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Synthesis and Performance Evaluation of Anti Temperature and Salt Resistant Polymer Filtrate Reducer 耐温耐盐聚合物降滤失剂的合成及性能评价
Pub Date : 2019-08-06 DOI: 10.4236/ojogas.2019.44020
Zhu Zhu, Huaiyuan Long, Dichen Tan, Song Wang, Zu-wen Wang, Shunyuan Zhang, Yu Deng
In the experiment, the filtrate loss of synthetic fluid loss control fluid was recorded in room temperature and high temperature in the composite brine base and sodium chloride brine base slurry, and compared with the filtrate loss before base polymer addition. In this way, the effect of filtration loss and salt resistance and temperature resistance of synthetic polymers were evaluated. The influence of the synthesized polymer on the rheological properties of the composite brine was also evaluated by determining the viscosity of the drilling fluid added to the base slurry and polymer. In the end, the structure of the synthetic polymers was characterized through the infrared spectrum, which initially analyzed through the mechanism of its function in reducing the filter loss. Finally, the products produced according to the recipe are given to the site and added to the two wells to record the drilling fluid performance data.
在实验中,记录了合成液损失控制液在室温和高温下在复合盐水基和氯化钠盐水基浆料中的滤失量,并与添加基础聚合物前的滤失率进行了比较。通过这种方式,评估了合成聚合物的过滤损失和耐盐性和耐温性的影响。通过测定添加到基浆和聚合物中的钻井液的粘度,还评估了合成聚合物对复合盐水流变性能的影响。最后,通过红外光谱对合成聚合物的结构进行了表征,初步分析了其降低滤失的作用机理。最后,将根据配方生产的产品送到现场,并添加到两口井中,以记录钻井液性能数据。
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引用次数: 0
A Fine Investigation on Geological Conditions for Oil Accumulation in the Paleogene Intersalt Shale Series in the Qianjiang Depression 潜江凹陷古近系盐间页岩系成油地质条件精细调查
Pub Date : 2019-08-06 DOI: 10.4236/ojogas.2019.44024
Xiaolong Ju, Junjun Shen, S. Zhong, Weihao Zhang, Jia-qi Liu, Fan Wei
This study dealt with the rhythmic Qian 3410 of the intersalt shale series in the Qianjiang Depression, in which the geological condition for oil accumulation in the rhythmic shale was investigated by using the basic drilling, core and well logging data, as well as data obtained from the thin section identification, SEM, mercury injection, X-ray diffraction and rock freezing heat analyses. The study result indicated that: 1) the intersalt shale series are characterized by TOC in a range of 0.35% - 6.38% (averaging 3.19%), Types I and II1 organic matter, and from immature to mature oil, indicative of a potential for generating a great volume of immature oil; 2) in the target layer, mineral compositions are complicated, which can divide into argillaceous dolomite facies, argillaceous limestone facies, dolomitic mudstone facies, and calcium-mirabilite-filling dolomitic mudstone facies; and 3) of them, the argillaceous dolomite facies is the most contributory, with reservoir spaces consisting of intergranular pores as dominant, as well as rare dissolution pores and seams. It is characterized by high organic abundance (4.23% - 6.38%), high content of brittle mineral (50% - 71%), low content of clay mineral (18% - 33%), high porosity (10.8% - 26.3%) and good oil-bearing properties (S1 distributed in 3.48 - 5.64 mg/g, and S1/TOC value in a range of 348 - 564 oil mg/g). Therefore, the argillaceous dolomite facies was considered the key target series to be explored for the intersalt shale oil in the study area in the coming days.
