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Parts Surface Defect Detection Algorithm Based on Improved YOLOv8s 基于改进YOLOv8s的零件表面缺陷检测算法
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-30 DOI: 10.1002/eng2.70569
Zhe Sun, Caiying Qiao, Dongrui Li, Enhua Zhang

Inspection of surface defects in industrial components is vital to ensuring product quality and operational safety. This study presents an improved YOLOv8s-based deep learning model designed to detect fatigue and linear cracks on part surfaces with high localization and classification accuracy. Unlike conventional manual inspection, the proposed system achieves real-time detection while maintaining low computational cost. A custom dataset comprising high-resolution images of concrete and metallic textures captured under diverse environmental conditions was used for training and evaluation. Data augmentation techniques such as Mosaic and Contrast Limited Adaptive Histogram Equalization (CLAHE) were employed to enhance generalization, and the model was trained for 100 epochs to ensure stable convergence. The enhanced YOLOv8s architecture integrates the Convolutional Block Attention Module (CBAM) and Ant Colony Optimization (ACO) for intelligent feature selection, resulting in improved learning efficiency and reduced overfitting. Experimental results show that the model achieves mAP@IoU = 0.5 of 0.9626 and [email protected]:0.95 of 0.7803, with validation box and class losses of 0.6849 and 0.5377, respectively. Precision and recall values of 0.926 and 0.923 demonstrate excellent detection completeness and low false positives. Comparative analysis with BsS-YOLO and Efficient YOLOv8-ES confirms the superior accuracy and efficiency of the proposed approach. Visual inspection further validates the model's robustness in identifying diverse crack patterns under challenging surface conditions. The improved YOLOv8s model thus offers a scalable, real-time, and accurate solution for automated defect detection in industrial applications. Future work will focus on multi-class defect recognition and deployment on lightweight edge-computing devices.

工业部件表面缺陷的检测对保证产品质量和操作安全至关重要。本研究提出了一种改进的基于yolov8的深度学习模型,用于检测零件表面的疲劳和线性裂纹,具有较高的定位和分类精度。与传统的人工检测不同,该系统实现了实时检测,同时保持了较低的计算成本。一个自定义数据集包含在不同环境条件下捕获的混凝土和金属纹理的高分辨率图像,用于训练和评估。采用马赛克和对比度有限自适应直方图均衡化(CLAHE)等数据增强技术增强模型的泛化能力,并对模型进行了100次epoch的训练,保证了模型的稳定收敛。增强的YOLOv8s架构集成了卷积块注意模块(CBAM)和蚁群优化(ACO)进行智能特征选择,提高了学习效率,减少了过拟合。实验结果表明,该模型实现了0.9626中的mAP@IoU = 0.5和[email protected]中的0.7803中的0.95,验证盒损失和类损失分别为0.6849和0.5377。查准率和查全率分别为0.926和0.923,检测完备性好,误报率低。与BsS-YOLO和Efficient YOLOv8-ES的对比分析证实了该方法具有较高的准确性和效率。目视检查进一步验证了模型在具有挑战性的表面条件下识别各种裂纹模式的鲁棒性。因此,改进的YOLOv8s模型为工业应用中的自动缺陷检测提供了可扩展的、实时的和准确的解决方案。未来的工作将集中在轻量级边缘计算设备上的多类缺陷识别和部署。
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引用次数: 0
An Explainable Triple-Layered Ensemble Model for Early Prediction of Suicide Risk Using Machine Learning 使用机器学习早期预测自杀风险的可解释的三层集成模型
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-30 DOI: 10.1002/eng2.70574
Md. Samiul Alom, Md. Anamul Hoque Tomal, Rukaiya Taha, Shamima Parvez, Md Abu Layek, Mohammad Mohsin, Md. Alamin Talukder

