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Structural Model of Kendeng Basin: A New Concept of Oil and Gas Exploration 柯登盆地构造模式:油气勘探新概念
Pub Date : 2020-07-31 DOI: 10.4236/ojogas.2020.54016
A. Novianto, Sutanto  , Suharsono  , C. Prasetyadi, T. Setiawan
Kendeng Basin stretches in an E-W direction from the Quaternary Merapi-Ungaran Volcano range in the West to the Madura Strait East of Jawa Timur Province, Indonesia. With Quaternary volcanic deposits covering this basin, its subsurface configuration has not been accurately identified. Several scholars suggest that its configuration forms an asymmetrical basin deepening to the south as a result of volcanic deposits and extending E-W direction. This paper answers what configuration Kendeng Basin has, including whether it consists of a simple asymmetrical shape as previous studies have interpreted or other patterns due to tectonic processes that took place during its formation. The research employed Gravity and Magnetic method, and the results were processed by spectral and gradient analyses. Both analyses revealed that Kendeng Basin formed Horst-Graben structures extending in an E-W direction based on a response to compression and strain forces during its formation. A structure with an E-W direction controls the shape of the Horst-Graben and is transected by a structural pattern extending in a NE-SW direction or known as the Meratus pattern. These findings provide an alternative to the concept of oil and gas exploration, which, until today, is merely known from the emergence of oil seepages in Kendeng Basin.
肯登盆地东西走向,从西部的第四纪默拉皮-乌加拉火山山脉一直延伸到印度尼西亚爪哇省东部的马杜拉海峡。由于第四纪火山沉积物覆盖了该盆地,其地下构造尚未准确确定。一些学者认为,它的构造形成了一个不对称的盆地,由于火山沉积而向南加深,并向东西方向延伸。本文回答了肯登盆地的构造,包括它是由以前的研究所解释的简单的不对称形状组成,还是由其形成过程中发生的构造过程引起的其他模式组成。研究采用了重力和磁力方法,并通过光谱和梯度分析对结果进行了处理。两种分析都表明,肯登盆地在形成过程中对压缩力和应变力的响应,形成了东西向延伸的霍斯特地堑结构。东西向的结构控制着霍斯特地堑的形状,并被沿NE-SW方向延伸的结构模式或称为Meratus模式横切。这些发现为油气勘探的概念提供了一种替代方案,直到今天,油气勘探还只是从肯登盆地的漏油现象中得知的。
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引用次数: 2
The Impact of Core Firing on EOR of Low Salinity-Surfactant Flooding 岩心燃烧对低盐表面活性剂驱采收率的影响
Pub Date : 2020-05-22 DOI: 10.4236/ojogas.2020.53009
A. Kerunwa
The combination of injection of lower saline brine and surfactant will increase recovery in sandstone rocks than either when any of the techniques is singly applied. In this work, core IFT test, pH test, flooding experiments and measurement of dispersion were performed on four core samples which were grouped into two: group A, which were not fired at a temperature of 500°C for 24 hours and group B which were fired. Two low saline brines were prepared: LS1 which was derived by the dilution of seawater four times and LS2 which was derived by ten times diluting the seawater. The surfactant used was ethoxylated alcohol surfactant. Coreflood experiments were then performed on the rock sample starting with the injection of low saline followed by low saline brine combined with surfactant (LSS). Results from the experiments show that with the injection of LS1 brine and LSS1 higher increment in recoveries were obtained for group B than for group A cores. The same trend was also noticed with the injection of LS2 and LSS2. From the results, LS1 gave higher increment in oil recovery than LS2. Also LSS1 gave higher recoveries when compared with LSS2. In all the cases tested, core samples which were fired gave higher recoveries even though they had low permeabilities of 993 md for sample 3 and 1017 md for sample 4 than those which were not fired with higher permeabilities of 1050 md and 1055 md for samples 1 and 2 with respectively. This was attributed to the alteration of wettability as well as that of permeability caused by sample firing. The dispersion profiles of the rock samples show that all samples are homogeneous.
