Pub Date : 2024-09-12DOI: 10.1007/s40010-024-00895-7
Sujeet Kumar, Binod Chandra Tripathy
In this paper we present the notion of bounded, convergent in Pringsheim sense, null in Pringsheim sense, regular, regular null and absolutely p-sumable double sequences of bi-complex numbers. We have also introduced the concept of repeated limit of the double sequences of bi-complex numbers. We have established that every P-convergent double sequence of bi-complex numbers is not always bounded but regular convergent double sequences of bi-complex numbers is bounded. It is shown that the introduced classes of double sequences of bi-complex numbers are linear spaces. With the help of the Euclidean norm defined on bi-complex numbers, it is shown that among these classes, the bounded classes are Banach spaces. We have established some of their algebraic and topological properties like solidity, monotonic, symmetric and convergence free. Suitable examples have been discussed to support the introduction of the classes of sequences and the properties, those fail to hold.
在本文中,我们提出了有界、普林斯海姆意义上的收敛、普林斯海姆意义上的无效、正则、正则无效和绝对可 p 求和的双复数双序列的概念。我们还引入了双复数双序列重复极限的概念。我们已经确定,每个双复数的 P 收敛双序列并不总是有界的,但双复数的正则收敛双序列是有界的。研究表明,引入的双复数双序列类是线性空间。借助定义在双复数上的欧氏规范,证明在这些类中,有界类是巴拿赫空间。我们建立了它们的一些代数和拓扑性质,如实体性、单调性、对称性和无收敛性。我们还讨论了一些合适的例子,以支持序列类的引入和那些不成立的性质。
{"title":"Double Sequences of Bi-complex Numbers","authors":"Sujeet Kumar, Binod Chandra Tripathy","doi":"10.1007/s40010-024-00895-7","DOIUrl":"10.1007/s40010-024-00895-7","url":null,"abstract":"<div><p>In this paper we present the notion of bounded, convergent in Pringsheim sense, null in Pringsheim sense, regular, regular null and absolutely <i>p</i>-sumable double sequences of bi-complex numbers. We have also introduced the concept of repeated limit of the double sequences of bi-complex numbers. We have established that every <i>P</i>-convergent double sequence of bi-complex numbers is not always bounded but regular convergent double sequences of bi-complex numbers is bounded. It is shown that the introduced classes of double sequences of bi-complex numbers are linear spaces. With the help of the Euclidean norm defined on bi-complex numbers, it is shown that among these classes, the bounded classes are Banach spaces. We have established some of their algebraic and topological properties like solidity, monotonic, symmetric and convergence free. Suitable examples have been discussed to support the introduction of the classes of sequences and the properties, those fail to hold.</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"463 - 469"},"PeriodicalIF":0.8,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-11DOI: 10.1007/s40010-024-00892-w
Sukanta Goswami, Sangeeta Bhagat, Dheeraj Pande, D. K. Choudhury, B. Saravanan, D. K. Sinha
The outcrops of greenstone belt and granite complex along Ramagiri-Penakacherla tract are analyzed for tectonics and associated deformation history related to crustal evolution. Field data connote more than five deformation events. Initial ductile deformation regime (D1-D4) passes through brittle-ductile (D5) to shallow brittle regime (D6). Multiple deformation events (D1-D5) resulted in shear zones with variable trends and sense. Three major generations of folding (F2–F4) imprinted over and obscure F1 folding in ductile regime. Younger granite intruded after F3 hence exhibit only F4 folds. Brittle regime (D6) is manifested by faults with dominant E-W trend affected all earlier deformation features. They show mainly normal and few strike slip motion with episodic reactivation with dominantly N-S stretching (i.e., σ3). Contact relationships between granite and country rocks give insight on depth and associated pressure-temperature condition. From deeper catazone through intermediate mesozone to shallow epizone granite the progressive increase in temperature contrast influence contact relationships with country rocks from concordant through gradational to sharp discordant. Structural attributes of the northern and southern end of the study area exhibit remarkable changes in granite character, which give information on changes in crustal depth. Supportive petro-mineralogical and geochemical evidences also imply for exhumed northerly tilted crust. Bhima and Kaladgi basins are developed due to this crustal block tilting and basin fill sediments were supplied from erosion of uplifted southern parts. During erosion, the exhumation leads to retrograde metamorphism which is better manifested in metabasic rocks. From the surface distance between epizone/mesozone and mesozone/catazone boundaries and average crustal depth difference between these two boundaries, a northerly tilt angle of 1.90 is estimated. The obduction at the southern end of Dharwar Craton and late stage N-S stretching is responsible for such tilting.
