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Morphology and structure study of polygon ZnO nanorods: Biomedical applications 多边形ZnO纳米棒的形态和结构研究:生物医学应用
Pub Date : 2021-01-01 DOI: 10.25082/MER.2021.01.001
Parastoo Khalili, M. Farahmandjou
In this study, zinc oxide (ZnO) nanoparticles (NPs) were first synthesized using co-precipitation method in the presence of Zn(NO3)2.6H2O precursor and calcined at different temperature of 450 oC and 1000 oC. Samples were then characterized by x-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The XRD study revealed the hexagonal wurtzite structure for annealed samples. SEM images showed tthat he morphology of the ZnO NPs changed from sphere-like shape to polygon shape by increasing temperature. The exact size of NPs were measured by TEM analysis about 40 nm for as-prepared samples. The EDS analysis demonstrated an increasing level of Zn element from 28.5 wt% to 50.8 wt% for as-synthesized and annealed samples, respectively.
本研究首先在Zn(NO3)2.6H2O前驱体存在下,采用共沉淀法合成氧化锌纳米颗粒(NPs),并在450℃和1000℃的不同温度下煅烧。然后用x射线衍射(XRD)、透射电子显微镜(TEM)、能谱(EDS)和扫描电子显微镜(SEM)对样品进行表征。XRD分析表明,退火后的样品具有六方纤锌矿结构。SEM图像显示,随着温度的升高,ZnO纳米粒子的形貌由球状变为多边形。用透射电镜对制备的样品测定了NPs的确切尺寸,约为40 nm。EDS分析表明,合成样品和退火样品的锌元素含量分别从28.5 wt%增加到50.8 wt%。
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引用次数: 0
Structural, electrical, and magnetic characterization of (1-x) BaTiO3-x Ni0.6Zn0.4Fe2O4 multiferroic ceramic composites (1-x) BaTiO3-x Ni0.6Zn0.4Fe2O4多铁陶瓷复合材料的结构、电学和磁性表征
Pub Date : 2021-01-01 DOI: 10.25082/mer.2021.01.002
G. Mowla, N. Hossain, M. Kabir, M. Haque, M. Ali, M. A. Kaiyum, M. Rahman
In the present work, pure BaTiO3, pure Ni0.6Zn0.4Fe2O4 and (1-x)BaTiO3-xNi0.6Zn0.4Fe2O4 (where x = 0.15, 0.25 & 0.35) multiferroic composites were synthesized through solid-state sintering scheme. Structural, microstructural, ferroelectric, and ferromagnetic analysis was performed. Both tetragonal perovskite phase (for BaTiO3 ferroelectric phase) and cubic spinel ferrite phase (for Ni0.6Zn0.4Fe2O4 ferromagnetic phase) were simultaneously presented within each composite. The ferrite phase exhibited a smaller crystallite size compared to the ferroelectric phase. All of the composites demonstrated homogenous irregular-shaped grains. The measured average grain size for 0.85BaTiO3-0.15Ni0.6Zn0.4Fe2O4, 0.75BaTiO3-0.25Ni0.6Zn0.4Fe2O4, 0.65BaTiO3-0.35Ni0.6Zn0.4Fe2O4 were 364.14 nm, 378.46 nm and 351.62nm, whereas the density values were 3.04g/cm3, 3.20g/cm3 and 3.13 g/cm3 for x = 0.35, 0.25, 0.15 respectively. However, the heterogenous microstructure was observed for all of the compositions. The composites exhibited an oval-shaped lossy capacitor hysteresis loop. However, 0.75BaTiO3-0.25Ni0.6Zn0.4Fe2O4 composite showed the highest remnant polarization (11.613 μC/cm2) and coercive field value (1.526 kV/cm), ensuring its usability for switching applications. In addition, 0.75BaTiO3-0.25Ni0.6Zn0.4Fe2O4 also exhibited the maximum saturation (Ms= 1.732 emu/g) and remnant magnetization (Mr= 0.025 emu/g) among the composites. Nevertheless, all of the composites derived 'wasp-waisted' hysteresis loops due to the presence of either superparamagnetic (SPM) particles or a mixer of a single domain (SD) and superparamagnetic particles.
