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Solidification/stabilization treatment of selenium in municipal solid waste incineration fly ash and its mechanisms 城市生活垃圾焚烧飞灰中硒的固化/稳定化处理及其机理
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-31 DOI: 10.1007/s10163-025-02418-x
Hailin Cao, Haitao Liu, Wenchao Ma, Luqian Weng

Municipal solid waste incineration (MSWI) fly ash is classified as hazardous waste because of its toxic constituents and requires solidification/stabilization (S/S) prior to safe landfill disposal. Selenium (Se), a particularly harmful element, presents significant environmental risks; however, research on its effective treatment remains limited, and no widely accepted remediation technology is currently available. This study evaluated the effectiveness of various S/S agents in stabilizing Se in fly ash, with a particular focus on iron micro-powder (IMP). The results indicate that IMP demonstrates superior solidification efficiency compared to conventional heavy metal chelating agents such as sodium sulfide and sodium dimethyldithiocarbamate, which exhibit negligible effectiveness. Under acidic conditions, the IMP achieved a Se stabilization rate of up to 97.6%, whereas its efficacy decreased in alkaline environments. To clarify the stabilization mechanism, the interactions between IMP and Se were examined in simulated leachates at different pH levels. SEM, EDS, and XPS analyses revealed that the primary S/S mechanism of IMP involves adsorption and reduction reactions. Specifically, the tetravalent selenium ions in solution were reduced to zero-valent selenium, which was subsequently deposited onto IMP surface, thereby achieving stabilization. Furthermore, the reaction process is significantly influenced by the environmental pH.

城市生活垃圾焚烧(MSWI)飞灰因其有毒成分而被归类为危险废物,在安全填埋处置之前需要固化/稳定化(S/S)。硒(Se)是一种特别有害的元素,具有重大的环境风险;然而,对其有效处理的研究仍然有限,目前还没有广泛接受的修复技术。本研究以铁微粉(IMP)为研究对象,评价了各种S/S剂稳定粉煤灰中硒的效果。结果表明,与传统的重金属螯合剂(如硫化钠和二甲基二硫代氨基甲酸钠)相比,IMP具有更好的凝固效率,而后者的效果可以忽略不计。在酸性条件下,IMP的硒稳定率高达97.6%,而在碱性环境下,其效果有所下降。为了阐明稳定机制,在不同pH水平的模拟渗滤液中研究了IMP和Se之间的相互作用。SEM、EDS和XPS分析表明,IMP的主要S/S机制涉及吸附和还原反应。具体而言,溶液中的四价硒离子被还原为零价硒,随后沉积在IMP表面,从而实现稳定化。此外,反应过程受环境pH值的显著影响。
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引用次数: 0
Implications of shorter sampling durations on the analysis of municipal solid waste generation and composition 缩短采样时间对分析城市固体废物产生和组成的影响
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-30 DOI: 10.1007/s10163-025-02401-6
Emenda Sembiring, Attar Hikmahtiar Ramadan, Muh Farid

Collecting samples of waste generation is essential for designing effective waste management strategies. Conducting waste generation sampling over a week or an 8-day period needs substantial demands on resources. The resource-intensive nature of extended sampling periods is notable. Shortening sampling days is beneficial and perhaps can also be cost effective. Cost-effective means reducing resource demands while maintaining the accuracy and reliability of waste generation data. The solid waste generation sampling data from two sub-districts both in Banyuwangi Regency and in Jembrana Regency, Indonesia were used for data source. Normality test and ANOVA (analysis of variance), followed by Tukey's post hoc analysis was utilized to analyze the variability among sampling duration, weekdays and weekend, and seasonal change. The generation of household wastes appears consistent in patterns over 4 or 8 days, irrespective of the sampling days falling on weekdays or weekends. When comparing the rainy and dry seasons, it was observed that only one sub-district in Muncar exhibited a statistically significant difference in waste generation. The remaining locations demonstrate no substantial statistical variation between the two seasons. This suggests a level of uniformity in waste generation across different time periods and seasonal condition, with Muncar being the sole exception.

