Iron chelating agents have important roles to play, both in human physiology and in the environment. In the latter case, persistence in the environment has given cause for concern in the case of synthetic iron chelating agents such as ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA), which do not readily biodegrade. Due to their long lifespan in the environment synthetic iron chelators can also participate in mobilization reactions, particularly with radionuclides such as 60Co. There is an eminent need to explore alternative iron chelating compounds, preferably, renewable in origin, to overcome the drawbacks of synthetic compounds, making plant biomass a potential source of iron chelating agents. Twelve biomass model compounds, representative of the biomass constituents, cellulose, hemicellulose, lignin and extractives (tannins), were tested for their iron complexation ability by measurement of the binding strengths with Fe(II) and Fe(III) in dimethylsulfoxide (DMSO), to ensure solubility, using spectrophotometric titration. The flavonols, kaempferol, quercetin and myricetin displayed the strongest binding affinity to Fe(II) and Fe(III) along with the greatest positive cooperativity as determined by the calculation of Hill coefficients. The lignin-representative compound, p-coumaric acid, showed the highest binding affinity to Fe(II) only. Carbohydrate model compounds did not show any evidence of binding to iron, despite some contrary evidence in literature about their ability to do so. This study points to the potential role that the flavonols class of compounds, and therefore by extension, plant tissues that are rich in extractives, may play in the exploration of biomass-derived iron chelants.
{"title":"Iron complexation by biomass model compounds†","authors":"Anurag S. Mandalika and Troy M. Runge","doi":"10.1039/D3VA00383C","DOIUrl":"https://doi.org/10.1039/D3VA00383C","url":null,"abstract":"<p >Iron chelating agents have important roles to play, both in human physiology and in the environment. In the latter case, persistence in the environment has given cause for concern in the case of synthetic iron chelating agents such as ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA), which do not readily biodegrade. Due to their long lifespan in the environment synthetic iron chelators can also participate in mobilization reactions, particularly with radionuclides such as <small><sup>60</sup></small>Co. There is an eminent need to explore alternative iron chelating compounds, preferably, renewable in origin, to overcome the drawbacks of synthetic compounds, making plant biomass a potential source of iron chelating agents. Twelve biomass model compounds, representative of the biomass constituents, cellulose, hemicellulose, lignin and extractives (tannins), were tested for their iron complexation ability by measurement of the binding strengths with Fe(<small>II</small>) and Fe(<small>III</small>) in dimethylsulfoxide (DMSO), to ensure solubility, using spectrophotometric titration. The flavonols, kaempferol, quercetin and myricetin displayed the strongest binding affinity to Fe(<small>II</small>) and Fe(<small>III</small>) along with the greatest positive cooperativity as determined by the calculation of Hill coefficients. The lignin-representative compound, <em>p</em>-coumaric acid, showed the highest binding affinity to Fe(<small>II</small>) only. Carbohydrate model compounds did not show any evidence of binding to iron, despite some contrary evidence in literature about their ability to do so. This study points to the potential role that the flavonols class of compounds, and therefore by extension, plant tissues that are rich in extractives, may play in the exploration of biomass-derived iron chelants.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 11","pages":" 1616-1627"},"PeriodicalIF":3.5,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/va/d3va00383c?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142524275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Magdalena J. Mkelemi, Grite N. Mwaijengo and Mwemezi J. Rwiza
The abnormally gigantic baobab tree (Adansonia digitata) is often referred to as the “Tree of Life” due to its ability to provide food, water, shelter, and traditional medicine for both humans and animals in arid regions. This special tree is a landmark of Africa's savanna and has attracted the attention of the global research community. This study investigated the potential of biochar derived from baobab seeds for the removal of metallic ions from groundwater. The biochar, prepared at 700 °C, exhibited a unique surface morphology with deep voids and varied structures, suggesting increased surface area and favorable conditions for adsorption. SEM-EDX analyses confirmed the elemental composition, with carbon being the predominant element. Furthermore, XRD analysis indicated an amorphous structure, enhancing adsorption capacity for heavy metal ions. Additionally, BET analysis revealed a significant surface area (1386.704 m2 g−1) and well-defined pores, emphasizing the material's potential for metallic ion removal. The metallic ion of choice for this research was Fe because of its abundance in the study area and the community's need for affordable technology for discoloration of reddish-brown groundwater caused by Fe ion presence. In the batch mode equilibrium studies, the effect of pH, contact time, adsorbent particle size, adsorbent dose, solution temperature, and initial metal ion concentration was investigated. Optimal pH metallic ion removal occurred under neutral pH conditions, with higher removal efficiency observed at increased contact time (up to 120 min) and adsorbent doses. Adsorption isotherm modeling using Langmuir and Freundlich models indicated favorable adsorption, with the Freundlich model providing a slightly better fit. In conclusion, baobab seed-derived biochar demonstrated promising potential as an efficient and sustainable adsorbent for metal ion removal from groundwater. Further exploration, including the development of activated carbon and field applications, is recommended for a comprehensive understanding and practical optimization of this material's capabilities for metal ion removal.