{"title":"Estimation of Crustal Tilting from Petrotectonic Interpretation of Mesozone Granitoid and its Marginal Parts, Eastern Dharwar Craton, India","authors":"Sukanta Goswami, Sangeeta Bhagat, Dheeraj Pande, D. K. Choudhury, B. Saravanan, D. K. Sinha","doi":"10.1007/s40010-024-00892-w","DOIUrl":"10.1007/s40010-024-00892-w","url":null,"abstract":"<div><p>The outcrops of greenstone belt and granite complex along Ramagiri-Penakacherla tract are analyzed for tectonics and associated deformation history related to crustal evolution. Field data connote more than five deformation events. Initial ductile deformation regime (D<sub>1</sub>-D<sub>4</sub>) passes through brittle-ductile (D<sub>5</sub>) to shallow brittle regime (D<sub>6</sub>). Multiple deformation events (D<sub>1</sub>-D<sub>5</sub>) resulted in shear zones with variable trends and sense. Three major generations of folding (F<sub>2</sub>–F<sub>4</sub>) imprinted over and obscure F<sub>1</sub> folding in ductile regime. Younger granite intruded after F<sub>3</sub> hence exhibit only F<sub>4</sub> folds. Brittle regime (D<sub>6</sub>) is manifested by faults with dominant E-W trend affected all earlier deformation features. They show mainly normal and few strike slip motion with episodic reactivation with dominantly N-S stretching (i.e., σ<sub>3</sub>). Contact relationships between granite and country rocks give insight on depth and associated pressure-temperature condition. From deeper catazone through intermediate mesozone to shallow epizone granite the progressive increase in temperature contrast influence contact relationships with country rocks from concordant through gradational to sharp discordant. Structural attributes of the northern and southern end of the study area exhibit remarkable changes in granite character, which give information on changes in crustal depth. Supportive petro-mineralogical and geochemical evidences also imply for exhumed northerly tilted crust. Bhima and Kaladgi basins are developed due to this crustal block tilting and basin fill sediments were supplied from erosion of uplifted southern parts. During erosion, the exhumation leads to retrograde metamorphism which is better manifested in metabasic rocks. From the surface distance between epizone/mesozone and mesozone/catazone boundaries and average crustal depth difference between these two boundaries, a northerly tilt angle of 1.9<sup>0</sup> is estimated. The obduction at the southern end of Dharwar Craton and late stage N-S stretching is responsible for such tilting.</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"391 - 421"},"PeriodicalIF":0.8,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-05DOI: 10.1007/s40010-024-00889-5
Mahendra Prasad, A. M. Parmeswaran, Kaman Singh
The transition temperature Tc of the superconductor signals the onset of superconductivity. We were curious to see the variation of Tc with the formula mass (FM) of well-studied high-Tc oxide superconductors to observe whether there exists any correlation between Tc and FM of these oxide superconductors. Interestingly, it is observed that the ratios of Tc /Fm of 8 different high-Tc superconductors which exhibit transition temperature ≥ 90 K, converge to show a ratio of 0.136 with a 14% deviation. Other superconductors and bismuth-based which have Tc less than 90 K differ significantly. Extrapolating the transition temperature to 25 °C, a formula mass FM of high-Tc oxide superconductor turns to be 2239 with only 14% deviation in different materials which have Tc ≥ 90 K. This means if oxide superconductors of formula mass 2239 are synthesized, then that materials could exhibit room-temperature superconductivity. The experimental work on YBCO superconductors is underway and results will be communicated essentially an extension of the present work.
