Pub Date : 2021-01-01DOI: 10.4236/ACES.2021.112012
Praneeth Nimmatoori, Ashok Kumar
This paper proposes a methodology using computational fluid dynamics (CFD)-FLUENT to simulate the dispersion of particulate matter releasing from a biosolid applied agricultural field and predict the particulate concentrations for different ranges of particle sizes. The discrete phase model (Lagrangian-Eulerian approach) was used in combination with each of the four turbulence models: Standard kε (kε), Realizable kε (Rkε), Standard kω (kω), and Shear-stress transport k-ω (SST) to predict particulate matter size concentrations for distances downwind of the agricultural field. In this modeling approach, particulates were simulated as discrete phase and air as continuous phase. The predicted particulate matter concentrations were compared statistically with their corresponding field study observations to evaluate the performance of turbulence models. The statistical analysis concluded that among four turbulence models, the discrete phase model when used with Rkε performed the best in predicting particulate matter concentrations for low (u < 2 m/s) and medium (2 < u < 5 m/s) wind speeds. For high (u > 5 m/s) wind speeds, Rkε, kω, and SST showed similar performances. The discrete phase model using Rkε performed very well and modeled the best concentrations for the particle sizes (μm): 0.23, 0.3, 0.4, 0.5, 0.65, 0.8, 1, 1.6, 2, 3, 4, and 5. For particle sizes: 7.5 and 10, the performances of Rkε, kε, kω, and SST were similar.
{"title":"Dispersion Modeling of Particulate Matter in Different Size Ranges Releasing from a Biosolids Applied Agricultural Field Using Computational Fluid Dynamics","authors":"Praneeth Nimmatoori, Ashok Kumar","doi":"10.4236/ACES.2021.112012","DOIUrl":"https://doi.org/10.4236/ACES.2021.112012","url":null,"abstract":"This paper proposes a methodology using computational fluid dynamics (CFD)-FLUENT to simulate the dispersion of particulate matter releasing from a biosolid applied agricultural field and predict the particulate concentrations for different ranges of particle sizes. The discrete phase model (Lagrangian-Eulerian approach) was used in combination with each of the four turbulence models: Standard kε (kε), Realizable kε (Rkε), Standard kω (kω), and Shear-stress transport k-ω (SST) to predict particulate matter size concentrations for distances downwind of the agricultural field. In this modeling approach, particulates were simulated as discrete phase and air as continuous phase. The predicted particulate matter concentrations were compared statistically with their corresponding field study observations to evaluate the performance of turbulence models. The statistical analysis concluded that among four turbulence models, the discrete phase model when used with Rkε performed the best in predicting particulate matter concentrations for low (u < 2 m/s) and medium (2 < u < 5 m/s) wind speeds. For high (u > 5 m/s) wind speeds, Rkε, kω, and SST showed similar performances. The discrete phase model using Rkε performed very well and modeled the best concentrations for the particle sizes (μm): 0.23, 0.3, 0.4, 0.5, 0.65, 0.8, 1, 1.6, 2, 3, 4, and 5. For particle sizes: 7.5 and 10, the performances of Rkε, kε, kω, and SST were similar.","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81537877","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.4236/ACES.2021.111005
Masaya Hayashi, Keisuke Kurashima, Hitoshi Habuka, A. Ishiguro, S. Ishii, Y. Daigo, Hideki Ito, I. Mizushima, Yoshinao Takahashi
An annealing process was developed for the practical recover of a purified py-rolytic carbon (PPyC) surface from damage, such as color change and peeling, due to fluorination during exposure to chlorine trifluoride gas at high tempera-tures for the cleaning of a silicon carbide chemical vapor deposition reactor. The PPyC surface was annealed at 900°C for 10 min in ambient nitrogen con-taining oxygen at the concentrations of 0.01% - 20%. The rainbow-like colored surface returned to the dark gray color of the original PPyC. Simultaneously, the thin peeled films disappeared. The Raman spectra showed that the PPyC surface chemical bonding returned to that of the original one. The oxygen concentration as low as 0.01% could recover the PPyC surface along with re-ducing the surface pit formation, when the combination of the exposure to chlorine trifluoride gas and the recovery was repeated.