{"title":"“Tree of life”: how baobab seed-derived biochar could lead to water safety for underprivileged communities through heavy metal (Fe) removal – SDG 6","authors":"Magdalena J. Mkelemi, Grite N. Mwaijengo and Mwemezi J. Rwiza","doi":"10.1039/D4VA00205A","DOIUrl":"https://doi.org/10.1039/D4VA00205A","url":null,"abstract":"<p >The abnormally gigantic baobab tree (<em>Adansonia digitata</em>) is often referred to as the “Tree of Life” due to its ability to provide food, water, shelter, and traditional medicine for both humans and animals in arid regions. This special tree is a landmark of Africa's savanna and has attracted the attention of the global research community. This study investigated the potential of biochar derived from baobab seeds for the removal of metallic ions from groundwater. The biochar, prepared at 700 °C, exhibited a unique surface morphology with deep voids and varied structures, suggesting increased surface area and favorable conditions for adsorption. SEM-EDX analyses confirmed the elemental composition, with carbon being the predominant element. Furthermore, XRD analysis indicated an amorphous structure, enhancing adsorption capacity for heavy metal ions. Additionally, BET analysis revealed a significant surface area (1386.704 m<small><sup>2</sup></small> g<small><sup>−1</sup></small>) and well-defined pores, emphasizing the material's potential for metallic ion removal. The metallic ion of choice for this research was Fe because of its abundance in the study area and the community's need for affordable technology for discoloration of reddish-brown groundwater caused by Fe ion presence. In the batch mode equilibrium studies, the effect of pH, contact time, adsorbent particle size, adsorbent dose, solution temperature, and initial metal ion concentration was investigated. Optimal pH metallic ion removal occurred under neutral pH conditions, with higher removal efficiency observed at increased contact time (up to 120 min) and adsorbent doses. Adsorption isotherm modeling using Langmuir and Freundlich models indicated favorable adsorption, with the Freundlich model providing a slightly better fit. In conclusion, baobab seed-derived biochar demonstrated promising potential as an efficient and sustainable adsorbent for metal ion removal from groundwater. Further exploration, including the development of activated carbon and field applications, is recommended for a comprehensive understanding and practical optimization of this material's capabilities for metal ion removal.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 12","pages":" 1735-1745"},"PeriodicalIF":3.5,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/va/d4va00205a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142714045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Maleigh Mifkovic, Brian D. Etz, Manoj K. Shukla and Shubham Vyas
Trimethylsiloxane (TriSil) surfactants are promising alternatives to per- and polyfluoroalkyl substances (PFAS), which are global recalcitrant and persistent environmental contaminants, in aqueous film-forming fire-fighting foams (AFFF). However, much less information is available on the environmental fate and degradation of TriSil surfactants. Thus, it is important to study the degradation chemistry of fluorine-free TriSil surfactants in the solution phase under various conditions to further assess their environmental impact. This computational study reports the prominent hydrolysis, reduction, and oxidation pathways of a truncated TriSil and proposes the major degradation products using density functional theory (DFT) calculations. We have identified the polydimethylsiloxane unit of TriSil to play a prominent role in aqueous solution reactivity initiated via hydrolysis and reduction, while oxidation mainly proceeds through H-atom abstraction along the polyethylene glycol unit. The results of this study aid in establishing the use of the alternative fluorine-free surfactant, TriSil, for fire-fighting foams from an environmental perspective.