本研究以潜江凹陷盐间页岩系韵律系钱3410为研究对象,利用钻井、岩心、测井等基础资料,以及薄片鉴定、扫描电镜、压汞、X射线衍射、岩石冻结热分析等资料,探讨了韵律系页岩成油的地质条件。研究结果表明:1)盐间页岩系列的特征是TOC在0.35%-6.38%(平均3.19%)之间,I型和II1型有机质,从未成熟油到成熟油,表明有可能产生大量未成熟油;2) 目的层矿物成分复杂,可分为泥质白云岩相、泥质灰岩相、白云质泥岩相和芒硝钙充填白云质泥岩相和;(3)其中泥质白云岩相贡献最大,储层空间以粒间孔隙为主,溶蚀孔隙和溶蚀缝较少。其特征是有机丰度高(4.23%-6.38%),脆性矿物含量高(50%-71%),粘土矿物含量低(18%-33%),孔隙度高(10.8%-26.3%),含油性能好(S1分布在3.48-5.64mg/g之间,S1/TOC值在348-564油mg/g之间)。因此,泥质白云岩相被认为是未来几天研究区盐间页岩油勘探的重点目标系列。
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引用次数: 1
Organic Geochemical Characteristics of Source Rocks of Hongshuizhuang Formation in the Mengjiawopu Section of Lingyuan-Ningcheng Basin in North China 陵源—宁城盆地孟家窝堡剖面红水庄组烃源岩有机地球化学特征
Pub Date : 2019-07-24 DOI: 10.4236/OJOGAS.2019.43014
Q. Xiong, You-jun Tang, Wenming Zong, Shouliang Sun, D. He, Feng Wang
Through the regional geological survey, outcrop section measurement and other field geological work, a block of black shale is found at the outcrop of Mengjiawopu Section of Hongshuizhuang Formation in Jixian County, and organic geochemical source rock analysis and evaluation methods are used to study the source rocks in Hongshuizhuang Formation. The set of source rocks is mainly gray-black silty mudstone and gray-black shale, with a cumulative thickness of 78 m; the total organic matter (TOC) is generally high, with an average content of 1.35%, of which good and rich source rock samples account for 86%. A combined analysis of the stable carbon isotope of kerogen, the correlation between Pr/nC17 and Ph/nC18, and the ratio of saturated hydrocarbon to aromatic hydrocarbon identifies that the organic matter is mainly Type Ⅱ kerogen; the equivalent vitrinite reflectance Ro of organic matter is from 1.68% to 1.94%. Rc, the correlation of the methylphenanthrene index (MPI) against the vitrinite reflectance is from 1.63% to 1.81%, with an average of 1.71%, and the Odd/Even Predominance (OEP) value is between 0.87 and 1.11, both indicating that the source rocks of the Hongshuizhuang Formation are at the stage of high to over maturation. In summary, the set of source rocks in Hongshuizhuang Formation is characterized by high organic matter content, good kerogen types, and high to over maturation stage.
通过区域地质调查、露头剖面测量等野外地质工作,在蓟县红水庄组孟家窝铺段露头发现一块黑色页岩,并采用有机地球化学烃源岩分析评价方法对红水庄段烃源岩进行了研究。该套烃源岩主要为灰黑色粉砂质泥岩和灰黑色页岩,累计厚度78m;总有机质(TOC)普遍较高,平均含量为1.35%,其中良富烃源岩样品占86%。通过对干酪根的稳定碳同位素、Pr/nC17与Ph/nC18的相关性以及饱和烃与芳烃的比值的综合分析,确定有机质主要为Ⅱ型干酪根;有机物的等效镜质组反射率Ro为1.68%至1.94%。Rc,甲基菲指数(MPI)与镜质组反射的相关性为1.63%至1.81%,平均为1.71%,奇数/偶数优势(OEP)值在0.87至1.11之间,均表明红水庄组烃源岩处于高熟-过熟阶段。综上所述,红水庄组烃源岩具有有机质含量高、干酪根类型好、高至过熟阶段的特点。
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引用次数: 0
Study on the Main Controlling Factors of the Early Ordovician Stromatolites Development in Liujiachang Area of Songzi City 松滋市刘家场地区早奥陶统叠层石发育的主要控制因素研究
Pub Date : 2019-07-23 DOI: 10.4236/OJOGAS.2019.43012
Lanjun Wu, Chuantao Xiao, Zhongzhe Cheng, Yichen Bao, Li Huang, Kang Chen
The Early Ordovician stromatolites in the study area are mainly exposed at the bottom and middle and lower parts of the Second Member of Nanjinguan Formation, the top of the Fourth Member of Nanjinguan Formation, the middle of the Second Member of Fenxiang Formation and the bottom of the First Member of Honghuayuan Formation. In order to find out the controlling factors of Lower Ordovician stromatolites development in the study area, the analysis data of carbon, oxygen isotope samples, macro element samples as well as their variation characteristics are studied and then combined them with previous research results, which is eventually beneficial for reaching the conclusion: sea level change is one of the main factors controlling the formation of stromatolites. There are five sea level change cycles in the Early Ordovician period. The analysis of sea level change and accommodation space variation characteristics show that when the growth rate of the accommodation space is approximately equal to that of carbonate, the circulation of seawater is well, and the amount of light and oxygen is sufficient, so that the cyanobacteria organism can be multiplied in large quantities. The growth and development provide favorable conditions, and favorable conditions are provided for the growth and development of stromatolites; The peak changes in CaO content and CaO/MgO ratio indicate that the formation period of stromatolites is arid climate environment with high water temperature and large evaporation. Prokaryote reproduction is suitable for the environments with high seawater cleanliness. When the amount of land-based debris injected into the sea increases, the turbidity of water will lead to a large number of deaths of algae microorganisms that form stromatolites, and the stromatolitic microbial mats cannot be preserved. In addition, the growth and predation of macro-organisms play a restrictive role in the development of stromatolite-forming micro-organisms blue-green algae. According to the actual situation of the development of the laminated rocks in the study area, what is the dominant function in the formation and decline of stromatolites between the evolution of metazoans and changing environments is discussed in the study.
