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Lower limit law of welding windows for explosive welding of dissimilar metals 异种金属爆炸焊接用焊接窗下限规律
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30126-7
Chang-gen Shi , Xuan Yang , Yu-heng Ge , Jun You , Hong-bao Hou

The influence of explosive charge thickness on the quality of explosive welding of dissimilar metals was investigated. The lower limit law should be followed in the course of explosive welding. Three welding experiments of stainless steel (410S) and steel (Q345R) were carried out in three different kinds of explosive charge thicknesses, namely 15, 25 and 35 mm. Interfaces of morphology and mechanical properties of three samples were observed and tested. It was found that micro and small wavy bonding is mainly formed for charge thickness of 15 mm whose strength is the highest with minor deformation and few defects in the interface; small and middle wavy bonding are mainly formed for charge thickness of 25 mm whose strength is comparatively mediocre; big wavy bonding is mainly formed for charge thickness of 35 mm whose strength is the lowest. The cause of high bonding strength of the micro and small wavy interface was analyzed and verified on the basis of the results of Electron Probe Micro-Analyzer (EPMA) tests of three selected samples.

研究了不同装药厚度对异种金属爆炸焊接质量的影响。在爆炸焊接过程中应遵循下限规律。对不锈钢(410S)和钢(Q345R)在15、25、35 mm三种不同装药厚度下进行了焊接实验。对三种试样的界面形貌和力学性能进行了观察和测试。结果表明:在电荷厚度为15 mm时,主要形成微、小波状结合,其强度最高,界面变形小,缺陷少;电荷厚度为25 mm时主要形成小、中波键合,强度较一般;电荷厚度为35 mm时,主要形成大波状键合,强度最低。通过电子探针微分析仪(EPMA)对三种样品的测试结果,分析并验证了微、小波浪形界面高结合强度的原因。
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引用次数: 16
Thermal stability of retained austenite and mechanical properties of medium-Mn steel during tempering treatment 中锰钢回火过程中残余奥氏体的热稳定性及力学性能
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30123-1
Xiao-li Zhao , Yong-jian Zhang , Cheng-wei Shao , Wei-jun Hui , Han Dong

The thermal stability of retained austenite (RA) and the mechanical properties of the quenched and intercritical annealed 0.1C-5Mn steel with the starting ultrafine lamellar duplex structure of ferrite and retained austenite during tempering within the range from 200 to 500 °C were studied by X-ray diffraction (XRD), transmission electron microscopy (TEM) and tensile testing. The results showed that there was a slight decrease in the RA volume fraction with increasing tempering temperature up to 400 °C. This caused a slight increase in the ultimate tensile strength (UTS) and a slight decrease in the total elongation (TE); thus, the product of UTS to TE (UTS×TE) as high as 31 GPa • % was obtained and remained nearly unchanged. However, a portion of the RA began to decompose when tempered at 500 °C and thus caused a ∼35% decrease of the RA fraction and a ∼16% decrease of the value of UTS×TE. It is concluded that the ultrafine lamellar duplex structure is rather stable and the excellent combination of strength and ductility could be retained with tempering temperature up to 400 °C. Thus, thermal processes such as galvanization are feasible for the tested steel provided that their temperatures are not higher than 400 °C.

采用x射线衍射(XRD)、透射电镜(TEM)和拉伸试验研究了在200 ~ 500℃回火过程中,以铁素体和残余奥氏体为起始超细层状双相组织的0.1C-5Mn钢的残余奥氏体(RA)热稳定性和淬火及临界间退火后的力学性能。结果表明,当回火温度达到400℃时,RA体积分数随回火温度的升高而略有下降。这导致极限抗拉强度(UTS)略有增加,总伸长率(TE)略有下降;因此,UTS到TE (UTS×TE)的产物高达31 GPa•%,并且几乎保持不变。然而,在500℃回火时,一部分RA开始分解,从而导致RA分数下降~ 35%,UTS×TE值下降~ 16%。结果表明,当回火温度达到400℃时,超细层状双相组织具有较好的稳定性,并能保持较好的强度和塑性结合。因此,在温度不高于400°C的条件下,热处理(如镀锌)对测试钢是可行的。
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引用次数: 13
Surface microstructure control of microalloyed steel during slab casting 板坯连铸过程中微合金钢表面组织的控制
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30120-6
Li-jun Xu, Shu-lan Zhang, Chun-gen Qiu, Sheng-tao Qiu, Xing-zhong Zhang