与单独应用任何一种技术相比,注入低盐水和表面活性剂的组合将提高砂岩的采收率。在这项工作中,对四个岩心样品进行了岩心IFT测试、pH测试、驱油实验和分散度测量,这些岩心样品分为两组:A组,在500°C的温度下24小时未烧制,B组烧制。制备了两种低盐水:通过四次稀释海水得到的LS1和通过十次稀释海水获得的LS2。所使用的表面活性剂是乙氧基化醇表面活性剂。然后对岩石样品进行岩心驱替实验,首先注入低盐水,然后注入与表面活性剂(LSS)结合的低盐水。实验结果表明,注入LS1盐水和LSS1后,B组岩心的回收率比A组岩心的高。在注射LS2和LSS2时也注意到了相同的趋势。从结果来看,LS1比LS2具有更高的采油增量。与LSS2相比,LSS1的回收率也更高。在所有测试的情况下,尽管样品3和样品4的渗透率较低,分别为993 md和1017 md,但烧制的岩芯样品的回收率高于未烧制的岩芯,样品1和2的渗透率分别为1050 md和1055 md。这归因于样品烧制引起的润湿性和渗透性的改变。岩石样品的分散剖面表明,所有样品都是均匀的。
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引用次数: 0
Shale Hydrocarbon Development Based on Drill Cuttings & TOC Analysis: Case Study of Brownshale Drill Cuttings of Well BS-03, Pematang Formation, Bengkalis Trough, Central Sumatra Basin 基于钻屑的页岩油气开发及TOC分析——以中苏门答腊盆地Bengkalis海槽Pematang组BS-03井棕页岩钻屑为例
Pub Date : 2020-05-13 DOI: 10.4236/ojogas.2020.53008
A. Buntoro, C. Prasetyadi, R. A. Wibowo, nbsp, Suranto
Brownshale is a lithology unit in the middle of the Pematang Formation consisting of brown to black shale that is deposited in the lacustrine environment. Brownshale from the results of previous studies stated as the main source rock in the Central Sumatra Basin, which is spread over several troughs, namely Balam, Aman, Rangau, Kiri, and Bengkalis Troughs, where Bengkalis Trough is the most extensive Trough. In the shale hydrocarbon prospecting analysis, Brownshale from previous researchers concluded that it had good prospects, based on several parameters including: TOC values with poor to very good quality. Brownshale formation is a type of kerogene as kerogen type of II/III, brittleness index greater than 0.48, and rock compressive strength below 10,000 Psi. One method in the development phase of shale hydrocarbon is to determine the fracable sweetspot window using drill cuttings and TOC, because there is no core data available. Based on the results of the well log analysis of well BS-03, it is obtained information that the Brownshale formation has a thickness of 1028 feet with intercalation laminated shale/sand section, so the mineral content varies greatly. From the ternary diagram of XRD (bulk analysis) results of drill cuttings of Brownshale formation of well BS-03, it can be seen that mineral distribution of Quartz-Clay-Calcite (Q-C-C) is spread between zone 1 to zone 3, namely: Dominant Quartz - Minor Clay & Carbonate (Zone 1: Brittle Quartz Rich), Dominant Carbonate - Quartz & Minor Clay (Zone 2: Brittle Carbonate Rich), and Quartz & Carbonate Balance - Clay minor (Zone 3: Ductile, hard to frac). This shows that not all Brownshale formation intervals are easy to frac (high fracability). From the XRD result, percentage of mineral content (bulk analysis) of Brownshale drill cuttings, there is an interesting phenomenon, i.e. the presence of sillimanite and kaliophilite minerals significantly starting at a depth of 10,780 ft and below, where both minerals have tenacity: brittle, and also from the results of the MBT analysis seen an interesting phenomenon, i.e. at a depth interval of about 10,780 ft the value of CEC drops below 3 meq/100 grams, and can be categorized as the brittle shale. Referring to the presence of sillimanite and kaliophilite minerals, as well as low MBT values, then at intervals of 10,780 ft below, it can be seen that at the bottom of the depth interval as a fracable sweetspot window, and at the upper depth interval of the Brownshale formation, it is believed to be a fracture barrier.
