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Upcycling of End-of-Life-Vehicle (ELV) plastics as a replacement for natural fine aggregate in concrete 将报废汽车(ELV)塑料升级再造,替代混凝土中的天然细骨料
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-03-04 DOI: 10.1016/j.rcradv.2024.200210
Juncheng Rao , Dharmappa Hagare , Zhong Tao

End-of-life vehicle (ELV) plastics pose technical challenges in conventional recycling due to their diverse polymer compositions. Consequently, landfilling remains the prevailing disposal method. This study explores an innovative approach by upcycling ELV plastics as a substitute for natural sand in concrete. The study investigates the physical, mechanical and economic performance of ELV plastic-containing concrete. Plastic aggregates were prepared from real-world ELV plastics, featuring particle sizes below 4.75 mm, with over 90 % falling within the range of 1.18–4.75 mm. The research involves replacing natural sand with ELV plastics at varying volumes (0 %, 15 %, 25 %, 35 %, and 40 %) and examines the effect of sand replacement on various concrete properties. The results suggest that as the replacement ratio increases, the workability, density, and strength of concrete decrease. However, the 28-day compressive strength of concrete at the maximum replacement rate of 40 % was found to be 39 MPa, which suffices for certain non-structural strength applications, such as traffic routes, shared-use paths, local streets and curbs. In addition, compared to previous studies using mixed commodity plastics, ELV plastics lead to significantly lower strength reductions at high replacement ratios. Scanning Electron Microscopy (SEM) analysis reveals a distinctive rough and fibrous aggregate morphology, which enhances physical binding and provides bridging effects within the concrete matrix, potentially mitigating strength loss. Moreover, the economic analysis highlights a significant potential to commercialize ELV plastics for concrete applications. This study demonstrates that ELV plastics can be effectively used at high replacement rates (up to 40 % by volume) in non-structural applications.

报废汽车塑料(ELV)由于其聚合物成分多种多样,给传统回收利用带来了技术挑战。因此,垃圾填埋仍然是最普遍的处理方法。本研究探索了一种创新方法,即在混凝土中使用 ELV 塑料作为天然砂的替代品。研究调查了含 ELV 塑料的混凝土的物理、机械和经济性能。塑料骨料由现实世界中的 ELV 塑料制备而成,颗粒大小低于 4.75 毫米,其中 90% 以上的颗粒大小在 1.18-4.75 毫米之间。研究涉及用不同体积(0%、15%、25%、35% 和 40%)的 ELV 塑料替代天然砂,并考察砂替代对各种混凝土性能的影响。结果表明,随着替代率的增加,混凝土的工作性、密度和强度都会降低。不过,在最大置换率为 40% 时,混凝土的 28 天抗压强度为 39 兆帕,足以满足某些非结构强度应用的要求,如交通路线、共用道路、地方街道和路缘石等。此外,与之前使用混合商品塑料进行的研究相比,ELV 塑料在高替换率下的强度降低幅度要小得多。扫描电子显微镜(SEM)分析揭示了一种独特的粗糙纤维状骨料形态,这种形态可增强物理结合力,并在混凝土基质中产生架桥效果,从而可能减轻强度损失。此外,经济分析凸显了 ELV 塑料在混凝土应用中的巨大商业潜力。这项研究表明,ELV 塑料可以在非结构性应用中以较高的替代率(高达 40%(体积))有效使用。
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引用次数: 0
Barriers and facilitators to recycling waste in hospitals: A mixed methods systematic review 医院废物回收的障碍和促进因素:混合方法系统回顾
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-03-01 DOI: 10.1016/j.rcradv.2024.200209
Lena Jungbluth , Denise Goodwin , Fraser Tull , Peter Bragge

Hospitals generate large amounts of waste, part of which is recyclable. However, research shows that recycling opportunities in hospitals often get missed with human behaviour playing an important role. Following current behavioural science, better understanding the influences on hospital recycling behaviour can support the design of promising behaviour change interventions, which draw on identified facilitators and help overcome identified barriers, to maximise recycling potential. Therefore, this systematic review aimed to investigate the barriers and facilitators to hospital waste recycling.

