p&gt;&lt;h3&gt;Graphical Abstract&lt;/h3&gt;&lt;p&gt;\u0000 Crystal structures of silver(I), gold(I) and mercury(II) complexes containing [Fe{C&lt;sub&gt;5&lt;/sub&gt;H&lt;s","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"273 - 292"},"PeriodicalIF":0.8,"publicationDate":"2022-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10870-022-00966-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5102165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystal structure and solid-state luminescence properties of [Tb(H2O)9]Cl(C10H6O4S4)2 (C10H6O4S42− = 2,6-naphthalenedisulfonate) [Tb(H2O)9]Cl(C10H6O4S4)2 (C10H6O4S42−= 2,6-萘二磺酸盐)的晶体结构和固态发光性能
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-10-26 DOI: 10.1007/s10870-022-00963-z
Ming-Qing Liu, Wen-Tong Chen, Lijun Wei, Qiu-Yue Zhong, Chuan-Kang Yin, Xiu-Guang Yi

A terbium 2,6-naphthalenedisulfonic acid compound, [Tb(H2O)9]Cl(C10H6O4S4)2 (C10H6O4S42− = 2,6-naphthalenedisulfonate), is prepared and characterized by single-crystal X-ray diffraction. This compound is characterized by an isolated structure with the terbium ion possessing a mono-capped square antiprism coordination geometry. The [Tb(H2O)9]3+ cations and (2,6-naphthalenedisulfonic acid)2− anions are linked by hydrogen-bonding interactions to yield a three-dimensional supramolecular network. The solid state luminescence spectrum reveals that this compound shows the strongest emission band in the red region. The luminescence emission peaks can be ascribed to the characteristic emissions of the 4f electron intrashell transitions 5D47F5, 5D47F4 and 5D47F2 of the Tb3+ ion. The CIE (Commission Internationale de L’Eclairage) chromaticity coordinates are (0.5647, 0.4338). Solid-state UV/Vis diffuse reflectance spectra reveal that compound 1 shows a wide optical band gap of 4.92 eV.

Graphical abstract

A novel terbium 2,6-naphthalenedisulfonic acid compound is prepared and characterized

制备了一种2,6-萘二磺酸铽化合物[Tb(H2O)9]Cl(C10H6O4S4)2 (C10H6O4S42−= 2,6-萘二磺酸盐),并用单晶x射线衍射对其进行了表征。该化合物具有分离结构,铽离子具有单帽方形反棱镜配位几何。[Tb(H2O)9]3+阳离子和(2,6-萘二磺酸)2 -阴离子通过氢键相互作用连接,形成三维超分子网络。固体发光光谱显示,该化合物在红色区域具有最强的发射带。发光发射峰可归因于Tb3+离子的4f电子壳内跃迁5D4→7F5、5D4→7F4和5D4→7F2的特征发射。CIE (Commission Internationale de L’eclairage)色度坐标为(0.5647,0.4338)。固体UV/Vis漫反射光谱显示化合物1具有4.92 eV的宽带隙。摘要制备了一种新型2,6-萘二磺酸铽化合物,并对其进行了表征
{"title":"Crystal structure and solid-state luminescence properties of [Tb(H2O)9]Cl(C10H6O4S4)2 (C10H6O4S42− = 2,6-naphthalenedisulfonate)","authors":"Ming-Qing Liu,&nbsp;Wen-Tong Chen,&nbsp;Lijun Wei,&nbsp;Qiu-Yue Zhong,&nbsp;Chuan-Kang Yin,&nbsp;Xiu-Guang Yi","doi":"10.1007/s10870-022-00963-z","DOIUrl":"10.1007/s10870-022-00963-z","url":null,"abstract":"<div><p>A terbium 2,6-naphthalenedisulfonic acid compound, [Tb(H<sub>2</sub>O)<sub>9</sub>]Cl(C<sub>10</sub>H<sub>6</sub>O<sub>4</sub>S<sub>4</sub>)<sub>2</sub> (C<sub>10</sub>H<sub>6</sub>O<sub>4</sub>S<sub>4</sub><sup>2−</sup> = 2,6-naphthalenedisulfonate), is prepared and characterized by single-crystal X-ray diffraction. This compound is characterized by an isolated structure with the terbium ion possessing a mono-capped square antiprism coordination geometry. The [Tb(H<sub>2</sub>O)<sub>9</sub>]<sup>3+</sup> cations and (2,6-naphthalenedisulfonic acid)<sup>2−</sup> anions are linked by hydrogen-bonding interactions to yield a three-dimensional supramolecular network. The solid state luminescence spectrum reveals that this compound shows the strongest emission band in the red region. The luminescence emission peaks can be ascribed to the characteristic emissions of the 4<i>f</i> electron intrashell transitions <sup>5</sup><i>D</i><sub>4</sub> → <sup>7</sup><i>F</i><sub>5</sub>, <sup>5</sup><i>D</i><sub>4</sub> → <sup>7</sup><i>F</i><sub>4</sub> and <sup>5</sup><i>D</i><sub>4</sub> → <sup>7</sup><i>F</i><sub>2</sub> of the Tb<sup>3+</sup> ion. The CIE (Commission Internationale de L’Eclairage) chromaticity coordinates are (0.5647, 0.4338). Solid-state UV/Vis diffuse reflectance spectra reveal that compound <b>1</b> shows a wide optical band gap of 4.92 eV.</p><h3>Graphical abstract</h3><p>A novel terbium 2,6-naphthalenedisulfonic acid compound is prepared and characterized</p>\u0000 <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\u0000 </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"266 - 272"},"PeriodicalIF":0.8,"publicationDate":"2022-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5019779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Polynuclear Cyanide-Bridged Heterobimetallic Complexes Based-on Pentacyanometallates: Synthesis, Crystal Structure and Magnetic Property 基于五氰金属酸盐的多核氰化物桥接杂双金属配合物:合成、晶体结构和磁性能
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-10-20 DOI: 10.1007/s10870-022-00967-9
Yu Xin, Zhijie Xu, Shuo Meng, Tong Cao, Mingjian Zhang, Xiaoyi Duan, Zhen Zhou, Daopeng Zhang

Three new cyanide-bridged heterobimetallic complexes {[Cu(L)]2[Cr(CN)5(NO)]}ClO4·2H2O (1), {{[Cu(cyclam)][Fe(CN)5(NO)]}·H2O}n (2), {{[Cu(cyclam)]3[Cr(CN)5(NO)]2}·CH3OH·4H2O}n (3) (L=2,12-dimethyl-3,7,11,17-tetraazabicyclo [11.3.1] heptadeca-1 (17), 13, 15-triene, cyclam=1,4,8,11-tetraazacyclodecane) have been successfully assembled from the pentacyanometalates and two copper(II) compounds and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. X-ray structural analysis revealed that the Complex 1 is a cationic trinuclear CrCu2 entity with the positive charge balanced by ClO4 ion, while complexes 2 and 3 were structurally characterized showing a 1D chain. The magnetic properties of the reported cyanide-bridged complexes have been experimentally studied and theoretically simulated, disclosing the ferromagnetic interaction between the Cr(I) ion and the Cu(II) ion through the cyanide bridge.