收集废物产生的样本对于设计有效的废物管理战略至关重要。在一周或8天的时间内进行废物产生抽样需要大量资源。延长采样周期的资源密集性是值得注意的。缩短采样天数是有益的,也许也可以降低成本。成本效益意味着减少资源需求,同时保持废物产生数据的准确性和可靠性。数据来源为印度尼西亚Banyuwangi县和Jembrana县两个街道的固体废物产生抽样数据。采用正态性检验和方差分析,然后采用Tukey事后分析分析抽样时间、工作日和周末以及季节变化之间的可变性。无论取样日是平日还是周末,在4天或8天内,家庭废物的产生模式似乎是一致的。在比较雨季和旱季时,观察到芒卡只有一个街道在废物产生量上有统计学上的显著差异。其余地点在两个季节之间没有明显的统计差异。这表明,在不同的时间段和季节条件下,废物产生有一定程度的一致性,而芒卡是唯一的例外。
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引用次数: 0
Real-time high-accuracy sorting of imbalanced non-ferrous scraps in ELVs: a deep learning approach with small-sample optimization elv中不平衡有色金属废料的实时高精度分选:小样本优化的深度学习方法
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-29 DOI: 10.1007/s10163-025-02406-1
Rui Wang, Qiu Pang, Zhili Hu, Lin Hua

The recycling and reuse of copper and aluminum from end-of-life vehicles (ELVs) present both significant economic and environmental opportunities. However, substantial differences in the amounts of copper and aluminum used in vehicles have led to an imbalance in the quantity of small scrap samples. Effectively detecting and sorting non-ferrous scraps from ELVs remains an urgent challenge. To address these challenges, this paper proposes an improved YOLOv8 detection algorithm, integrated with a small sample enhancement method for non-ferrous scrap. Sorting software was developed for conducting the experiments. The results demonstrate that efficient image fusion can be achieved by generating targeted images for underrepresented classes and carefully designing the fusion position, size, and method. The improved YOLOv8 detection model trained on the augmented dataset achieved optimal performance, with recognition accuracies of 98.5% for aluminum scrap and 98.1% for copper scrap, and a detection speed of 50 FPS, meeting real-time detection requirements. Furthermore, the developed system and software yielded sorting accuracy of 93.3% and purity of 92.6% during the scraps sorting experiments, both exceeding the industry standard of 90%. The proposed method of recovering these metals through sorting and recycling is not only environmentally friendly and energy-efficient but also offers substantial economic advantages.

报废车辆(elv)中铜和铝的回收和再利用带来了重大的经济和环境机遇。然而,由于车辆中铜和铝的使用量存在巨大差异,导致小废料样品的数量不平衡。有效地检测和分类电气化车辆中的有色金属废料仍然是一个紧迫的挑战。为了解决这些问题,本文提出了一种改进的YOLOv8检测算法,并结合了有色金属废料的小样本增强方法。开发了分选软件进行实验。结果表明,通过对代表性不足的类别生成目标图像,并仔细设计融合位置、大小和方法,可以实现有效的图像融合。改进的YOLOv8检测模型在增强数据集上训练得到了最优的性能,对废铝和废铜的识别准确率分别达到98.5%和98.1%,检测速度达到50 FPS,满足实时检测要求。开发的系统和软件在分选实验中分选精度为93.3%,分选纯度为92.6%,均超过90%的行业标准。提出的通过分类和再循环回收这些金属的方法不仅环保和节能,而且具有巨大的经济优势。
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引用次数: 0
A circular economy enabled zero waste assessment tool for construction projects 循环经济实现建筑项目零废弃物评估工具
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-28 DOI: 10.1007/s10163-025-02407-0
Nilmini Pradeepika Weerasinghe, Lahiru Thilakarathna, Akvan Gajanayake, Dilmini Amarasooriya, Ruwini Edirisinghe, Kevin Guomin Zhang, Sujeeva Setunge