研究区早奥陶统叠层石主要出露于南津关组二段底部、中下部、南津关四段顶部、汾乡组二段中部、红花园组一段底部。为了找出研究区下奥陶统叠层石发育的控制因素,对碳、氧同位素样品、常量元素样品的分析数据及其变化特征进行了研究,并将其与前人的研究成果相结合,这最终有利于得出这样的结论:海平面变化是控制叠层石形成的主要因素之一。早奥陶世有五个海平面变化周期。对海平面变化和容纳空间变化特征的分析表明,当容纳空间的生长速率与碳酸盐的生长速率大致相等时,海水的循环良好,光和氧气的量充足,从而使蓝藻生物能够大量繁殖。生长发育为叠层石的生长发育提供了有利条件;CaO含量和CaO/MgO比值的峰值变化表明叠层石的形成期为干旱气候环境,水温高,蒸发量大。原核生物繁殖适用于海水清洁度高的环境。当注入海洋的陆上碎屑数量增加时,水的浊度将导致形成叠层石的藻类微生物大量死亡,叠层石微生物垫无法保存。此外,大型生物的生长和捕食对叠层石形成微生物蓝绿藻的发育起着限制作用。根据研究区层状岩石发育的实际情况,讨论了后生动物的演化与环境的变化在叠层岩形成和衰退中的主导作用。
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引用次数: 1
Research on High Temperature and High Density White Oil Based Drilling Fluid and Its Application in Well 201H7-6 高温高密度白油基钻井液在201H7-6井的应用研究
Pub Date : 2019-07-23 DOI: 10.4236/OJOGAS.2019.43013
Bo Qin, Yidi Wang, Chunzhi Luo, Gang Liu
As the depth and horizontal length of shale gas development wells increase, the requirement for the temperature resistance and the ability of the drilling fluids to stabilize the shale formation becomes higher. A new type of high temperature and high density white oil based drilling fluid system has been developed in laboratory. Research shows that the drilling fluid system has good rheological property, low filtration loss, strong anti-debris pollution capability and good plugging performance at high temperature and high density. The system has been successfully applied in the 201H7-6 well. Application results show that the drilling fluid rheology, high temperature and high pressure fluid loss and demulsification voltage meet the field requirements. The drilling fluid performance is stable in drilling an 1800 m horizontal section, and no stuck or shale swelling and wellbore collapsing are induced. It is the first well drilled successfully with domestic white oil-based drilling fluid in Zigong Region. It also sets several new records including the deepest well, the shortest drilling cycle, and the fastest drilling speed in that region, which provides valuable experience for the future drilling activities.
