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Optimized Acidic Sites Distribution for Selective Synthesis of Alkylated Decalins over Acid-Treated Ru/HZSM-5 优化酸性位点分布,在酸处理过的 Ru/HZSM-5 上选择性合成烷基癸醛
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S003602442470136X
Guiling Wu, Wenli Zhao, Xinyue Yang, Xiaopo Niu, Zhen Guo, Danni Liu, Qingfa Wang

Producing high-density fuel of alkylated decalins from hydrodeoxygenation (HDO) of naphthalene derivatives is an environmentally friendly but still challenging method. Herein, a bifunctional Ru/HZSM-5 catalyst was fabricated by acid treatment (citric acid, oxalic acid, nitric acid) to effectively synthesize the alkylated decalins via HDO of naphthalene derivative. Acid treatment adjusted the acidic site distribution of Ru/HZSM-5. Nitric acid treatment (NA) resulted in more abundance of weak acidic sites which was beneficial for the dehydration process in HDO, and the lowest ratio of BAS/LAS to promote the hydrogenation of alkylated octalins, the rate-determining step of HDO. NA-treated Ru/HZSM-5 showed the highest HDO activity with the highest selectivity of 1,2-dimethyldecalin (74%). Besides, it also presents good HDO activity of naphthalene derivatives to produce high-density hydrocarbons. Therefore, Ru/HZ5-NA is a promising catalyst for the production of alkylated decalins and other high-value biofuels and chemicals.

摘要利用萘衍生物的加氢脱氧反应(HDO)生产高密度烷基化癸醛燃料是一种环境友好型方法,但仍具有挑战性。本文通过酸处理(柠檬酸、草酸、硝酸)制备了双功能 Ru/HZSM-5 催化剂,通过萘衍生物的加氢脱氧有效合成了烷基化癸醛。酸处理调整了 Ru/HZSM-5 的酸性位点分布。硝酸处理(NA)使弱酸性位点更加丰富,有利于 HDO 的脱水过程,同时使 BAS/LAS 的比例最低,从而促进了烷基化癸精的氢化,这是 HDO 的决定性步骤。经过 NA 处理的 Ru/HZSM-5 具有最高的 HDO 活性,对 1,2-二甲基萘烷的选择性最高(74%)。此外,它对生产高密度烃的萘衍生物也具有良好的 HDO 活性。因此,Ru/HZ5-NA 是生产烷基化癸醛及其他高价值生物燃料和化学品的一种前景广阔的催化剂。
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引用次数: 0
Photocatalytic Destruction of Ceftriaxone in Aqueous Solutions 光催化破坏水溶液中的头孢曲松
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701395
M. R. Sizykh, A. A. Batoeva, K. D. Alekseev

The kinetic tendencies in the destruction of cephalosporin antibiotics (ceftriaxone (CEF)) in photoinitiated oxidative systems were studied using a xenon lamp as a source of quasisolar radiation (UV–Vis). It was established that the oxidative systems under study can be arranged in the following series according to the efficiency and rate of antibiotic destruction: {UV–Vis/Fe2+/S2O(_{8}^{{2 - }})} > {Fe2+/S2O(_{8}^{{2 - }})} ( gg ) {UV–Vis/S2O(_{8}^{{2 - }})} > {UV–Vis}. The optimum conditions for the oxidative destruction of CEF in the {UV–Vis/Fe2+/S2O(_{8}^{{2 - }})} system are reached at [S2O(_{8}^{{2 - }})] : [CEF] = 30 : 1 and [S2O(_{8}^{{2 - }})] : [Fe2+] = 1 : 0.1. As the temperature increases to 40°C, the initial CEF oxidation rate and efficiency increase. The apparent activation energy of the CEF oxidation in the {UV–Vis/Fe2+/S2O(_{8}^{{2 - }})} system was 45 kJ mol–1, which is comparable to the values obtained for cephalosporin antibiotics. It was proved, using inhibitors of radical reactions, that the oxidative destruction of CEF in combined {UV–Vis/Fe2+/S2O(_{8}^{{2 - }})} proceeds by a multiradical mechanism involving reactive oxygen species (ROS): hydroxyl radicals and sulfate and superoxide radical anions. The obtained tendencies are in good agreement with the results of open-air studies with natural solar radiation; in the {Solar/Fe2+/S2O(_{8}^{{2 - }})} system, the oxidation of CEF is significantly intensified due to combined activation of persulfate by the iron ions, the UV-C (<300 nm) component of natural solar radiation, and the thermal exposure. The results indicate that using the combined {Solar/Fe2+/S2O(_{8}^{{2 - }})} oxidation system is promising for the destruction of antibiotics in order to reduce their release into the environment.