The rapid growth of construction waste combined with limited land availability, strict regulations for waste disposal, and associated health and environmental risks, has prompted the construction sector to focus on reducing waste generated due to construction activities. Zero waste is a concept closely aligned with the circular economy (CE), which aims to eliminate the generation of waste. However, achieving zero waste requires additional techniques and efforts beyond current on-site waste management practices. The lack of methods to assess a site’s progress towards zero waste by incorporating CE principles has motivated this research. The objective of this paper is to present the development of an assessment tool that can be used to assess the progress of a construction site towards zero waste. The research used a mixed methods approach combining a comprehensive literature review, semi-structured interviews, and case studies, to develop and validate the tool. The validation through case studies revealed that embedding CE principles of reduce, reuse, repurpose, recycle, and recover helps site managers take active steps towards achieving a zero-waste target. The developed tool aids construction site managers in making material-level disposal decisions and implementing managerial-level initiatives to drive zero-waste target.

建筑垃圾的迅速增长,加上土地供应有限,对废物处理的严格规定,以及相关的健康和环境风险,促使建筑部门把重点放在减少建筑活动产生的废物上。零废物是一个与循环经济密切相关的概念,旨在消除废物的产生。然而,实现零废物需要在目前现场废物管理实践之外的其他技术和努力。缺乏通过纳入CE原则来评估一个地点在零浪费方面的进展的方法,促使了这项研究。本文的目的是介绍一种评估工具的开发,该工具可用于评估建筑工地实现零废物的进展。该研究采用综合文献综述、半结构化访谈和案例研究相结合的混合方法来开发和验证该工具。通过案例研究的验证表明,嵌入减少、再利用、重新利用、再循环和回收的CE原则有助于现场管理者采取积极措施实现零浪费目标。开发的工具有助于建筑工地管理人员做出材料级处置决策,并实施管理级举措,以推动零废物目标。
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引用次数: 0
A systematic review of the potential of industrial organic by-products as black soldier fly larvae rearing substrates: nutrient content and environmental impact 工业有机副产品作为黑虻幼虫饲养基质潜力的系统综述:营养成分和环境影响
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-25 DOI: 10.1007/s10163-025-02408-z
Aulia Rodlia Fitriana, Arseto Yekti Bagastyo, Arry Febrianto, Chor Yong Tay, I. D. A. A. Warmadewanthi

An effective organic waste management can be achieved using black soldier fly (BSF) larvae, converting waste into a valuable biomass high in protein and fat content. This systematic review examined BSF bioconversion for processing industrial organic by-products, focusing on how substrate composition and type influence larvae protein and fat content. The objectives were to evaluate the potential of industrial organic by-products as BSF rearing substrates. A shortlisted number of peer-reviewed articles has been comprehensively analyzed. The results indicate that BSF bioconversion can be used to manage a variety of industrial organic by-products. The industry types in this article are divided into two categories: (1) Food Products, Beverages, and Tobacco Products; and (2) Production, Processing, and Preservation of the Meat, Fish, Fruits, Vegetables, Oils, and Fats. The nutritional composition of BSFL reared on these substrates, including total fat, protein, fatty acid and amino acid levels, was explored. The characteristics of larvae and prepupae were discussed for their potential uses. The bioconversion products can be used as animal feed, raw material in biodiesel production, cosmetics, pharmaceuticals, and biopolymers production. This article assessed the environmental impact of BSF bioconversion, encompassing greenhouse gas emissions, to determine its viability relative to other waste management methods.