超导体的转变温度 Tc 标志着超导性的开始。我们很想了解 Tc 随经过深入研究的高锝氧化物超导体的公式质量 (FM) 的变化情况,以观察这些氧化物超导体的 Tc 和 FM 之间是否存在任何相关性。有趣的是,我们观察到 8 种不同高锝超导体的 Tc /Fm 比值趋于一致,它们的转变温度≥ 90 K,比值为 0.136,偏差为 14%。Tc 小于 90 K 的其他超导体和铋基超导体的比值相差很大。将转变温度推断到 25 °C,高锝氧化物超导体的式质量 FM 变为 2239,在 Tc ≥ 90 K 的不同材料中仅有 14% 的偏差。有关 YBCO 超导体的实验工作正在进行中,实验结果将作为本研究的延伸予以公布。
{"title":"Transition Temperature versus Formula Mass of Selected High-TC Oxide Superconductors: A Step Closure to Room Temperature Superconductivity","authors":"Mahendra Prasad, A. M. Parmeswaran, Kaman Singh","doi":"10.1007/s40010-024-00889-5","DOIUrl":"10.1007/s40010-024-00889-5","url":null,"abstract":"<div><p>The transition temperature T<sub>c</sub> of the superconductor signals the onset of superconductivity. We were curious to see the variation of T<sub>c</sub> with the formula mass (F<sub>M</sub>) of well-studied high-T<sub>c</sub> oxide superconductors to observe whether there exists any correlation between T<sub>c</sub> and F<sub>M</sub> of these oxide superconductors. Interestingly, it is observed that the ratios of T<sub>c</sub> /F<sub>m</sub> of 8 different high-T<sub>c</sub> superconductors which exhibit transition temperature ≥ 90 K, converge to show a ratio of 0.136 with a 14% deviation. Other superconductors and bismuth-based which have T<sub>c</sub> less than 90 K differ significantly. Extrapolating the transition temperature to 25 °C, a formula mass F<sub>M</sub> of high-T<sub>c</sub> oxide superconductor turns to be 2239 with only 14% deviation in different materials which have T<sub>c</sub> ≥ 90 K. This means if oxide superconductors of formula mass 2239 are synthesized, then that materials could exhibit room-temperature superconductivity. The experimental work on YBCO superconductors is underway and results will be communicated essentially an extension of the present work.</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"387 - 390"},"PeriodicalIF":0.8,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-31DOI: 10.1007/s40010-024-00893-9
Satabdi Ray, Baby Bhattacharya
The main aim of this treatise is to establish the conception of sequence of multiset and countability on multiset topological spaces. Unlike any topological space, there are two subspaces in this context which are also countable M-topological space. Also, we obtained the relationship of the variants of countable M-topological spaces in the light of sequences in this environment.