{"title":"Aqueous solution degradation pathways of trimethylsiloxane surfactants†","authors":"Maleigh Mifkovic, Brian D. Etz, Manoj K. Shukla and Shubham Vyas","doi":"10.1039/D4VA00256C","DOIUrl":"https://doi.org/10.1039/D4VA00256C","url":null,"abstract":"<p >Trimethylsiloxane (TriSil) surfactants are promising alternatives to per- and polyfluoroalkyl substances (PFAS), which are global recalcitrant and persistent environmental contaminants, in aqueous film-forming fire-fighting foams (AFFF). However, much less information is available on the environmental fate and degradation of TriSil surfactants. Thus, it is important to study the degradation chemistry of fluorine-free TriSil surfactants in the solution phase under various conditions to further assess their environmental impact. This computational study reports the prominent hydrolysis, reduction, and oxidation pathways of a truncated TriSil and proposes the major degradation products using density functional theory (DFT) calculations. We have identified the polydimethylsiloxane unit of TriSil to play a prominent role in aqueous solution reactivity initiated <em>via</em> hydrolysis and reduction, while oxidation mainly proceeds through H-atom abstraction along the polyethylene glycol unit. The results of this study aid in establishing the use of the alternative fluorine-free surfactant, TriSil, for fire-fighting foams from an environmental perspective.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 1","pages":" 147-158"},"PeriodicalIF":3.5,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/va/d4va00256c?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142976322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lis Bach, Jakob Strand, Hadi Salame, Márta Simon, Janne Fritt-Rasmussen and Pernille Erland Jensen
Plastic litter is ubiquitous in the Arctic marine environment, but knowledge of the importance of specific sources is limited. This project aimed to investigate the input of plastic from untreated sewage discharged to the sea in Greenland. A method was developed to sample and quantify inputs of plastic in different size fractions from wastewater from two towns in Greenland. Plastic findings were visually characterized in terms of abundance, morphology, size, and chemically by characterizing the polymer composition using FTIR spectroscopy. The wastewater was found to be a source of both macro- and micro-sized plastic pollution. Of the total litter load, 70% of the mass was from plastic items larger than 25 mm. Wet wipes were found to be dominating and constituted 59% of the total emitted plastic by mass, but other sanitary items (sanitary pads and condoms) were also detected. A polymeric characterization of the macro-items by ATR-FTIR revealed that the wet wipes were mainly of PET (polyethylene terephthalate, a polyester) but also viscose and cellulose wet wipes were detected. In the microplastic fraction (<300 μm), the main contributor was PP (polypropylene; 65%), but also PE (polyethylene), PES (polyester), PS (polystyrene), cellulose and other polymers were detected. A characterization of the microfibers revealed a large contribution of white/transparent fibers that primarily were composed of cellulose (67%) while a smaller fraction (10%) was polyester (PES), including polyethylene terephthalate (PET). The findings of white/transparent microplastic fibers in the wastewater suggest that a fraction of these fibers is directly related to the presence of the cellulose, viscose and PET wet wipes. Our results suggest that implementing either regulatory or behavioral measures to prevent wet wipes from entering the wastewater or using technical solutions to eliminate the discharge of wet wipes into the marine environment via wastewater, could significantly reduce the emission of plastics of all sizes from wastewater to the marine environment.
{"title":"Wet wipes in untreated wastewater are a source of litter pollution to the arctic marine environment – a case study on the loads of litter and microplastics in wastewater effluents in Greenland†","authors":"Lis Bach, Jakob Strand, Hadi Salame, Márta Simon, Janne Fritt-Rasmussen and Pernille Erland Jensen","doi":"10.1039/D4VA00233D","DOIUrl":"https://doi.org/10.1039/D4VA00233D","url":null,"abstract":"<p >Plastic litter is ubiquitous in the Arctic marine environment, but knowledge of the importance of specific sources is limited. This project aimed to investigate the input of plastic from untreated sewage discharged to the sea in Greenland. A method was developed to sample and quantify inputs of plastic in different size fractions from wastewater from two towns in Greenland. Plastic findings were visually characterized in terms of abundance, morphology, size, and chemically by characterizing the polymer composition using FTIR spectroscopy. The wastewater was found to be a source of both macro- and micro-sized plastic pollution. Of the total litter load, 70% of the mass was from plastic items larger than 25 mm. Wet wipes were found to be dominating and constituted 59% of the total emitted plastic by mass, but other sanitary items (sanitary pads and condoms) were also detected. A polymeric characterization of the macro-items by ATR-FTIR revealed that the wet wipes were mainly of PET (polyethylene terephthalate, a polyester) but also viscose and cellulose wet wipes were detected. In the microplastic fraction (<300 μm), the main contributor was PP (polypropylene; 65%), but also PE (polyethylene), PES (polyester), PS (polystyrene), cellulose and other polymers were detected. A characterization of the microfibers revealed a large contribution of white/transparent fibers that primarily were composed of cellulose (67%) while a smaller fraction (10%) was polyester (PES), including polyethylene terephthalate (PET). The findings of white/transparent microplastic fibers in the wastewater suggest that a fraction of these fibers is directly related to the presence of the cellulose, viscose and PET wet wipes. Our results suggest that implementing either regulatory or behavioral measures to prevent wet wipes from entering the wastewater or using technical solutions to eliminate the discharge of wet wipes into the marine environment <em>via</em> wastewater, could significantly reduce the emission of plastics of all sizes from wastewater to the marine environment.