摘要 以氙灯作为准太阳辐射源(紫外可见光),研究了头孢菌素类抗生素(头孢曲松(CEF))在光引发氧化体系中的破坏动力学趋势。结果表明,根据抗生素破坏的效率和速度,所研究的氧化体系可分为以下系列:{UV-Vis/Fe2+/S2O(_{8}^{2 - }}} > {Fe2+/S2O(_{8}^{2 - }})} ( gg ) {UV-Vis/S2O(_{8}^{2 - }}} > {UV-Vis}。在{UV-Vis/Fe2+/S2O/(_{8}^{2 - }})} 系统中,[S2O/(_{8}^{2 - }})] : [CEF] = 30 : 1 和 [S2O(_{8}^{2 - }})] : [Fe2+] = 1 : 0.1 是 CEF 氧化破坏的最佳条件。当温度升高到 40°C 时,CEF 的初始氧化速率和效率都会增加。在{UV-Vis/Fe2+/S2O/(_{8}^{{2 - }})}体系中,CEF 氧化的表观活化能为 45 kJ mol-1,与头孢菌素类抗生素得到的数值相当。利用自由基反应抑制剂证明,在组合{UV-Vis/Fe2+/S2O/(_{8}^{{2 - }})} 中,CEF 的氧化破坏是通过多自由基机制进行的,其中涉及活性氧(ROS):羟自由基、硫酸根和超氧自由基阴离子。所获得的趋势与利用天然太阳辐射进行露天研究的结果非常一致;在{Solar/Fe2+/S2O(_{8}^{2 - }})}系统中,由于铁离子、天然太阳辐射中的紫外线-C(<300 nm)成分和热暴露共同激活了过硫酸盐,CEF 的氧化作用显著增强。结果表明,使用{Solar/Fe2+/S2O/(_{8}^{2 - }})} 组合氧化系统有望破坏抗生素,从而减少其在环境中的释放。
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引用次数: 0
Volume Effects in Interactions between L-Histidine and Pyridine Monocarboxylic Acid Isomers in an Aqueous Buffer Solution L 组氨酸和吡啶单羧酸异构体在水缓冲溶液中相互作用的体积效应
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701401
E. Yu. Tyunina, G. N. Tarasova, I. N. Mezhevoi, D. R. Stavnova

Densimetry is used to study the interaction between L-histidine (His) and nicotinic (NA), isonicotinic (INA), and picolinic acids (PA) in an aqueous buffer solution in the 288.15–313.15 K range of temperatures. Data on density are used to determine the apparent molar volumes and limiting apparent molar volumes of pyridine monocarboxylic acid (PyCOOH) isomers at infinite dilution, along with their temperature derivatives in a buffer solution containing the amino acid. Unlike the linear concentration dependences of the apparent molar volume of PyCOOH isomers in a buffer solution, the analogous dependences of ternary systems (PyCOOH–His–buffer) are nonlinear, indicating the formation of a molecular complex between the solutes. Limiting apparent molar expansibilities and their temperature derivatives are determined. Their values suggest that the ordering of the solvent grows in the series of isomers PA → NA → INA upon adding the amino acid to a buffer solution of PyCOOH. It is shown that the limiting apparent molar volumes of transferring PyCOOH from a buffer to a His-containing buffer solution have positive values and grow in the studied range of temperatures. The discussion of the results is based on the dominant types of molecular interactions between the solute and solvent using the Gurney model.

摘要密度测量法用于研究 L-组氨酸(His)与烟酸(NA)、异烟酸(INA)和皮考林酸(PA)在水缓冲溶液中的相互作用,温度范围为 288.15-313.15 K。密度数据用于确定无限稀释时吡啶单羧酸(PyCOOH)异构体的表观摩尔体积和极限表观摩尔体积,以及它们在含有氨基酸的缓冲溶液中的温度衍生物。与 PyCOOH 异构体在缓冲溶液中的表观摩尔体积的线性浓度依赖关系不同,三元系统(PyCOOH-His-缓冲溶液)的类似依赖关系是非线性的,表明溶质之间形成了分子复合物。我们测定了极限表观摩尔膨胀率及其温度导数。它们的值表明,在 PyCOOH 缓冲溶液中加入氨基酸后,溶剂的有序性在 PA → NA → INA 的异构体系列中增长。研究表明,将 PyCOOH 从缓冲溶液转移到含 His 的缓冲溶液的极限表观摩尔体积为正值,并在研究的温度范围内增长。对结果的讨论基于使用 Gurney 模型的溶质和溶剂之间的主要分子相互作用类型。
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引用次数: 0
Pillaring 2D Mordenite with TiO2 Nanoparticles 用二氧化钛纳米颗粒填充二维莫来石
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701450
M. G. Shelyapina, R. I. Yocupicio-Gaxiola, G. A. Val’kovskii, Yu. Kotolevich, V. Petranovskii