利用黑兵蝇(BSF)幼虫可以实现有效的有机废物管理,将废物转化为高蛋白质和高脂肪含量的有价值的生物质。本文系统综述了生物流化床在加工工业有机副产品中的生物转化,重点研究了底物组成和类型对幼虫蛋白质和脂肪含量的影响。目的是评价工业有机副产物作为奶牛养殖基质的潜力。入围的同行评议文章已被全面分析。结果表明,生物流化床生物转化可用于多种工业有机副产物的治理。本文中的行业类型分为两大类:(1)食品、饮料、烟草制品;(二)肉、鱼、水果、蔬菜、油脂的生产、加工和保存。研究了在这些基质上饲养的肉鸡的营养组成,包括总脂肪、蛋白质、脂肪酸和氨基酸水平。讨论了其幼虫和预蛹的特性及其潜在的应用价值。生物转化产品可作为动物饲料、生物柴油生产的原料、化妆品、药品和生物聚合物生产。本文评估了生物流化床生物转化的环境影响,包括温室气体排放,以确定其相对于其他废物管理方法的可行性。
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引用次数: 0
Co-utilization of phosphogypsum and agricultural organic solid waste for production of nutrient-rich soil: an effective approach for solid waste treatment 磷石膏与农业有机固体废物协同利用生产富营养化土壤:固体废物处理的有效途径
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-23 DOI: 10.1007/s10163-025-02399-x
Changyi He, Minjie He, Guangfei Qu, Rui Xu, Jiao Wei, Yingying Cai, Xinxin Liu

Phosphogypsum (PG) is a typical by-product of producing phosphoric acid using wet process sulfuric acid, and contains organic matter, heavy metals, and fluoride as its primary impurities. However, it is rich in plant-available elements such as P and K, making it an ideal soil amendment. In the process of agricultural production, agricultural organic solid waste also poses a threat to the environment, while affecting the process of building a beautiful countryside. Traditional agricultural organic solid waste treatment methods, including landfill disposal and incineration, are resource wasteful and polluting. Landfilling could trigger geological collapse, while incineration caused atmospheric pollution and forest fires. The co-utilization of PG and organic solid waste co-pyrolyzing the mixture to produce organic nutrient-rich soil was explored by mixing corn straw and PG. This study investigated the leaching toxicity and available element content of the pyrolysis products at different temperatures, ratios, and times. The experimental results found that co-pyrolysis achieved the solidification and stabilization of harmful elements, the maximum release of plant usable forms elements under conditions of biomass addition of 20%, pyrolysis at 900℃ for 1 h. This study provides a new direction for solid waste co-resource treatment, which can effectively alleviate the environmental pollution issues associated with inorganic and organic solid waste.

Graphical Abstract

磷石膏是湿法硫酸制磷酸的典型副产物,其主要杂质为有机物、重金属和氟化物。然而,它富含植物可利用的元素,如磷和钾,使其成为理想的土壤改良剂。在农业生产过程中,农业有机固体废弃物也对环境造成了威胁,同时影响了美丽乡村的建设进程。传统的农业有机固体废物处理方法,包括填埋处置和焚烧,是资源浪费和污染。垃圾填埋会引发地质崩塌,而焚烧会造成大气污染和森林火灾。通过将玉米秸秆与PG混合,探索PG与有机固体废弃物共热解混合物制备有机富营养化土壤的共利用,研究了不同温度、比例、次数下热解产物的浸出毒性和有效元素含量。实验结果发现,共热解在生物质添加量20%、900℃热解1 h的条件下,实现了有害元素的凝固稳定,植物可用形态元素的最大释放。本研究为固体废物共资源化处理提供了新的方向,可以有效缓解与无机和有机固体废物相关的环境污染问题。图形抽象
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引用次数: 0
Correction: Effect of phosphogypsum flotation purification on anhydrite properties 修正:磷石膏浮选提纯对硬石膏性能的影响
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-22 DOI: 10.1007/s10163-025-02410-5
Changrong Liu, Hongbin Tan, Xiaoling Ma, Feihua Yang, Jixiu Zhang, Faqin Dong, Maksim Kamarou, Dmitry Moskovskikh, Valentin Romanovski
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引用次数: 0
Promoting sustainability in Urban waste management in Amman for a circular economy 促进安曼城市废物管理的可持续性,实现循环经济
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-18 DOI: 10.1007/s10163-025-02405-2
Mohammad A. Shbool, Ammar Al-Bazi, Leen S. Jebril, Noha M. Nasrallah, Salwa A. Al-Amad, Basem O. Al-Souliman