Suicide ranks as the 18th leading cause of death worldwide among young adults, claiming over 720,000 lives each year. Early detection of individuals at risk is essential for timely intervention. This study introduces a Triple-Layer Ensemble (TLE) model that predicts suicidal behavior using machine learning techniques. The proposed model combines Random Forest (RF), Support Vector Machine (SVM), and K-Nearest Neighbors (KNN) to enhance prediction accuracy. Experimental results show that the TLE model surpasses individual classifiers and traditional ensemble methods, achieving 94.81% accuracy, 98.15% ROC-AUC, and a Matthews Correlation Coefficient (MCC) of 92.23%. To improve interpretability, Explainable AI (XAI) methods, Local Interpretable Model-Agnostic Explanations (LIME), and Shapley Additive Explanations (SHAP) highlight key predictors such as mental support, stress levels, and self-harm history. Additionally, a web-based platform incorporating the TLE model provides real-time suicide risk assessment, enabling healthcare professionals to implement personalized interventions. The proposed framework delivers high predictive performance with transparency and interpretability, offering a scalable solution for early suicide risk prediction and prevention.

自杀是全世界年轻人死亡的第18大原因,每年夺去72万多人的生命。早期发现有风险的个体对于及时干预至关重要。本研究引入了一个使用机器学习技术预测自杀行为的三层集成(TLE)模型。该模型结合随机森林(Random Forest, RF)、支持向量机(Support Vector Machine, SVM)和k近邻(K-Nearest Neighbors, KNN)来提高预测精度。实验结果表明,TLE模型优于单个分类器和传统的集成方法,准确率达到94.81%,ROC-AUC达到98.15%,Matthews相关系数(MCC)达到92.23%。为了提高可解释性,可解释人工智能(XAI)方法、局部可解释模型不可知论解释(LIME)和Shapley加性解释(SHAP)强调了关键的预测因素,如精神支持、压力水平和自残史。此外,结合TLE模型的基于网络的平台提供实时自杀风险评估,使医疗保健专业人员能够实施个性化干预。该框架具有较高的预测性能,具有透明性和可解释性,为早期自杀风险预测和预防提供了可扩展的解决方案。
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引用次数: 0
A Machine Learning Framework for Detecting and Preventing Cyber-Attacks in Industrial Cyber-Physical Systems 工业信息物理系统中检测和预防网络攻击的机器学习框架
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-30 DOI: 10.1002/eng2.70520
Anurag Sinha, Rejuwan Shamim, Mihika Mahendra, Trupti Mohota, G. Madhukar Rao, Mohammad Nadeem Ahmed, Mohammad Rashid Hussain, Satyam Solanki, Tanish Ranjan,  Bhaskar, Mini Kumari, Karan Dixit, Vyom Modi, Syed Immamul Ansarullah, Mohd Asif Shah

The increasing adoption of cyber-physical systems (CPS) in Industry 4.0 has heightened vulnerability to cyber threats. This study proposes a machine learning–based intrusion detection framework, DBID-Net, to effectively identify and prevent attacks in CPS environments. The framework integrates advanced modules for data handling and threat analysis, employing AMMIS for data cleaning, ADASYN for data augmentation, CESF for feature extraction, and the Whale Hopper Optimization Algorithm (WHOA) for optimal feature selection. A bidirectional learning model is used for intrusion detection, with WHOA further enhancing scalability and adaptive attack mitigation. Experimental results show that DBID-Net achieves an F1-score of 0.988, a sensitivity of 0.984, a specificity of 0.983, and an accuracy of 0.9916. These findings demonstrate that DBID-Net offers a robust and scalable solution for securing CPS infrastructures against evolving cyber threats in Industry 4.0.

在工业4.0时代,越来越多地采用网络物理系统(CPS)增加了对网络威胁的脆弱性。本研究提出了一种基于机器学习的入侵检测框架DBID-Net,以有效识别和预防CPS环境中的攻击。该框架集成了用于数据处理和威胁分析的高级模块,使用AMMIS进行数据清理,使用ADASYN进行数据增强,使用CESF进行特征提取,使用Whale Hopper优化算法(哇)进行最佳特征选择。采用双向学习模型进行入侵检测,进一步增强了可扩展性和自适应攻击缓解能力。实验结果表明,该方法的f1评分为0.988,灵敏度为0.984,特异性为0.983,准确率为0.9916。这些发现表明,DBID-Net为保护CPS基础设施免受工业4.0中不断变化的网络威胁提供了一个强大且可扩展的解决方案。
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引用次数: 0
Voltage Stability Assessment Based on Modified Line Voltage Stability Index in the Presence of Renewable Energy Integration and Credible Contingencies 基于修正线路电压稳定指标的可再生能源并网和可信事件下的电压稳定评估
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-30 DOI: 10.1002/eng2.70578
Yalew Gebru Werkie, George Nyauma Nyakoe, Cyrus Wabuge Wekesa