褐页岩是Pematang组中部的一个岩性单元,由沉积在湖泊环境中的棕色至黑色页岩组成。根据先前的研究结果,褐页岩是中苏门答腊盆地的主要烃源岩,分布在几个槽上,即巴拉姆、阿曼、兰高、基里和本卡利斯槽,其中本卡利斯海槽是最广泛的海槽。在页岩油气勘探分析中,先前研究人员的Brownshale根据几个参数得出结论,认为其具有良好的前景,这些参数包括:质量较差到非常好的TOC值。褐页岩地层是一种干酪根类型,干酪根类型为II/III,脆性指数大于0.48,岩石抗压强度低于10000Psi。页岩油气开发阶段的一种方法是使用钻屑和TOC来确定可压裂的最佳点窗口,因为没有可用的岩心数据。根据BS-03井的测井分析结果,得到的信息是,褐页岩层厚度为1028英尺,夹层页岩/砂段,因此矿物含量变化很大。从BS-03井褐页岩组岩屑的XRD(体相分析)结果三元图可以看出,石英-粘土-方解石(Q-C-C)的矿物分布在1区至3区之间,即:主要石英-次要粘土和碳酸盐(1区:富含脆性石英)、主要碳酸盐-石英和次要粘土(2区:富含脆性碳酸盐),石英和碳酸盐平衡-少量粘土(3区:韧性,难以压裂)。这表明并非所有的褐页岩地层层段都易于压裂(可压裂性高)。根据XRD结果,褐页岩岩屑的矿物含量百分比(本体分析),存在一个有趣的现象,即硅线石和亲钾石矿物的存在明显始于10780英尺及以下的深度,其中两种矿物都具有韧性:脆性,并且从MBT分析的结果中也看到了一个有趣现象,即在大约10780ft的深度间隔处CEC的值下降到3meq/100克以下并且可以被归类为脆性页岩。关于硅线石和亲钾岩矿物的存在,以及低MBT值,然后在10780英尺以下的层段,可以看出,在作为可压裂甜点窗口的深度层段底部,以及在褐页岩地层的上部深度层段,它被认为是一个断裂屏障。
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引用次数: 3
Heat Dissipation Modeling of In-Situ Conversion Process of Oil Shale 油页岩原位转化过程的散热模拟
Pub Date : 2020-01-22 DOI: 10.4236/ojogas.2020.52005
Atif Zafar, Yuliang Su, Wendong Wang, S. G. Alam, Danish Khan, M. Yasir, A. AlRassas, I. Ahmad
In-situ conversion of process of oil shale has been technically proven as a pilot field project. Gradually heating the reservoir by using subsurface electric heaters converts the oil shale reservoir kerogen into oil, gas and other producible components. This process also enhances the internal energy of the porous media as well as the subsurface fluid. Heat is transmitted in the reservoir within each fluid by different processes i.e. , due to the flow of fluid called advective process, and due to molecular diffusion where dispersive and diffusive processes take place. Heat transfer through conduction and convection mechanisms in the porous media are modeled mathematically and numerically incorporating the advective, dispersive and diffusive processes in the reservoir. The results show the production of oil and gas as a result of conversion of kerogen due to modeled heat dissipation.
油页岩原位转化工艺已作为中试项目在技术上得到了验证。利用地下电加热器对储层进行逐步加热,将油页岩储层干酪根转化为油、气和其他可生产组分。这一过程也提高了多孔介质和地下流体的内能。热通过不同的过程在每一种流体的储层中传递,即由于流体的流动(称为平流过程)和由于分子扩散(发生弥散和扩散过程)。结合储层中的平流、弥散和扩散过程,对多孔介质中的传导和对流传热进行了数学和数值模拟。结果表明,油气的生产是由于模拟的热耗散导致干酪根转化的结果。
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引用次数: 1
Economic Evaluation of Hydraulic Fracturing in a Gas Condensate Reservoir Operating below Dewpoint 露点以下凝析气藏水力压裂经济评价
Pub Date : 2020-01-01 DOI: 10.4236/ojogas.2020.53007
A. Kerunwa, Princewill O. Ariche, Nkemakolam Chinedu Izuwa
Hydraulic fracturing is among the approaches used to optimize production from a gas condensate reservoir. A detailed economic analysis is required to evaluate the profitability and feasibility of hydraulic fracturing as an optimization option in a gas condensate reservoir operating below dewpoint. The objective of this research is to evaluate the economic benefits derivable from the use of hydraulic fracturing to improve gas and liquid recovery from a gas condensate reservoir operating below dewpoint. This research considers the use of four profit indicators to ascertain the profitability of hydraulic fracturing in a gas condensate reservoir operating below dewpoint by increasing the fracture halflength, fracture width and fracture permeability. The production data of the reservoir was obtained and the economic calculations done on excel spreadsheet and plots generated. The four profit indicators considered in the research are Net Present Value, Payout, Discounted Cash Flow Rate of Return and Profit per Dollar Invested. The economic justification was done by carrying out a comparative economic analysis from the result obtained when the reservoir of study was unfractured with that obtained when the reservoir was fractured at various fracture parameters. The economic analysis was done considering a royalty and tax rate of 18.5% and 30% respectively and a gas price of $2/MSCF and condensate price of $30/bbl. This is done so as to find out if the additional cost of hydraulic fracturing can be offset by the recovery from the reservoir when its pressure declined below dewpoint. The result obtained showed that the additional recovery due to hydraulic fracturing by increasing the fracture halflength, fracture width and fracture permeability was not enough to justify the application of hydraulic fracturing when the reservoir pressure declined below dewpoint.