本论文的主要目的是在多集拓扑空间上建立多集序列和可数性的概念。与任何拓扑空间不同,这里有两个子空间也是可数 M 拓扑空间。此外,我们还根据该环境中的序列,得到了可数 M 拓扑空间变体的关系。
{"title":"A Study on Countability in the Context of Multiset Topological Spaces","authors":"Satabdi Ray, Baby Bhattacharya","doi":"10.1007/s40010-024-00893-9","DOIUrl":"10.1007/s40010-024-00893-9","url":null,"abstract":"<div><p>The main aim of this treatise is to establish the conception of sequence of multiset and countability on multiset topological spaces. Unlike any topological space, there are two subspaces in this context which are also countable M-topological space. Also, we obtained the relationship of the variants of countable M-topological spaces in the light of sequences in this environment.</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"457 - 461"},"PeriodicalIF":0.8,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-30DOI: 10.1007/s40010-024-00890-y
Gurwinder Singh, Rupinder Singh, P. S. Rao
Numerous studies have been published on conventional electrochemical machining with different tools and workpiece materials, machining parameters, and machining profile accuracy. Also, some studies have been reported on modified electrochemical machining to address the tool replica issues in conventional electrochemical machining with a novel 3D-printed thermoplastic-based inter-electrode slit between the tool and the W/P. But hitherto, little has been reported on the aspect ratio, and machining profile accuracy (overcut) in modified electrochemical machining. This study outlines the machining profile accuracy of modified electrochemical machining with the use of a novel square profile/cross-section inter-electrode slit along with feed rate, slit thickness, tool, workpiece material, and voltage based on Taguchi L18 orthogonal array. The machining profile accuracy of the cavity was ascertained in the form of the cavity dimensions along the X and Y axis, machined area, machining depth (Z), diagonal length (DL) of profile section, aspect ratio (DL/Z), and overcut. The study suggests that as per the multi-factor optimization approach for machining profile accuracy, the optimized settings of modified electrochemical machining are electrolyte concentration 100 g/l, voltage 21 V, workpiece/tool as Cu, feed rate 108 µm/min, inter-electrode slit thickness 4.5 mm with composite desirability 0.944. Further, at optimized settings of the modified electrochemical machining process in the present case study, porosity 23.95%, DL 10.955 mm, cavity length along the X-axis 4.817 mm, Y-axis 3.613 mm, and Z-axis 1.179 mm, aspect ratio of 9.29 and over cut 18.59 mm2 was achieved.
{"title":"On Machining Profile Accuracy in the Modified Electrochemical Machining Process","authors":"Gurwinder Singh, Rupinder Singh, P. S. Rao","doi":"10.1007/s40010-024-00890-y","DOIUrl":"10.1007/s40010-024-00890-y","url":null,"abstract":"<div><p>Numerous studies have been published on conventional electrochemical machining with different tools and workpiece materials, machining parameters, and machining profile accuracy. Also, some studies have been reported on modified electrochemical machining to address the tool replica issues in conventional electrochemical machining with a novel 3D-printed thermoplastic-based inter-electrode slit between the tool and the W/P. But hitherto, little has been reported on the aspect ratio, and machining profile accuracy (overcut) in modified electrochemical machining. This study outlines the machining profile accuracy of modified electrochemical machining with the use of a novel square profile/cross-section inter-electrode slit along with feed rate, slit thickness, tool, workpiece material, and voltage based on Taguchi L<sub>18</sub> orthogonal array. The machining profile accuracy of the cavity was ascertained in the form of the cavity dimensions along the <i>X</i> and <i>Y</i> axis, machined area, machining depth (<i>Z</i>), diagonal length (<i>DL</i>) of profile section, aspect ratio (<i>DL/Z</i>), and overcut. The study suggests that as per the multi-factor optimization approach for machining profile accuracy, the optimized settings of modified electrochemical machining are electrolyte concentration 100 g/l, voltage 21 V, workpiece/tool as Cu, feed rate 108 µm/min, inter-electrode slit thickness 4.5 mm with composite desirability 0.944. Further, at optimized settings of the modified electrochemical machining process in the present case study, porosity 23.95%, <i>DL</i> 10.955 mm, cavity length along the <i>X</i>-axis 4.817 mm, <i>Y</i>-axis 3.613 mm, and <i>Z-</i>axis 1.179 mm, aspect ratio of 9.29 and over cut 18.59 mm<sup>2</sup> was achieved.</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"423 - 436"},"PeriodicalIF":0.8,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-30DOI: 10.1007/s40010-024-00891-x
Prince Gupta, Rajeev Sharma, Sachi Gupta
The concept of fog computing refers to a paradigm of distributed computing that extends cloud computing to the most remote parts of the network. Simulators are useful for analyzing resource management techniques including load balancing, fault tolerance, and energy efficiency in fog computing settings. This could result in the creation of more effective resource management algorithms. Fog simulators offer a realistic environment for testing fog computing applications and systems, incorporating authentic network conditions, device capabilities, and application requirements. This aids in recognizing and resolving such problems before implementing fog computing systems in practical situations. Fog computing links the breach between the cloud and other networking edges, qualifying the decentralized operation of computing equipment. Traditional cloud computing has several problems, including latency, size, space, and network failure. Fog computing can quickly and easily fix these issues. Moreover, it creates a complicated set of issues for both the scientific community and business. Both have several unresolved issues to deal with, including standardizing architecture and dealing with issues like resource management, service management, quality of service (QoS), participation, and communication. The objective of the article is to present a study on simulators for fog computing and cloud information.