Modern power systems are significantly impacted by unpredictable load fluctuations, renewable energy integration, and an increasing number of outages—operational scenarios that have the potential to cause voltage instability and collapse. This necessitates near real-time monitoring and control by operators, enabling the identification of critical lines or vulnerable buses operating close to their stability limits. This study proposes a modified line voltage stability index (MLVSI) to enhance the accuracy and computational speed of voltage stability assessment (VSA) adapted to diverse operating scenarios. The index incorporates active and reactive power, the angular difference between sending end and receiving end bus voltages, and line impedance. Using the IEEE 57-bus test system, the proposed index was validated against existing stability indices—line stability index (Lmn), modern voltage stability index (MVSI), and novel collapse prediction index (NCPI)—by comparing accuracy and computation time under various operational scenarios. Results indicate that MLVSI provides higher accuracy and faster detection, particularly under extreme operating conditions. For example, compared with the NCPI, the MLVSI achieved a 4.8% improvement in accuracy and reduced the computation time by 0.07–0.103 s on different operating scenarios. The adaptability of MLVSI to diverse scenarios underscores its potential for broad application in the assessment of voltage stability.

现代电力系统受到不可预测的负荷波动、可再生能源整合和越来越多的停电(有可能导致电压不稳定和崩溃的运行场景)的显著影响。这就需要操作员进行近乎实时的监测和控制,从而能够识别接近其稳定极限的关键线路或脆弱总线。本文提出了一种改进的线路电压稳定指数(MLVSI),以提高电压稳定评估(VSA)的准确性和计算速度,以适应不同的运行场景。该指标包括有功和无功功率、发送端和接收端母线电压之间的角差以及线路阻抗。利用IEEE 57总线测试系统,通过比较各种运行场景下的准确性和计算时间,将所提出的指标与现有的稳定指标——线路稳定指数(Lmn)、现代电压稳定指数(MVSI)和新型崩溃预测指数(NCPI)进行了对比验证。结果表明,MLVSI提供了更高的准确性和更快的检测速度,特别是在极端的操作条件下。例如,与NCPI相比,MLVSI在不同操作场景下的精度提高了4.8%,计算时间缩短了0.07-0.103 s。MLVSI对各种场景的适应性突出了其在电压稳定性评估中的广泛应用潜力。
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引用次数: 0
Microwave-Assisted Technologies in Gold Extraction: A Review 微波辅助提金技术研究进展
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-29 DOI: 10.1002/eng2.70579
B. Shahbazi

This review critically examines the application of microwave-assisted technologies in gold mining and processing, highlighting their potential to improve extraction efficiency and environmental sustainability. The study focuses on the use of microwave irradiation in ore pretreatment, leaching enhancement, treatment of waste activated carbon, and synthesis of gold nanoparticles. Evidence from recent research demonstrates that microwave-assisted processes can significantly increase gold recovery rates, reduce processing times, and lower energy consumption compared to conventional techniques. For refractory ores, microwave pretreatment effectively improves mineral liberation and leaching kinetics, achieving extraction rates exceeding 90% in some cases. Additionally, the integration of microwave roasting with chemical additives such as NaOH and KOH has shown further enhancement in gold recovery. Despite these promising outcomes, challenges remain in terms of temperature control, process scalability, and optimization across different ore types. The review concludes by outlining key directions for future research, including the development of industrial-scale systems, comprehensive economic assessments, and the exploration of microwave applications in combination with alternative lixiviants. Overall, microwave-assisted technologies present a promising pathway toward more efficient and sustainable gold production.

