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Efficient photocatalytic degradation of methyl orange using cost-effective CQDs(/)CeO2 nanocomposites synthesised via sol–gel and hydrothermal methods 溶胶-凝胶法和水热法合成CeO2纳米复合材料,高效光催化降解甲基橙(/)
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-10-14 DOI: 10.1007/s12043-025-02997-2
M D Alshahrani

Nanotechnology offers innovative and sustainable solutions for environmental remediation. However, enhancing photocatalytic efficiency remains a significant challenge. In this study, we developed a cost-effective method for synthesising carbon quantum dot (CQD)-incorporated cerium oxide (CeO2) nanocomposites for efficient methyl orange (MO) degradation under direct sunlight. CeO2 nanosols and CQDs were synthesised via sol–gel and hydrothermal processes, respectively, and combined using a hydrothermal route with sonication-assisted mixing. The nanocomposites were calcinated at 600 °C and characterised using XRD, FTIR, Raman, PL spectroscopy, SEM and EDX to analyse their structural, morphological and surface properties. The specific surface area of the CQDs(/)CeO2 composites was determined to be 72.3 m2(/)g from the sol–gel method and 96.7 m2(/)g from the hydrothermal method, as measured by Brunauer–Emmett–Teller (BET) analysis. The optimised CQDs(/)CeO2 (1:100 ratio) exhibited enhanced MO degradation, with the MO degradation rate constant for the hydrothermal composite. The energy band gap of the sol–gel composite was found to be 2.78 eV, while the hydrothermal composite showed a band gap of 2.73 eV, facilitating improved light absorption. The degradation efficiency was further influenced by MO concentration, pH and catalyst loading. Additionally, CQDs(/)CeO2 demonstrated excellent catalytic stability over multiple cycles. These findings highlight the potential of CQDs(/)CeO2 nanocomposites for cost-effective water purification and disinfection applications.

Graphical abstract

纳米技术为环境修复提供了创新和可持续的解决方案。然而,提高光催化效率仍然是一个重大挑战。在这项研究中,我们开发了一种具有成本效益的方法来合成碳量子点(CQD)-氧化铈(CeO2)纳米复合材料,用于在直射阳光下高效降解甲基橙(MO)。分别通过溶胶-凝胶法和水热法合成了CeO2纳米溶胶和CQDs,并利用水热法在超声辅助混合下进行了合成。采用XRD、FTIR、拉曼光谱、PL光谱、SEM和EDX对纳米复合材料进行表征,分析其结构、形貌和表面性能。采用溶胶-凝胶法和水热法测定CQDs (/) CeO2复合材料的比表面积分别为72.3 m2 (/) g和96.7 m2 (/) g。优化后的CQDs (/) CeO2(1:100)在水热复合材料的MO降解速率不变的情况下,对MO的降解效果增强。溶胶-凝胶复合材料的能带隙为2.78 eV,而水热复合材料的能带隙为2.73 eV,有利于提高光吸收。MO浓度、pH和催化剂负载对降解效率有进一步的影响。此外,CQDs (/) CeO2在多个循环中表现出优异的催化稳定性。这些发现突出了CQDs (/) CeO2纳米复合材料在具有成本效益的水净化和消毒应用中的潜力。图形摘要
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引用次数: 0
Trajectory and null controllability of a control system governed by fractional-order composite relaxation differential equations 分数阶复合松弛微分方程控制系统的轨迹和零可控性
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-10-14 DOI: 10.1007/s12043-025-02983-8
Namrata Arya, Ganga Ram Gautam

The purpose of this paper is to study the trajectory controllability (which is said to be the strongest notion rather than other controllabilities) and null controllability of a control system commanded by fractional-order composite relaxation semi-linear differential equation. The linear control system under consideration addresses a classical problem in fluid dynamics, specifically focussing on the dynamics of a particle experiencing unsteady movement within a viscous fluid while subjected to gravitational forces. Initially, we derive the mild solution of the considered control system employing the results on (ak)-regularised families of bounded linear operator (matrices). Under some appropriate assumptions regarding non-linear terms and by utilising the Gronwall’s inequality, we establish the trajectory controllability and null controllability with constrained controls via fixed point technique. Finally, a few examples are shown to illustrate and explore the applications of the obtained findings.