Graphical Abstract

以五氰金属酸盐和两种铜(II)化合物为原料,成功地组装了三个新的氰化物桥接的杂双金属配合物{[Cu(L)]2[Cr(CN)5(NO)]}ClO4·2H2O(1)、{{[Cu(环)][Fe(CN)5(NO)]}·H2O}n(2)、{{[Cu(环)]3[Cr(CN)5(NO)]2}·CH3OH·4H2O}n (3) (L=2,12-二甲基-3,7,11,17-四氮杂环-1(17),13,15 -三烯,环am=1,4,8,11-四氮杂环癸烷),并通过元素分析、红外光谱和x射线结构测定对其进行了表征。x射线结构分析表明,配合物1是一个阳离子三核CrCu2实体,正电荷由ClO4−离子平衡,而配合物2和3在结构上表现为一维链。对所报道的氰化物桥接配合物的磁性进行了实验研究和理论模拟,揭示了Cr(I)离子和Cu(II)离子通过氰化物桥接之间的铁磁相互作用。图形抽象
{"title":"Polynuclear Cyanide-Bridged Heterobimetallic Complexes Based-on Pentacyanometallates: Synthesis, Crystal Structure and Magnetic Property","authors":"Yu Xin,&nbsp;Zhijie Xu,&nbsp;Shuo Meng,&nbsp;Tong Cao,&nbsp;Mingjian Zhang,&nbsp;Xiaoyi Duan,&nbsp;Zhen Zhou,&nbsp;Daopeng Zhang","doi":"10.1007/s10870-022-00967-9","DOIUrl":"10.1007/s10870-022-00967-9","url":null,"abstract":"<div><p>Three new cyanide-bridged heterobimetallic complexes {[Cu(L)]<sub>2</sub>[Cr(CN)<sub>5</sub>(NO)]}ClO<sub>4</sub>·2H<sub>2</sub>O (1), {{[Cu(cyclam)][Fe(CN)<sub>5</sub>(NO)]}·H<sub>2</sub>O}<sub>n</sub> (2), {{[Cu(cyclam)]<sub>3</sub>[Cr(CN)<sub>5</sub>(NO)]<sub>2</sub>}·CH<sub>3</sub>OH·4H<sub>2</sub>O}<sub>n</sub> (3) (L=2,12-dimethyl-3,7,11,17-tetraazabicyclo [11.3.1] heptadeca-1 (17), 13, 15-triene, cyclam=1,4,8,11-tetraazacyclodecane) have been successfully assembled from the pentacyanometalates and two copper(II) compounds and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. X-ray structural analysis revealed that the Complex 1 is a cationic trinuclear CrCu<sub>2</sub> entity with the positive charge balanced by ClO<sub>4</sub><sup>−</sup> ion, while complexes 2 and 3 were structurally characterized showing a 1D chain. The magnetic properties of the reported cyanide-bridged complexes have been experimentally studied and theoretically simulated, disclosing the ferromagnetic interaction between the Cr(I) ion and the Cu(II) ion through the cyanide bridge.</p><h3>Graphical Abstract</h3>\u0000 <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\u0000 </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"256 - 265"},"PeriodicalIF":0.8,"publicationDate":"2022-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5105462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, Characterizations, Crystal Structure, DFT, and Hirshfeld Surface Analysis of 4-Cyclohexyl-1-(thiophene-2-carbonyl)thiosemicarbazide 4-环己基-1-(噻吩-2-羰基)硫代氨基脲的合成、表征、晶体结构、DFT和Hirshfeld表面分析
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-10-13 DOI: 10.1007/s10870-022-00965-x
Shivendra Kumar Pandey, Seema Gupta, Shubham Jaiswal, M. K. Gond, M. K. Bharty, R. J. Butcher

The crystal structure of the thiosemicarbazide derivative 4-cyclohexyl-1-(thiophene-2-carbonyl)thiosemicarbazide (ChtcTSC), C12H17N3OS2, is reported here. The title compound ChtcTSC has been characterized by various physicochemical techniques viz UV–Vis., Infrared, and NMR. It crystallizes in the monoclinic system having space group P21/c. The dihedral angle between the thiophene and cyclohexyl rings is 60.7(4)°. The crystal packing is established by intermolecular N–H⋯O packing interactions involving a three-center donor hydrogen bond between the keto oxygen atom of the thiophene group and H atoms belonging to the hydrazine group which links the molecules into chains along the (011) plane of the unit cell. Hydrogen bonds between the hydrazine hydrogen atom and one of the thiophene groups and C–H⋯Cg π -ring interactions provide added stability to the crystal packing. The fingerprint plots associated with Hirshfeld surface analysis indicate that there are different types of weak interactions viz. O⋯H–C, O⋯H–N, and S⋯H–C. The geometry optimization has been performed using the DFT method, and geometrical parameters thus obtained for ChtcTSC correlate with the single-crystal X-ray data. The TD-DFT study showed a small HOMO and LUMO energy gap of 2.869 eV. The electronic transition from the ground state to the excited state due to a transfer of electrons from HOMO to LUMO levels is mainly associated with the n → π* transition.

Graphical Abstract

The crystal structure of 4-cyclohexyl-1-(thiophene-2-carbonyl)thiosemicarbazide (ChtcTSC) is reported here where the title compound ChtcTSC has been characterized by various physiochemical techniques including UV–Vis., Infrared, NMR, DFT and Hirshfeld surface analysis.

