Pub Date : 2024-08-02DOI: 10.1007/s11433-024-2417-8
Xinrun Mi, De Hou, Xiao Wang, Sabreen Hammouda, Caixing Liu, Zijian Xiong, Han Li, Yan Liu, Guiwen Wang, Aifeng Wang, Yisheng Chai, Yang Qi, Wei Li, Xiaoyuan Zhou, Yixi Su, D. I. Khomskii, Mingquan He, Zhigao Sheng, Young Sun
The spin-orbit assisted Mott insulator α-RuCl3 is a prime candidate for material realization of the Kitaev quantum spin liquid. While little attention has been paid to charge degrees of freedom, charge effects, such as electric polarization, may arise in this system. Here, we report distortion-induced local electric polarization in α-RuCl3 as evidenced by single-crystal X-ray diffraction, second harmonic generation (SHG) and dielectric measurements. The SHG signal appears at room temperature and develops substantially in the Kitaev paramagnetic state when short-range spin correlations come into play. Despite sizable pyroelectric currents in the Kitaev paramagnetic state, the absence of hysteresis in the polarization-electric field (P-E) points to the short-range nature of electric polarization. This localized electric polarization is likely the result of distortion-induced charge dimerization, achieved through virtual hopping-induced charge redistribution. In addition, the electric polarization is boosted by short-range spin correlations via spin-phonon coupling in the Kitaev paramagnetic state. Our results emphasize the importance of charge degrees of freedom in α-RuCl3, which establish a novel platform to investigate charge effects in Kitaev materials.
自旋轨道辅助莫特绝缘体 α-RuCl3 是实现基塔耶夫量子自旋液体的主要候选材料。虽然人们很少关注电荷自由度,但电荷效应(如电极化)可能会在该体系中出现。在此,我们通过单晶 X 射线衍射、二次谐波发生(SHG)和介电测量,报告了 α-RuCl3 中扭曲诱导的局部电极化。二次谐波发生(SHG)信号出现在室温下,当短程自旋相关性发挥作用时,SHG 信号在基塔耶夫顺磁态下大幅发展。尽管在基塔耶夫顺磁态下存在相当大的热释电电流,但极化-电场(P-E)中没有滞后现象,这表明电极化具有短程性质。这种局部电极化很可能是扭曲诱导电荷二聚化的结果,是通过虚跳诱导电荷再分布实现的。此外,在基塔耶夫顺磁态中,短程自旋相关性通过自旋-声子耦合增强了电极化。我们的研究结果强调了α-RuCl3 中电荷自由度的重要性,为研究基塔耶夫材料中的电荷效应建立了一个新平台。
{"title":"Evidence for distortion-induced local electric polarization in α-RuCl3","authors":"Xinrun Mi, De Hou, Xiao Wang, Sabreen Hammouda, Caixing Liu, Zijian Xiong, Han Li, Yan Liu, Guiwen Wang, Aifeng Wang, Yisheng Chai, Yang Qi, Wei Li, Xiaoyuan Zhou, Yixi Su, D. I. Khomskii, Mingquan He, Zhigao Sheng, Young Sun","doi":"10.1007/s11433-024-2417-8","DOIUrl":"10.1007/s11433-024-2417-8","url":null,"abstract":"<div><p>The spin-orbit assisted Mott insulator α-RuCl<sub>3</sub> is a prime candidate for material realization of the Kitaev quantum spin liquid. While little attention has been paid to charge degrees of freedom, charge effects, such as electric polarization, may arise in this system. Here, we report distortion-induced local electric polarization in α-RuCl<sub>3</sub> as evidenced by single-crystal X-ray diffraction, second harmonic generation (SHG) and dielectric measurements. The SHG signal appears at room temperature and develops substantially in the Kitaev paramagnetic state when short-range spin correlations come into play. Despite sizable pyroelectric currents in the Kitaev paramagnetic state, the absence of hysteresis in the polarization-electric field (<i>P-E</i>) points to the short-range nature of electric polarization. This localized electric polarization is likely the result of distortion-induced charge dimerization, achieved through virtual hopping-induced charge redistribution. In addition, the electric polarization is boosted by short-range spin correlations via spin-phonon coupling in the Kitaev paramagnetic state. Our results emphasize the importance of charge degrees of freedom in α-RuCl<sub>3</sub>, which establish a novel platform to investigate charge effects in Kitaev materials.</p></div>","PeriodicalId":774,"journal":{"name":"Science China Physics, Mechanics & Astronomy","volume":"67 9","pages":""},"PeriodicalIF":6.4,"publicationDate":"2024-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141931568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-02DOI: 10.1007/s11433-024-2426-0
C. Hanhart
{"title":"Important step towards an understanding of the exotic Zc(3900)","authors":"C. Hanhart","doi":"10.1007/s11433-024-2426-0","DOIUrl":"10.1007/s11433-024-2426-0","url":null,"abstract":"","PeriodicalId":774,"journal":{"name":"Science China Physics, Mechanics & Astronomy","volume":"67 9","pages":""},"PeriodicalIF":6.4,"publicationDate":"2024-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142409396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-02DOI: 10.1007/s11433-024-2415-y
Weike Deng, Sheng Long, Jiliang Jing
We extend our research on the energy flux and waveform characteristics of gravitational waves generated by merging nonspinning binary black holes through self-consistent effective one-body theory to include binary systems with slowly spinning black holes. Initially, we decompose the equation for the null tetrad component of the gravitationally perturbed Weyl tensor ψ