本文的目的是研究分数阶复合松弛半线性微分方程控制系统的轨迹可控性(据说是最强的可控性,而不是其他可控性)和零可控性。所考虑的线性控制系统解决了流体动力学中的一个经典问题,特别关注在受到重力作用时粘性流体中经历非定常运动的粒子的动力学。首先,我们利用有界线性算子(矩阵)的(a, k)-正则族上的结果,导出了所考虑的控制系统的温和解。在适当的非线性条件下,利用Gronwall不等式,利用不动点技术建立了约束控制下的轨迹可控性和零可控性。最后,给出了几个例子来说明和探讨所得结果的应用。
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引用次数: 0
Constraining SMEFT BSM scenarios with EWPO and (Delta _{textrm{CKM}}) 使用EWPO和约束SMEFT BSM场景 (Delta _{textrm{CKM}})
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-10-11 DOI: 10.1007/s12043-025-02990-9
Mathew Thomas Arun, Kuldeep Deka, Tripurari Srivastava

Precision observables are well known for constraining most of the beyond standard model (BSM) scenarios tightly, among which the electroweak precision observables (EWPO) play a significant role. Recent measurement of the W boson mass ((M_W)) at CDF-II has put a renewed focus on the EWPO and its ensuing constraints. In this study, we look at the scenarios where these BSM effects are encoded primarily in ten dimension-6 standard model effective field theory (SMEFT) operators (in the Warsaw basis) which contribute to the EWPO at tree-level. After presenting the fitting procedure and testing it on the S, T and V parameters, we go on to fit various BSM scenarios consisting of different well-motivated subsets of the 10 operators of our interest. To constrain these scenarios further, we augment the EWPO with (Delta _{textrm{CKM}}) measurement using 1-loop matching of the low-energy effective field theory to SMEFT operators at the Z-pole. We show that the inclusion of the (Delta _{textrm{CKM}}) constraint indeed results in stronger bounds on our Wilson coefficients. One of our operator subsets caters to the models of vector-like leptons, where we find out that such a minimal extension is in tension with the forward–backward asymmetry in the b-sector ((A_b^{textrm{FB}})) and (M_W). Finally, we also include the LEP-II observables pertaining to the WW production, thereby lifting the two associated blind directions, helping us present the results for the full fit.

精密可观测量以其对大多数超标准模型(BSM)情景的严格约束而闻名,其中电弱精密可观测量(EWPO)起着重要作用。最近在CDF-II上对W玻色子质量((M_W))的测量使人们重新关注EWPO及其随之而来的限制。在本研究中,我们研究了这些BSM效应主要编码在十维6标准模型有效场理论(SMEFT)算子(华沙基)中的场景,这些算子有助于树级EWPO。在给出拟合过程并在S、T和V参数上进行测试之后,我们继续拟合由我们感兴趣的10个算子的不同动机良好的子集组成的各种BSM场景。为了进一步限制这些情况,我们利用低能量有效场理论与z极SMEFT算子的1环匹配来增强EWPO (Delta _{textrm{CKM}})测量。我们表明,(Delta _{textrm{CKM}})约束的包含确实导致我们的威尔逊系数的更强的界限。我们的一个算子子集迎合了类矢量轻子的模型,在那里我们发现这样的最小扩展与b扇区((A_b^{textrm{FB}}))和(M_W)中的前后不对称是有张力的。最后,我们还包括了与WW生产相关的LEP-II观测值,从而提升了两个相关的盲方向,帮助我们呈现了完全拟合的结果。
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引用次数: 0
Geodesic motion and circular motion of particles around charged black hole immersed in non-linear Maxwell ( f(R) ) gravity 沉浸在非线性麦克斯韦引力中的带电黑洞周围粒子的测地线运动和圆周运动( f(R) )
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-12 DOI: 10.1007/s12043-025-02966-9
Indrajit Halder

This paper investigates the geodesic motion and circular motion of particles around a linear Maxwell (f(R)) black hole in a modified gravity black hole field, using a specific metric. It focusses on framing the effective potential function for photon-like as well as massive particles, revealing differences in the behaviour of coordinate and proper time relative to radial distance in the space–time geometry. The analysis focusses on effective potential curves obtained from specific equations, examining the dynamics of massless and massive particles in different scenarios. Moreover, it examines the stability of particle orbits using the Lyapunov exponent and explains how the circular orbit of a particle moving under the influence of gravitational field of the black hole is conditionally stabilised. This paper examines how the cosmological constant and gravitational modification parameter influence the circular and geodesic motion of the particle. Finally, this paper provides a graphical analysis of the radius of the innermost stable circular orbit and outermost stable circular orbit of the particles moving in the field of modified gravity.