报道了硫代氨基脲衍生物4-环己基-1-(噻吩-2-羰基)硫代氨基脲(ChtcTSC) C12H17N3OS2的晶体结构。标题化合物ChtcTSC已通过各种物理化学技术,即紫外-可见光谱进行了表征。红外线和核磁共振。在空间群为P21/c的单斜晶系中结晶。噻吩与环己基环之间的二面角为60.7(4)°。晶体填充是通过分子间N-H⋯O填充相互作用建立的,涉及噻吩基团的酮氧原子和属于肼基团的H原子之间的三中心供体氢键,该氢键沿着单元胞的(011)平面将分子连接成链。肼氢原子与噻吩基团之一之间的氢键和C-H⋯Cg π环相互作用为晶体填料提供了额外的稳定性。与Hirshfeld表面分析相关的指纹图谱表明存在不同类型的弱相互作用,即O⋯H-C, O⋯H-N和S⋯H-C。利用DFT方法对ChtcTSC进行了几何优化,得到的几何参数与单晶x射线数据具有一定的相关性。TD-DFT研究表明,HOMO和LUMO的能差较小,为2.869 eV。由HOMO到LUMO能级的电子转移引起的基态到激发态的电子跃迁主要与n→π*跃迁有关。摘要本文报道了4-环己基-1-(噻吩-2-羰基)硫代氨基脲(ChtcTSC)的晶体结构,并用紫外-可见等多种物理化学方法对该化合物进行了表征。,红外,核磁共振,DFT和赫希菲尔德表面分析。
{"title":"Synthesis, Characterizations, Crystal Structure, DFT, and Hirshfeld Surface Analysis of 4-Cyclohexyl-1-(thiophene-2-carbonyl)thiosemicarbazide","authors":"Shivendra Kumar Pandey,&nbsp;Seema Gupta,&nbsp;Shubham Jaiswal,&nbsp;M. K. Gond,&nbsp;M. K. Bharty,&nbsp;R. J. Butcher","doi":"10.1007/s10870-022-00965-x","DOIUrl":"10.1007/s10870-022-00965-x","url":null,"abstract":"<div><p>The crystal structure of the thiosemicarbazide derivative 4-cyclohexyl-1-(thiophene-2-carbonyl)thiosemicarbazide (ChtcTSC), C<sub>12</sub>H<sub>17</sub>N<sub>3</sub>OS<sub>2</sub>, is reported here. The title compound ChtcTSC has been characterized by various physicochemical techniques viz UV–Vis., Infrared, and NMR. It crystallizes in the monoclinic system having space group P2<sub>1</sub>/c. The dihedral angle between the thiophene and cyclohexyl rings is 60.7(4)<sup>°</sup>. The crystal packing is established by intermolecular N–H⋯O packing interactions involving a three-center donor hydrogen bond between the keto oxygen atom of the thiophene group and H atoms belonging to the hydrazine group which links the molecules into chains along the (011) plane of the unit cell. Hydrogen bonds between the hydrazine hydrogen atom and one of the thiophene groups and C–H⋯Cg π -ring interactions provide added stability to the crystal packing. The fingerprint plots associated with Hirshfeld surface analysis indicate that there are different types of weak interactions viz<i>.</i> O⋯H–C, O⋯H–N, and S⋯H–C. The geometry optimization has been performed using the DFT method, and geometrical parameters thus obtained for ChtcTSC correlate with the single-crystal X-ray data. The TD-DFT study showed a small HOMO and LUMO energy gap of 2.869 eV. The electronic transition from the ground state to the excited state due to a transfer of electrons from HOMO to LUMO levels is mainly associated with the n → π* transition.</p><h3>Graphical Abstract</h3><p>The crystal structure of 4-cyclohexyl-1-(thiophene-2-carbonyl)thiosemicarbazide (ChtcTSC) is reported here where the title compound ChtcTSC has been characterized by various physiochemical techniques including UV–Vis., Infrared, NMR, DFT and Hirshfeld surface analysis.</p>\u0000 <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\u0000 </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"244 - 255"},"PeriodicalIF":0.8,"publicationDate":"2022-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4558329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Self-assembly of Hybrid Solids {Hpz}2[H7CrMo6O24]·6H2O and [Co(2-Hampz)2Cl4] (pz = pyrazole, 2-ampz = 2-aminopyrazine) from Aqueous Solution {Hpz}2[H7CrMo6O24]·6H2O和[Co(2- hampz)2Cl4] (pz =吡唑,2-ampz = 2-氨基吡嗪)在水溶液中的自组装
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-10-01 DOI: 10.1007/s10870-022-00964-y
Memsy Chiriamkandath Kuriakose, Jisha Joseph, Glinta Mandumpal Joyson, Jency Thomas

Two new hybrid solids viz. {Hpz}2[H7CrMo6O24]·6H2O (1) and [Co(2-Hampz)2Cl4] (2) have been crystallized via solvent evaporation technique using pyrazole (pz) and 2-aminopyrazine (2-ampz) respectively. The solids were characterized using single crystal X-ray diffraction, fourier transform infrared spectroscopy, elemental analysis, scanning electron microscopy and thermal analysis. The solid 1 crystallized in orthorhombic system with space group Pbca, a = 23.1796(8), b = 11.1281(4), c = 25.1499(9) Å, Z = 8. The solid 2 crystallized in triclinic system with space group P-1, a = 7.1986(5), b = 7.3917(5), c = 7.8896(6) Å, α = 115.758(3), β = 110.450(3), γ = 96.904(3)°, Z = 1. While, solid 1 is a new Anderson–Evans cluster based solid, 2 is a new pseudopolymorph of cobalt complex [Co(2-ampz)4Cl2]. Crystal structure analysis suggested that supramolecular interactions facilitate the crystal packing in solids 1 and 2. In addition, the role of synthetic parameters in dictating the nature of self-assembly of solids 1 and 2 in aqueous medium has also been analyzed.

Graphical Abstract

An Anderson–Evans cluster based solid, {Hpz}2[H7CrMo6O24]·6H2O (1) and a new pseudopolymorph of cobalt complex [Co(2-ampz)4Cl2] viz. [Co(2-Hampz)2Cl4] (2) have been synthesized using pyrazole (pz) and 2-aminopyrazine (2-ampz) respectively.