本文综述了微波辅助技术在黄金开采和加工中的应用,强调了它们在提高提取效率和环境可持续性方面的潜力。研究了微波辐照在矿石预处理、强化浸出、废活性炭处理和纳米金合成等方面的应用。最近的研究表明,与传统技术相比,微波辅助工艺可以显著提高黄金回收率,减少处理时间,降低能耗。对于难选矿石,微波预处理有效地改善了矿物的解离和浸出动力学,在某些情况下提取率超过90%。此外,微波焙烧与NaOH、KOH等化学添加剂相结合,进一步提高了金的回收率。尽管取得了这些有希望的成果,但在温度控制、工艺可扩展性和不同矿石类型的优化方面仍然存在挑战。综述最后概述了未来研究的关键方向,包括工业规模系统的开发,综合经济评估以及微波与替代浸出剂结合应用的探索。总的来说,微波辅助技术为更有效和可持续的黄金生产提供了一条有希望的途径。
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引用次数: 0
Study on Hydrothermal Catalytic Oxidation Demulsification of Oily Sludge 水热催化氧化破乳含油污泥的研究
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-29 DOI: 10.1002/eng2.70559
Tao Yu, Zhenhu Chen, Rong Zhang, Mingming Du, Chengtun Qu

Oily sludge, a hazardous waste generated during crude oil exploitation, gathering, and transportation, with crude oil constituting one of its primary sources of pollution. Reclamation of hydrocarbon components within oily sludge constitutes a pivotal step toward its resource utilization. However, the presence of emulsifying surfactants and adhesion of crude oil to solid surfaces foster stable systems, which impede oil recovery and necessitate demulsification as a prerequisite for effective reclamation. HTCO, which generates abundant free radicals, represents a promising strategy for destabilizing the stabilized oil–water interface. This study employed single-factor and orthogonal array experiments to systematically investigate the effects of five key operational parameters on crude oil recovery efficiency: catalyst concentration (0–200 mg L−1), reaction temperature (50°C–250°C), reaction time (5–25 min), oxidation coefficient (1.0–3.0), and solid-to-liquid ratio (1:20–1:4). After HTCO treatment of oily sludge, optimal conditions were identified as follows: catalyst concentration at 50 mg L−1, temperature at 200°C, reaction time of 10 min, oxidation coefficient of 1, and solid-to-liquid ratio at 1:5. Under these parameters, the oil recovery efficiency reached 89.46%. HTCO synergistically breaks highly emulsified oil sludge efficiently with high recovery rates, enhances crude oil quality, reduces downstream costs, and delivers environmental benefits.

含油污泥是原油开采、收集和运输过程中产生的一种危险废弃物,原油是其主要污染源之一。含油污泥中烃类成分的回收是含油污泥资源化利用的关键环节。然而,乳化表面活性剂的存在和原油与固体表面的粘附形成了稳定的体系,这阻碍了原油的采收率,因此需要破乳作为有效回收的先决条件。HTCO产生大量自由基,是破坏稳定油水界面稳定的一种很有前途的策略。采用单因素试验和正交试验,系统考察了催化剂浓度(0 ~ 200 mg L−1)、反应温度(50℃~ 250℃)、反应时间(5 ~ 25 min)、氧化系数(1.0 ~ 3.0)、料液比(1:20 ~ 1:4)5个关键操作参数对原油采收率的影响。HTCO处理含油污泥的最佳条件为:催化剂浓度为50 mg L−1,温度为200℃,反应时间为10 min,氧化系数为1,料液比1:5。在此参数下,采收率达到89.46%。HTCO能够协同高效地分解高度乳化的油泥,具有高回收率,提高原油质量,降低下游成本,并带来环境效益。
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引用次数: 0
Sophisticated Audio Source Separation: A Statistical Exploration of Clarity and Precision With FastICA 复杂的音频源分离:与FastICA的清晰度和精度的统计探索
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-29 DOI: 10.1002/eng2.70575
Md. Razu Ahmed, Jannatul Mauya, Md. Shamim Reza, Ruhul Amin