Three databases were searched to identify studies in high-income countries, pertaining to barriers and facilitators to hospital waste recycling. Their findings were thematically analysed and narratively synthesised drawing on a combination of the Capability, Opportunity, Motivation – Behaviour (COM-B) model with a multi-level framework.

Twenty-four studies met pre-defined inclusion criteria. Reported influences on hospital waste recycling pertained to factors beyond the hospital environment (e.g. product design preventing recycling), the internal hospital environment (e.g. lack of access to recycling bins) and individuals working within hospitals (e.g. concerns about infection control). Most influences were located in the internal hospital environment. Many related to the physical opportunity of recycling behaviour, with the most dominant barriers being difficulties accessing appropriate recycling bins and lack of information or education on recycling.

This overview of barriers and facilitators to hospital waste recycling will aid researchers and practitioners in designing hospital waste recycling interventions addressing key identified influences. Combining the COM-B model with a multi-level framework allowed for identified influences to be organised in a nuanced manner.

医院会产生大量废物,其中一部分是可回收的。然而,研究表明,医院经常错失回收机会,其中人的行为起了重要作用。根据当前的行为科学,更好地了解医院回收行为的影响因素可以支持设计有前景的行为改变干预措施,利用已确定的促进因素,帮助克服已确定的障碍,最大限度地发挥回收潜力。因此,本系统综述旨在调查医院废物回收利用的障碍和促进因素。我们搜索了三个数据库,以确定高收入国家有关医院废物回收利用障碍和促进因素的研究。结合能力、机会、动机-行为(COM-B)模型和多层次框架,对这些研究结果进行了专题分析和叙述性综合。据报道,影响医院废物回收利用的因素包括医院环境以外的因素(如阻碍回收利用的产品设计)、医院内部环境(如缺乏回收箱)和医院内部员工(如对感染控制的担忧)。大多数影响因素来自医院内部环境。关于医院废物回收的障碍和促进因素的概述将有助于研究人员和从业人员针对已确定的主要影响因素设计医院废物回收干预措施。将COM-B模型与多层次框架相结合,可以对已识别的影响因素进行细致的组织。
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引用次数: 0
The role of product design in advancing the circular economy of electric and electronic equipment 产品设计在推动电气和电子设备循环经济中的作用
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-02-29 DOI: 10.1016/j.rcradv.2024.200207
Juhoantti Köpman, Jukka Majava

Circular economy (CE) processes, such as reuse, remanufacturing, and recycling, play a significant role in reducing the environmental impacts of modern manufacturing industries. However, electric and electronic equipment (EEE) is still often designed to function for a short usable life after which it is discarded. Furthermore, the current relatively low price and high availability of virgin raw materials, compared to those of recycled materials, decrease the financial viability of recycling. This study conducts a systematic literature review on product design-related issues in the CE of EEE and induces a novel model of product design considerations for the CE of EEE. The aim is to identify design traits that are hindering the CE of EEE and what measures can be taken in the product development phase to create EEE compatible with CE. This study points out general issues in the disassemblability and recyclability of EEE, as well as a recurring theme of conflicting design needs between different CE processes. Furthermore, the minimum entropy product design priority model is introduced as the novel contribution of this study to highlight the dependency between technological maturity, expected product lifespan, and suitable CE processes.

循环经济(CE)流程,如再利用、再制造和再循环,在减少现代制造业对环境的影响方面发挥着重要作用。然而,电气和电子设备(EEE)在设计上仍然通常只有很短的使用寿命,之后就会被丢弃。此外,与回收材料相比,目前原生原材料的价格相对较低,可获得性较高,这降低了回收利用的经济可行性。本研究对电子电器产品消费电子中与产品设计相关的问题进行了系统的文献综述,并为电子电器产品消费电子的产品设计考虑因素建立了一个新模型。其目的是找出阻碍电子电气产品的消费电子化的设计特征,以及在产品开发阶段可采取哪些措施来创造与消费电子化兼容的电子电气产品。这项研究指出了电子电气设备在可拆卸性和可回收性方面存在的普遍问题,以及不同消费电子产品工艺之间设计需求冲突这一反复出现的主题。此外,本研究还引入了最小熵产品设计优先模型,以强调技术成熟度、预期产品寿命和合适的消费电子工艺之间的依赖关系。
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引用次数: 0
Heterogeneity analysis of carbon intensity influence factor and low carbon economy path in east of China 华东地区碳强度影响因素与低碳经济路径的异质性分析
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-02-27 DOI: 10.1016/j.rcradv.2024.200208
Miao He , Wei Xiao , Mouyuan Fan , Yuanlu Xu