采用溶剂蒸发技术分别用吡唑(pz)和2-氨基吡嗪(2-ampz)制备了两种新的杂化固体{Hpz}2[H7CrMo6O24]·6H2O(1)和[Co(2- hampz)2Cl4](2)。采用单晶x射线衍射、傅里叶变换红外光谱、元素分析、扫描电镜和热分析对固体进行了表征。固体1在空间群为Pbca的正交晶系中结晶,a = 23.1796(8), b = 11.1281(4), c = 25.1499(9) Å, Z = 8。固体2在三斜晶系的结晶系统空间组织p - 1, a = 7.1986 (5), b = 7.3917 (5), c = 7.8896(6),α= 115.758(3),β= 110.450(3),γ= 96.904(3)°,Z = 1。固体1是一种新的Anderson-Evans簇基固体,而固体2是一种新的钴配合物[Co(2-ampz)4Cl2]伪多晶。晶体结构分析表明,超分子相互作用促进了固体1和固体2中的晶体堆积。此外,还分析了合成参数在决定固体1和固体2在水介质中自组装性质中的作用。摘要用吡唑(pz)和2-氨基吡嗪(2-ampz)分别合成了基于Anderson-Evans簇基的固体{Hpz}2[H7CrMo6O24]·6H2O(1)和新的钴配合物[Co(2-ampz)4Cl2]伪晶[Co(2-ampz) 2Cl4](2)。
{"title":"Self-assembly of Hybrid Solids {Hpz}2[H7CrMo6O24]·6H2O and [Co(2-Hampz)2Cl4] (pz = pyrazole, 2-ampz = 2-aminopyrazine) from Aqueous Solution","authors":"Memsy Chiriamkandath Kuriakose,&nbsp;Jisha Joseph,&nbsp;Glinta Mandumpal Joyson,&nbsp;Jency Thomas","doi":"10.1007/s10870-022-00964-y","DOIUrl":"10.1007/s10870-022-00964-y","url":null,"abstract":"<div><p>Two new hybrid solids viz<i>.</i> {H<i>pz</i>}<sub>2</sub>[H<sub>7</sub>CrMo<sub>6</sub>O<sub>24</sub>]·6H<sub>2</sub>O (<b>1</b>) and [Co(2-H<i>ampz</i>)<sub>2</sub>Cl<sub>4</sub>] (<b>2</b>) have been crystallized via solvent evaporation technique using pyrazole (<i>pz</i>) and 2-aminopyrazine (2-<i>ampz</i>) respectively. The solids were characterized using single crystal X-ray diffraction, fourier transform infrared spectroscopy, elemental analysis, scanning electron microscopy and thermal analysis. The solid <b>1</b> crystallized in orthorhombic system with space group <i>Pbca</i>, <i>a</i> = 23.1796(8), <i>b</i> = 11.1281(4), <i>c</i> = 25.1499(9) Å, Z = 8. The solid <b>2</b> crystallized in triclinic system with space group <i>P-</i>1, <i>a</i> = 7.1986(5), <i>b</i> = 7.3917(5), <i>c</i> = 7.8896(6) Å, <i>α</i> = 115.758(3), <i>β</i> = 110.450(3), <i>γ</i> = 96.904(3)°, Z = 1. While, solid <b>1</b> is a new Anderson–Evans cluster based solid, <b>2</b> is a new pseudopolymorph of cobalt complex [Co(2-<i>ampz</i>)<sub>4</sub>Cl<sub>2</sub>]. Crystal structure analysis suggested that supramolecular interactions facilitate the crystal packing in solids <b>1</b> and <b>2</b>. In addition, the role of synthetic parameters in dictating the nature of self-assembly of solids <b>1</b> and <b>2</b> in aqueous medium has also been analyzed.</p><h3>Graphical Abstract</h3><p>An Anderson–Evans cluster based solid, {H<i>pz</i>}<sub>2</sub>[H<sub>7</sub>CrMo<sub>6</sub>O<sub>24</sub>]·6H<sub>2</sub>O (<b>1</b>) and a new pseudopolymorph of cobalt complex [Co(2-<i>ampz</i>)<sub>4</sub>Cl<sub>2</sub>] viz<i>.</i> [Co(2-H<i>ampz</i>)<sub>2</sub>Cl<sub>4</sub>] (<b>2</b>) have been synthesized using pyrazole (<i>pz</i>) and 2-aminopyrazine (2-<i>ampz</i>) respectively.</p>\u0000 <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\u0000 </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"236 - 243"},"PeriodicalIF":0.8,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4058051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Crystal Structure Analysis of NH4[Zn(cma)(H2O)2]·H2O Using IAM and HAR Approaches 用IAM和HAR方法合成NH4[Zn(cma)(H2O)2]·H2O及其晶体结构分析
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-09-10 DOI: 10.1007/s10870-022-00961-1
Jana Chrappová, Yogeswara Rao Pateda, Erik Rakovský

The crystal structure of NH4[Zn(cma)(H2O)2]·H2O (cma3– = N-carboxymethylaspartate(3–)) is determined by single crystal X-ray structure analysis. The orthorombic crystals (P212121, a = 7.7901(4) Å, b = 11.2368(4) Å, c = 13.2048(5) Å, α = β = γ = 90°, Z = 4) were obtained from the reaction mixture in the form of racemic conglomerate. The single crystal X-ray structure analysis revealed the maximum deviation of bond angles around the Zn atom from an ideal octahedral geometry 14.09° with  = 67.23° and Θ = 236.69°. Intermolecular interactions are based mainly on a moderate N–H⋯O and O–H⋯O hydrogen bonds. The structure shares similar structural features with other structures containing aspartates and their derivatives as a ligands. The results of using different HAR methods based on semi-empirical (B3LYP) and non-empirical (PBE0) global hybrid GGA DFT functionals were compared.

Graphical Abstract

The crystal structure of NH4[Zn(cma)(H2O)2]·H2O (cma3– = N-carboxymethylaspartate(3–)) is determined by single crystal X-ray structure analysis. The orthorombic crystals (P212121, a = 7.7901(4) Å, b = 11.2368(4) Å, c = 13.2048(5) Å, α = β = γ = 90°, Z = 4) were obtained from the reaction mixture in the form of racemic conglomerate.