Amman, Jordan, faces escalating challenges in municipal solid waste management due to rapid urbanisation, population growth, and limited recycling participation. This study develops a novel decision-support framework that combines a System Dynamics (SD) model with fuzzy Analytic Hierarchy Process (AHP) and Artificial Neural Network (ANN) validation. The model explicitly integrates population trends, social awareness, recycling initiatives, and informal waste picker contributions into municipal waste forecasting. Social awareness was quantified using a fuzzy AHP survey of households, and its influence on source sorting behaviours was embedded as a dynamic feedback variable. Model validation demonstrates that the SD model achieved 94.3% prediction accuracy, outperforming the ANN’s 91.5%. Scenario testing showed that increasing household participation in source sorting by 20% annually reduced the growth rate of waste generation from 2.56% to 1.38%, diverting more than 60,000 tonnes from landfill by 2030. These findings underscore the critical role of behavioural interventions, beyond technical solutions, in reducing landfill dependency. By embedding social and behavioural variables within a predictive modelling framework, this study contributes a replicable tool for policymakers in Amman and other rapidly urbanising cities to advance circular economy strategies and long-term landfill planning.

由于快速的城市化、人口增长和有限的回收参与,约旦安曼在城市固体废物管理方面面临着日益严峻的挑战。本研究开发了一种新的决策支持框架,该框架将系统动力学(SD)模型与模糊层次分析法(AHP)和人工神经网络(ANN)验证相结合。该模型明确地将人口趋势、社会意识、回收倡议和非正式拾荒者的贡献纳入城市垃圾预测。采用模糊层次分析法对家庭进行量化,并将社会意识对资源分类行为的影响作为动态反馈变量嵌入。模型验证表明,SD模型的预测准确率达到94.3%,优于人工神经网络的91.5%。情景测试显示,家庭参与垃圾分类的比例每年增加20%,可将废物产生的增长率从2.56%降至1.38%,到2030年可从堆填区转移超过60,000吨废物。这些发现强调了除了技术解决方案之外,行为干预在减少对垃圾填埋场的依赖方面的关键作用。通过在预测模型框架中嵌入社会和行为变量,本研究为安曼和其他快速城市化城市的决策者提供了一个可复制的工具,以推进循环经济战略和长期垃圾填埋场规划。
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引用次数: 0
Efficient e-waste inventory management through distributed systems: a systematic review of frameworks and strategies 通过分布式系统进行有效的电子废物库存管理:对框架和战略的系统审查
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-16 DOI: 10.1007/s10163-025-02404-3
Hatim Madkhali, Haitham Assiri, Linh Nguyen, Manu Sharma, Sudhanshu Joshi, Ritu Chauhan, Omprakash Kaiwartya, Mukesh Prasad

Electronic waste (e-waste) poses environmental and health challenges, necessitating effective inventory management systems. This systematic literature review (SLR) explores the landscape of e-waste inventory and management using distributed systems, focusing on cloud, Internet of things (IoT), and blockchain. A total of 21 relevant research papers were selected and analyzed, considering factors, such as efficiency, scalability, security, transparency and traceability, advantages, limitations, and future work. The findings reveal that distributed systems, including cloud, IoT, and blockchain, offer promising solutions for optimizing e-waste management. These technologies enable enhanced operational efficiency, real-time monitoring, and data-driven decision-making. The SLR also identifies several future research opportunities. Transparency and traceability can be enhanced to track e-waste throughout the management process. Advanced data analytics techniques can extract insights from e-waste data, enabling informed decision-making and resource allocation strategies. While various studies touch upon specific components or subsystems, a holistic approach is needed to effectively manage e-waste on a scale. This includes addressing the gaps in scalability and integration of cloud computing and IoT technologies. Furthermore, the research should focus on ensuring transparency, traceability, and data security while also optimizing energy consumption for sustainable e-waste management. The identified challenges and future research opportunities serve as a roadmap for researchers to advance the field and optimize e-waste management processes toward a sustainable future.

