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CoS 2 :Ni 17 S 18 :Al 2 S 3 thin film as supercapacitor electrode for astounding energy storage and explicit photocatalyst for pollutants degradation cos2: ni17s18: al2s3薄膜作为超级电容器电极的惊人的能量存储和明确的光催化剂的污染物降解
3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-10-04 DOI: 10.1080/09243046.2023.2265785
Mahwash Mahar Gul, Khuram Shahzad Ahmad, Suliman A. Alderhami, Andrew Guy Thomas, Yasser T Alharbi, Laila Almanqur
AbstractThe ternary metal sulfide CoS2:Ni17S18:Al2S3 thin films were created in the presence of diethyldithiocarbamate as a sulfur source, pursued by physical vapour deposition. X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, UV-visible spectrophotometer, and Fourier transform infrared spectroscopy were used to identify and characterize the synthesised substances. The ternary metal sulfide had a mean crystallite size of 37.8 nm on the nanoscale. SEM revealed spherical particles with rounded edges particles. XPS presented Al 2p, Co 2p, Ni 2p and S 2p core level peaks of the elements. The ternary metal sulfide had a band gap energy of 3.49 eV. The phenomenal storage technology potential of the thin film was evaluated using cyclic voltammetry that revealed an astounding supercapacitance of 515 F g−1, demonstrating the material’s effectiveness. Voltammetric findings show the cycling stability of the nanoparticle thin film. Moreover, the photocatalytic degradation of contaminants such as methylene blue dye, pesticide zoxamide, and phenol was probed, with such a spectacular degradation rate constant of 4.11 × 10−2 min−1 with 91.5% degradation achieved for pesticide.Keywords: Supercapacitorenergy storagephotocatalystthin filmmetal sulfide AcknowledgementsAuthors express their gratitude to the Department of Environmental Sciences, Fatima Jinnah Women University, Pakistan for providing the technical and financial facilities needed for completion of this work. Authors also acknowledge the Higher Education Commission of Pakistan and Photon Science Institute, The University of Manchester, UK. The authors highly acknowledge Xuzhao Liu, PhD student, The University of Manchester, UK, for his tremendous help and assistance during the research. We are highly thankful to the Higher Education Commission of Pakistan for providing financial support for this research under NRPU project No. 15782.Disclosure statementNo potential conflict of interest was reported by the author(s).Data availability statementThe data that support the findings of this study are available from the corresponding author, upon reasonable request.
摘要以二乙基二硫代氨基甲酸酯为硫源,采用物理气相沉积法制备了三元金属硫化物CoS2:Ni17S18:Al2S3薄膜。利用x射线衍射、扫描电子显微镜、x射线光电子能谱、紫外可见分光光度计和傅里叶变换红外光谱对合成的物质进行了鉴定和表征。在纳米尺度上,三元金属硫化物的平均晶粒尺寸为37.8 nm。扫描电镜显示球形颗粒,颗粒边缘呈圆角。XPS显示出元素的Al 2p、Co 2p、Ni 2p和S 2p的核能级峰。三元金属硫化物的带隙能为3.49 eV。使用循环伏安法对薄膜的惊人存储技术潜力进行了评估,显示出惊人的515 F g−1的超级电容,证明了材料的有效性。伏安结果表明纳米颗粒薄膜具有循环稳定性。此外,对亚甲蓝染料、农药唑胺、苯酚等污染物的光催化降解进行了探索,其降解速率常数为4.11 × 10−2 min−1,对农药的降解率达到91.5%。关键词:超级电容储能光催化薄膜金属硫化物致谢作者感谢巴基斯坦法蒂玛真纳女子大学环境科学系为完成这项工作提供了所需的技术和资金支持。作者还感谢巴基斯坦高等教育委员会和英国曼彻斯特大学光子科学研究所。作者非常感谢英国曼彻斯特大学刘旭钊博士在研究过程中给予的巨大帮助和协助。我们非常感谢巴基斯坦高等教育委员会在NRPU项目15782下为这项研究提供财政支持。披露声明作者未报告潜在的利益冲突。数据可用性声明支持本研究结果的数据可在合理要求下从通讯作者处获得。
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引用次数: 0
Assessing thermoelectric performance of quasi 0D carbon and polyaniline nanocomposites using machine learning 利用机器学习评估准d碳和聚苯胺纳米复合材料的热电性能
3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-10-04 DOI: 10.1080/09243046.2023.2262875
Sergio Arroyo Armida, Dariush Ebrahimibagha, Mallar Ray, Shubhabrata Datta