随着页岩气开发井深度和水平长度的增加,对钻井液的耐温性和稳定页岩地层的能力提出了更高的要求。在实验室研制了一种新型高温高密度白油基钻井液体系。研究表明,该钻井液体系流变性好,滤失小,抗碎屑污染能力强,在高温高密度条件下具有良好的封堵性能。该系统已在201H7-6井成功应用。应用结果表明,钻井液流变性、高温高压滤失、破乳电压均满足现场要求。在1800 m水平段钻井过程中,钻井液性能稳定,未发生卡钻、泥页岩膨胀和井眼坍塌现象。这是自贡地区第一口国产白基钻井液成功钻井。该钻井还创下了该地区最深井、最短钻井周期、最快钻井速度等新纪录,为今后的钻井活动提供了宝贵的经验。
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引用次数: 2
Structural and Sedimentary Characteristics of Hydrocarbon-Rich Sags in Lacustrine Sub-Basin of Half Graben Type, Pearl River Mouth Basin, South China Sea 南海珠江口盆地半地堑型湖相次盆地富油气凹陷构造与沉积特征
Pub Date : 2019-07-23 DOI: 10.4236/OJOGAS.2019.43015
Lei He, Xiaolong Wang, N. Cai, Jie Qu, Xiong Zhu, Da-Cheng Lin
Pearl River Mouth Basin undergoes complex tectonic evolution processes and forms lacustrine, transitional and marine sediments. Drilling shows that there exist large petroleum reserves in the hydrocarbon-rich sags of Pearl River Mouth Basin, South China Sea. To reduce the risk, the exploration, structural and sedimentary characteristics of the hydrocarbon-rich sags should be identified and described. Drilling, seismic, and microfossil data are integrated to interpret the structural and sedimentary evolution of the hydrocarbon-rich sags in Pearl River Mouth Basin. By analyzing the tectonic and sedimentary evolutionary characteristics, three conclusions may be drawn: 1) The present regional tectonic characteristics of the PRMB are formed by mutual interactions of the Eurasian Plate, Pacific Plate, Philippine Plate and Indian Plate. During the Paleocene to early Eocene and late Eocene and early Oligocene, the PRMB is at the rifting stage. During the late Oligocene, the PRMB was at the rifting-depression transitional stage. After the Oligocene, the PRMB is at the depression stage. 2) Tectonic conditions control the sedimentation process in the hydrocarbon-rich sags. During the lacustrine sedimentation stage, synsedimentary faults and intense faulting control the sedimentation. During the transitional sedimentation stage, weak fault activity influences the deposition process in the hydrocarbon-rich sags. During the marine sedimentation stage, weak fault activity and depression activity control the deposition process in the hydrocarbon-rich sags. 3) Tectonic evolution affects the deposition process. The lacustrine, transitional and marine sedimentation corresponds to different tectonic conditions. The lacustrine sedimentation is formed under fault activity during the rifting stage. The transitional sedimentation is formed under weak fault activity during the late rifting stage. The marine sedimentation is formed under weak fault activity and depression activity during the rifting-depression and depression stages. 4) The half graben is beneficial for the formation of lacustrine source rocks, which is responsible for the hydrocarbon-rich sag. Therefore the half graben mode contributes to the hydrocarbon-rich sags.
珠江口盆地经历了复杂的构造演化过程,形成了湖相沉积、过渡沉积和海相沉积。钻探结果表明,南海珠江口盆地富油气凹陷具有较大的石油储量。为了降低风险,应识别和描述富烃凹陷的勘探、构造和沉积特征。综合钻探、地震和微体化石资料,解释珠江口盆地富烃凹陷的结构和沉积演化。通过对构造和沉积演化特征的分析,可以得出以下三个结论:1)珠江三角洲目前的区域构造特征是欧亚板块、太平洋板块、菲律宾板块和印度板块相互作用形成的。在古新世至始新世早期、始新世晚期和渐新世早期,PRMB处于裂谷作用阶段。渐新世晚期,PRMB处于裂谷-坳陷过渡阶段。渐新世以后,PRMB处于坳陷阶段。2) 构造条件控制着富烃凹陷的沉积过程。在湖泊沉积阶段,同沉积断层和强烈断裂控制着沉积作用。在过渡沉积阶段,弱断裂活动影响了富烃凹陷的沉积过程。在海相沉积阶段,弱断裂活动和凹陷活动控制着富烃凹陷的沉积过程。3) 构造演化影响沉积过程。湖泊沉积、过渡沉积和海洋沉积对应不同的构造条件。湖相沉积是在裂谷作用阶段的断裂活动下形成的。过渡沉积是在裂谷作用晚期的弱断裂活动下形成的。海相沉积是在断陷-坳陷阶段的弱断裂活动和坳陷活动下形成的。4) 半地堑有利于湖相烃源岩的形成,是形成富烃凹陷的原因。因此,半地堑模式有助于形成富油气凹陷。
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引用次数: 2
Investigation of Antioxidative Properties of Multifunctional Additives of Alkyl Phenolate Type and Development of New Lubricant Compositions 烷基酚类多功能添加剂抗氧化性能的研究及新型润滑油配方的开发
Pub Date : 2019-07-23 DOI: 10.4236/OJOGAS.2019.43017
Y. Ramazanova
The results of studies of the antioxidant properties of multifunctional alkylphenolate type additives indicate the calcium salts of condensation products of alkylphenols (C8 - C12) with formaldehyde and the following amines: aminoacetic acid, benzotriazole, diethanolamine and boric acid, as well as their carbonated compounds. The determination of the antioxidant properties of the additives is tested on the АПСМ-1M apparatus. New lubricant compositions for diesel internal combustion engines oil meeting the required standards for these oils have been developed. The study of additives, which possess simultaneously detergent-dispersing, neutralizing, antioxidant anti-wear properties, revealed the dependence of antioxidant properties on their alkalinity.