Lots of work has been done to investigate slab surface microstructure evolution during continuous casting in order to improve hot ductility and avoid transverse cracks. The slab surface microstructure after continuous casting was characterized by optical microscopy, and the precipitation behavior was investigated by transmission electron microscopy. At the same time, the mechanical properties of the slabs were measured using a Gleeble 1500D thermal simulator and the transformation temperatures were examined by means of a thermal dilatometer. The experimental results show that homogeneous microstructure without film-like ferrites and chain-like precipitates at grain boundary can be obtained through surface intensive cooling and transverse cracks do not occur on the slab surface. For the experimental steel, fine ferrite can form at slab surface when the water flow rate is larger than 1560 L/min at vertical section. As the distance to surface increases, microstructure turned to ferrite and pearlite. Moreover, nano-size carbonitrides precipitated in the ferrite grain and the size was larger at the junction of the dislocations. The mechanical experiment results show that the hot ductility of the sample deformed at 650 °C was better than that of the sample deformed at 750 °C. The reason is that film-like ferrite formed at the grain boundary in the sample deformed at 750 °C. Thus, the slab must be cooled quickly below Ar3 to prevent the occurrence of film-like ferrite and transverse cracks on the slab surface during casting.

为了提高连铸坯的热延展性和避免横向裂纹,人们对连铸坯表面组织的演变进行了大量的研究。用金相显微镜对连铸坯的表面组织进行了表征,并用透射电镜对连铸坯的析出行为进行了研究。同时,用Gleeble 1500D热模拟器测量了板坯的力学性能,并用热膨胀仪检测了板坯的相变温度。实验结果表明:通过表面强化冷却可以获得均匀的组织,晶界处没有膜状铁素体和链状析出物,板坯表面不产生横向裂纹;对于实验钢,当垂直断面水流速度大于1560 L/min时,板坯表面可形成细铁素体。随着与表面距离的增加,组织转变为铁素体和珠光体。铁素体晶粒中有纳米碳氮化物析出,且位错交界处的碳氮化物尺寸较大。力学试验结果表明,650℃变形试样的热塑性优于750℃变形试样。原因是在750℃下变形的试样在晶界处形成了薄膜状的铁素体。因此,铸坯必须迅速冷却到Ar3以下,以防止铸坯表面出现膜状铁素体和横向裂纹。
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引用次数: 3
Robust multi-objective optimization of rolling schedule for tandem cold rolling based on evolutionary direction differential evolution algorithm 基于进化方向差分进化算法的冷连轧轧制规程鲁棒多目标优化
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30119-X
Yong Li , Lei Fang

According to the actual requirements, profile and rolling energy consumption are selected as objective functions of rolling schedule optimization for tandem cold rolling. Because of mechanical wear, roll diameter has some uncertainty during the rolling process, ignoring which will cause poor robustness of rolling schedule. In order to solve this problem, a robust multi-objective optimization model of rolling schedule for tandem cold rolling was established. A differential evolution algorithm based on the evolutionary direction was proposed. The algorithm calculated the horizontal angle of the vector, which was used to choose mutation vector. The chosen vector contained converging direction and it changed the random mutation operation in differential evolution algorithm. Efficiency of the proposed algorithm was verified by two benchmarks. Meanwhile, in order to ensure that delivery thicknesses have descending order like actual rolling schedule during evolution, a modified Latin Hypercube Sampling process was proposed. Finally, the proposed algorithm was applied to the model above. Results showed that profile was improved and rolling energy consumption was reduced compared with the actual rolling schedule. Meanwhile, robustness of solutions was ensured.