AbstractThermoelectric materials have been widely recognized as a simple approach to harness green energy by converting thermal gradients into electrical energy. However, the intricate interplay between electrical conductivity, Seebeck coefficient, and thermal conductivity in thermoelectric materials presents a challenge to improving their efficiency. Traditional experimental methods and calculation methods have troublesome steps and long cycles for predicting new thermoelectric materials. In this work we present materials informatics-based approach, where statistical and machine learning models like correlation matrix, multiple linear regression, principal component analysis and artificial neural network were employed to find the relationship between features and thermoelectric performance. Furthermore, artificial neural network was used to analyze the roles of several compositional and microstructural features along with temperature on electrical conductivity, thermal conductivity, Seebeck coefficient and thermoelectric figure of merit (ZT) for PANI and quasi 0D carbon-based composites.Keywords: Nanocompositespolyanilinecarbon nanostructuresmaterials informaticsthermoelectric performancemachine learningdata analytics AcknowledgmentsMR acknowledges the support of “University of Alberta-Tecnologico de Monterrey Seed Fund, 2022-2023” and SNI fellowship awarded by CONACyT (Grant ID 1047863).Disclosure statementNo potential conflict of interest was reported by the authors.Data availability statementThe data can be requested and accessed from the authors.
摘要热电材料已被广泛认为是利用绿色能源的一种简单方法,它将热梯度转化为电能。然而,热电材料的导电性、塞贝克系数和导热系数之间复杂的相互作用对提高其效率提出了挑战。传统的实验方法和计算方法对新型热电材料的预测步骤繁琐,周期长。在这项工作中,我们提出了基于材料信息学的方法,其中使用统计和机器学习模型,如相关矩阵,多元线性回归,主成分分析和人工神经网络来寻找特征与热电性能之间的关系。此外,利用人工神经网络分析了几种成分和微观结构特征随温度变化对聚苯胺和准零碳基复合材料的电导率、导热系数、塞贝克系数和热电优值(ZT)的影响。关键词:纳米复合材料聚苯胺碳纳米结构材料信息学热电性能机器学习数据分析致谢smr感谢“阿尔伯塔大学蒙特雷种子基金,2022-2023”的支持和CONACyT授予的SNI奖学金(Grant ID 1047863)。披露声明作者未报告潜在的利益冲突。数据可用性声明可以向作者请求和访问数据。
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引用次数: 0
3D printing with tension and compaction: prevention of fiber waviness in 3D-printed continuous carbon fiber–reinforced thermoplastics 具有张力和压实的3D打印:防止3D打印连续碳纤维增强热塑性塑料中的纤维波纹
3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-09-18 DOI: 10.1080/09243046.2023.2260233
Naruki Ichihara, Masahito Ueda, Kentaro Kajiwara, Antoine Le Duigou, Mickael Castro
AbstractThe 3D printing of continuous carbon fiber–reinforced thermoplastics (c-CFRTP) results in fiber waviness and voids that limit mechanical performance. The effects of tensioning and compaction forces during 3D printing were experimentally studied to suppress fiber waviness. A tensioning force was generated along the filament to straighten the fibers by asynchronously controlling the filament feeding and print speeds. A compaction force was applied through the nozzle tip by setting the layer height to reduce the voids. Microscopic images of specimen cross-sections and surfaces indicated a reduction in fiber waviness and voids after these treatments, and three-point bending tests demonstrated improved mechanical properties. This combination of tensioning and compaction forces achieved 28% and 45% higher bending stiffness and strength, respectively. Tensioning and compaction forces are important printing parameters for the 3D printing of high-performance c-CFRTP.Keywords: Polymer-matrix compositesmechanical propertiesmechanical testing3D printing Disclosure statementNo potential conflict of interest was reported by the authors.Data availability statementThe data that support the findings of this study are available from the corresponding author, N. Ichihara, upon reasonable request.Additional informationFundingThis work was supported by the Japan Society for the Promotion of Science (JSPS) KAKENHI (Grant No. 22K20415). The synchrotron radiation experiments were performed at BL46XU of SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI) (Proposal No. 2018B1842).