This study expands the STIRPAT framework and utilizes mechanistic analysis and spatiotemporal heterogeneity analysis to examine the impact of market integration on carbon emission intensity and heterogeneity in East China. The findings reveal that market integrations play a significant role in reducing carbon emission intensity, and tax environment, urbanization, and consumption power prove to be important mechanism factors. The average treatment effect of industrial structure and energy structure also positively promotes emission reduction efforts. However, market integration coupling coordination degree, technology level, and the gap in high-quality development act as inhibiting factors on carbon emission intensity. Furthermore, the spatial and temporal heterogeneous evolution trend demonstrates distinct and evident agglomeration patterns among economic regions. To effectively leverage the unified large market mechanism to reduce carbon emission intensity, it is essential to consider the regional characteristics of different influencing factors and also focus on the role of important node cities in driving emission reduction efforts.

本研究拓展了 STIRPAT 框架,利用机理分析和时空异质性分析,考察了市场一体化对华东地区碳排放强度和异质性的影响。研究结果表明,市场一体化对降低碳排放强度具有重要作用,而税收环境、城镇化和消费能力被证明是重要的机制因素。产业结构和能源结构的平均处理效应也积极促进了减排努力。然而,市场一体化耦合协调程度、技术水平、高质量发展差距则是碳排放强度的抑制因素。此外,时空异质性演化趋势也显示出经济区域间不同的、明显的集聚模式。要有效利用统一大市场机制降低碳排放强度,必须考虑不同影响因素的区域特征,同时注重重要节点城市对减排工作的带动作用。
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引用次数: 0
Properties, production, and modification of polyhydroxyalkanoates 聚羟基烷酸酯的特性、生产和改性
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-02-19 DOI: 10.1016/j.rcradv.2024.200206
Xiangmin Liang , Daniel K. Cha , Qingqing Xie

Polyhydroxyalkanoates (PHAs) are polymers synthesized by diverse bacteria for carbon and energy storage applications. PHAs are biodegradable and nontoxic. They also exhibit properties similar to those of petroleum-based polymers. Therefore, these materials are promising alternatives to conventional plastics. This review aims to provide a comprehensive overview of PHA research, from production to application. This review summarizes the thermal and mechanical properties of various PHA homopolymers and copolymers, and compares them with those of common petroleum-based polymers. This comparison indicates that elongation at break is a major weakness of many PHAs. Different organic wastes used in PHA microbial production by mixed culture fermentation are summarized in this review. Important parameters of feedstock fermentation, culture selection, and PHA accumulation were compared. The pH and organic loading rate significantly affected the overall PHA yield, and various feedstocks led to different PHA compositions. Physical (blending and fiber reinforcement) and biological (cofeeding) modifications to improve the mechanical properties of PHA are elaborated in this review. Tensile properties are the major improvements among the mechanical properties after modification. Current applications of PHA and its derivatives are also presented in this work. They are primarily applied in the medicine, agriculture, and packaging industries. The widespread application of PHA faces challenges such as high production costs and limited mechanical properties. This study intends to stimulate further research into cost-effective methods for PHA production and to explore additional modification techniques.