本文采用固相烧结法合成了纯BaTiO3、纯Ni0.6Zn0.4Fe2O4和(1-x)BaTiO3- xni0.6 zn0.4 fe2o4(其中x = 0.15、0.25和0.35)多铁复合材料。进行了结构、微观结构、铁电和铁磁分析。在每种复合材料中同时存在四方钙钛矿相(对于BaTiO3铁电相)和立方尖晶石铁素体相(对于Ni0.6Zn0.4Fe2O4铁磁相)。与铁电相相比,铁素体相的晶粒尺寸更小。所有复合材料均表现出均匀的不规则形状晶粒。0.85BaTiO3-0.15Ni0.6Zn0.4Fe2O4、0.75BaTiO3-0.25Ni0.6Zn0.4Fe2O4、0.65BaTiO3-0.35Ni0.6Zn0.4Fe2O4的平均晶粒尺寸分别为364.14 nm、378.46 nm和351.62nm,而x = 0.35、0.25、0.15时的密度分别为3.04g/cm3、3.20g/cm3和3.13 g/cm3。然而,在所有的成分中都观察到异质组织。复合材料呈现椭圆形损耗电容滞回线。而0.75BaTiO3-0.25Ni0.6Zn0.4Fe2O4复合材料则表现出最高的残余极化(11.613 μC/cm2)和矫顽力场值(1.526 kV/cm),确保了其在开关领域的可用性。此外,0.75BaTiO3-0.25Ni0.6Zn0.4Fe2O4也表现出最大的饱和度(Ms= 1.732 emu/g)和剩余磁化强度(Mr= 0.025 emu/g)。然而,由于存在超顺磁(SPM)粒子或单畴(SD)和超顺磁粒子的混合,所有的复合材料都产生了“黄蜂腰”磁滞回线。
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引用次数: 1
Benefits and problems of chrome tanning in leather processing: Approach a greener technology in leather industry 铬鞣在皮革加工中的效益与问题:探讨皮革工业的绿色技术
Pub Date : 2021-01-01 DOI: 10.25082/mer.2021.01.004
K. Maraz
Tanning is the process of converting the raw skin and hides from different animals into a sustainable and manageable material called leather. Leather making is a very long process and consists of many different chemical and mechanical process steps. The most important step of the whole leather making process is the tanning step, which is performed commonly either by vegetable or mineral tanning. More than 85-90% of the leather making is performed by chrome tanning, which is the most common type of mineral tanning currently applied.
制革是将不同动物的原始皮肤和兽皮转化为一种可持续的、可管理的材料,称为皮革的过程。皮革制作是一个非常漫长的过程,包括许多不同的化学和机械工艺步骤。整个制革过程中最重要的一步是鞣制步骤,通常采用植物鞣制或矿物鞣制。超过85-90%的皮革制作是由铬鞣制完成的,这是目前最常用的矿物鞣制。
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引用次数: 5
Mechanical properties of biofiber/glass reinforced hybrid composites produced by hand lay-up method: A review 手工铺层法制备生物纤维/玻璃增强混杂复合材料的力学性能研究进展
Pub Date : 2021-01-01 DOI: 10.25082/mer.2021.01.003
M. Razzaq, Sababa Erfan Moma, S. Rabbi
Hybrid composites utilize more than one kind of strands within the same matrix to urge the synergistic impact of both fibers' properties on composites' general properties. Hybridization can be performed from artificial, natural, and a combination of both fibers. The constituent filaments can be altered in numerous ways, driving to the variety in composite properties. Partial substitution of glass fiber with natural ones offers an advantage compared with glass fiber composites while permitting to obtain a mechanical performance higher than using pure natural fiber composites. Recently, researchers are tending towards the development of hybrid composites which will provide good static properties. In this context, a concise review has been done on the recent developments of natural/glass fiber-reinforced composites made by hand lay-up method. It includes a survey of the past research already available involving the hybrid composites and the effect of various parameters on composites' performance studied by various researchers.