{"title":"Recovery Method of Pyrolytic Carbon Surface after Exposure to Chlorine Trifluoride Gas","authors":"Masaya Hayashi, Keisuke Kurashima, Hitoshi Habuka, A. Ishiguro, S. Ishii, Y. Daigo, Hideki Ito, I. Mizushima, Yoshinao Takahashi","doi":"10.4236/ACES.2021.111005","DOIUrl":"https://doi.org/10.4236/ACES.2021.111005","url":null,"abstract":"An annealing process was developed for the practical recover of a purified py-rolytic carbon (PPyC) surface from damage, such as color change and peeling, due to fluorination during exposure to chlorine trifluoride gas at high tempera-tures for the cleaning of a silicon carbide chemical vapor deposition reactor. The PPyC surface was annealed at 900°C for 10 min in ambient nitrogen con-taining oxygen at the concentrations of 0.01% - 20%. The rainbow-like colored surface returned to the dark gray color of the original PPyC. Simultaneously, the thin peeled films disappeared. The Raman spectra showed that the PPyC surface chemical bonding returned to that of the original one. The oxygen concentration as low as 0.01% could recover the PPyC surface along with re-ducing the surface pit formation, when the combination of the exposure to chlorine trifluoride gas and the recovery was repeated.","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84201495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.4236/aces.2021.111002
V. Dutka, Yaroslav Kovalskyi, O. Aksimentyeva, N. Oshchapovska
The polymer-mineral composites were synthesized using vinyl monomers styrene, methyl acrylate, and butyl acrylate with nano dispersed oxides Fe2O3, Cr2O3, V2O5 and SiO2 in the presence of benzoyl peroxide and other peroxide initiators. Benzoyl peroxide adsorption on Fe2O3, Cr2O3, and V2O5 surfaces was studied. The adsorption parameters were found: adsorption-desorption equilibrium constants, maximum adsorption, and the area occupied by the molecule benzoyl peroxide on the surface of the adsorbent. The molecular weights of the polymers in the composites and the degree of grafting of the macromolecules of the polymer to the surface of oxides were studied. It has been found that the surface of the dispersed oxides influences the rate of thermal decomposition of the peroxide initiators and the polymerization parameters of the vinyl monomers.
{"title":"Preparation of Polymer-Mineral Nanocomposites Based on Vinyl Monomers and Dispersed Inorganic Oxides","authors":"V. Dutka, Yaroslav Kovalskyi, O. Aksimentyeva, N. Oshchapovska","doi":"10.4236/aces.2021.111002","DOIUrl":"https://doi.org/10.4236/aces.2021.111002","url":null,"abstract":"The polymer-mineral composites were synthesized using vinyl monomers styrene, methyl acrylate, and butyl acrylate with nano dispersed oxides Fe2O3, Cr2O3, V2O5 and SiO2 in the presence of benzoyl peroxide and other peroxide initiators. Benzoyl peroxide adsorption on Fe2O3, Cr2O3, and V2O5 surfaces was studied. The adsorption parameters were found: adsorption-desorption equilibrium constants, maximum adsorption, and the area occupied by the molecule benzoyl peroxide on the surface of the adsorbent. The molecular weights of the polymers in the composites and the degree of grafting of the macromolecules of the polymer to the surface of oxides were studied. It has been found that the surface of the dispersed oxides influences the rate of thermal decomposition of the peroxide initiators and the polymerization parameters of the vinyl monomers.","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"6 1","pages":"18-28"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86937245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.1016/s0065-2377(21)00030-2
{"title":"Series Page","authors":"","doi":"10.1016/s0065-2377(21)00030-2","DOIUrl":"https://doi.org/10.1016/s0065-2377(21)00030-2","url":null,"abstract":"","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"57 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85804681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.1016/bs.ache.2021.10.007
S. Purohit, G. Brooks
{"title":"Application of solar thermal energy to metallurgical processes","authors":"S. Purohit, G. Brooks","doi":"10.1016/bs.ache.2021.10.007","DOIUrl":"https://doi.org/10.1016/bs.ache.2021.10.007","url":null,"abstract":"","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"15 1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80079003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.4236/ACES.2021.111004
O. D. Alabi-Babalola, E. Aransiola, T. Shittu
Post-consumer polymeric wastes in form of low-density polyethylene (LDPE) can now be considered suitable as a precursor for the synthesis of low-cost activated carbon (AC). This study produced AC from LDPE using sulphuric acid (H2SO4) and potassium hydroxide (KOH) as the activating agent. The reaction conditions for pyrolysis were varied in the range of 0.50 - 2.00 M, 400°C - 500°C, and 45 - 60 minutes. Physico-chemical investigations reveal that AC yield is significantly dependent on both carbonization temperatures and time. The obtained optimum values of 446.50°C and 51.09 mins gave a yield of 24% for the base-activated carbon. The high iodine numbers obtained strongly indicate the presence of large surface area and pore volumes is further confirmed using the Scanning Electron Microscopy (SEM) analysis which reveals the presence of pores on the external surface of the carbons. Fourier Transform Infrared Technique (FTIR) analysis further shows that the synthesized compounds are purely carbon with rich oxy-gen-surface complexes on the surface which is as a result of the introduction of the chemical oxidizing agents. The produced carbons were found to have high adsorption affinity for selected inorganic ions which are: Mn7+, Co2+, and Cr6+. Adsorption isotherm results show the adsorption process to be favourable with the Langmuir isotherm parameter RL having values of <1, while the Freudlich adsorption model was found to perfectly fit the data at selected adsorbent dosages and adsorbate concentrations. The pseu-do-second-order model provides the best correlation for the kinetic analysis. The acid-activated carbon was found to have better adsorption capacities than the base-activated carbon.