多功能烷基酚类添加剂的抗氧化性能研究结果表明,烷基酚(C8-C12)与甲醛和以下胺的缩合产物的钙盐:氨基乙酸、苯并三唑、二乙醇胺和硼酸,以及它们的碳酸化化合物。添加剂抗氧化性能的测定在АПСМ-1M仪器上进行测试。已经开发出满足这些油的要求标准的用于柴油内燃发动机油的新的润滑剂组合物。对同时具有洗涤剂分散性、中和性、抗氧化性和抗磨性的添加剂的研究揭示了其抗氧化性能对碱度的依赖性。
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引用次数: 1
Emulsion Polymerization of P (MMA-AA-EA) and Its Demulsifying Performance in Water/Oil Emulsion P(MMA-A-EA)的乳液聚合及其在水/油乳液中的破乳剂性能
Pub Date : 2019-07-23 DOI: 10.4236/OJOGAS.2019.43016
Xia Jiang, Zhiming Huang, Yuanzhu Mi, Jiazhe Kuang, Fan Ye
Stable water-in-oil emulsions are produced in oil exploitation and cause many environmental and operational issues. In this paper, a co-polymer demulsifier is reported in detail; an emulsion polymerization method is used to prepare nano-P (MMA-AA-EA) with MMA, AA and EA as the monomers, DVB as the cross-linker and APS as the initiator. The resulting products are characterized by FT-IR. Furthermore, the surface tension and particles size analysis is investigated. The results show that the surface tension reduction is 10.66 mN/m at 20°C when the concentration of co-polymer is 1000 ppm and the average size is 76.99 nm. Moreover, the HLB of polymer is discussed specifically by changing the amount of AA. With the increase of AA, the HLB value of the polymer is increased accordingly. Besides, the demulsification performance of the co-polymer is also evaluated at different synthesis and demulsification conditions. It is showed that the maximum demulsification efficiency is 96% at 70°C for 60 min. The optimum concentration of demulsifier is 400 ppm when the amounts of AA and DVB are 1.4 g and 0.1 g, respectively. At last, the process of demulsification is showed under a microscope; the coalescence process of water droplets is indicated under the action of the demulsifier.