混合复合材料在同一基体中使用一种以上的纤维,以促使两种纤维的性能对复合材料的一般性能产生协同影响。杂交可以从人造纤维、天然纤维和两种纤维的组合中进行。组成细丝可以以多种方式改变,从而导致复合材料性能的变化。用天然纤维部分替代玻璃纤维与玻璃纤维复合材料相比具有优势,同时可以获得比使用纯天然纤维复合材料更高的机械性能。近年来,研究人员正致力于开发具有良好静态性能的混杂复合材料。在此背景下,简要综述了手工铺层法制备天然/玻璃纤维增强复合材料的最新进展。它包括对过去已有的关于混杂复合材料的研究的综述,以及各种参数对复合材料性能的影响。
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引用次数: 3
Heat treatment effect on the distribution of organic clay in polymer nanocomposites 热处理对有机粘土在聚合物纳米复合材料中分布的影响
Pub Date : 2020-03-17 DOI: 10.25082/mer.2020.01.003
Jie Tian, Shenzhen City China Shenzhen Power Supply Co. Ltd., Yuming Zhao, Qing Ding, J. Ai, Li Shouding, Qi Cheng
In this paper, the effects of heat treatment temperature on the degree of exfoliation of organic clay under different compatibilizers were tested by using organic clay 93A, high density polyethylene (HDPE) and compatibilizer (PE-g-MA), polyethylene maleic anhydride copolymer (PEMA), maleic anhydride and polyethylene blend (MA/PE). The proportion of organic clay is 5 wt%, HDPE is 90 wt% and compatibilizer is 5 wt%. Temperature ranged from 210oC to 250oC, the position of [001] peak in the sample was determined, FESEM, TGA, FTIR and XRD was used to analyze the influence of temperature on the distribution behavior of clay in polymer system. The results are very significant for the industrial production of clay composite materials.
以有机粘土93A、高密度聚乙烯(HDPE)和相容剂(PE-g-MA)、聚乙烯-马来酸酐共聚物(PEMA)、马来酸酐和聚乙烯共混物(MA/PE)为试材,研究了热处理温度对不同相容剂作用下有机粘土剥离度的影响。有机粘土的比例为5wt%,HDPE为90wt%,相容剂为5wt%。温度范围为210℃至250℃,测定了[001]峰在样品中的位置,利用FESEM、TGA、FTIR和XRD分析了温度对粘土在聚合物体系中分布行为的影响。研究结果对粘土复合材料的工业化生产具有重要意义。
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引用次数: 0
Development of advanced high strength steels using hydrogen quench continuous annealing technology 采用氢淬连续退火技术开发先进高强度钢
Pub Date : 2019-08-23 DOI: 10.25082/MER.2020.01.002
F. Barrado, Tihe Zhou, C. Cathcart, P. Badgley, Sarah Zhang, David Overby
By using hydrogen quench continuous annealing technology, Stelco Inc. has developed a suite of Advanced High Strength Steel (AHSS) grades with tensile strength greater than 1000MPa to meet standard automotive specifications and for unique customer requirements. These grades were optimized by correlating chemical composition and processing parameters with microstructures and mechanical properties. Dual-Phase 980 (Stelco trademarked STELMAXTM 980DP), Multi-Phase 1180 (STELMAXTM 1180MP), Martensitic Steel 1300 (STELMAXTM 1300M) and 1500 (STELMAXTM 1500M) products met strength and formability requirements with excellent flatness and surface quality. Hydrogen quench continuous annealing technology not only ensures all developed AHSS grades have consistent mechanical properties across the entire strip length (from strip head to tail) and width (from edge to edge), but also produces high product yield compared with other continuous annealing processes.