本文研究了修正引力黑洞场中线性麦克斯韦(f(R))黑洞周围粒子的测地线运动和圆周运动。它着重于构造类光子粒子和大质量粒子的有效势函数,揭示时空几何中相对于径向距离的坐标和固有时的行为差异。分析的重点是由特定方程得到的有效势曲线,考察了不同情况下无质量粒子和有质量粒子的动力学。此外,它使用李亚普诺夫指数检验了粒子轨道的稳定性,并解释了在黑洞引力场影响下运动的粒子的圆形轨道是如何有条件地稳定的。本文考察了宇宙学常数和引力修正参数如何影响粒子的圆周运动和测地线运动。最后,本文给出了修正重力场中运动粒子的最内层稳定圆轨道半径和最外层稳定圆轨道半径的图解分析。
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引用次数: 0
Modified Legendre wavelet-based comparative study of a new model of romantic and interpersonal relationships 基于改进勒让德小波的浪漫与人际关系新模型的比较研究
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-08 DOI: 10.1007/s12043-025-02994-5
R Yeshwanth, S Kumbinarasaiah

Current biosocial theories, such as the influence of neurotransmitters on the behaviour, ecological perspectives that consider cultural, political, and institutional factors and interpersonal views like attachment, have shaped our understanding of romantic and interpersonal relationships as typical social experiences. However, these theories fail to offer a comprehensive framework for the relationship dynamics and a fully integrated theoretical approach is still missing. Here, we have developed a mathematical model to investigate the dynamics of romantic and interpersonal relationships between male, female, child and society via a system of fractional differential equations (SFDEs) to provide insight into the love/hate behaviour. The model comprises four classes describing the love/hate of males, females, children and society. The modified operational matrix of integration (OMI) of the Legendre wavelets is presented and used to solve the SFDEs. The model is solved using RK4, NDSolve and the Legendre wavelet collocation method (LWCM) for numerical analysis and comparison of the solutions. Numerical and graphical study of fractional order is done for different values of (gamma ). The pictorial analysis of various values of parameters to show the variation of classes is done. The Mathematica software has been used for numerical computations. This study reveals how the internal relationship and status affect the status of the society.

当前的生物社会理论,如神经递质对行为的影响,考虑文化、政治和制度因素的生态观点,以及依恋等人际观点,已经塑造了我们对浪漫和人际关系作为典型社会经验的理解。然而,这些理论未能为关系动力学提供一个全面的框架,缺乏一个完全整合的理论方法。在这里,我们开发了一个数学模型,通过分数阶微分方程(SFDEs)系统来研究男性、女性、儿童和社会之间的浪漫和人际关系的动态,以提供对爱/恨行为的洞察。该模型包括四个类,分别描述男性、女性、儿童和社会的爱/恨。提出了Legendre小波的改进运算积分矩阵(OMI),并将其用于求解SFDEs。采用RK4、NDSolve和Legendre小波搭配法(LWCM)对模型进行了求解,并对求解结果进行了数值分析和比较。对不同的(gamma )值进行了分数阶的数值和图形研究。对各种参数值进行了图形化分析,以显示类别的变化。使用Mathematica软件进行数值计算。本研究揭示了内在关系和地位是如何影响社会地位的。
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引用次数: 0
Feedback-driven model of dynamic information spreading in online social networks 在线社交网络中动态信息传播的反馈驱动模型
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-06 DOI: 10.1007/s12043-025-02999-0
Fuzhong Nian, Jingru Niu, Zhen Wang

This paper constructs a spreading model driven by positive and negative feedback interactions to study the impact of inter-individual feedback interaction on message spreading in online social networks. By analysing the network topology and the social attributes of the propagators, we introduce feedback interaction rules. In addition, the individual’s spreading motivation comes from the direct feedback interactions of multilevel neighbours and the group-level pressure of the social environment. Therefore, we established a feedback efficiency function. Experimental results show that the model is effective in promoting the positive spread of messages. Meanwhile, it is found that the increased social distance between individuals weakens the feedback strength, the group feedback rate enhances the expected spreading ability of the upline nodes and the group feedback has a more significant incentive effect than the neighbour feedback. Finally, the reasonableness of the model is verified by comparing with real cases.