水力压裂是用于优化凝析气藏产量的方法之一。对于露点以下凝析气藏,需要进行详细的经济分析,以评估水力压裂作为优化方案的盈利能力和可行性。本研究的目的是评估利用水力压裂提高露点以下凝析气藏气液采收率的经济效益。在露点以下凝析气藏中,通过增加裂缝半长、裂缝宽度和裂缝渗透率,利用4个盈利指标确定水力压裂的盈利能力。获得了该油藏的生产数据,并在excel表格上进行了经济计算,绘制了相应的图。研究中考虑的四个利润指标是净现值、支付、贴现现金流收益率和每投资一美元的利润。通过对研究储层在不同裂缝参数下未进行压裂与进行压裂的结果进行对比经济分析,得出了经济合理性。考虑到特许权使用费和税率分别为18.5%和30%,天然气价格为2美元/立方英尺,凝析油价格为30美元/桶,进行了经济分析。这样做是为了了解当油藏压力降至露点以下时,水力压裂的额外成本是否可以被油藏的采收率所抵消。结果表明,当储层压力降至露点以下时,水力压裂通过增加裂缝半长、裂缝宽度和裂缝渗透率所带来的额外采收率不足以证明水力压裂的应用。
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引用次数: 2
Components of Paraffin-Base and Naphthenic-Base Crude Oil and Their Effects on Interfacial Performance 石蜡基和环烷基原油组分及其对界面性能的影响
Pub Date : 2019-10-10 DOI: 10.4236/ojogas.2019.44022
Z. Yin, Pingnan Yuan, Xiang Lian, Y. Zheng, Heng Zheng
The saturate, aromatics, resin and asphaltene components of paraffin-base (PB) and naphthenic-base (HB) crude oil are separated by chromatographic column. The acidic components of crude oil are extracted by compounded polar solvents and identified by methyl esterification of diazomethane. The acidic components before and after asphaltene removal are investigated by gas chromatography-mass spectrometer. The effect of four fractions in simulated oil on interfacial activity is discussed. The results show PB is rich in naphthalene series and tri-aromatic steroids, and HB has a high content of phenanthrene series, chrysene series and methylpyrene, besides higher content of naphthalene series. The long carbon chain acids in HB oil decrease significantly by asphaltenes removal, confirming the presence of heavy oil acids in asphaltene. A little amount of saturates and aromatics in simulated oil can reduce the interfacial tension (IFT). When the content of asphaltenes of simulated oil is increased, IFT is initially decreased and finally increased because of stability of asphaltenes. When resin is increased, IFT is initially increased and then decreased. Simulated oil containing the resin from naphthenic-base oil is more sensitive to alkali than that of paraffin-base resin, which can reduce the IFT between oil and water at a larger range.
用色谱柱对石蜡基(PB)和环烷基(HB)原油中的饱和组分、芳烃组分、树脂组分和沥青质组分进行了分离。用复合极性溶剂提取原油中的酸性组分,用重氮甲烷甲酯化法进行鉴定。用气相色谱-质谱仪对沥青质脱除前后的酸性组分进行了研究。讨论了模拟油中四种组分对界面活性的影响。结果表明,PB含有丰富的萘系和三芳香族甾体,HB除萘系含量较高外,还含有较高的菲系、chrysene系和甲基芘。通过去除沥青质,HB油中的长碳链酸显著减少,证实了沥青质中存在重油酸。模拟油中加入少量的饱和烃和芳烃可以降低界面张力。当模拟油中沥青质含量增加时,由于沥青质的稳定性,IFT最初降低,最后增加。当树脂增加时,IFT最初增加,然后降低。含环烷基树脂的模拟油比石蜡基树脂对碱更敏感,可以在更大的范围内降低油和水之间的IFT。
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引用次数: 2
Assessment of Hazards in Gas Hydrates Recovery 天然气水合物回收的危险性评估
Pub Date : 2019-08-06 DOI: 10.4236/OJOGAS.2019.44018
C. Ejike
Gas hydrates are whitish balls containing enormous amount of methane gas at deep marine sediments. This energy source will account for future energy needs as it is said to be twice the value of all recoverable energy sources tapped till date. They are formed as a result of biogenic and thermogenic matters coupled with deep water conditions such as excessive pressure and diminishing temperature. Various recovery methods have been juxtaposed till date to influence the production of its reserves. However, appropriate assessment of the hazards and shortcomings hindering the large scale production of these reserve needs to be checkmated in order to facilitate the effective development of gas from methane hydrate in a near future.