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 2","pages":" 223-234"},"PeriodicalIF":3.5,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/va/d4va00233d?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143107384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Access to electricity is crucial for basic human activities and serves as a direct measure of energy poverty. In recent years, intergovernmental organizations have made significant strides in rural electrification to ensure energy security for all (rural populations, the poor, and the vulnerable). In developing countries, there is a positive correlation between rural infrastructure enhancement and rural livelihoods. Since the early 2000s, in Tanzania, there has been a major government rural electrification initiative to boost rural development. However, the extent to which rural electrification improves rural livelihoods remains unclear. This study was conducted to investigate the impact of rural electrification on household livelihoods in Tanzania, using the Mbulu District as a case study. The study employed a mixed research approach, combining qualitative and quantitative methods. The data were collected from 447 respondents through surveys and interviews with households in electrified and non-electrified areas, where information such as income levels, health, education access, self-employment, and asset ownership was collected. The results indicated a significant 45% increase in household income following electrification compared to non-electrification. About 47% of the respondents earned over 1 000 000 Tsh per month post-electrification, compared to 6% before. Access to modern healthcare improved, with 36% of the respondents being able to afford medication after electrification compared to 13% before electrification. Furthermore, educational opportunities expanded where 31% of the children were enrolled in private schools after electrification compared to 11% before electrification. Asset ownership showed marked improvements, with fewer households living in mud houses (10% post-electrification, down from 22%); all this confirms the significant impact of rural electrification on the improvement of rural development and household livelihood. Our study concludes that rural electrification significantly boosts household income, health service provision, education, and overall welfare which have a significant impact on environmental management. It recommends continued investment and sustained efforts from stakeholders, including the Tanzania Electricity Supply Company (TANESCO) to address challenges hindering electricity service expansion in rural areas. This study provides a foundation for informed policy decisions and actionable strategies to promote sustainable development in rural communities.
{"title":"Household welfare improvement in the Mbulu district of Tanzania: does rural electrification matter?","authors":"Hadija Matimbwa and Marco E. Mng'ong'o","doi":"10.1039/D4VA00259H","DOIUrl":"https://doi.org/10.1039/D4VA00259H","url":null,"abstract":"<p >Access to electricity is crucial for basic human activities and serves as a direct measure of energy poverty. In recent years, intergovernmental organizations have made significant strides in rural electrification to ensure energy security for all (rural populations, the poor, and the vulnerable). In developing countries, there is a positive correlation between rural infrastructure enhancement and rural livelihoods. Since the early 2000s, in Tanzania, there has been a major government rural electrification initiative to boost rural development. However, the extent to which rural electrification improves rural livelihoods remains unclear. This study was conducted to investigate the impact of rural electrification on household livelihoods in Tanzania, using the Mbulu District as a case study. The study employed a mixed research approach, combining qualitative and quantitative methods. The data were collected from 447 respondents through surveys and interviews with households in electrified and non-electrified areas, where information such as income levels, health, education access, self-employment, and asset ownership was collected. The results indicated a significant 45% increase in household income following electrification compared to non-electrification. About 47% of the respondents earned over 1 000 000 Tsh per month post-electrification, compared to 6% before. Access to modern healthcare improved, with 36% of the respondents being able to afford medication after electrification compared to 13% before electrification. Furthermore, educational opportunities expanded where 31% of the children were enrolled in private schools after electrification compared to 11% before electrification. Asset ownership showed marked improvements, with fewer households living in mud houses (10% post-electrification, down from 22%); all this confirms the significant impact of rural electrification on the improvement of rural development and household livelihood. Our study concludes that rural electrification significantly boosts household income, health service provision, education, and overall welfare which have a significant impact on environmental management. It recommends continued investment and sustained efforts from stakeholders, including the Tanzania Electricity Supply Company (TANESCO) to address challenges hindering electricity service expansion in rural areas. This study provides a foundation for informed policy decisions and actionable strategies to promote sustainable development in rural communities.