This study evaluates audio source separation with Fast Independent Component Analysis (FastICA) in a fully specified, reproducible pipeline and benchmarks it against Principal Component Analysis (PCA) and Nonnegative Matrix Factorization (NMF). Three conversational recordings collected at the Department of Statistics, Pabna University of Science and Technology were canonicalized to 48 kHz WAV 96.63 s each, converted to mono, trimmed at 25 dB, RMS-normalized, and time-aligned. Sources were mixed with a fixed 3 × 3 row-normalized Gaussian matrix. FastICA used parallel updates with a logcosh nonlinearity and unit-variance whitening; PCA served as a multichannel linear baseline; NMF operated on a mono short-time Fourier transform with KL divergence and NNDSVDA initialization, followed by soft masking and inverse transform. Performance was computed with BSS Eval after best-permutation and scale alignment and summarized over 10 runs as mean ± SD. FastICA achieved Signal-to-Distortion Ratio (SDR) 53.51 ± 0.07 dB, Signal-to-Interference Ratio (SIR) 53.52 ± 0.07 dB, and Signal-to-Artifact Ratio (SAR) 79.58 ± 0.00 dB, well above a 20 dB high-quality SDR threshold. PCA yielded SDR 2.79 ± 0.00 dB, SIR 2.79 ± 0.00 dB, SAR 80.64 ± 0.00 dB; NMF produced SDR −2.26 ± 0.00 dB, SIR 0.41 ± 0.00 dB, SAR 4.80 ± 0.00 dB. Waveform and spectrogram visualizations, together with descriptive, high-order, and entropy statistics, corroborate these outcomes. The results establish FastICA as an effective classical approach for audio source separation and provide a transparent reference pipeline for comparative studies using SDR, SIR, and SAR.

本研究在完全指定的可重复管道中使用快速独立分量分析(FastICA)评估音频源分离,并将其与主成分分析(PCA)和非负矩阵分解(NMF)进行基准测试。从帕纳科技大学统计系收集的三段对话录音分别规范化为48 kHz WAV 96.63 s,转换为单声道,在25 dB进行裁剪,rms归一化和时间对齐。源与固定的3 × 3行归一化高斯矩阵混合。FastICA采用logcosh非线性和单位方差白化并行更新;PCA作为多通道线性基线;NMF首先进行KL散度和NNDSVDA初始化的单频短时傅里叶变换,然后进行软掩模和反变换。在最佳排列和量表对齐后,使用BSS Eval计算性能,并以mean±SD总结10次运行。FastICA的信失真比(SDR)为53.51±0.07 dB,信干扰比(SIR)为53.52±0.07 dB,信伪比(SAR)为79.58±0.00 dB,远高于20 dB的高质量SDR阈值。主成分分析所得SDR为2.79±0.00 dB, SIR为2.79±0.00 dB, SAR为80.64±0.00 dB;NMF产生SDR−2.26±0.00 dB, SIR 0.41±0.00 dB, SAR 4.80±0.00 dB。波形和频谱图可视化,以及描述性、高阶和熵统计,证实了这些结果。结果表明,FastICA是一种有效的经典音频源分离方法,并为SDR、SIR和SAR的比较研究提供了透明的参考管道。
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引用次数: 0
HARVEST: A Locality-Enhanced Vision Transformer for Efficient Multi-Level Grocery Classification HARVEST:用于高效多级杂货分类的位置增强视觉转换器
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-29 DOI: 10.1002/eng2.70534
Anuruddha Paul, Rishi Raj, Mahendra Kumar Gourisaria, Amitkumar V. Jha, Nicu Bizon

Grocery product recognition faces unique challenges in distinguishing visually similar items across hierarchical categories while maintaining computational efficiency. Though powerful in image classification, traditional vision transformers (ViTs) struggle with specialized retail datasets due to their high parameter counts and inadequate local feature extraction for fine-grained distinctions. We present HARVEST, a lightweight transformer architecture that addresses these limitations through five key components: (1) shifted patch tokenization, which enhances local feature capture via overlapping diagonal patches; (2) local information enhancer, which injects spatial awareness into patch embeddings; and (3) hierarchical attention, an integrated module that dynamically unites locality-enhanced attention, cross-level attention, and progressive classification heads to effectively fuse multiscale features across hierarchical levels. Evaluated on the Hierarchical Grocery Store dataset, HARVEST achieves 98.73% coarse-grained and 97.06% fine-grained accuracy with only 2.66M parameters–82.7% fewer than conventional models. This performance stems from its ability to resolve critical retail recognition challenges: distinguishing near-identical packaging variants (e.g., juice flavors differing by subtle color gradients) and capturing hierarchical relationships between product categories (e.g., apples $$ to $$ varieties) through progressive classification heads. The architecture's efficiency and accuracy advance automated shelf monitoring and inventory systems without compromising computational practicality. HARVEST achieves real-time performance, defined as inference latency below 10 ms per image on an NVIDIA T4 GPU, with an average throughput of 146.6 images per second (batch size 1), thereby facilitating seamless assistive grocery classification.