本文构建了正负反馈互动驱动的传播模型,研究了网络社交网络中个体间反馈互动对信息传播的影响。通过分析网络拓扑结构和传播者的社会属性,引入反馈交互规则。此外,个体的传播动机来自多层次邻居的直接反馈互动和社会环境的群体层面压力。因此,我们建立了反馈效率函数。实验结果表明,该模型能够有效地促进信息的正向传播。同时,发现个体间社会距离的增加削弱了反馈强度,群体反馈率提高了上行节点的预期传播能力,群体反馈比邻居反馈具有更显著的激励作用。最后,通过与实际案例的比较,验证了模型的合理性。
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引用次数: 0
The travelling wave solutions to stochastic resonant nonlinear Schrödinger equation with both spatio-temporal and inter-modal dispersions having multiplicative white noise 具有乘性白噪声的时空和模态间色散随机共振非线性Schrödinger方程的行波解
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-02 DOI: 10.1007/s12043-025-02992-7
Na Tang, Bing-Wen Zhang

This paper constructs the travelling wave solutions of the stochastic resonant nonlinear Schrödinger equation that contains the stochastic term with multiplicative white noise based on the complete discriminant system for the polynomial method. By systematically investigating the polynomial law, we derive more abundant forms of travelling wave solutions. Notably, our new insight reveals that the non-averaged state of the solutions enables the characteristics of solitons and periodic modes to be maintained. In contrast, stochastic averaging will lead to changes in the periodic and soliton characteristics. In addition, we present the model diagrams for several specific parameters, which endows physical interpretations to the spatiotemporal structure in the white noise environment.

本文基于多项式方法的完全判别系统,构造了含乘性白噪声随机项的随机共振非线性Schrödinger方程的行波解。通过系统地研究多项式律,我们得到了更丰富的行波解形式。值得注意的是,我们的新见解揭示了解的非平均状态使孤子和周期模式的特征得以保持。相反,随机平均会导致周期和孤子特性的变化。此外,我们给出了几个具体参数的模型图,赋予白噪声环境下时空结构的物理解释。
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引用次数: 0
Stability of the Toda system related to a perturbed (R_I)-type recurrence relation 与摄动(R_I)型递推关系相关的Toda系统的稳定性
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-02 DOI: 10.1007/s12043-025-02988-3
Vinay Shukla, A Swaminathan

In this manuscript, a modified (R_I)-type recurrence relation is considered whose recurrence coefficients are perturbed by the addition or multiplication of a constant. Using the perturbed system of recurrence coefficients, perturbed extended relativistic Toda equations are derived. These equations are then represented in a matrix form. This matrix representation helps recover a Lax pair that has already been studied in the literature. Inferences about the stability of the resulting perturbed system of the Toda equations are drawn based on numerical experiments.

本文考虑了一种改进的(R_I)型递归关系,其递归系数被常数的加法或乘法所扰动。利用递推系数的摄动系统,导出了摄动扩展相对论Toda方程。然后用矩阵形式表示这些方程。这种矩阵表示有助于恢复文献中已经研究过的Lax对。通过数值实验得出了Toda方程扰动系统稳定性的推论。
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引用次数: 0
(beta )-decay properties of proton-rich Sn isotopes (beta )-富质子锡同位素的衰变性质
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-09-02 DOI: 10.1007/s12043-025-03001-7
Jameel-Un Nabi, Wajeeha Khalid, M Aswad Ali Shah