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 11","pages":" 1586-1597"},"PeriodicalIF":3.5,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/va/d4va00259h?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142524273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pooja Thathola, Elda M. Melchor-Martínez, Priyanka Adhikari, Saúl Antonio Hernández Martínez, Anita Pandey and Roberto Parra-Saldívar
The excessive use of emerging contaminants (ECs) in various applications has led to a global health crisis. ECs are found in groundwater, surface water, soils, and wastewater treatment plants at concentrations ranging from ng L−1 to μg L−1. This review explores the sources of ECs and laccase's role in their degradation. ECs encompass diverse categories with potential implications for human health, animals, and the environment, and their adverse effects are examined. Laccase, a key mediator, can oxidize non-phenolic compounds, broadening its substrate range. The review discusses the intricacies of laccase-mediated degradation and highlights its potential to improve global water resource sustainability. Innovative strategies, like laccase immobilization, are explored for EC removal, benefiting environmental preservation. In summary, the review addresses the issue of excessive EC use, their presence in water sources, and their impact on health, wildlife, and the ecosystem. Laccase offers promise for EC degradation, emphasizing its mechanism and potential for sustainable water resource management. Advanced techniques, including laccase immobilization, further demonstrate the commitment to tackling EC-induced environmental challenges.
{"title":"Laccase-mediated degradation of emerging contaminants: unveiling a sustainable solution","authors":"Pooja Thathola, Elda M. Melchor-Martínez, Priyanka Adhikari, Saúl Antonio Hernández Martínez, Anita Pandey and Roberto Parra-Saldívar","doi":"10.1039/D4VA00173G","DOIUrl":"10.1039/D4VA00173G","url":null,"abstract":"<p >The excessive use of emerging contaminants (ECs) in various applications has led to a global health crisis. ECs are found in groundwater, surface water, soils, and wastewater treatment plants at concentrations ranging from ng L<small><sup>−1</sup></small> to μg L<small><sup>−1</sup></small>. This review explores the sources of ECs and laccase's role in their degradation. ECs encompass diverse categories with potential implications for human health, animals, and the environment, and their adverse effects are examined. Laccase, a key mediator, can oxidize non-phenolic compounds, broadening its substrate range. The review discusses the intricacies of laccase-mediated degradation and highlights its potential to improve global water resource sustainability. Innovative strategies, like laccase immobilization, are explored for EC removal, benefiting environmental preservation. In summary, the review addresses the issue of excessive EC use, their presence in water sources, and their impact on health, wildlife, and the ecosystem. Laccase offers promise for EC degradation, emphasizing its mechanism and potential for sustainable water resource management. Advanced techniques, including laccase immobilization, further demonstrate the commitment to tackling EC-induced environmental challenges.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 11","pages":" 1500-1512"},"PeriodicalIF":3.5,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/va/d4va00173g?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Visible light-driven motors (Vis-LDMs) have shown significant potential for water decontamination processes through the synergistic interaction between their active movement and photocatalytic properties, enabling more efficient degradation of organic pollutants. This review highlights recent advances in Vis-LDMs photocatalysts for sustainable environmental pollution mitigation. Innovations include fuel-less Vis-LDMs with hybrid structures and crystalline materials, and biofuel alternatives like water and glucose, though logistical challenges persist. The use of natural materials like lignin and cellulose nanocrystals promotes sustainability but faces energy conversion efficiency challenges. Strategies to enhance efficiency, such as doping and heterojunction formation, are discussed. Advances in stability, reuse, and magnetic recovery capabilities are also reviewed. Collective behavior and environmental adaptability are explored to improve catalytic efficiency. Despite the presented advances, definitive solutions to these limitations have not yet been found. A perspective on the directions for future research is also included in this review, namely the need to resolve issues of scalability, cost-effectiveness, and environmental compatibility. Additionally, investing in Vis-LDMs with programmable routes and precise navigation can enhance versatility and accuracy. Selective behavior to target hazardous contaminants is important; the molecular imprinting technique being a potential solution. Future research should also focus on real-world testing and navigation improvements. Overcoming these challenges is essential to fully harness the potential of Vis-LDMs for environmental remediation and global environmental health.