杂货产品识别面临着独特的挑战,在保持计算效率的同时区分视觉上相似的物品。传统的视觉变压器(vit)虽然在图像分类方面很强大,但由于其参数数量高,并且对细粒度区分的局部特征提取不足,因此在特定的零售数据集上存在困难。我们提出了HARVEST,一种轻量级的转换器架构,通过五个关键组件解决了这些限制:(1)移位补丁标记化,通过重叠对角补丁增强局部特征捕获;(2)局部信息增强器,将空间感知注入到补丁嵌入中;(3)分层注意,动态统一位置增强注意、跨层次注意和递进分类头的集成模块,有效融合跨层次的多尺度特征。在分层杂货店数据集上评估,HARVEST达到98.73% coarse-grained and 97.06% fine-grained accuracy with only 2.66M parameters–82.7% fewer than conventional models. This performance stems from its ability to resolve critical retail recognition challenges: distinguishing near-identical packaging variants (e.g., juice flavors differing by subtle color gradients) and capturing hierarchical relationships between product categories (e.g., apples → $$ to $$ varieties) through progressive classification heads. The architecture's efficiency and accuracy advance automated shelf monitoring and inventory systems without compromising computational practicality. HARVEST achieves real-time performance, defined as inference latency below 10 ms per image on an NVIDIA T4 GPU, with an average throughput of 146.6 images per second (batch size 1), thereby facilitating seamless assistive grocery classification.
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引用次数: 0
Detailed Effects of Road Conditions and Lateral Maneuvers on Dynamic Stability of Four-Wheel-Steering Vehicles 道路条件和横向操纵对四轮转向车辆动态稳定性的详细影响
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-28 DOI: 10.1002/eng2.70584
Nguyen Cong Khai, Vo Tran Thi Bich Chau, Nguyen Gia Minh Thao

This study explores the detailed effects of speed, road adhesion, road slope, and dynamic maneuvers on the lateral stability of vehicles equipped with four-wheel steering (4WS) systems, also referred to as all-wheel steering (AWS) system. The research uses CarSim simulation software to comprehensively evaluate vehicle performance under various speeds (30–90 km/h), road slope (10°–30°) and adhesion coefficients (0.1–0.85) during lane changes and turning maneuvers. The results obtained reveal that 4WS significantly enhances stability and handling at moderate speeds and favorable adhesion conditions. However, high-speed operations, particularly on low adhesion surfaces or with a steep road slope, increase instability and safety risks. Practical implications also emphasize the importance of maintaining safe speeds, particularly under adverse road conditions, and decreasing speed during sharp turns to counteract centrifugal forces. Finally, these findings highlight the substantial role of cautious driving and adherence to speed limits in improving overall safety for 4WS vehicles.

本研究探讨了速度、道路附着力、道路坡度和动态操纵对配备四轮转向(4WS)系统(也称为全轮转向(AWS)系统)的车辆横向稳定性的详细影响。本研究采用CarSim仿真软件,综合评价了车辆在不同速度(30-90 km/h)、不同坡度(10°-30°)、不同附着系数(0.1-0.85)条件下变道和转弯机动时的性能。结果表明,在中等速度和良好的附着条件下,4WS显著提高了稳定性和操控性。然而,高速运行,特别是在低附着表面或陡峭的路面上,会增加不稳定性和安全风险。实际意义也强调了保持安全速度的重要性,特别是在不利的道路条件下,以及在急转弯时降低速度以抵消离心力。最后,这些发现强调了谨慎驾驶和遵守速度限制在提高4WS车辆整体安全性方面的重要作用。
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引用次数: 0
Computational and Experimental Analyses of the Synergistic Corrosion Inhibition of Green Phytochemicals Found in Yellow Bush in Acidic Media 酸性介质中黄色灌木绿色植物化学物质协同缓蚀的计算与实验分析
IF 2 Q3 COMPUTER SCIENCE, INTERDISCIPLINARY APPLICATIONS Pub Date : 2025-12-28 DOI: 10.1002/eng2.70563
Joseph Itodo Emmanuel, Fayen Odette Ngasoh, Chidiebele E. J. Uzoagba, Abdulhakeem Bello, Vitalis Chioh Anye, Azikiwe Peter Onwualu, Baboo Yashwansingh Surnam, Okoye Cyril Onyeka