用单晶x射线结构分析确定了NH4[Zn(cma)(H2O)2]·H2O (cma3 - = n -羧甲基天冬氨酸(3 -))的晶体结构。从反应混合物中得到正方晶(P212121, a = 7.7901(4) Å, b = 11.2368(4) Å, c = 13.2048(5) Å, α = β = γ = 90°,Z = 4)。单晶x射线结构分析表明,锌原子周围的键角最大偏离理想八面体构型14.09°,∑= 67.23°,Θ = 236.69°。分子间相互作用主要基于适度的N-H⋯O和O - h⋯O氢键。该结构与其他以天冬氨酸及其衍生物为配体的结构具有相似的结构特征。比较了基于半经验(B3LYP)和非经验(PBE0)全局混合GGA DFT泛函的HAR方法的结果。摘要用单晶x射线结构分析方法测定了NH4[Zn(cma)(H2O)2]·H2O (cma3 - = n -羧甲基天冬氨酸(3 -))的晶体结构。从反应混合物中得到正方晶(P212121, a = 7.7901(4) Å, b = 11.2368(4) Å, c = 13.2048(5) Å, α = β = γ = 90°,Z = 4)。
{"title":"Synthesis and Crystal Structure Analysis of NH4[Zn(cma)(H2O)2]·H2O Using IAM and HAR Approaches","authors":"Jana Chrappová,&nbsp;Yogeswara Rao Pateda,&nbsp;Erik Rakovský","doi":"10.1007/s10870-022-00961-1","DOIUrl":"10.1007/s10870-022-00961-1","url":null,"abstract":"<div><p>The crystal structure of NH<sub>4</sub>[Zn(<i>cma</i>)(H<sub>2</sub>O)<sub>2</sub>]·H<sub>2</sub>O (<i>cma</i><sup>3–</sup> = N-carboxymethylaspartate(3–)) is determined by single crystal X-ray structure analysis. The orthorombic crystals (<i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>, <i>a</i> = 7.7901(4) Å, <i>b</i> = 11.2368(4) Å, <i>c</i> = 13.2048(5) Å, <i>α</i> = <i>β</i> = <i>γ</i> = 90°, <i>Z</i> = 4) were obtained from the reaction mixture in the form of racemic conglomerate. The single crystal X-ray structure analysis revealed the maximum deviation of bond angles around the Zn atom from an ideal octahedral geometry 14.09° with <i>∑</i> = 67.23° and <i>Θ</i> = 236.69°. Intermolecular interactions are based mainly on a moderate N–H⋯O and O–H⋯O hydrogen bonds. The structure shares similar structural features with other structures containing aspartates and their derivatives as a ligands. The results of using different HAR methods based on semi-empirical (B3LYP) and non-empirical (PBE0) global hybrid GGA DFT functionals were compared.</p><h3>Graphical Abstract</h3><p>The crystal structure of NH<sub>4</sub>[Zn(<i>cma</i>)(H<sub>2</sub>O)<sub>2</sub>]·H<sub>2</sub>O (<i>cma</i><sup>3–</sup> = N-carboxymethylaspartate(3–)) is determined by single crystal X-ray structure analysis. The orthorombic crystals (<i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>, <i>a</i> = 7.7901(4) Å, <i>b</i> = 11.2368(4) Å, <i>c</i> = 13.2048(5) Å, <i>α</i> = <i>β</i> = <i>γ</i> = 90°, <i>Z</i> = 4) were obtained from the reaction mixture in the form of racemic conglomerate.</p>\u0000 <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\u0000 </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"228 - 235"},"PeriodicalIF":0.8,"publicationDate":"2022-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4743826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Synthesis, Crystal Structure Determination and Electrochemistry of Homoleptic Pd(0) Complexes Supported by Normal and Abnormal N-Heterocyclic Carbene Ligands 正常和异常n -杂环碳烯配体负载的同色Pd(0)配合物的合成、晶体结构测定和电化学
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-09-08 DOI: 10.1007/s10870-022-00962-0
Nurul Amin SK, Bibaswan Sen, Sk Jahir Abbas, Sk Imran Ali

Abnormal carbene complex of Pd(L1)2, where L1 = 1,3-Bis(2,6-diisopropylphenyl)-2,4-diphenylimidazole and normal carbene complex of Pd(L2)2, where L2 = 1,3-dimesityl-4,9-dioxonaphtho-2,3-diimidazole were prepared from a Pd(0) precursor Pd(COD)(CH2TMS)2. Both the complexes crystalize in the triclinic space group P-1 and cell parameters of Pd(L1)2 and Pd(L2)2 are a = 12.0477 Å, b = 17.5269 Å, c = 18.9786 Å, α = 114.4855°, β = 92.5295°, γ = 107.9472° and a = 11.5007 Å, b = 15.2316 Å, c = 17.9007 Å, α = 67.061°, β = 72.143°, γ = 72.183° respectively. In both case N-heterocyclic ligands are distorted towards palladium direction. Further, crystal structures reveal that the palladium atom is covalently bonded to the two aNHC and nNHC ligands respectively. The electrochemical properties of these complexes were determined by cyclic voltammetry analysis in THF solution under argon atmosphere. The enunciated reversibility of the complexes can be explained by sequential one electron oxidations of the palladium centre from Pd(0) to Pd(I) and then Pd(II).

Graphical Abstract

Abnormal carbene complex of Pd(L1)2, where L1 = 1,3-Bis(2,6-diisopropylphenyl)-2,4-diphenylimidazole and normal carbene complex of Pd(L2)2, where L2 = 1,3-dimesityl-4,9-dioxonaphtho-2,3-diimidazole were prepared from a Pd(0) precursor of Pd(COD)(CH2TMS)2. The crystal structures were determined by single crystal X-ray diffraction data and electrochemical properties were also determined by cyclic voltammetric analysis.

