Pub Date : 2023-12-21DOI: 10.1134/s1811238223700443
Hanqi Qian, Bo Jiang
{"title":"Silicone Resin Applications for Heat-Resistant Coatings: A Review","authors":"Hanqi Qian, Bo Jiang","doi":"10.1134/s1811238223700443","DOIUrl":"https://doi.org/10.1134/s1811238223700443","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138953399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-15DOI: 10.1134/s181123822370042x
A. A. Anisimov, E. O. Minyaylo, A. R. Shakirova, O. I. Shchegolikhina
Abstract
The development of organometallasiloxane chemistry from first polymeric systems to individual organometallasiloxanes and functional oligomeric compounds is considered. The structural diversity of organosilicon precursors and the variability of metal-containing components are presented. Synthetic approaches are considered in detail, including those that allow targeted production of organometallasiloxanes of a certain structure. Using the example of organometallasiloxanes synthesized from trifunctional organoalkoxysilanes, methods for the synthesis of unique stereoregular functional cyclosiloxanes and their derivatives are highlighted. Considerable attention is given to the applied aspects of various structure organometallasiloxanes and their derivatives. The state of the art of the chemistry of organometallasiloxanes and their further evolution are evaluated critically.
{"title":"Evolution of Organometallasiloxanes","authors":"A. A. Anisimov, E. O. Minyaylo, A. R. Shakirova, O. I. Shchegolikhina","doi":"10.1134/s181123822370042x","DOIUrl":"https://doi.org/10.1134/s181123822370042x","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The development of organometallasiloxane chemistry from first polymeric systems to individual organometallasiloxanes and functional oligomeric compounds is considered. The structural diversity of organosilicon precursors and the variability of metal-containing components are presented. Synthetic approaches are considered in detail, including those that allow targeted production of organometallasiloxanes of a certain structure. Using the example of organometallasiloxanes synthesized from trifunctional organoalkoxysilanes, methods for the synthesis of unique stereoregular functional cyclosiloxanes and their derivatives are highlighted. Considerable attention is given to the applied aspects of various structure organometallasiloxanes and their derivatives. The state of the art of the chemistry of organometallasiloxanes and their further evolution are evaluated critically.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138496789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-10DOI: 10.1134/s181123822370039x
N. S. Bredov, V. V. Kireev, V. A. Polyakov, I. B. Sokol’skaya, A. S. Esin
{"title":"Modern Approaches to Obtaining Organofunctional Silsesquioxanes","authors":"N. S. Bredov, V. V. Kireev, V. A. Polyakov, I. B. Sokol’skaya, A. S. Esin","doi":"10.1134/s181123822370039x","DOIUrl":"https://doi.org/10.1134/s181123822370039x","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136352929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-10DOI: 10.1134/s1811238223700418
V. I. Nedel’kin, A. V. Nedel’kin, B. A. Izmailov, A. B. Zachernyuk, E. N. Solov’eva, B. A. Zachernyuk
{"title":"Practical Application of Selected Functional Organosilicone Polymers","authors":"V. I. Nedel’kin, A. V. Nedel’kin, B. A. Izmailov, A. B. Zachernyuk, E. N. Solov’eva, B. A. Zachernyuk","doi":"10.1134/s1811238223700418","DOIUrl":"https://doi.org/10.1134/s1811238223700418","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136294954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-10DOI: 10.1134/s1811238223700406
E. S. Trankina, A. Yu. Kazantseva, D. A. Khanin, S. E. Lyubimov, E. G. Kononova, U. S. Andropova, A. M. Muzafarov
{"title":"Non-Isocyanate Poly(Siloxane-Urethanes) Based on Oligodimethylsiloxanes Containing Aminopropyl and Ethoxy Substituents","authors":"E. S. Trankina, A. Yu. Kazantseva, D. A. Khanin, S. E. Lyubimov, E. G. Kononova, U. S. Andropova, A. M. Muzafarov","doi":"10.1134/s1811238223700406","DOIUrl":"https://doi.org/10.1134/s1811238223700406","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136295696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-30DOI: 10.1134/s1811238223700388
V. V. Libanov, A. A. Kapustina, N. P. Shapkin