A series of new composites have been synthesized—TiO2 nanoparticles introduced in the interlayer space of layered mordenite. The effect of the hydrolysis medium of titanium tetraethoxide (water or a mixture of water with ethanol) and hydrolysis time (from 6 to 24 h) on the properties and texture of the composite was studied. Treatment in ethanol leads to partially preserved ordered layered structure of 2D mordenite, presumably due to the slowdown of the hydrolysis of titanium tetraethoxide; this, in turn, provides higher mesoporosity after calcination, created by anatase nanoparticles of ~4 nm in the interlayer space. Immobilization of TiO2 on the zeolite surface is indicated by the formation of Si–O–Ti bonds.

摘要 合成了一系列新型复合材料--在层状莫来石的层间空间中引入了纳米二氧化钛颗粒。研究了四氧化钛水解介质(水或水与乙醇的混合物)和水解时间(6 至 24 小时)对复合材料性能和质地的影响。在乙醇中处理可部分保留二维莫来石的有序层状结构,这可能是由于四氧化钛的水解速度减慢所致;这反过来又在煅烧后提供了更高的介孔率,由层间空间中约 4 纳米的锐钛型纳米颗粒形成。Si-O-Ti键的形成表明二氧化钛固定在沸石表面。
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引用次数: 0
Design of Three-Dimensional Nickel Foam/Carbon Fiber Composite Supported Nickel–Cobalt Hydroxides for High-Performance Supercapacitor Electrode Materials 设计用于高性能超级电容器电极材料的三维镍泡沫/碳纤维复合支撑镍钴氢氧化物
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701541
Yanyan Feng, Mingjing Cao, Yaping Zhou, Yan Wang, Wen Yang

Hydroxides of nickel-cobalt have been widely employed as supercapacitor electrode materials. However, the shortcomings such as a low specific surface and an unstable structure made it difficult to display an excellent electrochemical performance. To address the said problems, carbon fibers were grown in situ on foam nickel by CVD method to prepare a three-dimensional foam nickel/carbon fiber composite collector, and then nickel-cobalt hydroxides were obtained on the composite current collector by a hydrothermal method with the aim of a superior supercapacitor electrode material (CF/Ni–Co). Effects of anions of metal salts (such as acetate, nitrate, sulfate and chloride) on the morphology, structure and electrochemical performance of the obtained electrodes were investigated. The results suggested that the sample CF/Ni–Co(SO4) synthesized with nickel sulfate and cobalt sulfate possessed large specific surface area. It also displayed outstanding capacitive performance with a superb specific capacitance of 3675.6 F/g at 1 A/g, a high capacitance retention rate of 70.6% as the current density increased to 15 A/g, and a good cycling stability of 66.4% after 2000 cycles of charge-discharge at 15 A/g, demonstrating CF/Ni–Co(SO4) with the three-dimensional nickel foam/carbon fiber composite as current collector had great potential for high-performance supercapacitor electrode materials.

摘要 镍钴氢氧化物已被广泛用作超级电容器电极材料。然而,由于比表面小、结构不稳定等缺点,其难以发挥优异的电化学性能。针对上述问题,研究人员采用 CVD 法在泡沫镍上原位生长碳纤维,制备出三维泡沫镍/碳纤维复合集流体,然后采用水热法在复合集流体上获得镍钴氢氧化物,从而制备出性能优异的超级电容器电极材料(CF/Ni-Co)。研究了金属盐阴离子(如醋酸盐、硝酸盐、硫酸盐和氯化物)对所获电极的形貌、结构和电化学性能的影响。结果表明,用硫酸镍和硫酸钴合成的 CF/Ni-Co(SO4) 样品具有较大的比表面积。它还显示出优异的电容性能,在 1 A/g 条件下,比电容高达 3675.6 F/g;当电流密度增加到 15 A/g 时,电容保持率高达 70.6%;在 15 A/g 条件下充放电循环 2000 次后,循环稳定性高达 66.4%,这表明以三维泡沫镍/碳纤维复合材料为集流体的 CF/Ni-Co(SO4) 具有作为高性能超级电容器电极材料的巨大潜力。
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引用次数: 0
Heat Capacity of Acetone and Its Aqueous Solutions at High Temperatures and Pressures 丙酮及其水溶液在高温高压下的热容量
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701413
Z. I. Zaripov, R. R. Nakipov, S. V. Mazanov, F. M. Gumerov