{"title":"Simulators for Fog Computing and Information Processing","authors":"Prince Gupta, Rajeev Sharma, Sachi Gupta","doi":"10.1007/s40010-024-00891-x","DOIUrl":"10.1007/s40010-024-00891-x","url":null,"abstract":"<div><p>The concept of fog computing refers to a paradigm of distributed computing that extends cloud computing to the most remote parts of the network. Simulators are useful for analyzing resource management techniques including load balancing, fault tolerance, and energy efficiency in fog computing settings. This could result in the creation of more effective resource management algorithms. Fog simulators offer a realistic environment for testing fog computing applications and systems, incorporating authentic network conditions, device capabilities, and application requirements. This aids in recognizing and resolving such problems before implementing fog computing systems in practical situations. Fog computing links the breach between the cloud and other networking edges, qualifying the decentralized operation of computing equipment. Traditional cloud computing has several problems, including latency, size, space, and network failure. Fog computing can quickly and easily fix these issues. Moreover, it creates a complicated set of issues for both the scientific community and business. Both have several unresolved issues to deal with, including standardizing architecture and dealing with issues like resource management, service management, quality of service (QoS), participation, and communication. The objective of the article is to present a study on simulators for fog computing and cloud information.</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"437 - 447"},"PeriodicalIF":0.8,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-27DOI: 10.1007/s40010-024-00888-6
Sachin Devaiya, Shailesh Kumar Srivastava
Taking into consideration that the superposition of two summability methods is superior to the individual one, in this paper we present the calculations of the degree of approximation of functions and their conjugates belonging to the weighted Lipschitz class by a trigonometric polynomial generated by the application of product means (mathcal {C}^{1}.mathcal {T}) on their trigonometric Fourier series and conjugate series, respectively. Here we also reduce some conditions imposed on the increasing function (Psi (t)). Further, with the help of an example, we demonstrate the application of the results in the circumstances when the Fourier series of the function has the Gibbs phenomenon. We also provide a few corollaries that follow directly from our results.
{"title":"On Fourier Approximation of Periodic Functions and Their Conjugates Belonging to the Weighted Lipschitz Class","authors":"Sachin Devaiya, Shailesh Kumar Srivastava","doi":"10.1007/s40010-024-00888-6","DOIUrl":"10.1007/s40010-024-00888-6","url":null,"abstract":"<div><p>Taking into consideration that the superposition of two summability methods is superior to the individual one, in this paper we present the calculations of the degree of approximation of functions and their conjugates belonging to the weighted Lipschitz class by a trigonometric polynomial generated by the application of product means <span>(mathcal {C}^{1}.mathcal {T})</span> on their trigonometric Fourier series and conjugate series, respectively. Here we also reduce some conditions imposed on the increasing function <span>(Psi (t))</span>. Further, with the help of an example, we demonstrate the application of the results in the circumstances when the Fourier series of the function has the Gibbs phenomenon. We also provide a few corollaries that follow directly from our results. \u0000</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"449 - 455"},"PeriodicalIF":0.8,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-08DOI: 10.1007/s40010-024-00882-y
B. Dinesh, Jagadeesha Poyya, Farhan Zameer, Lokesh Koodlur Sannegowda, Chandrashekhar G. Joshi, Anjanapura V. Raghu