天然气水合物是深海沉积物中含有大量甲烷气体的白色球体。这种能源将满足未来的能源需求,因为据说它是迄今为止开采的所有可回收能源价值的两倍。它们是由生物成因和热成因物质加上深水条件(如过度压力和温度下降)形成的。迄今为止,各种回收方法已并列使用,以影响其储量的生产。然而,为了在不久的将来促进甲烷水合物天然气的有效开发,需要对阻碍这些储量大规模生产的危险和缺点进行适当的评估。
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引用次数: 3
Stable Production Technology for Horizontal Well Development in Shallow Water Delta Oilfield of Bohai Bay, China 渤海湾浅水三角洲油田水平井开发稳定生产技术
Pub Date : 2019-08-06 DOI: 10.4236/ojogas.2019.44021
Guangyi Sun, Qiongyuan Wu, Huijiang Chang, Xiaoming Chen, Shangqi Zhai
BZ Oilfield is a medium-sized oilfield with shallow delta facies deposits in Bohai Bay of China, compared with fluvial and delta facies oilfields, there is no mature experience for reference of reservoir configuration, well pattern arrangement and development model in offshore oilfields in China. In view of the difficulty in describing the reservoir configuration of shallow water delta, the single distributary sand dam in shallow water delta is characterized by well-seismic combination and multi-attribute constraints. The mathematical mechanism model of pinch-out position of sand body is established, fine characterization of BZ shallow water delta reservoir is put forward. The horizontal well pattern arrangement type for shallow water delta reservoir is proposed and the method of well pattern optimization based on vertical displacement theory is put forward. A method of inversion of reservoir connectivity using production dynamic data by numerical well testing is proposed and a new method for optimizing water injection rate in water injection wells is proposed aiming at the difficulty of recognizing injection-production connectivity of shallow water delta reservoirs. The fine configuration of BZ shallow water delta reservoir based on distributary sand dam is proposed, which guides the recognition of remaining oil distribution law. By deploying adjustment wells, the water flooding coincidence degree of actual drilling is 86% compared with that of pre-drilling prediction, which indicates that the research results of reservoir configuration can effectively guide the understanding of oilfield geology. Through the theoretical well arrangement type of vertical displacement of single sand body in horizontal wells of shallow water delta reservoir, a high water flooding recovery rate of 35% is achieved in primary well pattern. The connectivity coefficients of injection-production boundary of shallow water delta reservoir configuration are calculated, and the water injection distribution coefficients are obtained by normalizing the directional coefficients. This paper presents a configuration method based on multi-attribute fusion under the constraints of sedimentary process. In this paper, a shallow water delta reservoir configuration method based on multi-attribute fusion constrained by sedimentary process is proposed, and the injection-production connectivity coefficient and injection well distribution coefficient of the configuration boundary are calculated.
BZ油田是我国渤海湾浅三角洲相沉积的中型油田,与河流相、三角洲相油田相比,我国海上油田在储层配置、井网布置和开发模式等方面还没有成熟的经验可供借鉴。针对浅水三角洲储层形态难以描述的特点,浅水三角洲单分流砂坝具有良好的地震组合和多属性约束特征。建立了砂体尖灭位置的数学机理模型,对BZ浅水三角洲油藏进行了精细表征。提出了浅水三角洲油藏水平井网布置方式,提出了基于垂直位移理论的井网优化方法。针对浅水三角洲油藏注采连通性难以识别的问题,提出了一种利用数值试井生产动态数据反演油藏连通性的方法,并提出了优化注水井注水量的新方法。提出了以分流砂坝为基础的BZ浅水三角洲储层精细构造,指导了剩余油分布规律的认识。通过部署调整井,与钻前预测相比,实际钻井的水淹符合度为86%,表明储层配置研究成果可以有效地指导对油田地质的认识。通过浅水三角洲油藏水平井单砂体垂直驱替的理论布井方式,在一次井网中实现了35%的高水驱采收率。计算了浅水三角洲油藏配置注采边界的连通系数,并通过对方向系数进行归一化得到了注采分配系数。本文提出了一种在沉积过程约束下基于多属性融合的构造方法。本文提出了一种受沉积过程约束的基于多属性融合的浅水三角洲储层配置方法,并计算了配置边界的注采连通系数和注井分布系数。
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引用次数: 0