聚羟基烷酸酯(PHA)是由多种细菌合成的聚合物,可用于碳储存和能量储存。PHAs 可生物降解且无毒。它们还具有与石油基聚合物相似的特性。因此,这些材料有望成为传统塑料的替代品。本综述旨在全面概述从生产到应用的 PHA 研究。本综述总结了各种 PHA 均聚物和共聚物的热性能和机械性能,并与常见的石油基聚合物进行了比较。比较结果表明,断裂伸长率是许多 PHA 的主要弱点。本综述总结了混合培养发酵法生产 PHA 微生物时使用的不同有机废物。比较了原料发酵、培养物选择和 PHA 积累的重要参数。pH 值和有机物负载率对 PHA 的总体产量有显著影响,不同的原料会产生不同的 PHA 组成。本综述阐述了通过物理(混合和纤维增强)和生物(共饲)改良 PHA 机械性能的方法。拉伸性能是改性后机械性能的主要改进。本文还介绍了 PHA 及其衍生物的当前应用。它们主要应用于医药、农业和包装行业。PHA 的广泛应用面临着生产成本高和机械性能有限等挑战。本研究旨在促进对 PHA 生产成本效益方法的进一步研究,并探索更多改性技术。
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引用次数: 0
Industry hybrid regulation: Exploring a model for business-driven circular economy 行业混合监管:探索企业驱动的循环经济模式
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-02-18 DOI: 10.1016/j.rcradv.2024.200205
Hadi Chapardar

Government is often seen as the arbiter for environmental protection. Alternatively, firms can volunteer to proactively take collective action toward sustainability, called industry self-regulation. But, what happens when neither of the two alternatives can deliver the expected outcomes? This inductive study addresses such a situation in managing hazardous consumer waste in the province of Ontario, Canada, where waste management and later circular economy have been on the agenda since the 1980s. However, both self- and government regulation failed to spur the advancements required to close material loops effectively and efficiently. Finally, after three decades, actors developed a new path to transition to circular economy. This longitudinal process study focuses on this process to explore the changes in business-policy interactions that realized this transition. I analyze extensive qualitative data, including 55 interviews with top-level decision-makers in all stakeholder groups (businesses, policy-makers, NGOs, consultants, etc.). Based on the unearthed patterns, I propose a hybrid model for regulation. In this model, both business and government coordinate throughout the process to set the rules and enforce them. By allowing organically shaped competition, this model can spur proactivity and innovation, which are crucial for the transition to circular economy but are hard to incentivize in conventional policy-making. The model can be used in any situation where an urgent issue needs immediate proactive responses by business.

政府通常被视为环境保护的仲裁者。另外,企业也可以自愿采取集体行动,实现可持续发展,这就是所谓的行业自律。但是,当这两种选择都无法实现预期结果时,会发生什么呢?这项归纳式研究针对的就是加拿大安大略省在管理有害消费废物时遇到的这种情况,该省自 20 世纪 80 年代起就将废物管理和循环经济提上了议事日程。然而,自我监管和政府监管都未能推动有效和高效地关闭材料循环所需的进步。终于,在三十年后,行动者们开发出了一条向循环经济转型的新道路。本纵向过程研究聚焦于这一过程,以探索实现这一转变的企业与政策互动的变化。我分析了大量定性数据,包括与所有利益相关者群体(企业、政策制定者、非政府组织、顾问等)的高层决策者进行的 55 次访谈。根据所发现的模式,我提出了一种混合监管模式。在这种模式中,企业和政府在整个过程中相互协调,共同制定规则和执行规则。通过允许有机形成的竞争,这种模式可以刺激主动性和创新性,这对于向循环经济转型至关重要,但在传统的政策制定中却难以激励。该模式可用于任何需要企业立即积极应对紧急问题的情况。
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引用次数: 0
Utilization of high-volume fly ash in pervious concrete mixtures for mangrove conservation 在透水混凝土混合物中利用高体积粉煤灰保护红树林
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-02-08 DOI: 10.1016/j.rcradv.2024.200204
Januarti Jaya Ekaputri , Xevna De Elshinta Arellsya Ruitan , Himawan Tri Bayu Murti Petrus , Martin Anda , Liliek Harmianto Purbawinasta , Irwanda Laory , Davin H.E. Setiamarga , Nobuhiro Chijiwa , Chikako Fujiyama