以Pd(0)前体Pd(COD)(CH2TMS)2为原料,制备了Pd(L1)2的异常卡宾配合物(L1 = 1,3-二(2,6-二异丙基苯基)-2,4-二苯咪唑)和Pd(L2)2的正常卡宾配合物(L2 = 1,3-基-4,9-二恶萘弗-2,3-二咪唑)。Pd(L1)2和Pd(L2)2的晶胞参数分别为a = 12.0477 Å, b = 17.5269 Å, c = 18.9786 Å, α = 114.4855°,β = 92.5295°,γ = 107.9472°和a = 11.5007 Å, b = 15.2316 Å, c = 17.9007 Å, α = 67.061°,β = 72.143°,γ = 72.183°。在这两种情况下,n -杂环配体都向钯方向扭曲。此外,晶体结构表明钯原子分别与两个aNHC和nNHC配体共价结合。用循环伏安法测定了这些配合物在THF溶液中氩气氛下的电化学性能。配合物明显的可逆性可以用钯中心从Pd(0)到Pd(I)再到Pd(II)的连续单电子氧化来解释。摘要以Pd(COD)(CH2TMS)2的Pd(0)前驱体为原料,制备了Pd(L1)2的正卡宾配合物(L1 = 1,3-二(2,6-二异丙基苯基)-2,4-二苯咪唑)和Pd(L2)2的正卡宾配合物(L2 = 1,3-基-4,9-二恶萘磺-2,3-二咪唑)。用x -射线单晶衍射测定了晶体结构,并用循环伏安法测定了电化学性能。
{"title":"Synthesis, Crystal Structure Determination and Electrochemistry of Homoleptic Pd(0) Complexes Supported by Normal and Abnormal N-Heterocyclic Carbene Ligands","authors":"Nurul Amin SK,&nbsp;Bibaswan Sen,&nbsp;Sk Jahir Abbas,&nbsp;Sk Imran Ali","doi":"10.1007/s10870-022-00962-0","DOIUrl":"10.1007/s10870-022-00962-0","url":null,"abstract":"<div><p>Abnormal carbene complex of Pd(L1)<sub>2</sub>, where L1 = 1,3-Bis(2,6-diisopropylphenyl)-2,4-diphenylimidazole and normal carbene complex of Pd(L2)<sub>2</sub>, where L2 = 1,3-dimesityl-4,9-dioxonaphtho-2,3-diimidazole were prepared from a Pd(0) precursor Pd(COD)(CH<sub>2</sub>TMS)<sub>2</sub>. Both the complexes crystalize in the triclinic space group <i>P</i>-1 and cell parameters of Pd(L1)<sub>2</sub> and Pd(L2)<sub>2</sub> are <i>a</i> = 12.0477 Å, <i>b</i> = 17.5269 Å, <i>c</i> = 18.9786 Å, <i>α</i> = 114.4855°, <i>β</i> = 92.5295°, <i>γ</i> = 107.9472° and <i>a</i> = 11.5007 Å, <i>b</i> = 15.2316 Å, <i>c</i> = 17.9007 Å, <i>α</i> = 67.061°, <i>β</i> = 72.143°, <i>γ</i> = 72.183° respectively. In both case N-heterocyclic ligands are distorted towards palladium direction. Further, crystal structures reveal that the palladium atom is covalently bonded to the two aNHC and nNHC ligands respectively. The electrochemical properties of these complexes were determined by cyclic voltammetry analysis in THF solution under argon atmosphere. The enunciated reversibility of the complexes can be explained by sequential one electron oxidations of the palladium centre from Pd(0) to Pd(I) and then Pd(II).</p><h3>Graphical Abstract</h3><p>Abnormal carbene complex of Pd(L1)<sub>2</sub>, where L1 = 1,3-Bis(2,6-diisopropylphenyl)-2,4-diphenylimidazole and normal carbene complex of Pd(L2)<sub>2</sub>, where L2 = 1,3-dimesityl-4,9-dioxonaphtho-2,3-diimidazole were prepared from a Pd(0) precursor of Pd(COD)(CH<sub>2</sub>TMS)<sub>2</sub>. The crystal structures were determined by single crystal X-ray diffraction data and electrochemical properties were also determined by cyclic voltammetric analysis.</p>\u0000 <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\u0000 </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"217 - 227"},"PeriodicalIF":0.8,"publicationDate":"2022-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10870-022-00962-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4368742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dinuclear Azide-Bridged Copper(II) Polymer With Azido···π(pyridiyl) Interaction: Synthesis, Crystal Structure and Hirshfeld Surface Analysis 具有叠氮基···π(吡啶二基)相互作用的双核叠氮桥接铜(II)聚合物:合成、晶体结构和赫希菲尔德表面分析
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-09-07 DOI: 10.1007/s10870-022-00960-2
Layachi Merabet, Zouaoui Setifi, Hela Ferjani, David K. Geiger, Christopher Glidewell, Sibel Demir Kanmazalp, Fatima Setifi, Lakhemici Kaboub

A new coordination polymer of coper (II), [tetra-azido)tris(2-pyridyl)amine)dicopper(II)] (1) has been synthesized by the reaction between copper(II) nitrate hexahydrate, sodium azide and tris(2-pyridyl)amine under solvothermal conditions in aqueous methanol. The structure has been characterized by single-crystal X-ray diffraction. An analysis of Hirschfeld surfaces was examined. Single-crystal results reveals that the structure contains two independent copper(II) centers, both having approximately square pyramidal coordination: in one, two of the basal sites are occupied by bidentate tris-(2-pyridyl)amine and two azido ligands, with a third azido ligand at the apical site, while the other center is coordinated only by azido ligands. All azido ligands bind two copper centers, forming a coordination polymer chain with two types of Cu2N2 rings and one type of Cu4N4 ring, and in which all azido ligands form a bridge between two metal centers in mode µ-1,1. The Hirshfeld analysis revealed an azido··· (pyridyl) interaction in the coordination polymer chain, as well as weak C-H···N interactions, one of which links the chains into sheets.

Index Abstract

A new dinuclear copper (II) polymer [tetra-azido(tris(2-pyridyl)amine)dicopper(II)] (1) has been synthesized under solvothermal conditions and been characterized by single-crystal X-ray diffraction and Hirshfeld surface analysis.