The isobaric heat capacities of acetone and its binary aqueous solutions were measured using a heat capacity meter (IT-s-400). The measurements were performed at temperatures from 323.15 to 453.15 K and pressures below 19.6 MPa for acetone and at temperatures from 348.15 to 473.15 K and the same pressures for its solutions, at concentrations of 2.5, 3.5, and 5 wt % acetone. The expanded uncertainty of heat capacity, pressure, temperature, and concentration measurements at a 95% confidence level with a coverage factor k = 2 was estimated at 2.4%, 0.05%, 15 mK, and 0.001, respectively. The results were compared with the literature data in the given ranges of state parameters.

摘要 使用热容量计(IT-s-400)测量了丙酮及其二元水溶液的等压热容量。丙酮的测量是在 323.15 至 453.15 K 的温度和 19.6 MPa 以下的压力下进行的,丙酮溶液的测量是在 348.15 至 473.15 K 的温度和相同的压力下进行的,丙酮的浓度分别为 2.5、3.5 和 5 wt %。在覆盖因子 k = 2 的 95% 置信度下,热容量、压力、温度和浓度测量的扩展不确定度分别估计为 2.4%、0.05%、15 mK 和 0.001。结果与给定状态参数范围内的文献数据进行了比较。
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引用次数: 0
New Correlation of the Temperature-Dependent Thermal Conductivity of Binary Saturated Refrigerants Mixtures 二元饱和制冷剂混合物随温度变化的热导率的新相关性
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701437
Yanmeng Lv, Jianxiang Tian, Hua Jiang

In this paper, we utilize the REFPROP database and establish a new correlation between the temperature and the thermal conductivity of binary saturated refrigerants mixtures. Not only have we achieved a uniform set of parameters for each mixtures group at different ratios, but we have also considered the effect of the temperature T on the thermal conductivity ({{lambda }_{m}}) of the binary saturated refrigerants mixtures. The calculated results are compared with the data from the REFPROP database. The average absolute deviations (AADs) are computed. The majority of AADs are found to be less than 0.5% for all the cases considered. When compared to previously published correlations, this correlation better predicts the thermal conductivity of binary saturated refrigerants mixtures and will be useful for the future researches related to the heat dissipation engineering and engineering technology.

摘要 本文利用 REFPROP 数据库,建立了二元饱和制冷剂混合物的温度与导热系数之间的新关联。我们不仅为每组不同比例的混合物设定了统一的参数,还考虑了温度 T 对二元饱和制冷剂混合物热导率 ({{lambda }_{m}})的影响。计算结果与 REFPROP 数据库中的数据进行了比较。计算了平均绝对偏差(AADs)。结果发现,在所有情况下,平均绝对偏差都小于 0.5%。与之前公布的相关性相比,该相关性更好地预测了二元饱和制冷剂混合物的导热性,将有助于未来与散热工程和工程技术相关的研究。
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引用次数: 0
Sorption of Triterpene Glycoside on Different Brands of Active Carbon 三萜苷在不同品牌活性炭上的吸附作用
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701486
N. V. Mironenko, V. F. Selemenev, I. V. Shkutina, U. S. Ishchenko

The sorption of triterpene saponins is studied on different brands of active carbon under equilibrium conditions. The effect the surface activity of glycosides has on the course of the curves is established. Sorption isotherms are assessed using a formal approach based on selecting the sorption equations (Langmuir, Freundlich, BET, Redlich–Peterson) that describe the obtained dependences as closely as possible. Thermodynamic characteristics of the given process (energy of sorption, enthalpy, and entropy) are calculated using sorption curves in the coordinates of the Langmuir equation.