We explore the (beta )-decay features of the doubly magic nucleus (^{100})Sn and proton-rich Sn isotopes within the mass range 100(le ) A (le ) 110. Our calculations yield a Gamow–Teller (GT) strength of 4.157 for the transition from the ground state to the lowest excited state of (^{100})Sn, which closely aligns with the recently measured value of 4.381 at RIKEN. The GT strength distributions computed for (^{102-104, 106, 108})Sn exhibit good agreement with experimental observations. Additionally, we compare our GT data with previous theoretical calculations. The predicted half-lives are reproduced within a factor of 2 relative to the experimental values for (^{100-110})Sn. For the first time, we present microscopic calculations of electron capture, (beta ^{+}) decay, and proton emission rates for proton-rich Sn isotopes under stellar conditions. As the core density of a star reaches (10^{11}) g/cm(^3), electron capture rates calculated by up to seven orders of magnitude. In contrast, (beta ^{+}) decay rates remain largely unchanged with variations in core density but exhibit changes of up to three orders of magnitude with increasing core temperatures. A decreasing trend in stellar rates is observed with increasing neutron number N, specifically for even-even and odd-A Sn isotopes. The reported stellar rates provide valuable insights for the rp-process and simulation of post-silicon evolution of massive stars.

我们探索了质量范围为100 (le ) A (le ) 110的双幻核(^{100}) Sn和富质子Sn同位素的(beta ) -衰变特征。我们的计算得出(^{100}) Sn从基态到最低激发态转变的伽莫夫-泰勒(GT)强度为4.157,这与RIKEN最近测量的值4.381非常接近。(^{102-104, 106, 108}) Sn的GT强度分布与实验结果吻合较好。此外,我们将我们的GT数据与先前的理论计算进行了比较。与(^{100-110}) Sn的实验值相比,预测的半衰期在2倍的范围内重现。我们首次提出了富质子锡同位素在恒星条件下的电子捕获、(beta ^{+})衰变和质子发射率的微观计算。当恒星的核心密度达到(10^{11}) g/cm (^3)时,计算出的电子俘获率可达7个数量级。相比之下,(beta ^{+})衰变率随着堆芯密度的变化基本保持不变,但随着堆芯温度的升高,其变化幅度可达3个数量级。随着中子数N的增加,特别是偶偶和奇A Sn同位素,恒星速率呈下降趋势。报告的恒星速率为rp过程和大质量恒星后硅演化的模拟提供了有价值的见解。
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引用次数: 0
Spherically symmetric vacuum solutions of modified field equations in (f(R, Sigma , T))-gravity (f(R, Sigma , T)) -重力中修正场方程的球对称真空解
IF 2.1 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2025-08-31 DOI: 10.1007/s12043-025-02996-3
M Khater, M A Bakry

This study examines spherically symmetric static empty space solutions within the framework of the (f(R, Sigma , T))-gravity, where (f(R, Sigma , T)) is a general function of the scalar curvature R, the torsion scalar (Sigma ) and the trace of the energy–momentum tensor T. We reduce the modified Einstein equations to a single equation and demonstrate how to construct exact solutions across various (f(R, Sigma , T))-gravity models. Notably, we establish that for a broad class of models, including the (f(R, Sigma , T)=R+Sigma +2 eta T) model, the Schwarzschild metric serves as an exact solution to the field equations, alongside other classes of solutions. We discuss the significance of these findings in the context of solar system constraints on (f(R, Sigma , T)) theories of gravity. Additionally, the effects of space–time torsion and particle spin on the solar system are also explored.

本研究考察了(f(R, Sigma , T)) -重力框架内的球对称静态空间解,其中(f(R, Sigma , T))是标量曲率R、扭转标量(Sigma )和能量动量张量t轨迹的一般函数。我们将修正的爱因斯坦方程简化为一个方程,并演示了如何构建各种(f(R, Sigma , T)) -重力模型的精确解。值得注意的是,我们建立了一个广泛的模型类别,包括(f(R, Sigma , T)=R+Sigma +2 eta T)模型,史瓦西度规作为场方程的精确解,与其他类别的解一起。我们讨论了这些发现在太阳系约束(f(R, Sigma , T))引力理论的背景下的意义。此外,还探讨了时空扭转和粒子自旋对太阳系的影响。
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引用次数: 0
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Pramana
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