The Research of Polymer Film-Forming Plugging Agent for Drilling Fluid 聚合物钻井液成膜堵漏剂的研究
Pub Date : 2019-08-06 DOI: 10.4236/ojogas.2019.44019
Gang Liu, Chunzhi Luo, Baijing Wang
In order to improve the plugging and anti-collapse performance of water-based drilling fluid, a polymer film-forming plugging agent LWFD is synthesized by emulsion polymerization. The effect of the agent on rheology, API filtration loss, lubricity and film plugging of polymer drilling fluid and cationic drilling fluid is evaluated in laboratory. The experimental results show that the agent has little effect on the rheology and filtration loss of polymer drilling fluid and cationic drilling fluid, and can improve the lubricity of drilling fluid. The synthesized polymer film-forming plugging agent LWFD has good plugging properties for sand discs with different permeabilities, and the agent can effectively improve the film-forming plugging and temperature resistance of drilling fluid when combined with the inorganic nano-plugging agent NMFD. The high performance polymer drilling fluid formed by introducing polymer film-forming plugging agent LWFD and inorganic nano-plugging agent NMFD into polymer drilling fluid has comparable performance as Halliburton’s SHALEDRIL high performance drilling fluid, which can meet the requirements of on-site drilling and has application value.
为了提高水基钻井液的封堵和防塌性能,采用乳液聚合法合成了聚合物成膜封堵剂LWFD。在实验室评价了该剂对聚合物钻井液和阳离子钻井液流变性、API滤失、润滑性和堵膜性能的影响。实验结果表明,该剂对聚合物钻井液和阳离子钻井液的流变性和滤失影响不大,能改善钻井液的润滑性。合成的聚合物成膜堵剂LWFD对不同渗透率的砂盘具有良好的堵剂性能,与无机纳米堵剂NMFD复配,可有效提高钻井液的成膜堵性和耐温性。在聚合物钻井液中引入聚合物成膜堵剂LWFD和无机纳米堵剂NMFD形成的高性能聚合物钻井液,其性能与哈里伯顿SHALEDRIL高性能钻井液相当,能够满足现场钻井要求,具有应用价值。
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引用次数: 3
Experimental, Thermodynamic and Kinetic Studies for the Adsorption of Phenolic Compounds Derived from Oilfield Wastewater by the Corncob Hydrochar 玉米芯水溶液吸附油田废水中酚类化合物的实验、热力学和动力学研究
Pub Date : 2019-08-06 DOI: 10.4236/ojogas.2019.44023
Xie Liangcheng, Ding Kangle, Yan Liu, Zou Mei, H. Chao
The corncob hydrochar is prepared by using a stainless autoclave at 230°C for 8 h. The products are characterized by elemental analyzer, Fourier Transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and scanning electron microscope (SEM). The effects of hydrochar dosage, pH, adsorption time and phenol concentration on the adsorption performance of hydrochar are investigated by means of single-factor experimental analysis. Based on the experiments the adsorption thermodynamic and kinetics are tentatively discussed. The results show that abundant oxygen-containing functional groups are scattered on the surface of the corncob hydrochar. The adsorption kinetics of phenol on the hydrochar corresponds well with pseudo-second-order kinetic model. Thermodynamic studies indicate that Freundlich adsorption isotherm model is much better than Langmuir model in describing the adsorption of phenol on the corncob hydrochar at 25°C - 45°C. This study provides scientific basis for the development of cheap and efficient adsorbents for the removal of phenols derived from oilfield wastewater.
采用不锈钢高压釜在230°C下保温8h制备玉米芯水炭。通过元素分析仪、傅立叶变换红外光谱(FT-IR)、X射线衍射(XRD)和扫描电子显微镜(SEM)对产物进行了表征。采用单因素实验分析方法,研究了水炭用量、pH值、吸附时间和苯酚浓度对水炭吸附性能的影响。在实验的基础上,对吸附热力学和动力学进行了初步探讨。结果表明,玉米芯水炭表面分散着丰富的含氧官能团。苯酚在水炭上的吸附动力学符合拟二阶动力学模型。热力学研究表明,Freundlich吸附等温线模型比Langmuir模型更好地描述了25°C-45°C玉米芯对苯酚的吸附。本研究为开发廉价高效的油田废水中酚类吸附剂提供了科学依据。
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引用次数: 4
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长江油气:英文版
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