摘要连续碳纤维增强热塑性塑料(c-CFRTP)的3D打印导致纤维波纹和空隙,限制了机械性能。实验研究了3D打印过程中拉伸力和压实力对抑制纤维波纹的影响。通过异步控制送丝速度和打印速度,沿纤维产生张力,使纤维拉直。通过设置层高度来减小空隙,通过喷嘴尖端施加压实力。试样横截面和表面的显微图像表明,经过这些处理后,纤维的波纹度和空隙减少了,三点弯曲测试表明力学性能得到了改善。这种张紧力和压实力的组合分别使弯曲刚度和强度提高28%和45%。张紧力和压实力是高性能c-CFRTP 3D打印的重要打印参数。关键词:聚合物基复合材料力学性能力学测试3d打印公开声明作者未报告潜在利益冲突数据可得性声明支持本研究结果的数据可根据合理要求从通讯作者N. Ichihara处获得。本研究得到了日本科学促进会(JSPS) KAKENHI(批准号22K20415)的支持。同步辐射实验由日本同步辐射研究所(JASRI)批准(提案号2018B1842)在SPring-8的BL46XU上进行。
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引用次数: 0
Zein-Bioactive Glass nanocomposite Coating on Magnesium Alloy Substrate for Orthopedic Applications 用于骨科应用的镁合金基底上的Zein生物活性玻璃纳米复合涂层
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-09-04 DOI: 10.1080/09243046.2023.2253110
Narjes Ibrahem Khaled, D. Santhiya
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引用次数: 0
Liquid oxygen compatibility study: carbon nano-tubes based CFRP composite 碳纳米管基碳纤维复合材料的液氧相容性研究
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-09-04 DOI: 10.1080/09243046.2023.2253400
Yusuke Mine, Koichi Yonemoto, T. Fujikawa, Sukanta Das
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引用次数: 0
Effect of Ethylene-Vinyl Acetate on the properties of Polybutylene Terephthalate/ Ethylene-Vinyl Acetate polymer blends 乙烯醋酸乙烯酯对聚对苯二甲酸丁二醇酯/乙烯醋酸乙烯共聚物共混物性能的影响
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-09-04 DOI: 10.1080/09243046.2023.2253401
Pham Thi Hong Nga, Nguyen Van Thuc
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引用次数: 0
Kink band orientation of 3D printed continuous carbon fiber composites under compressive loading 压缩载荷下3D打印连续碳纤维复合材料的扭结带取向
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-08-28 DOI: 10.1080/09243046.2023.2238489
Ahmad Zuhair Bin Zakaria, Takuya Takahashi, A. Todoroki, M. Ueda
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引用次数: 0
Practical method for localizing low-velocity impact on a UAV composite wingbox structure under loading conditions 载荷条件下无人机复合材料翼箱结构低速冲击定位的实用方法
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-08-12 DOI: 10.1080/09243046.2023.2246794
B. Jang
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引用次数: 0
A comprehensive review of the elastic constants of carbon fibers: implications for design and manufacturing of high-performance composite materials 碳纤维弹性常数综述:对高性能复合材料设计和制造的启示
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-08-12 DOI: 10.1080/09243046.2023.2245210
F. Tanaka, T. Ishikawa, M. Tane
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引用次数: 0
Identification of invisible fatigue damage of thermosetting epoxy resin by non-destructive thermal measurement using entropy generation 基于熵产法的热固性环氧树脂的不可见疲劳损伤识别
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-30 DOI: 10.1080/09243046.2023.2230687
Natsuko Kudo, Ryohei Fujita, Y. Oya, T. Sakai, H. Nagano, J. Koyanagi
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引用次数: 3
期刊
Advanced Composite Materials
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