Nanotechnology research has advanced in the past two decades because of its tunable physicochemical properties. Among the wide range of metal-based nanoparticles, silver nanoparticles (AgNPs) have gained intense research prominence because of their peerless features such as excellent electrical conductivity, catalysis, and a broad range of promising bioactivities such as antioxidant, antibacterial, antifungal, anti-inflammatory, and anticancer effects. In attaining the colloidal stability of silver nanoparticles, capping plays an important role. These capping compounds are believed to provide dual functionality in the synthesis process, acting both as structure-directing and stabilizing agents. Polyvinylpyrrolidone (PVP) is a biocompatible, pH-stable, inert, non-toxic, temperature-resistant, and biodegradable polymer. In the present study, PVP capped silver nanoparticles are synthesized using glucose as a reducing agent, and studied the influence of PVP concentration on silver nanoparticles. Three different ratios of silver nitrate and PVP (1:1, 1:1.5, and 1:2) are taken for silver nanoparticle synthesis. Further, silver nanoparticles obtained are subjected to a series of examinations, including UV Spectrophotometry, SEM, X-Ray Diffraction Spectroscopy, Dynamic Light Scattering, and FTIR. The PVP capped silver nanoparticles are spherical, non-aggregated, polydisperse, and had a unimodal distribution, with diameters ranging from 40 to 100 nm. PVP capped silver nanoparticles are then subjected to antioxidant and antimicrobial activity investigation by spectrometry and agar well diffusion method respectively. The DPPH and the ABTS study revealed the radical scavenging activity of AgNPs. However, the PVP-capped silver nanoparticles did not show any antibacterial activity. This study showed the possibility of the application of PVP-capped AgNPs in the treatment of free radical-related diseases.
{"title":"Effect of Polyvinylpyrrolidone on Antioxidant and Antibacterial Activity of Silver Metal Nanoparticles: A Comparative Analysis","authors":"B. Dinesh, Jagadeesha Poyya, Farhan Zameer, Lokesh Koodlur Sannegowda, Chandrashekhar G. Joshi, Anjanapura V. Raghu","doi":"10.1007/s40010-024-00882-y","DOIUrl":"10.1007/s40010-024-00882-y","url":null,"abstract":"<div><p>Nanotechnology research has advanced in the past two decades because of its tunable physicochemical properties. Among the wide range of metal-based nanoparticles, silver nanoparticles (AgNPs) have gained intense research prominence because of their peerless features such as excellent electrical conductivity, catalysis, and a broad range of promising bioactivities such as antioxidant, antibacterial, antifungal, anti-inflammatory, and anticancer effects. In attaining the colloidal stability of silver nanoparticles, capping plays an important role. These capping compounds are believed to provide dual functionality in the synthesis process, acting both as structure-directing and stabilizing agents. Polyvinylpyrrolidone (PVP) is a biocompatible, <i>p</i>H-stable, inert, non-toxic, temperature-resistant, and biodegradable polymer. In the present study, PVP capped silver nanoparticles are synthesized using glucose as a reducing agent, and studied the influence of PVP concentration on silver nanoparticles. Three different ratios of silver nitrate and PVP (1:1, 1:1.5, and 1:2) are taken for silver nanoparticle synthesis. Further, silver nanoparticles obtained are subjected to a series of examinations, including UV Spectrophotometry, SEM, X-Ray Diffraction Spectroscopy, Dynamic Light Scattering, and FTIR. The PVP capped silver nanoparticles are spherical, non-aggregated, polydisperse, and had a unimodal distribution, with diameters ranging from 40 to 100 nm. PVP capped silver nanoparticles are then subjected to antioxidant and antimicrobial activity investigation by spectrometry and agar well diffusion method respectively. The DPPH and the ABTS study revealed the radical scavenging activity of AgNPs. However, the PVP-capped silver nanoparticles did not show any antibacterial activity. This study showed the possibility of the application of PVP-capped AgNPs in the treatment of free radical-related diseases.</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"359 - 368"},"PeriodicalIF":0.8,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141928358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-01DOI: 10.1007/s40010-024-00886-8
Jagdish Chandra Jat, Preeti Mehta
The coupling of aldehyde, amine, and alkyne (known as A3-coupling) is a versatile strategy for the synthesis of propargylamines which are important precursors for the biologically active molecules. Recently, phenylglyoxylic acid as a surrogate of aldehyde has gained importance in the above reaction via decarboxylative coupling. Transition metal catalysts of Cu and Au have been reported for this reaction. However, metal waste and their disposal is the major challenge faced by chemical industries. In this work, we have explored chitosan-supported zinc catalysts for the decarboxylative coupling of phenylglyoxylic acid with amine and alkyne. We found that this reaction gives the best yield under solvent-less condition. For comparison purpose, the catalytic activity of synthesized catalysts in various molecular solvents has also been explored.