通过使用氢淬火连续退火技术,Stelco股份有限公司开发了一套拉伸强度大于1000MPa的高级高强度钢(AHSS)等级,以满足标准汽车规范和独特的客户要求。通过将化学成分和工艺参数与微观结构和机械性能相关联,对这些等级进行了优化。双相980(Stelco商标STELMAXTM 980DP)、多相1180(STELMAXTM1180MP)、马氏体钢1300(STELMEXTM1300M)和1500(STELMXTM1500M)产品满足强度和成形性要求,具有优异的平面度和表面质量。氢淬火连续退火技术不仅确保所有开发的AHSS等级在整个带钢长度(从带钢头到带钢尾)和宽度(从带钢边缘到带钢边缘)上具有一致的机械性能,而且与其他连续退火工艺相比,产品产量也很高。
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引用次数: 1
A brief review on natural fiber used as a replacement of synthetic fiber in polymer composites 天然纤维在高分子复合材料中替代合成纤维的研究进展
Pub Date : 2019-07-17 DOI: 10.25082/MER.2019.02.007
Fatin I. Mahir, Kamrun Keya, Bijoy Sarker, Khandakar M. Nahiun, R. Khan
The use of composites in different sectors has become inevitable due to the enhancement in properties, reduction in the manufacturing cost and suitability to several applications. Among different classifications, polymeric composites are mainly focused on their use as structural components and the selection and composition of reinforcement play a vital role in determining the characteristics of the composite. Although composites are developed with man-made reinforcement in the beginning stage, in the present situation, natural reinforcements have proved excellent results in terms of properties. Hence, nowadays researches are mainly focused on the use of different natural fibers in different forms as reinforcements in a polymeric composite. This work presents a brief overview of the properties of natural fiber and natural fiber reinforced composites which is an emerging area in polymer science. Interests in natural fiber are reasonable due to the advantages of these materials compared to others, such as synthetic fiber composites, including low environmental impact and low cost and support their potential to be used. Moreover, the disadvantage of the synthetic and fiberglass as reinforcement, the use of natural fiber reinforced composite gained the attention of the young scientists, researchers, and engineers and are being exploited as a replacement for the conventional fiber such as glass, aramid, carbon, etc. Natural fibers have been proven alternative to synthetic fiber in transportation such as automobiles, railway coaches and aerospace, military, building, packaging, consumer products, and construction industries for ceiling paneling, partition boards, etc. However, in the development of these composites, some drawbacks have also emerged. In this paper, it has been tried to overview all of this together.
由于性能的提高、制造成本的降低以及对多种应用的适用性,复合材料在不同行业的使用已成为不可避免的。在不同的分类中,聚合物复合材料主要集中在其作为结构部件的用途上,增强材料的选择和组成对决定复合材料的特性起着至关重要的作用。尽管复合材料在最初阶段是用人造增强材料开发的,但在目前的情况下,天然增强材料在性能方面已经证明了良好的效果。因此,目前的研究主要集中在使用不同形式的不同天然纤维作为聚合物复合材料中的增强材料。本文简要介绍了天然纤维和天然纤维增强复合材料的性能,这是聚合物科学中的一个新兴领域。对天然纤维的兴趣是合理的,因为与合成纤维复合材料等其他材料相比,这些材料具有低环境影响和低成本的优势,并支持其使用潜力。此外,合成纤维和玻璃纤维作为增强材料的缺点,天然纤维增强复合材料的使用引起了年轻科学家、研究人员和工程师的注意,并被开发为玻璃、芳纶、碳等传统纤维的替代品。天然纤维已被证明是合成纤维的替代品,用于汽车、铁路客车和航空航天、军事、建筑、包装、消费品以及天花板、隔板等建筑行业。然而,在这些复合材料的开发过程中,也出现了一些缺点。在本文中,试图将所有这些放在一起进行概述。
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引用次数: 61
Natural fiber reinforced polymer composites: history, types, advantages, and applications 天然纤维增强聚合物复合材料:历史、类型、优势和应用
Pub Date : 2019-06-12 DOI: 10.25082/MER.2019.02.006
Kamrun Keya, Nasrin A. Kona, F. A. Koly, K. Maraz, Md. Naimul Islam, R. Khan
Nowadays, the use of natural fiber reinforced polymer-based composites is gradually increasing day by day for their many advantages for civil engineering construction applications. Due to their many advantages for polymer-based composite materials are widely used in civil construction, automobiles, aerospace, and many others. Natural fibers such as jute, kenaf, pineapple, sugarcane, hemp, oil palm, flax, and leaf, etc. are cheap, environmentally friendly, renewable, completely and partially biodegradable which can be utilized to obtain new high-performance polymer materials. These composites are having satisfactory mechanical properties (i.e. tensile properties, flexural stress-strain behavior, fracture toughness, and fracture strength) which make them more attractive than other composites. Due to easy availability and renewability, natural fibers can be used as an alternative of synthetic fibers as a reinforcing agent. The aim of this paper is to review different natural fibers reinforced based polymer composites with mechanical characterization, applications, also shows the opportunities, challenges and future demand of natural composite material towards civil applications.