{"title":"Advancements in visible light-driven micro/nanomotors for photodegradation of environmental pollutants","authors":"Vanessa R. Ferreira and Manuel Azenha","doi":"10.1039/D4VA00230J","DOIUrl":"10.1039/D4VA00230J","url":null,"abstract":"<p >Visible light-driven motors (Vis-LDMs) have shown significant potential for water decontamination processes through the synergistic interaction between their active movement and photocatalytic properties, enabling more efficient degradation of organic pollutants. This review highlights recent advances in Vis-LDMs photocatalysts for sustainable environmental pollution mitigation. Innovations include fuel-less Vis-LDMs with hybrid structures and crystalline materials, and biofuel alternatives like water and glucose, though logistical challenges persist. The use of natural materials like lignin and cellulose nanocrystals promotes sustainability but faces energy conversion efficiency challenges. Strategies to enhance efficiency, such as doping and heterojunction formation, are discussed. Advances in stability, reuse, and magnetic recovery capabilities are also reviewed. Collective behavior and environmental adaptability are explored to improve catalytic efficiency. Despite the presented advances, definitive solutions to these limitations have not yet been found. A perspective on the directions for future research is also included in this review, namely the need to resolve issues of scalability, cost-effectiveness, and environmental compatibility. Additionally, investing in Vis-LDMs with programmable routes and precise navigation can enhance versatility and accuracy. Selective behavior to target hazardous contaminants is important; the molecular imprinting technique being a potential solution. Future research should also focus on real-world testing and navigation improvements. Overcoming these challenges is essential to fully harness the potential of Vis-LDMs for environmental remediation and global environmental health.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 11","pages":" 1474-1499"},"PeriodicalIF":3.5,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/va/d4va00230j?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wei Xu, Chunhong Liu, Kaimin Du, Qiangsheng Gao, Zheming Liu and Weijian Wang
The past several years have witnessed great progress in utilization of industrial waste gypsum. Newly developed carbonation technology toward CaCO3 preparation also reveals a significant utilization way to recover high-value products from waste gypsum, whereas there is a shortage of systematic reviews reporting the most recent progress in carbonation of flue gas desulfurization gypsum (FGDG). This review provides a timely and comprehensive summary of major achievements regarding FGDG carbonation and calcium carbonate production to address future investigation directions. We start with a brief introduction of FGDG production and utilization approaches in practical use with their advantages and disadvantages. Then we systematically summarize two types of carbonation, including a direct way and an indirect way. The direct way typically involves three steps: CO2 capture and CO32− formation; CaSO4·2H2O dissolution; CaCO3 crystallization. High purity CaCO3 is prepared and the polymorph of precipitated CaCO3 is affected by many factors, such as the Ca2+/CO32− ratio, reaction conditions, impurities, and additives. The indirect way involves gypsum thermal reduction, carbonation, and sulfur recovery. Finally, challenges of current work and perspectives are presented to expedite future industrialization progress and provide a promising research direction for FGDG carbonation.