根据实际需求,选择型钢和轧制能耗作为冷连轧轧制规程优化的目标函数。由于机械磨损,轧辊直径在轧制过程中具有一定的不确定性,忽略这种不确定性将导致轧制计划的鲁棒性差。为解决这一问题,建立了冷连轧轧制规程的鲁棒多目标优化模型。提出了一种基于进化方向的差分进化算法。该算法通过计算向量的水平角度来选择突变向量。选取的矢量包含收敛方向,改变了差分进化算法中的随机变异操作。通过两个基准测试验证了算法的有效性。同时,为了保证轧制厚度在演化过程中与实际轧制计划一样呈降序排列,提出了一种改进的拉丁超立方体抽样过程。最后,将该算法应用于上述模型。结果表明,与实际轧制规程相比,改进后的轧型得到改善,轧制能耗降低。同时保证了解的鲁棒性。
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引用次数: 10
Cementites decomposition of a pearlitic ductile cast iron during graphitization annealing heat treatment 珠光体球墨铸铁在石墨化退火热处理过程中的渗碳体分解
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30124-3
Min-qiang Gao, Ying-dong Qu, Guang-long Li, Jun-hua You, Rong-de Li

Cementites decomposition of a pearlitic ductile cast iron during graphitization annealing heat treatment was investigated. Fractographies and microstructures of heat treated samples were observed using a scanning electron microscope and mechanical properties were measured by a universal tensile test machine. The results indicated that during isothermal annealing at 750 °C, the tensile strength of pearlitic ductile cast iron was increased to a peak value at 0.5 h, and decreased gradually thereafter but the elongation was enhanced with the increase of annealing time. Moreover, the diffusion coefficient of carbon atoms could be approximately calculated as 0.56 µm2/s that could be regarded as the shortrange diffusion. As the holding time was short (0. 5 h), diffusion of carbon atoms was incomplete and mainly occurred around the graphites where the morphology of cementites changed from fragmentized shape to granular shape. In addition, the ductile cast iron with tensile strength of 740 MPa and elongation of 7% could be achieved after graphitization annealing heat treatment for 0. 5 h. Two principal factors should be taken into account. First, the decomposition of a small amount of cementites was beneficial for increasing the ductility up to elongation of 7%. Second, the diffusion of carbon atoms from cementites to graphites could improve the binding force between graphites and matrix, enhancing the tensile strength to 740 MPa.

研究了珠光体球墨铸铁在石墨化退火热处理过程中渗碳体的分解。用扫描电镜观察热处理试样的断口形貌和显微组织,用万能拉伸试验机测定试样的力学性能。结果表明:在750℃等温退火过程中,珠光体球墨铸铁的抗拉强度在0.5 h时达到峰值,此后逐渐下降,但伸长率随退火时间的增加而提高;此外,碳原子的扩散系数可以近似计算为0.56µm2/s,可以认为是短距离扩散。由于保温时间短(0。5 h),碳原子的扩散不完全,主要发生在石墨周围,渗碳体的形态由碎片状变为粒状。另外,经0℃石墨化退火热处理后,可获得抗拉强度为740 MPa、伸长率为7%的球墨铸铁。应该考虑两个主要因素。首先,少量渗碳体的分解有利于提高塑性,伸长率可达7%。其次,碳原子从渗碳体向石墨的扩散可以提高石墨与基体之间的结合力,拉伸强度提高到740 MPa。
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引用次数: 6
Analysis of energy consumption for lump coal degradation in melting gasifier 熔融气化炉块煤降解能耗分析
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30116-4
Qi-hang Liu, Xiao-ming Li, Jun-xue Zhao

The volume hypothesis, a theory about the energy scale of comminution, was adopted to analyze the degradation behavior of lump coal under different heating time. The breakage energy of chars was determined by a compression test, and the results show that the ultimate strength of chars decreased at the early stage during the heating process, resulting in a decrease of the char breakage energy. At the late stage during the heating process, the char breakage energy increased with the increase of heating time. The power consumption coefficients CK of different chars were determined by a drum experiment, and then the char degradation behavior under different power consumptions was predicted. In addition, a gasification experiment was conducted to determine the gasification activation energy (with CO2) of lump coal heated for different time. The results show that the gasification activation energy increased greatly at the early stage during the heating process, which showed opposite change to the breakage energy of chars. Furthermore, the internal temperature and heat changes of the bonded coal briquette were calculated by using an unsteady heat conduction equation. The large difference between the surface and the center temperatures of coal and the large amount of heat absorption at the early stage during the heating process may have a negative effect on the breakage energy of chars.