The molecular structure of (1)

以六水硝酸铜(II)、叠氮化钠和三(2-吡啶基)胺为原料,在溶剂热条件下在甲醇水溶液中合成了一种新的铜(II)配位聚合物[四叠氮]三(2-吡啶基)胺二铜(II)](1)。用单晶x射线衍射对其结构进行了表征。对赫希菲尔德曲面进行了分析。单晶结果表明,该结构包含两个独立的铜(II)中心,它们都具有近似的方锥体配位:其中一个中心的两个基位被双齿三-(2-吡啶基)胺和两个叠氮配体占据,其中第三个叠氮配体位于顶端位置,而另一个中心仅由叠氮配体配位。所有的叠氮配体结合两个铜中心,形成两种Cu2N2环和一种Cu4N4环的配位聚合物链,其中所有的叠氮配体在两个金属中心之间以μ -1,1模式形成桥接。Hirshfeld分析发现配位聚合物链中存在叠氮···(吡啶基)相互作用,以及弱的C-H··N相互作用,其中一个相互作用将链连接成薄片。摘要在溶剂热条件下合成了一种新的双核铜(II)聚合物[四叠氮(三(2-吡啶基)胺)二铜(II)](1),并用单晶x射线衍射和Hirshfeld表面分析对其进行了表征。(1)分子结构
{"title":"Dinuclear Azide-Bridged Copper(II) Polymer With Azido···π(pyridiyl) Interaction: Synthesis, Crystal Structure and Hirshfeld Surface Analysis","authors":"Layachi Merabet,&nbsp;Zouaoui Setifi,&nbsp;Hela Ferjani,&nbsp;David K. Geiger,&nbsp;Christopher Glidewell,&nbsp;Sibel Demir Kanmazalp,&nbsp;Fatima Setifi,&nbsp;Lakhemici Kaboub","doi":"10.1007/s10870-022-00960-2","DOIUrl":"10.1007/s10870-022-00960-2","url":null,"abstract":"<div><p>A new coordination polymer of coper (II), [tetra-azido)tris(2-pyridyl)amine)dicopper(II)] (<b>1</b>) has been synthesized by the reaction between copper(II) nitrate hexahydrate, sodium azide and tris(2-pyridyl)amine under solvothermal conditions in aqueous methanol. The structure has been characterized by single-crystal X-ray diffraction. An analysis of Hirschfeld surfaces was examined. Single-crystal results reveals that the structure contains two independent copper(II) centers, both having approximately square pyramidal coordination: in one, two of the basal sites are occupied by bidentate tris-(2-pyridyl)amine and two azido ligands, with a third azido ligand at the apical site, while the other center is coordinated only by azido ligands. All azido ligands bind two copper centers, forming a coordination polymer chain with two types of Cu2N2 rings and one type of Cu4N4 ring, and in which all azido ligands form a bridge between two metal centers in mode µ-1,1. The Hirshfeld analysis revealed an azido··· (pyridyl) interaction in the coordination polymer chain, as well as weak C-H···N interactions, one of which links the chains into sheets.</p><h3>Index Abstract</h3><p>A new dinuclear copper (II) polymer [tetra-azido(tris(2-pyridyl)amine)dicopper(II)] (1) has been synthesized under solvothermal conditions and been characterized by single-crystal X-ray diffraction and Hirshfeld surface analysis.</p>\u0000 <figure><div><div><div><picture><source><img></source></picture></div><div><p>The molecular structure of (1)</p></div></div></div></figure>\u0000 </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"209 - 216"},"PeriodicalIF":0.8,"publicationDate":"2022-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4642143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Synthesis, Structure, and Reactivity of Triosmium Clusters Bearing a Metalated Dialkyl-substituted Pyrazine Ligand 含金属化二烷基取代吡嗪配体的三锇簇的合成、结构和反应性
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-09-05 DOI: 10.1007/s10870-022-00958-w
Md. Mahbub Alam, Fahima Islam, Subas Rajbangshi, Kazi A. Azam, Shishir Ghosh, Vladimir N. Nesterov, Michael G. Richmond, Shariff E. Kabir

Reactions of two dialkyl-substituted pyrazine ligands with a triosmium cluster are described. Both 2-ethyl-3-methylpyrazine (C4H2N2MeEt) and 2,5-dimethylpyrazine (C4H2N2Me2) react with the labile triosmium cluster [Os3(CO)10(NCMe)2] at 80 °C to afford [HOs3(CO)10(µ-C4HN2MeEt)] (1) and [HOs3(CO)10(µ-C4HN2Me2)] (2), respectively. Clusters 1 and 2 are formed via C–H bond activation at the α-carbon of the corresponding pyrazine ligand. Cluster 2 reacts with PPh3 at room temperature in the presence of Me3NO‧2H2O to yield the mono- and diphosphine-substituted clusters [HOs3(CO)9(PPh3)(µ-C4HN2Me2)] (3) and [HOs3(CO)8(PPh3)2(µ-C4HN2Me2)] (4), respectively, both of which exist in more than one isomeric form in solution. All new clusters have been characterized using spectroscopic methods together with single-crystal X-ray diffraction studies for 1, 2, and 4. The bonding in these clusters have been investigated by electronic structure calculations.

Graphical Abstract

Two new triosmium clusters bearing a metalated pyrazineligand have been synthesized and structurally characterized.The reactivity of one of these newly synthesized clusters towards PPh3 has also been investigated.