In environmental conservation, mangrove forests play a crucial role. Retransplanting mangrove propagules, however, faces challenges, and success rates are notably low. Achieving an optimal protector for propagules, balancing strength without impeding growth, is challenging. Mangrove propagules require a temporary protector with an optimal balance, neither too weak nor too strong, to shield them from current waves which is difficult. We propose using pervious concrete pots with high-volume fly ash activated with low NaOH concentrations. The investigation focuses on the influence of the mixing procedure on workability, compressive strength, and mineral composition. The novel discovery in this study is the specific sequence of stirring the ingredients using an alkali activator, which adds an interesting dimension to the research. It is recommended to adopt Sequence 2 in pervious concrete production, where NaOH dissolved FA in the mixture forming albite as N-A-S-H gel product. It surely enhanced both workability and the strength confirming uniform application processes. The two recommended variants, PFS-60 and PFBS-50, effectively utilize coal ash, meeting the target compressive strength range of 3–5 MPa and providing support for mangrove pots over a 3–4 year period. Notably, both compositions maintained consistent mechanical properties during exposure to tidal conditions for 240 days.They exhibit high permeability (694 liter/m²/minute), facilitating efficient water passage without sediment entrainment.

在环境保护方面,红树林发挥着至关重要的作用。然而,重新移植红树林繁殖体面临挑战,成功率明显偏低。如何为繁殖体提供最佳保护,既能兼顾强度,又不妨碍生长,是一项挑战。红树林繁殖体需要一个具有最佳平衡的临时保护器,既不能太弱也不能太强,以抵御当前的波浪,但这是很难做到的。我们建议使用透水混凝土盆,其中含有用低浓度 NaOH 活化的高容量粉煤灰。调查的重点是混合程序对工作性、抗压强度和矿物成分的影响。本研究的新发现是使用碱活化剂搅拌配料的特定顺序,这为研究增添了一个有趣的维度。建议在透水混凝土生产中采用序列 2,即 NaOH 在混合物中溶解 FA,形成白云石作为 N-A-S-H 凝胶产物。这无疑提高了工作性和强度,确认了均匀的应用过程。推荐的两种变体 PFS-60 和 PFBS-50 有效地利用了煤灰,达到了 3-5 兆帕的抗压强度目标范围,并在 3-4 年的时间内为红树林提供了支撑。值得注意的是,这两种材料在潮汐条件下暴露 240 天后仍能保持稳定的机械性能。它们具有很高的渗透性(694 升/平方米/分钟),有利于水的有效通过,不会夹带沉积物。
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引用次数: 0
Advancing environmental assessment of the circular economy: Challenges and opportunities 推进循环经济的环境评估:挑战与机遇
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-01-15 DOI: 10.1016/j.rcradv.2024.200203
Dwarakanath Ravikumar , Gregory A. Keoleian , Julien Walzberg , Garvin Heath , Martin C. Heller

The lifecycle assessment (LCA) framework is widely applied to comprehensively evaluate and improve the environmental performance of a circular economy (CE). The advances and application of LCA has been primarily restricted to evaluate the environmental performance of the CE at a micro-level, wherein the CE is implemented for a single product system.

However, the CE can be operationalized at two broader levels: the meso–level (for eco-industrial parks) and the macro-level (for a city, state, or nation). Six methodological challenges emerge when applying LCA to a meso‑ or macro-level CE and remain unaddressed in the existing literature. This includes: selecting a relevant system boundary and functional unit, addressing data paucity and uncertainty, accounting for stakeholder behavior, assessing the trade-offs from renewable energy (RE) use, accounting for manufacturing and technology evolution, and quantifying displacement and rebound. This article proposes potential solutions and research priorities to address the above challenges.

生命周期评估(LCA)框架被广泛应用于全面评估和改善循环经济(CE)的环境绩效。生命周期评估的进展和应用主要局限于在微观层面评估循环经济的环境绩效,即针对单一产品系统实施循环经济。然而,循环经济可以在两个更广泛的层面上运作:中观层面(生态工业园区)和宏观层面(城市、州或国家)。在将生命周期评估应用于中观或宏观层面的生态工业园区时,会出现六个方法上的挑战,而现有文献尚未解决这些挑战。这包括:选择相关的系统边界和功能单元、解决数据匮乏和不确定性、考虑利益相关者的行为、评估可再生能源(RE)使用的权衡、考虑制造和技术演进以及量化替代和反弹。本文提出了应对上述挑战的潜在解决方案和研究重点。
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引用次数: 0
The 21 most practiced RE-s of circular economy from LinkedIn company profiles on a global scale 从 LinkedIn 全球公司简介看循环经济最实用的 21 个 RE-s
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2024-01-10 DOI: 10.1016/j.rcradv.2024.200202
Georgios Tsironis , Theodoros Daglis , Konstantinos P. Tsagarakis