目前,天然纤维增强聚合物基复合材料因其在土木工程建设中的诸多优点,其使用量日益增加。由于聚合物基复合材料具有许多优点,被广泛应用于民用建筑、汽车、航空航天等领域。黄麻、红麻、菠萝、甘蔗、大麻、油棕、亚麻、树叶等天然纤维价格低廉、环保、可再生、完全或部分可生物降解,可用于制备高性能新型高分子材料。这些复合材料具有令人满意的机械性能(即拉伸性能,弯曲应力-应变行为,断裂韧性和断裂强度),使其比其他复合材料更具吸引力。天然纤维具有易于获得和可再生的特点,可以代替合成纤维作为补强剂。本文综述了不同天然纤维增强高分子复合材料的力学特性、应用情况,并指出了天然复合材料在民用领域的机遇、挑战和未来需求。
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引用次数: 81
Elastic modulus prediction for hybrid polymer composites 杂化聚合物复合材料的弹性模量预测
Pub Date : 2019-06-03 DOI: 10.25082/MER.2019.02.005
D. Rodrigue
To improve on the mechanical properties of polymers in general, the concept of hybrid composites was developed by using two or more different reinforcements in the same matrix, or by using two or more different sizes of the same reinforcement (auto-hybrid composites). In this case, most of the literature results showed that the resulting elastic modulus can be well approximated by the simple rule of mixture (linear additive law) from the tensile modulus of each reinforcement used alone. But is some cases, a positive deviation from this linear approximation was reported up to a point where an optimum composition can give a modulus above the value of both reinforcements used separately. In this work, a simple model is presented to show that positive deviations are possible and the optimum reinforcement ratio is around 25/75 in terms of the lowest/highest reinforcing particle. The model is also compared with literature data where good qualitative agreements are obtained as a first approximation.
为了提高聚合物的力学性能,混合复合材料的概念是通过在同一基体中使用两种或两种以上不同尺寸的增强材料,或使用两种或两种以上不同尺寸的增强材料(自混合复合材料)而发展起来的。在这种情况下,大多数文献结果表明,所得弹性模量可以由单独使用的每种钢筋的拉伸模量很好地近似为简单的混合规则(线性加性定律)。但在某些情况下,从这种线性近似的正偏差被报道到一个点,在这个点上,最佳组合可以给出高于两种增强材料分别使用的值的模量。在这项工作中,提出了一个简单的模型,表明可能存在正偏差,并且就最低/最高增强颗粒而言,最佳增强比约为25/75。该模型还与文献数据进行了比较,其中获得了良好的定性一致性作为第一近似。
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引用次数: 0
Mechanical, thermal and interfacial properties of Carbon-Kevlar reinforced epoxy composite 碳-芳纶增强环氧树脂复合材料的力学、热学和界面性能
Pub Date : 2019-05-31 DOI: 10.25082/MER.2019.02.004
Milon Hossain, Kamrun Keya, Nasrin A. Kona, N. Islam, F. A. Koly, M. A. Khan, Abu Bakar Siddiquee, J. Mahmud, R. Khan
Twill woven Carbon-Kevlar (CK) fabric was reinforced in epoxy matrix by conventional hand lay-up process. The fabric weight fraction in the composites was kept around 58% and stacking sequence was varied from single to five plies. Tensile test was performed and the fracture surface after tensile test was evaluated by scanning electron microscope (SEM). The test result revealed that the tensile properties are strongly dependent on the number of plies. Three point flexural test of the composite was also carried and an increasing trend was observed. Maximum impact energy was recorded for CK3 sample by 202.7 KJ/m2. Thermal stability of the composite was studied via the thermo gravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FT-IR) result show interaction between fiber and matrix material. Finally, CK fabric reinforced epoxy-based composites showed balanced and tailor-able mechanical properties by varying the number of plies, suitable for desired applications in many areas including building, construction, marine, automotive, etc.
采用传统的手工叠层工艺,在环氧树脂基体中对斜纹碳纤维(CK)织物进行了增强处理。复合材料中的织物重量分数保持在58%左右,堆叠顺序从单层到五层不等。进行拉伸试验,并通过扫描电子显微镜(SEM)评价拉伸试验后的断裂表面。试验结果表明,拉伸性能在很大程度上取决于帘布层的数量。还对复合材料进行了三点弯曲试验,并观察到了增加的趋势。CK3样品的最大冲击能量记录为202.7 KJ/m2。通过热重分析(TGA)和傅立叶变换红外光谱(FT-IR)研究了复合材料的热稳定性。结果表明,纤维与基体材料之间存在相互作用。最后,CK织物增强环氧基复合材料通过改变层数显示出平衡和可定制的机械性能,适用于建筑、建筑、海洋、汽车等许多领域的预期应用。
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引用次数: 1
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