{"title":"Adsorption and Kinetic Study of Activated Carbon Produced from Post-Consumer Low-Density Polyethylene (LDPE) Wastes","authors":"O. D. Alabi-Babalola, E. Aransiola, T. Shittu","doi":"10.4236/ACES.2021.111004","DOIUrl":"https://doi.org/10.4236/ACES.2021.111004","url":null,"abstract":"Post-consumer polymeric wastes in form of low-density polyethylene (LDPE) can now be considered suitable as a precursor for the synthesis of low-cost activated carbon (AC). This study produced AC from LDPE using sulphuric acid (H2SO4) and potassium hydroxide (KOH) as the activating agent. The reaction conditions for pyrolysis were varied in the range of 0.50 - 2.00 M, 400°C - 500°C, and 45 - 60 minutes. Physico-chemical investigations reveal that AC yield is significantly dependent on both carbonization temperatures and time. The obtained optimum values of 446.50°C and 51.09 mins gave a yield of 24% for the base-activated carbon. The high iodine numbers obtained strongly indicate the presence of large surface area and pore volumes is further confirmed using the Scanning Electron Microscopy (SEM) analysis which reveals the presence of pores on the external surface of the carbons. Fourier Transform Infrared Technique (FTIR) analysis further shows that the synthesized compounds are purely carbon with rich oxy-gen-surface complexes on the surface which is as a result of the introduction of the chemical oxidizing agents. The produced carbons were found to have high adsorption affinity for selected inorganic ions which are: Mn7+, Co2+, and Cr6+. Adsorption isotherm results show the adsorption process to be favourable with the Langmuir isotherm parameter RL having values of <1, while the Freudlich adsorption model was found to perfectly fit the data at selected adsorbent dosages and adsorbate concentrations. The pseu-do-second-order model provides the best correlation for the kinetic analysis. The acid-activated carbon was found to have better adsorption capacities than the base-activated carbon.","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"62 1","pages":"38-64"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82750675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.1016/bs.ache.2021.10.003
K. Zeng, Dian Zhong, Jun Li, G. Flamant
{"title":"Pyrolysis of carbonaceous feedstock driven by concentrated solar energy","authors":"K. Zeng, Dian Zhong, Jun Li, G. Flamant","doi":"10.1016/bs.ache.2021.10.003","DOIUrl":"https://doi.org/10.1016/bs.ache.2021.10.003","url":null,"abstract":"","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"41 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87781862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.4236/ACES.2021.111003
Mingxi Chen
Due to large volume and high hardness of thermal insulation materials mostly used in high temperature fields, a composite cooling powder and its thixotropic hydrogel for thermal protection are presented. The core of composite cooling material powder is super absorbent polymer, composing with metal salt, polysaccharide hydrosol and inorganic particles and other modifiers through a series of composite process, which can be easily stored for a long time. When needed, the powder can be mixed with water to obtain a kind of thixotropic hydrogel in a very short time. Experimental results show this thermal protection technology with thixotropic ability has excellent thermal protection performance, meanwhile flexible, adhesive and low cost, which exerts instantaneous cooling, efficient thermal protection and long-lasting flame-retardant protection.
{"title":"A Composite Cooling Powder and Its Thixotropic Hydrogel","authors":"Mingxi Chen","doi":"10.4236/ACES.2021.111003","DOIUrl":"https://doi.org/10.4236/ACES.2021.111003","url":null,"abstract":"Due to large volume and high hardness of thermal insulation materials mostly used in high temperature fields, a composite cooling powder and its thixotropic hydrogel for thermal protection are presented. The core of composite cooling material powder is super absorbent polymer, composing with metal salt, polysaccharide hydrosol and inorganic particles and other modifiers through a series of composite process, which can be easily stored for a long time. When needed, the powder can be mixed with water to obtain a kind of thixotropic hydrogel in a very short time. Experimental results show this thermal protection technology with thixotropic ability has excellent thermal protection performance, meanwhile flexible, adhesive and low cost, which exerts instantaneous cooling, efficient thermal protection and long-lasting flame-retardant protection.","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"40 1","pages":"29-37"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87796705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.4236/aces.2021.114016
T. Ramishvili, V. Tsitsishvili, T. Bukia
{"title":"Preparation of Ethyl 4-Nitrobenzoate Using Ultradispersed Natural Zeolite Catalysts, Ultrasound and Microwave Irradiation","authors":"T. Ramishvili, V. Tsitsishvili, T. Bukia","doi":"10.4236/aces.2021.114016","DOIUrl":"https://doi.org/10.4236/aces.2021.114016","url":null,"abstract":"","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"18 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87328691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-01-01DOI: 10.1016/bs.ache.2021.10.004
A. Bayon, A. J. Carrillo, E. Mastronardo, J. M. Coronado
{"title":"Thermochemical heat storage at high temperature","authors":"A. Bayon, A. J. Carrillo, E. Mastronardo, J. M. Coronado","doi":"10.1016/bs.ache.2021.10.004","DOIUrl":"https://doi.org/10.1016/bs.ache.2021.10.004","url":null,"abstract":"","PeriodicalId":7332,"journal":{"name":"Advances in Chemical Engineering and Science","volume":"42 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84299982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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