LinkedIn is a social media networking platform that provides users with publicly available data related to user and company profiles, job advertisements, groups, events, services, etc. The main feedback on the organizational trends around the Circular Economy (CE) has been mostly based on corporate reports and survey analytics while there are huge data volumes available online. This article aims to deliver valuable insights regarding global CE business activities. Those insights arise from data extracted οut of 7533 companies’ profiles on LinkedIn, containing the term CE in any profile section. Some significant findings include the companies’ geographical distribution (headquarters), the different industry sectors, each company's number of employees, followers, and foundation year. The last shows a significant increase in new CE companies over the last decade. Additionally, our work focuses on companies’ specialties and descriptions, which provide each organization's business activities and specialization. Finally, we investigated the presence of already studied and new Re- strategies, complemented by their most important interactions which undeniably indicate the dominance of the reuse-reduce-recycle triptych.

LinkedIn 是一个社交媒体网络平台,为用户提供与用户和公司简介、招聘广告、群组、活动、服务等相关的公开数据。有关循环经济(CE)组织趋势的主要反馈信息大多基于企业报告和调查分析,而在线数据量巨大。本文旨在提供有关全球 CE 业务活动的宝贵见解。这些洞察力来自 LinkedIn 上 7533 个公司简介中的数据,这些公司简介的任何部分都包含 CE 一词。一些重要发现包括公司的地理分布(总部)、不同的行业领域、每家公司的员工数量、关注者数量和成立年份。最后一项结果表明,在过去十年中,新成立的 CE 公司数量大幅增加。此外,我们的工作重点还放在公司的专业和描述上,它们提供了每个组织的业务活动和专业化程度。最后,我们对已研究过的和新的 Re- 战略进行了调查,并对其最重要的相互作用进行了补充,这无可否认地表明了再利用-再减少-再循环三部曲的主导地位。
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引用次数: 0
Agent-based simulation for technology implementation in an energy-based industrial symbiosis network 基于能源的工业共生网络中技术实施的代理模拟
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-12-30 DOI: 10.1016/j.rcradv.2023.200201
Zohre Saghafi, Ramin Roshandel

Agent-based modeling is a promising approach in industrial symbiosis (IS) simulation due to its bottom-up approach. However, the role of implementing feasible technologies in agent-based modeling of IS has been underexplored. In this paper, an agent-based model was developed to optimize the economic benefits of IS stakeholders in a case study region. Feasible technologies were integrated into the proposed model to generate additional economic profit and enhance circularity. The model was implemented on a case study involving a chicken farm, cow farm, dairy, edible oil plant, and a Combined Heat and Power (CHP) plant. Technologies including anaerobic digestion, organic Rankine cycle, heat pump, and membrane separation were employed to produce biogas, recover waste heat, and purify wastewater. While the fossil-based energy consumed by industries reduced, all the waste streams could be recovered. The techno-economic specifications of these technologies had a significant impact on the symbiotic relationships.

基于代理的建模因其自下而上的方法而成为工业共生(IS)模拟的一种有前途的方法。然而,在基于代理的工业共生建模中实施可行技术的作用还未得到充分探索。本文开发了一个基于代理的模型,以优化案例研究区域中 IS 利益相关者的经济效益。可行的技术被整合到拟议的模型中,以产生额外的经济利润并增强循环性。该模型是在一个案例研究中实施的,涉及养鸡场、奶牛场、奶制品厂、食用油厂和热电联产(CHP)厂。采用了厌氧消化、有机郎肯循环、热泵和膜分离等技术来生产沼气、回收废热和净化废水。在工业消耗的化石能源减少的同时,所有废物流均可回收。这些技术的技术经济规格对共生关系产生了重大影响。
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引用次数: 0
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