{"title":"Mechanochemical Interaction of Phenylboronic Acid with Polyphenylsilsesquioxane and a Hydroxy(phenyl)siloxane Oligomer","authors":"V. V. Libanov, A. A. Kapustina, N. P. Shapkin","doi":"10.1134/s1811238223700388","DOIUrl":"https://doi.org/10.1134/s1811238223700388","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136336466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-30DOI: 10.1134/s1811238223700376
E. E. Kim, T. M. Il’ina, Yu. N. Kononevich, D. S. Ionov, D. A. Khanin, G. G. Nikiforova, A. M. Muzafarov
{"title":"New Fluorescent Materials Based on Polysiloxanes and Boron Bis(β-diketonates)","authors":"E. E. Kim, T. M. Il’ina, Yu. N. Kononevich, D. S. Ionov, D. A. Khanin, G. G. Nikiforova, A. M. Muzafarov","doi":"10.1134/s1811238223700376","DOIUrl":"https://doi.org/10.1134/s1811238223700376","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136342596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-30DOI: 10.1134/s1811238223700364
Yu. V. Bilichenko, Pham Van Thuan, R. S. Borisov, A. A. Kolenchenko, V. V. Kireev
{"title":"Functionalized Oligoaryloxycyclotriphosphazenes and Noncombustible Binders Based on Them","authors":"Yu. V. Bilichenko, Pham Van Thuan, R. S. Borisov, A. A. Kolenchenko, V. V. Kireev","doi":"10.1134/s1811238223700364","DOIUrl":"https://doi.org/10.1134/s1811238223700364","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136342602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-26DOI: 10.1134/S1811238223700352
E. V. Kuznetsova, E. M. Shirokova, Yu. A. Puchkova, E. V. Yastremsky, S. N. Chvalun
The self-organization of biocompatible amphiphilic block copolymers of D,L-lactide and ethylene oxide with various hydrophobic poly(D,L-lactide) block length in aqueous media has been investigated. It has been shown that the nature of nonselective organic solvent has a considerable effect on the size, size polydispersity, and morphology of micelles of a block copolymer with a long poly(D,L-lactide) block. To elucidate the dependence of properties of block copolymer micelles on the common organic solvent type (acetone, tetrahydrofuran, N,N-dimethylformamide, and acetonitrile) various parameters of the used solvents have been estimated, and correlation between the Flory–Huggins coefficient and the surface tension between the hydrophobic block and the nonselective organic solvent and the parameters of micellar structures has been found.
研究了具有不同疏水聚(D, l -丙交酯)嵌段长度的生物相容性D, l -丙交酯和环氧乙烷两亲共聚物在水介质中的自组织。研究表明，非选择性有机溶剂的性质对长聚(D, l -丙交酯)嵌段共聚物的尺寸、尺寸多分散性和胶束形态有相当大的影响。为了阐明嵌段共聚物胶束性质与常用有机溶剂类型(丙酮、四氢呋喃、N、N-二甲基甲酰胺和乙腈)的关系，我们估计了所用溶剂的各种参数，并发现了疏水嵌段与非选择性有机溶剂之间的弗洛里-哈金斯系数和表面张力与胶束结构参数之间的相关性。
{"title":"Study of the Effect of Nonselective Organic Solvent Nature on the Self-Organization of Amphiphilic Block Copolymers of D,L-Lactide and Ethylene Oxide in Aqueous Solution","authors":"E. V. Kuznetsova, E. M. Shirokova, Yu. A. Puchkova, E. V. Yastremsky, S. N. Chvalun","doi":"10.1134/S1811238223700352","DOIUrl":"10.1134/S1811238223700352","url":null,"abstract":"<p>The self-organization of biocompatible amphiphilic block copolymers of D,L-lactide and ethylene oxide with various hydrophobic poly(D,L-lactide) block length in aqueous media has been investigated. It has been shown that the nature of nonselective organic solvent has a considerable effect on the size, size polydispersity, and morphology of micelles of a block copolymer with a long poly(D,L-lactide) block. To elucidate the dependence of properties of block copolymer micelles on the common organic solvent type (acetone, tetrahydrofuran, <i>N</i>,<i>N</i>-dimethylformamide, and acetonitrile) various parameters of the used solvents have been estimated, and correlation between the Flory–Huggins coefficient and the surface tension between the hydrophobic block and the nonselective organic solvent and the parameters of micellar structures has been found.</p>","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134797542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-26DOI: 10.1134/S1811238223700339
Leninsky Prospekt, 29, Moscow, 119991
{"title":"In Memoriam of I. Ya. Erukhimovich","authors":"Leninsky Prospekt, 29, Moscow, 119991","doi":"10.1134/S1811238223700339","DOIUrl":"10.1134/S1811238223700339","url":null,"abstract":"","PeriodicalId":740,"journal":{"name":"Polymer Science, Series C","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134797540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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