{"title":"Synthesis and Application of Heterogeneous Zinc Catalysts for Decarboxylative Coupling","authors":"Jagdish Chandra Jat, Preeti Mehta","doi":"10.1007/s40010-024-00886-8","DOIUrl":"10.1007/s40010-024-00886-8","url":null,"abstract":"<p>The coupling of aldehyde, amine, and alkyne (known as A<sup>3</sup>-coupling) is a versatile strategy for the synthesis of propargylamines which are important precursors for the biologically active molecules. Recently, phenylglyoxylic acid as a surrogate of aldehyde has gained importance in the above reaction via decarboxylative coupling. Transition metal catalysts of Cu and Au have been reported for this reaction. However, metal waste and their disposal is the major challenge faced by chemical industries. In this work, we have explored chitosan-supported zinc catalysts for the decarboxylative coupling of phenylglyoxylic acid with amine and alkyne. We found that this reaction gives the best yield under solvent-less condition. For comparison purpose, the catalytic activity of synthesized catalysts in various molecular solvents has also been explored.</p>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 4","pages":"369 - 385"},"PeriodicalIF":0.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141869221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-10DOI: 10.1007/s40010-024-00885-9
Mahesh Puri Goswami, Raj Kumar
The aim of this article is to define the Caputo derivative of bicomplex order for the functions of a bicomplex variable, which we refer to as the Bicomplex Caputo Derivative (BCD) throughout the paper. We achieve BCD via the development of the Caputo derivative of bicomplex order for the bicomplex-valued functions of real variable and discuss some of its significant properties. We also compare BCD with the bicomplex Riemann–Liouville derivative and integral. We demonstrate the advantages of the properties of BCD by finding the derivatives of some elementary bicomplex functions. The useful applications of BCD are found in constructing bicomplex fractional Maxwell’s equations in the vacuum and source-free domains. The solutions of bicomplex fractional Maxwell’s equations are obtained by considering a bicomplex vector field, and it is proved that in this way the number of equations is reduced by half.
{"title":"Bicomplex Caputo Derivative: A Comparative Study with Bicomplex Riemann–Liouville Operators and Applications","authors":"Mahesh Puri Goswami, Raj Kumar","doi":"10.1007/s40010-024-00885-9","DOIUrl":"10.1007/s40010-024-00885-9","url":null,"abstract":"<div><p>The aim of this article is to define the Caputo derivative of bicomplex order for the functions of a bicomplex variable, which we refer to as the Bicomplex Caputo Derivative (BCD) throughout the paper. We achieve BCD via the development of the Caputo derivative of bicomplex order for the bicomplex-valued functions of real variable and discuss some of its significant properties. We also compare BCD with the bicomplex Riemann–Liouville derivative and integral. We demonstrate the advantages of the properties of BCD by finding the derivatives of some elementary bicomplex functions. The useful applications of BCD are found in constructing bicomplex fractional Maxwell’s equations in the vacuum and source-free domains. The solutions of bicomplex fractional Maxwell’s equations are obtained by considering a bicomplex vector field, and it is proved that in this way the number of equations is reduced by half.</p></div>","PeriodicalId":744,"journal":{"name":"Proceedings of the National Academy of Sciences, India Section A: Physical Sciences","volume":"94 3","pages":"345 - 358"},"PeriodicalIF":0.8,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40010-024-00885-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141585210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}