{"title":"A brief review on flue gas desulfurization gypsum recovery toward calcium carbonate preparation","authors":"Wei Xu, Chunhong Liu, Kaimin Du, Qiangsheng Gao, Zheming Liu and Weijian Wang","doi":"10.1039/D4VA00179F","DOIUrl":"10.1039/D4VA00179F","url":null,"abstract":"<p >The past several years have witnessed great progress in utilization of industrial waste gypsum. Newly developed carbonation technology toward CaCO<small><sub>3</sub></small> preparation also reveals a significant utilization way to recover high-value products from waste gypsum, whereas there is a shortage of systematic reviews reporting the most recent progress in carbonation of flue gas desulfurization gypsum (FGDG). This review provides a timely and comprehensive summary of major achievements regarding FGDG carbonation and calcium carbonate production to address future investigation directions. We start with a brief introduction of FGDG production and utilization approaches in practical use with their advantages and disadvantages. Then we systematically summarize two types of carbonation, including a direct way and an indirect way. The direct way typically involves three steps: CO<small><sub>2</sub></small> capture and CO<small><sub>3</sub></small><small><sup>2−</sup></small> formation; CaSO<small><sub>4</sub></small>·2H<small><sub>2</sub></small>O dissolution; CaCO<small><sub>3</sub></small> crystallization. High purity CaCO<small><sub>3</sub></small> is prepared and the polymorph of precipitated CaCO<small><sub>3</sub></small> is affected by many factors, such as the Ca<small><sup>2+</sup></small>/CO<small><sub>3</sub></small><small><sup>2−</sup></small> ratio, reaction conditions, impurities, and additives. The indirect way involves gypsum thermal reduction, carbonation, and sulfur recovery. Finally, challenges of current work and perspectives are presented to expedite future industrialization progress and provide a promising research direction for FGDG carbonation.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 10","pages":" 1351-1363"},"PeriodicalIF":3.5,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/va/d4va00179f?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208622","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mineral carbonation is a promising strategy for mitigating carbon emissions and combating climate change. This study investigates the efficacy and sustainability of MgO-based stabilization techniques for soft marine soils, incorporating supplementary cementitious materials (SCMs) such as biochar and slag. A combination of laboratory experiments and rigorous analyses was utilized to elucidate the complex interplay between the additives and their impacts on soil hydraulic characteristics, carbon sequestration potential, embodied energy, and economic viability. Mercury intrusion porosimetry (MIP) was employed to characterize pore structure changes induced by carbonation, while X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to correlate mineral formations. The results indicate that MgO–biochar-treated soils exhibit enhanced soil air content, pore connectivity, and carbon sequestration efficiency compared to MgO–slag-treated soils, exhibiting reduced pore volumes and limited CO2 diffusion. Integrating biochar with MgO enhanced brucite and nesquehonite precipitation due to biochar's porous structure and functionalized surface area, facilitating gas diffusion and nucleation for mineral formation. Sustainability assessments highlight the environmental and economic trade-offs, positioning MgO–biochar and MgO–slag combinations as cost-effective and environmentally friendly alternatives. This research provides theoretical guidance for sustainable soil stabilization and efficient CO2 mineralization, offering valuable insights for researchers, practitioners, and policymakers addressing climate change challenges.
矿物碳化是减少碳排放和应对气候变化的一项有前途的战略。本研究调查了以氧化镁为基础的软质海洋土壤稳定技术的有效性和可持续性,并结合了生物炭和矿渣等补充胶凝材料(SCMs)。研究结合实验室实验和严格的分析,阐明了添加剂之间复杂的相互作用及其对土壤水力特性、固碳潜力、体现能源和经济可行性的影响。采用汞渗入孔隙测定法(MIP)来描述碳化引起的孔隙结构变化,同时采用 X 射线衍射(XRD)和扫描电子显微镜(SEM)来关联矿物形态。结果表明,与氧化镁-矿渣处理过的土壤相比,氧化镁-生物炭处理过的土壤空气含量、孔隙连通性和固碳效率都有所提高,但孔隙体积减少,二氧化碳扩散受限。由于生物炭的多孔结构和功能化表面积,将生物炭与氧化镁结合可提高青金石和内沸石的沉淀,促进气体扩散和矿物形成的成核。可持续性评估强调了环境和经济的权衡,将氧化镁-生物炭和氧化镁-矿渣组合定位为具有成本效益和环境友好的替代品。这项研究为可持续的土壤稳定化和高效的二氧化碳矿化提供了理论指导,为应对气候变化挑战的研究人员、从业人员和决策者提供了宝贵的见解。