稳定的油包水乳液在石油开采中产生,并引起许多环境和操作问题。本文详细报道了一种共聚破乳剂;以MMA、AA和EA为单体,DVB为交联剂,APS为引发剂,采用乳液聚合法制备了纳米P(MMA-AA-EA)。通过FT-IR对所得产物进行了表征。此外,还对表面张力和颗粒尺寸分析进行了研究。结果表明,当共聚物的浓度为1000ppm,平均粒径为76.99nm时,在20°C下,表面张力降低了10.66mN/m。此外,通过改变AA的量,具体讨论了聚合物的HLB。随着AA的增加,聚合物的HLB值也相应增加。此外,还对共聚物在不同合成和破乳条件下的破乳性能进行了评价。结果表明,在70℃、60min条件下,破乳剂的最高破乳剂效率为96%。当AA和DVB的用量分别为1.4g和0.1g时,破乳剂最佳浓度为400ppm。最后,在显微镜下观察了破乳过程;指出了破乳剂作用下水滴的聚结过程。
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引用次数: 2
Pressure Transient Analysis of an Intersecting Rollover Faulted Crest Boundary in Niger Delta Oil Field 尼日尔三角洲油田交叉翻转断层顶边界的压力瞬态分析
Pub Date : 2019-04-24 DOI: 10.4236/OJOGAS.2019.42010
K. K. Ihekoronye, I. P. Nwosu
Pressure transient analysis has been extensively applied to detect anomalies in a reservoir system. These anomalies may be presented in the form of an intersection of the crestal and the antithetic fault associated with a growth fault. Interpretation of this fault can only be achieved through the use of pressure transient analysis. The objective of the research work is to analyze and test the faulted crest, depth of the anticline structure and examine the near well bore conditions in order to evaluate whether the well productivity is governed by wellbore effects (skin effects + well bore effect) or the reservoir at large. A case study of a well in the Niger delta is considered with a series of build up test carried out in two intervals of both upper and lower gauge readings. In this study, a computer aided design which uses a pressure derivative approach is used in this work to match the pressure derivative of an intersecting fault (angle) model to the field data, and the model assumes the characteristics of the reservoir. Based on the result of the interpreted data, simulation is done by using a non linear regression method (least square). The simulated data interpreted are achieved through the regression coefficient which provides a quantitative measure of the agreement between field data and the model. In conclusion, the best cases are taken from all the results and a nodal analysis is performed to diagnose the inflow performance of the well through the transient analysis in order to optimize the recovery of the oilfield.
压力瞬变分析已广泛应用于油藏系统异常检测。这些异常可能以波峰和与生长断层相关的对偶断层相交的形式出现。对该断层的解释只能通过使用压力瞬态分析来实现。研究工作的目的是分析和测试断层顶、背斜构造深度和近井眼条件,以评价井的产能是受井筒效应(表皮效应+井眼效应)还是受储层整体影响。以尼日尔三角洲的一口井为例,在上下两个量程中进行了一系列的累积测试。在本研究中,采用压力导数方法的计算机辅助设计,将相交断层(角度)模型的压力导数与现场数据相匹配,该模型假设了油藏的特征。根据解译数据的结果,采用非线性回归方法(最小二乘法)进行了模拟。通过回归系数实现模拟数据的解译,为现场数据与模型之间的一致性提供了定量度量。综上所述,从所有结果中选取最佳案例,进行节点分析,通过瞬态分析来诊断该井的流入动态,从而优化油田的采收率。
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引用次数: 0
Design of Wireless Transmission System for Shallow Seismograph Based on 433 M Module 基于433m模块的浅层地震仪无线传输系统设计
Pub Date : 2019-04-19 DOI: 10.4236/OJOGAS.2019.42007
Liu Li, Chengguang Zhang, Li Taiquan, Liu Yu, Jin Yan, Zhou Chao
Because of its portability, the non-cable seismograph has become the future development trend of geophysical instruments. A new wireless data transmission device of 433 M module was proposed; a wireless network was built using the EL1663B_PA module of the SI4463 core, and through the SPI interface to modify the internal parameters. Data transmission used dual antenna mode, the main station as the center of the wireless network coverage up to 550 m or more. The wireless time synchronization system was designed to realize the wireless connection communication between the shallow seismograph and the sensor of each observation point. This program aimed to eliminate the necessary connecting cable and batteries between the conventional shallow seismograph and the detector, greatly reducing the weight of the equipment, and making the shallow seismograph truly low cost, lightweight, flexible and easy to operate and so on.
无缆地震仪由于其便携性,已成为地球物理仪器未来的发展趋势。提出了一种新型的433M模块无线数据传输装置;使用SI4463核心的EL1663B_PA模块,并通过SPI接口修改内部参数,构建了无线网络。数据传输采用双天线模式,以主站为中心的无线网络覆盖范围可达550米或以上。设计了无线时间同步系统,实现了浅层地震仪与各观测点传感器之间的无线连接通信。该方案旨在消除传统浅层地震仪与探测器之间必要的连接电缆和电池,大大减轻设备重量,使浅层地震机真正实现低成本、轻量化、灵活易操作等。
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引用次数: 0
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长江油气:英文版
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