The synergistic corrosion inhibition of a unique molecular combination, hexadecanoic acid-methyl ester, terpineol, and 1,5,9-undecatriene-2,6,10-trimethyl-(Z) present in Sunshine Ligustrum (yellow bush) extract was investigated on Fe (110) crystal surfaces in acidic medium. The study employed density functional theory (DFT), Monte Carlo (MC) simulations, radial distribution function (RDF), weight loss (WL), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), FE-SEM, and EDX analyses. The orbital matching principle (OMP) revealed that neutral 1,5,9-undecatriene-2,6,10-trimethyl-(Z) and terpineol donate electrons from their HOMO to the 3d-orbital of iron, due to their small energy gaps (0.530 and 0.552 eV, respectively). The protonated hexadecanoic acid-methyl ester and terpineol revealed higher HOMO (−0.229 and −0.239 eV); this indicates initial adsorption by physisorption followed by chemisorption. MC analysis showed that the three phytochemicals were synergistically adsorbed at low-energy sites. The RDF suggests the phytochemicals will bond with steel by chemisorption. The raw extract demonstrated high inhibition efficiencies of 77.53% by WL at 40 ppm and approximately 90% by EIS and Tafel plots at 60 ppm. Tafel plots indicate that yellow bush is a mixed-type (ambiodic) inhibitor. EIS analysis showed that the charge-transfer resistance (Rct) increased significantly from 8.91 ± 6.6E-2 to 88.91 ± 7.4E-1Ωcm2 with increasing inhibitor concentration, while the double-layer capacitance (Cdl) decreased from 716.47 ± 5.3 to 357.4 ± 3.1μFcm2. FE-SEM and EDX confirmed the formation of a protective layer that effectively inhibited acidic corrosion. The results strongly suggest that these three phytochemicals warrant further screening before industry deployment as effective, low-dosage green corrosion inhibitors for the control of acidic corrosion of API 5 L X65 steel.

研究了阳光女贞子(黄色灌木)提取物中独特的分子组合——十六烷酸-甲酯、松油醇和1,5,9-十一烷-2,6,10-三甲基(Z)在酸性介质中Fe(110)晶体表面的协同缓蚀作用。研究采用密度泛函理论(DFT)、蒙特卡罗(MC)模拟、径向分布函数(RDF)、失重(WL)、电化学阻抗谱(EIS)、动电位极化(PDP)、FE-SEM和EDX分析。轨道匹配原理(OMP)表明,中性的1,5,9-十一碳烯-2,6,10-三甲基-(Z)和松油醇由于能隙小(分别为0.530和0.552 eV),将HOMO上的电子给到了铁的3d轨道上。质子化的十六烷酸甲酯和松油醇HOMO较高(- 0.229和- 0.239 eV);这表明最初的吸附是物理吸附,然后是化学吸附。MC分析表明,这三种植物化学物质在低能位点具有协同吸附作用。RDF表明植物化学物质将通过化学吸附与钢结合。粗提物在40 ppm时WL的抑制效率为77.53%,在60 ppm时EIS和Tafel的抑制效率约为90%。Tafel图显示黄灌木为混合型(两生型)抑制剂。EIS分析表明,随着抑制剂浓度的增加,电荷转移电阻(Rct)从8.91±6.6E-2显著增加到88.91±7.4E-1Ωcm2,而双层电容(Cdl)从716.47±5.3降低到357.4±3.1μFcm2。FE-SEM和EDX证实了保护层的形成,有效地抑制了酸性腐蚀。结果强烈表明,在工业应用之前,这三种植物化学物质值得进一步筛选,作为有效的低剂量绿色缓蚀剂,用于控制API 5l X65钢的酸性腐蚀。
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