描述了两种二烷基取代吡嗪配体与三锇簇的反应。2-乙基-3-甲基吡嗪(C4H2N2MeEt)和2,5-二甲基吡嗪(C4H2N2Me2)在80℃下与不稳定的三聚氰铵簇[Os3(CO)10(NCMe)2]反应,分别生成[HOs3(CO)10(µ-C4HN2MeEt)](1)和[HOs3(CO)10(µ-C4HN2Me2)](2)。簇1和簇2是通过相应吡嗪配体α-碳上的C-H键活化形成的。簇2在Me3NO·2H2O存在下与PPh3在室温下反应,分别生成单膦和二膦取代簇[HOs3(CO)9(PPh3)(µ- c4hn2me2)](3)和[HOs3(CO)8(PPh3)2(µ- c4hn2me2)](4),两者在溶液中以不止一种异构形式存在。所有的新团簇都使用光谱方法和单晶x射线衍射研究来表征1、2和4。通过电子结构计算研究了这些团簇中的键合。摘要合成了两个新的含金属化吡嗪配体的三锇簇,并对其进行了结构表征。研究了其中一种新合成的簇对PPh3的反应性。
{"title":"Synthesis, Structure, and Reactivity of Triosmium Clusters Bearing a Metalated Dialkyl-substituted Pyrazine Ligand","authors":"Md. Mahbub Alam,&nbsp;Fahima Islam,&nbsp;Subas Rajbangshi,&nbsp;Kazi A. Azam,&nbsp;Shishir Ghosh,&nbsp;Vladimir N. Nesterov,&nbsp;Michael G. Richmond,&nbsp;Shariff E. Kabir","doi":"10.1007/s10870-022-00958-w","DOIUrl":"10.1007/s10870-022-00958-w","url":null,"abstract":"<div><p>Reactions of two dialkyl-substituted pyrazine ligands with a triosmium cluster are described. Both 2-ethyl-3-methylpyrazine (C<sub>4</sub>H<sub>2</sub>N<sub>2</sub>MeEt) and 2,5-dimethylpyrazine (C<sub>4</sub>H<sub>2</sub>N<sub>2</sub>Me<sub>2</sub>) react with the labile triosmium cluster [Os<sub>3</sub>(CO)<sub>10</sub>(NCMe)<sub>2</sub>] at 80 °C to afford [HOs<sub>3</sub>(CO)<sub>10</sub>(µ-C<sub>4</sub>HN<sub>2</sub>MeEt)] (<b>1</b>) and [HOs<sub>3</sub>(CO)<sub>10</sub>(µ-C<sub>4</sub>HN<sub>2</sub>Me<sub>2</sub>)] (<b>2</b>), respectively. Clusters <b>1</b> and <b>2</b> are formed <i>via</i> C–H bond activation at the α-carbon of the corresponding pyrazine ligand. Cluster <b>2</b> reacts with PPh<sub>3</sub> at room temperature in the presence of Me<sub>3</sub>NO‧2H<sub>2</sub>O to yield the mono- and diphosphine-substituted clusters [HOs<sub>3</sub>(CO)<sub>9</sub>(PPh<sub>3</sub>)(µ-C<sub>4</sub>HN<sub>2</sub>Me<sub>2</sub>)] (<b>3</b>) and [HOs<sub>3</sub>(CO)<sub>8</sub>(PPh<sub>3</sub>)<sub>2</sub>(µ-C<sub>4</sub>HN<sub>2</sub>Me<sub>2</sub>)] (<b>4</b>), respectively, both of which exist in more than one isomeric form in solution. All new clusters have been characterized using spectroscopic methods together with single-crystal X-ray diffraction studies for <b>1</b>, <b>2</b>, and <b>4</b>. The bonding in these clusters have been investigated by electronic structure calculations.</p><h3>Graphical Abstract</h3><p>Two new triosmium clusters bearing a metalated pyrazine\u0000ligand have been synthesized and structurally characterized.\u0000The reactivity of one of these newly synthesized clusters towards PPh<sub>3</sub> has also been investigated.</p>\u0000 <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\u0000 </div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"197 - 208"},"PeriodicalIF":0.8,"publicationDate":"2022-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4231258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystal Structure Characterization, Interaction Energy Analysis and DFT Studies of 3-(4-Chlorophenyl)-N-phenylquinoxalin-2-amine 3-(4-氯苯基)- n-苯基喹啉-2-胺晶体结构表征、相互作用能分析和DFT研究
IF 0.8 4区 化学 Q4 CRYSTALLOGRAPHY Pub Date : 2022-08-16 DOI: 10.1007/s10870-022-00959-9
P. Akhileshwari, K. R. Kiran, M. A. Sridhar, M. P. Sadashiva

The title compound is synthesized, and characterized by spectroscopic and XRD methods. The compound crystallizes in the orthorhombic crystal system with the space group P212121. The structure exhibits C–H⋯N intermolecular interaction and π⋯π interactions. Hirshfeld surface analysis was performed to determine the individual contributions of intermolecular contacts to the crystal packing. The structural and electronic properties of the molecule were investigated by density functional theory method with B3LYP hybrid functional. Intramolecular interactions involved in the crystal structure was analyzed through topological atom-in-molecules analysis and noncovalent interactions method. Molecular electrostatic potential surface shows the chemical reactive regions around the nitrogen and hydrogen atoms.

The article presents the characterization of synthesized compound by single crystal X-ray diffractionmethod. Atom-in-molecules analysis and noncovalent interactions Intramolecularinteractions involved in the crystal structure were analyzed by DFT method.

合成了标题化合物,并用光谱和XRD方法对其进行了表征。该化合物在具有空间群P212121的正交晶系中结晶。该结构表现出C-H⋯N分子间相互作用和π⋯π相互作用。赫希菲尔德表面分析是为了确定分子间接触对晶体堆积的个别贡献。采用B3LYP杂化泛函的密度泛函方法研究了该分子的结构和电子性质。通过拓扑原子-分子分析和非共价相互作用方法分析了分子内相互作用对晶体结构的影响。分子静电势面显示了氮和氢原子周围的化学反应区。本文用单晶x射线衍射法对合成的化合物进行了表征。用DFT方法分析了分子内原子相互作用和分子内非共价相互作用对晶体结构的影响。
{"title":"Crystal Structure Characterization, Interaction Energy Analysis and DFT Studies of 3-(4-Chlorophenyl)-N-phenylquinoxalin-2-amine","authors":"P. Akhileshwari,&nbsp;K. R. Kiran,&nbsp;M. A. Sridhar,&nbsp;M. P. Sadashiva","doi":"10.1007/s10870-022-00959-9","DOIUrl":"10.1007/s10870-022-00959-9","url":null,"abstract":"<p>The title compound is synthesized, and characterized by spectroscopic and XRD methods. The compound crystallizes in the orthorhombic crystal system with the space group <i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>. The structure exhibits C–H⋯N intermolecular interaction and π⋯π interactions. Hirshfeld surface analysis was performed to determine the individual contributions of intermolecular contacts to the crystal packing. The structural and electronic properties of the molecule were investigated by density functional theory method with B3LYP hybrid functional. Intramolecular interactions involved in the crystal structure was analyzed through topological atom-in-molecules analysis and noncovalent interactions method. Molecular electrostatic potential surface shows the chemical reactive regions around the nitrogen and hydrogen atoms.</p><p>The article presents the characterization of synthesized compound by single crystal X-ray diffraction\u0000method. Atom-in-molecules analysis and noncovalent interactions Intramolecular\u0000interactions involved in the crystal structure were analyzed by DFT method.</p>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 2","pages":"185 - 196"},"PeriodicalIF":0.8,"publicationDate":"2022-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10870-022-00959-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4636628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of Chemical Crystallography
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1