摘要 在平衡条件下,研究了三萜皂苷在不同品牌活性碳上的吸附情况。确定了苷的表面活性对曲线走向的影响。吸附等温线的评估采用了一种正式的方法,该方法基于选择尽可能接近地描述所得依赖关系的吸附方程(Langmuir、Freundlich、BET、Redlich-Peterson)。利用 Langmuir 方程坐标中的吸附曲线计算给定过程的热力学特征(吸附能、焓和熵)。
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引用次数: 0
Sol–Gel Synthesis of C3N4-Decorated AlFeO3 Photocatalyst and Environmental Purification of Methyl Orange Wastewater C3N4-Decorated AlFeO3 光催化剂的溶胶-凝胶合成及甲基橙废水的环境净化
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701553
Jianmin Li, Yongjun He, Yang Zhao

The C3N4/AlFeO3 photocatalysts were synthesized successfully via a sol-gel route and low temperature calcination process. When C3N4 is coupled with AlFeO3 to form a special heterojunction, the crystal structure, composition and optical band gap of the main lattice phase are not changed. However, its surface morphology, optical absorption coefficient and photocatalytic activity are greatly improved compared with pure C3N4 and AlFeO3. Photocatalytic experiments confirmed that the C3N4/AlFeO3 photocatalyst showed high photocatalytic activity for degradation of methyl orange under visible light irradiation, and its degradation rate was 9.40 times that of C3N4 and 5.13 times that of AlFeO3. The optimal catalyst content, dye concentration and pH value are 1 g/L, 20 mg/L and 5, respectively. Capture and stability experiments confirmed that the C3N4/AlFeO3 photocatalyst is recyclable, and holes, hydroxyl radicals and superoxide radicals are the main active species in the photocatalysis process.

摘要 通过溶胶-凝胶路线和低温煅烧工艺成功合成了C3N4/AlFeO3光催化剂。当 C3N4 与 AlFeO3 耦合形成特殊异质结时,主晶格相的晶体结构、组成和光带隙均未发生变化。然而,与纯 C3N4 和 AlFeO3 相比,其表面形貌、光吸收系数和光催化活性都得到了极大改善。光催化实验证实,C3N4/AlFeO3 光催化剂在可见光照射下降解甲基橙具有很高的光催化活性,其降解率是 C3N4 的 9.40 倍,AlFeO3 的 5.13 倍。最佳催化剂含量、染料浓度和 pH 值分别为 1 g/L、20 mg/L 和 5。捕获和稳定性实验证实,C3N4/AlFeO3 光催化剂是可回收的,空穴、羟基自由基和超氧自由基是光催化过程中的主要活性物种。
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引用次数: 0
Quantum Chemical Study, In Silico ADMET Profile Analysis, Molecular Docking, and MD Simulation of 5-(Furan-2-ylmethylidene) thiazolo[3,4-a] benzimidazole-2-thione 5-(呋喃-2-亚甲基)噻唑并[3,4-a]苯并咪唑-2-硫酮的量子化学研究、硅烷 ADMET 特征分析、分子对接和 MD 模拟
IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL Pub Date : 2024-09-11 DOI: 10.1134/S0036024424701577
Youcef Megrouss, Salem Yahiaoui, Mansour Azayez, Chafika Farah Kaouche, Zohra Douaa Benyahlou, Sid Ahmed Kaas, Mokhtaria Drissi, Abdelkader Chouaih

In the current study, the most stable optimized structure of the named compound 5-(furan-2-ylmethylidene) thiazolo[3,4-a] benzimidazole-2-thione (FThBZ) was determined using the B3LYP/6-311++G(d,p) basis set. The nature of molecular interactions between molecules in the crystal via different type of bonds was investigated using Lattice Energy analysis and non-covalent reduced density gradient (NC-RDG) and Fukui functions are performed to study the chemical reactivity of the compound. The dipole moment values, first and second order polarizability and hyperpolarizability of the title compound were calculated. A symptom of Alzheimer’s is the appearance of amyloid plaques, or senile plaques: made up of aggregates of beta-amyloid peptide between nerve cells. To overcome this effect, there is a need for a potent and effective inhibitor that inhibits the proper functioning of amyloid precursor protein (APP). In this regard, we conducted an in silico docking and molecular dynamics simulation study.

摘要 在本研究中,利用 B3LYP/6-311++G(d,p) 基集确定了 5-(呋喃-2-基亚甲基)噻唑并[3,4-a] 苯并咪唑-2-硫酮(FThBZ)这一命名化合物最稳定的优化结构。利用晶格能分析和非共价还原密度梯度(NC-RDG)及福井函数研究了晶体中分子间通过不同类型的键相互作用的性质,从而研究了该化合物的化学反应性。计算了标题化合物的偶极矩值、一阶和二阶极化率以及超极化率。阿尔茨海默氏症的症状之一是出现淀粉样斑块或老年斑:由神经细胞间的β-淀粉样肽聚集而成。为了克服这种影响,需要一种能抑制淀粉样前体蛋白(APP)正常运作的强效抑制剂。为此,我们进行了一项硅对接和分子动力学模拟研究。
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引用次数: 0
期刊
Russian Journal of Physical Chemistry A
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