采用关于粉碎能量尺度的体积假设理论,分析了块煤在不同加热时间下的降解行为。通过压缩试验确定了煤焦的破碎能,结果表明,在加热过程的早期,煤焦的极限强度降低,导致煤焦的破碎能降低。在加热过程的后期,随着加热时间的延长,焦炭破碎能逐渐增大。通过转鼓试验确定了不同焦炭的功耗系数CK,并对不同功耗下焦炭的降解行为进行了预测。此外,还进行了气化实验,确定了不同加热时间块煤的气化活化能(含CO2)。结果表明:在加热过程中,气化活化能在加热初期大幅增加,与焦炭破碎能的变化相反;采用非定常热传导方程计算了粘结型煤的内部温度和热量变化。在加热过程中,煤的表面温度与中心温度相差较大,前期吸热量大,可能会对煤焦的破碎能产生负面影响。
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引用次数: 1
Springback behavior of tailor rolled blank in U-shape forming 轧坯u形成形的回弹行为
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30118-8
Ri-huan Lu , Xiang-hua Liu , Shou-dong Chen , Lu Feng , Xian-lei Hu , Li-zhong Liu

The springback of tailor rolled blanks with quenching and partitioning steels was investigated. In order to find out the springback behavior and related influence factors for the novel sheets, both experimental and simulation methods have been used to compare and analyze the springback characteristics of equal thickness blanks and tailor rolled blanks in U-channel forming. From the results, the overall springback angles of tailor rolled blanks at thin and thick sides are respectively 106. 79° and 99. 705°, which are both lower than those of the corresponding equal thickness blanks. Due to the existence of the thickness transition zone, the stress distribution in thin and thick sides of blanks is changed. The location of dangerous region in thin side of tailor rolled blanks is closer to the end of side, and the thick side moved to the middle of straight wall, which are different with the equal thickness blanks. Afterwards, the released quantitles of tangential stress and strain per unit section of blank are adopted to calculate relative springback angles and give novel evaluation criteria for qualitatively analyzing the amount of springback angles. By comparing the results, it shows that the tangential strain method is more suitable for the actual situation.

研究了淬火配分钢拼轧坯料的回弹性能。为了找出新型板料的回弹特性及其影响因素,采用实验和仿真相结合的方法,对等厚板料和定制轧制板料在u型孔道成形过程中的回弹特性进行了对比分析。结果表明,裁轧薄板和厚板的整体回弹角分别为106。79°和99°。705°,均低于相应等厚坯料。由于厚度过渡区的存在,改变了坯料薄厚两侧的应力分布。与等厚坯料不同的是,裁轧坯料薄侧危险区位置更靠近端部,厚侧危险区位置更靠近直壁中部。然后,采用坯料单位截面切向应力和应变释放量计算相对回弹角,给出了新的评价标准,用于定性分析回弹角的大小。结果表明,切向应变法更适合实际情况。
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引用次数: 6
Current status and development trends of innovative blast furnace ironmaking technologies aimed to environmental harmony and operation intellectualization 以环境和谐和操作智能化为目标的高炉炼铁创新技术的现状及发展趋势
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30115-2
Hong-tao Wang, Wei Zhao, Man-sheng Chu, Cong Feng, Zheng-gen Liu, Jue Tang

Blast furnace (BF) ironmaking is dominant for reducing pollution emission and energy consumption in iron and steel industry. Under the increasingly strict environmental pressure, some innovative technologies of BF ironmaking for environmental protection have been developed and applied in actual operating facilities. The current state of BF ironmaking in Europe, America, Japan, and China were briefly overviewed. Moreover, some innovative BF ironmaking technologies aiming at environmental harmony and operation intellectualization in the world, such as waste gas recycling sintering, BF operation with coke oven gas injection, ferro-coke, lime coating coke, BF visualization and intellectualization, were roundly summarized. Finally, some discussion on the technologies was carried out and the development trends of BF ironmaking were pointed out. The review could provide references and supports for the progress of environment-friendly technologies of BF ironmaking, thereby promoting their practical applications and achieving sustainable development of BF ironmaking, especially for Chinese ironmaking industry.