{"title":"Impacts of biochar and slag on carbon sequestration potential and sustainability assessment of MgO-stabilized marine soils: insights from MIP analysis†","authors":"Chikezie Chimere Onyekwena, Qi Li, Yong Wang, Ishrat Hameed Alvi, Yunlu Hou, Chima Finnian Ukaomah and Theogene Hakuzweyezu","doi":"10.1039/D4VA00095A","DOIUrl":"10.1039/D4VA00095A","url":null,"abstract":"<p >Mineral carbonation is a promising strategy for mitigating carbon emissions and combating climate change. This study investigates the efficacy and sustainability of MgO-based stabilization techniques for soft marine soils, incorporating supplementary cementitious materials (SCMs) such as biochar and slag. A combination of laboratory experiments and rigorous analyses was utilized to elucidate the complex interplay between the additives and their impacts on soil hydraulic characteristics, carbon sequestration potential, embodied energy, and economic viability. Mercury intrusion porosimetry (MIP) was employed to characterize pore structure changes induced by carbonation, while X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to correlate mineral formations. The results indicate that MgO–biochar-treated soils exhibit enhanced soil air content, pore connectivity, and carbon sequestration efficiency compared to MgO–slag-treated soils, exhibiting reduced pore volumes and limited CO<small><sub>2</sub></small> diffusion. Integrating biochar with MgO enhanced brucite and nesquehonite precipitation due to biochar's porous structure and functionalized surface area, facilitating gas diffusion and nucleation for mineral formation. Sustainability assessments highlight the environmental and economic trade-offs, positioning MgO–biochar and MgO–slag combinations as cost-effective and environmentally friendly alternatives. This research provides theoretical guidance for sustainable soil stabilization and efficient CO<small><sub>2</sub></small> mineralization, offering valuable insights for researchers, practitioners, and policymakers addressing climate change challenges.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 11","pages":" 1564-1577"},"PeriodicalIF":3.5,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/va/d4va00095a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Diptiman De, Priyotosh Ghosh, Sriman De and Prithidipa Sahoo
Considering the significant toxicity of arsenite (AsO2−), arsenate (AsO43−), and hydrogen sulphide (H2S), the early detection of these ions and gas using simple methods like naked-eye chemosensing could have substantial implications for environmental and industrial applications. With these factors in mind, we have developed a novel and straightforward colorimetric chemosensor called NADNP (2-hydroxy naphthaldehyde conjugated 2,4-dinitrophenyl hydrazine) for swift paper-based colorimetric detection of arsenite, arsenate, and H2S, based on a deprotonation mechanism. NADNP exhibits strong binding affinity towards sulfide, arsenite, and arsenate, with very lower detection limits (LOD) of 0.17 μM, 0.15 μM and 0.15 μM respectively, and the binding stoichiometry between these detected ions and NADNP is determined to be 1 : 1 through Job's plot analysis. Structural elucidation and electronic properties calculation have been conducted via DFT (Density Functional Theory) studies for correlation with the spectroscopic analyses. The ‘three-in-one’ paper strip-based chemosensor could be considered a promising colorimetric tool for rapid, cost-effective, selective, and sensitive “on-spot” sensing and monitoring of arsenite, arsenate, and sulfide in environmental samples.
{"title":"Naked eye detection of arsenite, arsenate, and H2S by a Schiff base naphthaldehyde conjugate using a single paper strip, based on a deprotonation mechanism†","authors":"Diptiman De, Priyotosh Ghosh, Sriman De and Prithidipa Sahoo","doi":"10.1039/D4VA00213J","DOIUrl":"10.1039/D4VA00213J","url":null,"abstract":"<p >Considering the significant toxicity of arsenite (AsO<small><sub>2</sub></small><small><sup>−</sup></small>), arsenate (AsO<small><sub>4</sub></small><small><sup>3−</sup></small>), and hydrogen sulphide (H<small><sub>2</sub></small>S), the early detection of these ions and gas using simple methods like naked-eye chemosensing could have substantial implications for environmental and industrial applications. With these factors in mind, we have developed a novel and straightforward colorimetric chemosensor called NADNP (2-hydroxy naphthaldehyde conjugated 2,4-dinitrophenyl hydrazine) for swift paper-based colorimetric detection of arsenite, arsenate, and H<small><sub>2</sub></small>S, based on a deprotonation mechanism. NADNP exhibits strong binding affinity towards sulfide, arsenite, and arsenate, with very lower detection limits (LOD) of 0.17 μM, 0.15 μM and 0.15 μM respectively, and the binding stoichiometry between these detected ions and NADNP is determined to be 1 : 1 through Job's plot analysis. Structural elucidation and electronic properties calculation have been conducted <em>via</em> DFT (Density Functional Theory) studies for correlation with the spectroscopic analyses. The ‘three-in-one’ paper strip-based chemosensor could be considered a promising colorimetric tool for rapid, cost-effective, selective, and sensitive “on-spot” sensing and monitoring of arsenite, arsenate, and sulfide in environmental samples.</p>","PeriodicalId":72941,"journal":{"name":"Environmental science. Advances","volume":" 11","pages":" 1578-1585"},"PeriodicalIF":3.5,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/va/d4va00213j?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142208624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}