电子废物对环境和健康构成挑战,需要有效的库存管理系统。本系统文献综述(SLR)探讨了使用分布式系统的电子废物库存和管理的前景,重点是云,物联网(IoT)和区块链。综合考虑效率、可扩展性、安全性、透明度和可追溯性、优势、局限性和未来工作等因素,共选择并分析了21篇相关研究论文。研究结果表明,包括云、物联网和区块链在内的分布式系统为优化电子废物管理提供了有前途的解决方案。这些技术能够提高作业效率、实时监控和数据驱动决策。单反还确定了几个未来的研究机会。可以提高透明度和可追溯性,以便在整个管理过程中跟踪电子废物。先进的数据分析技术可以从电子垃圾数据中提取见解,从而实现明智的决策和资源分配策略。虽然各种研究都涉及具体的组件或子系统,但需要一种全面的方法来有效地管理电子废物。这包括解决云计算和物联网技术在可扩展性和集成方面的差距。此外,研究应侧重于确保透明度、可追溯性和数据安全性,同时优化能源消耗,以实现可持续的电子废物管理。确定的挑战和未来的研究机会可以作为研究人员推进该领域和优化电子废物管理过程的路线图,以实现可持续的未来。
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引用次数: 0
Advances in the potential application of froth flotation for the recovery of graphite from spent alkaline and Zn/C batteries 泡沫浮选回收废碱电池和锌/C电池中石墨的潜在应用研究进展
IF 3 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-13 DOI: 10.1007/s10163-025-02402-5
D. Davoise, G. Gascó, P. Almendros, A. Méndez

The recovery of graphite has been investigated mainly for black mass from spent Li-ion batteries. However, less research has been performed on the graphite recovery from spent Zn/C and alkaline batteries. Graphite is a critical raw material and it is necessary to search for new secondary sources to recover it. The main advance of this research is to study the application of froth flotation for the recovery of graphite from black mass of spent Zn/C and alkaline batteries. The effect of two thermal pre-treatment processes (roasting at 340ºC and pyrolysis at 600ºC) plus an attrition stage previous froth flotation have been analyzed. Experimental results showed that pyrolysis treatment of black mass from Zn/C and alkaline batteries allows greater selectivity of graphite versus Mn/Zn minerals. This may be due to a modification of the particle size do related to the removal of the finest ones, as well as a modification of the surface chemistry of the graphite and/or manganese oxides. In addition, the thermal treatment also modifies the mineralogical composition of the Mn oxides.

Graphical abstract

研究了从废锂离子电池中回收石墨的方法。然而,从废锌/碳电池和碱性电池中回收石墨的研究较少。石墨是一种重要的原料,有必要寻找新的二次来源来回收它。本研究的主要进展是研究泡沫浮选在废锌碳电池和碱性电池黑团中回收石墨的应用。分析了两种热预处理工艺(340℃焙烧和600℃热解)加磨矿阶段前泡沫浮选的效果。实验结果表明,对Zn/C和碱性电池中的黑色物质进行热解处理,石墨比Mn/Zn矿物具有更高的选择性。这可能是由于与去除最细的颗粒有关的颗粒尺寸的改变,以及石墨和/或锰氧化物的表面化学性质的改变。此外,热处理还改变了锰氧化物的矿物组成。图形抽象
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引用次数: 0
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Journal of Material Cycles and Waste Management
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