高炉炼铁在降低钢铁工业污染排放和能耗方面占主导地位。在日益严格的环境压力下,一些创新的高炉炼铁环保技术已被开发出来并应用于实际运行设施中。简要介绍了欧洲、美国、日本和中国的高炉炼铁现状。全面总结了国内外以环境和谐和操作智能化为目标的一些高炉炼铁创新技术,如废气循环烧结、焦炉注气高炉操作、铁炭、涂石灰炭、高炉可视化和智能化等。最后对高炉炼铁技术进行了探讨,并指出了高炉炼铁的发展趋势。本文的研究可为高炉炼铁环境友好型技术的发展提供参考和支持,从而促进高炉炼铁环境友好型技术的实际应用,实现高炉炼铁特别是中国炼铁工业的可持续发展。
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引用次数: 29
Tribological performance of uncoated and TiCN-coated D2, M2 and M4 steels under lubricated condition 未涂覆和涂覆ticn的D2, M2和M4钢在润滑条件下的摩擦学性能
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30122-X
Luis Daniel Aguilera Camacho, Santos García Miranda, Karla Judith Moreno

Hard coatings are used to improve the wear resistance of metals which largely depends on adhesion between substrate and coating. The wear and friction behavior of uncoated and TiCN-coated D2, M2 and M4 steels were evaluated by a pin-on-disk test under lubricated conditions. In order to evaluate the influence of lubricant on wear performance, dry friction tests were also performed. The results showed that friction coefficients were very similar for both uncoated and TiCN-coated steels. Under lubricated conditions, the uncoated D2 tool steel exhibited the lowest friction coefficient, but the TiCN-coated D2 steel presented the smallest wear rate. Abrasion was the main wear mechanism in all the tribocouples. Additionally, microhardness measurements were carried out, finding an influence of the steel substrate on the hardness of the coatings. Besides, adhesion test was conducted, suggesting a good adhesion of class 1 between substrates and TiCN coatings.

硬质涂层用于提高金属的耐磨性,这在很大程度上取决于基体与涂层之间的附着力。在润滑条件下,通过销盘试验评估了未涂覆和涂覆ticn的D2、M2和M4钢的磨损和摩擦行为。为了评价润滑油对磨损性能的影响,还进行了干摩擦试验。结果表明,未涂层钢和ticn涂层钢的摩擦系数非常相似。在润滑条件下,未涂层D2工具钢的摩擦系数最低,而涂层ticn的D2工具钢的磨损率最小。磨损是摩擦副的主要磨损机制。此外,还进行了显微硬度测试,发现了钢基体对涂层硬度的影响。此外,还进行了附着力测试,表明基体与TiCN涂层具有良好的1级附着力。
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引用次数: 7
Ripening behavior of M23C6 carbides in P92 steel during aging at 800 °C 800℃时效过程中P92钢中M23C6碳化物的熟化行为
2区 材料科学 Q2 Materials Science Pub Date : 2017-08-01 DOI: 10.1016/S1006-706X(17)30127-9
Xu Yang , Bo Liao , Fu-ren Xiao , Wei Yan , Yi-yin Shan , Ke Yang

The rapid coarsening of the M23C6 carbides has been held responsible for the creep fracture in 9–12Cr martensitic heat resistant steels. A commercial P92 steel was subjected to thermal aging at a high temperature of 800 °C to investigate the ripening behavior of the M23C6 carbides. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed to characterize the microstructure evolution, especially the ripening process of the M23C6 carbides. The new concept of the effective mean size, dependent on the critical radius, was introduced to correct the measured mean size and then the Ostwald theory was applied to describe the ripening behavior of the M23C6 carbides. The ripening of the M23C6 carbides was revealed to be grain boundary diffusion controlled.

M23C6碳化物的快速粗化是导致9-12Cr马氏体耐热钢蠕变断裂的主要原因。在800℃的高温下对一种P92钢进行热时效,研究了M23C6碳化物的熟化行为。采用扫描电镜(SEM)和透射电镜(TEM)对M23C6碳化物的微观结构演变进行了表征,尤其是其成熟过程。引入了依赖于临界半径的有效平均尺寸的新概念,对测量的平均尺寸进行了修正,并应用奥斯特瓦尔德理论描述了M23C6碳化物的成熟行为。M23C6碳化物的成熟受晶界扩散控制。
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引用次数: 14
期刊
Journal of Iron and Steel Research(International)
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